Soil desiccation cracking is a prevalent natural phenomenon that poses significant geotechnical and geoenvironmental challenges.Cracks typically initiate at surface defects such as air bubbles,large aggregates,tiny pi...Soil desiccation cracking is a prevalent natural phenomenon that poses significant geotechnical and geoenvironmental challenges.Cracks typically initiate at surface defects such as air bubbles,large aggregates,tiny pits,or uneven surfaces,where localized stress concentrations are readily induced.This study conducted a series of laboratory desiccation tests on slurry samples to investigate the initiation and propagation of desiccation cracks in the presence of varying types and quantities of surface defects.Digital image correlation(DIC)technology was employed to monitor the strain and displacement fields on the soil surface during the desiccation process.The results reveal that strain and displacement data derived from DIC can precisely predict the initiation sites and propagation directions of desiccation cracks.In samples with internal defects,cracks predominantly propagate through the defect,whereas external defects tend to initiate cracks along their edges.In samples with multiple defects,Y-shaped crack patterns generally form initially,followed by T-shaped and straight cracks,driven by the evolving stress field.The dynamic interplay between crack formation and tensile stress redistribution governs the initiation and propagation of desiccation cracks.展开更多
Based on inspection data,the authors analyze and summarize the main types and distribution characteristics of tunnel structural defects.These defects are classified into three types:surface defects,internal defects,an...Based on inspection data,the authors analyze and summarize the main types and distribution characteristics of tunnel structural defects.These defects are classified into three types:surface defects,internal defects,and defects behind the structure.To address the need for rapid detection of different defect types,the current state of rapid detection technologies and equipment,both domestically and internationally,is systematically reviewed.The research reveals that surface defect detection technologies and equipment have developed rapidly in recent years.Notably,the integration of machine vision and laser scanning technologies have significantly improved detection efficiency and accuracy,achieving crack detection precision of up to 0.1 mm.However,the non-contact rapid detection of internal and behind-the-structure defects remains constrained by hardware limitations,with traditional detection remaining dominant.Nevertheless,phased array radar,ultrasonic,and acoustic vibration detection technologies have become research hotspots in recent years,offering promising directions for detecting these challenging defect types.Additionally,the application of multisensor fusion technology in rapid detection equipment has further enhanced detection capabilities.Devices such as cameras,3D laser scanners,infrared thermal imagers,and radar demonstrate significant advantages in rapid detection.Future research in tunnel inspection should prioritize breakthroughs in rapid detection technologies for internal and behind-the-structure defects.Efforts should also focus on developing multifunctional integrated detection vehicles that can simultaneously inspect both surface and internal structures.Furthermore,progress in fully automated,intelligent systems with precise defect identification and real-time reporting will be essential to significantly improve the efficiency and accuracy of tunnel inspection.展开更多
Achieving high-quality perovskite films without surface defects is regarded as a crucial target for the development of durable high-performance perovskite solar cells.Additive engineering is commonly employed to simul...Achieving high-quality perovskite films without surface defects is regarded as a crucial target for the development of durable high-performance perovskite solar cells.Additive engineering is commonly employed to simultaneously control the growth of perovskite crystals and passivate defects.Here,4-(trifluoromethyl)benzoic anhydride(4-TBA)composed of benzene rings functionalized with carbonyl and trifluoromethyl groups was used as an example additive to study the characteristics of additives used for producing high-quality perovskites and controlling their surface properties.The interaction between4-TBA and perovskite precursor materials was investigated using density functional theory(DFT)simulations.The electron-rich carbonyl group efficiently passivated the under-coordinated lead-ion defects.Additionally,hydrogen bonding between trifluoromethyl and organic cations prevents the generation of cation vacancies.Because of its intrinsic hydrophobicity,the trifluoromethyl group simultaneously improves the moisture and heat stability of the film.4-TBA serves as a universal modifier for various perovskite compositions.The power conversion efficiency(PCE)of inverted perovskite solar cells(PSCs)based on methylammonium(MA)with 4-TBA was improved from 16.15%to 19.28%.Similarly,the PCE of inverted PSCs based on a cesium formamidinium MA(CsFAMA)perovskite film increased from20.72%to 23.58%,upon addition of 4-TBA.Furthermore,the moisture and thermal stability of 4-TBAtreated films and devices was significantly enhanced,along with prolonged device performance.Our work provides guidance on selecting the structure and functional groups that are essential for surface defect passivation and the production of high-quality perovskites.展开更多
The rapid progress in the construction of heavy-haul and high-speed railways has led to a surge in rail defects and unforeseen failures.Addressing this issue necessitates the implementation of more sophisticated rail ...The rapid progress in the construction of heavy-haul and high-speed railways has led to a surge in rail defects and unforeseen failures.Addressing this issue necessitates the implementation of more sophisticated rail inspection methods,specifically involving real-time,precise detection,and assessment of rail defects.Current applications fail to address the evolving requirements,prompting the need for advancements.This paper provides a summary of various types of rail defects and outlines both traditional and innovative non-destructive inspection techniques,examining their fundamental features,benefits,drawbacks,and practical suitability for railway track inspection.It also explores potential enhancements to equipment and software.The comprehensive review draws upon pertinent international research and review papers.Furthermore,the paper introduces a fusion of inspection methods aimed at enhancing the overall reliability of defect detection.展开更多
Infectious bone defects represent a substantial challenge in clinical practice,necessitating the deployment of advanced therapeutic strategies.This study presents a treatment modality that merges a mild photothermal t...Infectious bone defects represent a substantial challenge in clinical practice,necessitating the deployment of advanced therapeutic strategies.This study presents a treatment modality that merges a mild photothermal therapy hydrogel with a pulsed drug delivery mechanism.The system is predicated on a hydrogel matrix that is thermally responsive,characteristic of bone defect sites,facilitating controlled and site-specific drug release.The cornerstone of this system is the incorporation of mild photothermal nanoparticles,which are activated within the temperature range of 40–43°C,thereby enhancing the precision and efficacy of drug delivery.Our findings demonstrate that the photothermal response significantly augments the localized delivery of therapeutic agents,mitigating systemic side effects and bolstering efficacy at the defect site.The synchronized pulsed release,cooperated with mild photothermal therapy,effectively addresses infection control,and promotes bone regeneration.This approach signifies a considerable advancement in the management of infectious bone defects,offering an effective and patient-centric alternative to traditional methods.Our research endeavors to extend its applicability to a wider spectrum of tissue regeneration scenarios,underscoring its transformative potential in the realm of regenerative medicine.展开更多
