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再论DETERMINER
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作者 国文 《昌潍师专学报》 1998年第3期56-57,共2页
Determiner 是国外语言学家提出的话法术语,在各种语法著作中当做词类介绍,国内语言学界将其译为"限定词"。作者在分析了其来源、构成、分类及作用等后,提出 Determiner 不应被视作"词",而应看作是词组成分,可译为&... Determiner 是国外语言学家提出的话法术语,在各种语法著作中当做词类介绍,国内语言学界将其译为"限定词"。作者在分析了其来源、构成、分类及作用等后,提出 Determiner 不应被视作"词",而应看作是词组成分,可译为"限定语"。 展开更多
关键词 determiner 限定词 词组成分 限定语
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Layers of the Determiner Phrase in Mandarin Chinese
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作者 HONG Shuang 《Journal of Literature and Art Studies》 2018年第6期946-950,共5页
There are three probabilities to claim that Mandarin Chinese has multiple Determiner Phrase (DP) structures: (1) Simpson (2001) takes “de” in nominal phrase as the head of the structure: “Zhangsan de shu” ... There are three probabilities to claim that Mandarin Chinese has multiple Determiner Phrase (DP) structures: (1) Simpson (2001) takes “de” in nominal phrase as the head of the structure: “Zhangsan de shu” is a DP and “de” is the head D. In this theory, when “de” and demonstratives like “this/that” appear in the same structure, there is going to be a multiple DP structure. (2) Huang, Li & Li (2008) take both pronouns and demonstratives as the heads of the appositive structures like “tamen zhe sange haizi”. In this opinion, Mandarin Chinese has Split-D structures like Italian, Hungarian and Greek. (3) It seems that a Mandarin DP could have double heads D when two determiners both appear in the same structure. In “renhe zhe lei wenti”, the determiners “renhe” and “zhe” both appear. The structure is going to be analyzed as a multiple DP or a Split-D structure. However, the paper proves that Mandarin Chinese has no multiple DP structures, not like Italian, Hungarian or Greek. 展开更多
关键词 nominal phrase determiner phrase layers of DP
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Japanese-Chinese Machine Translation of Japanese Determiners Based on Templates
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作者 Ling Wang Zhongjian Wang 《Modern Electronic Technology》 2022年第1期43-48,共6页
The machine translation of Japanese sentences with determiners,like“shi­ka...nai”,“tyoutto...dakedeha”,“tada...dake”and so on,are more special and regular on sentences structure.The research collects and cl... The machine translation of Japanese sentences with determiners,like“shi­ka...nai”,“tyoutto...dakedeha”,“tada...dake”and so on,are more special and regular on sentences structure.The research collects and classifies the Japanese sentences which contain the determiners.The classification is carried out by according to the characteristics of Japanese sentences and translation habit of Chinese sentences.Through further abstraction and sim­plification,translation templates are extracted by gathering grammar rules information,studying syntax and analysis the collocation mode of sentenc­es.Those determiners express confirmed meaning,and the corresponding translation Chinese sentences have the same characteristic.By analyzing the sentence characteristics with determiners and formalizing the sentences struc­ture,the translation templates are abstracted.By investigating the structure characteristic of original sentences with translation templates,the similarity algorithm was defined.The threshold value of the similarity calculation was obtained by preliminary experiments,and the experiments of Japanese-Chi­nese translation are carried out by a small corpus.The experimental results for several kinds of Japanese sentences with determiners show the translation accuracy rate is 68.6%,template coverage rate reach 83.3%.At last,through the analysis for the translation errors,following conclusion is drawn:the results of morphological analysis are erroneous,because the error of word segmentation the part of speech tagging also are erroneous,result in the grammar structure cannot match with templates;the original sentences are long and especially complex sentences;the templates are too complicated;the similarity calculation method needs to discuss further,and so on. 展开更多
关键词 Japanese determiners Similarity calculation Machine translation Translation templates
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Establishment of a Determination Method for Fruit Texture in Chieh-qua Using Texture Analyzer
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作者 Ying WANG Xuan DU Na LIU 《Agricultural Biotechnology》 2026年第1期54-59,共6页
