By using a rigid bulky carboxylic ligand a-cyanocinnamic acid(CCA),a dinuclear dysprosium(Ⅲ) complex [Dy_(2)(CCA)_(6)(MeOH)_(4)](1) was synthesized.Single crystal X-ray crystallography reveals that the two eight-coor...By using a rigid bulky carboxylic ligand a-cyanocinnamic acid(CCA),a dinuclear dysprosium(Ⅲ) complex [Dy_(2)(CCA)_(6)(MeOH)_(4)](1) was synthesized.Single crystal X-ray crystallography reveals that the two eight-coordinate dysprosium ions are bridged by four deprotonated carboxyl groups,forming a centrosymmetric paddle-wheel-1ike structure.Dynamic magnetic property measurements indicate that complex 1 displays field-induced slow magnetic relaxation.The temperature-dependent relaxation times can be fitted using Orbach and Raman processes with parameters of n=2.8(2),C=27(8) s^(-1)/K^(n),τ_(0)=5(2) × 10^(-10) s and U_(eff)=40(3) cm^(-1).Magnetic studies on the diamagnetic Y~Ⅲ-diluted analogue[Dy_(0.206)Y_(1.794)(CCA)_(6)(MeOH)_(4)](2) reveal its slow magnetic relaxation behavior without external dc field and the antiferromagnetic coupling between the Dy^(Ⅲ) ions in 1.Fits on the obtained relaxation times of 2lead to the parameters of n=4.5(3),C=0.7(2) s^(-1)/K^(n),τ_0=2.8(2) × 10^(-9) s and U_(eff)=38(2) cm^(-1).The results suggest that slow magnetic relaxation originates from the single-ion relaxation of Dy^(Ⅲ) ions.Moreover,the diamagnetic dilution can suppress other fast relaxation pathways at low temperature,on account of the elimination of magnetic coupling and dipolar interaction.Ab initio calculations were then performed on the single Dy^(Ⅲ) ion species {YDy} and indicate that the first excited Kramers doublets(KDs)lie at ca.76 cm^(-1),which is slightly higher than the experimental U_(eff) value.The intramolecular magnetic interactions were also calculated and indicate a weak ferromagnetic dipole-diploe magnetic interaction and an antiferromagnetic exchange coupling.展开更多
Simultaneous effects of conduction band non-parabolicity and hydrostatic pressure on the binding energies of 1S, 2S, and 2P states along with diamagnetic susceptibility of an on-center hydrogenic impurity confined in ...Simultaneous effects of conduction band non-parabolicity and hydrostatic pressure on the binding energies of 1S, 2S, and 2P states along with diamagnetic susceptibility of an on-center hydrogenic impurity confined in typical GaAs/Alx- Ga1-x As spherical quantum dots are theoretically investigated using the matrix diagonalization method. In this regard, the effect of band non-parabolieity has been performed using the Luttinger-Kohn effective mass equation. The binding energies and the diamagnetic susceptibility of the hydrogenic impurity are computed as a function of the dot radius and different values of the pressure in the presence of conduction band non-parabolicity effect. The results we arrived at are as follows： the incorporation of the band edge non-parabolicity increases the binding energies and decreases the absolute value of the diamagnetic susceptibility for a given pressure and radius; the binding energies increase and the magnitude of the diamagnetic susceptibility reduces with increasing pressure.展开更多
As an innovative,low-power consuming,and low-stiffness suspension approach,the diamagnetic levitation technique has attracted considerable interest because of its potential applicability in miniaturized mechanical sys...As an innovative,low-power consuming,and low-stiffness suspension approach,the diamagnetic levitation technique has attracted considerable interest because of its potential applicability in miniaturized mechanical systems.The foundation of a diamagnetic levitation system is mathematical modeling,which is essential for operating performance optimization and stability prediction.However,few studies on systematic mathematical modeling have been reported.In this study,a systematic mathematical model for a disc-shaped diamagnetically levitated rotor on a permanent magnet array is proposed.Based on the proposed model,the magnetic field distribution characteristics,diamagnetic levitation force characteristics(i.e.,levitation height and stiffness),and optimized theoretical conditions for realizing stable levitation are determined.Experiments are conducted to verify the feasibility of the proposed mathematical model.Theoretical predictions and experimental results indicate that increasing the levitation height enlarges the stable region.Moreover,with a further increase in the rotor radius,the stable regions of the rotor gradually diminish and even vanish.Thus,when the levitation height is fixed,a moderate rotor radius permits stable levitation.This study proposes a mathematical modeling method for a diamagnetic levitation system that has potential applications in miniaturized mechanical systems.展开更多
The spectra of Rydberg hydrogen atom in magnetic fields have been calculated using linear variational method with B-splines basis functions [Acta Phys. Sin. 55 （2006） 3380]. Based on these calculations we have done...The spectra of Rydberg hydrogen atom in magnetic fields have been calculated using linear variational method with B-splines basis functions [Acta Phys. Sin. 55 （2006） 3380]. Based on these calculations we have done some statistics analysis about the high Rydberg energy levels. The nearest-neighbor energy spacing distribution and the 3-statistics have been shown about diamagnetic Rydberg hydrogen atom with the magnetic field being 0.6 T and 6 T. The phenomena of multiply crossing, multiply anti-crossing, and the mixed of crossing and anti-crossing of energy levels have appeared in this paper. For both cases, in range of lower energy, the energy 1evel statistics properties close to Poisson distribution. With the increasing of the energy, the energy level statistics properties are away to Poisson distribution and tend to Wigner distribution step by step.展开更多
A theoretical calculation is carried out to investigate the spectrum of a barium Rydberg atom in an external magnetic field. Using an effective approach incorporating quantum defect into the centrifugal term in the Ha...A theoretical calculation is carried out to investigate the spectrum of a barium Rydberg atom in an external magnetic field. Using an effective approach incorporating quantum defect into the centrifugal term in the Hamiltonian, we reexamine the reported spectrum of the barium Rydberg atom in a magnetic field of 2.89 T [J. Phys. B 28 L537 （1995）]. Our calculation employs B-spline basis expansion and complex coordinate rotation techniques. For single photon absorption from the ground 6s2 to 6snp Rydberg states, the spectrum is not influenced by quantum defects of channels ns and nd. The calculation is in agreement with the experimental observations until the energy reaches E = -60 cm-1. Beyond this energy, closer to the threshold, the calculated and experimental results do not agree with each other. Possible reasons for their discrepancies are discussed. Our study affirms an energy range where the diamagnetic spectrum of the barium atom can be explained thoroughly using a hydrogen model potential.展开更多
