On December 2, 2017, the 2nd Seminar on the Development Strategy of China＇s Oil and Gas Resources was held in Beijing. This seminar was hosted by the Strategic Research Center for Oil and Gas Resources, Ministry of L...On December 2, 2017, the 2nd Seminar on the Development Strategy of China＇s Oil and Gas Resources was held in Beijing. This seminar was hosted by the Strategic Research Center for Oil and Gas Resources, Ministry of Land （MLR） and Resources and sponsored by both the CNOOC Exploration Department and the School of Ocean and Earth Sciences of Tongji University. With the theme of ＂deepwater and deep-layer oil and gas resources and development strategy＂,展开更多
Deep and ultra-deep layers in the petroliferous basins of China are characterized by large temperature difference and complicated thermal evolution history.The control effects of temperature and thermal evolution hist...Deep and ultra-deep layers in the petroliferous basins of China are characterized by large temperature difference and complicated thermal evolution history.The control effects of temperature and thermal evolution history on the differences of hydrocarbon phase states and the hydrocarbon generation history in deep and ultra-deep layers are researched less and unsystematically.To deal with this situation,based on a large number of temperature and pressure data of deeplayers and combined with the complicated historical situation of deep layer evolution in the oil and gas basins of China,the effects of temperature,heating time and pressure on the hydrocarbon formation temperature and phase state were analyzed,and the types of temperature and pressure relationships were classified.Finally,based on the classification of thermal evolution history of deep and ultra-deep layers,We discussed the control effects of basin thermal evolution history on the hydrocarbon generation and phase state,and the following research results were obtained.First,the hydrocarbon phase states of deep layers in different basins and regions are greatly different,and they are mainly affected by temperature,heating time,heating rate,pressure,source rock types and other factors.And temperature is the most important factor controlling hydrocarbon generation and phase state distribution.Second,under the conditions of rapid temperature increasing and short heating time,there still maybe oil reservoirs and condensate gas reservoirs in deep and ultra-deep layersin thecase ofhigh temperature.Third,overpressureinhibitshydrocarbon generationand pyrolysis.Fourth,thereis a closerelationship betweentemperature and formation pressure of deeplayers,whichcan be divided into three types,i.e.,lowemedium temperature and high pressure type,high temperature and high pressure type,and medium temperature and lowemedium pressure type.Fifth,the thermal evolution history of deep and ultra-deep layers can be divided into four types,namely the late rapid subsidence,heating and low geothermal gradient type,the late rapid subsidence,heating and high geothermal gradient type,the middleelate rapid heating and late uplifting and cooling type,and the early great subsidence and rapid heating and middleelate great uplift erosion and cooling type.In conclusion,deep and ultra-deep layers in the basins with different types of thermal history are different in hydrocarbon phase states,accumulation stages and prospects.展开更多
The sand layer B of Dongying Formation of CFD oilfield in Bohai offshore belongs to the middle deep layer of buried hill overlap deposit. Its reservoir distribution has the characteristics of large burial depth, thin ...The sand layer B of Dongying Formation of CFD oilfield in Bohai offshore belongs to the middle deep layer of buried hill overlap deposit. Its reservoir distribution has the characteristics of large burial depth, thin thickness and rapidly lateral change. Because of low resolution of seismic data and overlying sand layer. It is difficult to identify and interpret the structure of sand layer accurately. The uncertainty of structure and reservoir restricts the fine development of B sand layer. In order to identify the top surface of reservoir effectively. The seismic data are processed by using the reflection coefficient inversion method. The results show that the inversion resolution of reflection coefficient is significantly higher than that of original data. The top surface of sand layer B and its overlying sand layer can be well identified and traced. Carrying out structural interpretation of B sand layer based on reflection coefficient inversion data and the microstructure and the formation tip extinction point are implemented. Based on the constraint of new interpretation level, the sedimentary facies plane distribution of B sand layer is described and make prediction of dominant reservoir development area in detail combining with sedimentary paleogeomorphology, along layer attribute section and limited drilling data. The research shows that the study area is mainly from the northwest material sources, the slope belt in the northwest is close to the lake shoreline with a gentle slope and shallow water depositional environment, which is located on the main transport and deposition channels. The shallow water gentle slope landform is suitable for forming large-area sand bar deposition, mainly composed of underwater distributary channel and debouch bars facies, which is the dominant reservoir development area. The research conclusion guides the deployment and implementation of the development well location effectively.展开更多
The mesopelagic communities are important for food web and carbon pump in ocean,but the large-scale studies of them are still limited until now because of the difficulties on sampling and analyzing of mesopelagic orga...The mesopelagic communities are important for food web and carbon pump in ocean,but the large-scale studies of them are still limited until now because of the difficulties on sampling and analyzing of mesopelagic organisms.Mesopelagic organisms,especially micronekton,can form acoustic deep scattering layers(DSLs)and DSLs are widely observed.To explore the spatial patterns of DSLs and their possible influencing factors,the DSLs during daytime(10:00–14:00)were investigated in the subtropical northwestern Pacific Ocean(13°–23.5°N,153°–163°E)using a shipboard acoustic Doppler current profiler at 38 kHz.The study area was divided into three parts using k-means cluster analysis:the northern part(NP,22°–24°N),the central part(CP,17°–22°N),and the southern part(SP,12°–17°N).The characteristics of DSLs varied widely with latitudinal gradient.Deepest core DSLs(523.5 m±17.4 m),largest nautical area scattering coefficient(NASC)(130.8 m^(2)/n mile^(2)±41.0 m^(2)/n mile^(2)),and most concentrated DSLs(mesopelagic organisms gathering level,6.7%±0.7%)were observed in NP.The proportion of migration was also stronger in NP(39.7%)than those in other parts(18.6%in CP and 21.5%in SP)for mesopelagic organisms.The latitudinal variation of DSLs was probably caused by changes in oxygen concentration and light intensity of mesopelagic zones.A positive relationship between NASC and primary productivity was identified.A four-months lag was seemed to exist.This study provides the first basin-scale baselines information of mesopelagic communities in the northwest Pacific with acoustic approach.Further researches are suggested to gain understandings of seasonal and annual variations of DSLs in the region.展开更多
In recent years,drilling data from wells Pengshen 10,Heshen 9,Tongshen 17 and Zhengyang 1 in the Sichuan Basin have confirmed the presence of a set of porous reef-beach limestone reservoirs in the Upper Permian Changx...In recent years,drilling data from wells Pengshen 10,Heshen 9,Tongshen 17 and Zhengyang 1 in the Sichuan Basin have confirmed the presence of a set of porous reef-beach limestone reservoirs in the Upper Permian Changxing Formation,which breaks the traditional view that deep carbonate oil and gas are only distributed in porous dolomite reservoirs and karst fracture-cavity limestone reservoirs.Through core and thin section observations,geochemical analysis,and well-seismic based reservoir identification and tracking,the study on formation mechanism of pores in deep reef-beach limestone reservoirs is carried out,this study provides insights in four aspects.(1)Porous reef-beach limestone reservoirs are developed in the Changxing Formation in deep-buried layers.The reservoir space is composed of intergranular pores,framework pores,intra-fossil pores,moldic pores and dissolution pores,which are formed in depositional and epigenetic environments.(2)The intermittently distributed porous reef-beach complexes are surrounded by relatively dense micrite limestone,which leads to the formation of local abnormal high-pressure inside the reef-beach complexes with the temperature increased.(3)The floor of the Changxing Formation reservoir is composed with interbedded tight mudstone and limestone of the Upper Permian Wujiaping Formation,and the roof is the tight micrite limestone interbedded with mudstone of the first member of Lower Triassic Feixianguan Formation.Under the clamping of dense roof and floor,the abnormal high-pressure in the Changxing Formation is formed.Abnormal high-pressure(overpressured compartment)is the key to maintain the pores formed in the depositional and epigenetic environments in deep-buried layers.(4)Based on the identification of roof,floor and reef-beach complexes,the favorable reef-beach limestone reservoir distribution area of 10.3×10^(4) km^(2) is predicted by well-seismic integration.These insights lay the theoretical foundation for the development of deep porous limestone reservoirs,expand the new field of exploration of deep-buried limestone reservoirs in the Sichuan Basin.展开更多
