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Grasp Control of Dexterous Hands Based on Bibliometric Analysis:A Survey
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作者 Zhe Xu Sihan Huang +3 位作者 Liya Yao Jiahao Zhu Guoxin Wang Yan Yan 《Chinese Journal of Mechanical Engineering》 2025年第6期47-66,共20页
Recent years have witnessed unprecedented development in humanoid robotics,with dexterous hand grasping emerging as a focal research area across industrial and academic sectors.To track the state-of-the-art dexterous ... Recent years have witnessed unprecedented development in humanoid robotics,with dexterous hand grasping emerging as a focal research area across industrial and academic sectors.To track the state-of-the-art dexterous hand grasp,a review of dexterous hand grasp based on bibliometric analysis is executed.The related studies on dexterous hand grasp are collected from the Web of Science for analysis,where the publication details and cooperation situations from the perspectives of country,institute,etc.are discussed.The keywords cluster is adopted to find the hot research topic of dexterous hand grasp.The development trend of dexterous hand grasp is explored based on the top 25 keywords with the strongest citation bursts.The review findings indicate that precision control via multimodal fusion,autonomous task understanding and intelligent decision,and in-hand dexterous manipulation are top three hotspots in future. 展开更多
关键词 Humanoid robot dexterous hand Grasp control Bibliometric analysis Development trend
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Long-term motion prediction and dexterous capturing analysis for tumbling satellites
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作者 Dezhi ZHANG Guocai YANG +3 位作者 Junhong JI Shaowei FAN Minghe JIN Hong LIU 《Chinese Journal of Aeronautics》 2025年第12期415-429,共15页
Accurate motion prediction of free-tumbling satellites is crucial for the success of capture operations.This paper proposes a two-step method to estimate the motion states and parameters of such satellites,thereby ena... Accurate motion prediction of free-tumbling satellites is crucial for the success of capture operations.This paper proposes a two-step method to estimate the motion states and parameters of such satellites,thereby enabling precise long-term motion prediction.This paper begins with a measurement of the system's degree of observability,quantified through the Empirical Observability Gramian(EOG).Based on this measurement,a batch processing algorithm is first employed to estimate the satellite's constant parameters offline.Subsequently,an online filtering algorithm,utilizing a minimal state set,fine-tunes these parameters and estimates the motion states in real time.This integrated approach significantly enhances both convergence properties and estimation accuracy,particularly for systems with poor observability.Utilizing the predicted long-term motion of the satellite,a composite evaluation metric is formulated to identify the optimal capture point and moment.The base pose of the space robot is then adjusted to ensure that the optimal capture point lies within the manipulator's dexterous workspace,which is determined through a pre-constructed capability map.The effectiveness of the proposed method is demonstrated through both simulation and experimental results. 展开更多
关键词 dexterous capturing Motion prediction OBSERVABILITY Parameter estimation Tumbling satellites
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IntuiGrasp:Bio-inspired Dexterous Hand with Intuitive Teaching
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作者 Yihao ZHOU Haohui HUANG +1 位作者 Chenguang YANG Wenjun YE 《Artificial Intelligence Science and Engineering》 2025年第3期220-228,共9页
IntuiGrasp is a novel three-fingered dexterous hand that pioneers bio-inspired demonstrations with intuitive priors(BDIP)to bridge the gap between human tactile intuition and robotic execution.Unlike conven-tional pro... IntuiGrasp is a novel three-fingered dexterous hand that pioneers bio-inspired demonstrations with intuitive priors(BDIP)to bridge the gap between human tactile intuition and robotic execution.Unlike conven-tional programming,BDIP leverages human's innate priors(e.g.,“A pack of tissues requires gentle grasps,cups demand firm contact”)by enabling real-time transfer of gesture and force policies during physical demon-stration.When a human demonstrator wears IntuiGrasp,driven rings provide real-time haptic feedback on contact stress and slip,while inte-grated tactile sensors translate these human policies into image data,offering valuable data for imitation learning.In this study,human teachers use IntuiGrasp to demonstrate how to grasp three types of objects:a cup,a crumpled tissue pack,and a thin playing card.IntuiGrasp translates the policies for grasping these objects into image information that describes tactile sensations in real time. 展开更多
