Aeolian deposits across the Yarlung Zangbo River Basin on the southern Tibetan Plateau record the landscape and atmospheric evolution of Earth's Third Pole.The complex mountain-basin system exhibits nonlinear resp...Aeolian deposits across the Yarlung Zangbo River Basin on the southern Tibetan Plateau record the landscape and atmospheric evolution of Earth's Third Pole.The complex mountain-basin system exhibits nonlinear responses to climate forcing,complicating the interpretation of its high-altitude environmental dynamics.Investigating the magnetic enhancement mechanism of aeolian deposits offers an opportunity to decipher climate signals.Our analysis of three aeolian sections from the basin indicates that magnetic minerals are predominantly low-coercivity ferrimagnetic minerals,and grain sizes fine from upper to lower reaches due to climate shifts from arid to humid.Magnetic enhancement in the upper reaches primarily originates from dust input,while dust input and pedogenesis contribute variably over time in the middle and lower reaches.Similar complex patterns occur in the Ili basin,a mountain-basin system in northwestern China.They differ from the Chinese Loess Plateau,where long-distance-transported dust is well-mixed and the pedogenic enhancement model is applied,and desert peripheries where short-distance dust is transported and the dust input model is applied.We summarize the magnetic enhancement mechanisms in various settings and offer a new framework for applying magnetic techniques in paleoclimate reconstruction within global mountain-basin systems,which highlights the need for caution in interpreting their magnetic susceptibility records.展开更多
BACKGROUND The number of tumor deposits(TDs)does not play a part in the current tumor node metastasis staging.Negative lymph node(NLN)status is associated with the prognosis of colorectal cancer(CRC),but its clear rol...BACKGROUND The number of tumor deposits(TDs)does not play a part in the current tumor node metastasis staging.Negative lymph node(NLN)status is associated with the prognosis of colorectal cancer(CRC),but its clear role in N1c stage remains to be defined.AIM To evaluate the combination of TDs and NLNs as potential prognostic indicators in N1c CRC.METHODS We retrospectively identified 107 consecutive patients who had N1c CRC radically resected at China-Japan Friendship Hospital.The combination of TDs and NLNs was calculated by the formula NLNTD=NLN/(TD+1).Cutoff values of NLNs and NLNTD were determined using the R package“survminer”.Disease-free survival(DFS),overall survival(OS)and cancer-specific survival(CSS)were determined using the Kaplan-Meier method to assess the impact of NLNTD on prognosis.Results were compared using the log-rank test.RESULTS The median follow-up time was 63.17(45.33-81.37)months for DFS,with 33.64%(36/107)of patients experiencing recurrence during follow-up.Five-year DFS was 66.0%(57.3%-76.0%).There was no significant difference in prognosis between patients with>12 and≤12 NLNs(P=0.058)for DFS.Similar results were seen according to the number of TDs.The definition of NLNTD=NLN/(TD+1)with a cutoff value of 6 divided patients into two groups with different DFS(P=0.005).Five-year DFS for patients with NLNTD>6 was 73.5%(63.6%-85.0%),compared with 50.0%(35.7%-70.0%)for those with NLNTD≤6.These two groups had different prognosis without perineural invasion(P=0.012)or lymphovascular invasion(P=0.002)even neither(P=0.053).Similar results were seen for OS and CSS.CONCLUSION NLNTD could serve as important prognostic factor for outcomes in N1c CRC patients.These patients could be stratified for prognosis through NLNTD and the high-risk should be given more attention during treatment.展开更多
Quartz vein-type tungsten deposits are a common W deposit type.Their ore vein distribution was previously considered to be controlled by regional horizontal tectonic stress.In this paper,14 tungsten deposits with fan-...Quartz vein-type tungsten deposits are a common W deposit type.Their ore vein distribution was previously considered to be controlled by regional horizontal tectonic stress.In this paper,14 tungsten deposits with fan-shaped mineralization in SE China are summarized,and the relations between their ore veins and granite and the ore-forming structural stress field are analyzed.These deposits have a post-magmatic hydrothermal genesis and involve the formation of two sets of veins with similar strike and opposite dips at the top of the ore-causative granite bodies,forming a vertical fan-shaped profile.Their ore veins were coeval with the underlying granite bodies,and generally extend along the long axis of the granite.In such fan-shaped ore formation,the stress is highly focused at the top of the granite and gradually weakens outward.The maximum principal stress(σ1)is perpendicular to the granite contact surface,and radiates outward from the pluton.Meanwhile,the minimum principal stress(σ3)forms an arc-shaped band parallel to the contact surface.Our findings,together with published numerical modeling indicate that the emplacement dynamics of granitic magma(rather than regional horizontal tectonic stress)are essential controls on the distribution of ore veins in quartz vein-type tungsten deposits.展开更多
The green energy transition relies heavily on critical metals,such as rare earth elements(REEs).However,their reserves are primarily focused in a few countries,such as China,which accounts for approximately 70%of glob...The green energy transition relies heavily on critical metals,such as rare earth elements(REEs).However,their reserves are primarily focused in a few countries,such as China,which accounts for approximately 70%of global production.Hence,several countries are currently looking for alternative resources for REEs.Alternative REE resources in the supply chain include recycling of e-waste,industrial waste like red mud and phosphogypsum,coal ash,mine tailings,ocean floor sediments,and even certain types of sedimentary deposits like phosphorites where REEs are present in lower concentrations but at larger volumes compared to primary ore deposits which are becoming targets by REEs industry.Currently,several studies are going on the development of eco-friendly REEs extraction technologies from phosphorite deposits.Consequently,advanced data analysis tools,such as Machine Learning(ML),are becoming increasingly important in mineral prospectivity and are rapidly gaining traction in the earth sciences.Phosphorite deposits are mainly used to manufacture fertilizers as these rocks are known for their significant phosphorus content.Moreover,these formations are considered a prospective resource of REEs.The different types of phosphorite deposits such as continental,seamount,and ore deposits worldwide reported concentrations of∑REE upto 18,000µg/g.Due to the augmented claim of REEs for various ultra-modern,and green technology applications that are required to switch over to a carbon-neutral environment,these phosphorite deposits have become an important target mostly because of their relatively higher content of REEs especially heavy rare earth elements(HREE).For example,Mississippian phosphorites reported ∑ HREE 7,000µg/g.To have a comprehensive understanding of the REEs potential of these phosphorite deposits which also include several Chinese phosphorite deposits,this study is undertaken to review the phosphorite deposits in the world and their REEs potential,in addition to some of the associated aspects such as applications and formation mechanisms for different types of phosphorite deposits such as igneous phosphate deposits,sedimentary phosphorite deposits,marine phosphorite deposits,cave phosphate deposits,and insular guano deposits.Other important aspects include their occurrences,types,geochemical characteristics,the REEs enrichment mechanisms,and various recovery methods adopted to recover REEs from different phosphorite deposits.The present review paper concludes that the recent studies highlight the global potential of phosphorite deposits to satisfy the increasing demand for REEs.Extracting REEs from phosphorite presents no significant technological or environmental difficulties,as long as radioactive elements are eliminated.In India,more comprehensive geological surveys,along with the advancement of new methods and evaluations,are required to locate phosphorite deposits with high concentrations of REEs.展开更多
We read with great interest the article by Sun et al addressing the prognostic role of tumor deposits(TDs)and negative lymph nodes in N1c colorectal cancer.Their proposal of the NLNTD index is a valuable step toward r...We read with great interest the article by Sun et al addressing the prognostic role of tumor deposits(TDs)and negative lymph nodes in N1c colorectal cancer.Their proposal of the NLNTD index is a valuable step toward refining risk stratification in this subgroup.In our recently published population-based cohort of 111106 patients with early-stage colon cancer,TD positivity,classified as N1c according to AJCC definitions,was independently associated with significantly worse overall and disease-specific survival,even after propensity score matching.Taken together,these findings show that TDs are adverse prognostic factors across stages.They should inform treatment planning and follow-up,rather than be regarded as incidental.展开更多
One reference in the original manuscript contained incorrect bibliographic information and cited a non-existent publication:Traczyk A(1999)Pleistocene debris cover beds and block-debris tongues in the north-western pa...One reference in the original manuscript contained incorrect bibliographic information and cited a non-existent publication:Traczyk A(1999)Pleistocene debris cover beds and block-debris tongues in the north-western part of theŚlęża Massif(Poland)and their formation under permafrost conditions.Geographia Polonica 81(1).This erroneous reference has now been removed from the references list.展开更多