The linear analysis of the influence of diamagnetic effect and toroidal rotation at the edge of tokamak plasmas with BOUT++ is discussed in this paper. This analysis is done by solving the dispersion relation, which i...The linear analysis of the influence of diamagnetic effect and toroidal rotation at the edge of tokamak plasmas with BOUT++ is discussed in this paper. This analysis is done by solving the dispersion relation, which is calculated through the numerical integration of the terms with different physics. This method is able to reveal the contributions of the different terms to the total growth rate. The diamagnetic effect stabilizes the ideal ballooning modes through inhibiting the contribution of curvature. The toroidal rotation effect is also able to suppress the curvaturedriving term, and the stronger shearing rate leads to a stronger stabilization effect. In addition,through linear analysis using the energy form, the curvature-driving term provides the free energy absorbed by the line-bending term, diamagnetic term and convective term.展开更多
A novel micro-machined diamagnetic stable.levitation system （MDSLS） which is composed of a free permanent magnetic rotor, a ring lifting permanent magnet and two diamagnetic stabilizers was presented. The static and...A novel micro-machined diamagnetic stable.levitation system （MDSLS） which is composed of a free permanent magnetic rotor, a ring lifting permanent magnet and two diamagnetic stabilizers was presented. The static and dynamic stable characters of MDSLS were analyzed. The coupled non-linear differential equations were used to describe six-degree-of-freedom motion of the levitated rotor, and the equivalent surface current and combined dia- magnetic image current method were utilized to model the interaction forces and torques between the lifting perma- nent magnet and rotor permanent magnet and also between the rotor permanent magnet and diamagnetic sub- strates. Because of difficulty to get analytical solution, the numerical calculation based on Runge-Kutta method was used to solve the dynamic model. The vibration frequencies were identified b~ fast Fourier transform （FFT） analysis. According to their resonance characteristics and parameters, the translational and angular dynamic stiff- ness were also calculated. The results show that the levitation of the rotor in MDSLS is stable, and the MDSLS is potential for the application in levitation inertial sensor.展开更多
A paper by Mi et al. [1] suggested that certain nano-sized hematite (α-Fe2O3) particles had diamagnetic properties at room temperature. Since diamagnetic behavior is not a property normally attributed to hem...A paper by Mi et al. [1] suggested that certain nano-sized hematite (α-Fe2O3) particles had diamagnetic properties at room temperature. Since diamagnetic behavior is not a property normally attributed to hematite particles (hematite is generally regarded as a canted antiferromagnetic material at room temperature) we decided to test the validity of the suggestions in [1] by performing magnetic susceptibility and magnetic hysteresis measurements on a series of hematite nanoparticles with average sizes of 8 nm, 30 nm and 40 nm in diameter. We initially considered two possible explanations for the apparent diamagnetic behavior of the nanoparticles in [1]: either 1) the hematite nanoparticles themselves exhibited this unusual diamagnetic behavior, or 2) the diamagnetic response was simply the signal created by a diamagnetic dispersant that was overriding a weak positive magnetic susceptibility signal of the hematite nanoparticles. Our experiments strongly suggested the latter explanation that the apparent “diamagnetic” behavior seen in [1] was caused by a diamagnetic dispersant dominating the magnetic properties of the dispersed hematite nanoparticles.展开更多
With time-of-flight and electric field ionization detection technique, we investigate the motional Stark effect for highly excited Rydberg barium in high magnetic field and its active cancellation experimentally. In t...With time-of-flight and electric field ionization detection technique, we investigate the motional Stark effect for highly excited Rydberg barium in high magnetic field and its active cancellation experimentally. In the experiment, the atom beam is aligned at a small angle of 15° with respect to the magnetic field. The motional Stark effect cancellation is demonstrated on two sets of. circularly polarized spectra in static magnetic field B = 1.00000 Tesla and B = 1.70000 Tesla, respectively, although the effect is very small （- 3.5 Vcm^-1） in our apparatus configuration.展开更多
Existence of the magnetic field of Saturn and the temperature around 70 - 100 K nearby of it bring us to the idea of diamagnetism and superconductivity of the rings particles. The rings could emerge from the icy parti...Existence of the magnetic field of Saturn and the temperature around 70 - 100 K nearby of it bring us to the idea of diamagnetism and superconductivity of the rings particles. The rings could emerge from the icy particles moving on chaotic orbits around Saturn within protoplanetary cloud. After appearance of the magnetic field of Saturn all chaotic orbits of icy particles start to shift to the magnetic equator plane, where there is a minimum of the particles magnetic energy, due to diamagnetic force of expulsion like Meissner phenomenon. Each particle comes to the stable position preventing its own horizontal and vertical shift. Particles are locked within three-dimensional magnetic well due to Abrikosov quantum vortex phenomenon for superconductor. This mechanism is valid and it works even particles have a small fraction of superconductor. Final picture is similar to the picture of iron particles forms the same shape around a magnet on laboratory table. Any other phenomena like gravity resonances, dusty plasma and others may bring some peculiarities to the final picture of the rings. It follows that magnetic field of Saturn and low temperature around of it are the main reason for the rings origin and the rings is product of the early time of the magnetic field of Saturn appearance. Additional matter to the rings also may come from the frozen water particles generated from the Saturn sputniks geysers due to magnetic coupling between planet and satellites. The data of Cassini mission to Saturn rings are conforming suggested theory of their origin and existence.展开更多
