Dynamic melt modification of polyethylene via the direct grafting of peroxide fragments shows promise for the development of processable functionalized materials.In this study,four linear low-density polyethylenes(LLD...Dynamic melt modification of polyethylene via the direct grafting of peroxide fragments shows promise for the development of processable functionalized materials.In this study,four linear low-density polyethylenes(LLDPEs)with comparable molecular weights but different short-chain branch(SCB)contents(ranging of 5-66 per 1000 carbon atoms)were modified via dynamic melt mixing using 2 wt% benzoyl peroxide at 145℃ and 50 r/min for 30 min.The influence of SCB content on the processability and structure of the resulting products was systematically investigated.All modified products exhibited good melt processability with melt flow rates(MFR)ranging from 0.46 g/10min to 1.07 g/10min.Products derived from low-SCB LLDPEs showed a lower MFR,higher cross-linking content,a larger number of long-chain branches,and a higher degree of benzoyl grafting.In contrast,those produced from high-SCB LLDPEs exhibited improved processability,reduced cross-linking,fewer long-chain branches,and lower benzoyl grafting levels.A detailed structural investigation of the soluble and insoluble fractions,which were separated using trichlorobenzene fractionation,was conducted to analyze the structural features of various modified products and demonstrate that the SCB content(i.e.,tertiary carbon density)significantly influences radical coupling during dynamic modification.Elevated tertiary carbon density,by introducing greater steric hindrance,suppresses radical coupling during dynamic modification,thereby reducing the efficiency of both crosslinking and peroxide fragment grafting.These findings provide new insights into the structure-reactivity relationships in peroxide-induced polyethylene modification and lay the foundation for tailoring material properties via dynamic processing.展开更多
During the hoisting process of the offshore substation,changes in the hoisting speed can affect the hoisting system.Therefore,this study set four different speed conditions for the lifting and lowering stages of the i...During the hoisting process of the offshore substation,changes in the hoisting speed can affect the hoisting system.Therefore,this study set four different speed conditions for the lifting and lowering stages of the installation process,and studied the impact of different lifting and lowering speeds on the hoisting system under the same environmental conditions through numerical simulation.The results show that during the lifting operation,as the lifting speed increases,the swing motion of the substation and the installation vessel tends to decrease,and the faster the hoisting speed,the more obvious the swing suppression of the substation and the installation vessel,and the smaller the fluctuation in the tension amplitude of the slings and mooring lines.In contrast,during the lowering operation,as the lowering speed increases,the swing motion of the substation and the installation vessel tends to increase,and the faster the lowering speed,the more obvious the swing amplification effect of the substation and the installation vessel.Therefore,during hoisting operations,increasing the lifting speed and reducing the lowering speed can mitigate the motion performance of the hoisting coupling system,reduce the tension amplitude variation of the sling and mooring,and ensure the smooth progress of the hoisting operation.展开更多
Strong long-wavelength laser pulses enable direct manipulation of atomic lattices for engineering novel quantum states in complex materials.Nonlinear coupling between two infrared-active phonon modes(TO_(1) and TO_(2)...Strong long-wavelength laser pulses enable direct manipulation of atomic lattices for engineering novel quantum states in complex materials.Nonlinear coupling between two infrared-active phonon modes(TO_(1) and TO_(2)),induced by intense terahertz light fields,significantly enhances the amplitude of the TO_(1) mode and facilitates ultrafast control of transient structural distortions.This light-induced distortion reduces the lattice thermal conductivity from 8.1 W·m^(-1)·K^(-1)to 3.0 W·m^(-1)·K^(-1).The reduction originates from the nonlinear coupling,which enhances anharmonic interactions in the lattice potential energy and substantially shortens the phonon lifetime(τ).This work demonstrates a strategy applicable to other perovskite materials and provides a framework for investigating light-induced electrical,optical,and thermodynamic phase transitions.展开更多
Data-driven process monitoring is an effective approach to assure safe operation of modern manufacturing and energy systems,such as thermal power plants being studied in this work.Industrial processes are inherently d...Data-driven process monitoring is an effective approach to assure safe operation of modern manufacturing and energy systems,such as thermal power plants being studied in this work.Industrial processes are inherently dynamic and need to be monitored using dynamic algorithms.Mainstream dynamic algorithms rely on concatenating current measurement with past data.This work proposes a new,alternative dynamic process monitoring algorithm,using dot product feature analysis(DPFA).DPFA computes the dot product of consecutive samples,thus naturally capturing the process dynamics through temporal correlation.At the same time,DPFA's online computational complexity is lower than not just existing dynamic algorithms,but also classical static algorithms(e.g.,principal component analysis and slow feature analysis).The detectability of the new algorithm is analyzed for three types of faults typically seen in process systems:sensor bias,process fault and gain change fault.Through experiments with a numerical example and real data from a thermal power plant,the DPFA algorithm is shown to be superior to the state-of-the-art methods,in terms of better monitoring performance(fault detection rate and false alarm rate)and lower computational complexity.展开更多
Under the paradigm of Industry 5.0,intelligent manufacturing transcends mere efficiency enhancement by emphasizing human-machine collaboration,where human expertise plays a central role in assembly processes.Despite a...Under the paradigm of Industry 5.0,intelligent manufacturing transcends mere efficiency enhancement by emphasizing human-machine collaboration,where human expertise plays a central role in assembly processes.Despite advancements in intelligent and digital technologies,assembly process design still heavily relies on manual knowledge reuse,and inefficiencies and inconsistent quality in process documentation are caused.To address the aforementioned issues,this paper proposes a knowledge push method of complex product assembly process design based on distillation model-based dynamically enhanced graph and Bayesian network.First,an initial knowledge graph is constructed using a BERT-BiLSTM-CRF model trained with integrated human expertise and a fine-tuned large language model.Then,a confidence-based dynamic weighted fusion strategy is employed to achieve dynamic incremental construction of the knowledge graph with low resource consumption.Subsequently,a Bayesian network model is constructed based on the relationships between assembly components,assembly features,and operations.Bayesian network reasoning is used to push assembly process knowledge under different design requirements.Finally,the feasibility of the Bayesian network construction method and the effectiveness of Bayesian network reasoning are verified through a specific example,significantly improving the utilization of assembly process knowledge and the efficiency of assembly process design.展开更多