[Objectives]This study was conducted to establish a quantitative assessment method for the textural quality of chieh-qua fruit.[Methods]Using two modes of a texture analyzer,namely TPA(texture profile analysis)and pun... [Objectives]This study was conducted to establish a quantitative assessment method for the textural quality of chieh-qua fruit.[Methods]Using two modes of a texture analyzer,namely TPA(texture profile analysis)and puncture,the index data of the fruit were obtained by setting different trigger forces,deformation levels,test speeds,as well as puncture speeds and puncture depths.The data included TPA hardness,adhesiveness,springiness,cohesiveness,gumminess,chewiness,resilience,as well as skin hardness,skin toughness,flesh hardness,fracturability,and compactness.[Results]Different deformation levels had a significant impact on all parameters.Hardness,adhesiveness,gumminess and chewiness showed a trend of first increasing and then decreasing with the deformation level increasing.When the deformation level was 30%,the adhesiveness,gumminess and chewiness reached their maximum values.When the deformation level was 50%,TPA hardness reached its maximum.When the compression speed was 3 mm/s,the measured values of TPA hardness,adhesiveness,chewiness,and resilience were at their maximums.The skin hardness varied significantly under different trigger forces.When the trigger force was 15 g,the skin hardness reached a maximum value of 944.63 g,and the skin toughness,flesh hardness,fracturability,and compactness also reach their maximum values respectively.When the puncture depth was 12 mm,the flesh hardness and skin toughness reached their maximums of 682.51 g and 1.82 mm,respectively.In the TPA mode,the flesh hardness of chieh-qua showed an extremely significant negative correlation with springiness,cohesiveness,and resilience(P<0.01).The fruit fracturability detected by puncture had an extremely significant positive correlation with compactness(P<0.01).[Conclusions]The evaluation method for measuring chieh-qua texture by combining TPA and the puncture mode could accurately and quantitatively reflect the differences in the flesh texture quality of chieh-qua.The optimal parameters for texture measurement of chieh-qua fruit were determined as a 15 g trigger force with 50%deformation and a 3 mm/s compression speed in TPA mode,and a 15 g trigger force with a 12 mm puncture depth in puncture mode.Puncture speed was found to have no significant effect on the texture indices of chieh-qua. 展开更多
关键词 CHIEH-QUA Texture analyzer Texture quality Determination method
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Spatiotemporal Variability of Influencing Factors on Tuberculosis Incidence in Jiangsu Province,China during 2011−2021
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作者 Yifan Tang Tenglong Li +7 位作者 Cheng Chen Kai Wang Mingming Chen Junhui Lin Sifan Wang Limei Zhu Chengxiu Ling Qiao Liu 《Biomedical and Environmental Sciences》 2026年第2期234-238,共5页
Tuberculosis(TB),one of the oldest infectious diseases caused by Mycobacterium tuberculosis,poses a considerable challenge to global public health.There are approximately 10 million new TB cases worldwide annually,and... Tuberculosis(TB),one of the oldest infectious diseases caused by Mycobacterium tuberculosis,poses a considerable challenge to global public health.There are approximately 10 million new TB cases worldwide annually,and TB claims the lives of nearly 3 million people each year,making it one of the leading causes of death from a single infectious disease[1].China ranks third globally in terms of TB burden,with approximately 733,000 TB cases reported in 2023[2].Based on the ecological model of health determinants developed by Whitehead and Dahlgren,health determinants can be classified into direct causes. 展开更多
关键词 tuberculosis incidence infectious diseases influencing factors mycobacterium tuberculosisposes spatiotemporal variability China ecological model health determinants jiangsu province
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Research on the visualization method of lithology intelligent recognition based on deep learning using mine tunnel images
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作者 Aiai Wang Shuai Cao +1 位作者 Erol Yilmaz Hui Cao 《International Journal of Minerals,Metallurgy and Materials》 2026年第1期141-152,共12页
An image processing and deep learning method for identifying different types of rock images was proposed.Preprocessing,such as rock image acquisition,gray scaling,Gaussian blurring,and feature dimensionality reduction... An image processing and deep learning method for identifying different types of rock images was proposed.Preprocessing,such as rock image acquisition,gray scaling,Gaussian blurring,and feature dimensionality reduction,was conducted to extract useful feature information and recognize and classify rock images using Tensor Flow-based convolutional neural network(CNN)and Py Qt5.A rock image dataset was established and separated into workouts,confirmation sets,and test sets.The framework was subsequently compiled and trained.The categorization approach was evaluated using image data from the validation and test datasets,and key metrics,such as accuracy,precision,and recall,were analyzed.Finally,the classification model conducted a probabilistic analysis of the measured data to determine the equivalent lithological type for each image.The experimental results indicated that the method combining deep learning,Tensor Flow-based CNN,and Py Qt5 to recognize and classify rock images has an accuracy rate of up to 98.8%,and can be successfully utilized for rock image recognition.The system can be extended to geological exploration,mine engineering,and other rock and mineral resource development to more efficiently and accurately recognize rock samples.Moreover,it can match them with the intelligent support design system to effectively improve the reliability and economy of the support scheme.The system can serve as a reference for supporting the design of other mining and underground space projects. 展开更多