关键词 bio-inspired dexterous hand haptic demonstration imitation learning intuitive priors tactile-visual fusion
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Design and control of integrated pneumatic dexterous robot finger 被引量:8
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作者 王志恒 张立彬 +2 位作者 鲍官军 钱少明 杨庆华 《Journal of Central South University》 SCIE EI CAS 2011年第4期1105-1114,共10页
Based on flexible pneumatic actuator(FPA),bending joint and side-sway joint,a new kind of pneumatic dexterous robot finger was developed.The finger is equipped with one five-component force sensor and four contactless... Based on flexible pneumatic actuator(FPA),bending joint and side-sway joint,a new kind of pneumatic dexterous robot finger was developed.The finger is equipped with one five-component force sensor and four contactless magnetic rotary encoders.Mechanical parts and FPAs are integrated,which reduces the overall size of the finger.Driven by FPA directly,the joint output torque is more accurate and the friction and vibration can be effectively reduced.An improved adaptive genetic algorithm(IAGA) was adopted to solve the inverse kinematics problem of the redundant finger.The statics of the finger was analyzed and the relation between fingertip force and joint torque was built.Finally,the finger force/position control principle was introduced.Tracking experiments of fingertip force/position were carried out.The experimental results show that the fingertip position tracking error is within ±1 mm and the fingertip force tracking error is within ±0.4 N.It is also concluded from the theoretical and experimental results that the finger can be controlled and it has a good application prospect. 展开更多
关键词 pneumatic dexterous finger flexible pneumatic actuator (FPA) robot multi-fingered dexterous hand bending joint sidesway joint
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DESIGN OF A NOVEL DEXTEROUS ROBOT HAND 被引量:4
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作者 JiangLi LiuHong +3 位作者 XieZongwu JinMinghe GaoXiaohui HirzingerG 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2004年第3期360-363,共4页
In the robotic community more and more hands are developed. Based on theexperience of HIT Hand and DLR Hand II, a smaller and easier manufactured dexterous robot hand withmultisen-sory function and high integration is... In the robotic community more and more hands are developed. Based on theexperience of HIT Hand and DLR Hand II, a smaller and easier manufactured dexterous robot hand withmultisen-sory function and high integration is jointly developed. The prototype of the hand issuccessfully built. It has 4 fingers in total 13-DOFs (degree of freedom). Each finger has 3-DOFsand 4 joints, the last 2 joints are mechanically coupled by means of four-bar linkage mechanism. Italso has an additional DOF to realize motion of the thumb relative to the palm. The fingertip forcecan reach up to 10 N. Full integration of mechanical body, actuation system, multisensory system andelectronics is a significant feature. DSP based control system is implemented in PCI busarchitecture and the serial communication between the hand and DSP needs only 2 lines. 展开更多
关键词 dexterous robot hand MULTISENSORY INTEGRATION Serial communication
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Cartesian impedance control of dexterous robot hand 被引量:2
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作者 姜力 刘宏 蔡鹤皋 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2005年第3期239-244,共6页
Presents a novel compliant motion control for a robot hand using the Cartesian impedance approach based on fingertip force measurements. The fingertip can accurately track desired motion in free space and appear as me... Presents a novel compliant motion control for a robot hand using the Cartesian impedance approach based on fingertip force measurements. The fingertip can accurately track desired motion in free space and appear as mechanical impedance in constrained space. In the position based impedance control strategy, any switching mode in contact transition phase is not needed. The impedance parameters can be adjusted in a certain range according to various tasks. In this paper, the analysis of the finger’s kinematics and dynamics is given. Experimental results have shown the effectiveness of this control strategy. 展开更多