The aims of this study were to prepare novel transfersomes(TFs)for tacrolimus to treat atopic dermatitis,and to observe the therapeutic effects on mice atopic dermatitis,as compared to commercial tacrolimus ointment(P...The aims of this study were to prepare novel transfersomes(TFs)for tacrolimus to treat atopic dermatitis,and to observe the therapeutic effects on mice atopic dermatitis,as compared to commercial tacrolimus ointment(Protopic)and liposomes-gel.Different kinds of surfactantsdsodium cholate,Tween 80 and Span 80 were investigated to prepare TFs respectively.TFs-Tween 80 was selected as the optimal carrier owing to the best deformability and the highest drug retentions.Entrapment efficiency and diameter were also evaluated.The optimized TFs were further made into gel and in vitro drug release of TFs-gel after 24 h was higher than the commercial ointment.Cumulative drug release from TFs-gel after 12 h in vitro was 37.6%.The optimized TFs-gel illustrated remarkably highest drug skin retentions when compared with liposomes-gel and commercial ointment in vivo skin retention experiments.The amounts of tacrolimus in epidermis and dermis from TFsgel were 3.8 times and 4.2 times respectively as much as ointment,while liposomes-gel was only 1.7 times and 1.4 times respectively as compared to ointment.Topical application of TFs-gel displayed the best therapeutic effect on mice atopic dermatitis induced by repeated topical application of 2,4-dinitrofluorobenzene.Thus TFs displayed superior performance and effective skin target for topical delivery of tacrolimus.展开更多
Natural gas exploration in Nanpu sag, Bohai Bay Basin, has achieved breakthroughs in recent years, and a number of natural gas and condensate wells with high yield have been found in several structures in the beach ar...Natural gas exploration in Nanpu sag, Bohai Bay Basin, has achieved breakthroughs in recent years, and a number of natural gas and condensate wells with high yield have been found in several structures in the beach area. Daily gas production of single wells is up to 170,000 m3, and high-yield wells are mainly distributed in？the Nanpu No. 1 structural belt.？Studies have shown that these natural gases are mainly hydrocarbon gases, with methane content about 80% to 90% and ethane 6%-9%, so they are mainly wet gas; and non-hydrocarbons are at a low level.？Carbon isotopes of methane range from -42‰ to -36‰, and ethane from -28‰ to -26‰. Calculated maturity based on the relationship between δ13C and Ro of natural gas, the gases are equivalent to those generated from organic matter when Ro is 1.0%-1.7% （mainly 1.25%-1.32%）. The natural gas is oil-type gas generated from the source rocks at mature to high mature stage, associated with condensate, so carbon isotopes of the gases are heavier. Natural gas in the Nanpu No.1 structural belt is mainly associated gas with condensate. The analysis of the origin and source of natural gas and condensate, combined with the monomer hydrocarbon carbon isotopes and biomarker, indicated that the main source rocks in the Nanpu No.1 structural belt were Es3 （the lower member of the Shahejie Formation）, followed by Es1 （the upper member of the Shahejie Formation）.？The high-mature hydrocarbons from source rocks in the deep sag mainly migrated through deep inherited faults into shallow traps and accumulated to form oil and gas pools. Therefore, there is a great potential for exploring gas in deep layers.展开更多
Focused on the lost circulation control in deep naturally fractured reservoirs, the multiscale structure of fracture plugging zone is proposed based on the theory of granular matter mechanics, and the structural failu...Focused on the lost circulation control in deep naturally fractured reservoirs, the multiscale structure of fracture plugging zone is proposed based on the theory of granular matter mechanics, and the structural failure pattern of plugging zone is developed to reveal the plugging zone failure mechanisms in deep, high temperature, high pressure, and high in-situ stress environment. Based on the fracture plugging zone strength model, key performance parameters are determined for the optimal selection of loss control material(LCM). Laboratory fracture plugging experiments with new LCM are carried out to evaluate the effect of the key performance parameters of LCM on fracture plugging quality. LCM selection strategy for fractured reservoirs is developed. The results show that the force chain formed by LCMs determines the pressure stabilization of macro-scale fracture plugging zone. Friction failure and shear failure are the two major failure patterns of fracture plugging zone. The strength of force chain depends on the performance of micro-scale LCM, and the LCM key performance parameters include particle size distribution, fiber aspect ratio, friction coefficient, compressive strength, soluble ability and high temperature resistance. Results of lab experiments and field test show that lost circulation control quality can be effectively improved with the optimal material selection based on the extracted key performance parameters of LCMs.展开更多
In the second member of the Upper Triassic Xujiahe Formation(T_(3)x_(2))in the Xinchang area,western Sichuan Basin,only a low percent of reserves has been recovered,and the geological model of gas reservoir sweet spot...In the second member of the Upper Triassic Xujiahe Formation(T_(3)x_(2))in the Xinchang area,western Sichuan Basin,only a low percent of reserves has been recovered,and the geological model of gas reservoir sweet spot remains unclear.Based on a large number of core,field outcrop,test and logging-seismic data,the T_(3)x_(2) gas reservoir in the Xinchang area is examined.The concept of fault-fold-fracture body(FFFB)is proposed,and its types are recognized.The main factors controlling fracture development are identified,and the geological models of FFFB are established.FFFB refers to faults,folds and associated fractures reservoirs.According to the characteristics and genesis,FFFBs can be divided into three types:fault-fracture body,fold-fracture body,and fault-fold body.In the hanging wall of the fault,the closer to the fault,the more developed the effective fractures;the greater the fold amplitude and the closer to the fold hinge plane,the more developed the effective fractures.Two types of geological models of FFFB are established:fault-fold fracture,and matrix storage and permeability.The former can be divided into two subtypes:network fracture,and single structural fracture,and the later can be divided into three subtypes:bedding fracture,low permeability pore,and extremely low permeability pore.The process for evaluating favorable FFFB zones was formed to define favorable development targets and support the well deployment for purpose of high production.The study results provide a reference for the exploration and development of deep tight sandstone oil and gas reservoirs in China.展开更多
With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can b...With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can be extended,and the prediction of the depth limit of oil accumulation(DLOA),are issues that have attracted significant attention in petroleum geology.Since it is difficult to characterize the evolution of the physical properties of the marine carbonate reservoir with burial depth,and the deepest drilling still cannot reach the DLOA.Hence,the DLOA cannot be predicted by directly establishing the relationship between the ratio of drilling to the dry layer and the depth.In this study,by establishing the relationships between the porosity and the depth and dry layer ratio of the carbonate reservoir,the relationships between the depth and dry layer ratio were obtained collectively.The depth corresponding to a dry layer ratio of 100%is the DLOA.Based on this,a quantitative prediction model for the DLOA was finally built.The results indicate that the porosity of the carbonate reservoir,Lower Ordovician in Tazhong area of Tarim Basin,tends to decrease with burial depth,and manifests as an overall low porosity reservoir in deep layer.The critical porosity of the DLOA was 1.8%,which is the critical geological condition corresponding to a 100%dry layer ratio encountered in the reservoir.The depth of the DLOA was 9,000 m.This study provides a new method for DLOA prediction that is beneficial for a deeper understanding of oil accumulation,and is of great importance for scientific guidance on deep oil drilling.展开更多
