This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using s...This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using simulated pyrolysis data as the training dataset.Various feature extraction methods are utilized,and five neural network architectures are developed to predict the co-cracking product distribution based on molecular structures.High-throughput screening of 12946 molecules outside the training dataset identifies the top 10 initiators for each target product—ethylene,propylene,and butadiene.The relative error between predicted and simulated values is less than 7%.Additionally,reaction pathway analysis elucidates the mechanisms by which initiators influence the distribution of cracking products.The proposed framework provides a practical and efficient approach for the rapid identification and evaluation of high-performance cracking initiators.展开更多
Investigating the characteristics of synchronous electrical explosions of multiple exploding foil initiators(EFI)in the same circuit,a four-point series-connected EFI circuit utilizing flexible flat cables was designe...Investigating the characteristics of synchronous electrical explosions of multiple exploding foil initiators(EFI)in the same circuit,a four-point series-connected EFI circuit utilizing flexible flat cables was designed to analyze the electrical explosion characteristics.Loop current and terminal voltages of each EFI were recorded to characterize the multi-point series-connected EFI explosion.The effects of voltage,capacitance,and loop length on the response time,energy deposition,and energy utilization efficiency of the multi-point series-connected EFI were explored.Based on the FIRESET model,a mathematical model for the multi-point series-connected EFI explosion was developed,and the influence of initial resistivity on the peak voltage during electrical explosion was quantitatively analyzed.Results indicate that the primary factor influencing the response time is the conduction performance of the switch,while the synchronization deviation is minimally affected by variations in voltage and capacitance.At an inter-electrode spacing of 50 mm,within the voltage range of 1,500–3,000 V and capacitance range of 0.22–1.5μF,the minimum and maximum synchronization deviations of the four-point EFI were 2 ns and 11 ns,respectively.As input energy increases,the deposited energy of the EFI rises,but the overall energy utilization efficiency decreases.The computational results of the proposed model align well with the experimental data.Furthermore,higher initial resistivity in the series-connected circuit corresponds to a higher peak voltage during electrical explosion.This work elucidates the characteristics of multi-point series-connected EFI explosions,offering valuable insights for the design of multi-point EFI circuits.展开更多
The operational Tropical Regional Atmospheric Model System(TRAMS)often underestimates initial typhoon intensity when using the global analysis field as the initial condition.The TRAMS tropical cyclone(TC)initializatio...The operational Tropical Regional Atmospheric Model System(TRAMS)often underestimates initial typhoon intensity when using the global analysis field as the initial condition.The TRAMS tropical cyclone(TC)initialization scheme,developed based on the incremental analysis updates(IAU)technique,effectively reduces initial bias.However,the original IAU-based TC initialization scheme only adjusts the wind field at the analysis moment,with other variables adjusted implicitly under the model's constraints according to a gradually inserted wind increment(named“univariate adjustment scheme”hereafter).The univariate adjustment scheme requires approximately 3 h to reach a dynamic equilibrium state,which constrains the assimilation of hourly TC observations and causes excessive dissipation of meaningful short-wave information in adjustment increments.To address this limitation,this study develops a multivariate adjustment IAU-based TC initialization scheme that incorporates gradient wind balance and hydrostatic balance as its largescale constraints.Numerical experiments with TC Hato(2017)demonstrate that the multivariate adjustment scheme reduces the IAU relaxation time to 1 h while marginally improving forecast skill.These findings are consistently replicated across 12 additional TC cases.The development of the IAU-based multivariate adjustment initialization scheme establishes a foundation for 4-D initialization using hourly TC observations.展开更多
The Global Governance Initiative(GGI)is another important public good that China has provided for the international community,following the Global Development Initiative,the Global Security Initiative,and the Global C...The Global Governance Initiative(GGI)is another important public good that China has provided for the international community,following the Global Development Initiative,the Global Security Initiative,and the Global Civilization Initiative.As a sub-field of global governance,global climate governance has hitherto progressed slowly,exhibiting growing deficits in discourse,institutions,and actions.The governance paradigm is in desperate need of revamping,especially under the guidance of an innovative initiative.At the conceptual level,the GGI has gone beyond the Western governance discourse by outlining the institutional starting point,foundations of legitimacy,action orientations,ultimate goals,and practical support for good global climate governance through its five core concepts.At the practical level,the spillover effects of China's achievements in climate governance and the collective rise of the Global South have created favorable conditions,domestically and internationally,for the GGI to lead the way forward toward good global climate governance.However,the fact that the international political and economic order remains unjust and inequitable indicates that this will inevitably be a long-term process replete with rivalries in the pursuit of breakthroughs.展开更多