In integrated circuit(IC)manufacturing,fast,nondestructive,and precise detection of defects in patterned wafers,realized by bright-field microscopy,is one of the critical factors for ensuring the final performance and...In integrated circuit(IC)manufacturing,fast,nondestructive,and precise detection of defects in patterned wafers,realized by bright-field microscopy,is one of the critical factors for ensuring the final performance and yields of chips.With the critical dimensions of IC nanostructures continuing to shrink,directly imaging or classifying deep-subwavelength defects by bright-field microscopy is challenging due to the well-known diffraction barrier,the weak scattering effect,and the faint correlation between the scattering cross-section and the defect morphology.Herein,we propose an optical far-field inspection method based on the form-birefringence scattering imaging of the defective nanostructure,which can identify and classify various defects without requiring optical super-resolution.The technique is built upon the principle of breaking the optical form birefringence of the original periodic nanostructures by the defect perturbation under the anisotropic illumination modes,such as the orthogonally polarized plane waves,then combined with the high-order difference of far-field images.We validated the feasibility and effectiveness of the proposed method in detecting deep subwavelength defects through rigid vector imaging modeling and optical detection experiments of various defective nanostructures based on polarization microscopy.On this basis,an intelligent classification algorithm for typical patterned defects based on a dual-channel AlexNet neural network has been proposed,stabilizing the classification accuracy ofλ/16-sized defects with highly similar features at more than 90%.The strong classification capability of the two-channel network on typical patterned defects can be attributed to the high-order difference image and its transverse gradient being used as the network’s input,which highlights the polarization modulation difference between different patterned defects more significantly than conventional bright-field microscopy results.This work will provide a new but easy-to-operate method for detecting and classifying deep-subwavelength defects in patterned wafers or photomasks,which thus endows current online inspection equipment with more missions in advanced IC manufacturing.展开更多
To solve the problem of low detection accuracy for complex weld defects,the paper proposes a weld defects detection method based on improved YOLOv5s.To enhance the ability to focus on key information in feature maps,t...To solve the problem of low detection accuracy for complex weld defects,the paper proposes a weld defects detection method based on improved YOLOv5s.To enhance the ability to focus on key information in feature maps,the scSE attention mechanism is intro-duced into the backbone network of YOLOv5s.A Fusion-Block module and additional layers are added to the neck network of YOLOv5s to improve the effect of feature fusion,which is to meet the needs of complex object detection.To reduce the computation-al complexity of the model,the C3Ghost module is used to replace the CSP2_1 module in the neck network of YOLOv5s.The scSE-ASFF module is constructed and inserted between the neck network and the prediction end,which is to realize the fusion of features between the different layers.To address the issue of imbalanced sample quality in the dataset and improve the regression speed and accuracy of the loss function,the CIoU loss function in the YOLOv5s model is replaced with the Focal-EIoU loss function.Finally,ex-periments are conducted based on the collected weld defect dataset to verify the feasibility of the improved YOLOv5s for weld defects detection.The experimental results show that the precision and mAP of the improved YOLOv5s in detecting complex weld defects are as high as 83.4%and 76.1%,respectively,which are 2.5%and 7.6%higher than the traditional YOLOv5s model.The proposed weld defects detection method based on the improved YOLOv5s in this paper can effectively solve the problem of low weld defects detection accuracy.展开更多
A comprehensive understanding of the relevance between molecular structure and passivation ability to screen efficient modifiers is essential for enhancing the performance of perovskite solar cells(PSCs).Here,three si...A comprehensive understanding of the relevance between molecular structure and passivation ability to screen efficient modifiers is essential for enhancing the performance of perovskite solar cells(PSCs).Here,three similarπ-πstacking molecules namely benzophenone(BPN),diphenyl sulfone(DPS),and diphenyl sulfoxide(DPSO)are used as back-interface modifiers in carbon-based CsPbBr_(3)PSCs.After investigation,the results demonstrate the positive effect of the p-πconjugation characteristic inπ-πstacking molecules on maximizing their passivation ability.The p-πco njugation of DPSO enables a higher coordinative activity of oxygen atom in its S=O group than that in 0=S=O group of DPS and C=O group of BPN,which gives a superior passivation effect of DPSO on defects of perovskite films.The modification of DPSO also significantly improves the p-type behavior of perovskite films and the back-interfacial energetics matching,inducing an increase of hole extraction and a decrease of energy loss.Finally,the unencapsulated carbon-based CsPbBr_(3)PSCs with DPSO achieve a maximum power conversion efficiency of 10.60%and outstanding long-term stability in high-temperature,high-humidity(85℃,85%relative humidity)air environment.This work provides insights into the influence of the structure ofπ-πstacking molecules on their ability to improve the perovskite films quality and therefore the PSCs performance.展开更多
Phenanthrene(Phe)is one of the common polycyclic aromatic hydrocarbons in the environment,and recent studies show that it can cause cardiac developmental toxicity and immunotoxicity.However,it is still unknown whether...Phenanthrene(Phe)is one of the common polycyclic aromatic hydrocarbons in the environment,and recent studies show that it can cause cardiac developmental toxicity and immunotoxicity.However,it is still unknown whether it can affect the hematopoietic development in aquatic organisms.To address this question,zebrafish(Danio rerio)were chronically exposed to Phe at different concentrations.We found that Phe caused structural damage to the renal tubules in the kidney,induced malformed erythrocytes in peripheral blood,and decreased the proportion of myeloid cells in adult zebrafish,suggesting possible negative impacts that Phe posed to hematopoietic development.Then,using in situ hybridization technology,we found that Phe decreased the expression of primitive hematopoietic marker genes,specifically gata1 and pu.1,accompanied by an obstruction of primitive erythrocyte circulation.Furthermore,Phe impaired definitive hematopoiesis,increased aberrations of the transient hematopoietic site(PBI),and reduced the generation of hematopoietic stem cells,ultimately influencing the number of erythrocytes and myeloid cells.The findings suggested that Phe could induce hematopoietic toxicity in zebrafish embryos and pose unknown ecological risks.展开更多
As the global population ages,osteoporotic bone fractures leading to bone defects are increasingly becoming a significant challenge in the field of public health.Treating this disease faces many challenges,especially ...As the global population ages,osteoporotic bone fractures leading to bone defects are increasingly becoming a significant challenge in the field of public health.Treating this disease faces many challenges,especially in the context of an imbalance between osteoblast and osteoclast activities.Therefore,the development of new biomaterials has become the key.This article reviews various design strategies and their advantages and disadvantages for biomaterials aimed at osteoporotic bone defects.Overall,current research progress indicates that innovative design,functionalization,and targeting of materials can significantly enhance bone regeneration under osteoporotic conditions.By comprehensively considering biocompatibility,mechanical properties,and bioactivity,these biomaterials can be further optimized,offering a range of choices and strategies for the repair of osteoporotic bone defects.展开更多