Upper Circumpolar Deep Water(UCDW)and North Pacifi c Deep Water(NPDW)coexist in the upper deep layer(i.e.,with a 1.2-2.0-℃potential temperature range and a 2000-4100-dbar pressure range)of the Eastern Philippine Sea....Upper Circumpolar Deep Water(UCDW)and North Pacifi c Deep Water(NPDW)coexist in the upper deep layer(i.e.,with a 1.2-2.0-℃potential temperature range and a 2000-4100-dbar pressure range)of the Eastern Philippine Sea.They have similar properties in potential temperature and salinity,while have a signifi cant diff erence in dissolved silicate.Based on the repeated observations along a 137°E transect from the World Ocean Database(WOD18),this study revealed the interannual variability of dissolved silicate in the upper deep layer of the Eastern Philippine Sea.Dissolved silicate increased in 1995,1996,2005,2006,and 2007,and decreased in 1997,2000,2001,2002,and 2004.Composition analysis showed that the large diff erence between positive and negative dissolved silicate anomalies occurred mainly at~15°N and north of 25°N,with the concentration reaching 4.25μmol/g.Further analysis indicated that the interannual dissolved silicate variability was related to the zonal current variation in the upper deep layer.The relatively strong(weak)westward current transport increased(decreased)NPDW to the Eastern Philippine Sea,thereby resulting in increased(decreased)dissolved silicate.展开更多
In a convective scheme featuring a discretized cloud size density, the assumed lateral mixing rate is inversely proportional to the exponential coefficient of plume size. This follows a typical assumption of-1, but it...In a convective scheme featuring a discretized cloud size density, the assumed lateral mixing rate is inversely proportional to the exponential coefficient of plume size. This follows a typical assumption of-1, but it has unveiled inherent uncertainties, especially for deep layer clouds. Addressing this knowledge gap, we conducted comprehensive large eddy simulations and comparative analyses focused on terrestrial regions. Our investigation revealed that cloud formation adheres to the tenets of Bernoulli trials, illustrating power-law scaling that remains consistent regardless of the inherent deep layer cloud attributes existing between cloud size and the number of clouds. This scaling paradigm encompasses liquid, ice, and mixed phases in deep layer clouds. The exponent characterizing the interplay between cloud scale and number in the deep layer cloud, specifically for liquid, ice, or mixed-phase clouds, resembles that of shallow convection,but converges closely to zero. This convergence signifies a propensity for diminished cloud numbers and sizes within deep layer clouds. Notably, the infusion of abundant moisture and the release of latent heat by condensation within the lower atmospheric strata make substantial contributions. However, this role in ice phase formation is limited. The emergence of liquid and ice phases in deep layer clouds is facilitated by the latent heat and influenced by the wind shear inherent in the middle levels. These interrelationships hold potential applications in formulating parameterizations and post-processing model outcomes.展开更多
In recent years,major breakthroughs have been made in natural gas exploration in deep and ultra-deep strata in the Sichuan Basin,but the overall successful rate is low.To further clarify the prospects there,it is nece...In recent years,major breakthroughs have been made in natural gas exploration in deep and ultra-deep strata in the Sichuan Basin,but the overall successful rate is low.To further clarify the prospects there,it is necessary to make an in-depth analysis of the previously discovered large-scale reef-shoal gasfields such as Puguang,Yuanba,Anyue and Longgang and deep shale gas discovery in Dingshan and Dongxi,southern Sichuan Basin.On one hand,large high-energy facies are the basis for controlling the development of large-scale reef-shoal reservoirs in conventional reef-shoal areas.The reservoir original porosity is high.The atmospheric freshwater dissolution in the early diagenetic stage,dolomitization,unconformity karst,and“poreefracture coupling”mainly control the development of secondary pores.The contribution of hydrothermalfluids to reservoir is double-sided,and such early pores can be preserved till present due to those retention processes such as early hydrocarbon charging.Apart from continuous preservation as the key factor,most gas reservoirs are featured by“near-source enrichment,phase transformation,and dynamic adjustment”.On the other hand,deep shale gas generally has the characteristics of“high pressure,high porosity,and high gas content”,that is,“overpressure and rich gas”.The key to the development of high-quality deep shales with high pores are“quartz compression retaining pore”and“reservoirfluid overpressure”.The weak tectonic effect in the late stage is the main reason for deep shale gas to maintain the“high pressure and high gas content”.In conclusion,technological advances like geological target identification and“sweet spot”prediction,as well as deep,high-temperature and high-pressure engineering processes,are the guarantee for efficient exploration of conventional and unconventional deep and ultra-deep natural gas,which has great potential in the Sichuan Basin.展开更多
Based on analysis of pore features and pore skeleton composition of shale,a“rigid elastic chimeric”pore skeleton model of shale gas reservoir was built.Pore deformation mechanisms leading to increase of shale porosi...Based on analysis of pore features and pore skeleton composition of shale,a“rigid elastic chimeric”pore skeleton model of shale gas reservoir was built.Pore deformation mechanisms leading to increase of shale porosity due to the pore skeleton deformation under overpressure were sorted out through analysis of stress on the shale pore and skeleton.After reviewing the difficulties and defects of existent porosity measurement methods,a dynamic deformed porosity measurement method was worked out and used to measure the porosity of overpressure Silurian Longmaxi Formation shale under real formation conditions in southern Sichuan Basin.The results show:(1)The shale reservoir is a mixture of inorganic rock particles and organic matter,which contains inorganic pores supported by rigid skeleton particles and organic pores supported by elastic-plastic particles,and thus has a special“rigid elastic chimeric”pore structure.(2)Under the action of formation overpressure,the inorganic pores have tiny changes that can be assumed that they don’t change in porosity,while the organic pores may have large deformation due to skeleton compression,leading to the increase of radius,connectivity and ultimately porosity of these pores.(3)The“dynamic”deformation porosity measurement method combining high injection pressure helium porosity measurement and kerosene porosity measurement method under ultra-high variable pressure can accurately measure porosity of unconnected micro-pores under normal pressure conditions,and also the porosity increment caused by plastic skeleton compression deformation.(4)The pore deformation mechanism of shale may result in the"abnormal"phenomenon that the shale under formation conditions has higher porosity than that under normal pressure,so the overpressure shale reservoir is not necessarily“ultra-low in porosity”,and can have porosity over 10%.Application of this method in Well L210 in southern Sichuan has confirmed its practicality and reliability.展开更多
Acid fracturing is an indispensable technology in the efficient development of carbonate oil and gas rosarvoirs.As for deep and ultra-deep marine carbonate oil and gas reservoirs,however,existing acid fracturing techn...Acid fracturing is an indispensable technology in the efficient development of carbonate oil and gas rosarvoirs.As for deep and ultra-deep marine carbonate oil and gas reservoirs,however,existing acid fracturing technologies can hardly create complex fracture networks because of their particular engineering and geological characteristics.In order to realize the efficient three-dimensional development of deep and ultra-deep marine carbonate oil and gas reservoirs,this paper revealed the acid fracturing difficulties of this kind of reservoirs based on the engineering and geological characteristics of deep marine carbonate oil and gas reservoirs in China.Then,by taking the efficient three-dimensional development of deep and ultra-deep marine carbonate oiland gas reservoirs as the target,the technical conceptof three-dimensional acid fracturing(3D-AF)was putforward based on the techniques of volume acid fracturing and deep acid fracturing.In addition,its technical connotation was il lustrated,and its key technologies were described in detail.Finally,its development direction in the next step was pointed out.And the following research results were obtained.First,the 3D-AF technology contains three basic connotations:(1)selecting the corresponding acid penetration technology according to reservoir types so as to realize sufficient resarvoir stimulation on the plane;(2)creating complex acid-fracture volume with higher flow conductivity under high closed pressure;(3)deploying acid-fracture volume rationally along the long hole section so as to realize sufficient reservoir stimulation in the wellbore direction.Second,there are three key technologies of 3D-AF,i.e.,the technology for predicting the effective acid-penetrate distance under the coupling action of multi-feld,multi-scale and multi-fluid,the technology for optimizing the flow conductivity of complex acid-fracture volume,and the technology for precisely deploying acid in the long section of horizontal well or highly deviated well.Third,in order to promote the further development of 3D-AFtechnology,it is necessary to carry out researches on three technologies,i.e.,the technology for predicting and reducing the fracturing pressure of ultra-deep reservoir,the tech-nology for predicting the geometry of acid-fracture body ina strongly heterogeneous reservoir,and the staged reservoir production technology and new fluid technology with high temperature resistance,low reaction rate and low friction resistance coefficient for long hole sections(over 7000 m).展开更多