The stress-strain behavior of calcareous sand is significantly influencedby particle breakage(B)and initial relative density(Dri),but few constitutive models consider their combined effects.To bridge this gap,we condu...The stress-strain behavior of calcareous sand is significantly influencedby particle breakage(B)and initial relative density(Dri),but few constitutive models consider their combined effects.To bridge this gap,we conducted a series of triaxial tests on calcareous sand with varying Dri and stress paths,examining particle breakage and critical state behavior.Key findingsinclude:(1)At a constant stress ratio(η),B follows a hyperbolic relationship with mean effective stress(p'),and for a given p',B increases proportionally withη;(2)The critical state line(CSL)moves downward with increasing Dri,whereas the critical state friction angle(φcs)decreases with increasing B.Based on these findings,we propose a unifiedbreakage evolution model to quantify particle breakage in calcareous sand under various loading conditions.Integrating this model with the Normal Consolidation Line(NCL)and CSL equations,we successfully simulate the steepening of NCL and CSL slopes as B increases with the onset of particle breakage.Furthermore,we quantitatively evaluate the effect of B onφcs.Finally,within the framework of Critical State Soil Mechanics and Hypoplasticity theory,we develop a hypoplastic model incorporating B and Dri.The model is validated through strong agreement with experimental results across various initial relative densities,stress paths and drainage conditions.展开更多
Ice lens initiation is the core issue in understanding the dynamic process of frost heave.However,there are still limitations to find an adequate criterion for describing the formation of ice lens.A series of one-dime...Ice lens initiation is the core issue in understanding the dynamic process of frost heave.However,there are still limitations to find an adequate criterion for describing the formation of ice lens.A series of one-dimensional freezing tests is designed using the particle image velocimetry(PIV)method to monitor the frost heave and ice lens formation.The results show that the conventional parameters,such as displacement and velocity,cannot be used to track the ice lens formation,while the strain can be employed to detect the ice lens formation and investigate the freezing change patterns.This study proposes strain as a new criterion for assessing ice lens initiation,applicable across various soil types and freezing conditions(constant freezing and ramped freezing).The strain change in the region where the ice lens forms is the largest during the freezing process.Additionally,strain curves at the top of the soil samples can reveal different freezing patterns and distinguish the first and second frost heave stages.This newly developed technology enables continuous,non-destructive monitoring of ice lens initiation across diverse conditions and soil types,enhancing data visualization and three-dimensional modeling of freezing parameters while improving traditional methods by directly measuring velocity and strain in frost heave investigations.The study is expected to enhance the research of ice lens criterion and provide a new perspective for monitoring the freezing process.展开更多
The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated....The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated.By adjusting the furnace cooling time after solution treatment and the aging temperature,Ti6422 alloy samples were developed with a multi-level lamellar microstructure,in-cluding microscaleαcolonies and α_(p) lamellae,as well as nanoscale α_(s) phases.Extending the furnace cooling time after solution treatment at 920℃ for 1 h from 240 to 540 min,followed by aging at 600℃ for 6 h,increased the α_(p) lamella content,reduced the α_(s) phase content,expanded theαcolonies and α_(p) lamellae size,and improved the impact toughness from 22.7 to 53.8 J/cm^(2).Additionally,under the same solution treatment,raising the aging temperature from 500 to 700℃ resulted in a decrease in the α_(s) phase content and a growth in the thickness of the α_(p) lamella and α_(s) phase.The impact toughness increased significantly with these changes.Samples with high α_(p) lamellae content or large α_(s) phase size exhibited high crack initiation and propagation energies.Impact deformation caused severe kinking of the α_(p) lamellae in crack initiation and propagation areas,leading to a uniform and high-density kernel average misorientation(KAM)distribu-tion,enhancing plastic deformation coordination and uniformity.Moreover,the multidirectional arrangement of coarserαcolonies and α_(p) lamellae continuously deflect the crack propagation direction,inhibiting crack propagation.展开更多
Stanbic Bank Zimbabwe is strategically positioning itself as a critical bridge for Zimbabwe’s local businesses,seeking to navigate the vast and complex Chinese market.