BACKGROUND Tumor deposits(TDs)are an independent predictor of poor prognosis in colorec-tal cancer(CRC)patients.Enhanced follow-up and treatment monitoring for TD+patients may improve survival rates and quality of lif...BACKGROUND Tumor deposits(TDs)are an independent predictor of poor prognosis in colorec-tal cancer(CRC)patients.Enhanced follow-up and treatment monitoring for TD+patients may improve survival rates and quality of life.However,the detection of TDs relies primarily on postoperative pathological examination,which may have a low detection rate due to sampling limitations.AIM To evaluate the spectral computed tomography(CT)parameters of primary tu-mors and the largest regional lymph nodes(LNs),to determine their value in predicting TDs in CRC.METHODS A retrospective analysis was conducted which included 121 patients with CRC whose complete spectral CT data were available.Patients were divided into the TDs+group and the TDs-group on the basis of their pathological results.Spectral CT parameters of the primary CRC lesion and the largest regional LNs were measured,including the normalized iodine concentration(NIC)in both the arte-rial and venous phases,and the LN-to-primary tumor ratio was calculated.Stati-stical methods were used to evaluate the diagnostic efficacy of each spectral para-meter.RESULTS Among the 121 CRC patients,33(27.2%)were confirmed to be TDs+.The risk of TDs positivity was greater in patients with positive LN metastasis,higher N stage and elevated carcinoembryonic antigen and cancer antigen 19-9 levels.The NIC(LNs in both the arterial and venous phases),NIC(primary tumors in the venous phase),and the LN-to-primary tumor ratio in both the arterial and venous phases were associated with TDs(P<0.05).In mul-tivariate logistic regression analysis,the arterial phase LN-to-primary tumor ratio was identified as an independent predictor of TDs,demonstrating the highest diagnostic performance(area under the curve:0.812,sensitivity:0.879,specificity:0.648,cutoff value:1.145).CONCLUSION The spectral CT parameters of the primary colorectal tumor and the largest regional LNs,especially the LN-to-primary tumor ratio,have significant clinical value in predicting TDs in CRC.展开更多
Previous studies have indicated that sediment gravity flow deposits developed in lacustrine active extensional rift basins are primarily influenced by tectonics and to a lesser extent by climate.Our present work revea...Previous studies have indicated that sediment gravity flow deposits developed in lacustrine active extensional rift basins are primarily influenced by tectonics and to a lesser extent by climate.Our present work reveals that climate can obscure the effect of tectonic subsidence by regulating sediment supply;conversely,tectonics can impede the sedimentary manifestation of climatic impacts.Here a case study has been presented to assess the impact of climate-modulated rapid lake-level rise and tectonic subsidence on the development of coarse-grained gravity flow deposits in the Dongying rift margin of the Bohai Bay Basin,eastern China.The lithofacies analysis reveals frequent bed amalgamation,abundant thick massive coarse-grained deposits,widespread cross bedding and plant fragments,and incomplete composite bed formed by high-energy erosion,indicating that the hyperpycnal flow is an important mechanism driving the deposition of these coarse-grained sediments.Detailed sequence stratigraphic analysis and sediment dispersal pattern suggest that the long-striped nearshore subaqueous fan systems induced by outburst-flood hyperpycnal flow distributed along the border fault,are primarily controlled by long-term tectonics,while the rapid rise of lake level driven by short-term climate change possibly intensifies seasonal flood-generated hyperpycnal flow occurrences and consequently promotes the basinal fan progradation.The maximum scale of these coarse-grained gravity flow deposits of the basinal fan systems are typically attained during the transgressive systems tract,which deviates from the classical sequence stratigraphic model.Furthermore,it presented a continuous transition from the proximal to the distal part,encompassing traction flows and turbidity currents during the periods of relatively stable tectonics.Nevertheless,gravel-rich debris flows appear to predominate the dispersion of coarse-grained sediments during periods characterized by intense tectonic activity.The coarse-grained gravity flow deposits in the lacustrine rift margin reported here,challenge the traditional beliefs:this study suggests that subaqueous deposits abundantly preserved in the transgressive setting.展开更多
The polar layered deposits(PLD) of Mars can provide deep insight into paleoclimate changes over the planet's last several million years. Since the 1960s, researchers have studied almost all aspects of Martian PLD ...The polar layered deposits(PLD) of Mars can provide deep insight into paleoclimate changes over the planet's last several million years. Since the 1960s, researchers have studied almost all aspects of Martian PLD properties, searching for patterns that might reveal periodic characteristics of the planet's climate history. Although much progress has been made in our understanding of orbital periodicities reflected in the PLD, questions remain regarding how Martian orbital changes have affected the formation of the PLD and regarding the extent of climate information that is recorded in the PLD. Future studies of PLD should be carried out via integrated research that targets multi-profiles throughout the entire Martian polar regions that would clarify their general features at the hemisphere scale. Numerical modeling, coupled with modern observations of dust and water vapor transportation, should greatly advance our understanding of planetary climate evolution. Furthermore, future landing missions may help to clarify the paleoclimatic characteristics reflected in the PLD by drilling into these layered deposits and measuring mineralogical and geochemical compositions of the drilled samples.展开更多
This study highlights a new by-product source for cobalt by recycling Paleoproterozoic Mn deposits.We present a geochemical modeling approach utilizing Principal Component Analysis(PCA)for available geochemical data o...This study highlights a new by-product source for cobalt by recycling Paleoproterozoic Mn deposits.We present a geochemical modeling approach utilizing Principal Component Analysis(PCA)for available geochemical data of Paleoproterozoic manganese deposits found in Africa and Brazil,which exhibit anomalous cobalt contents(up to 1200 ppm)along with other metals such as copper,nickel,and vanadium.The PCA results for the correlation coefficient matrix of the Enrichment Factor(_(EF))values of major and trace elements from samples of eight Mn deposits found in Africa and Brazil(Kisenge-Kamata,Moanda,Nsuta in Africa,and Azul,Buritirama,Lagoa do Riacho,Morro da Mina,and Serra do Navio in Brazil)yielded a cumulative variance of 53.3%for PC1(34%)and PC2(19.3%).In PC1,the highest positive loadings correspond to the variables Mn_(EF),Ni_(EF),and Co_(EF),while the highest negative loadings correspond to the variables Si_(EF),Fe_(EF),K_(EF),Ti_(EF),Cr_(EF),and Zr_(EF).PC2 exhibits the highest positive loadings for the variables Ca_(_(EF)),Mg_(EF),and P_(EF),while the highest negative loadings are for Cu_(EF)and V_(EF).The biplot diagram representation showed that clusters of vectors Mn_(EF),Ni_(EF),Co_(EF),V_(EF),and Cu_(EF)influence samples of Mn-carbonate rock,Mn-carbonate-silicate rock,Mn-silicate rock,and Mn-carbonate-siliciclastic rock,all with high Co_(EF)values(up to 414).The cluster of vectors Ca_(_(EF)),Mg_(EF),and P_(EF)significantly influence carbonate rock and dolomite marble,which have low Co_(EF)values(close to 0).The cluster of vectors Si_(EF),Fe_(EF),K_(EF),Ti_(EF),Cr_(EF),and Zr_(EF)strongly influences siliciclastic rock,which exhibits low Co_(EF)values.On the other hand,the cluster of vectors Cu_(EF)and V_(EF)influences oxidized Mn ore,which exhibits Co_(EF)values of up to 108.The results reveal a dichotomy regarding the origin of cobalt and other metal enrichments in these deposits linked to the Mn redox cycle.This process involves the formation of Mn-oxyhydroxides with the adsorption of Co and other metals under oxic conditions,followed by the burial of these Mn oxides in an anoxic diagenetic environment,where microbial sulfate reduction leads to the nucleation of Mn-carbonates and the formation of metal-rich sulfides(Fe,Co,Ni,V).Additionally,detrital input and sulfide phases(e.g.,framboidal pyrite)for the formation of Mn-rich siliciclastic rocks associated with Mn-carbonate rocks are evidenced by proxies Si_(EF),Fe_(EF),K_(EF),Ti_(EF),Cr_(EF),and Zr_(EF).This new exploration approach,supported by geochemical modeling through PCA,enhances our understanding of the genesis of these Paleoproterozoic manganese deposits and highlights a new route for cobalt exploration.In the increasing global demand for cobalt,particularly in applications involving electric vehicle batteries and energy storage,exploring these deposits emerges as an alternative source to produce these critical metals.展开更多
Changing political and market conditions have disrupted energy security.European economies are planning to utilize their own resources of energy raw materials,including consideration of the advisability of returning a...Changing political and market conditions have disrupted energy security.European economies are planning to utilize their own resources of energy raw materials,including consideration of the advisability of returning abandoned coal resources to use.The research using the proposed methodology examined the impact of the ongoing mine closure processes on the potential ability to develop the remaining deposit.It was found that the greatest influence on the availability of unclosed shafts was the active concession to extract minerals from the deposit and the availability of unclosed main plant facilities.The assessment of the possibilities of coal resources management in the deposits of liquidated mines has not been the subject of extensive scientific research so far.The information obtained can be used as a reference point for detailed analysis and multi-criteria evaluation,after which the decision maker makes the decision.The method is designed for liquidated mines,but with certain modifications it can also be used by mining companies.展开更多