The discovery of shock waves at observations sun like stars quasi-zero method. Shock waves associated with solar flares in Ha, it is shown that the amplitude of shock waves decreases to the edge of the sun, it follows...The discovery of shock waves at observations sun like stars quasi-zero method. Shock waves associated with solar flares in Ha, it is shown that the amplitude of shock waves decreases to the edge of the sun, it follows that these waves are global. The conclusion is that the appearance of these waves may be connected with explosions in the deeper layers of the sun.展开更多
To reveal the influencing effect of the long-term straw mulching on the soil moisture, this paper employed the field experiment data in 2010 of a typical area of Taihang Mountains plain, observed the soil moisture dyn...To reveal the influencing effect of the long-term straw mulching on the soil moisture, this paper employed the field experiment data in 2010 of a typical area of Taihang Mountains plain, observed the soil moisture dynamic regularities under different mulching patterns by virtue of depressimeter and neutron probe, analyzed the characteristics of soil water content and storage in different depths and seasons under the long-term straw mulching. The results showed that the long-term straw mulching can keep the soil moisture conservation of the deep, while decreased the shallow.(1) The long-term straw mulching can changed the type of soil water movement. If no straw mulching, the type is mainly evaporation-infiltration. And with straw mantle the type would change into infiltration. The number of zero flux plane would be reduced or absent.(2) The long-term straw mulching can increase the soil water reserves of the whole soil profile with the depth between 0 cm and 220 cm. But the soil water content of the layer from 30 cm to 80 cm decreased and the soil water content of the layer from 80 cm to 220 cm increased instead., The effect of soil moisture conservation on winter wheat is not obvious;(3) With no straw mulching, the depth of infiltration recharge by rainfall or irrigation is shallower than 80 cm. In a straw mulching, the influence depth is can extend to 120 cm;(4) With no straw mulching, there is a deep layer on the depth of 220 cm between March and June, while this layer will disappear with a long-term straw mulching.展开更多
Based on a large number of geological and geophysical data,the formation,fracture-caves types and hydrocarbon distribution of hoodoo-upland on the Ordovician karst slope in the Tahe area,Tarim Basin,are discussed by a...Based on a large number of geological and geophysical data,the formation,fracture-caves types and hydrocarbon distribution of hoodoo-upland on the Ordovician karst slope in the Tahe area,Tarim Basin,are discussed by analyzing faults and strata thickness.The hoodoo-upland was made of high peaks and narrow valleys in the Ordovician karst slope during the Early Hercynian karst period,which were distributed along the NNE positive flower structure and had inherited evolution.The fault-fractures and fracture-vugs complex were extremely developed,with a thickness of 100 m.The cumulative oil production of 60% oil wells was more than 20×10^(4) t per well in the hoodoo-upland,where the residual thickness of the Ordovician Yingshan Formation was greater than karst depressions.Caves formed by the shelter of collapsed breccias were developed in the valleys.They were 1.6 to 13.5 m high,with a filling rate of 51.6%.The positive flower structure under the settings of strike-slip compression controlled the early formation of the hoodoo-upland on the karst slope,resulting in the differences of drainage distribution and karstification.Compared with the water-rich karst valley,the hoodoo-upland with lean water suffered weaker karstification,had thicker residual stratum,and was higher in terrain.In rainy season,the meteoric water flew and corrode along the cracks,forming a complex network of fractures and caves.Combined with inherited uplift and the effective match of the NNE deep faults,oil and gas continuously charged into the reservoir space in the upland,forming the hoodoo fracture-cave reservoir with vertically quasi continuous distribution,high hydrocarbon abundance and high production.展开更多
DDCl-1 type seismic profiler for deep sediment layers is a large scale marine survey equipment. Its penetrating strata depth may reach to 1 km. This equipment suits surveys for continental shelf,seafloor trench and ge...DDCl-1 type seismic profiler for deep sediment layers is a large scale marine survey equipment. Its penetrating strata depth may reach to 1 km. This equipment suits surveys for continental shelf,seafloor trench and geological structure under seafloor etc. It suits also geological environment surveys of seafloor resources.The working principle, block diagrams composition and echo signal processing characteristics are presented, and some typical strata profiles are shown.展开更多
Clastic rock reservoirs in petroliferous basins are generally rich in feldspars. Feldspar dissolution has developed widely in clastic reservoirs, and the resulting secondary pores are crucial in deeply buried reservoi...Clastic rock reservoirs in petroliferous basins are generally rich in feldspars. Feldspar dissolution has developed widely in clastic reservoirs, and the resulting secondary pores are crucial in deeply buried reservoirs. Based on a study of the diagenesis of clastic reservoirs in the Bohai Bay Basin, Tarim Basin, and Pearl River Mouth Basin and physical and numerical simulation experiments of fluid-rock interactions, this paper proposed a successive formation model of secondary pores via feldspar dissolution in deeply buried clastic reservoirs, considering the global research progresses in feldspar dissolution in clastic rocks. Feldspar dissolution can occur from shallow open systems to deep-ultra deep closed systems in petroliferous basins, resulting in the successive formation of secondary pores at different diagenetic stages. The successive mechanism includes three aspects. The first aspect is the succession of corrosive fluids that dissolve minerals. Meteoric freshwater dominates at the Earth’s surface and the early diagenetic A stage. Subsequently, organic acids and COformed via kerogen maturation dominate at the early diagenetic B stage to the middle diagenetic stage. COand organic acids formed via hydrocarbon oxidation in hydrocarbon reservoirs dominate at the middle diagenetic B stage to the late diagenetic stage. The second aspect is the successive formation processes of secondary pores via feldspar dissolution. Large-scale feldspar secondary pores identified in deep reservoirs include secondary pores formed at shallow-medium depths that are subsequently preserved into deep layers, as well as secondary pores formed at deep depths. Existing secondary pores in deeply buried reservoirs are the superposition of successively feldspar dissolution caused by different acids at different stages. The third aspect is a successive change in the feldspar alteration pathways and porosity enhancement/preservation effect. Open to semi-open diagenetic systems are developed from the Earth’s surface to the early diagenetic stage, and feldspar dissolution forms enhanced secondary pores. Nearly closed to closed diagenetic systems develop in the middle to late diagenetic stages, and feldspar dissolution forms redistributional secondary pores. The associated cementation causes compression resistance of the rock, which is favorable for the preservation of secondary pores in deep layers. These new insights extend the formation window of secondary pores in petroliferous basins from the traditional acid-oil generation window to a high-temperature gas generation window after hydrocarbon charging. The proposed model explains the genesis of deep-ultra deep high-quality reservoirs with low-permeability, medium-porosity and dominating feldspar secondary pores, which is significant for hydrocarbon exploration in deep to ultra-deep layers.展开更多
文摘On December 2, 2017, the 2nd Seminar on the Development Strategy of China＇s Oil and Gas Resources was held in Beijing. This seminar was hosted by the Strategic Research Center for Oil and Gas Resources, Ministry of Land （MLR） and Resources and sponsored by both the CNOOC Exploration Department and the School of Ocean and Earth Sciences of Tongji University. With the theme of ＂deepwater and deep-layer oil and gas resources and development strategy＂,
基金supported by the National Key Rescarch and Development Program of China"Accumulation patem and exploration direction of ultra-deep and middle Ncoprotierozoic oil and gas"(No.2017YFC0603106)Key Project of Natural Science Foundation of China"Constraints of hate Mesoznic palcogoothermal fiekd on litho sphenic dynamic evolution andoil and gas occ urrence inOrdosand Qinshui sedimentary basins"(No.41630312)MajorNational Science and Technology Project of the 13th FYP"Structural evolution and preservation conditions of the southwest of Ordos Basin in the middle-upper Proterozoic and lower Palcozoic"(No.2017ZX05005-002-008).