Solar cell defects exhibit significant variations and multiple types,with some defect data being difficult to acquire or having small scales,posing challenges in terms of small sample and small target in defect detect...Solar cell defects exhibit significant variations and multiple types,with some defect data being difficult to acquire or having small scales,posing challenges in terms of small sample and small target in defect detection for solar cells.In order to address this issue,this paper proposes a multi-step approach for detecting the complex defects of solar cells.First,individual cell plates are extracted from electroluminescence images for block-by-block detection.Then,StyleGAN2-Ada is utilized for generative adversarial networks data augmentation to expand the number of defect samples in small sample defects.Finally,the fake dataset is combined with real dataset,and the improved YOLOv5 model is trained on this mixed dataset.Experimental results demonstrate that the proposed method achieves a superior performance in detecting the defects with small sample and small target,with the final recall rate reaching 99.7%,an increase of 3.9% compared with the unimproved model.Additionally,the precision and mean average precision are increased by 3.4% and 3.5%,respectively.Moreover,the experiments demonstrate that the improved network training on the mixed dataset can effectively enhance the detection performance of the model.The combination of these approaches significantly improves the network’s ability to detect solar cell defects.展开更多
The stability of perovskite solar cells(PSCs)is adversely affected by nonradiative recombination resulting from buried interface defects.Herein,we synthesize a polyionic liquid,poly(p-vinylbenzyl trimethylam-monium he...The stability of perovskite solar cells(PSCs)is adversely affected by nonradiative recombination resulting from buried interface defects.Herein,we synthesize a polyionic liquid,poly(p-vinylbenzyl trimethylam-monium hexafluorophosphate)(PTA),and introduce it into the buried interface of PSCs.The quaternary ammonium cation(N(-CH_(3))^(3+))in PTA can fill the vacancies of organic cations within the perovskite structure and reduce shallow energy level defects.Additionally,the hexafluorophosphate(PF6−)in PTA forms a Lewis acid-base interaction with Pb^(2+)in the perovskite layer,effectively passivating deep en-ergy level defects.Furthermore,hydrogen bonding can be established between organic cations and the PF6−anion,preventing the formation of shallow energy level defects.Through this synergistic mecha-nism,the deep and shallow energy level defects are effectively mitigated,resulting in improved device performance.As a result,the resulting treated inverted PSC exhibits an impressive power conversion ef-ficiency(PCE)of 24.72%.Notably,the PTA-treated PSCs exhibit remarkable stability,with 88.5%of the original PCE retained after undergoing heat aging at 85℃ for 1078 h,and 89.1%of the initial PCE main-tained following continuous exposure to light for 1100 h at the maximum power point.Synergistically suppressing multiple defects at the buried interface through the use of polyionic liquids is a promising way to improve the commercial viability of PSCs.展开更多
The impact of casting defects on the weldability of K4951 superalloy was investigated using tungsten inert gas(TIG)welding.The as-cast K4951 superalloy samples with prefabricated U-shaped grooves of varying depths and...The impact of casting defects on the weldability of K4951 superalloy was investigated using tungsten inert gas(TIG)welding.The as-cast K4951 superalloy samples with prefabricated U-shaped grooves of varying depths and widths were TIG welded,and the microstructures,cracks morphology,and precipitated phases were analyzed using optical microscope,scanning electron microscope,transmission electron microscope,and energy dispersive X-ray spectrometer.The results reveal that the dimensions of casting defects significantly affect the weldability of K4951.Deep defects(greater than 2 mm)lead to rapid crack propagation,while wider defects can moderate the propagation process of cracks.Elemental segregation and the formation of precipitated phases,such as MC carbides,are observed in the fusion zone,contributing to welding cracks.An optimal groove aspect ratio(depth-to-width)between 0.2 and 0.5 minimizes crack formation tendency and enhances tensile strength,resulting in a mixed brittle-ductile fracture mode of joint after high-temperature tensile testing.展开更多
The accuracy and reliability of non-destructive testing(NDT)approaches in detecting interior corrosion problems are critical,yet research in this field is limited.This work describes a novel way to monitor the structu...The accuracy and reliability of non-destructive testing(NDT)approaches in detecting interior corrosion problems are critical,yet research in this field is limited.This work describes a novel way to monitor the structural integrity of steel gas pipelines that uses advanced numerical modeling techniques to anticipate fracture development and corrosion effects.The objective is to increase pipeline dependability and safety through more precise,real-time health evaluations.Compared to previous approaches,our solution provides higher accuracy in fault detection and quantification,making it ideal for pipeline integritymonitoring in real-world applications.To solve this issue,statistical analysis was conducted on the size and directional distribution features of about 380,000 sets of internal corrosion faults,as well as simulations of erosion and wear patterns on bent pipes.Using real defectmorphologies,we developed a modeling framework for typical interior corrosion flaws.We evaluated and validated the applicability and effectiveness of in-service inspection processes,as well as conducted on-site comparison tests.The results show that(1)the length and width of corrosion defects follow a log-normal distribution,the clock orientation follows a normal distribution,and the peak depth follows a Freundlich EX function distribution pattern;(2)pipeline corrosion defect data can be classified into three classes using the K-means clustering algorithm,allowing rapid and convenient acquisition of typical size and orientation characteristics of internal corrosion defects;(3)the applicability range and boundary conditions of various NDT techniques were verified,establishing comprehensive selection principles for internal corrosion defect detection technology;(4)on-site inspection results showed a 31%The simulation and validation platform for typical interior corrosion issues greatly enhances the accuracy and reliability of detection data.展开更多
Transition-metal perovskite oxides,ABO_(3±δ),are promising alternatives to precious metal catalysts for water splitting due to their tunable structures and defect engineering potential.However,polycrystalline pe...Transition-metal perovskite oxides,ABO_(3±δ),are promising alternatives to precious metal catalysts for water splitting due to their tunable structures and defect engineering potential.However,polycrystalline perovskites often show variations in composition and surface structure,complicating the identification of their underlying structure-activity relationship.In this work,we propose a surface ion-exchange strategy that finely tunes anionic and cationic defects on the surface of single-crystal BaNiO_(3),while maintaining its bulk structure and introducing surface Ni-Fe pairs.Through in situ characterization,we reveal that surface defects and Ni-Fe pairs enhance OH^(-)adsorption at both oxygen vacancies and Ni/Fe sites,facilitating a synergistic adsorbate evolution mechanism and lattice oxygen mechanism.Notably,the unique surface structure enables the faster deprotonation of intermediates and oxygen evolution reaction(OER).Thanks to the optimized surface configuration and OER mechanism,the catalyst shows excellent water oxidation performance in both rotating disk electrode and membrane electrode assembly tests.展开更多
The advancement of aqueous magnesium ion energy storage devices encounters limitations due to the substantial hydration radius of magnesium ions(Mg^(2+))and their strong electrostatic interaction with the primary mate...The advancement of aqueous magnesium ion energy storage devices encounters limitations due to the substantial hydration radius of magnesium ions(Mg^(2+))and their strong electrostatic interaction with the primary material.Consequently,this study successfully developed a MnS/MnO heterostructure through a straightforward hydrothermal and annealing method,marking its initial application in aqueous magnesium ion capacitors(AMICs).The fabricated MnS/MnO heterostructure,characterized by S defects,also generates Mn defects via in-situ initiation of early electrochemical processes.This unique dual ion defects MnS/MnO heterostructure(DID-MnS/MnO)enables the transformation of MnS and MnO,initially not highly active electrochemically for Mg^(2+),into cathode materials exhibiting high electrochemical activity and superior performance.Moreover,DID-MnS/MnO enhances conductivity,improves the kinetics of surface redox reactions,and increases the diffusion rate of Mg^(2+).Furthermore,this study introduces a dual energy storage mechanism for DID-MnS/MnO,which,in conjunction with dual ion defects,offers additional active sites for Mg^(2+)insertion/deinsertion in the host material,mitigating volume expansion and structural degradation during repeated charge-discharge cycles,thereby significantly enhancing cycling reversibility.As anticipated,using a three-electrode system,the developed DID-MnS/MnO demonstrated a discharge specific capacity of 237.9 mAh/g at a current density of 0.1 A/g.Remarkably,the constructed AMIC maintained a capacity retention rate of 94.3%after 10000 cycles at a current density of 1.0 A/g,with a specific capacitance of 165.7 F/g.Hence,DID-MnS/MnO offers insightful perspectives for designing alternative clean energy sources and is expected to contribute significantly to the advancement of the clean energy sector.展开更多