The dynamic recrystallization（DRX） behavior of Ti-6Al-2Zr-1Mo-1V alloy was investigated at deformation temperature of 1000-1100 °C and strain rate of 10-3-1.0 s-1 by using compression test.The results show that...The dynamic recrystallization（DRX） behavior of Ti-6Al-2Zr-1Mo-1V alloy was investigated at deformation temperature of 1000-1100 °C and strain rate of 10-3-1.0 s-1 by using compression test.The results show that discontinuous dynamic recrystallization（DDRX） is the predominant recrystallization mechanism at temperature higher than 1050 °C and strain rate lower than 0.01 s-1.Meanwhile,continuous dynamic recrystallization is the main mechanism observed at temperature below 1050 °C and strain rate above 0.01 s-1,mixed with a few DDRX grains.In addition,decreasing strain rate and increasing deformation temperature are found to facilitate the progress of DRX and refinement of grains in the Ti alloy in β forging process.展开更多
The absorbing process in isolating and coating process of α-olefin drag reducing polymer was studied by molecular dynamic simulation method, on basis of coating theory of α-olefin drag reducing polymer particles wit...The absorbing process in isolating and coating process of α-olefin drag reducing polymer was studied by molecular dynamic simulation method, on basis of coating theory of α-olefin drag reducing polymer particles with polyurethane as coating material. The distributions of sodium laurate, sodium dodeeyl sulfate, and sodium dodeeyl benzene sulfonate on the surface of α-olefin drag reducing polymer particles were almost the same, but the bending degrees of them were obviously different. The bending degree of SLA molecules was greater than those of the other two surfactant molecules. Simulation results of absorbing and accumulating structure showed that, though hydrophobie properties of surfactant molecules were almost the same, water density around long chain sulfonate sodium was bigger than that around alkyl sulfate sodium. This property goes against useful absorbing and accumulating on the surface of α-olefin drag reducing polymer particles; simulation results of interactions of different surfactant and multiple hydroxyl compounds on surface of particles showed that, interactions of different surfaetant and one kind of multiple hydroxyl compound were similar to those of one kind of surfaetant and different multiple hydroxyl compounds. These two contrast types of interactions also exhibited the differences of absorbing distribution and closing degrees to surface of particles. The sequence of closing degrees was derived from simulation; control step of addition polymerization interaction in coating process was absorbing mass transfer process, so the more closed to surface of particle the multiple hydroxyl compounds were, the easier interactions With isoeyanate were. Simulation results represented the compatibility relationship between surfactant and multiple hydroxyl compounds. The isolating and coating processes of α-olefin drag reducing polymer were further understood on molecule and atom level through above simulation research, and based on the simulation, a referenced theoretical basis was provided for practical optimal selection and experimental preparation of α-olefin drag reducing polymer particles suspension isolation agent.展开更多
In the research of parachute, canopy inflation process modeling is one of the most complicated tasks. As canopy often experiences the largest deformations and loa-dings during a very short time, it is of great difficu...In the research of parachute, canopy inflation process modeling is one of the most complicated tasks. As canopy often experiences the largest deformations and loa-dings during a very short time, it is of great difficulty for theoretical analysis and experimental measurements. In this paper, aerodynamic equations and structural dynamics equations were developed for describing parachute opening process, and an iterative coupling solving strategy incorpo- rating the above equations was proposed for a small-scale, flexible and flat-circular parachute. Then, analyses were carried out for canopy geometry, time-dependent pressure difference between the inside and outside of the canopy, transient vortex around the canopy and the flow field in the radial plane as a sequence in opening process. The mechanism of the canopy shape development was explained from perspective of transient flow fields during the inflation process. Experiments of the parachute opening process were conducted in a wind tunnel, in which instantaneous shape of the canopy was measured by high velocity camera and the opening loading was measured by dynamometer balance. The theoretical predictions were found in good agreement with the experimental results, validating the proposed approach. This numerical method can improve the situation of strong dependence of parachute research on wind tunnel tests, and is of significance to the understanding of the mechanics of parachute inflation process.展开更多
One of the assumptions of previous research in evolutionary game dynamics is that individuals use only one rule to update their strategy. In reality, an individual's strategy update rules may change with the envir...One of the assumptions of previous research in evolutionary game dynamics is that individuals use only one rule to update their strategy. In reality, an individual's strategy update rules may change with the environment, and it is possible for an individual to use two or more rules to update their strategy. We consider the case where an individual updates strategies based on the Moran and imitation processes, and establish mixed stochastic evolutionary game dynamics by combining both processes. Our aim is to study how individuals change strategies based on two update rules and how this affects evolutionary game dynamics. We obtain an analytic expression and properties of the fixation probability and fixation times(the unconditional fixation time or conditional average fixation time) associated with our proposed process. We find unexpected results. The fixation probability within the proposed model is independent of the probabilities that the individual adopts the imitation rule update strategy. This implies that the fixation probability within the proposed model is equal to that from the Moran and imitation processes. The one-third rule holds in the proposed mixed model. However, under weak selection, the fixation times are different from those of the Moran and imitation processes because it is connected with the probability that individuals adopt an imitation update rule. Numerical examples are presented to illustrate the relationships between fixation times and the probability that an individual adopts the imitation update rule, as well as between fixation times and selection intensity. From the simulated analysis, we find that the fixation time for a mixed process is greater than that of the Moran process, but is less than that of the imitation process. Moreover, the fixation times for a cooperator in the proposed process increase as the probability of adopting an imitation update increases; however, the relationship becomes more complex than a linear relationship.展开更多
In this paper, a novel near-net-shape forming process, continuous semisolid extrusion process （CSEP） of AZ31 alloy was proposed, and the dynamical solidification behaviors and metal flow during the process were firs...In this paper, a novel near-net-shape forming process, continuous semisolid extrusion process （CSEP） of AZ31 alloy was proposed, and the dynamical solidification behaviors and metal flow during the process were firstly investigated. During casting AZ31 alloy by this process, non-uniform microstructure distributions and non- equilibrium solidification region near the roll surface were found in the roll-shoe gap. Microstructural evolution from dendrite to rosette and spherical grains was observed during the casting by CSEP. Casting temperature, roll-shoe gap width and cooling ability have great effect on casting process and metal flow, so these factors should be carefully controlled, a proper casting temperature of 710-750℃ is suggested. The white α phases were strongly stretched during the processing, and the remnant liquids are correspondingly distributes along the solid phase boundaries and also show stripped lines.展开更多