关键词 rock picture recognition convolutional neural network intelligent support for roadways deep learning lithology determination
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Pressure calibrations of high-pressure large-volume presses at HPSTAR
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作者 Yongjiang Xu Peiyan Wu +17 位作者 Sheng Shang Xue Wang Taihang Li Shuchang Gao Shijie Lv Hang Cheng Qianzhi Xu Shang Lei Jiajia Feng Lei Zhao Wim van Westrenen Takayuki Ishii Bin Chen Lei Su Yang Ding Wenge Yang Ho-Kwang Mao Yanhao Lin 《Matter and Radiation at Extremes》 2026年第1期111-130,共20页
Large-volume presses(LVPs)are widely utilized in diverse research fields—including high-pressure physics,chemistry,materials science,and Earth and planetary sciences—to investigate the physical and chemical properti... Large-volume presses(LVPs)are widely utilized in diverse research fields—including high-pressure physics,chemistry,materials science,and Earth and planetary sciences—to investigate the physical and chemical properties of materials under extreme high-pressure and hightemperature conditions.A prerequisite for achieving reproducible property measurements is the determination and control of pressure within experimental setups.However,the lack of precise pressure calibration in LVPs hinders the broader application of such devices in ultrahigh-pressure studies.This study employs a suite of standard phase transition-based pressure markers—comprising metallic conductors,semiconductors,and minerals—through both in situ and ex situ identification approaches,to establish pressure calibration curves ranging from 0.4 to>30 GPa for various types of LVP installed at the Center for High Pressure Science and Technology Advanced Research(HPSTAR),Beijing,including piston–cylinder,cubic,and multi-anvil presses.The results provide a unified and traceable pressure reference for highpressure experiments conducted at HPSTAR,while also offering technical guidance and calibration standards for other researchers utilizing similar LVP systems,thereby enabling more consistent comparison between different laboratories.This work facilitates the advancement of LVP research toward broader applications in higher-pressure regimes. 展开更多
关键词 CHEMISTRY earth planetary sciences pressure calibration high pressure physics materials science investigate physical chemical properties materials determination control pressure
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Modernization of traditional Chinese medicine in cancer therapy:“3 D”innovative Chinese medicine
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作者 Hui Liu Yunxiao Ge Zigang Dong 《Chinese Journal of Natural Medicines》 2026年第2期189-202,共14页
Traditional Chinese medicine(TCM)has garnered increasing attention globally,with its modernization becoming a prominent research focus both within China and internationally.However,the lack of a precise definition for... Traditional Chinese medicine(TCM)has garnered increasing attention globally,with its modernization becoming a prominent research focus both within China and internationally.However,the lack of a precise definition for TCM modernization has hindered clear guidance for its development.Additionally,cancer remains a significant global public health challenge,largely untreatable with current methods.Therefore,a comprehensive understanding of TCM modernization is crucial for its evolution,revolution,drug discovery,and cancer therapy.This study provides an overview of the history,theory,characteristics,and evolution of TCM,highlighting its potential in cancer prevention and treatment.We propose a definition for TCM modernization,innovative Chinese medicine(ICM),and elucidate strategies to elevate TCM from a supporting role to a leading one.Electronic databases such as PubMed,Web of Science,ScienceDirect,and Clinical Trials were utilized to retrieve relevant literature spanning from 1979 to 2024,with most publications being from the last five years,using keywords like“Traditional Chinese medicine”,“Cancer”,“Mechanism”,and“Clinical trial”.In this study,we introduce the theory of TCM modernization following target identification and initial compound screening:ICM,defined by“3 D”elements:definite active ingredient composition and content,determined functional mechanism,and detection through evidence-based medicine.Overall,the“3 D”definition of ICM will establish a standard for ICM,accelerate TCM modernization,enhance drug discovery targeting cancer and various human diseases,and benefit patients worldwide. 展开更多