Mechano luminescence(ML),which involves the emission of light under mechanical stimuli,shows great potential in various applications such as sensing,imaging,and energy harvesting.Current research suggests that the lum...Mechano luminescence(ML),which involves the emission of light under mechanical stimuli,shows great potential in various applications such as sensing,imaging,and energy harvesting.Current research suggests that the luminescence mechanism of ML is typically connected to specific defects present within the material.In this study,we focus on the investigation of ML defects in Pr^(3+)-doped NaNbO_(3)/LiNbO_(3)heterojunctions,employing a combination of experimental and theoretical approaches.Through experimental analysis,we confirmed the presence of the heterojunction and its influence on ML intensity,and the optimal doping ratio for the heterojunction in ML was established.Furthermore,we examined the influence of varying Pr^(3+)doping concentrations on ML behavior and a proof-of-concept was demonstrated using the X-rays charged heterostructural phosphor as a stress sensor for biological applications.The position and concentration of internal defects in the ML material were scrutinized through thermo luminescence tests employing the variable heating rate method and positron annihilation.Complementing the experimental findings,theoretical simulations were conducted to elucidate the underlying mechanisms responsible for the observed ML defects.Density functional theory calculations were employed to investigate the energy levels,charge transfer processes,and lattice distortions within the heterojunctions under mechanical stress.Theoretical predictions were compared and validated against the experimental results.The integration of experimental and theoretical approaches provides a comprehensive understanding of the ML behavior of Pr^(3+)-doped NaNbO_(3)/LiNbO_(3)heterojunctions.The insights gained from this research contribute to the development of novel ML materials and pave the way for their applications in next-generation sensing and energy conversion devices.展开更多
The features of optical defects in a chemical vapor deposition (CVD) synthetic type Ⅱ a diamond were characterized using photoluminescence (PL) spectroscopy, before and after electron irradiation. The sample was cut ...The features of optical defects in a chemical vapor deposition (CVD) synthetic type Ⅱ a diamond were characterized using photoluminescence (PL) spectroscopy, before and after electron irradiation. The sample was cut within a {100} growth layer, and irradiated with 2 MeV electrons along the <100> axis. PL spectra of sample were collected under 532 nm and 355 nm laser excitation, at room temperature and 77 K, and linear scanning analysis along incident depth was applied to determine the distribution of defects. The pre-irradiation characterization results revealed uniformly distributed PL centers at 389 nm, 469 nm, 533 nm, 575 nm (ZPL of NV 0), 637 nm (ZPL of NV -), and 736.7/737.1 nm (ZPL doublet of SiV -). After irradiation, the differential responses of these as-grown defects were observed, alongside the emergence of irradiation-induced defects, namely 489 nm center, H3 center (ZPL at 504 nm) and GR1 center (ZPL at 741 nm). The maximum penetration depth of 2 MeV electron-irradiation induced defects was determined to be 2.1 mm. This work primarily presents the depth profiles of both as-grown and irradiation-induced defects in 2 MeV electrons irradiated diamond. The result provides experimental data for better understanding of the radiation effect in diamonds. Serving as a reference for diamond enhancement by electron irradiation.展开更多
Solution-processed Cu(In,Ga)Se_(2)(CIGS) solar cells suffer from serious carrier recombination and power conversion efficiency(PCE) loss because of the poor film properties and easy formation of defects.Herein, we pro...Solution-processed Cu(In,Ga)Se_(2)(CIGS) solar cells suffer from serious carrier recombination and power conversion efficiency(PCE) loss because of the poor film properties and easy formation of defects.Herein, we propose Ag&Se co-selenization strategy to enhance the crystallization and passivate harmful defects of the CIGS films. The formation of Ag-Se phase during the selenization process enables the formation of large grains and suppresses the deep level defects. It is found that Ag doping can enlarge the depletion region width, lower the Urbach energy and prolong the carrier lifetime. As a result, a champion solution-processed CIGS solar cell presents a high efficiency of 16.48% with the highly improved opencircuit voltage(VOC) of 662 m V and fill factor(FF) of 75.8%. This work provides an efficient strategy to prepare high quality solution-processed CIGS films for high-performance CIGS solar cells.展开更多
While early transition metal-based materials,such as MXene,has emerged as an efficient catalyst for the Mg-based hydrogen storage materials,their strong interaction with hydrogen resulted in the high hydrogen diffusio...While early transition metal-based materials,such as MXene,has emerged as an efficient catalyst for the Mg-based hydrogen storage materials,their strong interaction with hydrogen resulted in the high hydrogen diffusion barrier,hindering further improvement of catalytic activity.A MXene is characterized by rich anionic groups on its surface,significantly affecting electronic and catalytic functionalities.Using Nb_(2)CT_(x)as an example,we herein illustrate the critical role of anionic T_(x)defects on controlling hydrogen dissociation and diffusion processes in Mg-based hydrogen storage materials.The hydrogen desorption properties of MgH_(2)can be significantly enhanced by utilizing T_(x)controllable Nb_(2)CT_(x),and it can release 3.57 wt.%hydrogen within 10 min under 240℃with the reduced dehydrogenation activation barrier.It also realized stable de/hydrogenation reactions for at least 50 cycles.DFT studies combined with kinetic analysis revealed that the catalyst‒hydrogen interaction could be systematically controlled by optimizing surface T_(x)defect density,accelerating the hydrogen dissociation and diffusion processes at the same time.These results demonstrate that the T_(x)defects serve as the effective catalytically active centers of Nb_(2)CT_(x),offering a flexible catalyst design guideline.展开更多
基金supported by the National Natural Science Foundation of China(Grant Nos.42525201,42230710,42407521).
文摘Soil desiccation cracking is a prevalent natural phenomenon that poses significant geotechnical and geoenvironmental challenges.Cracks typically initiate at surface defects such as air bubbles,large aggregates,tiny pits,or uneven surfaces,where localized stress concentrations are readily induced.This study conducted a series of laboratory desiccation tests on slurry samples to investigate the initiation and propagation of desiccation cracks in the presence of varying types and quantities of surface defects.Digital image correlation(DIC)technology was employed to monitor the strain and displacement fields on the soil surface during the desiccation process.The results reveal that strain and displacement data derived from DIC can precisely predict the initiation sites and propagation directions of desiccation cracks.In samples with internal defects,cracks predominantly propagate through the defect,whereas external defects tend to initiate cracks along their edges.In samples with multiple defects,Y-shaped crack patterns generally form initially,followed by T-shaped and straight cracks,driven by the evolving stress field.The dynamic interplay between crack formation and tensile stress redistribution governs the initiation and propagation of desiccation cracks.