On September 1,2025,Chinese President Xi Jinping solemnly proposed the Global Governance Initiative(GGI)at the“Shanghai Cooperation Organization Plus”meeting,answering a question posed by the times:what kind of glob...On September 1,2025,Chinese President Xi Jinping solemnly proposed the Global Governance Initiative(GGI)at the“Shanghai Cooperation Organization Plus”meeting,answering a question posed by the times:what kind of global governance system to build and how to reform and improve global governance.The GGI is committed to sovereign equality,the international rule of law,multilateralism,the people-centered approach,and real results,offering China's wisdom and solutions for building a more just and equitable global governance system.On the journey ahead,China will hold high the banner of a community with a shared future for humanity and advance the GGI through multiple measures,effectively strengthening and improving global governance.展开更多
The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechani...The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechanics analysis with transparent soil model tests.An analytical expression for the stress field at the dominant crack tip was derived from the slope stress distribution by superposing the corresponding stress intensity factors(SIFs).The theoretical predictions were then validated against observations from transparent soil model tests.The influences of slope angle(β),crack inclination angle(α),crack position parameter(b),and crack length parameter(h)on crack initiation and propagation were quantified.The results indicated that:(1)cracks at the slope crest tended to propagate in shear mode,and the shear crack initiation angle(θ_(s))was approximately 8°.Cracks at the slope toe might propagate in either tensile or shear mode.(2)θ_(s) at the slope crest increased withβ,b,and l,and decreased withα.The maximum change inθ_(s) induced by the considered parameters was approximately 30°.(3)The tensile crack initiation angle(θ_(t))at the slop toe decreased withβ,α,and l,while the influence of b was comparatively minor.The maximum change inθ_(t) caused by individual parameters ranged approximately from 25°to 60°.Predicted crack propagation modes and directions showed good agreement with experimental results.These findings provide theoretical guidance for stability assessments of valley slopes controlled by dominant crack propagation.展开更多
The cemented tailings backfill(CTB)with initial defects is more prone to destabilization damage under the influence of various unfavorable factors during the mining process.In order to investigate its influence on the...The cemented tailings backfill(CTB)with initial defects is more prone to destabilization damage under the influence of various unfavorable factors during the mining process.In order to investigate its influence on the stability of underground mining engineering,this paper simulates the generation of different degrees of initial defects inside the CTB by adding different contents of air-entraining agent(AEA),investigates the acoustic emission RA/AF eigenvalues of CTB with different contents of AEA under uniaxial compression,and adopts various denoising algorithms(e.g.,moving average smoothing,median filtering,and outlier detection)to improve the accuracy of the data.The variance and autocorrelation coefficients of RA/AF parameters were analyzed in conjunction with the critical slowing down(CSD)theory.The results show that the acoustic emission RA/AF values can be used to characterize the progressive damage evolution of CTB.The denoising algorithm processed the AE signals to reduce the effects of extraneous noise and anomalous spikes.Changes in the variance curves provide clear precursor information,while abrupt changes in the autocorrelation coefficient can be used as an auxiliary localization warning signal.The phenomenon of dramatic increase in the variance and autocorrelation coefficient curves during the compression-tightening stage,which is influenced by the initial defects,can lead to false warnings.As the initial defects of the CTB increase,its instability precursor time and instability time are prolonged,the peak stress decreases,and the time difference between the CTB and the instability damage is smaller.The results provide a new method for real-time monitoring and early warning of CTB instability damage.展开更多
To investigate the long-term stability of soft-hard interbedded rock masses with initial damage induced by earthquakes and periodic drying and wetting,this study prepared samples with different initial damage through ...To investigate the long-term stability of soft-hard interbedded rock masses with initial damage induced by earthquakes and periodic drying and wetting,this study prepared samples with different initial damage through cyclic loading and unloading(CLU)experiments followed by cyclic drying and wetting(CDW)experiments,and finally conducted creep experiments.The study analyzed the effects of initial damage on creep mechanical behavior,crack evolution,and explored failure precursor information,revealing the damage failure mechanisms.The results show that the structural characteristics of the rock mass control its macroscopic failure mode.Initial damage promotes microcrack development,influences the fracture mode,and increases the proportion of high-frequency(200−280 kHz)acoustic emission events during creep.Meanwhile,initial damage exacerbates creep characteristics,increasing the creep rate,shortening total creep failure time,and reducing long-term strength.The damage failure is attributed to:the generation of internal cracks and pores in the rock caused by CLU;mineral hydrolysis and expansion-contraction due to CDW,resulting in weakened intergranular cementation;and full development of cracks and pores under creep stress.Additionally,the deformation difference coefficient and the coefficient of variation of RA/AF values can serve as precursor indicators for creep failure.展开更多
As we enter the year 2026,the international system continues to receive shocks from Donald Trump,arguably the 21st century’s most disruptive US leader.His return to the White House in 2025 coincided with the 80th ann...As we enter the year 2026,the international system continues to receive shocks from Donald Trump,arguably the 21st century’s most disruptive US leader.His return to the White House in 2025 coincided with the 80th anniversary of the defeat of fascism and the establishment of the United Nations,the multilateral platform that carried the world’s hope for peace,restraint and collective security.The coincidence was unsettling.A world order designed to limit power now confronts a moment in which power is exercised openly,transactionally and unapologetically.展开更多
The effects of initial spin orientation on the final electron beam polarization in laser wakefield acceleration in a pre-polarized plasma are investigated theoretically and numerically.From the results of variation of...The effects of initial spin orientation on the final electron beam polarization in laser wakefield acceleration in a pre-polarized plasma are investigated theoretically and numerically.From the results of variation of the initial spin direction,the spin dynamics of the electron beam are found to depend on the self-injection mechanism.The effects of wakefields and laser fields are studied using test particle dynamics and particle-in-cell simulations based on the Thomas-Bargmann-Michel-Telegdi equation.Compared with transverse injection,longitudinal injection is found to be preferable for obtaining a highly polarized electron beam.展开更多