关键词 Traditional Chinese medicine Innovative Chinese medicine Definite active ingredient composition and content Determined functional mechanism Detection through evidence-based medicine Cancer therapy Drug discovery
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Content Determination of Zhuang Medicine Sauropus spatulifolius Beille from Guangxi
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作者 Lixin SUN Yongshan JIN +8 位作者 Wenjing YANG Aipeng LI Yarong WEI Liangna SU Chengxu CHEN Fangyuan SHEN Yanmin LU Suoyi HUANG Lixiang LU 《Medicinal Plant》 2026年第1期1-4,共4页
[Objectives]To determine the content of Zhuang medicine Sauropus spatulifolius Beille from Guangxi.[Methods]The amino acid content of S.spatulifolius Beille was determined by ultraviolet spectrophotometry(UVs).The con... [Objectives]To determine the content of Zhuang medicine Sauropus spatulifolius Beille from Guangxi.[Methods]The amino acid content of S.spatulifolius Beille was determined by ultraviolet spectrophotometry(UVs).The content of kaempferol-3-O-gentiobioside in S.spatulifolius Beille was determined by liquid chromatography-mass spectrometry(LC-MS).Pesticide residues in S.spatulifolius Beille were detected by gas chromatography-mass spectrometry(GC-MS).Heavy metal elements arsenic(As),cadmium(Cd),and lead(Pb)in S.spatulifolius Beille were detected by inductively coupled plasma mass spectrometry(ICP-MS).[Results]The amino acid content in S.spatulifolius Beille was 3.233 mg/g,with a relative standard deviation(RSD)of 0.36%.The content of kaempferol-3-O-gentiobioside was 1.15μg/mL.No pesticide residues or heavy metals were detected in the S.spatulifolius Beille medicinal material.[Conclusions]This study improves the quality control system for S.spatulifolius Beille and provides a reference basis for the quality standard control of Zhuang medicine S.spatulifolius Beille from Guangxi. 展开更多
关键词 Zhuang medicine Sauropus spatulifolius Beille Liquid chromatography-mass spectrometry(LC-MS) Gas chromatography-mass spectrometry(GC-MS) Inductively coupled plasma mass spectrometry(ICP-MS) Content determination
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The Stretched Field Method for Approximating Gross Determiners Ⅱ
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作者 ZHANG Jie(The First Institute of Oceanolagy, SOA, Qingdao 266003)FANG Guohong(Institute of Oceanology, Academia Sinica, Qingdao 266071) 《Systems Science and Systems Engineering》 CSCD 1996年第4期473-476,478-479,共7页
The paper is the continuation of the previous article in which the stretched field method on is developed to solve the equations for grossly determiners. The first degree result is the same as the Lundgren’s small pa... The paper is the continuation of the previous article in which the stretched field method on is developed to solve the equations for grossly determiners. The first degree result is the same as the Lundgren’s small parameter expansion 展开更多
关键词 The Stretched Field Method for Approximating Gross determiners
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Strong variation in frequencies of male and female determiners between neighboring housefly populations 被引量:1
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作者 Xuan Li Fangfei Lin +1 位作者 Louis van de Zande Leo W.Beukeboom 《Insect Science》 SCIE CAS CSCD 2022年第5期1470-1482,共13页
Sex-determination mechanisms evolve rapidly and vary between species.Occasionally,polymorphic systems are found,like in the housefly.Studying the dynamics and stability of such systems can provide a better understandi... Sex-determination mechanisms evolve rapidly and vary between species.Occasionally,polymorphic systems are found,like in the housefly.Studying the dynamics and stability of such systems can provide a better understanding of the evolution of sex-determination systems.In the housefly,dominant male-determining loci(M)can lie not only on the Y chromosome(M^(Y)),but also on autosomes(M^(A))or the X chromosome(M^(X)).M enforces male development by inhibiting the female-determining gene transformer(tra).A mutant tra allele,tra^(D),is insensitive to M and is a dominant female determiner.M^(Y) prevails at high latitudes and polymorphic M loci together with tra^(D) at low latitudes.To get more insight into the stability and frequencies of these sex determiners with mutually exclusive dominance,we investigated 5 regional Spanish populations.We found strong variation among populations.Two populations with hemizygous M^(III) were found,2 contained homozygous M^(X) with additional hemizygous MI and M^(II) in 1 population.One population contained homozygous and hemizygous M^(X) with additionally hemizygous M^(II).All females in populations with homozygous M,had tra^(D),whereas no tra^(D) was found in populations without homozygous M.Our results indicate locally stable systems may either harbor a single hemizygous M and no tra^(D),corresponding to a male heterogametic system,or homozygous and/or multiple M and heterozygous tra^(D),reminiscent of a female heterogametic system.They support that M loci can accumulate in the presence of a dominant female determiner.Limited migration between populations may contribute to the stability of these systems. 展开更多