文摘Based on inspection data,the authors analyze and summarize the main types and distribution characteristics of tunnel structural defects.These defects are classified into three types:surface defects,internal defects,and defects behind the structure.To address the need for rapid detection of different defect types,the current state of rapid detection technologies and equipment,both domestically and internationally,is systematically reviewed.The research reveals that surface defect detection technologies and equipment have developed rapidly in recent years.Notably,the integration of machine vision and laser scanning technologies have significantly improved detection efficiency and accuracy,achieving crack detection precision of up to 0.1 mm.However,the non-contact rapid detection of internal and behind-the-structure defects remains constrained by hardware limitations,with traditional detection remaining dominant.Nevertheless,phased array radar,ultrasonic,and acoustic vibration detection technologies have become research hotspots in recent years,offering promising directions for detecting these challenging defect types.Additionally,the application of multisensor fusion technology in rapid detection equipment has further enhanced detection capabilities.Devices such as cameras,3D laser scanners,infrared thermal imagers,and radar demonstrate significant advantages in rapid detection.Future research in tunnel inspection should prioritize breakthroughs in rapid detection technologies for internal and behind-the-structure defects.Efforts should also focus on developing multifunctional integrated detection vehicles that can simultaneously inspect both surface and internal structures.Furthermore,progress in fully automated,intelligent systems with precise defect identification and real-time reporting will be essential to significantly improve the efficiency and accuracy of tunnel inspection.
基金supported by a Research Grant of Pukyong National University(2023)。
文摘Achieving high-quality perovskite films without surface defects is regarded as a crucial target for the development of durable high-performance perovskite solar cells.Additive engineering is commonly employed to simultaneously control the growth of perovskite crystals and passivate defects.Here,4-(trifluoromethyl)benzoic anhydride(4-TBA)composed of benzene rings functionalized with carbonyl and trifluoromethyl groups was used as an example additive to study the characteristics of additives used for producing high-quality perovskites and controlling their surface properties.The interaction between4-TBA and perovskite precursor materials was investigated using density functional theory(DFT)simulations.The electron-rich carbonyl group efficiently passivated the under-coordinated lead-ion defects.Additionally,hydrogen bonding between trifluoromethyl and organic cations prevents the generation of cation vacancies.Because of its intrinsic hydrophobicity,the trifluoromethyl group simultaneously improves the moisture and heat stability of the film.4-TBA serves as a universal modifier for various perovskite compositions.The power conversion efficiency(PCE)of inverted perovskite solar cells(PSCs)based on methylammonium(MA)with 4-TBA was improved from 16.15%to 19.28%.Similarly,the PCE of inverted PSCs based on a cesium formamidinium MA(CsFAMA)perovskite film increased from20.72%to 23.58%,upon addition of 4-TBA.Furthermore,the moisture and thermal stability of 4-TBAtreated films and devices was significantly enhanced,along with prolonged device performance.Our work provides guidance on selecting the structure and functional groups that are essential for surface defect passivation and the production of high-quality perovskites.
文摘The rapid progress in the construction of heavy-haul and high-speed railways has led to a surge in rail defects and unforeseen failures.Addressing this issue necessitates the implementation of more sophisticated rail inspection methods,specifically involving real-time,precise detection,and assessment of rail defects.Current applications fail to address the evolving requirements,prompting the need for advancements.This paper provides a summary of various types of rail defects and outlines both traditional and innovative non-destructive inspection techniques,examining their fundamental features,benefits,drawbacks,and practical suitability for railway track inspection.It also explores potential enhancements to equipment and software.The comprehensive review draws upon pertinent international research and review papers.Furthermore,the paper introduces a fusion of inspection methods aimed at enhancing the overall reliability of defect detection.
基金supported by the National Natural Science Foundation of China(32171354,82222015,82171001)The National Key Research and Development Program of China2023YFC2413600Research Funding from West China School/Hospital of Stomatology,Sichuan University(No.RCDWIS2023-1).
文摘Infectious bone defects represent a substantial challenge in clinical practice,necessitating the deployment of advanced therapeutic strategies.This study presents a treatment modality that merges a mild photothermal therapy hydrogel with a pulsed drug delivery mechanism.The system is predicated on a hydrogel matrix that is thermally responsive,characteristic of bone defect sites,facilitating controlled and site-specific drug release.The cornerstone of this system is the incorporation of mild photothermal nanoparticles,which are activated within the temperature range of 40–43°C,thereby enhancing the precision and efficacy of drug delivery.Our findings demonstrate that the photothermal response significantly augments the localized delivery of therapeutic agents,mitigating systemic side effects and bolstering efficacy at the defect site.The synchronized pulsed release,cooperated with mild photothermal therapy,effectively addresses infection control,and promotes bone regeneration.This approach signifies a considerable advancement in the management of infectious bone defects,offering an effective and patient-centric alternative to traditional methods.Our research endeavors to extend its applicability to a wider spectrum of tissue regeneration scenarios,underscoring its transformative potential in the realm of regenerative medicine.
基金funded by National Natural Science Foundation of China(Grant Nos.52130504,52305577,and 52175509)the Key Research and Development Plan of Hubei Province(Grant No.2022BAA013)+4 种基金the Major Program(JD)of Hubei Province(Grant No.2023BAA008-2)the Interdisciplinary Research Program of Huazhong University of Science and Technology(2023JCYJ047)the Innovation Project of Optics Valley Laboratory(Grant No.OVL2023PY003)the Postdoctoral Fellowship Program(Grade B)of China Postdoctoral Science Foundation(Grant No.GZB20230244)the fellowship from the China Postdoctoral Science Foundation(2024M750995)。
文摘In integrated circuit(IC)manufacturing,fast,nondestructive,and precise detection of defects in patterned wafers,realized by bright-field microscopy,is one of the critical factors for ensuring the final performance and yields of chips.With the critical dimensions of IC nanostructures continuing to shrink,directly imaging or classifying deep-subwavelength defects by bright-field microscopy is challenging due to the well-known diffraction barrier,the weak scattering effect,and the faint correlation between the scattering cross-section and the defect morphology.Herein,we propose an optical far-field inspection method based on the form-birefringence scattering imaging of the defective nanostructure,which can identify and classify various defects without requiring optical super-resolution.The technique is built upon the principle of breaking the optical form birefringence of the original periodic nanostructures by the defect perturbation under the anisotropic illumination modes,such as the orthogonally polarized plane waves,then combined with the high-order difference of far-field images.We validated the feasibility and effectiveness of the proposed method in detecting deep subwavelength defects through rigid vector imaging modeling and optical detection experiments of various defective nanostructures based on polarization microscopy.On this basis,an intelligent classification algorithm for typical patterned defects based on a dual-channel AlexNet neural network has been proposed,stabilizing the classification accuracy ofλ/16-sized defects with highly similar features at more than 90%.The strong classification capability of the two-channel network on typical patterned defects can be attributed to the high-order difference image and its transverse gradient being used as the network’s input,which highlights the polarization modulation difference between different patterned defects more significantly than conventional bright-field microscopy results.This work will provide a new but easy-to-operate method for detecting and classifying deep-subwavelength defects in patterned wafers or photomasks,which thus endows current online inspection equipment with more missions in advanced IC manufacturing.