关键词 cartesian impedance control sliding mode control dexterous robot hand
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Design and modeling for a kind of humanoid dexterous hand with elastic palm
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作者 魏博 蒋志宏 +5 位作者 肖涛 袁宝峰 李洪杰 李辉 董悫 刘士龙 《Journal of Beijing Institute of Technology》 EI CAS 2013年第4期470-476,共7页
With dexterous hands, robots can improve the work scope and work ability significantly. As palms of the existing multi-hand robots are made of steel plates that have small contact area, the robots cannot grab firmly. ... With dexterous hands, robots can improve the work scope and work ability significantly. As palms of the existing multi-hand robots are made of steel plates that have small contact area, the robots cannot grab firmly. In this study, a new five-fingered dexterous robot hand is developed. Having flexible palm with 17 degree of freedoms ( DOFs), the hand can grasp more stably and firm- ly. First, the forward kinematics and inverse kinematics of the fingers and the hand are calculated. Then, the connection between the force exerting on the end effectors and the torque exerting on the joint is set up, laying the foundation for the following control. Finally, through the analysis and sim- ulation of the position, velocity and acceleration, the trajectory planning has a better performance. 展开更多
关键词 dexterous hands flexible palm inverse kinematics MODELING
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System design of a dexterous lightweight robot arm with remote control
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作者 Li Tian Sun Kui Jiang Zainan Xie Zongwu Liu Hong 《High Technology Letters》 EI CAS 2012年第3期248-255,共8页
This paper presents a novel remote controlled dexterous robot arm with 6 degrees of freedom (DOF). As a highly integrated mechatronics system, sensors and their signal processing system are integrated inside each jo... This paper presents a novel remote controlled dexterous robot arm with 6 degrees of freedom (DOF). As a highly integrated mechatronics system, sensors and their signal processing system are integrated inside each joint. To lighten the weight, almost all mechanical parts are made of aluminum and the robot control system is placed outside. The modular concept is adopted during the robot design process for time and cost saving. Considering the much greater torque acted on the two shoulder joints, the joint shells are strengthened in the design to increase joint stiffness and suppress system vibration. Meanwhile, to simplify the maintenance, a new spring pins electronic connector is designed to disassemble every joint, connector and link independently without cutting any cables. The teleoperation technology enables the robot to offer more convenient service definitely for people' s daily life. Virtual reality technology is used to solve the time delay problem during teleoperation. Finally, two typical daily chore experiments are implemented to prove the manipulation ability of the dexterous robot arm. 展开更多
关键词 dexterous robot arm LIGHTWEIGHT modular joint virtual reality l multisensory ca-pability
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MANIPULATION KINEMATICS ON DEXTEROUS HANDS CONSIDERING PURE ROLLING CONTACTS AS PASSIVE JOINTS
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作者 Yang Yang Tamio Arai 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2005年第3期361-365,共5页
The manipulation and constraint equations are established by considering the pure rolling motion in a dexterous hand as two passive joints. According to mapping relation among the motion of the system, the differentia... The manipulation and constraint equations are established by considering the pure rolling motion in a dexterous hand as two passive joints. According to mapping relation among the motion of the system, the differential kinematics and mobility are studied. The minimal structure for realizing the task motion of the object is obtained, and the conditions for dexterous manipulation are presented. Finally, some rolling manipulations are used as examples to demonstrate the applicability of approach proposed. 展开更多