In an era of profound changes to global trade,food security,and industrial organization,the ChinaIndonesia“Two Countries,Twin Parks”initiative has emerged as a strategic experiment with farreaching implications.Anch...In an era of profound changes to global trade,food security,and industrial organization,the ChinaIndonesia“Two Countries,Twin Parks”initiative has emerged as a strategic experiment with farreaching implications.Anchored in marine protein processing and advanced food manufacturing,this collaboration reflects not only a convergence of economic interests but also a deliberate rethinking of how China engages with global resources,technology,and partners.展开更多
During deep coal mining,an instability failure of coal usually occurs under the combined effect of initial damage and triaxial cyclic loading and unloading(TCLU).Therefore,this study investigated the impact of initial...During deep coal mining,an instability failure of coal usually occurs under the combined effect of initial damage and triaxial cyclic loading and unloading(TCLU).Therefore,this study investigated the impact of initial damage on mechanical behavior and acoustic emission(AE)characteristics of coal under TCLU.Initial damage variables(IDVs)of coal specimens were quantified using preloading,followed by TCLU experiments to assess the deformation,energy distribution,and fracture development.The results revealed that the increase in IDVs significantly reduced the structural integrity of coal specimens,increased the cumulative irreversible strain,and enhanced the dissipated energy owing to microfracture expansion.Moreover,AE monitoring showed earlier activation of fractures and a higher occurrence of large-scale rupture events of coal specimens with high IDVs,which correlated with decreasing AE b values(reflecting the different scales of fracture within specimens)and increasing S values(reflecting the AE activity within specimens).Additionally,computed tomography analysis revealed intensified fracture networks and increasing three-dimensional fractal dimensions of coal specimens with higher IDVs.Finally,the coupling effect of TCLU and initial damage on the weakening mechanism of coal was investigated.Initial damage significantly reduced the structural integrity of coal by increasing the number of weak planes within coal specimens,contributing to the earlier activation and rapid expansion of fractures at low stress levels under TCLU and eventually accelerating the weakening process of coal.This study provides a scientific basis and theoretical support for the prevention and control of dynamic disasters in deep coal mining.展开更多
The prepolymer polyurethanes （PUs） based on isophorone diisocyanate （IPDI）, poly（propylene glycol） （PPG）, 1,4-butanediol （BDO） and dimethylopropionic acid （DMPA） were synthesized at 75-80 ℃ for 7-8 hours,...The prepolymer polyurethanes （PUs） based on isophorone diisocyanate （IPDI）, poly（propylene glycol） （PPG）, 1,4-butanediol （BDO） and dimethylopropionic acid （DMPA） were synthesized at 75-80 ℃ for 7-8 hours, using dibutyltin dilauate （DBTDL） as catalyzer, and polyurethane-acrylate hybrid emulsion was prepared after methyl methacrylate （MMA） was polymerized, using potassium persulfate and azobisisobutyronitrile （AIBN） as initiator, respectively. The influences of these factors such as the kind of initiator, the feed method of initiator and the addition of initiator on properties of polyurethane-acrylate were studied. The FTIR and GPC of aqueous polyurethane were analyzed. The FTIR spectra show that the degree of microphase-separate between the soft segments and rigid segments is high. The analysis of molecular weights stated that molecular weights increased most significantly after amine was added. The experimental results reveal that the appearance of emulsion is excellent, the film is harder and the water absorption radio of the film is less when oil-solubility AIBN is used as initiator. The semi-continuous can increase the molecular weight of polymer and the optimum amount of the initiator was 3% for MMA.展开更多
Multifunctional organolithium initiator was prepared in cyclohexane solvent. The process started with adding the cyclohexane solution of butadiene to naphthalene-lithium in batches to produce butadiene oligomer dilith...Multifunctional organolithium initiator was prepared in cyclohexane solvent. The process started with adding the cyclohexane solution of butadiene to naphthalene-lithium in batches to produce butadiene oligomer dilithium with 4-8 butadiene repeating units. In the first feeding, the maximum loading of cyclohexane and the minimum concentration of butadiene cyclohexane solution must be controlled under Vcyclohexane 〈 1.33 VTHF and p 〉 40.6cN. Then, SnCl4 was added and eventually the multifunctional organolithium initiator containing Sn atom was synthesized through coupling reaction. Experiment results showed that adding the cyclohexane solution in batches was effective in overcoming some difficulties, such as insolubility of naphthalene-lithium in cyclohexane, low efficiency of naphthalene-lithium in initiating butadiene. In practice, benzene can be replaced by cyclohexane completely, which can not only reduce environmental pollution from benzene, but also overcome the difficulty of solvent recovery caused by similar boiling point between benzene and cyclohexane. Prepared with multifunctional organolithium containing Sn atom as initiator, the star-shaped solution polymerized styrene-butadiene rubber （star S-SBR） with better vulcanization performances, lower rolling resistance and higher wet-skid resistance was obtained.展开更多
基金The financial support provided by the Project of the National Natural Science Foundation of China (22308314,U22A20415)the Natural Science Foundation of Zhejiang Province (LQ24B060001)+1 种基金the "Pioneer" and "Leading Goose" Research & Development Program of Zhejiang (2022C01SA442617)the SINOPEC Technology Development Project (224244)
文摘This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using simulated pyrolysis data as the training dataset.Various feature extraction methods are utilized,and five neural network architectures are developed to predict the co-cracking product distribution based on molecular structures.High-throughput screening of 12946 molecules outside the training dataset identifies the top 10 initiators for each target product—ethylene,propylene,and butadiene.The relative error between predicted and simulated values is less than 7%.Additionally,reaction pathway analysis elucidates the mechanisms by which initiators influence the distribution of cracking products.The proposed framework provides a practical and efficient approach for the rapid identification and evaluation of high-performance cracking initiators.
