Selective flocculation is an idea separation method to separate ultrafine pyrite from coal. A number of selective flocculation separation tests under different conditions have been done and the results are very encour...Selective flocculation is an idea separation method to separate ultrafine pyrite from coal. A number of selective flocculation separation tests under different conditions have been done and the results are very encouraging. The results also show that desulfurization and deashing can be finished simultaneously in selective fIocculation process. It is an advanced coal desulfurization process.展开更多
Desulfurization of coke oven gas(COG)is a critical step for achieving green and sustainable development in the coking industry.Ammonium binuclear cobalt phthalocyanine sulfonate(PDS),serving as the core catalyst in th...Desulfurization of coke oven gas(COG)is a critical step for achieving green and sustainable development in the coking industry.Ammonium binuclear cobalt phthalocyanine sulfonate(PDS),serving as the core catalyst in the Hydroquinone-PDSFerrous sulfate(HPF)desulfurization process,requires precise concentration monitoring for process optimization.To address the limitations of traditional detection methods,including insufficient sensitivity,cumbersome manual operations,and weak anti-interference capability,this study developed a fully automated analytical system and method based on spectrophotometry,thereby filling a technological gap in automated PDS detection.Systematic performance validation demonstrated that the autoanalyzer exhibits excellent sensitivity and a wide linear range,with results consistent with industrial standard methods.Leveraging a programmable logic controller(PLC),the system achieves end-to-end automation from sample pretreatment to data feedback,overcoming limitations inherent in manual operations such as delayed sample processing and human-induced errors,which significantly enhances the sensitivity and timeliness of PDS concentration monitoring in complex industrial matrices.The proposed method offers triple benefits of environmental friendliness,cost-effectiveness,and social value,providing key technical support for the coking industry.展开更多
文摘Selective flocculation is an idea separation method to separate ultrafine pyrite from coal. A number of selective flocculation separation tests under different conditions have been done and the results are very encouraging. The results also show that desulfurization and deashing can be finished simultaneously in selective fIocculation process. It is an advanced coal desulfurization process.
基金supported by the cross-sectional research project sponsored by Jilin Baoli Science and Technology Co.(2024-2200-0800-0378)
文摘Desulfurization of coke oven gas(COG)is a critical step for achieving green and sustainable development in the coking industry.Ammonium binuclear cobalt phthalocyanine sulfonate(PDS),serving as the core catalyst in the Hydroquinone-PDSFerrous sulfate(HPF)desulfurization process,requires precise concentration monitoring for process optimization.To address the limitations of traditional detection methods,including insufficient sensitivity,cumbersome manual operations,and weak anti-interference capability,this study developed a fully automated analytical system and method based on spectrophotometry,thereby filling a technological gap in automated PDS detection.Systematic performance validation demonstrated that the autoanalyzer exhibits excellent sensitivity and a wide linear range,with results consistent with industrial standard methods.Leveraging a programmable logic controller(PLC),the system achieves end-to-end automation from sample pretreatment to data feedback,overcoming limitations inherent in manual operations such as delayed sample processing and human-induced errors,which significantly enhances the sensitivity and timeliness of PDS concentration monitoring in complex industrial matrices.The proposed method offers triple benefits of environmental friendliness,cost-effectiveness,and social value,providing key technical support for the coking industry.