The western coast of Hainan Island exhibits a savanna landscape. Many types of sand dunes, including transverse dune ridges, longitudinal dune ridges, elliptical dunes, coppice dunes, and climbing dunes, are widely di...The western coast of Hainan Island exhibits a savanna landscape. Many types of sand dunes, including transverse dune ridges, longitudinal dune ridges, elliptical dunes, coppice dunes, and climbing dunes, are widely distributed in the coastal zone. In winter, high-frequency and high-energy NE winds （dominant winds） are prevalent, with a resultant drift direction （RDD） of S35.6°W. In spring, low-frequency and low-energy SW secondary winds prevail, with a RDD of N25.1°E. Wind tunnel simulations revealed that the airflow over the dune surface is the main factor controlling the erosion and deposition patterns of dune surfaces and the morphological development of dunes. In the region＇s bidirectional wind environment, with two seasonally distinct energy levels, the airflow over the surface of elliptical dunes, barchan dunes, and transverse dune ridges will exhibit a transverse pattern, whereas the airflow over longitudinal dunes ridges exhibits a lateral pattern and that over climbing dunes exhibits a climbing-circumfluent pattern. These patterns represent different dynamic processes. The coastal dunes on the western coast of Hainan Island are influenced by factors such as onshore winds, sand sources, coastal slopes, rivers, and forest shelter belts. The source of the sand that supplements these dunes particularly influences the development pattern： when there is more sand, the pattern shows positive equilibrium deposition between dune ridges and dunes; otherwise, it shows negative equilibrium deposition. The presence or absence of forest shelter belts also influences deposition and dune development patterns and transformation of dune forms. Coastal dunes and inland desert dunes experience similar dynamic processes, but the former have more diversified shapes and more complex formation mechanisms.展开更多
For critical engineering systems such as aircraft and aerospace vehicles, accurate Remaining Useful Life(RUL) prediction not only means cost saving, but more importantly, is of great significance in ensuring system re...For critical engineering systems such as aircraft and aerospace vehicles, accurate Remaining Useful Life(RUL) prediction not only means cost saving, but more importantly, is of great significance in ensuring system reliability and preventing disaster. RUL is affected not only by a system's intrinsic deterioration, but also by the operational conditions under which the system is operating. This paper proposes an RUL prediction approach to estimate the mean RUL of a continuously degrading system under dynamic operational conditions and subjected to condition monitoring at short equi-distant intervals. The dynamic nature of the operational conditions is described by a discrete-time Markov chain, and their influences on the degradation signal are quantified by degradation rates and signal jumps in the degradation model. The uniqueness of our proposed approach is formulating the RUL prediction problem in a semi-Markov decision process framework, by which the system mean RUL can be obtained through the solution to a limited number of equations. To extend the use of our proposed approach in real applications, different failure standards according to different operational conditions are also considered. The application and effectiveness of this approach are illustrated by a turbofan engine dataset and a comparison with existing results for the same dataset.展开更多
Abstract The Nansha ultra-crust layer-block is confined by ultra-crustal boundary faults of distinctive features, bordering the Kangtai-Shuangzi-Xiongnan extensional faulted zone on the north, the Baxian-Baram-Yoca-Cu...Abstract The Nansha ultra-crust layer-block is confined by ultra-crustal boundary faults of distinctive features, bordering the Kangtai-Shuangzi-Xiongnan extensional faulted zone on the north, the Baxian-Baram-Yoca-Cuyo nappe faulted zone on the south, the Wan'an-Natuna strike-slip tensional faulted zone on the west and the Mondoro-Panay strike-slip compressive faulted zone on the east. These faults take the top of the Nansha asthenosphere as their common detachmental surface. The Cenozoic dynamic process of the ultra-crust layer-block can be divided into four stages: K2-E21, during which the northern boundary faults extended, this ultra-crust layer-block was separated from the South China-Indosinian continental margin, the Palaeo-South China Sea subducted southwards and the Sibu accretion wedge was formed; E22-E31, during which the Southwest sub-sea basin extended and orogeny was active due to the collision of the Sibu accretion wedge; E32-N11, during which the central sub-sea basin extended, the Miri accretion wedge was formed and “A-type” subduction of the southern margin of the north Balawan occurred; N12-the present, during which large-scale thrusting and napping of the boundary faults in the south and mountain-building have taken place and the South China Sea stopped its extension.展开更多
Taking CPU time cost and analysis accuracy into account, dynamic explicit finite ele- ment method is adopted to optimize the forming process of autobody panels that often have large sizes and complex geometry. In this...Taking CPU time cost and analysis accuracy into account, dynamic explicit finite ele- ment method is adopted to optimize the forming process of autobody panels that often have large sizes and complex geometry. In this paper, for the sake of illustrating in detail how dynamic explicit finite element method is applied to the numerical simulation of the autobody panel forming process,an example of optimization of stamping process pain meters of an inner door panel is presented. Using dynamic explicit finite element code Ls-DYNA3D, the inner door panel has been optimized by adapting pa- rameters such as the initial blank geometry and position, blank-holder forces and the location of drawbeads, and satisfied results are obtained.展开更多
The determination of intrinsic deformation parameters inducing grain refinement mechanism of dynamic recrystallization (DRX) contributes to the relative forming process design. For Ni80A superalloy, the processing map...The determination of intrinsic deformation parameters inducing grain refinement mechanism of dynamic recrystallization (DRX) contributes to the relative forming process design. For Ni80A superalloy, the processing maps were constructed by the derivation of the stress-strain data coming from a series of isothermal compression tests at temperatures of 1273^-1473 K and strain rates of 0.01-10 s^-1. According to the processing maps and microstructural validation, the deformation parameter windows with DRX mechanism were separated in an innovative deformation mechanism map. In addition, the deformation activation energy representing deformation energy barrier was introduced to further optimize such windows. Finally, the enhanced processing maps were constructed and the parameter domains corresponding to DRX mechanism and lower deformation barrier were determined as follows: at ε=0.3, domains: 1296-1350 K, 0.056-0.32 s^-1 and 1350-1375 K, 0.035-0.11 s^-1;at ε=0.5, domains: 1290-1348 K, 0.2-0.5 s^-1 and 1305-1370 K, 0.035-0.2 s^-1;at ε=0.7, domains: 1290-1355 K, 0.042-0.26 s^-1;at ε=0.9, domains: 1298-1348 K, 0.037-0.224 s^-1.展开更多
