After discussing the reflective method of structure and behavior in the State design pattern based on Role Object pattern and the Reflective pattern of software architecture, this paper proposes a reflective state pat...After discussing the reflective method of structure and behavior in the State design pattern based on Role Object pattern and the Reflective pattern of software architecture, this paper proposes a reflective state pattern with dynamic constructiveness. This paper explains the meta level and the base level, which are two levels of this pattern, and specifies the relation of two levels by using Meta Object Protocol (MOP). Then it discusses mechanism of interception and reification for reflecting base object from Meta object. Finally this paper gives an example of network server for applying the Reflective State pattern.展开更多
Understanding the structure-property relationships in polycyclic conjugated hydrocarbons(PCHs)is crucial in controlling their electronic properties and developing new optically functional materials.Aromaticity is a fu...Understanding the structure-property relationships in polycyclic conjugated hydrocarbons(PCHs)is crucial in controlling their electronic properties and developing new optically functional materials.Aromaticity is a fundamentally important and intriguing property of numerous organic chemical structures and has stimulated a myriad of experimental and theoretical investigations.Exploiting aromaticity rules for the rational design of optoelectronic materials with the desired photophysical characteristics is a challenging yet fascinating task.Herein we present an in-depth computational and spectroscopic study on the structure-property relationships of dinaphthopentalenes(DNPs).Results highlight that the different fusion patterns between 4nπand 4n+2πunits endow these PCHs with the tunable aromaticity in the ground state/excited state,which leads to the diverse electronic structures and consequently the distinctive excited state photophysics.Accordingly,we propose a combined aromaticity design strategy for rationally modulating and tailoring electronic and optical properties of PCH skeletons.These outcomes not only present a full picture of the excited state dynamics of the DNP system and afford a new class of efficient singlet fission-active materials but also provide some basic guidelines for exploiting aromaticity rules to design and develop new optical function materials.展开更多
基金The research wsa supported in part by the Middleware Software Division of Software Group of Fujitsu L imited inJapantechnolo
文摘After discussing the reflective method of structure and behavior in the State design pattern based on Role Object pattern and the Reflective pattern of software architecture, this paper proposes a reflective state pattern with dynamic constructiveness. This paper explains the meta level and the base level, which are two levels of this pattern, and specifies the relation of two levels by using Meta Object Protocol (MOP). Then it discusses mechanism of interception and reification for reflecting base object from Meta object. Finally this paper gives an example of network server for applying the Reflective State pattern.
基金supported by the National Natural Science Foundation of China(grant nos.22005210,21833005,and 22231009).
文摘Understanding the structure-property relationships in polycyclic conjugated hydrocarbons(PCHs)is crucial in controlling their electronic properties and developing new optically functional materials.Aromaticity is a fundamentally important and intriguing property of numerous organic chemical structures and has stimulated a myriad of experimental and theoretical investigations.Exploiting aromaticity rules for the rational design of optoelectronic materials with the desired photophysical characteristics is a challenging yet fascinating task.Herein we present an in-depth computational and spectroscopic study on the structure-property relationships of dinaphthopentalenes(DNPs).Results highlight that the different fusion patterns between 4nπand 4n+2πunits endow these PCHs with the tunable aromaticity in the ground state/excited state,which leads to the diverse electronic structures and consequently the distinctive excited state photophysics.Accordingly,we propose a combined aromaticity design strategy for rationally modulating and tailoring electronic and optical properties of PCH skeletons.These outcomes not only present a full picture of the excited state dynamics of the DNP system and afford a new class of efficient singlet fission-active materials but also provide some basic guidelines for exploiting aromaticity rules to design and develop new optical function materials.
