The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the...The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the TiNb binary alloy system during spinodal decomposition,and then the formation mechanism of core-shell structure was revealed.In addition,the influences of initial temperature gradient,average temperature,and initial concentration distribution of the system on the core-shell structure were investigated.Results show that the initial concentration gradient is the key factor for forming the core-shell structure.Besides,larger initial temperature gradient and higher average temperature can promote the formation of core-shell structure,which can be stabilized by adjusting the initial concentration distribution of the Nb-rich region in TiNb binary alloy.As a theoretical basis,this research provides a novel and simple strategy for the preparation of TiNb-based alloys and other materials with peculiar core-shell structures and desirable mechanical and physical properties.展开更多
In this article,we conduct a study on mixed quasi-martingale Hardy spaces that are defined by means of the mixed L_(p)-norm.By utilizing Doob’s inequalities,we explore the atomic decomposition and quasi-martingale in...In this article,we conduct a study on mixed quasi-martingale Hardy spaces that are defined by means of the mixed L_(p)-norm.By utilizing Doob’s inequalities,we explore the atomic decomposition and quasi-martingale inequalities of mixed quasi-martingale Hardy spaces.Moreover,we furnish sufficient conditions for the boundedness ofσ-sublinear operators in these spaces.These findings extend the existing conclusions regarding mixed quasi-martingale Hardy spaces defined with the help of the mixed L_(p)-norm.展开更多
Noise interference critically impairs the stability and data accuracy of sensing systems.However,current suppression strategies fail to concurrently mitigate intrinsic system noise and extrinsic environmental noise.Th...Noise interference critically impairs the stability and data accuracy of sensing systems.However,current suppression strategies fail to concurrently mitigate intrinsic system noise and extrinsic environmental noise.This study introduces a composite denoising approach to address this challenge.This method is based on the ameliorated ellipse fitting algorithm(AEFA)and adaptive successive variational mode decomposition(ASVMD).This algorithm employs AEFA to eliminate system noise tightly coupled with direct-current and alternating-current components in the interference signal,thereby obtaining a phase signal containing only environmental noise.The ASVMD technique adaptively extracts environmental noise components predominantly present in the phase signal.To achieve optimal decomposition results automatically,the permutation entropy criterion is employed to refine decomposition parameters.The correlation coefficient is utilized to differentiate effective components from noise components in the decomposition results.Experimental results indicate that the combined AEFA and ASVMD algorithm effectively suppresses both system and environmental noises.When applied to 50 Hz vibration signal processing,the proposed approach achieves a noise reduction of 17.81 dB and a phase resolution of 35.14μrad/√Hz.Given the excellent performance of the noise suppression,the proposed approach holds great application potential in high-performance interferometric sensing systems.展开更多
Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits ...Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits in the future.However,designing catalysts that simultaneously exhibit high activity and long-term stability remains a significant challenge.Tuning the catalyst’s structure and electronic properties is an effective strategy for enhancing the reaction performance.In this work,a series of NixZr/ZSM-5 catalysts were prepared using the incipient wetness impregnation method,and the effect of Zr loadings on catalyst properties and performance was systematically investigated.The calcined and reduced catalysts were characterized by low-temperature N_(2)adsorption-desorption,XRD,SEM,H_(2)-TPR and XPS.The results showed that the addition of Zr significantly increased the specific surface area of the catalyst and reduced the metal particle size.Smaller NiO particles were found to enter the pores of the HZSM-5 support,and electronic interactions between NiO and ZrO_(2)markedly enhanced the metal-support interaction.The catalyst exhibited optimal catalytic performance at a Zr loading of 5%,achieving a maximum methane conversion of 68%at 625℃,maintaining activity for 900 min,and delivering a carbon yield of 1927%.Further increasing the Zr loading yielded only limited improvements in catalytic performance.Characterization of the spent catalysts and carbon products via TEM,Raman spectroscopy,and TGA revealed that the introduction of ZrO_(2)reduced metal sintering and promoted a shift in carbon nanofibers growth mode from tip-growth to base-growth.The mechanism of base-growth enabled the catalyst to maintain reaction activity for an extended period.展开更多
Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl m...Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl methylphosphonate(DIMP),a commonly used CWA surrogate,is widely studied to enhance our understanding of CWA behavior.The prevailing thermal decomposition model for DIMP,developed approximately 25 years ago,is based on data collected in nitrogen atmospheres at temperatures ranging from 700 K to 800 K.Despite its limitations,this model continues to serve as a foundation for research across various thermal and reactive environments,including combustion studies.Our recent experiments have extended the scope of decomposition analysis by examining DIMP in both nitrogen and zero air across a lower temperature range of 175℃ to 250℃.Infrared spectroscopy results under nitrogen align well with the established model;however,we observed that catalytic effects,stemming from decomposition byproducts and interactions with stainless steel surfaces,alter the reaction kinetics.In zero air environments,we observed a novel infrared absorption band.Spectral fitting suggests this band may represent a combination of propanal and acetone,while GCMS analysis points to vinyl formate and acetone as possible constituents.Although the precise identity of these new products remains unresolved,our findings clearly indicate that the existing decomposition model cannot be reliably extended to lower temperatures or non-nitrogen environments without further revisions.展开更多