基金supported by Postgraduate Research&Practice Innovation Program of Jiangsu Province(Grant No.KYCX24_4084).
文摘To solve the problem of low detection accuracy for complex weld defects,the paper proposes a weld defects detection method based on improved YOLOv5s.To enhance the ability to focus on key information in feature maps,the scSE attention mechanism is intro-duced into the backbone network of YOLOv5s.A Fusion-Block module and additional layers are added to the neck network of YOLOv5s to improve the effect of feature fusion,which is to meet the needs of complex object detection.To reduce the computation-al complexity of the model,the C3Ghost module is used to replace the CSP2_1 module in the neck network of YOLOv5s.The scSE-ASFF module is constructed and inserted between the neck network and the prediction end,which is to realize the fusion of features between the different layers.To address the issue of imbalanced sample quality in the dataset and improve the regression speed and accuracy of the loss function,the CIoU loss function in the YOLOv5s model is replaced with the Focal-EIoU loss function.Finally,ex-periments are conducted based on the collected weld defect dataset to verify the feasibility of the improved YOLOv5s for weld defects detection.The experimental results show that the precision and mAP of the improved YOLOv5s in detecting complex weld defects are as high as 83.4%and 76.1%,respectively,which are 2.5%and 7.6%higher than the traditional YOLOv5s model.The proposed weld defects detection method based on the improved YOLOv5s in this paper can effectively solve the problem of low weld defects detection accuracy.
基金financial supports from the Natural Science Foundation of Shandong Province(ZR2021ME037)the National Natural Science Foundation of China(52472259,22179051 and 61604143)+2 种基金the National Key Research and Development Program of China(2021YFE0111000)the Special Fund of Taishan Scholar Program of Shandong Province(tsqnz20221141)the Foundation of Key Laboratory of Advanced Technique&Preparation for Renewable Energy Materials,Ministry of Education,Yunnan Normal University(OF2022-02)。
文摘A comprehensive understanding of the relevance between molecular structure and passivation ability to screen efficient modifiers is essential for enhancing the performance of perovskite solar cells(PSCs).Here,three similarπ-πstacking molecules namely benzophenone(BPN),diphenyl sulfone(DPS),and diphenyl sulfoxide(DPSO)are used as back-interface modifiers in carbon-based CsPbBr_(3)PSCs.After investigation,the results demonstrate the positive effect of the p-πconjugation characteristic inπ-πstacking molecules on maximizing their passivation ability.The p-πco njugation of DPSO enables a higher coordinative activity of oxygen atom in its S=O group than that in 0=S=O group of DPS and C=O group of BPN,which gives a superior passivation effect of DPSO on defects of perovskite films.The modification of DPSO also significantly improves the p-type behavior of perovskite films and the back-interfacial energetics matching,inducing an increase of hole extraction and a decrease of energy loss.Finally,the unencapsulated carbon-based CsPbBr_(3)PSCs with DPSO achieve a maximum power conversion efficiency of 10.60%and outstanding long-term stability in high-temperature,high-humidity(85℃,85%relative humidity)air environment.This work provides insights into the influence of the structure ofπ-πstacking molecules on their ability to improve the perovskite films quality and therefore the PSCs performance.
基金supported by the National Natural Science Foundation of China(Nos.22276117 and 22076108)the Science and Technology Innovation Talent Team Project of Shanxi Province(No.202204051002024).
文摘Phenanthrene(Phe)is one of the common polycyclic aromatic hydrocarbons in the environment,and recent studies show that it can cause cardiac developmental toxicity and immunotoxicity.However,it is still unknown whether it can affect the hematopoietic development in aquatic organisms.To address this question,zebrafish(Danio rerio)were chronically exposed to Phe at different concentrations.We found that Phe caused structural damage to the renal tubules in the kidney,induced malformed erythrocytes in peripheral blood,and decreased the proportion of myeloid cells in adult zebrafish,suggesting possible negative impacts that Phe posed to hematopoietic development.Then,using in situ hybridization technology,we found that Phe decreased the expression of primitive hematopoietic marker genes,specifically gata1 and pu.1,accompanied by an obstruction of primitive erythrocyte circulation.Furthermore,Phe impaired definitive hematopoiesis,increased aberrations of the transient hematopoietic site(PBI),and reduced the generation of hematopoietic stem cells,ultimately influencing the number of erythrocytes and myeloid cells.The findings suggested that Phe could induce hematopoietic toxicity in zebrafish embryos and pose unknown ecological risks.
基金supported by the National Natural Science Foundation of China(Nos.82160419 and 82302772)Guizhou Basic Research Project(No.ZK[2023]General 201)。
文摘As the global population ages,osteoporotic bone fractures leading to bone defects are increasingly becoming a significant challenge in the field of public health.Treating this disease faces many challenges,especially in the context of an imbalance between osteoblast and osteoclast activities.Therefore,the development of new biomaterials has become the key.This article reviews various design strategies and their advantages and disadvantages for biomaterials aimed at osteoporotic bone defects.Overall,current research progress indicates that innovative design,functionalization,and targeting of materials can significantly enhance bone regeneration under osteoporotic conditions.By comprehensively considering biocompatibility,mechanical properties,and bioactivity,these biomaterials can be further optimized,offering a range of choices and strategies for the repair of osteoporotic bone defects.
文摘Solar cell defects exhibit significant variations and multiple types,with some defect data being difficult to acquire or having small scales,posing challenges in terms of small sample and small target in defect detection for solar cells.In order to address this issue,this paper proposes a multi-step approach for detecting the complex defects of solar cells.First,individual cell plates are extracted from electroluminescence images for block-by-block detection.Then,StyleGAN2-Ada is utilized for generative adversarial networks data augmentation to expand the number of defect samples in small sample defects.Finally,the fake dataset is combined with real dataset,and the improved YOLOv5 model is trained on this mixed dataset.Experimental results demonstrate that the proposed method achieves a superior performance in detecting the defects with small sample and small target,with the final recall rate reaching 99.7%,an increase of 3.9% compared with the unimproved model.Additionally,the precision and mean average precision are increased by 3.4% and 3.5%,respectively.Moreover,the experiments demonstrate that the improved network training on the mixed dataset can effectively enhance the detection performance of the model.The combination of these approaches significantly improves the network’s ability to detect solar cell defects.