文摘Investigating the characteristics of synchronous electrical explosions of multiple exploding foil initiators(EFI)in the same circuit,a four-point series-connected EFI circuit utilizing flexible flat cables was designed to analyze the electrical explosion characteristics.Loop current and terminal voltages of each EFI were recorded to characterize the multi-point series-connected EFI explosion.The effects of voltage,capacitance,and loop length on the response time,energy deposition,and energy utilization efficiency of the multi-point series-connected EFI were explored.Based on the FIRESET model,a mathematical model for the multi-point series-connected EFI explosion was developed,and the influence of initial resistivity on the peak voltage during electrical explosion was quantitatively analyzed.Results indicate that the primary factor influencing the response time is the conduction performance of the switch,while the synchronization deviation is minimally affected by variations in voltage and capacitance.At an inter-electrode spacing of 50 mm,within the voltage range of 1,500–3,000 V and capacitance range of 0.22–1.5μF,the minimum and maximum synchronization deviations of the four-point EFI were 2 ns and 11 ns,respectively.As input energy increases,the deposited energy of the EFI rises,but the overall energy utilization efficiency decreases.The computational results of the proposed model align well with the experimental data.Furthermore,higher initial resistivity in the series-connected circuit corresponds to a higher peak voltage during electrical explosion.This work elucidates the characteristics of multi-point series-connected EFI explosions,offering valuable insights for the design of multi-point EFI circuits.
基金supported by the National University of Defense Technology(NUDT)Research Initiation Funding for High-Level Scientific and Technological Innovative Talents(202402-YJRC-LJ-001)the National Natural Science Foundation of China(Grant No.U2142213)+1 种基金the Basic and Applied Basic Research Foundation of Guangdong Province(Grants 2025A1515011835,2022A1515011870)the National Natural Science Foundation of China(Grant No.42305167)。
文摘The operational Tropical Regional Atmospheric Model System(TRAMS)often underestimates initial typhoon intensity when using the global analysis field as the initial condition.The TRAMS tropical cyclone(TC)initialization scheme,developed based on the incremental analysis updates(IAU)technique,effectively reduces initial bias.However,the original IAU-based TC initialization scheme only adjusts the wind field at the analysis moment,with other variables adjusted implicitly under the model's constraints according to a gradually inserted wind increment(named“univariate adjustment scheme”hereafter).The univariate adjustment scheme requires approximately 3 h to reach a dynamic equilibrium state,which constrains the assimilation of hourly TC observations and causes excessive dissipation of meaningful short-wave information in adjustment increments.To address this limitation,this study develops a multivariate adjustment IAU-based TC initialization scheme that incorporates gradient wind balance and hydrostatic balance as its largescale constraints.Numerical experiments with TC Hato(2017)demonstrate that the multivariate adjustment scheme reduces the IAU relaxation time to 1 h while marginally improving forecast skill.These findings are consistently replicated across 12 additional TC cases.The development of the IAU-based multivariate adjustment initialization scheme establishes a foundation for 4-D initialization using hourly TC observations.
基金2024 Shaanxi Provincial Social Science Fund Annual Project titled"Research on Chinese Modernization from the Perspective of Overseas Studies on the Communist Party of China"(Project Number:2024B002)a 2024 key project of Xi'an Jiaotong University for studying and expounding Xi Jinping Thought on Culture titled"Research on the World Implications of a New Model for Human Advancement"(Project Number:SKZX2024003)funded by the"Top Young Talents Project"(TZ0275)of Shaanxi Province's second batch of"Special Support Program for High-Level Talents"(Philosophy,Social Sciences,Culture,and Arts).
文摘The Global Governance Initiative(GGI)is another important public good that China has provided for the international community,following the Global Development Initiative,the Global Security Initiative,and the Global Civilization Initiative.As a sub-field of global governance,global climate governance has hitherto progressed slowly,exhibiting growing deficits in discourse,institutions,and actions.The governance paradigm is in desperate need of revamping,especially under the guidance of an innovative initiative.At the conceptual level,the GGI has gone beyond the Western governance discourse by outlining the institutional starting point,foundations of legitimacy,action orientations,ultimate goals,and practical support for good global climate governance through its five core concepts.At the practical level,the spillover effects of China's achievements in climate governance and the collective rise of the Global South have created favorable conditions,domestically and internationally,for the GGI to lead the way forward toward good global climate governance.However,the fact that the international political and economic order remains unjust and inequitable indicates that this will inevitably be a long-term process replete with rivalries in the pursuit of breakthroughs.