It is quite evident that it is not anomalous metal transport,nor unique depositional conditions,nor any single factor at the deposit scale,that dictates whether a mineral deposit becomes a giant or not.A hierarchical ...It is quite evident that it is not anomalous metal transport,nor unique depositional conditions,nor any single factor at the deposit scale,that dictates whether a mineral deposit becomes a giant or not.A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments.For giant orogenic,intrusion-related gold systems（IRGS） and Carlin-type gold deposits and iron oxide-copper-gold（IOCG） deposits,there are common factors among all of these at the lithospheric to crustal scale.All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or,in the case of most Phanerozoic orogenic giants,define the primary suture zones between tectonic terranes.Giant provinces of IRGS,IOCG,and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamprophyric to granitic magmas and associated heat flux to generate the giant province.The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids,whereas the association of such melts with Carlin-type ores is more indirect and enigmatic.Giant orogenic gold provinces show no direct relationship to such magmatism.forming from metamorphic fluids,but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures.In contrast to their province scale similarities,the different giant gold deposit styles show contrasting critical controls at the district to deposit scale.For orogenic gold deposits,the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits,with resultant geometrical and lithostratigraphic complexity as a guide to their location.There are few giant IRGS due to their inferior fluid-flux systems relative to orogenic gold deposits,and those few giants are essentially preservational exceptions.Many Carlin-type deposits are giants due to the exceptional conjunction of both structural and lithological parameters that caused reactive and permeable rocks,enriched in syngenetic gold,to be located below an impermeable cap along antiformal ＂trends＂.Hydrocarbons probably played an important role in concentrating metal.The supergiant Post-Betze deposit has additional ore zones in strain heterogeneities surrounding the pre-gold Goldstrike stock.All unequivocal IOCG deposits are giant or near-giant deposits in terms of gold-equivalent resources,partly due to economic factors for this relatively poorly understood,low Cu-Au grade deposit type.The supergiant Olympic Dam deposit,the most shallowly formed deposit among the larger IOCGs,probably owes its origin to eruption of volatile-rich hybrid magma at surface,with formation of a large maar and intense and widespread brecciation,alteration and Cu-Au-U deposition in a huge rock volume.展开更多
A preliminary survey of silver isotopic composition in four polymetallic ores in eastern China shows a larger variation inδ^(109)Ag from-0.014‰to+0.983‰,which is within the total ranges for the entire respective or...A preliminary survey of silver isotopic composition in four polymetallic ores in eastern China shows a larger variation inδ^(109)Ag from-0.014‰to+0.983‰,which is within the total ranges for the entire respective ore deposit types worldwide.The diversity of silver isotopic compositions in oredeposits reported here and previous studies seemed to preclude simple isotopic links to particular sources,but reflected the silver isotope fractionation in transport-and deposit-related processes instead.Theδ^(109)Ag values in supergene samples from the Qixiashan Pb-Zn-Ag polymetallic deposit are more positive,in consistent with the statistical δ^(109)Ag distribution from-0.4‰to+2.2‰in 36 pieces of supergene ore samples around the World,which reflects the diverse controls on silver isotope fractionation from the first-order thermodynamic effect,reduction-mediated reaction,remobilization of silver with surficial low-temperature weathering processes.The hypogene samples in Dazhuangzi orogenic Au-Ag ore deposit,have δ^(109)Ag values close to 0,which implies that equilibrium partitioning associated with metal sources at the high-temperature does not result in a resolvable difference in silver isotopic compositions.By contrast,the hypogene samples which are dominated by pyrite without visible silver minerals (i.e.,skarn iron ore deposit in Edongnan) have shown the largest variation range of δ^(109)Ag,followed by that from the porphyry copper ore in Zijinshan.It could be concluded that the surface adsorption and/or lattice substitution are important factors to control Ag isotope fractionation in oreforming processes,especially for skarn deposits with only pyrite.The perspective of silver isotope shows great potentials to understand the processes that lead to the concentrations of metals to economic levels and to constrain the physicochemical conditions during ore-mineralization in metallic ore-deposits.展开更多
The application of machine learning for pyrite discrimination establishes a robust foundation for constructing the ore-forming history of multi-stage deposits;however,published models face challenges related to limite...The application of machine learning for pyrite discrimination establishes a robust foundation for constructing the ore-forming history of multi-stage deposits;however,published models face challenges related to limited,imbalanced datasets and oversampling.In this study,the dataset was expanded to approximately 500 samples for each type,including 508 sedimentary,573 orogenic gold,548 sedimentary exhalative(SEDEX)deposits,and 364 volcanogenic massive sulfides(VMS)pyrites,utilizing random forest(RF)and support vector machine(SVM)methodologies to enhance the reliability of the classifier models.The RF classifier achieved an overall accuracy of 99.8%,and the SVM classifier attained an overall accuracy of 100%.The model was evaluated by a five-fold cross-validation approach with 93.8%accuracy for the RF and 94.9%for the SVM classifier.These results demonstrate the strong feasibility of pyrite classification,supported by a relatively large,balanced dataset and high accuracy rates.The classifier was employed to reveal the genesis of the controversial Keketale Pb-Zn deposit in NW China,which has been inconclusive among SEDEX,VMS,or a SEDEX-VMS transition.Petrographic investigations indicated that the deposit comprises early fine-grained layered pyrite(Py1)and late recrystallized pyrite(Py2).The majority voting classified Py1 as the VMS type,with an accuracy of RF and SVM being 72.2%and 75%,respectively,and confirmed Py2 as an orogenic type with 74.3% and 77.1%accuracy,respectively.The new findings indicated that the Keketale deposit originated from a submarine VMS mineralization system,followed by late orogenic-type overprinting of metamorphism and deformation,which is consistent with the geological and geochemical observations.This study further emphasizes the advantages of Machine learning(ML)methods in accurately and directly discriminating the deposit types and reconstructing the formation history of multi-stage deposits.展开更多
Numerous intermediate to felsic igneous rocks are present in both subduction and collisional orogens.However,porphyry copper deposits(PCDs)are comparatively rare.The underlying factors that differentiate fertile magma...Numerous intermediate to felsic igneous rocks are present in both subduction and collisional orogens.However,porphyry copper deposits(PCDs)are comparatively rare.The underlying factors that differentiate fertile magmas,which give rise to PCDs,from barren magmas in a specific geological setting are not well understood.In this study,three supervised machine learning algorithms:random forest(RF),logistic regression(LR)and support vector machine(SVM)were employed to classify metallogenic fertility in southeastern Tibet,Sanjiang orogenic belt,based on whole-rock trace element and Sr-Nd isotopic ratios.The performance of the RF model is better than LR and SVM models.Feature importance analysis of the models reveals that the concentration of Y,Eu,and Th,along with Sr-Nd isotope compositions are crucial variables in distinguishing fertile and barren samples.However,when the optimized models were applied to predict the datasets of Miocene Gangdese porphyry copper belt and Jurassic Gangdese arc representing collision and subduction settings respectively,a marked decline in metrics occurred in all three models,particularly on the subduction dataset.This substantial decrease indicates the compositional characteristics of intrusions across different tectonic settings could be diverse in a multidimensional space,highlighting the complex interplay of geological factors influencing PCD’s formation.展开更多
Fine-grained sediments are widely distributed and constitute the most abundant component in sedi-mentary systems,thus the research on their genesis and distribution is of great significance.In recent years,fine-graine...Fine-grained sediments are widely distributed and constitute the most abundant component in sedi-mentary systems,thus the research on their genesis and distribution is of great significance.In recent years,fine-grained sediment gravity-flows(FGSGF)have been recognized as an important transportation and depositional mechanism for accumulating thick successions of fine-grained sediments.Through a comprehensive review and synthesis of global research on FGSGF deposition,the characteristics,depositional mechanisms,and distribution patterns of fine-grained sediment gravity-flow deposits(FGSGFD)are discussed,and future research prospects are clarified.In addition to the traditionally recognized low-density turbidity current and muddy debris flow,wave-enhanced gravity flow,low-density muddy hyperpycnal flow,and hypopycnal plumes can all form widely distributed FGSGFD.At the same time,the evolution of FGSGF during transportation can result in transitional and hybrid gravity-flow deposits.The combination of multiple triggering mechanisms promotes the widespread develop-ment of FGSGFD,without temporal and spatial limitations.Different types and concentrations of clay minerals,organic matters,and organo-clay complexes are the keys to controlling the flow transformation of FGSGF from low-concentration turbidity currents to high-concentration muddy debris flows.Further study is needed on the interaction mechanism of FGSGF caused by different initiations,the evolution of FGSGF with the effect of organic-inorganic synergy,and the controlling factors of the distribution pat-terns of FGSGFD.The study of FGSGFD can shed some new light on the formation of widely developed thin-bedded siltstones within shales.At the same time,these insights may broaden the exploration scope of shale oil and gas,which have important geological significances for unconventional shale oil and gas.展开更多