关键词 Pure rolling Passive joints Differential kinematics dexterous hands
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Hollow fiber-based strain sensors with desirable modulus and sensitivity at effective deformation for dexterous electroelastomer cylindrical actuator
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作者 Yang Zhang Keqi Deng +10 位作者 Tingting Shen Yong Huang Zhenjin Xu Jinhui Zhang Hang Jin Xin Liu Lida Xu Lianjie Lu Shiying Li Daoheng Sun Dezhi Wu 《Microsystems & Nanoengineering》 2025年第1期375-388,共14页
The electroelastomer cylindrical actuators,a typical representation of soft actuators,have recently aroused increasing interest owing to their advantages in flexibility,deformability,and spatial utilization rate.Propr... The electroelastomer cylindrical actuators,a typical representation of soft actuators,have recently aroused increasing interest owing to their advantages in flexibility,deformability,and spatial utilization rate.Proprioception is crucial for controlling and monitoring the shape and position of these actuators.However,most existing flexible sensors have a modulus mismatch with the actuation unit,hindering the free movement of these actuators.Herein,a low-modulus strain sensor based on laser-induced cellular graphitic flakes(CGF)onto the surface of hollow TPU fibers(HTF)is present.Through the electrostatic self-assembly technology,the flexible sensor features a unique hybrid sensing unit including soft HTF as substrate and rigid CGF as conductive path.As a result,the sensor simultaneously possesses desirable modulus(~0.155 MPa),a gauge factor of 220.3(25%<ε<50%),fast response/recovery behaviors(31/62 ms),and a low detection limit(0.1%strain).Integrating the sensor onto the electroelastomer cylindrical actuators enables precise measurement of deformation modes,directions,and quantity.As proof-of-concept demonstrations,a prototype soft robot with high-precision perception is successfully designed,achieving real-time detection of its deformations during the crawling process.Thus,the proposed scheme sheds new light on the development of intelligent soft robots. 展开更多
关键词 dexterous actuator PROPRIOCEPTION electroelastomer cylindrical actuatorsa electroelastomer soft actuatorshave controlling monitoring shape position hollow fiber modulus mismatch
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Human-like dexterous manipulation for anthropomorphic five-fingered hands:A review
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作者 Yayu Huang Dongxuan Fan +5 位作者 Haonan Duan Dashun Yan Wen Qi Jia Sun Qian Liu Peng Wang 《Biomimetic Intelligence & Robotics》 2025年第1期35-57,共23页
Humans excel at dexterous manipulation;however,achieving human-level dexterity remains a significant challenge for robots.Technological breakthroughs in the design of anthropomorphic robotic hands,as well as advanceme... Humans excel at dexterous manipulation;however,achieving human-level dexterity remains a significant challenge for robots.Technological breakthroughs in the design of anthropomorphic robotic hands,as well as advancements in visual and tactile perception,have demonstrated significant advantages in addressing this issue.However,coping with the inevitable uncertainty caused by unstructured and dynamic environments in human-like dexterous manipulation tasks,especially for anthropomorphic five-fingered hands,remains an open problem.In this paper,we present a focused review of human-like dexterous manipulation for anthropomorphic five-fingered hands.We begin by defining human-like dexterity and outlining the tasks associated with human-like robot dexterous manipulation.Subsequently,we delve into anthropomorphism and anthropomorphic five-fingered hands,covering definitions,robotic design,and evaluation criteria.Furthermore,we review the learning methods for achieving human-like dexterity in anthropomorphic five-fingered hands,including imitation learning,reinforcement learning and their integration.Finally,we discuss the existing challenges and propose future research directions.This review aims to stimulate interest in scientific research and future applications. 展开更多
关键词 Anthropomorphic five-fingered hands Human-like dexterous manipulation Robot learning REVIEW
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SoftGrasp:Adaptive grasping for dexterous hand based on multimodal imitation learning