基金supported by the Science,Technology,and Innovation Commission of Shenzhen Municipality(No.GJHZ20220913143204008)the Shccig-Qinling Program(No.SMYJY202300294C)+3 种基金National Natural Science Foundation of China(Nos.22261142666,52372225,52172237,22305191)the Shaanxi Science Fund for Distinguished Young Scholars(No.2022JC-21)the Research Fund of the State Key Laboratory of Solidification Processing(NPU)China(No.2021-QZ-02).
文摘The stability of perovskite solar cells(PSCs)is adversely affected by nonradiative recombination resulting from buried interface defects.Herein,we synthesize a polyionic liquid,poly(p-vinylbenzyl trimethylam-monium hexafluorophosphate)(PTA),and introduce it into the buried interface of PSCs.The quaternary ammonium cation(N(-CH_(3))^(3+))in PTA can fill the vacancies of organic cations within the perovskite structure and reduce shallow energy level defects.Additionally,the hexafluorophosphate(PF6−)in PTA forms a Lewis acid-base interaction with Pb^(2+)in the perovskite layer,effectively passivating deep en-ergy level defects.Furthermore,hydrogen bonding can be established between organic cations and the PF6−anion,preventing the formation of shallow energy level defects.Through this synergistic mecha-nism,the deep and shallow energy level defects are effectively mitigated,resulting in improved device performance.As a result,the resulting treated inverted PSC exhibits an impressive power conversion ef-ficiency(PCE)of 24.72%.Notably,the PTA-treated PSCs exhibit remarkable stability,with 88.5%of the original PCE retained after undergoing heat aging at 85℃ for 1078 h,and 89.1%of the initial PCE main-tained following continuous exposure to light for 1100 h at the maximum power point.Synergistically suppressing multiple defects at the buried interface through the use of polyionic liquids is a promising way to improve the commercial viability of PSCs.
基金National Natural Science Foundation of China(52201054,52175368)National Science and Technology Major Projects(J2019-VI-0018-0133)+2 种基金Liaoning Provincial Science and Technology Program(2023-BS-019,2023-MS-020)National Key R&D Program of China(2021YFB3700401)Key Specialized Research and Development Break-Through-Unveiling and Commanding the Special Project Program in Liaoning Province(2021JH15)。
文摘The impact of casting defects on the weldability of K4951 superalloy was investigated using tungsten inert gas(TIG)welding.The as-cast K4951 superalloy samples with prefabricated U-shaped grooves of varying depths and widths were TIG welded,and the microstructures,cracks morphology,and precipitated phases were analyzed using optical microscope,scanning electron microscope,transmission electron microscope,and energy dispersive X-ray spectrometer.The results reveal that the dimensions of casting defects significantly affect the weldability of K4951.Deep defects(greater than 2 mm)lead to rapid crack propagation,while wider defects can moderate the propagation process of cracks.Elemental segregation and the formation of precipitated phases,such as MC carbides,are observed in the fusion zone,contributing to welding cracks.An optimal groove aspect ratio(depth-to-width)between 0.2 and 0.5 minimizes crack formation tendency and enhances tensile strength,resulting in a mixed brittle-ductile fracture mode of joint after high-temperature tensile testing.
基金The“13th Five-Year Plan”National Science and Technology Major Project,2016ZX05052,Changchao QiThe China National Petroleum Corporation Science and Technology Project,2021DJ6505,Changchao Qi.
文摘The accuracy and reliability of non-destructive testing(NDT)approaches in detecting interior corrosion problems are critical,yet research in this field is limited.This work describes a novel way to monitor the structural integrity of steel gas pipelines that uses advanced numerical modeling techniques to anticipate fracture development and corrosion effects.The objective is to increase pipeline dependability and safety through more precise,real-time health evaluations.Compared to previous approaches,our solution provides higher accuracy in fault detection and quantification,making it ideal for pipeline integritymonitoring in real-world applications.To solve this issue,statistical analysis was conducted on the size and directional distribution features of about 380,000 sets of internal corrosion faults,as well as simulations of erosion and wear patterns on bent pipes.Using real defectmorphologies,we developed a modeling framework for typical interior corrosion flaws.We evaluated and validated the applicability and effectiveness of in-service inspection processes,as well as conducted on-site comparison tests.The results show that(1)the length and width of corrosion defects follow a log-normal distribution,the clock orientation follows a normal distribution,and the peak depth follows a Freundlich EX function distribution pattern;(2)pipeline corrosion defect data can be classified into three classes using the K-means clustering algorithm,allowing rapid and convenient acquisition of typical size and orientation characteristics of internal corrosion defects;(3)the applicability range and boundary conditions of various NDT techniques were verified,establishing comprehensive selection principles for internal corrosion defect detection technology;(4)on-site inspection results showed a 31%The simulation and validation platform for typical interior corrosion issues greatly enhances the accuracy and reliability of detection data.
基金supported by the National Natural Science Foundation of China(No.22278203)the Program for Jiangsu SpeciallyAppointed Professors(R2023T05)+1 种基金the Startup Foundation for Introducing Talent of NUIST(2024R078)the Natural Science Foundation of Jiangsu Province(BK20240707)。
文摘Transition-metal perovskite oxides,ABO_(3±δ),are promising alternatives to precious metal catalysts for water splitting due to their tunable structures and defect engineering potential.However,polycrystalline perovskites often show variations in composition and surface structure,complicating the identification of their underlying structure-activity relationship.In this work,we propose a surface ion-exchange strategy that finely tunes anionic and cationic defects on the surface of single-crystal BaNiO_(3),while maintaining its bulk structure and introducing surface Ni-Fe pairs.Through in situ characterization,we reveal that surface defects and Ni-Fe pairs enhance OH^(-)adsorption at both oxygen vacancies and Ni/Fe sites,facilitating a synergistic adsorbate evolution mechanism and lattice oxygen mechanism.Notably,the unique surface structure enables the faster deprotonation of intermediates and oxygen evolution reaction(OER).Thanks to the optimized surface configuration and OER mechanism,the catalyst shows excellent water oxidation performance in both rotating disk electrode and membrane electrode assembly tests.
基金supported by the National Natural Science Foundation of China(Nos.52071171,52202248)Liaoning BaiQianWan Talents Program(LNBQW2018B0048)+8 种基金Shenyang Science and Technology Project(21-108-9-04)Key Research Project of Department of Education of Liaoning Province(LJKZZ20220015)the Research Fund for the Doctoral Program of Liaoning Province(2022-BS-114)Chunhui Program of the Ministry of Education of the People’s Republic of China(202201135)Australian Research Council(ARC)through Future Fellowship(FT210100298,FT210100806)Discovery Project(DP220100603)Linkage Project(LP210100467,LP210200504,LP210200345,LP220100088)Industrial Transformation Training Centre(IC180100005)schemes,and the Australian Government through the Cooperative Research Centres Projects(CRCPXIII000077)the Australian Renewable Energy Agency(ARENA)as part of ARENA’s Transformative Research Accelerating Commercialisation Program(TM021).