Unraveling the precise mineralization age is vital to understand the geodynamic setting and ore-forming mechanism of the sediment-hosted Pb-Zn deposit;this has long been a challenge.The Sichuan-Yunnan-Guizhou(SYG)tria...Unraveling the precise mineralization age is vital to understand the geodynamic setting and ore-forming mechanism of the sediment-hosted Pb-Zn deposit;this has long been a challenge.The Sichuan-Yunnan-Guizhou(SYG)triangle in the southwestern margin of the Yangtze Block is a globally recognized carbonate-hosted Pb-Zn metallogenic province and also an essential part of the South China low-temperature metallogenic domain.This region has>30 million tons(Mt)Zn and Pb resources and shows the enrichment of dispersed metals,such as Ga,Ge,Cd,Se,and Tl.During the past 2 decades,abundant data on mineralization ages of Pb-Zn deposits within the SYG triangle have been documented based on various radioisotopic dating methods,resulting in significant progress in understanding the geodynamic background and ore formation of Pb-Zn deposits hosted in sedimentary rocks at SYG triangle.This paper provides a comprehensive summary of the geochronological results and Pb-Sr isotopic data regarding Pb-Zn deposits in the SYG triangle,which identified two distinct Pb-Zn mineralization periods influencing the dynamic processes associated with the expansion and closure of the Paleo-Tethys Ocean in the western margin of the Yangtze Block.The predominant phase of Pb-Zn mineralization at SYG triangle spanned from the Middle Triassic to Early Jurassic(226-191 Ma),which was intensely correlated with the large-scale basin fluid transport triggered by the closure of the Paleo-Tethys Ocean and Indosinian orogeny.The secondary Pb-Zn mineralization phase occurred during the Late Devonian to Late Carboniferous and was controlled by extensional structures associated with the expansion of the Paleo-Tethys Ocean.Further investigation is necessary to clarify the occurrence and potential factors involved in the Pb-Zn mineralization events during the Late Devonian to Late Carboniferous.展开更多
The key factor that controls the genesis of porphyry Cu deposits(PCDs)in collisional orogens remains a debated topic.This study employs whole-rock La/Yb proxies to quantitatively constrain the spatial and temporal var...The key factor that controls the genesis of porphyry Cu deposits(PCDs)in collisional orogens remains a debated topic.This study employs whole-rock La/Yb proxies to quantitatively constrain the spatial and temporal variations in crustal thickness of the South Armenian-Iranian magmatic belt(SAIMB)within the Zagros orogen(central Tethys region)since the Eocene.Our results show that rapid crustal thickening occurred first in the NW section of the SAIMB at~35 Ma,then propagated southeastward into the central and SE sections at~25 Ma and 20 Ma,respectively,indicating that the Arabia-Eurasia collision was diachronous.The formation of the large and giant collision-related PCDs in the SAIMB might have been controlled by the collision process because they developed first in the NW section of the SAIMB and subsequently propagated southeastward into the central and SE sections.More importantly,crustal thickness mapping shows that the PCDs are preferentially developed in the thickened crust areas(>50 km).Our findings propose that thickened crust is critical for the formation of the PCDs in collisional orogens by promoting Fe^(2+)-rich minerals as a fractionating phase,driving magmatic auto-oxidation and releasing Cu into the magmas.The Cu is then partitioned into magmatic fluids,sustaining the porphyry systems.Furthermore,our research highlights that the thickened crust hosting PCDs was characterized by a previously thinner crust(<40 km),where magmas had low oxygen fugacity due to the absence of the auto-oxidation process.Consequently,chalcophile elements(e.g.,Cu)efficiently separated from the melt through sulfide segregation,forming large Cu-bearing lower-crustal cumulates.These cumulates can be mobilized with an increase in oxygen fugacity,incorporating into subsequent porphyry mineralization.We thus propose that the crustal thickness evolution over time controls the formation of the PCDs in collisional orogens.There are two essential stages in the collision-related PCDs formation:the first is high-flux magmatism in the thin crustal setting(<40 km),leading to metal-fertilized lower crust through sulfide segregation,and the second is the intracrustal auto-oxidation during crustal thickening(>50 km)which facilitates pre-enriched sulfides in the lower crust to re-dissolve,releasing Cu into the magmas.展开更多
Molybdenum is one of the dominant minerals in China because of its rich reserves.In recent years,outstanding breakthroughs have been made in molybdenum prospecting in China,and the distribution of molybdenum deposits ...Molybdenum is one of the dominant minerals in China because of its rich reserves.In recent years,outstanding breakthroughs have been made in molybdenum prospecting in China,and the distribution of molybdenum deposits in China is found to have a"planar pattern".In general,the molybdenum deposits are concentrated in eastern China,including the largest molybdenum reserves of Henan Province.In terms of the scale of molybdenum deposits,the identified resources of the superlarge deposits are the most important,which account for about 53%of the whole country,and those of the large deposits account for about 30%,those of the medium-sized deposits account for about 14%,those of the small-sized deposits,mine spots and mineralization account for about 3%.The molybdenum deposits are mainly classified as porphyry type,skarn type,hydrothermal(vein)type and sedimentary(metamorphic)type in genesis,and the identified resources of these types account for 85.75%,8.83%,2.79%and 2.63%of the total resources respectively.Based on the statistics of precise chronology data of molybdenites Re-Os,Mo-mineralization can be divided into 6 periods in Chinese geological history,which are Precambrian(〉800 Ma),Cambrian-Silurian(540-415 Ma,Caledonian),Devonian-Permian(400-290 Ma,Hecynian),Triassic(260-200 Ma,Indosinian),Jurassic-Cretaceous(195-70 Ma,Yanshanian)and Paleogene-Neogene(65-10 Ma,Himalayan).Mo mineralization during the Yanshanian period is the strongest one,in which about 76.69%of the Chinese total identified resources was formed.The second is the Himalayan period.According to spatial-temporal distribution characteristics of molybdenum deposits,the metallogenic regularity of molybdenum deposits was preliminarily summarized,and 41 level-Ⅲmolybdenum-forming belts,13 level-Ⅱmolybdenum-forming provinces and 4 level-Ⅰmolybdenum-forming domains were ascertained in the mainland of China.There are 39 metallogenic series of and 60 sub-series of molybdenum deposits with molybdenum as the dominant metal and corresponding representative molybdenum deposits proposed.Metallogenic lineages of molybdenum deposits were also established.Spatial-temporal evolution of different types of molybdenum deposits,and the relationship between Mo-mineralization and tectonic evolution have been discussed in this paper.On this basis,the authors think that element Mo is an effective tracer for recording the crustal evolution history of China.At present,there are some problems in the exploration of Mo deposits in China,such as uneven exploration degrees in eastern and western China,shallow exploration depth,low and uneven grade,complex associated components,difficulty of mineral development and utilization,increasing costs of prospecting,and so on.According to successful experience of superficial and deep prospecting and considering also the discussion above,some suggestions are proposed for the prospecting of molybdenum deposits in the future.展开更多
China is rich in tin resources,and contains many types of tin deposits.Among the tin deposit types,the cassiterite-sulfide type,skarn type and quartz vein type occupy a large proportion of tin resources and reserves.F...China is rich in tin resources,and contains many types of tin deposits.Among the tin deposit types,the cassiterite-sulfide type,skarn type and quartz vein type occupy a large proportion of tin resources and reserves.From the aspect of exploitation and utilization,the most important types are cassiterite-sulfide type and quartz vein type.The cassiterite-sulfide type tin deposits are mainly located in Northern Guangxi and Eastern Yunnan,skarn type deposits are mainly distributed in the ore-concentration areas of South Hunan in Middle Nanling,and the quartz vein type tin deposits are mainly distributed in South China,such as Western Fujian,Middle Jiangxi,Northern Guangzhou and Southern Hunan.The most important metallogenic epoch for tin deposits is the Mesozoic era.The metallogenic geotectonic background is mainly continental environments after orogeny process,with strong tectonic changes,interlaced deep fracture and frequent magmatism.And the most distinctive feature is the well developed Mesozoic granites,which have a close relationship with tin mineralization.Based on the detailed study of the data from 873 tin deposits in China,this paper summarized the metallogenic regularity of tin deposits,classified 20 important metallogenic series of tin or tin-associated deposits,and inferred that the cassiterite-sulfide type,skarn type,quartz vein type and greisen type are the main prediction types of tin resources.Forty-four tin-mineralization belts were divided,among which,19 belts are the most important.In addition,a series of maps about tin metallogenic belts and tin metallogenic regularity were compiled,aiming to provide theoretical basis for potential estimation and prediction of tin mineral resources.展开更多
基金National Natural Science Foundation of China,No.42501182The Open Foundation of Key Laboratory of Western China’s Environmental System,Ministry of Education,Lanzhou Universitythe Fundamental Research Funds for the Central Universities,No.lzujbky-2024-jdzx01。
文摘Aeolian deposits across the Yarlung Zangbo River Basin on the southern Tibetan Plateau record the landscape and atmospheric evolution of Earth's Third Pole.The complex mountain-basin system exhibits nonlinear responses to climate forcing,complicating the interpretation of its high-altitude environmental dynamics.Investigating the magnetic enhancement mechanism of aeolian deposits offers an opportunity to decipher climate signals.Our analysis of three aeolian sections from the basin indicates that magnetic minerals are predominantly low-coercivity ferrimagnetic minerals,and grain sizes fine from upper to lower reaches due to climate shifts from arid to humid.Magnetic enhancement in the upper reaches primarily originates from dust input,while dust input and pedogenesis contribute variably over time in the middle and lower reaches.Similar complex patterns occur in the Ili basin,a mountain-basin system in northwestern China.They differ from the Chinese Loess Plateau,where long-distance-transported dust is well-mixed and the pedogenic enhancement model is applied,and desert peripheries where short-distance dust is transported and the dust input model is applied.We summarize the magnetic enhancement mechanisms in various settings and offer a new framework for applying magnetic techniques in paleoclimate reconstruction within global mountain-basin systems,which highlights the need for caution in interpreting their magnetic susceptibility records.