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作者 Yihong Li Ce Guo +4 位作者 Junkai Ren Bailiang Chen Chuang Cheng Hui Zhang Huimin Lu 《Biomimetic Intelligence & Robotics》 2025年第2期116-131,共16页
Biomimetic grasping is crucial for robots to interact with the environment and perform complex tasks,making it a key focus in robotics and embodied intelligence.However,achieving human-level finger coordination and fo... Biomimetic grasping is crucial for robots to interact with the environment and perform complex tasks,making it a key focus in robotics and embodied intelligence.However,achieving human-level finger coordination and force control remains challenging due to the need for multimodal perception,including visual,kinesthetic,and tactile feedback.Although some recent approaches have demonstrated remarkable performance in grasping diverse objects,they often rely on expensive tactile sensors or are restricted to rigid objects.To address these challenges,we introduce SoftGrasp,a novel multimodal imitation learning approach for adaptive,multi-stage grasping of objects with varying sizes,shapes,and hardness.First,we develop an immersive demonstration platform with force feedback to collect rich,human-like grasping datasets.Inspired by human proprioceptive manipulation,this platform gathers multimodal signals,including visual images,robot finger joint angles,and joint torques,during demonstrations.Next,we utilize a multi-head attention mechanism to align and integrate multimodal features,dynamically allocating attention to ensure comprehensive learning.On this basis,we design a behavior cloning method based on an angle-torque loss function,enabling multimodal imitation learning.Finally,we validate SoftGrasp in extensive experiments across various scenarios,demonstrating its ability to adaptively adjust joint forces and finger angles based on real-time inputs.These capabilities result in a 98%success rate in real-world experiments,achieving dexterous and stable grasping.Source code and demonstration videos are available at https://github.com/nubot-nudt/SoftGrasp. 展开更多
关键词 Adaptive grasping dexterous hand Multimodal fusion Imitation learning
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Force-closure orchard dexterous hand grasping model
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作者 Xiulan Bao Mengtao Ren +3 位作者 Xiaojie Ma Biyu Chen Yougang Bao Jincheng Mao 《International Journal of Agricultural and Biological Engineering》 2025年第4期139-148,共10页
The digital orchard is an important trend for the future development of orchards towards intelligentization.The current wide variety of orchard gripping objects with different sizes and material characteristics brings... The digital orchard is an important trend for the future development of orchards towards intelligentization.The current wide variety of orchard gripping objects with different sizes and material characteristics brings challenges for gripping operations.In order to improve the versatility and dexterity of the orchard end-effector,a humanoid 14-degree-of-freedom orchard dexterous hand is designed for agronomic operations.An optimal design scheme of the orchard dexterous hand combining orchard gesture analysis and human hand structure is proposed,and the design of the modular fingers,palm,and overall structure of the orchard dexterous hand is completed.The orthogonal and inverse kinematics model of the dexterous hand is established to analyze the motion space of the fingertips,and the dexterity of the orchard dexterous hand is verified by combining with the Kapandji test.The equivalent distribution model of the contact force is solved according to the Hertz theory,and the grasping matrix is established based on the friction surface contact model to realize force-closure,which describes the relationship between the finger and the object being grasped in the configuration.The experimental platform of dexterous hand in the orchard is built,and the experiments of gesture formation,grasping,and contact force testing are carried out.The results show that the dexterous hand can form all kinds of gestures commonly used in the orchard and can grasp spherical fruit with diameters of 26-90 mm,masses of 11-238 g,and all kinds of orchard-specific working tools;for navel oranges with masses of 234 g,the dexterous hand can realize stable grasping under different gestures.This provides a theoretical basis and technical support for the realization of complex agronomy in orchards. 展开更多
关键词 digital orchard dexterous hand orchard gesture force-closure