基金support to this study from the National Natural Science Foundation of China,NSFC(Grant No.52278367)The Belt and Road Special Foundation of the National Key Laboratory ofWater Disaster Prevention(Grant No.2024nkms08).
文摘The stress-strain behavior of calcareous sand is significantly influencedby particle breakage(B)and initial relative density(Dri),but few constitutive models consider their combined effects.To bridge this gap,we conducted a series of triaxial tests on calcareous sand with varying Dri and stress paths,examining particle breakage and critical state behavior.Key findingsinclude:(1)At a constant stress ratio(η),B follows a hyperbolic relationship with mean effective stress(p'),and for a given p',B increases proportionally withη;(2)The critical state line(CSL)moves downward with increasing Dri,whereas the critical state friction angle(φcs)decreases with increasing B.Based on these findings,we propose a unifiedbreakage evolution model to quantify particle breakage in calcareous sand under various loading conditions.Integrating this model with the Normal Consolidation Line(NCL)and CSL equations,we successfully simulate the steepening of NCL and CSL slopes as B increases with the onset of particle breakage.Furthermore,we quantitatively evaluate the effect of B onφcs.Finally,within the framework of Critical State Soil Mechanics and Hypoplasticity theory,we develop a hypoplastic model incorporating B and Dri.The model is validated through strong agreement with experimental results across various initial relative densities,stress paths and drainage conditions.
基金supported by the National Natural Science Foundation of China(Grant No.52178376)National Key R&D Program of China(Grant No.2022YFB2603301)Science and Technology Research and Development Program of China Railway Group Limited(Grant No.2022-ZD-13).
文摘Ice lens initiation is the core issue in understanding the dynamic process of frost heave.However,there are still limitations to find an adequate criterion for describing the formation of ice lens.A series of one-dimensional freezing tests is designed using the particle image velocimetry(PIV)method to monitor the frost heave and ice lens formation.The results show that the conventional parameters,such as displacement and velocity,cannot be used to track the ice lens formation,while the strain can be employed to detect the ice lens formation and investigate the freezing change patterns.This study proposes strain as a new criterion for assessing ice lens initiation,applicable across various soil types and freezing conditions(constant freezing and ramped freezing).The strain change in the region where the ice lens forms is the largest during the freezing process.Additionally,strain curves at the top of the soil samples can reveal different freezing patterns and distinguish the first and second frost heave stages.This newly developed technology enables continuous,non-destructive monitoring of ice lens initiation across diverse conditions and soil types,enhancing data visualization and three-dimensional modeling of freezing parameters while improving traditional methods by directly measuring velocity and strain in frost heave investigations.The study is expected to enhance the research of ice lens criterion and provide a new perspective for monitoring the freezing process.
基金supported by the National Natural Science Foundation of China(No.52090041).
文摘The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated.By adjusting the furnace cooling time after solution treatment and the aging temperature,Ti6422 alloy samples were developed with a multi-level lamellar microstructure,in-cluding microscaleαcolonies and α_(p) lamellae,as well as nanoscale α_(s) phases.Extending the furnace cooling time after solution treatment at 920℃ for 1 h from 240 to 540 min,followed by aging at 600℃ for 6 h,increased the α_(p) lamella content,reduced the α_(s) phase content,expanded theαcolonies and α_(p) lamellae size,and improved the impact toughness from 22.7 to 53.8 J/cm^(2).Additionally,under the same solution treatment,raising the aging temperature from 500 to 700℃ resulted in a decrease in the α_(s) phase content and a growth in the thickness of the α_(p) lamella and α_(s) phase.The impact toughness increased significantly with these changes.Samples with high α_(p) lamellae content or large α_(s) phase size exhibited high crack initiation and propagation energies.Impact deformation caused severe kinking of the α_(p) lamellae in crack initiation and propagation areas,leading to a uniform and high-density kernel average misorientation(KAM)distribu-tion,enhancing plastic deformation coordination and uniformity.Moreover,the multidirectional arrangement of coarserαcolonies and α_(p) lamellae continuously deflect the crack propagation direction,inhibiting crack propagation.
文摘Stanbic Bank Zimbabwe is strategically positioning itself as a critical bridge for Zimbabwe’s local businesses,seeking to navigate the vast and complex Chinese market.
文摘On September 1,2025,Chinese President Xi Jinping solemnly proposed the Global Governance Initiative(GGI)at the“Shanghai Cooperation Organization Plus”meeting,answering a question posed by the times:what kind of global governance system to build and how to reform and improve global governance.The GGI is committed to sovereign equality,the international rule of law,multilateralism,the people-centered approach,and real results,offering China's wisdom and solutions for building a more just and equitable global governance system.On the journey ahead,China will hold high the banner of a community with a shared future for humanity and advance the GGI through multiple measures,effectively strengthening and improving global governance.