The aim of this study was to develop a palatable donepezil(DP) orodispersible film(ODF)to facilitate the swallowing process and investigate the effect of cyclodextrin on tastemasking based on dynamic process and in vi...The aim of this study was to develop a palatable donepezil(DP) orodispersible film(ODF)to facilitate the swallowing process and investigate the effect of cyclodextrin on tastemasking based on dynamic process and in vivo drug absorption. Complexation of DP with hydroxypropyl-β-cyclodextrin(HP-β-CD) was applied to mask the bitter taste then the prepared complexes were incorporated into ODF using solvent casting method. The tastemasking efficiency was evaluated by e-tongue; meanwhile the pharmacokinetic behavior of DP/HP-β-CD ODF was investigated by in vivo study. Results showed the optimized film was more palatable than donepezil hydrochloride(DH) film and was bioequivalent with DH. The molecular mechanism was revealed by phase solubility study, Fourier-transform infrared spectrometer(FT-IR), Differential scanning calorimeter(DSC), X-ray diffraction(XRD) and molecular modeling. Taste-masking was attributed to the formation of DP/HP-β-CD which was due to moderate interaction between DP and HP-β-CD. The stability of DP/HP-β-CD was decreased because of the acid environment in stomach, which facilitated the absorption of DP. These results extended our understanding about the application of cyclodextrin complexation and provided guidance for the design of ODF especially for drugs with disgusting taste.展开更多
A new meso-mechanical testing scheme based on SEM was developed to carry out the experiment of microfracturing process of rocks. The microfracturing process of the pre-crack marble sample on surrounding rock in the im...A new meso-mechanical testing scheme based on SEM was developed to carry out the experiment of microfracturing process of rocks. The microfracturing process of the pre-crack marble sample on surrounding rock in the immerged Long-big tunnel in Jinping Cascade II Hydropower Station under uniaxial compression was recorded by using the testing scheme. According to the stereology theory, the propagation and coalescent of cracks at meso-scale were quantitatively investigated with digital technology. Therefore, the basic geometric information of rock microcracks such as area, angle, length, width, perimeter, was obtained from binary images after segmentation. The failure mechanism of specimen under uniaxial compression with the quantitative information was studied from macro and microscopic point of view. The results show that the image of microfracturing process of the specimen can be observed and recorded digitally. During the damage of the specimen, the distribution of microcracks in the specimen is still subjected to exponential distribution with some microcracks concentrated in certain regions. Finally, the change law of the fractal dimension of the local element in marble sample under different external load conditions is obtained by means of the statistical calculation of the fractal dimension.展开更多
Among the geo-hazards caused by the great Wenchuan Earthquake, the rapid and long runout rockslide-debris flow is of primary concern due to the large volume of displaced material and the resultant catastrophic impacts...Among the geo-hazards caused by the great Wenchuan Earthquake, the rapid and long runout rockslide-debris flow is of primary concern due to the large volume of displaced material and the resultant catastrophic impacts to the landscape and socioeconomic structure. In order to analyze the dynamical process of this kind of geo-hazard, the Donghekou rockslide-debris flow is given as an example in this paper. This event, which killed 780 people, initiated at an elevation of 1300 m with a total long run-out distance of more than 2400 m. The slide mass is mainly composed of dolomite limestone and siliceous limestone of Sinian system, together with carbon slate and phyllite of Cambrian. During the processes from slide initiation to the final cessation of slide movement, five dynamic stages took place, here identified as the initiation stage, the acceleration of movement stage, the air-blast effect stage, the impact and redirection stage and the long runout slidematerial accumulation stage. Field investigations indicate that due to the effects of the earthquake, the dynamics of the Donghekou rockslide-debris flow are apparently controlled by geologic and tectonic conditions, the local geomorphological aspects of the terrain, and the microstructural and macroscopic mechanical properties of rocks which compose the slide mass. These three main factors which dictate the Donghekou rockslide-debris flow dynamics are discussed in detail in this paper, and significant results of field investigations and tests of materials are presented. The above dynamical processes are analyzed in this paper, and some useful conclusions have been gained.展开更多
The dynamic recrystallization behavior of 25CrMo4 steel was systematically investigated by compression deformation at different temperatures and strain rates on a Gleeble 1500 thermal mechanical simulation tester. The...The dynamic recrystallization behavior of 25CrMo4 steel was systematically investigated by compression deformation at different temperatures and strain rates on a Gleeble 1500 thermal mechanical simulation tester. The flow curves under different deformation conditions were obtained, and the effects of deformation temperature and strain rate on the appearance of the flow curves were discussed. Based on the experimental flow curves, the activation energy determined by regression analysis was Q = 337 kJ/mol, and the constitutive model was constructed. All the characteristic points of the flow curves were identified from the work hardening rate curves （θ= dσ/dε vs σ）, which were derived from the flow curves. Then, the kinetics model of dynamic recrystallization was determined by combining the Avrami equation with the stress loss resulted from the dynamic recrystallization. With the aid of the kinetics model, the effect of strain on the efficiency of power dissipation was discussed. Furthermore, the optimum parameters for the forging process were determined based on the processing maps.展开更多
The solutions of dynamic optimization problems are usually very difficult due to their highly nonlinear and multidimensional nature. 13enetic algorithm （GA） has been proved to be a teasibte method when the gradient ...The solutions of dynamic optimization problems are usually very difficult due to their highly nonlinear and multidimensional nature. 13enetic algorithm （GA） has been proved to be a teasibte method when the gradient is difficult to calculate. Its advantage is that the control profiles at all time stages are optimized simultaneously, but its convergence is very slow in the later period of evolution and it is easily trapped in the local optimum. In this study, a hybrid improved genetic algorithm （HIGA） for solving dynamic optimization problems is proposed to overcome these defects. Simplex method （SM） is used to perform the local search in the neighborhood of the optimal solution. By using SM, the ideal searching direction of global optimal solution could be found as soon as possible and the convergence speed of the algorithm is improved. The hybrid algorithm presents some improvements, such as protecting the best individual, accepting immigrations, as well as employing adaptive crossover and Ganssian mutation operators. The efficiency of the proposed algorithm is demonstrated by solving several dynamic optimization problems. At last, HIGA is applied to the optimal production of secreted protein in a fed batch reactor and the optimal feed-rate found by HIGA is effective and relatively stable.展开更多
