The conventional forming limit diagram （FLD） is described as a plot of major strain versus minor strain. However, FLD is dependent on forming history and strain path. In the present study, a forming limit stress-bas...The conventional forming limit diagram （FLD） is described as a plot of major strain versus minor strain. However, FLD is dependent on forming history and strain path. In the present study, a forming limit stress-based diagram （FLSD） has been adopted to predict the fracture limit of aluminum alloy （AA） 5052-O1 sheet. Nakazima test is simulated by plastic constitutive formula derived from the modified Gurson-Tvergaard-Needleman （GTN） model. An in situ tensile test with scanning electron microscope （SEM） is proposed to determine the parameters in GTN model. The damage evolution is observed and recorded, and the parameters of GTN model are identified through counting void fraction at three damage stages of AA5052-O 1. According to the experimental results, the original void volume fraction, the volume fraction of potential nucleated voids, the critical void volume fraction, the void volume fraction at the final failure of material are assigned as 0.002 918, 0.024 9, 0.030 103, 0.048 54, respectively. The stress and strain are obtained at the last loading step before crack. FLSD and FLD of AA5052-O 1 are plotted. Compared with the experimental Nakazima test and uniaxial tensile test, the predicted results show a good agreement. The parameters determined by in situ tensile test can be applied to the research of the forming limit for ductile metals.展开更多
Intense human activities have greatly changed the flood generation conditions in most areas of the world, and have destroyed the consistency in the annual flood peak and volume series. For design flood estimation, coa...Intense human activities have greatly changed the flood generation conditions in most areas of the world, and have destroyed the consistency in the annual flood peak and volume series. For design flood estimation, coaxial correlation diagram and conceptual hydrological model are two frequently used tools to adjust and reconstruct the flood series under human disturbance. This study took a typical mountain catchment of the Haihe River Basin as an example to investigate the effects of human activities on flood regime and to compare and assess the two adjustment methods. The main purpose is to construct a conceptual hydrological model which can incorporate the effects of human activities. The results show that the coaxial correlation diagram is simple and widely-used, but can only adjust the time series of total flood volumes. Therefore, it is only applicable under certain conditions(e.g. There is a strong link between the flood peaks and volumes and the link is not significantly affected by human activities). The conceptual model is a powerful tool to adjust the time series of both flood peak flows and flood volumes over different durations provided that it is closely related to the catchment hydrological characteristics, specifically accounting for the effects of human activities, and incorporating expert knowledge when estimating or calibrating parameters. It is suggested that the two methods should be used together to cross check each other.展开更多
First order reversal curves （FORC） of nanocomposite Nd2Fe14B/Fe3B magnetic materials were measured to attain a FORC diagram, which characterizes reversible magnetization, irreversible magnetization, and magnetic int...First order reversal curves （FORC） of nanocomposite Nd2Fe14B/Fe3B magnetic materials were measured to attain a FORC diagram, which characterizes reversible magnetization, irreversible magnetization, and magnetic interactions in a hysteresis system. Then, generalized mov- ing Preisach model （GMPM） was implemented based on the FORC diagram. Reversible and irreversible magnetizations shown in FORCs and a FORC diagram were used as an input of GMPM. Coupling interaction between reversible and irreversible magnetizations was added when calculating reversible magnetization. Meanwhile, irreversible magnetic moments＇ interaction was approximately represented by mean field interaction. The result shows that the simulated main curves mostly coincide with the experimental curves.展开更多
A three-step XML Schema modeling method is presented, namely first establishing a diagram of conceptual modeling, then transforming it to UML class diagram and finally mapping it to XML Schema. A case study of handlin...A three-step XML Schema modeling method is presented, namely first establishing a diagram of conceptual modeling, then transforming it to UML class diagram and finally mapping it to XML Schema. A case study of handling furniture design data is given to illustrate the detail of conversion process.展开更多