We report the direct observation of coupling between a single self-assembled InAs quantum dot and a wetting layer, based on strong diamagnetic shifts of many-body exciton states using magneto-photoluminescence spectro...We report the direct observation of coupling between a single self-assembled InAs quantum dot and a wetting layer, based on strong diamagnetic shifts of many-body exciton states using magneto-photoluminescence spectroscopy. An extremely large positive diamagnetic coefficient is observed when an electron in the wetting layer combines with a hole in the quantum dot; the coefficient is nearly one order of magnitude larger than that of the exciton states confined in the quantum dots. Recombination of electrons with holes in a quantum dot of the coupled system leads to an unusual negative diamagnetic effect, which is five times stronger than that in a pure quantum dot system. This effect can be attributed to the expansion of the wavefunction of remaining electrons in the wetting layer or the spread of electrons in the excited states of the quantum dot to the wetting layer after recombination. In this case, the wavefunction extent of the final states in the quantum dot plane is much larger than that of the initial states because of the absence of holes in the quantum dot to attract electrons. The properties of emitted photons that depend on the large electron wavefunction extents in the wetting layer indicate that the coupling occurs between systems of different dimensionality, which is also verified from the results obtained by applying a magnetic field in different configurations. This study paves a new way to observe hybrid states with zero- and two-dimensional structures, which could be useful for investigating the Kondo physics and implementing spin-based solid-state quantum information processing.展开更多
The chirality-induced spin selectivity(CISS)has been found in the antiferromagnetic and paramagnetic chiral inorganic materials with unpaired electrons,while rarely reported in the spin-paired diamagnetic inorganic ma...The chirality-induced spin selectivity(CISS)has been found in the antiferromagnetic and paramagnetic chiral inorganic materials with unpaired electrons,while rarely reported in the spin-paired diamagnetic inorganic materials with spin-pairing energy.Here,we report the CISS in the spin-paired diamagnetic BiOBr endowed with three levels of chiral mesostructures.Chiral mesostructured BiOBr films(CMBFs)were fabricated through a sugar alcohol-induced hydrothermal route.The antipodal CMBFs exhibited chirality-dependent,magnetic field-independent magnetic circular dichroism(MCD)signals,which indicates the existence of spin selectivity.The spin selectivity of CMBFs was speculated to be the result of the competing effect between the externally applied magnetic field and the effective magnetic field arisen from the spin electron motions in chiral potential.The chirality-induced effective magnetic field acts on the magnetic moment of electrons,potentially overcoming the spin-pairing energy and producing opposite energy changes for spin-down and spin-up electrons.展开更多
Crystal-phase low-dimensional structures offer great potential for the implementation of photonic devices of interest for quantum information processing.In this context,unveiling the fundamental parameters of the crys...Crystal-phase low-dimensional structures offer great potential for the implementation of photonic devices of interest for quantum information processing.In this context,unveiling the fundamental parameters of the crystal phase structure is of much relevance for several applications.Here,we report on the anisotropy of the g-factor tensor and diamagnetic coefficient in wurtzite/zincblende(WZ/ZB)crystal-phase quantum dots(QDs)realized in single InP nanowires.The WZ and ZB alternating axial sections in the NWs are identified by high-angle annular dark-field scanning transmission electron microscopy.The electron(hole)g-factor tensor and the exciton diamagnetic coefficients in WZ/ZB crystal-phase QDs are determined through micro-photoluminescence measurements at low temperature(4.2 K)with different magnetic field configurations,and rationalized by invoking the spin-correlated orbital current model.Our work provides key parameters for band gap engineering and spin states control in crystal-phase low-dimensional structures in nanowires.展开更多
For predicting the molar diamagnetic susceptibilities of inorganic compounds, a novel connectivity index ^mG based on adjacency matrix of molecular graphs and ionic parameter gi was proposed. The gi is defined as gi=...For predicting the molar diamagnetic susceptibilities of inorganic compounds, a novel connectivity index ^mG based on adjacency matrix of molecular graphs and ionic parameter gi was proposed. The gi is defined as gi=（ni^0.5-0.91）^4·xi^0.5｜Zi^0.5, where Zi, ni, xi are the valence, the outer electronic shell primary quantum number, and the electronegativity of atom i respectively. The good QSPR models for the molar diamagnetic susceptibilities can be constructed from ^0G and ^1G by using multivariate linear regression （MLR） method and artificial neural network （NN） method. The correlation coefficient r, standard error, and average absolute deviation of the MLR model and NN model are 0.9868, 5.47 cgs, 4.33 cgs, 0.9885, 5.09 cgs and 4.06 cgs, respectively, for the 144 inorganic compounds. The cross-validation by using the leave-one-out method demonstrates that the MLR model is highly reliable from the point of view of statistics. The average absolute deviations of predicted values of the molar diamagnetic susceptibility of other 62 inorganic compounds （test set） are 4.72 cgs and 4.06 cgs for the MLR model and NN model. The results show that the current method is more effective than literature methods for estimating the molar diamagnetic susceptibility of an inorganic compound. Both MLR and NN methods can provide acceptable models for the prediction of the molar diamagnetic susceptibilities. The NN model for the molar diamagnetic susceptibilities appears more reliable than the MLR model.展开更多