基金Supported by the National High Level Hospital Clinical Research Funding,No.2023-NHLHCRF-BQ-32 and No.2023-NHLHCRFYYPPLC-ZR-13National Key Research and Development Program of China,No.2024YFE0198300Beijing Municipal Natural Science Foundation,No.7222316.
文摘BACKGROUND The number of tumor deposits(TDs)does not play a part in the current tumor node metastasis staging.Negative lymph node(NLN)status is associated with the prognosis of colorectal cancer(CRC),but its clear role in N1c stage remains to be defined.AIM To evaluate the combination of TDs and NLNs as potential prognostic indicators in N1c CRC.METHODS We retrospectively identified 107 consecutive patients who had N1c CRC radically resected at China-Japan Friendship Hospital.The combination of TDs and NLNs was calculated by the formula NLNTD=NLN/(TD+1).Cutoff values of NLNs and NLNTD were determined using the R package“survminer”.Disease-free survival(DFS),overall survival(OS)and cancer-specific survival(CSS)were determined using the Kaplan-Meier method to assess the impact of NLNTD on prognosis.Results were compared using the log-rank test.RESULTS The median follow-up time was 63.17(45.33-81.37)months for DFS,with 33.64%(36/107)of patients experiencing recurrence during follow-up.Five-year DFS was 66.0%(57.3%-76.0%).There was no significant difference in prognosis between patients with>12 and≤12 NLNs(P=0.058)for DFS.Similar results were seen according to the number of TDs.The definition of NLNTD=NLN/(TD+1)with a cutoff value of 6 divided patients into two groups with different DFS(P=0.005).Five-year DFS for patients with NLNTD>6 was 73.5%(63.6%-85.0%),compared with 50.0%(35.7%-70.0%)for those with NLNTD≤6.These two groups had different prognosis without perineural invasion(P=0.012)or lymphovascular invasion(P=0.002)even neither(P=0.053).Similar results were seen for OS and CSS.CONCLUSION NLNTD could serve as important prognostic factor for outcomes in N1c CRC patients.These patients could be stratified for prognosis through NLNTD and the high-risk should be given more attention during treatment.
基金funded by the National Key Research&Development Program of China(No.2021YFC2900100)the Guangxi Natural Science Foundation(No.2022GXNSFFA035025)+3 种基金the Chinese National Natural Science Foundation(No.42372099)the China Geological Survey(No.DD20190379)the Science&Technology Fundamental Resources Investigation Program(No.2022FY101800)the Major Talent Program of Guangxi Zhuang Autonomous Region,and the Innovation Project of Guangxi Graduate Education(No.YCSW2023345)。
文摘Quartz vein-type tungsten deposits are a common W deposit type.Their ore vein distribution was previously considered to be controlled by regional horizontal tectonic stress.In this paper,14 tungsten deposits with fan-shaped mineralization in SE China are summarized,and the relations between their ore veins and granite and the ore-forming structural stress field are analyzed.These deposits have a post-magmatic hydrothermal genesis and involve the formation of two sets of veins with similar strike and opposite dips at the top of the ore-causative granite bodies,forming a vertical fan-shaped profile.Their ore veins were coeval with the underlying granite bodies,and generally extend along the long axis of the granite.In such fan-shaped ore formation,the stress is highly focused at the top of the granite and gradually weakens outward.The maximum principal stress(σ1)is perpendicular to the granite contact surface,and radiates outward from the pluton.Meanwhile,the minimum principal stress(σ3)forms an arc-shaped band parallel to the contact surface.Our findings,together with published numerical modeling indicate that the emplacement dynamics of granitic magma(rather than regional horizontal tectonic stress)are essential controls on the distribution of ore veins in quartz vein-type tungsten deposits.
基金the Anusandhan National Research Foundation(ANRF),Science and Engineering Research Board(SERB),Department of Science&Technology,Government of India for a start-up research grant(M-14/0599,Sanction order no.SRG/2022/001478)Seed Grant under Institutions of Eminence(IoE),Banaras Hindu University(BHU)(Dev.Scheme No.6031)for financial assistance.
文摘The green energy transition relies heavily on critical metals,such as rare earth elements(REEs).However,their reserves are primarily focused in a few countries,such as China,which accounts for approximately 70%of global production.Hence,several countries are currently looking for alternative resources for REEs.Alternative REE resources in the supply chain include recycling of e-waste,industrial waste like red mud and phosphogypsum,coal ash,mine tailings,ocean floor sediments,and even certain types of sedimentary deposits like phosphorites where REEs are present in lower concentrations but at larger volumes compared to primary ore deposits which are becoming targets by REEs industry.Currently,several studies are going on the development of eco-friendly REEs extraction technologies from phosphorite deposits.Consequently,advanced data analysis tools,such as Machine Learning(ML),are becoming increasingly important in mineral prospectivity and are rapidly gaining traction in the earth sciences.Phosphorite deposits are mainly used to manufacture fertilizers as these rocks are known for their significant phosphorus content.Moreover,these formations are considered a prospective resource of REEs.The different types of phosphorite deposits such as continental,seamount,and ore deposits worldwide reported concentrations of∑REE upto 18,000µg/g.Due to the augmented claim of REEs for various ultra-modern,and green technology applications that are required to switch over to a carbon-neutral environment,these phosphorite deposits have become an important target mostly because of their relatively higher content of REEs especially heavy rare earth elements(HREE).For example,Mississippian phosphorites reported ∑ HREE 7,000µg/g.To have a comprehensive understanding of the REEs potential of these phosphorite deposits which also include several Chinese phosphorite deposits,this study is undertaken to review the phosphorite deposits in the world and their REEs potential,in addition to some of the associated aspects such as applications and formation mechanisms for different types of phosphorite deposits such as igneous phosphate deposits,sedimentary phosphorite deposits,marine phosphorite deposits,cave phosphate deposits,and insular guano deposits.Other important aspects include their occurrences,types,geochemical characteristics,the REEs enrichment mechanisms,and various recovery methods adopted to recover REEs from different phosphorite deposits.The present review paper concludes that the recent studies highlight the global potential of phosphorite deposits to satisfy the increasing demand for REEs.Extracting REEs from phosphorite presents no significant technological or environmental difficulties,as long as radioactive elements are eliminated.In India,more comprehensive geological surveys,along with the advancement of new methods and evaluations,are required to locate phosphorite deposits with high concentrations of REEs.
文摘We read with great interest the article by Sun et al addressing the prognostic role of tumor deposits(TDs)and negative lymph nodes in N1c colorectal cancer.Their proposal of the NLNTD index is a valuable step toward refining risk stratification in this subgroup.In our recently published population-based cohort of 111106 patients with early-stage colon cancer,TD positivity,classified as N1c according to AJCC definitions,was independently associated with significantly worse overall and disease-specific survival,even after propensity score matching.Taken together,these findings show that TDs are adverse prognostic factors across stages.They should inform treatment planning and follow-up,rather than be regarded as incidental.
文摘One reference in the original manuscript contained incorrect bibliographic information and cited a non-existent publication:Traczyk A(1999)Pleistocene debris cover beds and block-debris tongues in the north-western part of theŚlęża Massif(Poland)and their formation under permafrost conditions.Geographia Polonica 81(1).This erroneous reference has now been removed from the references list.
文摘BACKGROUND Tumor deposits(TDs)are an independent predictor of poor prognosis in colorec-tal cancer(CRC)patients.Enhanced follow-up and treatment monitoring for TD+patients may improve survival rates and quality of life.However,the detection of TDs relies primarily on postoperative pathological examination,which may have a low detection rate due to sampling limitations.AIM To evaluate the spectral computed tomography(CT)parameters of primary tu-mors and the largest regional lymph nodes(LNs),to determine their value in predicting TDs in CRC.METHODS A retrospective analysis was conducted which included 121 patients with CRC whose complete spectral CT data were available.Patients were divided into the TDs+group and the TDs-group on the basis of their pathological results.Spectral CT parameters of the primary CRC lesion and the largest regional LNs were measured,including the normalized iodine concentration(NIC)in both the arte-rial and venous phases,and the LN-to-primary tumor ratio was calculated.Stati-stical methods were used to evaluate the diagnostic efficacy of each spectral para-meter.RESULTS Among the 121 CRC patients,33(27.2%)were confirmed to be TDs+.The risk of TDs positivity was greater in patients with positive LN metastasis,higher N stage and elevated carcinoembryonic antigen and cancer antigen 19-9 levels.The NIC(LNs in both the arterial and venous phases),NIC(primary tumors in the venous phase),and the LN-to-primary tumor ratio in both the arterial and venous phases were associated with TDs(P<0.05).In mul-tivariate logistic regression analysis,the arterial phase LN-to-primary tumor ratio was identified as an independent predictor of TDs,demonstrating the highest diagnostic performance(area under the curve:0.812,sensitivity:0.879,specificity:0.648,cutoff value:1.145).CONCLUSION The spectral CT parameters of the primary colorectal tumor and the largest regional LNs,especially the LN-to-primary tumor ratio,have significant clinical value in predicting TDs in CRC.