According to the railway transportation system＇s characteristics, a new cellular automaton model for the single- line railway system is presented in this paper. Based on this model, several simulations were done to i...According to the railway transportation system＇s characteristics, a new cellular automaton model for the single- line railway system is presented in this paper. Based on this model, several simulations were done to imitate the train operation under three working diagrams. From a different angle the results show how the organization of train operation impacts on the railway carrying capacity. By using the non-parallel train working diagram the influence of fast-train on slow-train is found to be the strongest. Many slow-trains have to wait in-between neighbouring stations to let the fast-train（s） pass through first. So the slow-train will advance like a wave propagating from the departure station to the arrival station. This also resembles the situation of a highway jammed traffic flow. Furthermore, the nonuniformity of travel times between the sections also greatly limits the railway carrying capacity. After converting the nonuniform sections into the sections with uniform travel times while the total travel time is kept unchanged, all three carrying capacities are improved greatly as shown by simulation. It also shows that the cellular automaton model is an effective and feasible way to investigate the railway transportation system.展开更多
A slightly modified central atoms model was proposed. The probabilities of various clusters with the central atoms and their nearest neighboring shells can be calculated neglecting the assumption of the parameter of e...A slightly modified central atoms model was proposed. The probabilities of various clusters with the central atoms and their nearest neighboring shells can be calculated neglecting the assumption of the parameter of energy in the central atoms model in proportion to the number of other atoms i (referred with the central atom). A parameter P α is proposed in this model, which equals to reciprocal of activity coefficient of α component, therefore, the new model can be understood easily. By this model, the Al Zn phase diagram and its thermodynamic properties were calculated, the results coincide with the experimental data.展开更多
Based on an analysis of 280 Type SNIa supernovae and gamma-ray bursts redshifts in the range of z = 0.0104 - 8.1 the Hubble diagram is shown to follow a strictly exponential slope predicting an exponentially expanding...Based on an analysis of 280 Type SNIa supernovae and gamma-ray bursts redshifts in the range of z = 0.0104 - 8.1 the Hubble diagram is shown to follow a strictly exponential slope predicting an exponentially expanding or static universe. At redshifts > 2 - 3 ΛCDM models show a poor agreement with the observed data. Based on the results presented in this paper, the Hubble diagram test does not necessarily support the idea of expansion according to the big-bang concordance model.展开更多
Based on the static compression experiments, the compressive stress-strain curve of multi-layer corrugated boards is simplified into three sections of linear elasticity, sub-buckling going with local collapse and dens...Based on the static compression experiments, the compressive stress-strain curve of multi-layer corrugated boards is simplified into three sections of linear elasticity, sub-buckling going with local collapse and densification. By considering the structure factors of multi-layer corrugated boards, the energy absorption model is obtained and characterized by the structure factors of corrugated cell-wall. The model is standardized by the solid modulus and it is universal for corrugated structures of different basis material. In the liner-elastic section, with the increase of the load, the energy absorption per unit volume of multi-layer corrugated boards gradually increases; in the sub-buckling section going with local collapse, the compression resistance of multi-layer corrugated boards goes on under a nearly constant load, but the energy absorption per unit volume rapidly increases with the increase of the compression strain. It is shown as an ascending curve in the energy absorption diagram. In the densification section, the corrugated sandwich core has no energy absorption capability. A good consistency is achieved between theoretical and experimental energy absorption curves. In designing the cushioning package, the cushioning properties can be evaluated by the theoretical model without more experiments. The suggested method to develop the energy absorption diagram for corrugated boards can be used to characterize the cushioning properties and optimize the structures of corrugated sandwich structures.展开更多