文摘The advancement of aqueous magnesium ion energy storage devices encounters limitations due to the substantial hydration radius of magnesium ions(Mg^(2+))and their strong electrostatic interaction with the primary material.Consequently,this study successfully developed a MnS/MnO heterostructure through a straightforward hydrothermal and annealing method,marking its initial application in aqueous magnesium ion capacitors(AMICs).The fabricated MnS/MnO heterostructure,characterized by S defects,also generates Mn defects via in-situ initiation of early electrochemical processes.This unique dual ion defects MnS/MnO heterostructure(DID-MnS/MnO)enables the transformation of MnS and MnO,initially not highly active electrochemically for Mg^(2+),into cathode materials exhibiting high electrochemical activity and superior performance.Moreover,DID-MnS/MnO enhances conductivity,improves the kinetics of surface redox reactions,and increases the diffusion rate of Mg^(2+).Furthermore,this study introduces a dual energy storage mechanism for DID-MnS/MnO,which,in conjunction with dual ion defects,offers additional active sites for Mg^(2+)insertion/deinsertion in the host material,mitigating volume expansion and structural degradation during repeated charge-discharge cycles,thereby significantly enhancing cycling reversibility.As anticipated,using a three-electrode system,the developed DID-MnS/MnO demonstrated a discharge specific capacity of 237.9 mAh/g at a current density of 0.1 A/g.Remarkably,the constructed AMIC maintained a capacity retention rate of 94.3%after 10000 cycles at a current density of 1.0 A/g,with a specific capacitance of 165.7 F/g.Hence,DID-MnS/MnO offers insightful perspectives for designing alternative clean energy sources and is expected to contribute significantly to the advancement of the clean energy sector.
基金supported by the National Natural Science Foundation of China(52201008,52372003)Natural Science Foundation of Heilongjiang Province of China(ZD2023E004)+1 种基金Fundamental Research Funds for the Central Universities(3072020CF2515,3072022CFJ2504)the State Key Laboratory of Particle Detection and Electronics(SKLPDE-KF-202311)。
文摘Mechano luminescence(ML),which involves the emission of light under mechanical stimuli,shows great potential in various applications such as sensing,imaging,and energy harvesting.Current research suggests that the luminescence mechanism of ML is typically connected to specific defects present within the material.In this study,we focus on the investigation of ML defects in Pr^(3+)-doped NaNbO_(3)/LiNbO_(3)heterojunctions,employing a combination of experimental and theoretical approaches.Through experimental analysis,we confirmed the presence of the heterojunction and its influence on ML intensity,and the optimal doping ratio for the heterojunction in ML was established.Furthermore,we examined the influence of varying Pr^(3+)doping concentrations on ML behavior and a proof-of-concept was demonstrated using the X-rays charged heterostructural phosphor as a stress sensor for biological applications.The position and concentration of internal defects in the ML material were scrutinized through thermo luminescence tests employing the variable heating rate method and positron annihilation.Complementing the experimental findings,theoretical simulations were conducted to elucidate the underlying mechanisms responsible for the observed ML defects.Density functional theory calculations were employed to investigate the energy levels,charge transfer processes,and lattice distortions within the heterojunctions under mechanical stress.Theoretical predictions were compared and validated against the experimental results.The integration of experimental and theoretical approaches provides a comprehensive understanding of the ML behavior of Pr^(3+)-doped NaNbO_(3)/LiNbO_(3)heterojunctions.The insights gained from this research contribute to the development of novel ML materials and pave the way for their applications in next-generation sensing and energy conversion devices.
基金This work is supported by National Natural Science Foundation of China(No.42372054)。
文摘The features of optical defects in a chemical vapor deposition (CVD) synthetic type Ⅱ a diamond were characterized using photoluminescence (PL) spectroscopy, before and after electron irradiation. The sample was cut within a {100} growth layer, and irradiated with 2 MeV electrons along the <100> axis. PL spectra of sample were collected under 532 nm and 355 nm laser excitation, at room temperature and 77 K, and linear scanning analysis along incident depth was applied to determine the distribution of defects. The pre-irradiation characterization results revealed uniformly distributed PL centers at 389 nm, 469 nm, 533 nm, 575 nm (ZPL of NV 0), 637 nm (ZPL of NV -), and 736.7/737.1 nm (ZPL doublet of SiV -). After irradiation, the differential responses of these as-grown defects were observed, alongside the emergence of irradiation-induced defects, namely 489 nm center, H3 center (ZPL at 504 nm) and GR1 center (ZPL at 741 nm). The maximum penetration depth of 2 MeV electron-irradiation induced defects was determined to be 2.1 mm. This work primarily presents the depth profiles of both as-grown and irradiation-induced defects in 2 MeV electrons irradiated diamond. The result provides experimental data for better understanding of the radiation effect in diamonds. Serving as a reference for diamond enhancement by electron irradiation.
基金National Natural Science Foundation of China (62104061, 62074052, 61974173 and 52072327)。
文摘Solution-processed Cu(In,Ga)Se_(2)(CIGS) solar cells suffer from serious carrier recombination and power conversion efficiency(PCE) loss because of the poor film properties and easy formation of defects.Herein, we propose Ag&Se co-selenization strategy to enhance the crystallization and passivate harmful defects of the CIGS films. The formation of Ag-Se phase during the selenization process enables the formation of large grains and suppresses the deep level defects. It is found that Ag doping can enlarge the depletion region width, lower the Urbach energy and prolong the carrier lifetime. As a result, a champion solution-processed CIGS solar cell presents a high efficiency of 16.48% with the highly improved opencircuit voltage(VOC) of 662 m V and fill factor(FF) of 75.8%. This work provides an efficient strategy to prepare high quality solution-processed CIGS films for high-performance CIGS solar cells.
基金supported by Liuchuang Program of Chongqing Municipality(cx2022038)the Fundamental Research Funds for the Central Universities(2022CDJQY-013)the Graduate Research and Innovation Foundation of Chongqing,China(CYB22005).
文摘While early transition metal-based materials,such as MXene,has emerged as an efficient catalyst for the Mg-based hydrogen storage materials,their strong interaction with hydrogen resulted in the high hydrogen diffusion barrier,hindering further improvement of catalytic activity.A MXene is characterized by rich anionic groups on its surface,significantly affecting electronic and catalytic functionalities.Using Nb_(2)CT_(x)as an example,we herein illustrate the critical role of anionic T_(x)defects on controlling hydrogen dissociation and diffusion processes in Mg-based hydrogen storage materials.The hydrogen desorption properties of MgH_(2)can be significantly enhanced by utilizing T_(x)controllable Nb_(2)CT_(x),and it can release 3.57 wt.%hydrogen within 10 min under 240℃with the reduced dehydrogenation activation barrier.It also realized stable de/hydrogenation reactions for at least 50 cycles.DFT studies combined with kinetic analysis revealed that the catalyst‒hydrogen interaction could be systematically controlled by optimizing surface T_(x)defect density,accelerating the hydrogen dissociation and diffusion processes at the same time.These results demonstrate that the T_(x)defects serve as the effective catalytically active centers of Nb_(2)CT_(x),offering a flexible catalyst design guideline.