文摘Deep and ultra-deep layers in the petroliferous basins of China are characterized by large temperature difference and complicated thermal evolution history.The control effects of temperature and thermal evolution history on the differences of hydrocarbon phase states and the hydrocarbon generation history in deep and ultra-deep layers are researched less and unsystematically.To deal with this situation,based on a large number of temperature and pressure data of deeplayers and combined with the complicated historical situation of deep layer evolution in the oil and gas basins of China,the effects of temperature,heating time and pressure on the hydrocarbon formation temperature and phase state were analyzed,and the types of temperature and pressure relationships were classified.Finally,based on the classification of thermal evolution history of deep and ultra-deep layers,We discussed the control effects of basin thermal evolution history on the hydrocarbon generation and phase state,and the following research results were obtained.First,the hydrocarbon phase states of deep layers in different basins and regions are greatly different,and they are mainly affected by temperature,heating time,heating rate,pressure,source rock types and other factors.And temperature is the most important factor controlling hydrocarbon generation and phase state distribution.Second,under the conditions of rapid temperature increasing and short heating time,there still maybe oil reservoirs and condensate gas reservoirs in deep and ultra-deep layersin thecase ofhigh temperature.Third,overpressureinhibitshydrocarbon generationand pyrolysis.Fourth,thereis a closerelationship betweentemperature and formation pressure of deeplayers,whichcan be divided into three types,i.e.,lowemedium temperature and high pressure type,high temperature and high pressure type,and medium temperature and lowemedium pressure type.Fifth,the thermal evolution history of deep and ultra-deep layers can be divided into four types,namely the late rapid subsidence,heating and low geothermal gradient type,the late rapid subsidence,heating and high geothermal gradient type,the middleelate rapid heating and late uplifting and cooling type,and the early great subsidence and rapid heating and middleelate great uplift erosion and cooling type.In conclusion,deep and ultra-deep layers in the basins with different types of thermal history are different in hydrocarbon phase states,accumulation stages and prospects.
文摘The sand layer B of Dongying Formation of CFD oilfield in Bohai offshore belongs to the middle deep layer of buried hill overlap deposit. Its reservoir distribution has the characteristics of large burial depth, thin thickness and rapidly lateral change. Because of low resolution of seismic data and overlying sand layer. It is difficult to identify and interpret the structure of sand layer accurately. The uncertainty of structure and reservoir restricts the fine development of B sand layer. In order to identify the top surface of reservoir effectively. The seismic data are processed by using the reflection coefficient inversion method. The results show that the inversion resolution of reflection coefficient is significantly higher than that of original data. The top surface of sand layer B and its overlying sand layer can be well identified and traced. Carrying out structural interpretation of B sand layer based on reflection coefficient inversion data and the microstructure and the formation tip extinction point are implemented. Based on the constraint of new interpretation level, the sedimentary facies plane distribution of B sand layer is described and make prediction of dominant reservoir development area in detail combining with sedimentary paleogeomorphology, along layer attribute section and limited drilling data. The research shows that the study area is mainly from the northwest material sources, the slope belt in the northwest is close to the lake shoreline with a gentle slope and shallow water depositional environment, which is located on the main transport and deposition channels. The shallow water gentle slope landform is suitable for forming large-area sand bar deposition, mainly composed of underwater distributary channel and debouch bars facies, which is the dominant reservoir development area. The research conclusion guides the deployment and implementation of the development well location effectively.
基金The National Natural Science Foundation of China under contract No.42076122the China Ocean Mineral Resources Research and Development Association Program under contract Nos DY135-E2-3-04,DY135-E2-2-04 and JS-KTFA-2018-01.
文摘The mesopelagic communities are important for food web and carbon pump in ocean,but the large-scale studies of them are still limited until now because of the difficulties on sampling and analyzing of mesopelagic organisms.Mesopelagic organisms,especially micronekton,can form acoustic deep scattering layers(DSLs)and DSLs are widely observed.To explore the spatial patterns of DSLs and their possible influencing factors,the DSLs during daytime(10:00–14:00)were investigated in the subtropical northwestern Pacific Ocean(13°–23.5°N,153°–163°E)using a shipboard acoustic Doppler current profiler at 38 kHz.The study area was divided into three parts using k-means cluster analysis:the northern part(NP,22°–24°N),the central part(CP,17°–22°N),and the southern part(SP,12°–17°N).The characteristics of DSLs varied widely with latitudinal gradient.Deepest core DSLs(523.5 m±17.4 m),largest nautical area scattering coefficient(NASC)(130.8 m^(2)/n mile^(2)±41.0 m^(2)/n mile^(2)),and most concentrated DSLs(mesopelagic organisms gathering level,6.7%±0.7%)were observed in NP.The proportion of migration was also stronger in NP(39.7%)than those in other parts(18.6%in CP and 21.5%in SP)for mesopelagic organisms.The latitudinal variation of DSLs was probably caused by changes in oxygen concentration and light intensity of mesopelagic zones.A positive relationship between NASC and primary productivity was identified.A four-months lag was seemed to exist.This study provides the first basin-scale baselines information of mesopelagic communities in the northwest Pacific with acoustic approach.Further researches are suggested to gain understandings of seasonal and annual variations of DSLs in the region.
基金Supported by the National Natural Science Foundation of China(U23B20154)General Program of the National Natural Science Foundation of China(42372169)。
文摘In recent years,drilling data from wells Pengshen 10,Heshen 9,Tongshen 17 and Zhengyang 1 in the Sichuan Basin have confirmed the presence of a set of porous reef-beach limestone reservoirs in the Upper Permian Changxing Formation,which breaks the traditional view that deep carbonate oil and gas are only distributed in porous dolomite reservoirs and karst fracture-cavity limestone reservoirs.Through core and thin section observations,geochemical analysis,and well-seismic based reservoir identification and tracking,the study on formation mechanism of pores in deep reef-beach limestone reservoirs is carried out,this study provides insights in four aspects.(1)Porous reef-beach limestone reservoirs are developed in the Changxing Formation in deep-buried layers.The reservoir space is composed of intergranular pores,framework pores,intra-fossil pores,moldic pores and dissolution pores,which are formed in depositional and epigenetic environments.(2)The intermittently distributed porous reef-beach complexes are surrounded by relatively dense micrite limestone,which leads to the formation of local abnormal high-pressure inside the reef-beach complexes with the temperature increased.(3)The floor of the Changxing Formation reservoir is composed with interbedded tight mudstone and limestone of the Upper Permian Wujiaping Formation,and the roof is the tight micrite limestone interbedded with mudstone of the first member of Lower Triassic Feixianguan Formation.Under the clamping of dense roof and floor,the abnormal high-pressure in the Changxing Formation is formed.Abnormal high-pressure(overpressured compartment)is the key to maintain the pores formed in the depositional and epigenetic environments in deep-buried layers.(4)Based on the identification of roof,floor and reef-beach complexes,the favorable reef-beach limestone reservoir distribution area of 10.3×10^(4) km^(2) is predicted by well-seismic integration.These insights lay the theoretical foundation for the development of deep porous limestone reservoirs,expand the new field of exploration of deep-buried limestone reservoirs in the Sichuan Basin.