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Humanoid dexterous hands from structure to gesture semantics for enhanced human–robot interaction:A review
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作者 Xin Li Wenfu Xu +1 位作者 Zaiqiao Ye Han Yuan 《Biomimetic Intelligence & Robotics》 2025年第4期1-12,共12页
As human–robot interaction(HRI)technology advances,dexterous robotic hands are playing a dual role—serving both as tools for manipulation and as channels for non-verbal communication.While much of the existing resea... As human–robot interaction(HRI)technology advances,dexterous robotic hands are playing a dual role—serving both as tools for manipulation and as channels for non-verbal communication.While much of the existing research emphasizes improving grasping and structural dexterity,the semantic dimension of gestures and its impact on user experience has been relatively overlooked.Studies from HRI and cognitive psychology consistently show that the naturalness and cognitive empathy of gestures significantly influence user trust,satisfaction,and engagement.This shift reflects a broader transition from mechanically driven designs toward cognitively empathic interactions—robots’ability to infer human affect,intent,and social context to generate appropriate nonverbal responses.In this paper,we argue that large language models(LLMs)enable a paradigm shift in gesture control—from rule-based execution to semantic-driven,context-aware generation.By leveraging LLMs and visual-language models,robots can interpret environmental and social cues,dynamically map emotions,and generate gestures aligned with human communication norms.We conducted a comprehensive review of research in dexterous hand mechanics,gesture semantics,and user experience evaluation,integrating insights from linguistics and cognitive science.Furthermore,we propose a closed-loop framework—"perception–cognition–generation–assessment"—to guide gesture design through iterative,multimodal feedback.This framework lays the conceptual foundation for building universal,adaptive,and emotionally intelligent gesture systems in future human–robot interaction. 展开更多
关键词 Human–robot interaction(HRI) dexterous hand Large language models GESTURE Communication
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Human-machine shared control:New avenue to dexterous prosthetic hand manipulation 被引量:4
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作者 YANG DaPeng LIU Hong 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2021年第4期767-773,共7页
At present,albeit the dexterous hand prostheses of multiple degrees of freedom(DOFs)have become prosperous on the market,the user’s demand on intuitively operating these devices have not been well addressed so that t... At present,albeit the dexterous hand prostheses of multiple degrees of freedom(DOFs)have become prosperous on the market,the user’s demand on intuitively operating these devices have not been well addressed so that their acceptance rate is relatively low.The unintuitive control method and inadequate sensory feedback are frequently cited as the two barriers to the successful application of these dexterous products.Recently,driven by the wave of artificial intelligence(AI),a series of shared control methods have emerged,in which"bodily function"(myoelectric control)and"artificial intelligence"(local autonomy,computer vision,etc.)are tightly integrated,and provided a new conceptual solution for the intuitive operation of dexterous prostheses.In this paper,the background and development trends of this type of methods are described in detail,and the potential development directions and the key technologies that need breakthroughs are indicated.In practice,we instantiate this shared control strategy by proposing a new method combining simultaneous myoelectric control,multi-finger grasp autonomy,and augmented reality(AR)feedback together.This method"divides"the human sophisticated reach-and-grasp task into several subtasks,and then"conquers"them by using different strategies from either human or machine perspective.It is highly expected that the shared control methods with hybrid human-machine intelligence could address the control problem of dexterous prostheses. 展开更多
关键词 robotic hand dexterous prostheses shared control computer vision deep learning
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Design and fabrication of a gecko-inspired surface for improving the grasping ability of a humanoid dexterous hand 被引量:2