关键词 ANEUPLOIDY HOUSEFLY polymorphic sex determination recombination regional variation sex-determining loci
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DETERMINE评分在急性ST段抬高型心肌梗死患者预后中的预测价值
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作者 石子凡 刘泽岩 +3 位作者 徐凤 万俊 王仙岩 程景林 《医师在线》 2025年第9期55-58,共4页
目的探讨DETERMINE评分在急性ST段抬高型心肌梗死(STEMI)患者预后中的预测价值。方法选择2022年1月~2023年2月期间安徽医科大学第二附属医院收治的206例急性STEMI患者作为研究对象,根据病理性Q波、碎裂QRS波导联数及T波倒置导联数计算... 目的探讨DETERMINE评分在急性ST段抬高型心肌梗死(STEMI)患者预后中的预测价值。方法选择2022年1月~2023年2月期间安徽医科大学第二附属医院收治的206例急性STEMI患者作为研究对象,根据病理性Q波、碎裂QRS波导联数及T波倒置导联数计算通过心电图指标评估心肌梗死面积以确定除颤器植入风险评分(DETERMINE评分),并根据DETERMINE评分以近似四分位数分为四组,包括0~2分组(n=73)、3~5分组(n=36)、6~9分组(n=61)和≥10分组(n=36),比较各组间超声心电图指标、术后TIMI血流分级、罪犯血管及冠状动脉狭窄程度(SYNTAX积分)等差异,并根据随访1年的预后状况,即主要不良心血管事件(MACE)发生情况,采用多因素Logistic回归分析影响急性STEMI患者预后的相关因素。结果各组性别、年龄、BMI、基础疾病史、罪犯血管等基线资料比较,差异无统计学意义(P>0.05)。各组左心室舒张末期容积(LVEDV)比较,差异无统计学意义(P>0.05);0~2分组左心室舒张末期内径(LVEDd)显著低于6~9分组、≥10分组,差异有统计学意义(P<0.05);四组左心室射血分数(LVEF)比较,≥10分组<6~9分组<3~5分组<0~2分组,差异有统计学意义(P<0.05);各组术后TIMI血流分级比较,差异无统计学意义(P>0.05);四组SYNTAX积分比较,≥10分组>6~9分组>3~5分组>0~2分组,差异有统计学意义(P<0.05);多因素Logistic回归分析结果显示,DETERMINE评分和SYNTAX积分升高、LVEDd和LVEF降低是STEMI患者发生MACE的危险因素(OR=2.447、2.000、1.556、1.848,P<0.05)。结论DETERMINE评分用于预测急性STEMI患者的预后具有一定的临床应用价值,为判断急性STEMI患者预后提供一种简单且快速的风险评估工具。 展开更多
关键词 DETERMINE评分 ST段抬高型心肌梗死 主要不良心血管事件 预测价值
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Capillary electrophoresis as sample introduction system for highly sensitive and interference-free determination of ^(99)Tc by ICP-MS 被引量:2
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作者 Dan Zhou Liangjin Bao +6 位作者 Haoqi Long Duo Zhou Yuwei Xu Bo Wang Chuanqin Xia Liang Xian Chengbin Zheng 《Chinese Chemical Letters》 2025年第4期398-402,共5页
Although inductively coupled plasma mass spectrometry(ICP-MS) retains high sensitivity and has been intensively used for the measurement of ^(99)Tc, it usually suffers from tedious, expensive, and timeconsuming sample... Although inductively coupled plasma mass spectrometry(ICP-MS) retains high sensitivity and has been intensively used for the measurement of ^(99)Tc, it usually suffers from tedious, expensive, and timeconsuming sample pretreatments due to the isobaric interferences from ^(99)Ru and ^(98)Mo^(1)H. Herein, capillary electrophoresis(CE) was applied as sample introduction system for the sensitive, and interferencefree determination of ^(99)TcO_(4)^(-) from RuO_(4)^(-), and MoO_(4)^(2-) by ICP-MS with a simple sample treatment. Compared to the conventional methods, the hyphenated CE-ICP-MS avoids the use of expensive separation resins and reduces the consumption of mineral acid, representing a simpler, more efficient and environmentally benign approach. Moreover, the proposed method exhibits higher accuracy compared with the mathematical correction method using the natural isotope ratio of ^(99)Ru and ^(101)Ru, and significantly reduces sample consumption and the amount of waste, thus remarkably alleviating the radioactive exposure to operators and the pressure of radioactive waste treatment. Under the optimized conditions, the detection limits of 25 μg/L and 0.06 μg/L were obtained for RuO_(4)^(-) and ReO_(4)^(-)(Tc was replaced by Re), respectively, with relative standard deviation(RSD) lower than 5%. In addition, efficient recoveries of RuO_(4)^(-),ReO_(4)^(-),and ^(99)TcO_(4)^(-) from simulated Hanford site groundwater were achieved. The method is expected to be a promising candidate for sensitive and accurate analysis of ^(99)Tc from contaminated environmental samples. 展开更多
关键词 Radionuclide technetium-99 Capillary electrophoresis-inductively coupled plasma mass spectrometry(CE-ICP-MS) Rhenium(Re) Interference-free determination
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Simultaneous determination of peroxydisulfate and bisulfite concentrations with quenching-agent-assisted iodometry 被引量:1
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作者 Xinghong Wu Jun Deng +4 位作者 Jiawei Ye Pengyi Wang Xiangbin Huang Xin Yu Huabin Zeng 《Journal of Environmental Sciences》 2025年第8期153-162,共10页