基金financially supported by the National Nature Science Foundation of China(Nos.52379110 and 42207222)the Key Technologies for Accurate Diagnosis and Intelligent Prevention and Control of Slope Hazards in Open Pit Mines,181 Major R&D projects of Metallurgical Corporation of China Ltd。
文摘The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechanics analysis with transparent soil model tests.An analytical expression for the stress field at the dominant crack tip was derived from the slope stress distribution by superposing the corresponding stress intensity factors(SIFs).The theoretical predictions were then validated against observations from transparent soil model tests.The influences of slope angle(β),crack inclination angle(α),crack position parameter(b),and crack length parameter(h)on crack initiation and propagation were quantified.The results indicated that:(1)cracks at the slope crest tended to propagate in shear mode,and the shear crack initiation angle(θ_(s))was approximately 8°.Cracks at the slope toe might propagate in either tensile or shear mode.(2)θ_(s) at the slope crest increased withβ,b,and l,and decreased withα.The maximum change inθ_(s) induced by the considered parameters was approximately 30°.(3)The tensile crack initiation angle(θ_(t))at the slop toe decreased withβ,α,and l,while the influence of b was comparatively minor.The maximum change inθ_(t) caused by individual parameters ranged approximately from 25°to 60°.Predicted crack propagation modes and directions showed good agreement with experimental results.These findings provide theoretical guidance for stability assessments of valley slopes controlled by dominant crack propagation.
基金Projects(52374138,51764013)supported by the National Natural Science Foundation of ChinaProject(20204BCJ22005)supported by the Training Plan for Academic and Technical Leaders of Major Disciplines of Jiangxi Province,China+1 种基金Project(2019M652277)supported by the China Postdoctoral Science FoundationProject(20192ACBL21014)supported by the Natural Science Youth Foundation Key Projects of Jiangxi Province,China。
文摘The cemented tailings backfill(CTB)with initial defects is more prone to destabilization damage under the influence of various unfavorable factors during the mining process.In order to investigate its influence on the stability of underground mining engineering,this paper simulates the generation of different degrees of initial defects inside the CTB by adding different contents of air-entraining agent(AEA),investigates the acoustic emission RA/AF eigenvalues of CTB with different contents of AEA under uniaxial compression,and adopts various denoising algorithms(e.g.,moving average smoothing,median filtering,and outlier detection)to improve the accuracy of the data.The variance and autocorrelation coefficients of RA/AF parameters were analyzed in conjunction with the critical slowing down(CSD)theory.The results show that the acoustic emission RA/AF values can be used to characterize the progressive damage evolution of CTB.The denoising algorithm processed the AE signals to reduce the effects of extraneous noise and anomalous spikes.Changes in the variance curves provide clear precursor information,while abrupt changes in the autocorrelation coefficient can be used as an auxiliary localization warning signal.The phenomenon of dramatic increase in the variance and autocorrelation coefficient curves during the compression-tightening stage,which is influenced by the initial defects,can lead to false warnings.As the initial defects of the CTB increase,its instability precursor time and instability time are prolonged,the peak stress decreases,and the time difference between the CTB and the instability damage is smaller.The results provide a new method for real-time monitoring and early warning of CTB instability damage.
基金Project(U22A20603)supported by the National Natural Science Foundation of ChinaProject(2023YFC3008300)supported by the National Key Research and Development Program of China。
文摘To investigate the long-term stability of soft-hard interbedded rock masses with initial damage induced by earthquakes and periodic drying and wetting,this study prepared samples with different initial damage through cyclic loading and unloading(CLU)experiments followed by cyclic drying and wetting(CDW)experiments,and finally conducted creep experiments.The study analyzed the effects of initial damage on creep mechanical behavior,crack evolution,and explored failure precursor information,revealing the damage failure mechanisms.The results show that the structural characteristics of the rock mass control its macroscopic failure mode.Initial damage promotes microcrack development,influences the fracture mode,and increases the proportion of high-frequency(200−280 kHz)acoustic emission events during creep.Meanwhile,initial damage exacerbates creep characteristics,increasing the creep rate,shortening total creep failure time,and reducing long-term strength.The damage failure is attributed to:the generation of internal cracks and pores in the rock caused by CLU;mineral hydrolysis and expansion-contraction due to CDW,resulting in weakened intergranular cementation;and full development of cracks and pores under creep stress.Additionally,the deformation difference coefficient and the coefficient of variation of RA/AF values can serve as precursor indicators for creep failure.
文摘As we enter the year 2026,the international system continues to receive shocks from Donald Trump,arguably the 21st century’s most disruptive US leader.His return to the White House in 2025 coincided with the 80th anniversary of the defeat of fascism and the establishment of the United Nations,the multilateral platform that carried the world’s hope for peace,restraint and collective security.The coincidence was unsettling.A world order designed to limit power now confronts a moment in which power is exercised openly,transactionally and unapologetically.
基金supported by the National Natural Science Foundation of China(Grant Nos.11804348,11775056,11975154,12225505,and 12405281)the Science Challenge(Project No.TZ2018005)+2 种基金supported by the Shanghai Pujiang Program(Grant No.23PJ1414600)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB0890203)supported by the Accelerator Technology Helmholtz Infrastructure consortium ATHENA.