Ⅰ. INTRODUCTION Studies on the coordination of metal ions with ligands in aqueous solution are in fashion in inorganic biochemistry. So far, there have been only three methods known in the study on the coordination o...Ⅰ. INTRODUCTION Studies on the coordination of metal ions with ligands in aqueous solution are in fashion in inorganic biochemistry. So far, there have been only three methods known in the study on the coordination of metal ions in aqueous solution by NMR, i.e. by展开更多
TTHA complexes with diamagnetic rare earth ions (La3+, Y3+ and Lu3+) were studied by 1H and 13C NMR spectroscopy. A symmetric structural model was suggested for La(TTHA) complex and an asymmetric model for Y(TTHA) and...TTHA complexes with diamagnetic rare earth ions (La3+, Y3+ and Lu3+) were studied by 1H and 13C NMR spectroscopy. A symmetric structural model was suggested for La(TTHA) complex and an asymmetric model for Y(TTHA) and Lu(TTHA) complexes. The complex formation was dependent on the pH value of the solution. The interactions of La(TTHA) with the additional metal ions (La3+, Y3+ and Ca2+) were relatively weak, but relatively strong for that of Lu(TTHA) with the additional Lu3+.展开更多
Spin chiral anisotropy(SChA)refers to the occurrence of different spin polarization in antipodal chiral structures.Herein,we report the SChA in diamagnetic chiral mesostructured In2O3 films(CMIFs)with manifestation of...Spin chiral anisotropy(SChA)refers to the occurrence of different spin polarization in antipodal chiral structures.Herein,we report the SChA in diamagnetic chiral mesostructured In2O3 films(CMIFs)with manifestation of chirality-dependent magnetic circular dichroism(MCD)signals.CMIFs were grown on fluorine-doped tin dioxide conductive glass(FTO)substrates,which were synthesized via a hydrothermal route,with malic acid used as the symmetry-breaking agent.Two levels of chirality have been identified in CMIFs:primary nanoflakes with atomically twisted crystal lattices and secondary helical stacking of the nanoflakes.CMIFs exhibit chirality-dependent asymmetric MCD signals due to the different interactions of chirality-induced effective magnetic field and external magnetic field,which distinguish from the commonly observed external magnetic fielddependent symmetric MCD signals.These findings provide insights into spin manipulation of spin-paired diamagnets.展开更多
In this study,we present a comprehensive evaluation of the magnetic field measurements from the Vector Field Magnetometer(VFM)aboard the recently launched Macao Science Satellite-1(MSS-1).One-year data from November 2...In this study,we present a comprehensive evaluation of the magnetic field measurements from the Vector Field Magnetometer(VFM)aboard the recently launched Macao Science Satellite-1(MSS-1).One-year data from November 2,2023,to November 1,2024,are considered.The MSS-1 flies with a low inclination(41°)and is designed to provide high-resolution magnetic field measurements,especially for monitoring the evolution of the South Atlantic Anomaly.Earlier studies confirmed the possibility of using MSS-1A data to model the Earth’s main magnetic field(e.g.,Jiang Y et al.,2024).Therefore,in this study we focus on the magnetic signatures related to the external field,which are primarily associated with magnetospheric and ionospheric currents.The global distributions of the magnetic residuals from MSS-1A show a pattern consistent with that derived from the European Space Agency’s Swarm A satellite.A statistical survey of the conjugated observations(withΔt<5 min andΔR<150 km)between the two satellites showed that the difference between their magnetic residuals is within±3 nanoteslas.By separating the magnetic residuals at the noon and midnight hours,we see that the MSS-1A data can effectively capture features of the magnetospheric and ionospheric currents,such as the magnetospheric ring current and ionospheric equatorial electrojet.Moreover,the magnetic residuals from MSS-1A show a diamagnetic effect caused by post-sunset equatorial plasma bubbles,which also suggests that the MSS-1A data have the potential to reveal the ionospheric structures.The comprehensive evaluations performed within this study demonstrate that the MSS-1A provides high-quality magnetic field data reaching the level of the Swarm satellite,which enables a deeper understanding of the modeling of Earth’s magnetic field as well as monitoring of the magnetic environment.展开更多
Zero resistance and Meissner effect are two crucial experimental evidences of superconductivity in determining a new kind of superconductor, which can be detected by transport and diamagnetic measurements. In this pap...Zero resistance and Meissner effect are two crucial experimental evidences of superconductivity in determining a new kind of superconductor, which can be detected by transport and diamagnetic measurements. In this paper, we briefly review the main transport and magnetization results on the one unit cell （1-UC） FeSe films grown on SrTiO3 （STO） substrates from our team in recent years, which identify the high temperature superconductivity in 1-UC FeSe films.展开更多
Chou and Chen’s report in the 1970s suggested conformational protein adaptation (CPA) might be influenced by low frequency phonons acting as “a possible information system”. This report proposes the universal force...Chou and Chen’s report in the 1970s suggested conformational protein adaptation (CPA) might be influenced by low frequency phonons acting as “a possible information system”. This report proposes the universal force of electromagnetism initiates the phonon system they cited as it per-turbs paramagnetic/diamagnetic dampers within the protein matrix to produce a quantized low frequency phonon signal series. (http://www.phy.ilstu.edu/~ren/phononsims/page3.html) The signal series is iteratively processed by the protein beta sub-unit, the system, to posi-tion the alpha sub-unit, the outcome, a classic non-linear resonance system resulting in con-formational protein adaptation (CPA). CPA “priming” enables a secondary ATP/redox driven power system to complete cell activity. The evolutionary appearance of these two systems reflects their hierarchy: 1) a low energy phonon driven information control circuit governed by principles of physics that, along with proteins, may have preceded planet earth, and 2), an ATP/redox power completion circuit directed by principles of chemistry that evolved in living systems 1 billion or more years after earth formed.展开更多
基金Project supported by the National Natural Science Foundation of China (21805048,22005069)the Natural Science Foundation of Guangdong Province (2022A1515011145,2023A1515010602)+2 种基金the Science and Technology Research Project of Guangzhou (202102080023,202201020166)the Project for Key Areas of Ordinary Colleges and Universities of Guangdong Province(2022ZDZX4035)the "Climbing Program" Special Funds of Guangdong Province (pdjh 2023b0389)。