基金financially supported by the Science and Technology Project of PetroChina Company Limited,China(No.2022DJ6314)the National Natural Science Foundation of China(No.52173056)。
文摘Dynamic melt modification of polyethylene via the direct grafting of peroxide fragments shows promise for the development of processable functionalized materials.In this study,four linear low-density polyethylenes(LLDPEs)with comparable molecular weights but different short-chain branch(SCB)contents(ranging of 5-66 per 1000 carbon atoms)were modified via dynamic melt mixing using 2 wt% benzoyl peroxide at 145℃ and 50 r/min for 30 min.The influence of SCB content on the processability and structure of the resulting products was systematically investigated.All modified products exhibited good melt processability with melt flow rates(MFR)ranging from 0.46 g/10min to 1.07 g/10min.Products derived from low-SCB LLDPEs showed a lower MFR,higher cross-linking content,a larger number of long-chain branches,and a higher degree of benzoyl grafting.In contrast,those produced from high-SCB LLDPEs exhibited improved processability,reduced cross-linking,fewer long-chain branches,and lower benzoyl grafting levels.A detailed structural investigation of the soluble and insoluble fractions,which were separated using trichlorobenzene fractionation,was conducted to analyze the structural features of various modified products and demonstrate that the SCB content(i.e.,tertiary carbon density)significantly influences radical coupling during dynamic modification.Elevated tertiary carbon density,by introducing greater steric hindrance,suppresses radical coupling during dynamic modification,thereby reducing the efficiency of both crosslinking and peroxide fragment grafting.These findings provide new insights into the structure-reactivity relationships in peroxide-induced polyethylene modification and lay the foundation for tailoring material properties via dynamic processing.
基金support from the National Natural Science Foundation of China(No.52271287)funding from the State Key Laboratory of Hydraulic Engineering Intelligent Construction and Operation,Tianjin University。
文摘During the hoisting process of the offshore substation,changes in the hoisting speed can affect the hoisting system.Therefore,this study set four different speed conditions for the lifting and lowering stages of the installation process,and studied the impact of different lifting and lowering speeds on the hoisting system under the same environmental conditions through numerical simulation.The results show that during the lifting operation,as the lifting speed increases,the swing motion of the substation and the installation vessel tends to decrease,and the faster the hoisting speed,the more obvious the swing suppression of the substation and the installation vessel,and the smaller the fluctuation in the tension amplitude of the slings and mooring lines.In contrast,during the lowering operation,as the lowering speed increases,the swing motion of the substation and the installation vessel tends to increase,and the faster the lowering speed,the more obvious the swing amplification effect of the substation and the installation vessel.Therefore,during hoisting operations,increasing the lifting speed and reducing the lowering speed can mitigate the motion performance of the hoisting coupling system,reduce the tension amplitude variation of the sling and mooring,and ensure the smooth progress of the hoisting operation.
基金Project supported by the National Key Research and Development Program of China(Grant No.2024YFF0508503)。
文摘Strong long-wavelength laser pulses enable direct manipulation of atomic lattices for engineering novel quantum states in complex materials.Nonlinear coupling between two infrared-active phonon modes(TO_(1) and TO_(2)),induced by intense terahertz light fields,significantly enhances the amplitude of the TO_(1) mode and facilitates ultrafast control of transient structural distortions.This light-induced distortion reduces the lattice thermal conductivity from 8.1 W·m^(-1)·K^(-1)to 3.0 W·m^(-1)·K^(-1).The reduction originates from the nonlinear coupling,which enhances anharmonic interactions in the lattice potential energy and substantially shortens the phonon lifetime(τ).This work demonstrates a strategy applicable to other perovskite materials and provides a framework for investigating light-induced electrical,optical,and thermodynamic phase transitions.
基金supported in part by the National Science Fund for Distinguished Young Scholars of China(62225303)the National Natural Science Fundation of China(62303039,62433004)+2 种基金the China Postdoctoral Science Foundation(BX20230034,2023M730190)the Fundamental Research Funds for the Central Universities(buctrc202201,QNTD2023-01)the High Performance Computing Platform,College of Information Science and Technology,Beijing University of Chemical Technology
文摘Data-driven process monitoring is an effective approach to assure safe operation of modern manufacturing and energy systems,such as thermal power plants being studied in this work.Industrial processes are inherently dynamic and need to be monitored using dynamic algorithms.Mainstream dynamic algorithms rely on concatenating current measurement with past data.This work proposes a new,alternative dynamic process monitoring algorithm,using dot product feature analysis(DPFA).DPFA computes the dot product of consecutive samples,thus naturally capturing the process dynamics through temporal correlation.At the same time,DPFA's online computational complexity is lower than not just existing dynamic algorithms,but also classical static algorithms(e.g.,principal component analysis and slow feature analysis).The detectability of the new algorithm is analyzed for three types of faults typically seen in process systems:sensor bias,process fault and gain change fault.Through experiments with a numerical example and real data from a thermal power plant,the DPFA algorithm is shown to be superior to the state-of-the-art methods,in terms of better monitoring performance(fault detection rate and false alarm rate)and lower computational complexity.
基金Supported by National Key Research and Development Program(Grant No.2024YFB3312700)National Natural Science Foundation of China(Grant No.52405541)the Changzhou Municipal Sci&Tech Program(Grant No.CJ20241131)。
文摘Under the paradigm of Industry 5.0,intelligent manufacturing transcends mere efficiency enhancement by emphasizing human-machine collaboration,where human expertise plays a central role in assembly processes.Despite advancements in intelligent and digital technologies,assembly process design still heavily relies on manual knowledge reuse,and inefficiencies and inconsistent quality in process documentation are caused.To address the aforementioned issues,this paper proposes a knowledge push method of complex product assembly process design based on distillation model-based dynamically enhanced graph and Bayesian network.First,an initial knowledge graph is constructed using a BERT-BiLSTM-CRF model trained with integrated human expertise and a fine-tuned large language model.Then,a confidence-based dynamic weighted fusion strategy is employed to achieve dynamic incremental construction of the knowledge graph with low resource consumption.Subsequently,a Bayesian network model is constructed based on the relationships between assembly components,assembly features,and operations.Bayesian network reasoning is used to push assembly process knowledge under different design requirements.Finally,the feasibility of the Bayesian network construction method and the effectiveness of Bayesian network reasoning are verified through a specific example,significantly improving the utilization of assembly process knowledge and the efficiency of assembly process design.