An Approximate Voronoi Boundary Network is constructed as the environmental model by way of enlar-ging the obstacle raster. The connectivity of the path network under complex environment is ensured through build-ing t...An Approximate Voronoi Boundary Network is constructed as the environmental model by way of enlar-ging the obstacle raster. The connectivity of the path network under complex environment is ensured through build-ing the second order Approximate Voronoi Boundary Network after adding virtual obstacles at joint-close grids. Thismethod embodies the network structure of the free area of environment with less nodes, so the complexity of pathplanning problem is reduced largely. An optimized path for mobile robot under complex environment is obtainedthrough the Genetic Algorithm based on the elitist rule and re-optimized by using the path-tightening method. Sincethe elitist one has the only authority of crossover, the management of one group becomes simple, which makes forobtaining the optimized path quickly. The Approximate Voronoi Boundary Network has a good tolerance to the im-precise a priori information and the noises of sensors under complex environment. Especially it is robust in dealingwith the local or partial changes, so a small quantity of dynamic obstacles is difficult to alter the overall character ofits connectivity, which means that it can also be adopted in dynamic environment by fusing the local path planning.展开更多
According to the ion and molecule coexistence theory, the activity model of Fe-Si-B ternary system was es- tablished, and the influence of ratio ：Csi/XZe, boron content and temperature, etc. on the activity of the me...According to the ion and molecule coexistence theory, the activity model of Fe-Si-B ternary system was es- tablished, and the influence of ratio ：Csi/XZe, boron content and temperature, etc. on the activity of the melt com- pound was investigated. The results show that the FeB activity is high in the liquid iron, when Xsl/XFo is 0. 5 ; the ac- tivity of boron increases with increasing the boron content for different contents of xe and xs, and the activity of boron at the ratio xFo = 0.4 is about one order of magnitude higher than that for the XFo = 0. 8; The activities of the melt compound were also affected by temperature, but the influencing extent was little. The equal activity diagrams of silicon and boron were drawn for the first time according to the model results.展开更多
In this study,geochemical anomaly separation was carried out with methods based on the distribution model,which includes probability diagram(MPD),fractal(concentration-area technique),and U-statistic methods.The main ...In this study,geochemical anomaly separation was carried out with methods based on the distribution model,which includes probability diagram(MPD),fractal(concentration-area technique),and U-statistic methods.The main objective is to evaluate the efficiency and accuracy of the methods in separation of anomalies on the shear zone gold mineralization.For this purpose,samples were taken from the secondary lithogeochemical environment(stream sediment samples)on the gold mineralization in Saqqez,NW of Iran.Interpretation of the histograms and diagrams showed that the MPD is capable of identifying two phases of mineralization.The fractal method could separate only one phase of change based on the fractal dimension with high concentration areas of the Au element.The spatial analysis showed two mixed subpopulations after U=0 and another subpopulation with very high U values.The MPD analysis followed spatial analysis,which shows the detail of the variations.Six mineralized zones detected from local geochemical exploration results were used for validating the methods mentioned above.The MPD method was able to identify the anomalous areas higher than 90%,whereas the two other methods identified 60%(maximum)of the anomalous areas.The raw data without any estimation for the concentration was used by the MPD method using aminimum of calculations to determine the threshold values.Therefore,the MPD method is more robust than the other methods.The spatial analysis identified the detail soft hegeological and mineralization events that were affected in the study area.MPD is recommended as the best,and the spatial U-analysis is the next reliable method to be used.The fractal method could show more detail of the events and variations in the area with asymmetrical grid net and a higher density of sampling or at the detailed exploration stage.展开更多
Time-temperature-transformation diagram for epoxy-terminated poly(phenylene ether ketone) and 4, 4*-diaminodiphenyl sulfone was studied using a differential scanning calorimeter, thermal grametry analyzer and a cone-a...Time-temperature-transformation diagram for epoxy-terminated poly(phenylene ether ketone) and 4, 4*-diaminodiphenyl sulfone was studied using a differential scanning calorimeter, thermal grametry analyzer and a cone-and-plate rheometer. Based on a predicting model proposed here, which is used for determining the times to vitrification (tvit), and only few experimental results from DSC, T’GA and cone-and-plate rileometer, TTT diagram can be easily determined.展开更多
From the measured phase equilibria data and experimental thermochemical properties, the TmCl_3-ACl (A=Na, K, Rb, Cs) phase diagrams were optimized and calculated using the CALPHAD technique. For describing the Gibbs e...From the measured phase equilibria data and experimental thermochemical properties, the TmCl_3-ACl (A=Na, K, Rb, Cs) phase diagrams were optimized and calculated using the CALPHAD technique. For describing the Gibbs energies of the liquid phase in these systems, the new modified quasichemical model in the pair-approximation for short-range ordering was used. A set of thermodynamic functions was optimized and gotten based on an interactive computer-assisted analysis. The calculated phase diagrams and thermodynamic data are self-consistent.展开更多