文摘By using a rigid bulky carboxylic ligand a-cyanocinnamic acid(CCA),a dinuclear dysprosium(Ⅲ) complex [Dy_(2)(CCA)_(6)(MeOH)_(4)](1) was synthesized.Single crystal X-ray crystallography reveals that the two eight-coordinate dysprosium ions are bridged by four deprotonated carboxyl groups,forming a centrosymmetric paddle-wheel-1ike structure.Dynamic magnetic property measurements indicate that complex 1 displays field-induced slow magnetic relaxation.The temperature-dependent relaxation times can be fitted using Orbach and Raman processes with parameters of n=2.8(2),C=27(8) s^(-1)/K^(n),τ_(0)=5(2) × 10^(-10) s and U_(eff)=40(3) cm^(-1).Magnetic studies on the diamagnetic Y~Ⅲ-diluted analogue[Dy_(0.206)Y_(1.794)(CCA)_(6)(MeOH)_(4)](2) reveal its slow magnetic relaxation behavior without external dc field and the antiferromagnetic coupling between the Dy^(Ⅲ) ions in 1.Fits on the obtained relaxation times of 2lead to the parameters of n=4.5(3),C=0.7(2) s^(-1)/K^(n),τ_0=2.8(2) × 10^(-9) s and U_(eff)=38(2) cm^(-1).The results suggest that slow magnetic relaxation originates from the single-ion relaxation of Dy^(Ⅲ) ions.Moreover,the diamagnetic dilution can suppress other fast relaxation pathways at low temperature,on account of the elimination of magnetic coupling and dipolar interaction.Ab initio calculations were then performed on the single Dy^(Ⅲ) ion species {YDy} and indicate that the first excited Kramers doublets(KDs)lie at ca.76 cm^(-1),which is slightly higher than the experimental U_(eff) value.The intramolecular magnetic interactions were also calculated and indicate a weak ferromagnetic dipole-diploe magnetic interaction and an antiferromagnetic exchange coupling.
文摘Simultaneous effects of conduction band non-parabolicity and hydrostatic pressure on the binding energies of 1S, 2S, and 2P states along with diamagnetic susceptibility of an on-center hydrogenic impurity confined in typical GaAs/Alx- Ga1-x As spherical quantum dots are theoretically investigated using the matrix diagonalization method. In this regard, the effect of band non-parabolieity has been performed using the Luttinger-Kohn effective mass equation. The binding energies and the diamagnetic susceptibility of the hydrogenic impurity are computed as a function of the dot radius and different values of the pressure in the presence of conduction band non-parabolicity effect. The results we arrived at are as follows： the incorporation of the band edge non-parabolicity increases the binding energies and decreases the absolute value of the diamagnetic susceptibility for a given pressure and radius; the binding energies increase and the magnitude of the diamagnetic susceptibility reduces with increasing pressure.
基金Supported by National Natural Science Foundation of China (Grant No.52275537)Nanjing Major Scientific and Technological Project of China (Grant No.202209011)。
文摘As an innovative,low-power consuming,and low-stiffness suspension approach,the diamagnetic levitation technique has attracted considerable interest because of its potential applicability in miniaturized mechanical systems.The foundation of a diamagnetic levitation system is mathematical modeling,which is essential for operating performance optimization and stability prediction.However,few studies on systematic mathematical modeling have been reported.In this study,a systematic mathematical model for a disc-shaped diamagnetically levitated rotor on a permanent magnet array is proposed.Based on the proposed model,the magnetic field distribution characteristics,diamagnetic levitation force characteristics(i.e.,levitation height and stiffness),and optimized theoretical conditions for realizing stable levitation are determined.Experiments are conducted to verify the feasibility of the proposed mathematical model.Theoretical predictions and experimental results indicate that increasing the levitation height enlarges the stable region.Moreover,with a further increase in the rotor radius,the stable regions of the rotor gradually diminish and even vanish.Thus,when the levitation height is fixed,a moderate rotor radius permits stable levitation.This study proposes a mathematical modeling method for a diamagnetic levitation system that has potential applications in miniaturized mechanical systems.
基金Supported by the National Natural Science Foundation of China under Grant No.10774042
文摘The spectra of Rydberg hydrogen atom in magnetic fields have been calculated using linear variational method with B-splines basis functions [Acta Phys. Sin. 55 （2006） 3380]. Based on these calculations we have done some statistics analysis about the high Rydberg energy levels. The nearest-neighbor energy spacing distribution and the 3-statistics have been shown about diamagnetic Rydberg hydrogen atom with the magnetic field being 0.6 T and 6 T. The phenomena of multiply crossing, multiply anti-crossing, and the mixed of crossing and anti-crossing of energy levels have appeared in this paper. For both cases, in range of lower energy, the energy 1evel statistics properties close to Poisson distribution. With the increasing of the energy, the energy level statistics properties are away to Poisson distribution and tend to Wigner distribution step by step.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11174329 and 91121005)the National Basic Research Program of China(Grant Nos.2012CB922101 and 2013CB922003)
文摘A theoretical calculation is carried out to investigate the spectrum of a barium Rydberg atom in an external magnetic field. Using an effective approach incorporating quantum defect into the centrifugal term in the Hamiltonian, we reexamine the reported spectrum of the barium Rydberg atom in a magnetic field of 2.89 T [J. Phys. B 28 L537 （1995）]. Our calculation employs B-spline basis expansion and complex coordinate rotation techniques. For single photon absorption from the ground 6s2 to 6snp Rydberg states, the spectrum is not influenced by quantum defects of channels ns and nd. The calculation is in agreement with the experimental observations until the energy reaches E = -60 cm-1. Beyond this energy, closer to the threshold, the calculated and experimental results do not agree with each other. Possible reasons for their discrepancies are discussed. Our study affirms an energy range where the diamagnetic spectrum of the barium atom can be explained thoroughly using a hydrogen model potential.