文摘The effects of initial spin orientation on the final electron beam polarization in laser wakefield acceleration in a pre-polarized plasma are investigated theoretically and numerically.From the results of variation of the initial spin direction,the spin dynamics of the electron beam are found to depend on the self-injection mechanism.The effects of wakefields and laser fields are studied using test particle dynamics and particle-in-cell simulations based on the Thomas-Bargmann-Michel-Telegdi equation.Compared with transverse injection,longitudinal injection is found to be preferable for obtaining a highly polarized electron beam.
文摘In an era of profound changes to global trade,food security,and industrial organization,the ChinaIndonesia“Two Countries,Twin Parks”initiative has emerged as a strategic experiment with farreaching implications.Anchored in marine protein processing and advanced food manufacturing,this collaboration reflects not only a convergence of economic interests but also a deliberate rethinking of how China engages with global resources,technology,and partners.
基金supported by the National Key R&D Program of China(Grant No.2022YFC3004704)the National Natural Science Foundation of China(Grant No.52174166)Graduate Research and Innovation Foundation of Chongqing,China(Grant No.CYB23031),which were gratefully acknowledged.
文摘During deep coal mining,an instability failure of coal usually occurs under the combined effect of initial damage and triaxial cyclic loading and unloading(TCLU).Therefore,this study investigated the impact of initial damage on mechanical behavior and acoustic emission(AE)characteristics of coal under TCLU.Initial damage variables(IDVs)of coal specimens were quantified using preloading,followed by TCLU experiments to assess the deformation,energy distribution,and fracture development.The results revealed that the increase in IDVs significantly reduced the structural integrity of coal specimens,increased the cumulative irreversible strain,and enhanced the dissipated energy owing to microfracture expansion.Moreover,AE monitoring showed earlier activation of fractures and a higher occurrence of large-scale rupture events of coal specimens with high IDVs,which correlated with decreasing AE b values(reflecting the different scales of fracture within specimens)and increasing S values(reflecting the AE activity within specimens).Additionally,computed tomography analysis revealed intensified fracture networks and increasing three-dimensional fractal dimensions of coal specimens with higher IDVs.Finally,the coupling effect of TCLU and initial damage on the weakening mechanism of coal was investigated.Initial damage significantly reduced the structural integrity of coal by increasing the number of weak planes within coal specimens,contributing to the earlier activation and rapid expansion of fractures at low stress levels under TCLU and eventually accelerating the weakening process of coal.This study provides a scientific basis and theoretical support for the prevention and control of dynamic disasters in deep coal mining.
基金the Bidding Project of the Industrialization Technology of High Performance Polymer Emulsion and-Aqueous Wood Coating from YueGang Key Fields of Technology(No.B10-B2050260)
文摘The prepolymer polyurethanes （PUs） based on isophorone diisocyanate （IPDI）, poly（propylene glycol） （PPG）, 1,4-butanediol （BDO） and dimethylopropionic acid （DMPA） were synthesized at 75-80 ℃ for 7-8 hours, using dibutyltin dilauate （DBTDL） as catalyzer, and polyurethane-acrylate hybrid emulsion was prepared after methyl methacrylate （MMA） was polymerized, using potassium persulfate and azobisisobutyronitrile （AIBN） as initiator, respectively. The influences of these factors such as the kind of initiator, the feed method of initiator and the addition of initiator on properties of polyurethane-acrylate were studied. The FTIR and GPC of aqueous polyurethane were analyzed. The FTIR spectra show that the degree of microphase-separate between the soft segments and rigid segments is high. The analysis of molecular weights stated that molecular weights increased most significantly after amine was added. The experimental results reveal that the appearance of emulsion is excellent, the film is harder and the water absorption radio of the film is less when oil-solubility AIBN is used as initiator. The semi-continuous can increase the molecular weight of polymer and the optimum amount of the initiator was 3% for MMA.
基金supported by the "Tenth Five" National Scientific and Technological Projects (No.2004BA310A41 )
文摘Multifunctional organolithium initiator was prepared in cyclohexane solvent. The process started with adding the cyclohexane solution of butadiene to naphthalene-lithium in batches to produce butadiene oligomer dilithium with 4-8 butadiene repeating units. In the first feeding, the maximum loading of cyclohexane and the minimum concentration of butadiene cyclohexane solution must be controlled under Vcyclohexane 〈 1.33 VTHF and p 〉 40.6cN. Then, SnCl4 was added and eventually the multifunctional organolithium initiator containing Sn atom was synthesized through coupling reaction. Experiment results showed that adding the cyclohexane solution in batches was effective in overcoming some difficulties, such as insolubility of naphthalene-lithium in cyclohexane, low efficiency of naphthalene-lithium in initiating butadiene. In practice, benzene can be replaced by cyclohexane completely, which can not only reduce environmental pollution from benzene, but also overcome the difficulty of solvent recovery caused by similar boiling point between benzene and cyclohexane. Prepared with multifunctional organolithium containing Sn atom as initiator, the star-shaped solution polymerized styrene-butadiene rubber （star S-SBR） with better vulcanization performances, lower rolling resistance and higher wet-skid resistance was obtained.