基金Project (2007CB613803) supported by the National Basic Research Program of ChinaProject (2010GQC0170) supported by the Natural Science Foundation of Jiangxi Province,ChinaProject (GJJ11159) supported by the Educational Committee of Jiangxi Province,China
文摘The dynamic recrystallization（DRX） behavior of Ti-6Al-2Zr-1Mo-1V alloy was investigated at deformation temperature of 1000-1100 °C and strain rate of 10-3-1.0 s-1 by using compression test.The results show that discontinuous dynamic recrystallization（DDRX） is the predominant recrystallization mechanism at temperature higher than 1050 °C and strain rate lower than 0.01 s-1.Meanwhile,continuous dynamic recrystallization is the main mechanism observed at temperature below 1050 °C and strain rate above 0.01 s-1,mixed with a few DDRX grains.In addition,decreasing strain rate and increasing deformation temperature are found to facilitate the progress of DRX and refinement of grains in the Ti alloy in β forging process.
文摘The absorbing process in isolating and coating process of α-olefin drag reducing polymer was studied by molecular dynamic simulation method, on basis of coating theory of α-olefin drag reducing polymer particles with polyurethane as coating material. The distributions of sodium laurate, sodium dodeeyl sulfate, and sodium dodeeyl benzene sulfonate on the surface of α-olefin drag reducing polymer particles were almost the same, but the bending degrees of them were obviously different. The bending degree of SLA molecules was greater than those of the other two surfactant molecules. Simulation results of absorbing and accumulating structure showed that, though hydrophobie properties of surfactant molecules were almost the same, water density around long chain sulfonate sodium was bigger than that around alkyl sulfate sodium. This property goes against useful absorbing and accumulating on the surface of α-olefin drag reducing polymer particles; simulation results of interactions of different surfactant and multiple hydroxyl compounds on surface of particles showed that, interactions of different surfaetant and one kind of multiple hydroxyl compound were similar to those of one kind of surfaetant and different multiple hydroxyl compounds. These two contrast types of interactions also exhibited the differences of absorbing distribution and closing degrees to surface of particles. The sequence of closing degrees was derived from simulation; control step of addition polymerization interaction in coating process was absorbing mass transfer process, so the more closed to surface of particle the multiple hydroxyl compounds were, the easier interactions With isoeyanate were. Simulation results represented the compatibility relationship between surfactant and multiple hydroxyl compounds. The isolating and coating processes of α-olefin drag reducing polymer were further understood on molecule and atom level through above simulation research, and based on the simulation, a referenced theoretical basis was provided for practical optimal selection and experimental preparation of α-olefin drag reducing polymer particles suspension isolation agent.
基金the National Natural Science Foundation of China(10377006).
文摘In the research of parachute, canopy inflation process modeling is one of the most complicated tasks. As canopy often experiences the largest deformations and loa-dings during a very short time, it is of great difficulty for theoretical analysis and experimental measurements. In this paper, aerodynamic equations and structural dynamics equations were developed for describing parachute opening process, and an iterative coupling solving strategy incorpo- rating the above equations was proposed for a small-scale, flexible and flat-circular parachute. Then, analyses were carried out for canopy geometry, time-dependent pressure difference between the inside and outside of the canopy, transient vortex around the canopy and the flow field in the radial plane as a sequence in opening process. The mechanism of the canopy shape development was explained from perspective of transient flow fields during the inflation process. Experiments of the parachute opening process were conducted in a wind tunnel, in which instantaneous shape of the canopy was measured by high velocity camera and the opening loading was measured by dynamometer balance. The theoretical predictions were found in good agreement with the experimental results, validating the proposed approach. This numerical method can improve the situation of strong dependence of parachute research on wind tunnel tests, and is of significance to the understanding of the mechanics of parachute inflation process.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.71871171,71871173,and 71832010)
文摘One of the assumptions of previous research in evolutionary game dynamics is that individuals use only one rule to update their strategy. In reality, an individual's strategy update rules may change with the environment, and it is possible for an individual to use two or more rules to update their strategy. We consider the case where an individual updates strategies based on the Moran and imitation processes, and establish mixed stochastic evolutionary game dynamics by combining both processes. Our aim is to study how individuals change strategies based on two update rules and how this affects evolutionary game dynamics. We obtain an analytic expression and properties of the fixation probability and fixation times(the unconditional fixation time or conditional average fixation time) associated with our proposed process. We find unexpected results. The fixation probability within the proposed model is independent of the probabilities that the individual adopts the imitation rule update strategy. This implies that the fixation probability within the proposed model is equal to that from the Moran and imitation processes. The one-third rule holds in the proposed mixed model. However, under weak selection, the fixation times are different from those of the Moran and imitation processes because it is connected with the probability that individuals adopt an imitation update rule. Numerical examples are presented to illustrate the relationships between fixation times and the probability that an individual adopts the imitation update rule, as well as between fixation times and selection intensity. From the simulated analysis, we find that the fixation time for a mixed process is greater than that of the Moran process, but is less than that of the imitation process. Moreover, the fixation times for a cooperator in the proposed process increase as the probability of adopting an imitation update increases; however, the relationship becomes more complex than a linear relationship.
基金supports from National High-Tech R&D Program of China (GrantNo. 2007AA03Z111)Natural Science Foundation of China (Grant No. 50604007)the Program for New Century Excellent Talents in University (Grant No.NCET-06-0285 and NCET-08-0097)
文摘In this paper, a novel near-net-shape forming process, continuous semisolid extrusion process （CSEP） of AZ31 alloy was proposed, and the dynamical solidification behaviors and metal flow during the process were firstly investigated. During casting AZ31 alloy by this process, non-uniform microstructure distributions and non- equilibrium solidification region near the roll surface were found in the roll-shoe gap. Microstructural evolution from dendrite to rosette and spherical grains was observed during the casting by CSEP. Casting temperature, roll-shoe gap width and cooling ability have great effect on casting process and metal flow, so these factors should be carefully controlled, a proper casting temperature of 710-750℃ is suggested. The white α phases were strongly stretched during the processing, and the remnant liquids are correspondingly distributes along the solid phase boundaries and also show stripped lines.