基金supported by program of Fusion Reactor Physics and Digital Tokamak with the CAS ‘OneThree-Five’ Strategic Planningthe JSPS-NRF-NSFC A3 Foresight Program in the field of Plasma Physics (NSFC: No. 11261140328 and NRF: No. z012K2A2A6000443)+1 种基金supported by National Natural Science Foundation of China under Contract Nos. 11405215, 11505236 and 11675217the National Magnetic Confinement Fusion Science Program of China under Contract Nos. 2015GB101003, 2014GB106001 and 2013GB111002
文摘The linear analysis of the influence of diamagnetic effect and toroidal rotation at the edge of tokamak plasmas with BOUT++ is discussed in this paper. This analysis is done by solving the dispersion relation, which is calculated through the numerical integration of the terms with different physics. This method is able to reveal the contributions of the different terms to the total growth rate. The diamagnetic effect stabilizes the ideal ballooning modes through inhibiting the contribution of curvature. The toroidal rotation effect is also able to suppress the curvaturedriving term, and the stronger shearing rate leads to a stronger stabilization effect. In addition,through linear analysis using the energy form, the curvature-driving term provides the free energy absorbed by the line-bending term, diamagnetic term and convective term.
基金The National Natural Science Foundation ofChina (No60402003)The Weaponry Pre-liminary Research Foundation of China (No9140A09020706JW0314)
文摘A novel micro-machined diamagnetic stable.levitation system （MDSLS） which is composed of a free permanent magnetic rotor, a ring lifting permanent magnet and two diamagnetic stabilizers was presented. The static and dynamic stable characters of MDSLS were analyzed. The coupled non-linear differential equations were used to describe six-degree-of-freedom motion of the levitated rotor, and the equivalent surface current and combined dia- magnetic image current method were utilized to model the interaction forces and torques between the lifting perma- nent magnet and rotor permanent magnet and also between the rotor permanent magnet and diamagnetic sub- strates. Because of difficulty to get analytical solution, the numerical calculation based on Runge-Kutta method was used to solve the dynamic model. The vibration frequencies were identified b~ fast Fourier transform （FFT） analysis. According to their resonance characteristics and parameters, the translational and angular dynamic stiff- ness were also calculated. The results show that the levitation of the rotor in MDSLS is stable, and the MDSLS is potential for the application in levitation inertial sensor.
文摘A paper by Mi et al. [1] suggested that certain nano-sized hematite (α-Fe2O3) particles had diamagnetic properties at room temperature. Since diamagnetic behavior is not a property normally attributed to hematite particles (hematite is generally regarded as a canted antiferromagnetic material at room temperature) we decided to test the validity of the suggestions in [1] by performing magnetic susceptibility and magnetic hysteresis measurements on a series of hematite nanoparticles with average sizes of 8 nm, 30 nm and 40 nm in diameter. We initially considered two possible explanations for the apparent diamagnetic behavior of the nanoparticles in [1]: either 1) the hematite nanoparticles themselves exhibited this unusual diamagnetic behavior, or 2) the diamagnetic response was simply the signal created by a diamagnetic dispersant that was overriding a weak positive magnetic susceptibility signal of the hematite nanoparticles. Our experiments strongly suggested the latter explanation that the apparent “diamagnetic” behavior seen in [1] was caused by a diamagnetic dispersant dominating the magnetic properties of the dispersed hematite nanoparticles.
基金Supported by the National Natural Science Foundation of China under Grant No 10404033.
文摘With time-of-flight and electric field ionization detection technique, we investigate the motional Stark effect for highly excited Rydberg barium in high magnetic field and its active cancellation experimentally. In the experiment, the atom beam is aligned at a small angle of 15° with respect to the magnetic field. The motional Stark effect cancellation is demonstrated on two sets of. circularly polarized spectra in static magnetic field B = 1.00000 Tesla and B = 1.70000 Tesla, respectively, although the effect is very small （- 3.5 Vcm^-1） in our apparatus configuration.
文摘Existence of the magnetic field of Saturn and the temperature around 70 - 100 K nearby of it bring us to the idea of diamagnetism and superconductivity of the rings particles. The rings could emerge from the icy particles moving on chaotic orbits around Saturn within protoplanetary cloud. After appearance of the magnetic field of Saturn all chaotic orbits of icy particles start to shift to the magnetic equator plane, where there is a minimum of the particles magnetic energy, due to diamagnetic force of expulsion like Meissner phenomenon. Each particle comes to the stable position preventing its own horizontal and vertical shift. Particles are locked within three-dimensional magnetic well due to Abrikosov quantum vortex phenomenon for superconductor. This mechanism is valid and it works even particles have a small fraction of superconductor. Final picture is similar to the picture of iron particles forms the same shape around a magnet on laboratory table. Any other phenomena like gravity resonances, dusty plasma and others may bring some peculiarities to the final picture of the rings. It follows that magnetic field of Saturn and low temperature around of it are the main reason for the rings origin and the rings is product of the early time of the magnetic field of Saturn appearance. Additional matter to the rings also may come from the frozen water particles generated from the Saturn sputniks geysers due to magnetic coupling between planet and satellites. The data of Cassini mission to Saturn rings are conforming suggested theory of their origin and existence.