基金supported by the National Natural Science Foundation of China(Nos.42172109,41872113,42172108)China National Petroleum Corporation-China University of Petroleum(Beijing)strategic cooperation science and technology project(ZLZX2020-02)+2 种基金Science Foundation of China University of Petroleum(Beijing)(Nos.2462020BJRC002,2462020YXZZ020)Natural Science Foundation of Chongqing(CSTB2022NSCQ-MSX1166)Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202201511).
文摘Previous studies have indicated that sediment gravity flow deposits developed in lacustrine active extensional rift basins are primarily influenced by tectonics and to a lesser extent by climate.Our present work reveals that climate can obscure the effect of tectonic subsidence by regulating sediment supply;conversely,tectonics can impede the sedimentary manifestation of climatic impacts.Here a case study has been presented to assess the impact of climate-modulated rapid lake-level rise and tectonic subsidence on the development of coarse-grained gravity flow deposits in the Dongying rift margin of the Bohai Bay Basin,eastern China.The lithofacies analysis reveals frequent bed amalgamation,abundant thick massive coarse-grained deposits,widespread cross bedding and plant fragments,and incomplete composite bed formed by high-energy erosion,indicating that the hyperpycnal flow is an important mechanism driving the deposition of these coarse-grained sediments.Detailed sequence stratigraphic analysis and sediment dispersal pattern suggest that the long-striped nearshore subaqueous fan systems induced by outburst-flood hyperpycnal flow distributed along the border fault,are primarily controlled by long-term tectonics,while the rapid rise of lake level driven by short-term climate change possibly intensifies seasonal flood-generated hyperpycnal flow occurrences and consequently promotes the basinal fan progradation.The maximum scale of these coarse-grained gravity flow deposits of the basinal fan systems are typically attained during the transgressive systems tract,which deviates from the classical sequence stratigraphic model.Furthermore,it presented a continuous transition from the proximal to the distal part,encompassing traction flows and turbidity currents during the periods of relatively stable tectonics.Nevertheless,gravel-rich debris flows appear to predominate the dispersion of coarse-grained sediments during periods characterized by intense tectonic activity.The coarse-grained gravity flow deposits in the lacustrine rift margin reported here,challenge the traditional beliefs:this study suggests that subaqueous deposits abundantly preserved in the transgressive setting.
基金supported financially by the Key Research Program of the Institute of Geology and Geophysics, CAS (Grant No. IGGCAS-202102 and IGGCAS-201905)。
文摘The polar layered deposits(PLD) of Mars can provide deep insight into paleoclimate changes over the planet's last several million years. Since the 1960s, researchers have studied almost all aspects of Martian PLD properties, searching for patterns that might reveal periodic characteristics of the planet's climate history. Although much progress has been made in our understanding of orbital periodicities reflected in the PLD, questions remain regarding how Martian orbital changes have affected the formation of the PLD and regarding the extent of climate information that is recorded in the PLD. Future studies of PLD should be carried out via integrated research that targets multi-profiles throughout the entire Martian polar regions that would clarify their general features at the hemisphere scale. Numerical modeling, coupled with modern observations of dust and water vapor transportation, should greatly advance our understanding of planetary climate evolution. Furthermore, future landing missions may help to clarify the paleoclimatic characteristics reflected in the PLD by drilling into these layered deposits and measuring mineralogical and geochemical compositions of the drilled samples.
基金the Department of Geology at the Federal University of Ceará(DEGEO-UFC)and Prof.Dr.Felipe Holanda dos Santos for their support and guidance during the research process.FHS would like to thank the Society of Economic Geologists(SEG)for the Student Research Grant.WAS is funded by CNPq,under grant number(407255/2022-2).
文摘This study highlights a new by-product source for cobalt by recycling Paleoproterozoic Mn deposits.We present a geochemical modeling approach utilizing Principal Component Analysis(PCA)for available geochemical data of Paleoproterozoic manganese deposits found in Africa and Brazil,which exhibit anomalous cobalt contents(up to 1200 ppm)along with other metals such as copper,nickel,and vanadium.The PCA results for the correlation coefficient matrix of the Enrichment Factor(_(EF))values of major and trace elements from samples of eight Mn deposits found in Africa and Brazil(Kisenge-Kamata,Moanda,Nsuta in Africa,and Azul,Buritirama,Lagoa do Riacho,Morro da Mina,and Serra do Navio in Brazil)yielded a cumulative variance of 53.3%for PC1(34%)and PC2(19.3%).In PC1,the highest positive loadings correspond to the variables Mn_(EF),Ni_(EF),and Co_(EF),while the highest negative loadings correspond to the variables Si_(EF),Fe_(EF),K_(EF),Ti_(EF),Cr_(EF),and Zr_(EF).PC2 exhibits the highest positive loadings for the variables Ca_(_(EF)),Mg_(EF),and P_(EF),while the highest negative loadings are for Cu_(EF)and V_(EF).The biplot diagram representation showed that clusters of vectors Mn_(EF),Ni_(EF),Co_(EF),V_(EF),and Cu_(EF)influence samples of Mn-carbonate rock,Mn-carbonate-silicate rock,Mn-silicate rock,and Mn-carbonate-siliciclastic rock,all with high Co_(EF)values(up to 414).The cluster of vectors Ca_(_(EF)),Mg_(EF),and P_(EF)significantly influence carbonate rock and dolomite marble,which have low Co_(EF)values(close to 0).The cluster of vectors Si_(EF),Fe_(EF),K_(EF),Ti_(EF),Cr_(EF),and Zr_(EF)strongly influences siliciclastic rock,which exhibits low Co_(EF)values.On the other hand,the cluster of vectors Cu_(EF)and V_(EF)influences oxidized Mn ore,which exhibits Co_(EF)values of up to 108.The results reveal a dichotomy regarding the origin of cobalt and other metal enrichments in these deposits linked to the Mn redox cycle.This process involves the formation of Mn-oxyhydroxides with the adsorption of Co and other metals under oxic conditions,followed by the burial of these Mn oxides in an anoxic diagenetic environment,where microbial sulfate reduction leads to the nucleation of Mn-carbonates and the formation of metal-rich sulfides(Fe,Co,Ni,V).Additionally,detrital input and sulfide phases(e.g.,framboidal pyrite)for the formation of Mn-rich siliciclastic rocks associated with Mn-carbonate rocks are evidenced by proxies Si_(EF),Fe_(EF),K_(EF),Ti_(EF),Cr_(EF),and Zr_(EF).This new exploration approach,supported by geochemical modeling through PCA,enhances our understanding of the genesis of these Paleoproterozoic manganese deposits and highlights a new route for cobalt exploration.In the increasing global demand for cobalt,particularly in applications involving electric vehicle batteries and energy storage,exploring these deposits emerges as an alternative source to produce these critical metals.
文摘Changing political and market conditions have disrupted energy security.European economies are planning to utilize their own resources of energy raw materials,including consideration of the advisability of returning abandoned coal resources to use.The research using the proposed methodology examined the impact of the ongoing mine closure processes on the potential ability to develop the remaining deposit.It was found that the greatest influence on the availability of unclosed shafts was the active concession to extract minerals from the deposit and the availability of unclosed main plant facilities.The assessment of the possibilities of coal resources management in the deposits of liquidated mines has not been the subject of extensive scientific research so far.The information obtained can be used as a reference point for detailed analysis and multi-criteria evaluation,after which the decision maker makes the decision.The method is designed for liquidated mines,but with certain modifications it can also be used by mining companies.