Fenton/Fenton-like reactions have gained popularity for their remarkable proficiency in decomposing organic pollutants,especially when enhanced by reductants addition for accel-erating the Fe2+regeneration.Nevertheles... Fenton/Fenton-like reactions have gained popularity for their remarkable proficiency in decomposing organic pollutants,especially when enhanced by reductants addition for accel-erating the Fe2+regeneration.Nevertheless,these works predominantly centered on the formation and utilization of hydroxyl radicals(•OH)in the process,neglecting the evolution of oxidant and reductant due to the difficulty in the simultaneous determination of these two components.By employing the quenching-iodometric method,we could simultaneously determine the concentrations of HSO_(3)-and peroxydisulfate(PDS).This method first employed an excess of peroxymonosulfate(PMS)to effectively quench HSO_(3)-,and then used the iodometric spectrophotometry to simultaneously determine the concentrations of PMS and PDS in the reaction system.Finally,through precise stoichiometric relationships,we could accurately calculate the concentration of HSO_(3)-.Based on this method,we achieved concentration measurements that,upon linear fitting,yielded a correlation coefficient(R^(2))surpassing 0.99,unequivocally affirming the method’s accuracy and trustworthiness.In this work,an innovation approach for determining the concentrations of HSO_(3)-(reductant)and PDS(oxidant)was explored.Additionally,the resilience of the method was verified across different pH levels and in the presence of diverse impurity ions.The results ensured precise concentration measure-ments in the real wastewater.This method was characterized by its simplicity,rapid analysis,and environmental friendliness,offering a newanalytical strategy for the determination of PDS and HSO_(3)-in environmental samples.The method enables more meticulous monitoring of chemical usage in water treatment,facilitating optimized dosing strategies and assessments of reductant-enhanced Fenton or Fenton-like system in water purification. 展开更多
关键词 PDS BISULFITE PMS Simultaneous determination IODOMETRY
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Accurate determination of reaction rate constants for lithium-ion batteries by characteristic time-decomposed overpotential 被引量:1
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作者 Yifu Chen Haitao Zhu +7 位作者 Mengyuan Zhou Maoyuan Li Ruoyu Xiong Shuaiyi Yang Shiyu Zhang Yun Zhang Jingying Xie Huamin Zhou 《Journal of Energy Chemistry》 2025年第7期608-618,共11页
The reaction rate constant is a crucial kinetic parameter that governs the charge and discharge performance of batteries,particularly in high-rate and thick-electrode applications.However,conventional estimation or fi... The reaction rate constant is a crucial kinetic parameter that governs the charge and discharge performance of batteries,particularly in high-rate and thick-electrode applications.However,conventional estimation or fitting methods often overestimate the charge transfer overpotential,leading to substantial errors in reaction rate constant measurements.These inaccuracies hinder the accurate prediction of voltage profiles and overall cell performance.In this study,we propose the characteristic time-decomposed overpotential(CTDO)method,which employs a single-layer particle electrode(SLPE)structure to eliminate interference overpotentials.By leveraging the distribution of relaxation times(DRT),our method effectively isolates the characteristic time of the charge transfer process,enabling a more precise determination of the reaction rate constant.Simulation results indicate that our approach reduces measurement errors to below 2%,closely aligning with theoretical values.Furthermore,experimental validation demonstrates an 80% reduction in error compared to the conventional galvanostatic intermittent titration technique(GITT)method.Overall,this study provides a novel voltage-based approach for determining the reaction rate constant,enhancing the applicability of theoretical analysis in electrode structural design and facilitating rapid battery optimization. 展开更多
关键词 Kinetic parameter determination Decomposed overpotentials Charge transfer overpotential Characteristic time Single-layer particle
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H–He Demixing Driven by Anisotropic Hydrogen Diffusion 被引量:1
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作者 Xiaoju Chang Dongdong Kang +1 位作者 Bo Chen Jiayu Dai 《Chinese Physics Letters》 2025年第5期33-42,共10页
The dynamics of phase separation in H–He binary systems within gas giants such as Jupiter and Saturn exhibit remarkable complexity, yet lack systematic investigation. Through large-scale machine-learning-accelerated ... The dynamics of phase separation in H–He binary systems within gas giants such as Jupiter and Saturn exhibit remarkable complexity, yet lack systematic investigation. Through large-scale machine-learning-accelerated molecular dynamics simulations spanning broad temperature-pressure-composition(2000–10000 K, 1–7 Mbar,pure H to pure He) regimes, we systematically determine self and mutual diffusion coefficients in H–He systems and establish a six-dimensional framework correlating temperature, pressure, helium abundance, phase separation degree, diffusion coefficients, and anisotropy. Key findings reveal that hydrogen exhibits active directional migration with pronounced diffusion anisotropy, whereas helium passively aggregates in response. While the conventional mixing rule underestimates mutual diffusion coefficients by neglecting velocity cross-correlations,the assumption of an ideal thermodynamic factor(Q = 1) overestimates them due to unaccounted non-ideal thermodynamic effects—both particularly pronounced in strongly phase-separated regimes. Notably, hydrogen's dual role, anisotropic diffusion and bond stabilization via helium doping, modulates demixing kinetics. Large-scale simulations(216,000 atoms) propose novel phase-separation paradigms, such as “hydrogen bubble/wisp” formation, challenging the classical “helium rain” scenario, striving to bridge atomic-scale dynamics to planetary-scale phase evolution. 展开更多