基金This work was supported by the National Basic Research Program of China （Nos. 2013CB328706 and 2014CB921003）, the National Natural Science Foundation of China （Nos. 91436101, 11174356, and 61275060）, the Strategic Priority Research Program of the Chinese Academy of Sciences （No. XDB07030200）, and the 100 Talents Program of Chinese Academy of Sciences. We thank Jean-Pierre Leburton for helpful discussions.
文摘We report the direct observation of coupling between a single self-assembled InAs quantum dot and a wetting layer, based on strong diamagnetic shifts of many-body exciton states using magneto-photoluminescence spectroscopy. An extremely large positive diamagnetic coefficient is observed when an electron in the wetting layer combines with a hole in the quantum dot; the coefficient is nearly one order of magnitude larger than that of the exciton states confined in the quantum dots. Recombination of electrons with holes in a quantum dot of the coupled system leads to an unusual negative diamagnetic effect, which is five times stronger than that in a pure quantum dot system. This effect can be attributed to the expansion of the wavefunction of remaining electrons in the wetting layer or the spread of electrons in the excited states of the quantum dot to the wetting layer after recombination. In this case, the wavefunction extent of the final states in the quantum dot plane is much larger than that of the initial states because of the absence of holes in the quantum dot to attract electrons. The properties of emitted photons that depend on the large electron wavefunction extents in the wetting layer indicate that the coupling occurs between systems of different dimensionality, which is also verified from the results obtained by applying a magnetic field in different configurations. This study paves a new way to observe hybrid states with zero- and two-dimensional structures, which could be useful for investigating the Kondo physics and implementing spin-based solid-state quantum information processing.
基金supported by the National Key R&D Program of China(No.2021YFA1200300)the National Natural Science Foundation of China(Nos.21931008,21975184,21873072,and 21922304)the scientific foundation of the Shanghai Municipal Science and Technology Commission(Nos.19JC1410300).
文摘The chirality-induced spin selectivity(CISS)has been found in the antiferromagnetic and paramagnetic chiral inorganic materials with unpaired electrons,while rarely reported in the spin-paired diamagnetic inorganic materials with spin-pairing energy.Here,we report the CISS in the spin-paired diamagnetic BiOBr endowed with three levels of chiral mesostructures.Chiral mesostructured BiOBr films(CMBFs)were fabricated through a sugar alcohol-induced hydrothermal route.The antipodal CMBFs exhibited chirality-dependent,magnetic field-independent magnetic circular dichroism(MCD)signals,which indicates the existence of spin selectivity.The spin selectivity of CMBFs was speculated to be the result of the competing effect between the externally applied magnetic field and the effective magnetic field arisen from the spin electron motions in chiral potential.The chirality-induced effective magnetic field acts on the magnetic moment of electrons,potentially overcoming the spin-pairing energy and producing opposite energy changes for spin-down and spin-up electrons.
基金This work was supported by the National Natural Science Foundation of China(Nos.11934019,61675228,11721404,51761145104,and 11874419)the Strategic Priority Research Program,the Instrument Developing Project and the Interdisciplinary Innovation Team of the Chinese Academy of Sciences(Nos.XDB28000000 and YJKYYQ20180036)+2 种基金the Key RD Program of Guangdong Province(No.2018B030329001)the Key Laboratory Fund(No.614280303051701)We acknowledge financial support from the SUPERTOP project,QUANTERA ERA-NET Cofund in Quantum Technologies.
文摘Crystal-phase low-dimensional structures offer great potential for the implementation of photonic devices of interest for quantum information processing.In this context,unveiling the fundamental parameters of the crystal phase structure is of much relevance for several applications.Here,we report on the anisotropy of the g-factor tensor and diamagnetic coefficient in wurtzite/zincblende(WZ/ZB)crystal-phase quantum dots(QDs)realized in single InP nanowires.The WZ and ZB alternating axial sections in the NWs are identified by high-angle annular dark-field scanning transmission electron microscopy.The electron(hole)g-factor tensor and the exciton diamagnetic coefficients in WZ/ZB crystal-phase QDs are determined through micro-photoluminescence measurements at low temperature(4.2 K)with different magnetic field configurations,and rationalized by invoking the spin-correlated orbital current model.Our work provides key parameters for band gap engineering and spin states control in crystal-phase low-dimensional structures in nanowires.
基金Project supported by the University Natural Science Foundation of Jiangsu Province （No. 04KJD150195）. Acknowledgement The authors wish to express our gratitude to the referees for their value comments.
文摘For predicting the molar diamagnetic susceptibilities of inorganic compounds, a novel connectivity index ^mG based on adjacency matrix of molecular graphs and ionic parameter gi was proposed. The gi is defined as gi=（ni^0.5-0.91）^4·xi^0.5｜Zi^0.5, where Zi, ni, xi are the valence, the outer electronic shell primary quantum number, and the electronegativity of atom i respectively. The good QSPR models for the molar diamagnetic susceptibilities can be constructed from ^0G and ^1G by using multivariate linear regression （MLR） method and artificial neural network （NN） method. The correlation coefficient r, standard error, and average absolute deviation of the MLR model and NN model are 0.9868, 5.47 cgs, 4.33 cgs, 0.9885, 5.09 cgs and 4.06 cgs, respectively, for the 144 inorganic compounds. The cross-validation by using the leave-one-out method demonstrates that the MLR model is highly reliable from the point of view of statistics. The average absolute deviations of predicted values of the molar diamagnetic susceptibility of other 62 inorganic compounds （test set） are 4.72 cgs and 4.06 cgs for the MLR model and NN model. The results show that the current method is more effective than literature methods for estimating the molar diamagnetic susceptibility of an inorganic compound. Both MLR and NN methods can provide acceptable models for the prediction of the molar diamagnetic susceptibilities. The NN model for the molar diamagnetic susceptibilities appears more reliable than the MLR model.