The prediction of the thermodynamic properties of ternary systems from the properties of their sub-binary systems is of great importance to phase diagram calculations. In the present study, a new asymmetric model whic...The prediction of the thermodynamic properties of ternary systems from the properties of their sub-binary systems is of great importance to phase diagram calculations. In the present study, a new asymmetric model which has more clear physical significance has been developed for evaluating the ternary thermodynamic properties from its three binary components. The model is considered to be rigorous in the case where the pseudobinary systems of fixed X2/X3 are regular are regular solution. The application of new model to the prediction of ternary enthalpies of mixing for Bi-Ga-Sn, Au-Ag-Sn and NaCl-KCl-CaCl2 systems shows that the calculated results by new model are closer to experimental data than those by Toop's model.展开更多
The Ge-La binary system was critically assessed by means of the calculation of phase diagram （CALPHAD） technique. The asso- ciate model was used for the liquid phase containing the constituent species Ge, La, Ge3La5...The Ge-La binary system was critically assessed by means of the calculation of phase diagram （CALPHAD） technique. The asso- ciate model was used for the liquid phase containing the constituent species Ge, La, Ge3La5, and Ge1.7La. The terminal solid solution diamond-（Ge） with a small solubility of La was described using the substitutional model, in which the excess Gibbs energy was formulated with the Redlich-Kister equation. The compounds with homogeneity ranges, μ（Gel.7La）, β（Ge1.7La）, and （GeLa）, were modeled using two sublatrices asα（Ge,La）l.7La, β（Ge,La）l.7La, and （Ge,La）（Ge,La）, respectively. The intermediate phases with no solubility ranges, Ge4Las, GeaLa4, Ge3Las, and GeLa3, were treated as stoichiometric compounds. The three allotropic modifications of La, dhcp-La, fcc-La, and bcc-La, were kept as pure element phases since no solubility of Ge in La was reported. A set of self-consistent thermodynamic parameters of the Ge-La binary system was obtained. The calculation results agree well with the available experimental data from literatures.展开更多
Software system can be classified into many function modules from the perspective of user. Unified modeling language( UML) class diagram of each function module was extracted,and design characteristic metrics which in...Software system can be classified into many function modules from the perspective of user. Unified modeling language( UML) class diagram of each function module was extracted,and design characteristic metrics which influenced software maintainability were selected based on UML class diagram.Choosing metrics of UML class diagram as predictors,and mean maintenance time of function module was regarded as software maintainability parameter. Software maintainability models were built by using back propagation( BP) neural network and radial basis function( RBF) neural network, respectively and were simulated by MATLAB. In order to evaluate the performance of models,the training results were analyzed and compared with leaveone-out cross-validation and model performance evaluation criterion. The result indicated that RBF arithmetic was superior to BP arithmetic in predicting software maintainability.展开更多
基金Aeronautical Science Foundation of China （03H53048）
文摘The conventional forming limit diagram （FLD） is described as a plot of major strain versus minor strain. However, FLD is dependent on forming history and strain path. In the present study, a forming limit stress-based diagram （FLSD） has been adopted to predict the fracture limit of aluminum alloy （AA） 5052-O1 sheet. Nakazima test is simulated by plastic constitutive formula derived from the modified Gurson-Tvergaard-Needleman （GTN） model. An in situ tensile test with scanning electron microscope （SEM） is proposed to determine the parameters in GTN model. The damage evolution is observed and recorded, and the parameters of GTN model are identified through counting void fraction at three damage stages of AA5052-O 1. According to the experimental results, the original void volume fraction, the volume fraction of potential nucleated voids, the critical void volume fraction, the void volume fraction at the final failure of material are assigned as 0.002 918, 0.024 9, 0.030 103, 0.048 54, respectively. The stress and strain are obtained at the last loading step before crack. FLSD and FLD of AA5052-O 1 are plotted. Compared with the experimental Nakazima test and uniaxial tensile test, the predicted results show a good agreement. The parameters determined by in situ tensile test can be applied to the research of the forming limit for ductile metals.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41130639, 51179045, 41201028)the Nonprofit Industry Financial Program of MWR of China (201501022)