关键词 molecular dynamics simulations gas giants helium diffusion h he systems hydrogen diffusion determine self mutual diffusion coefficients h he binary systems dynamics phase separation
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LoRa Sense:Sensing and Optimization of LoRa Link Behavior Using Path-Loss Models in Open-Cast Mines
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作者 Bhanu Pratap Reddy Bhavanam Prashanth Ragam 《Computer Modeling in Engineering & Sciences》 SCIE EI 2025年第1期425-466,共42页
The Internet of Things(IoT)has orchestrated various domains in numerous applications,contributing significantly to the growth of the smart world,even in regions with low literacy rates,boosting socio-economic developm... The Internet of Things(IoT)has orchestrated various domains in numerous applications,contributing significantly to the growth of the smart world,even in regions with low literacy rates,boosting socio-economic development.This study provides valuable insights into optimizing wireless communication,paving the way for a more connected and productive future in the mining industry.The IoT revolution is advancing across industries,but harsh geometric environments,including open-pit mines,pose unique challenges for reliable communication.The advent of IoT in the mining industry has significantly improved communication for critical operations through the use of Radio Frequency(RF)protocols such as Bluetooth,Wi-Fi,GSM/GPRS,Narrow Band(NB)-IoT,SigFox,ZigBee,and Long Range Wireless Area Network(LoRaWAN).This study addresses the optimization of network implementations by comparing two leading free-spreading IoT-based RF protocols such as ZigBee and LoRaWAN.Intensive field tests are conducted in various opencast mines to investigate coverage potential and signal attenuation.ZigBee is tested in the Tadicherla open-cast coal mine in India.Similarly,LoRaWAN field tests are conducted at one of the associated cement companies(ACC)in the limestone mine in Bargarh,India,covering both Indoor-toOutdoor(I2O)and Outdoor-to-Outdoor(O2O)environments.A robust framework of path-loss models,referred to as Free space,Egli,Okumura-Hata,Cost231-Hata and Ericsson models,combined with key performance metrics,is employed to evaluate the patterns of signal attenuation.Extensive field testing and careful data analysis revealed that the Egli model is the most consistent path-loss model for the ZigBee protocol in an I2O environment,with a coefficient of determination(R^(2))of 0.907,balanced error metrics such as Normalized Root Mean Square Error(NRMSE)of 0.030,Mean Square Error(MSE)of 4.950,Mean Absolute Percentage Error(MAPE)of 0.249 and Scatter Index(SI)of 2.723.In the O2O scenario,the Ericsson model showed superior performance,with the highest R^(2)value of 0.959,supported by strong correlation metrics:NRMSE of 0.026,MSE of 8.685,MAPE of 0.685,Mean Absolute Deviation(MAD)of 20.839 and SI of 2.194.For the LoRaWAN protocol,the Cost-231 model achieved the highest R^(2)value of 0.921 in the I2O scenario,complemented by the lowest metrics:NRMSE of 0.018,MSE of 1.324,MAPE of 0.217,MAD of 9.218 and SI of 1.238.In the O2O environment,the Okumura-Hata model achieved the highest R^(2)value of 0.978,indicating a strong fit with metrics NRMSE of 0.047,MSE of 27.807,MAPE of 27.494,MAD of 37.287 and SI of 3.927.This advancement in reliable communication networks promises to transform the opencast landscape into networked signal attenuation.These results support decision-making for mining needs and ensure reliable communications even in the face of formidable obstacles. 展开更多
关键词 Internet of things long range wireless area network ZigBee mining environments path-loss models coefficient of determination mean square error
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A scoping review of maternal mortality,its health determinants,and factors that influence care utilization in women of child-bearing years in Nigeria
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作者 Sarah Ifunaya Anumudu Chijioke Christopher Uhegwu Christian Kosisochukwu Anumudu 《Global Health Journal》 2025年第3期185-199,共15页