文摘The aims of this study were to prepare novel transfersomes(TFs)for tacrolimus to treat atopic dermatitis,and to observe the therapeutic effects on mice atopic dermatitis,as compared to commercial tacrolimus ointment(Protopic)and liposomes-gel.Different kinds of surfactantsdsodium cholate,Tween 80 and Span 80 were investigated to prepare TFs respectively.TFs-Tween 80 was selected as the optimal carrier owing to the best deformability and the highest drug retentions.Entrapment efficiency and diameter were also evaluated.The optimized TFs were further made into gel and in vitro drug release of TFs-gel after 24 h was higher than the commercial ointment.Cumulative drug release from TFs-gel after 12 h in vitro was 37.6%.The optimized TFs-gel illustrated remarkably highest drug skin retentions when compared with liposomes-gel and commercial ointment in vivo skin retention experiments.The amounts of tacrolimus in epidermis and dermis from TFsgel were 3.8 times and 4.2 times respectively as much as ointment,while liposomes-gel was only 1.7 times and 1.4 times respectively as compared to ointment.Topical application of TFs-gel displayed the best therapeutic effect on mice atopic dermatitis induced by repeated topical application of 2,4-dinitrofluorobenzene.Thus TFs displayed superior performance and effective skin target for topical delivery of tacrolimus.
基金State Oil and Gas Special Project(2008ZX05004-003)China Petroleum Technology Research Project(2008A-0609)co-funded
文摘Natural gas exploration in Nanpu sag, Bohai Bay Basin, has achieved breakthroughs in recent years, and a number of natural gas and condensate wells with high yield have been found in several structures in the beach area. Daily gas production of single wells is up to 170,000 m3, and high-yield wells are mainly distributed in？the Nanpu No. 1 structural belt.？Studies have shown that these natural gases are mainly hydrocarbon gases, with methane content about 80% to 90% and ethane 6%-9%, so they are mainly wet gas; and non-hydrocarbons are at a low level.？Carbon isotopes of methane range from -42‰ to -36‰, and ethane from -28‰ to -26‰. Calculated maturity based on the relationship between δ13C and Ro of natural gas, the gases are equivalent to those generated from organic matter when Ro is 1.0%-1.7% （mainly 1.25%-1.32%）. The natural gas is oil-type gas generated from the source rocks at mature to high mature stage, associated with condensate, so carbon isotopes of the gases are heavier. Natural gas in the Nanpu No.1 structural belt is mainly associated gas with condensate. The analysis of the origin and source of natural gas and condensate, combined with the monomer hydrocarbon carbon isotopes and biomarker, indicated that the main source rocks in the Nanpu No.1 structural belt were Es3 （the lower member of the Shahejie Formation）, followed by Es1 （the upper member of the Shahejie Formation）.？The high-mature hydrocarbons from source rocks in the deep sag mainly migrated through deep inherited faults into shallow traps and accumulated to form oil and gas pools. Therefore, there is a great potential for exploring gas in deep layers.
基金Supported by the National Natural Science Foundation of China(Grant No.51604236)Science and Technology Program of Sichuan Province(Grant No.2018JY0436)the Sichuan Province Youth Science and Technology Innovation Team Project(Grant No.2016TD0016)
文摘Focused on the lost circulation control in deep naturally fractured reservoirs, the multiscale structure of fracture plugging zone is proposed based on the theory of granular matter mechanics, and the structural failure pattern of plugging zone is developed to reveal the plugging zone failure mechanisms in deep, high temperature, high pressure, and high in-situ stress environment. Based on the fracture plugging zone strength model, key performance parameters are determined for the optimal selection of loss control material(LCM). Laboratory fracture plugging experiments with new LCM are carried out to evaluate the effect of the key performance parameters of LCM on fracture plugging quality. LCM selection strategy for fractured reservoirs is developed. The results show that the force chain formed by LCMs determines the pressure stabilization of macro-scale fracture plugging zone. Friction failure and shear failure are the two major failure patterns of fracture plugging zone. The strength of force chain depends on the performance of micro-scale LCM, and the LCM key performance parameters include particle size distribution, fiber aspect ratio, friction coefficient, compressive strength, soluble ability and high temperature resistance. Results of lab experiments and field test show that lost circulation control quality can be effectively improved with the optimal material selection based on the extracted key performance parameters of LCMs.
基金Supported by the Sinopec Science and Technology Project(P21040-1).
文摘In the second member of the Upper Triassic Xujiahe Formation(T_(3)x_(2))in the Xinchang area,western Sichuan Basin,only a low percent of reserves has been recovered,and the geological model of gas reservoir sweet spot remains unclear.Based on a large number of core,field outcrop,test and logging-seismic data,the T_(3)x_(2) gas reservoir in the Xinchang area is examined.The concept of fault-fold-fracture body(FFFB)is proposed,and its types are recognized.The main factors controlling fracture development are identified,and the geological models of FFFB are established.FFFB refers to faults,folds and associated fractures reservoirs.According to the characteristics and genesis,FFFBs can be divided into three types:fault-fracture body,fold-fracture body,and fault-fold body.In the hanging wall of the fault,the closer to the fault,the more developed the effective fractures;the greater the fold amplitude and the closer to the fold hinge plane,the more developed the effective fractures.Two types of geological models of FFFB are established:fault-fold fracture,and matrix storage and permeability.The former can be divided into two subtypes:network fracture,and single structural fracture,and the later can be divided into three subtypes:bedding fracture,low permeability pore,and extremely low permeability pore.The process for evaluating favorable FFFB zones was formed to define favorable development targets and support the well deployment for purpose of high production.The study results provide a reference for the exploration and development of deep tight sandstone oil and gas reservoirs in China.
基金This work was supported by the Beijing Nova Program[Z211100002121136]Open Fund Project of State Key Laboratory of Lithospheric Evolution[SKL-K202103]+1 种基金Joint Funds of National Natural Science Foundation of China[U19B6003-02]the National Natural Science Foundation of China[42302149].We would like to thank Prof.Zhu Rixiang from the Institute of Geology and Geophysics,Chinese Academy of Sciences.
文摘With continuous hydrocarbon exploration extending to deeper basins,the deepest industrial oil accumulation was discovered below 8,200 m,revealing a new exploration field.Hence,the extent to which oil exploration can be extended,and the prediction of the depth limit of oil accumulation(DLOA),are issues that have attracted significant attention in petroleum geology.Since it is difficult to characterize the evolution of the physical properties of the marine carbonate reservoir with burial depth,and the deepest drilling still cannot reach the DLOA.Hence,the DLOA cannot be predicted by directly establishing the relationship between the ratio of drilling to the dry layer and the depth.In this study,by establishing the relationships between the porosity and the depth and dry layer ratio of the carbonate reservoir,the relationships between the depth and dry layer ratio were obtained collectively.The depth corresponding to a dry layer ratio of 100%is the DLOA.Based on this,a quantitative prediction model for the DLOA was finally built.The results indicate that the porosity of the carbonate reservoir,Lower Ordovician in Tazhong area of Tarim Basin,tends to decrease with burial depth,and manifests as an overall low porosity reservoir in deep layer.The critical porosity of the DLOA was 1.8%,which is the critical geological condition corresponding to a 100%dry layer ratio encountered in the reservoir.The depth of the DLOA was 9,000 m.This study provides a new method for DLOA prediction that is beneficial for a deeper understanding of oil accumulation,and is of great importance for scientific guidance on deep oil drilling.