文摘Intense human activities have greatly changed the flood generation conditions in most areas of the world, and have destroyed the consistency in the annual flood peak and volume series. For design flood estimation, coaxial correlation diagram and conceptual hydrological model are two frequently used tools to adjust and reconstruct the flood series under human disturbance. This study took a typical mountain catchment of the Haihe River Basin as an example to investigate the effects of human activities on flood regime and to compare and assess the two adjustment methods. The main purpose is to construct a conceptual hydrological model which can incorporate the effects of human activities. The results show that the coaxial correlation diagram is simple and widely-used, but can only adjust the time series of total flood volumes. Therefore, it is only applicable under certain conditions(e.g. There is a strong link between the flood peaks and volumes and the link is not significantly affected by human activities). The conceptual model is a powerful tool to adjust the time series of both flood peak flows and flood volumes over different durations provided that it is closely related to the catchment hydrological characteristics, specifically accounting for the effects of human activities, and incorporating expert knowledge when estimating or calibrating parameters. It is suggested that the two methods should be used together to cross check each other.
文摘First order reversal curves （FORC） of nanocomposite Nd2Fe14B/Fe3B magnetic materials were measured to attain a FORC diagram, which characterizes reversible magnetization, irreversible magnetization, and magnetic interactions in a hysteresis system. Then, generalized mov- ing Preisach model （GMPM） was implemented based on the FORC diagram. Reversible and irreversible magnetizations shown in FORCs and a FORC diagram were used as an input of GMPM. Coupling interaction between reversible and irreversible magnetizations was added when calculating reversible magnetization. Meanwhile, irreversible magnetic moments＇ interaction was approximately represented by mean field interaction. The result shows that the simulated main curves mostly coincide with the experimental curves.
基金Supported by the National Key Project Foundation of China (No. 2001BA201A06)
文摘A three-step XML Schema modeling method is presented, namely first establishing a diagram of conceptual modeling, then transforming it to UML class diagram and finally mapping it to XML Schema. A case study of handling furniture design data is given to illustrate the detail of conversion process.
文摘According to the railway transportation system＇s characteristics, a new cellular automaton model for the single- line railway system is presented in this paper. Based on this model, several simulations were done to imitate the train operation under three working diagrams. From a different angle the results show how the organization of train operation impacts on the railway carrying capacity. By using the non-parallel train working diagram the influence of fast-train on slow-train is found to be the strongest. Many slow-trains have to wait in-between neighbouring stations to let the fast-train（s） pass through first. So the slow-train will advance like a wave propagating from the departure station to the arrival station. This also resembles the situation of a highway jammed traffic flow. Furthermore, the nonuniformity of travel times between the sections also greatly limits the railway carrying capacity. After converting the nonuniform sections into the sections with uniform travel times while the total travel time is kept unchanged, all three carrying capacities are improved greatly as shown by simulation. It also shows that the cellular automaton model is an effective and feasible way to investigate the railway transportation system.
文摘A slightly modified central atoms model was proposed. The probabilities of various clusters with the central atoms and their nearest neighboring shells can be calculated neglecting the assumption of the parameter of energy in the central atoms model in proportion to the number of other atoms i (referred with the central atom). A parameter P α is proposed in this model, which equals to reciprocal of activity coefficient of α component, therefore, the new model can be understood easily. By this model, the Al Zn phase diagram and its thermodynamic properties were calculated, the results coincide with the experimental data.
文摘Based on an analysis of 280 Type SNIa supernovae and gamma-ray bursts redshifts in the range of z = 0.0104 - 8.1 the Hubble diagram is shown to follow a strictly exponential slope predicting an exponentially expanding or static universe. At redshifts > 2 - 3 ΛCDM models show a poor agreement with the observed data. Based on the results presented in this paper, the Hubble diagram test does not necessarily support the idea of expansion according to the big-bang concordance model.
