With greater market demand,interest in the selective production of linearα-olefins has been increasing.This review discusses the principles underlying the evolution of the ligand design,co-catalysts,reaction mechanis...With greater market demand,interest in the selective production of linearα-olefins has been increasing.This review discusses the principles underlying the evolution of the ligand design,co-catalysts,reaction mechanisms,and polyethylene formation in ethylene tetramerization systems over the past few decades,with particular emphasis on the recent use of asymmetric active catalytic centers leading to more competitive performance in selective oligomerization.展开更多
基金National Natural Science Foundation of China(NSFC,22071178)the China Petroleum Science and Technology Program(2020B-2512)for financial support.
文摘With greater market demand,interest in the selective production of linearα-olefins has been increasing.This review discusses the principles underlying the evolution of the ligand design,co-catalysts,reaction mechanisms,and polyethylene formation in ethylene tetramerization systems over the past few decades,with particular emphasis on the recent use of asymmetric active catalytic centers leading to more competitive performance in selective oligomerization.