基金Supported by the National Key Research and Development Program of China(No.2018YFC0309800)the National Natural Science Foundation of China(Nos.42176021,91858203)+1 种基金the Open Project Program of State Key Laboratory of Tropical Oceanography(No.LTOZZ2001)the Key Special Project for Introduced Talents Team of Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)(No.GML2019ZD0304)。
文摘Upper Circumpolar Deep Water(UCDW)and North Pacifi c Deep Water(NPDW)coexist in the upper deep layer(i.e.,with a 1.2-2.0-℃potential temperature range and a 2000-4100-dbar pressure range)of the Eastern Philippine Sea.They have similar properties in potential temperature and salinity,while have a signifi cant diff erence in dissolved silicate.Based on the repeated observations along a 137°E transect from the World Ocean Database(WOD18),this study revealed the interannual variability of dissolved silicate in the upper deep layer of the Eastern Philippine Sea.Dissolved silicate increased in 1995,1996,2005,2006,and 2007,and decreased in 1997,2000,2001,2002,and 2004.Composition analysis showed that the large diff erence between positive and negative dissolved silicate anomalies occurred mainly at~15°N and north of 25°N,with the concentration reaching 4.25μmol/g.Further analysis indicated that the interannual dissolved silicate variability was related to the zonal current variation in the upper deep layer.The relatively strong(weak)westward current transport increased(decreased)NPDW to the Eastern Philippine Sea,thereby resulting in increased(decreased)dissolved silicate.
基金supported by the Second Tibetan Plateau Scientific Expedition and Research Program (STEP) (Grant No.2019QZKK010203)the National Natural Science Foundation of China (Grant No.42175174 and 41975130)+1 种基金the Natural Science Foundation of Sichuan Province (Grant No.2022NSFSC1092)the Sichuan Provincial Innovation Training Program for College Students (Grant No.S202210621009)。
文摘In a convective scheme featuring a discretized cloud size density, the assumed lateral mixing rate is inversely proportional to the exponential coefficient of plume size. This follows a typical assumption of-1, but it has unveiled inherent uncertainties, especially for deep layer clouds. Addressing this knowledge gap, we conducted comprehensive large eddy simulations and comparative analyses focused on terrestrial regions. Our investigation revealed that cloud formation adheres to the tenets of Bernoulli trials, illustrating power-law scaling that remains consistent regardless of the inherent deep layer cloud attributes existing between cloud size and the number of clouds. This scaling paradigm encompasses liquid, ice, and mixed phases in deep layer clouds. The exponent characterizing the interplay between cloud scale and number in the deep layer cloud, specifically for liquid, ice, or mixed-phase clouds, resembles that of shallow convection,but converges closely to zero. This convergence signifies a propensity for diminished cloud numbers and sizes within deep layer clouds. Notably, the infusion of abundant moisture and the release of latent heat by condensation within the lower atmospheric strata make substantial contributions. However, this role in ice phase formation is limited. The emergence of liquid and ice phases in deep layer clouds is facilitated by the latent heat and influenced by the wind shear inherent in the middle levels. These interrelationships hold potential applications in formulating parameterizations and post-processing model outcomes.
基金supported by the Special and Significant Project of National Science and Technology"Shale Gas Zone Target Evaluation and Exploration Technology"(No.:2017ZX05036)Distribution and Exploration Evalu-ation of Southern Marine Carbonate Large and Medium-Scale Oil and Gas Fields"(No:2017ZX05005-003).
文摘In recent years,major breakthroughs have been made in natural gas exploration in deep and ultra-deep strata in the Sichuan Basin,but the overall successful rate is low.To further clarify the prospects there,it is necessary to make an in-depth analysis of the previously discovered large-scale reef-shoal gasfields such as Puguang,Yuanba,Anyue and Longgang and deep shale gas discovery in Dingshan and Dongxi,southern Sichuan Basin.On one hand,large high-energy facies are the basis for controlling the development of large-scale reef-shoal reservoirs in conventional reef-shoal areas.The reservoir original porosity is high.The atmospheric freshwater dissolution in the early diagenetic stage,dolomitization,unconformity karst,and“poreefracture coupling”mainly control the development of secondary pores.The contribution of hydrothermalfluids to reservoir is double-sided,and such early pores can be preserved till present due to those retention processes such as early hydrocarbon charging.Apart from continuous preservation as the key factor,most gas reservoirs are featured by“near-source enrichment,phase transformation,and dynamic adjustment”.On the other hand,deep shale gas generally has the characteristics of“high pressure,high porosity,and high gas content”,that is,“overpressure and rich gas”.The key to the development of high-quality deep shales with high pores are“quartz compression retaining pore”and“reservoirfluid overpressure”.The weak tectonic effect in the late stage is the main reason for deep shale gas to maintain the“high pressure and high gas content”.In conclusion,technological advances like geological target identification and“sweet spot”prediction,as well as deep,high-temperature and high-pressure engineering processes,are the guarantee for efficient exploration of conventional and unconventional deep and ultra-deep natural gas,which has great potential in the Sichuan Basin.
基金Supported by the National Science and Technology Major Project of China(2017ZX05035).
文摘Based on analysis of pore features and pore skeleton composition of shale,a“rigid elastic chimeric”pore skeleton model of shale gas reservoir was built.Pore deformation mechanisms leading to increase of shale porosity due to the pore skeleton deformation under overpressure were sorted out through analysis of stress on the shale pore and skeleton.After reviewing the difficulties and defects of existent porosity measurement methods,a dynamic deformed porosity measurement method was worked out and used to measure the porosity of overpressure Silurian Longmaxi Formation shale under real formation conditions in southern Sichuan Basin.The results show:(1)The shale reservoir is a mixture of inorganic rock particles and organic matter,which contains inorganic pores supported by rigid skeleton particles and organic pores supported by elastic-plastic particles,and thus has a special“rigid elastic chimeric”pore structure.(2)Under the action of formation overpressure,the inorganic pores have tiny changes that can be assumed that they don’t change in porosity,while the organic pores may have large deformation due to skeleton compression,leading to the increase of radius,connectivity and ultimately porosity of these pores.(3)The“dynamic”deformation porosity measurement method combining high injection pressure helium porosity measurement and kerosene porosity measurement method under ultra-high variable pressure can accurately measure porosity of unconnected micro-pores under normal pressure conditions,and also the porosity increment caused by plastic skeleton compression deformation.(4)The pore deformation mechanism of shale may result in the"abnormal"phenomenon that the shale under formation conditions has higher porosity than that under normal pressure,so the overpressure shale reservoir is not necessarily“ultra-low in porosity”,and can have porosity over 10%.Application of this method in Well L210 in southern Sichuan has confirmed its practicality and reliability.
基金supported by the National Natural Science Foundation of China"Research on acidizing mechanism under the coupling of temperature,fracture flow,acid-rock reaction,and stress damage for fractured carbonate rocks"(No.51704249)National Natural Science Foundation of China"Acid fracturing of low-permeability and tight oil and gas reservoirs"(No.51525404)the China Postdoctoral Science Foundation-General Program Research on acidizing mechanism of fracture network in deep,high-temperature,fractured carbonat rocks"(No.2017M623063).