基金National Natural Science Foundation of China, No.40671186 No.40271012
文摘The western coast of Hainan Island exhibits a savanna landscape. Many types of sand dunes, including transverse dune ridges, longitudinal dune ridges, elliptical dunes, coppice dunes, and climbing dunes, are widely distributed in the coastal zone. In winter, high-frequency and high-energy NE winds （dominant winds） are prevalent, with a resultant drift direction （RDD） of S35.6°W. In spring, low-frequency and low-energy SW secondary winds prevail, with a RDD of N25.1°E. Wind tunnel simulations revealed that the airflow over the dune surface is the main factor controlling the erosion and deposition patterns of dune surfaces and the morphological development of dunes. In the region＇s bidirectional wind environment, with two seasonally distinct energy levels, the airflow over the surface of elliptical dunes, barchan dunes, and transverse dune ridges will exhibit a transverse pattern, whereas the airflow over longitudinal dunes ridges exhibits a lateral pattern and that over climbing dunes exhibits a climbing-circumfluent pattern. These patterns represent different dynamic processes. The coastal dunes on the western coast of Hainan Island are influenced by factors such as onshore winds, sand sources, coastal slopes, rivers, and forest shelter belts. The source of the sand that supplements these dunes particularly influences the development pattern： when there is more sand, the pattern shows positive equilibrium deposition between dune ridges and dunes; otherwise, it shows negative equilibrium deposition. The presence or absence of forest shelter belts also influences deposition and dune development patterns and transformation of dune forms. Coastal dunes and inland desert dunes experience similar dynamic processes, but the former have more diversified shapes and more complex formation mechanisms.
基金the National Natural science Foundation of China (No. 71701008) for supporting this research
文摘For critical engineering systems such as aircraft and aerospace vehicles, accurate Remaining Useful Life(RUL) prediction not only means cost saving, but more importantly, is of great significance in ensuring system reliability and preventing disaster. RUL is affected not only by a system's intrinsic deterioration, but also by the operational conditions under which the system is operating. This paper proposes an RUL prediction approach to estimate the mean RUL of a continuously degrading system under dynamic operational conditions and subjected to condition monitoring at short equi-distant intervals. The dynamic nature of the operational conditions is described by a discrete-time Markov chain, and their influences on the degradation signal are quantified by degradation rates and signal jumps in the degradation model. The uniqueness of our proposed approach is formulating the RUL prediction problem in a semi-Markov decision process framework, by which the system mean RUL can be obtained through the solution to a limited number of equations. To extend the use of our proposed approach in real applications, different failure standards according to different operational conditions are also considered. The application and effectiveness of this approach are illustrated by a turbofan engine dataset and a comparison with existing results for the same dataset.
文摘Abstract The Nansha ultra-crust layer-block is confined by ultra-crustal boundary faults of distinctive features, bordering the Kangtai-Shuangzi-Xiongnan extensional faulted zone on the north, the Baxian-Baram-Yoca-Cuyo nappe faulted zone on the south, the Wan'an-Natuna strike-slip tensional faulted zone on the west and the Mondoro-Panay strike-slip compressive faulted zone on the east. These faults take the top of the Nansha asthenosphere as their common detachmental surface. The Cenozoic dynamic process of the ultra-crust layer-block can be divided into four stages: K2-E21, during which the northern boundary faults extended, this ultra-crust layer-block was separated from the South China-Indosinian continental margin, the Palaeo-South China Sea subducted southwards and the Sibu accretion wedge was formed; E22-E31, during which the Southwest sub-sea basin extended and orogeny was active due to the collision of the Sibu accretion wedge; E32-N11, during which the central sub-sea basin extended, the Miri accretion wedge was formed and “A-type” subduction of the southern margin of the north Balawan occurred; N12-the present, during which large-scale thrusting and napping of the boundary faults in the south and mountain-building have taken place and the South China Sea stopped its extension.
文摘Taking CPU time cost and analysis accuracy into account, dynamic explicit finite ele- ment method is adopted to optimize the forming process of autobody panels that often have large sizes and complex geometry. In this paper, for the sake of illustrating in detail how dynamic explicit finite element method is applied to the numerical simulation of the autobody panel forming process,an example of optimization of stamping process pain meters of an inner door panel is presented. Using dynamic explicit finite element code Ls-DYNA3D, the inner door panel has been optimized by adapting pa- rameters such as the initial blank geometry and position, blank-holder forces and the location of drawbeads, and satisfied results are obtained.
基金Project(cstc2018jcyj AX0459)supported by Chongqing Basic Research and Frontier Exploration,ChinaProject(P2017-020)supported by Open Fund Project of State Key Laboratory of Materials Processing and Die&Mould Technology,ChinaProject(SKLMTZZKT-2017M15)supported by Research Project of State Key Laboratory of Mechanical Transmission,China
文摘The determination of intrinsic deformation parameters inducing grain refinement mechanism of dynamic recrystallization (DRX) contributes to the relative forming process design. For Ni80A superalloy, the processing maps were constructed by the derivation of the stress-strain data coming from a series of isothermal compression tests at temperatures of 1273^-1473 K and strain rates of 0.01-10 s^-1. According to the processing maps and microstructural validation, the deformation parameter windows with DRX mechanism were separated in an innovative deformation mechanism map. In addition, the deformation activation energy representing deformation energy barrier was introduced to further optimize such windows. Finally, the enhanced processing maps were constructed and the parameter domains corresponding to DRX mechanism and lower deformation barrier were determined as follows: at ε=0.3, domains: 1296-1350 K, 0.056-0.32 s^-1 and 1350-1375 K, 0.035-0.11 s^-1;at ε=0.5, domains: 1290-1348 K, 0.2-0.5 s^-1 and 1305-1370 K, 0.035-0.2 s^-1;at ε=0.7, domains: 1290-1355 K, 0.042-0.26 s^-1;at ε=0.9, domains: 1298-1348 K, 0.037-0.224 s^-1.
