Driven by the dual imperatives of global plastic pollution control and carbon neutrality,research on depolymerizable polymers has become a cutting-edge focus in polymer science.With the continuous emergence of innovat...Driven by the dual imperatives of global plastic pollution control and carbon neutrality,research on depolymerizable polymers has become a cutting-edge focus in polymer science.With the continuous emergence of innovative materials,strengthened policy support,and maturing industrial chains,these polymers are demonstrating transformative potential in critical sectors,such as environmental protection,healthcare,and industrial manufacturing,promising for reshaping the future landscape of the plastics industry.展开更多
Target is one of the essential parts in inertial confinement fusion(ICF)experiments.To ensure the symmetry and hydrodynamic stability in the implosion,there are stringent specifications for the target.Driven by the ne...Target is one of the essential parts in inertial confinement fusion(ICF)experiments.To ensure the symmetry and hydrodynamic stability in the implosion,there are stringent specifications for the target.Driven by the need to fabricate the target required by ICF experiments,a series of target fabrication techniques,including capsule fabrication techniques and the techniques of target characterization and assembly,are developed by the Research Center of Laser Fusion(RCLF),China Academy of Engineering Physics(CAEP).The capsule fabrication techniques for preparing polymer shells,glow discharge polymer(GDP)shells and hollow glass micro-sphere(HGM)are studied,and the techniques of target characterization and assembly are also investigated in this paper.Fundamental research about the target fabrication is also done to improve the quality of the target.Based on the development of target fabrication techniques,some kinds of target have been prepared and applied in the ICF experiments.展开更多
To combat the crisis of today's synthetic polymers arising from unsustainable production and disposal,it is essential for the synthetic polymer community to reshape the current polymer industry with sustainable po...To combat the crisis of today's synthetic polymers arising from unsustainable production and disposal,it is essential for the synthetic polymer community to reshape the current polymer industry with sustainable polymers.As an emerging class of sustainable polymers,the development of chemically depolymerizable polymers(CDPs),which can undergo closed-loop depolymerization/repolymerization cycles to reproduce virgin polymers without the loss of properties from recovered monomers,offers an ideal solution to preserve finite natural resources,provides a feasible solution to the end-of-life issue of polymer waste,and thereby establishes a circular materials economy.However,two grand key challenges have been encountered in the establishment of practically useful CDPs:how to balance polymerization and depolymerization ability and how to unify conflicted depolymerizability and physical properties.Accordingly,this critical review article presents our vision for summarizing feasible strategies to overcome the above two significant challenges and the design principles for constructing an ideal CDP by highlighting selected major progress made in this rapidly expanding field.展开更多
文摘Driven by the dual imperatives of global plastic pollution control and carbon neutrality,research on depolymerizable polymers has become a cutting-edge focus in polymer science.With the continuous emergence of innovative materials,strengthened policy support,and maturing industrial chains,these polymers are demonstrating transformative potential in critical sectors,such as environmental protection,healthcare,and industrial manufacturing,promising for reshaping the future landscape of the plastics industry.
文摘Target is one of the essential parts in inertial confinement fusion(ICF)experiments.To ensure the symmetry and hydrodynamic stability in the implosion,there are stringent specifications for the target.Driven by the need to fabricate the target required by ICF experiments,a series of target fabrication techniques,including capsule fabrication techniques and the techniques of target characterization and assembly,are developed by the Research Center of Laser Fusion(RCLF),China Academy of Engineering Physics(CAEP).The capsule fabrication techniques for preparing polymer shells,glow discharge polymer(GDP)shells and hollow glass micro-sphere(HGM)are studied,and the techniques of target characterization and assembly are also investigated in this paper.Fundamental research about the target fabrication is also done to improve the quality of the target.Based on the development of target fabrication techniques,some kinds of target have been prepared and applied in the ICF experiments.
基金the National Natural Science Foundation of China(22031005)the National Natural Science Foundation of China(22371089)+13 种基金the National Natural Science Foundation of China(22071016)the National Natural Science Foundation of China(22125101)the National Natural Science Foundation of China(22293062)the National Natural Science Foundation of China(52322304)the National Natural Science Foundation of China(U23A2083)the National Natural Science Foundation of China(22225104)the National Natural Science Foundation of China(21925107)the National Natural Science Foundation of China(22371194)the National Key R&D Program of China(2021YFA1501700)the National Key R&D Program of China(2021YFA1501600)the National Key R&D Program of China(2021YFB3801901)Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates(2023B1212060003)the National Science Foundation(DMR-2042494)CNPC Innovation Fund(2020D-5007-0406)。
文摘To combat the crisis of today's synthetic polymers arising from unsustainable production and disposal,it is essential for the synthetic polymer community to reshape the current polymer industry with sustainable polymers.As an emerging class of sustainable polymers,the development of chemically depolymerizable polymers(CDPs),which can undergo closed-loop depolymerization/repolymerization cycles to reproduce virgin polymers without the loss of properties from recovered monomers,offers an ideal solution to preserve finite natural resources,provides a feasible solution to the end-of-life issue of polymer waste,and thereby establishes a circular materials economy.However,two grand key challenges have been encountered in the establishment of practically useful CDPs:how to balance polymerization and depolymerization ability and how to unify conflicted depolymerizability and physical properties.Accordingly,this critical review article presents our vision for summarizing feasible strategies to overcome the above two significant challenges and the design principles for constructing an ideal CDP by highlighting selected major progress made in this rapidly expanding field.