基金Funded by the National Natural Science Foundation of China (No.50905120)
文摘Based on the static compression experiments, the compressive stress-strain curve of multi-layer corrugated boards is simplified into three sections of linear elasticity, sub-buckling going with local collapse and densification. By considering the structure factors of multi-layer corrugated boards, the energy absorption model is obtained and characterized by the structure factors of corrugated cell-wall. The model is standardized by the solid modulus and it is universal for corrugated structures of different basis material. In the liner-elastic section, with the increase of the load, the energy absorption per unit volume of multi-layer corrugated boards gradually increases; in the sub-buckling section going with local collapse, the compression resistance of multi-layer corrugated boards goes on under a nearly constant load, but the energy absorption per unit volume rapidly increases with the increase of the compression strain. It is shown as an ascending curve in the energy absorption diagram. In the densification section, the corrugated sandwich core has no energy absorption capability. A good consistency is achieved between theoretical and experimental energy absorption curves. In designing the cushioning package, the cushioning properties can be evaluated by the theoretical model without more experiments. The suggested method to develop the energy absorption diagram for corrugated boards can be used to characterize the cushioning properties and optimize the structures of corrugated sandwich structures.
基金Project (60234030) supported by the National Natural Science Foundation of China
文摘An Approximate Voronoi Boundary Network is constructed as the environmental model by way of enlar-ging the obstacle raster. The connectivity of the path network under complex environment is ensured through build-ing the second order Approximate Voronoi Boundary Network after adding virtual obstacles at joint-close grids. Thismethod embodies the network structure of the free area of environment with less nodes, so the complexity of pathplanning problem is reduced largely. An optimized path for mobile robot under complex environment is obtainedthrough the Genetic Algorithm based on the elitist rule and re-optimized by using the path-tightening method. Sincethe elitist one has the only authority of crossover, the management of one group becomes simple, which makes forobtaining the optimized path quickly. The Approximate Voronoi Boundary Network has a good tolerance to the im-precise a priori information and the noises of sensors under complex environment. Especially it is robust in dealingwith the local or partial changes, so a small quantity of dynamic obstacles is difficult to alter the overall character ofits connectivity, which means that it can also be adopted in dynamic environment by fusing the local path planning.
基金Item Sponsored by National Key Technology Research and Development Program in 11th Five-Year Plan of China(2009BAB45B05)
文摘According to the ion and molecule coexistence theory, the activity model of Fe-Si-B ternary system was es- tablished, and the influence of ratio ：Csi/XZe, boron content and temperature, etc. on the activity of the melt com- pound was investigated. The results show that the FeB activity is high in the liquid iron, when Xsl/XFo is 0. 5 ; the ac- tivity of boron increases with increasing the boron content for different contents of xe and xs, and the activity of boron at the ratio xFo = 0.4 is about one order of magnitude higher than that for the XFo = 0. 8; The activities of the melt compound were also affected by temperature, but the influencing extent was little. The equal activity diagrams of silicon and boron were drawn for the first time according to the model results.
文摘In this study,geochemical anomaly separation was carried out with methods based on the distribution model,which includes probability diagram(MPD),fractal(concentration-area technique),and U-statistic methods.The main objective is to evaluate the efficiency and accuracy of the methods in separation of anomalies on the shear zone gold mineralization.For this purpose,samples were taken from the secondary lithogeochemical environment(stream sediment samples)on the gold mineralization in Saqqez,NW of Iran.Interpretation of the histograms and diagrams showed that the MPD is capable of identifying two phases of mineralization.The fractal method could separate only one phase of change based on the fractal dimension with high concentration areas of the Au element.The spatial analysis showed two mixed subpopulations after U=0 and another subpopulation with very high U values.The MPD analysis followed spatial analysis,which shows the detail of the variations.Six mineralized zones detected from local geochemical exploration results were used for validating the methods mentioned above.The MPD method was able to identify the anomalous areas higher than 90%,whereas the two other methods identified 60%(maximum)of the anomalous areas.The raw data without any estimation for the concentration was used by the MPD method using aminimum of calculations to determine the threshold values.Therefore,the MPD method is more robust than the other methods.The spatial analysis identified the detail soft hegeological and mineralization events that were affected in the study area.MPD is recommended as the best,and the spatial U-analysis is the next reliable method to be used.The fractal method could show more detail of the events and variations in the area with asymmetrical grid net and a higher density of sampling or at the detailed exploration stage.