基金Proj ect supported by the National Natural Science Foundation of China
文摘Ⅰ. INTRODUCTION Studies on the coordination of metal ions with ligands in aqueous solution are in fashion in inorganic biochemistry. So far, there have been only three methods known in the study on the coordination of metal ions in aqueous solution by NMR, i.e. by
基金Project supported by the National Natural Science Foundation of China and the Science Foundation of Laboratory of Rare Earth Chemistry and Physics.
文摘TTHA complexes with diamagnetic rare earth ions (La3+, Y3+ and Lu3+) were studied by 1H and 13C NMR spectroscopy. A symmetric structural model was suggested for La(TTHA) complex and an asymmetric model for Y(TTHA) and Lu(TTHA) complexes. The complex formation was dependent on the pH value of the solution. The interactions of La(TTHA) with the additional metal ions (La3+, Y3+ and Ca2+) were relatively weak, but relatively strong for that of Lu(TTHA) with the additional Lu3+.
基金supported by the National Key Research and Development Program of China(No.2021YFA1200301,S.A.C.)the National Natural Science Foundation of China(Nos.21931008,S.A.C.and 21975184,Y.Y.D.)Shanghai Pilot Program for Basic Research-Shanghai Jiao Tong University(No.21TQ1400219).
文摘Spin chiral anisotropy(SChA)refers to the occurrence of different spin polarization in antipodal chiral structures.Herein,we report the SChA in diamagnetic chiral mesostructured In2O3 films(CMIFs)with manifestation of chirality-dependent magnetic circular dichroism(MCD)signals.CMIFs were grown on fluorine-doped tin dioxide conductive glass(FTO)substrates,which were synthesized via a hydrothermal route,with malic acid used as the symmetry-breaking agent.Two levels of chirality have been identified in CMIFs:primary nanoflakes with atomically twisted crystal lattices and secondary helical stacking of the nanoflakes.CMIFs exhibit chirality-dependent asymmetric MCD signals due to the different interactions of chirality-induced effective magnetic field and external magnetic field,which distinguish from the commonly observed external magnetic fielddependent symmetric MCD signals.These findings provide insights into spin manipulation of spin-paired diamagnets.
基金supported by the National Natural Science Foundation of China(Grant Nos.42474200 and 42174186)Chao Xiong is supported by the Dragon 6 cooperation 2024-2028(Project No.95437).
文摘In this study,we present a comprehensive evaluation of the magnetic field measurements from the Vector Field Magnetometer(VFM)aboard the recently launched Macao Science Satellite-1(MSS-1).One-year data from November 2,2023,to November 1,2024,are considered.The MSS-1 flies with a low inclination(41°)and is designed to provide high-resolution magnetic field measurements,especially for monitoring the evolution of the South Atlantic Anomaly.Earlier studies confirmed the possibility of using MSS-1A data to model the Earth’s main magnetic field(e.g.,Jiang Y et al.,2024).Therefore,in this study we focus on the magnetic signatures related to the external field,which are primarily associated with magnetospheric and ionospheric currents.The global distributions of the magnetic residuals from MSS-1A show a pattern consistent with that derived from the European Space Agency’s Swarm A satellite.A statistical survey of the conjugated observations(withΔt<5 min andΔR<150 km)between the two satellites showed that the difference between their magnetic residuals is within±3 nanoteslas.By separating the magnetic residuals at the noon and midnight hours,we see that the MSS-1A data can effectively capture features of the magnetospheric and ionospheric currents,such as the magnetospheric ring current and ionospheric equatorial electrojet.Moreover,the magnetic residuals from MSS-1A show a diamagnetic effect caused by post-sunset equatorial plasma bubbles,which also suggests that the MSS-1A data have the potential to reveal the ionospheric structures.The comprehensive evaluations performed within this study demonstrate that the MSS-1A provides high-quality magnetic field data reaching the level of the Swarm satellite,which enables a deeper understanding of the modeling of Earth’s magnetic field as well as monitoring of the magnetic environment.
基金supported by the National Basic Research Program of China(Grant Nos.2013CB934600 and 2012CB921300)the National Natural Science Foundation of China(Grant Nos.11222434 and 11174007)the Research Fund for the Doctoral Program of Higher Education(RFDP)of China
文摘Zero resistance and Meissner effect are two crucial experimental evidences of superconductivity in determining a new kind of superconductor, which can be detected by transport and diamagnetic measurements. In this paper, we briefly review the main transport and magnetization results on the one unit cell （1-UC） FeSe films grown on SrTiO3 （STO） substrates from our team in recent years, which identify the high temperature superconductivity in 1-UC FeSe films.
文摘Chou and Chen’s report in the 1970s suggested conformational protein adaptation (CPA) might be influenced by low frequency phonons acting as “a possible information system”. This report proposes the universal force of electromagnetism initiates the phonon system they cited as it per-turbs paramagnetic/diamagnetic dampers within the protein matrix to produce a quantized low frequency phonon signal series. (http://www.phy.ilstu.edu/~ren/phononsims/page3.html) The signal series is iteratively processed by the protein beta sub-unit, the system, to posi-tion the alpha sub-unit, the outcome, a classic non-linear resonance system resulting in con-formational protein adaptation (CPA). CPA “priming” enables a secondary ATP/redox driven power system to complete cell activity. The evolutionary appearance of these two systems reflects their hierarchy: 1) a low energy phonon driven information control circuit governed by principles of physics that, along with proteins, may have preceded planet earth, and 2), an ATP/redox power completion circuit directed by principles of chemistry that evolved in living systems 1 billion or more years after earth formed.