Objectives:This scoping review aims to methodically identify and analyse the determinants which influence maternal mortality and healthcare utilization in women of childbearing years in Nigeria.The review specifically... Objectives:This scoping review aims to methodically identify and analyse the determinants which influence maternal mortality and healthcare utilization in women of childbearing years in Nigeria.The review specifically addresses the difficulties faced in assessing medical care,and the ongoing initiatives to lower the maternal mortality ratio.Methods:Primary studies(published after year 2000)focused on maternal mortality,health determinants,and the utilization of maternal healthcare services in Nigeria were retrieved following a systematic search across multiple databases,including Scopus,PubMed,Google Scholar,and Web of Science.These were screened using defined inclusion and exclusion criteria.Data from these studies were extracted and thematically analysed to identify common themes and trends.Results:A total of 21 publications were included in this review comprising 2 qualitative,17 quantitative,and2 mixed study designs.Major health determinants identified in these studies include hypertensive disorders of pregnancy,haemorrhage,and sepsis/septicaemia,contributing as much as 29%,24%,and 14.2%of maternal deaths respectively in over 10%of the reviewed studies.Similarly,social-economic determinants including poverty,maternal education,health system issues and culture significantly impacted the utilization of maternal healthcare services,inadvertently impacting maternal mortality.Despite various maternal health interventions such as the"Abiye"Safe Motherhood Initiative,the Integrated Maternal,Newborn,and Child Health Strategy and strengthening emergency obstetric care by governmental and non-governmental agencies,early childbearing,unemployment,large family sizes,and dependence on male spouses continued to result in suboptimal utilization of services and adverse maternal outcomes.Conclusion:This scoping review comprehensively integrated existing data from published studies to provide a detailed picture of maternal mortality,its health determinants,and factors influencing care utilization among women of childbearing age in Nigeria and approaches to reduce maternal mortality in the country and possibly in the West African sub-region. 展开更多
关键词 Maternal mortality Health determinants Hypertensive disorders of pregnancy HAEMORRHAGE Social determinants Maternal healthcare utilization Socioeconomic factors NIGERIA
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Combining transformer and 3DCNN models to achieve co-design of structures and sequences of antibodies in a diffusional manner
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作者 Yue Hu Feng Tao +3 位作者 Jiajie Xu Wen-Jun Lan Jing Zhang Wei Lan 《Journal of Pharmaceutical Analysis》 2025年第6期1406-1408,共3页
AlphaPanda(AlphaFold2[1]inspired protein-specific antibody design in a diffusional manner)is an advanced algorithm for designing complementary determining regions(CDRs)of the antibody targeted the specific epitope,com... AlphaPanda(AlphaFold2[1]inspired protein-specific antibody design in a diffusional manner)is an advanced algorithm for designing complementary determining regions(CDRs)of the antibody targeted the specific epitope,combining transformer[2]models,3DCNN[3],and diffusion[4]generative models. 展开更多
关键词 advanced algorithm diffusion generative models dcnn epitope targeting antibody design complementary determining regions complementary determining regions cdrs transformer models
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Quantitative Study of Multiple Components in Tetracera asiatica Based on High-Performance Liquid Chromatography
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作者 Fangfang DA Yufeng CHEN +4 位作者 Ziwan YUAN Ying LIU Yaoting MENG Kequn HE Yanmin XIE 《Asian Agricultural Research》 2025年第10期28-31,44,共5页
[Objectives]To establish an HPLC method for the quantitative determination of multiple phenolic acid components in Tetracera asiatica medicinal material,providing a basis for establishing its quality standards.[Method... [Objectives]To establish an HPLC method for the quantitative determination of multiple phenolic acid components in Tetracera asiatica medicinal material,providing a basis for establishing its quality standards.[Methods]An Inertsil ODS-C 18 column(250 mm×4.6 mm,5μm)was used.The mobile phase consisted of acetonitrile-0.2% phosphoric acid solution(10:90).The flow rate was 1.0 mL/min.The detection wavelength was 274 nm.The column temperature was 25℃.The injection volume was 10μL.The content of three components,gallic acid,protocatechuic acid,and protocatechualdehyde,was determined in 13 batches of T.asiatica.[Results]Gallic acid showed good linearity within the range of 0.020-6.400μg/mL,protocatechuic acid within 0.201-6.432μg/mL,and protocatechualdehyde within 0.202-6.464μg/mL(r>0.9990).The average recovery rates ranged from 98.61%to 101.17%,with RSD s between 1.21%and 2.69%.[Conclusions]The quantitative determination method established in this study is simple and feasible,and can provide a basis for the quality evaluation of T.asiatica. 展开更多
关键词 Tetracera asiatica HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY (HPLC) COMPONENTS QUANTITATIVE determination
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