文摘The aim of this study was to develop a palatable donepezil(DP) orodispersible film(ODF)to facilitate the swallowing process and investigate the effect of cyclodextrin on tastemasking based on dynamic process and in vivo drug absorption. Complexation of DP with hydroxypropyl-β-cyclodextrin(HP-β-CD) was applied to mask the bitter taste then the prepared complexes were incorporated into ODF using solvent casting method. The tastemasking efficiency was evaluated by e-tongue; meanwhile the pharmacokinetic behavior of DP/HP-β-CD ODF was investigated by in vivo study. Results showed the optimized film was more palatable than donepezil hydrochloride(DH) film and was bioequivalent with DH. The molecular mechanism was revealed by phase solubility study, Fourier-transform infrared spectrometer(FT-IR), Differential scanning calorimeter(DSC), X-ray diffraction(XRD) and molecular modeling. Taste-masking was attributed to the formation of DP/HP-β-CD which was due to moderate interaction between DP and HP-β-CD. The stability of DP/HP-β-CD was decreased because of the acid environment in stomach, which facilitated the absorption of DP. These results extended our understanding about the application of cyclodextrin complexation and provided guidance for the design of ODF especially for drugs with disgusting taste.
基金Projects(50674040, 50539090) supported by the National Natural Science Foundation of ChinaProject(CX07B_128z) supported by the Cultivate Creative Postgraduate Foundation of Jiangsu Province, China
文摘A new meso-mechanical testing scheme based on SEM was developed to carry out the experiment of microfracturing process of rocks. The microfracturing process of the pre-crack marble sample on surrounding rock in the immerged Long-big tunnel in Jinping Cascade II Hydropower Station under uniaxial compression was recorded by using the testing scheme. According to the stereology theory, the propagation and coalescent of cracks at meso-scale were quantitatively investigated with digital technology. Therefore, the basic geometric information of rock microcracks such as area, angle, length, width, perimeter, was obtained from binary images after segmentation. The failure mechanism of specimen under uniaxial compression with the quantitative information was studied from macro and microscopic point of view. The results show that the image of microfracturing process of the specimen can be observed and recorded digitally. During the damage of the specimen, the distribution of microcracks in the specimen is still subjected to exponential distribution with some microcracks concentrated in certain regions. Finally, the change law of the fractal dimension of the local element in marble sample under different external load conditions is obtained by means of the statistical calculation of the fractal dimension.
基金supported by the National Natural Science Foundation of China (NSFC) (Grant No. 40802067)the National Basic Research Program of China (973 program, Grant No.2008CB425803)+1 种基金the Basic Scientific Research Operating Expenses of Institute of Geomechanics, CAGS (Grant No. DZLXJK200805)the Land and Natural Resources of China (Grant No. 1212010914025)
文摘Among the geo-hazards caused by the great Wenchuan Earthquake, the rapid and long runout rockslide-debris flow is of primary concern due to the large volume of displaced material and the resultant catastrophic impacts to the landscape and socioeconomic structure. In order to analyze the dynamical process of this kind of geo-hazard, the Donghekou rockslide-debris flow is given as an example in this paper. This event, which killed 780 people, initiated at an elevation of 1300 m with a total long run-out distance of more than 2400 m. The slide mass is mainly composed of dolomite limestone and siliceous limestone of Sinian system, together with carbon slate and phyllite of Cambrian. During the processes from slide initiation to the final cessation of slide movement, five dynamic stages took place, here identified as the initiation stage, the acceleration of movement stage, the air-blast effect stage, the impact and redirection stage and the long runout slidematerial accumulation stage. Field investigations indicate that due to the effects of the earthquake, the dynamics of the Donghekou rockslide-debris flow are apparently controlled by geologic and tectonic conditions, the local geomorphological aspects of the terrain, and the microstructural and macroscopic mechanical properties of rocks which compose the slide mass. These three main factors which dictate the Donghekou rockslide-debris flow dynamics are discussed in detail in this paper, and significant results of field investigations and tests of materials are presented. The above dynamical processes are analyzed in this paper, and some useful conclusions have been gained.
基金financially supported by the National Basic Research Program of China(No.2011CB012903)
文摘The dynamic recrystallization behavior of 25CrMo4 steel was systematically investigated by compression deformation at different temperatures and strain rates on a Gleeble 1500 thermal mechanical simulation tester. The flow curves under different deformation conditions were obtained, and the effects of deformation temperature and strain rate on the appearance of the flow curves were discussed. Based on the experimental flow curves, the activation energy determined by regression analysis was Q = 337 kJ/mol, and the constitutive model was constructed. All the characteristic points of the flow curves were identified from the work hardening rate curves （θ= dσ/dε vs σ）, which were derived from the flow curves. Then, the kinetics model of dynamic recrystallization was determined by combining the Avrami equation with the stress loss resulted from the dynamic recrystallization. With the aid of the kinetics model, the effect of strain on the efficiency of power dissipation was discussed. Furthermore, the optimum parameters for the forging process were determined based on the processing maps.
基金Supported by Major State Basic Research Development Program of China （2012CB720500）, National Natural Science Foundation of China （Key Program： Ul162202）, National Science Fund for Outstanding Young Scholars （61222303）, National Natural Science Foundation of China （21276078, 21206037） and the Fundamental Research Funds for the Central Universities.
文摘The solutions of dynamic optimization problems are usually very difficult due to their highly nonlinear and multidimensional nature. 13enetic algorithm （GA） has been proved to be a teasibte method when the gradient is difficult to calculate. Its advantage is that the control profiles at all time stages are optimized simultaneously, but its convergence is very slow in the later period of evolution and it is easily trapped in the local optimum. In this study, a hybrid improved genetic algorithm （HIGA） for solving dynamic optimization problems is proposed to overcome these defects. Simplex method （SM） is used to perform the local search in the neighborhood of the optimal solution. By using SM, the ideal searching direction of global optimal solution could be found as soon as possible and the convergence speed of the algorithm is improved. The hybrid algorithm presents some improvements, such as protecting the best individual, accepting immigrations, as well as employing adaptive crossover and Ganssian mutation operators. The efficiency of the proposed algorithm is demonstrated by solving several dynamic optimization problems. At last, HIGA is applied to the optimal production of secreted protein in a fed batch reactor and the optimal feed-rate found by HIGA is effective and relatively stable.