基金funded by Talent Award under the 1000 Plan Project from the Chinese Government
文摘It is quite evident that it is not anomalous metal transport,nor unique depositional conditions,nor any single factor at the deposit scale,that dictates whether a mineral deposit becomes a giant or not.A hierarchical approach thus is required to progressively examine controlling parameters at successively decreasing scales in the total mineral system to understand the location of giant gold deposits in non-arc environments.For giant orogenic,intrusion-related gold systems（IRGS） and Carlin-type gold deposits and iron oxide-copper-gold（IOCG） deposits,there are common factors among all of these at the lithospheric to crustal scale.All are sited in giant gold provinces controlled by complex fundamental fault or shear zones that follow craton margins or,in the case of most Phanerozoic orogenic giants,define the primary suture zones between tectonic terranes.Giant provinces of IRGS,IOCG,and Carlin-type deposits require melting of metasomatized lithosphere beneath craton margins with ascent of hybrid lamprophyric to granitic magmas and associated heat flux to generate the giant province.The IRGS and IOCG deposits require direct exsolution of volatile-rich magmatic-hydrothermal fluids,whereas the association of such melts with Carlin-type ores is more indirect and enigmatic.Giant orogenic gold provinces show no direct relationship to such magmatism.forming from metamorphic fluids,but show an indirect relationship to lamprophyres that reflect the mantle connectivity of controlling first-order structures.In contrast to their province scale similarities,the different giant gold deposit styles show contrasting critical controls at the district to deposit scale.For orogenic gold deposits,the giants appear to have formed by conjunction of a greater number of parameters to those that control smaller deposits,with resultant geometrical and lithostratigraphic complexity as a guide to their location.There are few giant IRGS due to their inferior fluid-flux systems relative to orogenic gold deposits,and those few giants are essentially preservational exceptions.Many Carlin-type deposits are giants due to the exceptional conjunction of both structural and lithological parameters that caused reactive and permeable rocks,enriched in syngenetic gold,to be located below an impermeable cap along antiformal ＂trends＂.Hydrocarbons probably played an important role in concentrating metal.The supergiant Post-Betze deposit has additional ore zones in strain heterogeneities surrounding the pre-gold Goldstrike stock.All unequivocal IOCG deposits are giant or near-giant deposits in terms of gold-equivalent resources,partly due to economic factors for this relatively poorly understood,low Cu-Au grade deposit type.The supergiant Olympic Dam deposit,the most shallowly formed deposit among the larger IOCGs,probably owes its origin to eruption of volatile-rich hybrid magma at surface,with formation of a large maar and intense and widespread brecciation,alteration and Cu-Au-U deposition in a huge rock volume.
基金supported by the National Natural Science Foundations of China(Nos.41973005,41673001)China National Space Administration(CNSA)(No.D020205)。
文摘A preliminary survey of silver isotopic composition in four polymetallic ores in eastern China shows a larger variation inδ^(109)Ag from-0.014‰to+0.983‰,which is within the total ranges for the entire respective ore deposit types worldwide.The diversity of silver isotopic compositions in oredeposits reported here and previous studies seemed to preclude simple isotopic links to particular sources,but reflected the silver isotope fractionation in transport-and deposit-related processes instead.Theδ^(109)Ag values in supergene samples from the Qixiashan Pb-Zn-Ag polymetallic deposit are more positive,in consistent with the statistical δ^(109)Ag distribution from-0.4‰to+2.2‰in 36 pieces of supergene ore samples around the World,which reflects the diverse controls on silver isotope fractionation from the first-order thermodynamic effect,reduction-mediated reaction,remobilization of silver with surficial low-temperature weathering processes.The hypogene samples in Dazhuangzi orogenic Au-Ag ore deposit,have δ^(109)Ag values close to 0,which implies that equilibrium partitioning associated with metal sources at the high-temperature does not result in a resolvable difference in silver isotopic compositions.By contrast,the hypogene samples which are dominated by pyrite without visible silver minerals (i.e.,skarn iron ore deposit in Edongnan) have shown the largest variation range of δ^(109)Ag,followed by that from the porphyry copper ore in Zijinshan.It could be concluded that the surface adsorption and/or lattice substitution are important factors to control Ag isotope fractionation in oreforming processes,especially for skarn deposits with only pyrite.The perspective of silver isotope shows great potentials to understand the processes that lead to the concentrations of metals to economic levels and to constrain the physicochemical conditions during ore-mineralization in metallic ore-deposits.
基金the National Key Research and Development Program of China(2021YFC2900300)the Natural Science Foundation of Guangdong Province(2024A1515030216)+2 种基金MOST Special Fund from State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences(GPMR202437)the Guangdong Province Introduced of Innovative R&D Team(2021ZT09H399)the Third Xinjiang Scientific Expedition Program(2022xjkk1301).
文摘The application of machine learning for pyrite discrimination establishes a robust foundation for constructing the ore-forming history of multi-stage deposits;however,published models face challenges related to limited,imbalanced datasets and oversampling.In this study,the dataset was expanded to approximately 500 samples for each type,including 508 sedimentary,573 orogenic gold,548 sedimentary exhalative(SEDEX)deposits,and 364 volcanogenic massive sulfides(VMS)pyrites,utilizing random forest(RF)and support vector machine(SVM)methodologies to enhance the reliability of the classifier models.The RF classifier achieved an overall accuracy of 99.8%,and the SVM classifier attained an overall accuracy of 100%.The model was evaluated by a five-fold cross-validation approach with 93.8%accuracy for the RF and 94.9%for the SVM classifier.These results demonstrate the strong feasibility of pyrite classification,supported by a relatively large,balanced dataset and high accuracy rates.The classifier was employed to reveal the genesis of the controversial Keketale Pb-Zn deposit in NW China,which has been inconclusive among SEDEX,VMS,or a SEDEX-VMS transition.Petrographic investigations indicated that the deposit comprises early fine-grained layered pyrite(Py1)and late recrystallized pyrite(Py2).The majority voting classified Py1 as the VMS type,with an accuracy of RF and SVM being 72.2%and 75%,respectively,and confirmed Py2 as an orogenic type with 74.3% and 77.1%accuracy,respectively.The new findings indicated that the Keketale deposit originated from a submarine VMS mineralization system,followed by late orogenic-type overprinting of metamorphism and deformation,which is consistent with the geological and geochemical observations.This study further emphasizes the advantages of Machine learning(ML)methods in accurately and directly discriminating the deposit types and reconstructing the formation history of multi-stage deposits.
基金financially supported by the National Key Research and Development Program of China(2019YFA0708602,2022YFF0800903)National Natural Science Foundation of China(42472112,U2244217,41973045)+1 种基金Basic Science and Technology Research Fundings of the Institute of Geology,CAGS(JKYZD202312)Geological Survey Projects of the China Geological Survey(DD20242878,DD20243512).
文摘Numerous intermediate to felsic igneous rocks are present in both subduction and collisional orogens.However,porphyry copper deposits(PCDs)are comparatively rare.The underlying factors that differentiate fertile magmas,which give rise to PCDs,from barren magmas in a specific geological setting are not well understood.In this study,three supervised machine learning algorithms:random forest(RF),logistic regression(LR)and support vector machine(SVM)were employed to classify metallogenic fertility in southeastern Tibet,Sanjiang orogenic belt,based on whole-rock trace element and Sr-Nd isotopic ratios.The performance of the RF model is better than LR and SVM models.Feature importance analysis of the models reveals that the concentration of Y,Eu,and Th,along with Sr-Nd isotope compositions are crucial variables in distinguishing fertile and barren samples.However,when the optimized models were applied to predict the datasets of Miocene Gangdese porphyry copper belt and Jurassic Gangdese arc representing collision and subduction settings respectively,a marked decline in metrics occurred in all three models,particularly on the subduction dataset.This substantial decrease indicates the compositional characteristics of intrusions across different tectonic settings could be diverse in a multidimensional space,highlighting the complex interplay of geological factors influencing PCD’s formation.
基金supported by National Natural Science Foundation of China(Grant Nos.42072126,42372139)the Natural Science Foundation of Sichuan Province(Grant Nos.2022NSFSC0990).
文摘Fine-grained sediments are widely distributed and constitute the most abundant component in sedi-mentary systems,thus the research on their genesis and distribution is of great significance.In recent years,fine-grained sediment gravity-flows(FGSGF)have been recognized as an important transportation and depositional mechanism for accumulating thick successions of fine-grained sediments.Through a comprehensive review and synthesis of global research on FGSGF deposition,the characteristics,depositional mechanisms,and distribution patterns of fine-grained sediment gravity-flow deposits(FGSGFD)are discussed,and future research prospects are clarified.In addition to the traditionally recognized low-density turbidity current and muddy debris flow,wave-enhanced gravity flow,low-density muddy hyperpycnal flow,and hypopycnal plumes can all form widely distributed FGSGFD.At the same time,the evolution of FGSGF during transportation can result in transitional and hybrid gravity-flow deposits.The combination of multiple triggering mechanisms promotes the widespread develop-ment of FGSGFD,without temporal and spatial limitations.Different types and concentrations of clay minerals,organic matters,and organo-clay complexes are the keys to controlling the flow transformation of FGSGF from low-concentration turbidity currents to high-concentration muddy debris flows.Further study is needed on the interaction mechanism of FGSGF caused by different initiations,the evolution of FGSGF with the effect of organic-inorganic synergy,and the controlling factors of the distribution pat-terns of FGSGFD.The study of FGSGFD can shed some new light on the formation of widely developed thin-bedded siltstones within shales.At the same time,these insights may broaden the exploration scope of shale oil and gas,which have important geological significances for unconventional shale oil and gas.