文摘Time-temperature-transformation diagram for epoxy-terminated poly(phenylene ether ketone) and 4, 4*-diaminodiphenyl sulfone was studied using a differential scanning calorimeter, thermal grametry analyzer and a cone-and-plate rheometer. Based on a predicting model proposed here, which is used for determining the times to vitrification (tvit), and only few experimental results from DSC, T’GA and cone-and-plate rileometer, TTT diagram can be easily determined.
基金Project supported by the Foundation of Natural Science of Anhui Province (00046509) and Foundation of Natural Science of Anhui Education Committee (2000j1090)
文摘From the measured phase equilibria data and experimental thermochemical properties, the TmCl_3-ACl (A=Na, K, Rb, Cs) phase diagrams were optimized and calculated using the CALPHAD technique. For describing the Gibbs energies of the liquid phase in these systems, the new modified quasichemical model in the pair-approximation for short-range ordering was used. A set of thermodynamic functions was optimized and gotten based on an interactive computer-assisted analysis. The calculated phase diagrams and thermodynamic data are self-consistent.
文摘The prediction of the thermodynamic properties of ternary systems from the properties of their sub-binary systems is of great importance to phase diagram calculations. In the present study, a new asymmetric model which has more clear physical significance has been developed for evaluating the ternary thermodynamic properties from its three binary components. The model is considered to be rigorous in the case where the pseudobinary systems of fixed X2/X3 are regular are regular solution. The application of new model to the prediction of ternary enthalpies of mixing for Bi-Ga-Sn, Au-Ag-Sn and NaCl-KCl-CaCl2 systems shows that the calculated results by new model are closer to experimental data than those by Toop's model.
基金supported by the National Natural Science Foundation of China (Nos.50731002 and 50671009)
文摘The Ge-La binary system was critically assessed by means of the calculation of phase diagram （CALPHAD） technique. The asso- ciate model was used for the liquid phase containing the constituent species Ge, La, Ge3La5, and Ge1.7La. The terminal solid solution diamond-（Ge） with a small solubility of La was described using the substitutional model, in which the excess Gibbs energy was formulated with the Redlich-Kister equation. The compounds with homogeneity ranges, μ（Gel.7La）, β（Ge1.7La）, and （GeLa）, were modeled using two sublatrices asα（Ge,La）l.7La, β（Ge,La）l.7La, and （Ge,La）（Ge,La）, respectively. The intermediate phases with no solubility ranges, Ge4Las, GeaLa4, Ge3Las, and GeLa3, were treated as stoichiometric compounds. The three allotropic modifications of La, dhcp-La, fcc-La, and bcc-La, were kept as pure element phases since no solubility of Ge in La was reported. A set of self-consistent thermodynamic parameters of the Ge-La binary system was obtained. The calculation results agree well with the available experimental data from literatures.
文摘Software system can be classified into many function modules from the perspective of user. Unified modeling language( UML) class diagram of each function module was extracted,and design characteristic metrics which influenced software maintainability were selected based on UML class diagram.Choosing metrics of UML class diagram as predictors,and mean maintenance time of function module was regarded as software maintainability parameter. Software maintainability models were built by using back propagation( BP) neural network and radial basis function( RBF) neural network, respectively and were simulated by MATLAB. In order to evaluate the performance of models,the training results were analyzed and compared with leaveone-out cross-validation and model performance evaluation criterion. The result indicated that RBF arithmetic was superior to BP arithmetic in predicting software maintainability.