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作者 JIANG ZhiHong SHEN MingHui +2 位作者 MA YiFan CHE JiangTao LI Hui 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2023年第3期784-792,共9页
Many studies have examined the design,fabrication and characteristics of gecko-inspired adhesives,but applied research on gecko-inspired surfaces in humanoid dexterous hands is relatively scarce.Here,a wedged slanted ... Many studies have examined the design,fabrication and characteristics of gecko-inspired adhesives,but applied research on gecko-inspired surfaces in humanoid dexterous hands is relatively scarce.Here,a wedged slanted structure with a curved substrate suitable for humanoid dexterous fingers was designed and manufactured via ultraprecision machining and replica molding.The adhesion and friction properties of the wedged slanted structure show obvious anisotropic characteristics in the gripping and releasing directions,and the influence of structural parameters and motion parameters on the adhesion and friction was systematically studied.The humanoid dexterous fingers with gecko-inspired surfaces greatly increased the grasping force limit(increase to 4.02 times)based on the grasping of measuring cups with different volumes of water and improved the grasping stability based on the picking up of smooth steel balls of different diameters.This study shows that this process,based on ultraprecision machining and replica molding,is a green,high-efficiency,and low-cost method to fabricate large-area biomimetic surfaces that has potential applications in dexterous humanoid hands to improve grasping ability,stability and adaptability. 展开更多
关键词 gecko-inspired surface curved substrate ultraprecision machining FRICTION humanoid dexterous hand
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A novel dexterity optimization scheme with kinematic uncertainty handling capability for redundant space manipulators
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作者 Xiaohang YANG Dongxu CHEN +2 位作者 Zhiyuan ZHAO Jingdong ZHAO Hong LIU 《Chinese Journal of Aeronautics》 2026年第1期643-655,共13页
In the construction and maintenance for large space equipment,it is essential to ensure the control accuracy and improve the dexterity of the space manipulator.In this paper,a FiniteTime Convergence Kinematic Control(... In the construction and maintenance for large space equipment,it is essential to ensure the control accuracy and improve the dexterity of the space manipulator.In this paper,a FiniteTime Convergence Kinematic Control(FTCKC)added with Acceleration Level Dexterity Optimization(ALDO)scheme is proposed to solve the kinematic uncertainty and dexterity optimization problems of redundant space manipulators.Concretely,distinguishing from the asymptotic convergence property of traditional adaptive Jacobian methods,the FTCKC scheme is adopted to construct the equality constraint to address the model uncertainty problem,and its error can converge within a finite time.Subsequently,the dexterity index is reconstructed at acceleration level by a multi-level target handling method.Then,the equality constraint,optimization task,and limit constraints are reformulated as a quadratic programming problem.Moreover,a Recurrent Neural Network(RNN)is engineered for the constructed FTCKC-ALDO scheme.Finally,the superiority of the FTCKC-ALDO-RNN scheme is verified by experiments. 展开更多
关键词 Dexterity optimization Model uncertainty Recurrent Neural Network(RNN) Trajectory tracking Large space equipment
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热激活延迟荧光敏化荧光薄膜激发态弛豫:受体跃迁偶极矩的关键作用
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作者 杜敏 郭子龙 +1 位作者 马骁楠 杨文胜 《高等学校化学学报》 北大核心 2025年第10期85-96,共12页
在热激活延迟荧光(TADF)敏化荧光(TSF)体系中,受体跃迁偶极矩(TDM)对激发态弛豫路径的影响尚不明确.本文通过构建受体TDM差异显著的TSF薄膜—双[4-(9,9-二甲基-9,10-二氢吖啶)苯基]硫砜/1,3,5,7-四甲基-8-苯基-氟硼二吡咯(DMAC-DPS/TMeP... 在热激活延迟荧光(TADF)敏化荧光(TSF)体系中,受体跃迁偶极矩(TDM)对激发态弛豫路径的影响尚不明确.本文通过构建受体TDM差异显著的TSF薄膜—双[4-(9,9-二甲基-9,10-二氢吖啶)苯基]硫砜/1,3,5,7-四甲基-8-苯基-氟硼二吡咯(DMAC-DPS/TMePh-BDP)与双二苯胺基苯基蒽醌/2,4-双[4-(二乙氨基)-2-羟基苯基]方酸[AQ(PhDPA)_(2)/DiEA-SQ],利用稳态/瞬态荧光技术探究了模型体系的激发态弛豫路径.结果表明,TDM较大的DiEA-SQ通过增强光谱重叠积分扩大Förster半径(R_(0)),从而有效抑制了Dexter能量转移(DET).值得注意的是,高TDM受体虽可抑制DET导致的无辐射弛豫,但其光致发光量子产率因自吸收(SA)效应而显著降低.研究发现,提升受体TDM是增强Förster共振能量转移(FRET)效率并抑制DET的有效策略,但需设计具有更大斯托克斯位移的受体分子或结合光学结构以抑制SA效应.这种机理层面的理解为TSF发光器件的设计提供了理论支撑. 展开更多
关键词 热激活延迟荧光敏化荧光 跃迁偶极矩 Förster共振能量转移 Dexter能量转移 自吸收效应
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