基金supported by the National Natural Science Foundation of China(92162218,42302101,42202099)the Guizhou Provincial Natural Science Foundation(ZK[2023]477)。
文摘Unraveling the precise mineralization age is vital to understand the geodynamic setting and ore-forming mechanism of the sediment-hosted Pb-Zn deposit;this has long been a challenge.The Sichuan-Yunnan-Guizhou(SYG)triangle in the southwestern margin of the Yangtze Block is a globally recognized carbonate-hosted Pb-Zn metallogenic province and also an essential part of the South China low-temperature metallogenic domain.This region has>30 million tons(Mt)Zn and Pb resources and shows the enrichment of dispersed metals,such as Ga,Ge,Cd,Se,and Tl.During the past 2 decades,abundant data on mineralization ages of Pb-Zn deposits within the SYG triangle have been documented based on various radioisotopic dating methods,resulting in significant progress in understanding the geodynamic background and ore formation of Pb-Zn deposits hosted in sedimentary rocks at SYG triangle.This paper provides a comprehensive summary of the geochronological results and Pb-Sr isotopic data regarding Pb-Zn deposits in the SYG triangle,which identified two distinct Pb-Zn mineralization periods influencing the dynamic processes associated with the expansion and closure of the Paleo-Tethys Ocean in the western margin of the Yangtze Block.The predominant phase of Pb-Zn mineralization at SYG triangle spanned from the Middle Triassic to Early Jurassic(226-191 Ma),which was intensely correlated with the large-scale basin fluid transport triggered by the closure of the Paleo-Tethys Ocean and Indosinian orogeny.The secondary Pb-Zn mineralization phase occurred during the Late Devonian to Late Carboniferous and was controlled by extensional structures associated with the expansion of the Paleo-Tethys Ocean.Further investigation is necessary to clarify the occurrence and potential factors involved in the Pb-Zn mineralization events during the Late Devonian to Late Carboniferous.
基金funded by the National Key R&D Program of China(Grant No.2022YFC2905000)the NSFC(Grant No.42230813)+4 种基金the Opening Foundation of State Key Laboratory of Continental Dynamics,Northwest University(Grant No.23LCD12)the Opening Foundation of the Key Laboratory of Continental Dynamics of Ministry of Natural Resources(Grant No.J2408)the Sichuan Province Natural Science Foundation(Grant Nos.2024NSFSC1954,2025ZNSFSC1196)the Open Research Fund Program of Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring(Central South University),Ministry of Education(11300-502401003)the Everest Scientific Research Program of Chengdu University of Technology(Grant No.2024ZF11407).
文摘The key factor that controls the genesis of porphyry Cu deposits(PCDs)in collisional orogens remains a debated topic.This study employs whole-rock La/Yb proxies to quantitatively constrain the spatial and temporal variations in crustal thickness of the South Armenian-Iranian magmatic belt(SAIMB)within the Zagros orogen(central Tethys region)since the Eocene.Our results show that rapid crustal thickening occurred first in the NW section of the SAIMB at~35 Ma,then propagated southeastward into the central and SE sections at~25 Ma and 20 Ma,respectively,indicating that the Arabia-Eurasia collision was diachronous.The formation of the large and giant collision-related PCDs in the SAIMB might have been controlled by the collision process because they developed first in the NW section of the SAIMB and subsequently propagated southeastward into the central and SE sections.More importantly,crustal thickness mapping shows that the PCDs are preferentially developed in the thickened crust areas(>50 km).Our findings propose that thickened crust is critical for the formation of the PCDs in collisional orogens by promoting Fe^(2+)-rich minerals as a fractionating phase,driving magmatic auto-oxidation and releasing Cu into the magmas.The Cu is then partitioned into magmatic fluids,sustaining the porphyry systems.Furthermore,our research highlights that the thickened crust hosting PCDs was characterized by a previously thinner crust(<40 km),where magmas had low oxygen fugacity due to the absence of the auto-oxidation process.Consequently,chalcophile elements(e.g.,Cu)efficiently separated from the melt through sulfide segregation,forming large Cu-bearing lower-crustal cumulates.These cumulates can be mobilized with an increase in oxygen fugacity,incorporating into subsequent porphyry mineralization.We thus propose that the crustal thickness evolution over time controls the formation of the PCDs in collisional orogens.There are two essential stages in the collision-related PCDs formation:the first is high-flux magmatism in the thin crustal setting(<40 km),leading to metal-fertilized lower crust through sulfide segregation,and the second is the intracrustal auto-oxidation during crustal thickening(>50 km)which facilitates pre-enriched sulfides in the lower crust to re-dissolve,releasing Cu into the magmas.
基金funded by the National Natural Science Fund for Youth(Grant No.41402069)Scientific Research Fund of the China Central Non-Commercial Institute(Grant No.1305,K1022 and K1001)+1 种基金Geological Survey Program of comprehensive study of Chinese mineral geology and regional metallogenic regularity(Grant No.12120114039701,12120114039601)mineral resources potential evaluation(Grant No.1212010633901)
文摘Molybdenum is one of the dominant minerals in China because of its rich reserves.In recent years,outstanding breakthroughs have been made in molybdenum prospecting in China,and the distribution of molybdenum deposits in China is found to have a"planar pattern".In general,the molybdenum deposits are concentrated in eastern China,including the largest molybdenum reserves of Henan Province.In terms of the scale of molybdenum deposits,the identified resources of the superlarge deposits are the most important,which account for about 53%of the whole country,and those of the large deposits account for about 30%,those of the medium-sized deposits account for about 14%,those of the small-sized deposits,mine spots and mineralization account for about 3%.The molybdenum deposits are mainly classified as porphyry type,skarn type,hydrothermal(vein)type and sedimentary(metamorphic)type in genesis,and the identified resources of these types account for 85.75%,8.83%,2.79%and 2.63%of the total resources respectively.Based on the statistics of precise chronology data of molybdenites Re-Os,Mo-mineralization can be divided into 6 periods in Chinese geological history,which are Precambrian(〉800 Ma),Cambrian-Silurian(540-415 Ma,Caledonian),Devonian-Permian(400-290 Ma,Hecynian),Triassic(260-200 Ma,Indosinian),Jurassic-Cretaceous(195-70 Ma,Yanshanian)and Paleogene-Neogene(65-10 Ma,Himalayan).Mo mineralization during the Yanshanian period is the strongest one,in which about 76.69%of the Chinese total identified resources was formed.The second is the Himalayan period.According to spatial-temporal distribution characteristics of molybdenum deposits,the metallogenic regularity of molybdenum deposits was preliminarily summarized,and 41 level-Ⅲmolybdenum-forming belts,13 level-Ⅱmolybdenum-forming provinces and 4 level-Ⅰmolybdenum-forming domains were ascertained in the mainland of China.There are 39 metallogenic series of and 60 sub-series of molybdenum deposits with molybdenum as the dominant metal and corresponding representative molybdenum deposits proposed.Metallogenic lineages of molybdenum deposits were also established.Spatial-temporal evolution of different types of molybdenum deposits,and the relationship between Mo-mineralization and tectonic evolution have been discussed in this paper.On this basis,the authors think that element Mo is an effective tracer for recording the crustal evolution history of China.At present,there are some problems in the exploration of Mo deposits in China,such as uneven exploration degrees in eastern and western China,shallow exploration depth,low and uneven grade,complex associated components,difficulty of mineral development and utilization,increasing costs of prospecting,and so on.According to successful experience of superficial and deep prospecting and considering also the discussion above,some suggestions are proposed for the prospecting of molybdenum deposits in the future.
基金supported by the National Natural Science Foundation(grant No.41202025,41302058)Funds on basic researches for central public welfare academic institutes(grant No.K1325 and YK1401)the China Geological Survey Project(Nos.1212011220369,1212010633903,12120114039601 and 12120114019401)
文摘China is rich in tin resources,and contains many types of tin deposits.Among the tin deposit types,the cassiterite-sulfide type,skarn type and quartz vein type occupy a large proportion of tin resources and reserves.From the aspect of exploitation and utilization,the most important types are cassiterite-sulfide type and quartz vein type.The cassiterite-sulfide type tin deposits are mainly located in Northern Guangxi and Eastern Yunnan,skarn type deposits are mainly distributed in the ore-concentration areas of South Hunan in Middle Nanling,and the quartz vein type tin deposits are mainly distributed in South China,such as Western Fujian,Middle Jiangxi,Northern Guangzhou and Southern Hunan.The most important metallogenic epoch for tin deposits is the Mesozoic era.The metallogenic geotectonic background is mainly continental environments after orogeny process,with strong tectonic changes,interlaced deep fracture and frequent magmatism.And the most distinctive feature is the well developed Mesozoic granites,which have a close relationship with tin mineralization.Based on the detailed study of the data from 873 tin deposits in China,this paper summarized the metallogenic regularity of tin deposits,classified 20 important metallogenic series of tin or tin-associated deposits,and inferred that the cassiterite-sulfide type,skarn type,quartz vein type and greisen type are the main prediction types of tin resources.Forty-four tin-mineralization belts were divided,among which,19 belts are the most important.In addition,a series of maps about tin metallogenic belts and tin metallogenic regularity were compiled,aiming to provide theoretical basis for potential estimation and prediction of tin mineral resources.