文摘Acid fracturing is an indispensable technology in the efficient development of carbonate oil and gas rosarvoirs.As for deep and ultra-deep marine carbonate oil and gas reservoirs,however,existing acid fracturing technologies can hardly create complex fracture networks because of their particular engineering and geological characteristics.In order to realize the efficient three-dimensional development of deep and ultra-deep marine carbonate oil and gas reservoirs,this paper revealed the acid fracturing difficulties of this kind of reservoirs based on the engineering and geological characteristics of deep marine carbonate oil and gas reservoirs in China.Then,by taking the efficient three-dimensional development of deep and ultra-deep marine carbonate oiland gas reservoirs as the target,the technical conceptof three-dimensional acid fracturing(3D-AF)was putforward based on the techniques of volume acid fracturing and deep acid fracturing.In addition,its technical connotation was il lustrated,and its key technologies were described in detail.Finally,its development direction in the next step was pointed out.And the following research results were obtained.First,the 3D-AF technology contains three basic connotations:(1)selecting the corresponding acid penetration technology according to reservoir types so as to realize sufficient resarvoir stimulation on the plane;(2)creating complex acid-fracture volume with higher flow conductivity under high closed pressure;(3)deploying acid-fracture volume rationally along the long hole section so as to realize sufficient reservoir stimulation in the wellbore direction.Second,there are three key technologies of 3D-AF,i.e.,the technology for predicting the effective acid-penetrate distance under the coupling action of multi-feld,multi-scale and multi-fluid,the technology for optimizing the flow conductivity of complex acid-fracture volume,and the technology for precisely deploying acid in the long section of horizontal well or highly deviated well.Third,in order to promote the further development of 3D-AFtechnology,it is necessary to carry out researches on three technologies,i.e.,the technology for predicting and reducing the fracturing pressure of ultra-deep reservoir,the tech-nology for predicting the geometry of acid-fracture body ina strongly heterogeneous reservoir,and the staged reservoir production technology and new fluid technology with high temperature resistance,low reaction rate and low friction resistance coefficient for long hole sections(over 7000 m).
文摘The discovery of shock waves at observations sun like stars quasi-zero method. Shock waves associated with solar flares in Ha, it is shown that the amplitude of shock waves decreases to the edge of the sun, it follows that these waves are global. The conclusion is that the appearance of these waves may be connected with explosions in the deeper layers of the sun.
基金supported by National Fund Science and Technology Project(41672249 and 41602271)China Geological Survey Project(DD20160190)Shallow Geothermal Energy Development and Geothermal Reservoir Injection(SK201501)
文摘To reveal the influencing effect of the long-term straw mulching on the soil moisture, this paper employed the field experiment data in 2010 of a typical area of Taihang Mountains plain, observed the soil moisture dynamic regularities under different mulching patterns by virtue of depressimeter and neutron probe, analyzed the characteristics of soil water content and storage in different depths and seasons under the long-term straw mulching. The results showed that the long-term straw mulching can keep the soil moisture conservation of the deep, while decreased the shallow.(1) The long-term straw mulching can changed the type of soil water movement. If no straw mulching, the type is mainly evaporation-infiltration. And with straw mantle the type would change into infiltration. The number of zero flux plane would be reduced or absent.(2) The long-term straw mulching can increase the soil water reserves of the whole soil profile with the depth between 0 cm and 220 cm. But the soil water content of the layer from 30 cm to 80 cm decreased and the soil water content of the layer from 80 cm to 220 cm increased instead., The effect of soil moisture conservation on winter wheat is not obvious;(3) With no straw mulching, the depth of infiltration recharge by rainfall or irrigation is shallower than 80 cm. In a straw mulching, the influence depth is can extend to 120 cm;(4) With no straw mulching, there is a deep layer on the depth of 220 cm between March and June, while this layer will disappear with a long-term straw mulching.
基金Supported by the National Natural Science Foundation of China(U1663204)National Major Oil and Gas Project(2016ZX05014002-007)。
文摘Based on a large number of geological and geophysical data,the formation,fracture-caves types and hydrocarbon distribution of hoodoo-upland on the Ordovician karst slope in the Tahe area,Tarim Basin,are discussed by analyzing faults and strata thickness.The hoodoo-upland was made of high peaks and narrow valleys in the Ordovician karst slope during the Early Hercynian karst period,which were distributed along the NNE positive flower structure and had inherited evolution.The fault-fractures and fracture-vugs complex were extremely developed,with a thickness of 100 m.The cumulative oil production of 60% oil wells was more than 20×10^(4) t per well in the hoodoo-upland,where the residual thickness of the Ordovician Yingshan Formation was greater than karst depressions.Caves formed by the shelter of collapsed breccias were developed in the valleys.They were 1.6 to 13.5 m high,with a filling rate of 51.6%.The positive flower structure under the settings of strike-slip compression controlled the early formation of the hoodoo-upland on the karst slope,resulting in the differences of drainage distribution and karstification.Compared with the water-rich karst valley,the hoodoo-upland with lean water suffered weaker karstification,had thicker residual stratum,and was higher in terrain.In rainy season,the meteoric water flew and corrode along the cracks,forming a complex network of fractures and caves.Combined with inherited uplift and the effective match of the NNE deep faults,oil and gas continuously charged into the reservoir space in the upland,forming the hoodoo fracture-cave reservoir with vertically quasi continuous distribution,high hydrocarbon abundance and high production.
文摘DDCl-1 type seismic profiler for deep sediment layers is a large scale marine survey equipment. Its penetrating strata depth may reach to 1 km. This equipment suits surveys for continental shelf,seafloor trench and geological structure under seafloor etc. It suits also geological environment surveys of seafloor resources.The working principle, block diagrams composition and echo signal processing characteristics are presented, and some typical strata profiles are shown.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41872140, 41821002, 41911530189)the National Major Science and Technology Special Grant (Grant No. 2016ZX05006-007)+2 种基金the Special Fund for Taishan Scholar Project (Grant No. tsqn201909061)the Fundamental Research Funds for the Central Universities (Grant No. 20CX06067A)the Marine S&T Fund of Shandong Province for Pilot National Laboratory for Marine Science and Technology (Qingdao) (Grant No. 2021QNLM020001)。
文摘Clastic rock reservoirs in petroliferous basins are generally rich in feldspars. Feldspar dissolution has developed widely in clastic reservoirs, and the resulting secondary pores are crucial in deeply buried reservoirs. Based on a study of the diagenesis of clastic reservoirs in the Bohai Bay Basin, Tarim Basin, and Pearl River Mouth Basin and physical and numerical simulation experiments of fluid-rock interactions, this paper proposed a successive formation model of secondary pores via feldspar dissolution in deeply buried clastic reservoirs, considering the global research progresses in feldspar dissolution in clastic rocks. Feldspar dissolution can occur from shallow open systems to deep-ultra deep closed systems in petroliferous basins, resulting in the successive formation of secondary pores at different diagenetic stages. The successive mechanism includes three aspects. The first aspect is the succession of corrosive fluids that dissolve minerals. Meteoric freshwater dominates at the Earth’s surface and the early diagenetic A stage. Subsequently, organic acids and COformed via kerogen maturation dominate at the early diagenetic B stage to the middle diagenetic stage. COand organic acids formed via hydrocarbon oxidation in hydrocarbon reservoirs dominate at the middle diagenetic B stage to the late diagenetic stage. The second aspect is the successive formation processes of secondary pores via feldspar dissolution. Large-scale feldspar secondary pores identified in deep reservoirs include secondary pores formed at shallow-medium depths that are subsequently preserved into deep layers, as well as secondary pores formed at deep depths. Existing secondary pores in deeply buried reservoirs are the superposition of successively feldspar dissolution caused by different acids at different stages. The third aspect is a successive change in the feldspar alteration pathways and porosity enhancement/preservation effect. Open to semi-open diagenetic systems are developed from the Earth’s surface to the early diagenetic stage, and feldspar dissolution forms enhanced secondary pores. Nearly closed to closed diagenetic systems develop in the middle to late diagenetic stages, and feldspar dissolution forms redistributional secondary pores. The associated cementation causes compression resistance of the rock, which is favorable for the preservation of secondary pores in deep layers. These new insights extend the formation window of secondary pores in petroliferous basins from the traditional acid-oil generation window to a high-temperature gas generation window after hydrocarbon charging. The proposed model explains the genesis of deep-ultra deep high-quality reservoirs with low-permeability, medium-porosity and dominating feldspar secondary pores, which is significant for hydrocarbon exploration in deep to ultra-deep layers.