Improved delay detached eddy simulation is performed to explore the flow features and aero-optical effects of turrets with different bottom cylinder height at a freestream Mach number Ma=0.7.Analysis of both the time-...Improved delay detached eddy simulation is performed to explore the flow features and aero-optical effects of turrets with different bottom cylinder height at a freestream Mach number Ma=0.7.Analysis of both the time-averaged and instantaneous flow features demonstrate that the shock motion causes the oscillation of separated shear layer.In flow analysis,two unsteady shock-wake-correlated modes are discerned:the asymmetric shifting mode and the symmetric breathing mode.With the increase of cylinder height,the relative energy of shock gradually increases,which goes from 26%to 59%.The proper orthogonal decomposition analysis yields the single frequency peak for the two dominant modes.The frequency peaks of shifting mode are generally at StD<0.23,while the frequency peaks of breathing mode are generally at StD>0.26.The dynamic mode decomposition analysis gives range of frequency peak.The frequency peaks of shifting mode are in the range of StD=0.11-0.23,and the frequency peaks of breathing mode are in range of StD=0.26-0.41.Optical distortion analysis indicates that the distortion calculated in five cases is linked to the breathing mode.When the beam passes through the turbulent wake,it exhibits the high-frequency and high-amplitude characteristics.展开更多
Succession is one of the most extensively studied ecological phenomena,yet debates persist about the importance of dispersal and external factors in driving this process.We aimed to quantify the influence of these fac...Succession is one of the most extensively studied ecological phenomena,yet debates persist about the importance of dispersal and external factors in driving this process.We aimed to quantify the influence of these factors by investigating how wing-related traits evolve across succession of blowfly(Diptera:Calliphoridae)communities in South Brazil.Rat carrion was placed in both forest and grassland habitats,and the associated blowfly communities were documented throughout the decomposition process.Using morphometric analysis,we measured wing and thorax traits and assessed trait changes over succession through mixed models.Our findings revealed that carrion succession follows distinct trajectories in forest and grassland environments.Specifically,we observed that Calliphora lopesi predominantly visited carcasses during the final phase of decomposition,resulting in significant differences in species composition and wing size between habitats.In forests,wing size increased toward the later stages of succession,whereas an opposite trend was observed in grasslands.Notably,these trait patterns were only evident at the species level,indicating that intraspecific trait variation is irrelevant.Stronger dispersers tend to arrive during the later stages of succession,suggesting that dispersal has a negligible role in shaping successional dynamics.Instead,environmental differences between habitats drive trait patterns throughout succession.Our results suggest that community composition in ephemeral resources is governed by deterministic processes and that successional stages can be predicted based on blowfly wing traits.Specifically,the presence of the large-winged C.lopesi indicates late decay,while the small-winged Chrysomia albiceps and Lucilia eximia are indicative of early decay.展开更多
The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.A...The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.Accordingly,comprehensive kinetic study by employing thermalgravimetric analysis at various heating rates was presented in this paper.Two main weight loss regions were observed during heating.The initial region corresponded to the dehydration of crystal water,whereas the subsequent region with overlapping peaks involved complex decomposition reactions.The overlapping peaks were separated into two individual reaction peaks and the activation energy of each peak was calculated using isoconversional kinetics methods.The activation energy of peak 1 exhibited a continual increase as the reaction conversion progressed,while that of peak 2 steadily decreased.The optimal kinetic models,identified as belonging to the random nucleation and subsequent growth category,provided valuable insights into the mechanism of the decomposition reactions.Furthermore,the adjustment factor was introduced to reconstruct the kinetic mechanism models,and the reconstructed models described the kinetic mechanism model more accurately for the decomposition reactions.This study enhanced the understanding of the thermochemical behavior and kinetic parameters of the lepidolite sulfation product decomposition reactions,further providing theoretical basis for promoting the selective extraction of lithium.展开更多
Accurate photovoltaic(PV)power generation forecasting is essential for the efficient integration of renewable energy into power grids.However,the nonlinear and non-stationary characteristics of PV power signals,driven...Accurate photovoltaic(PV)power generation forecasting is essential for the efficient integration of renewable energy into power grids.However,the nonlinear and non-stationary characteristics of PV power signals,driven by fluctuating weather conditions,pose significant challenges for reliable prediction.This study proposes a DOEP(Decomposition–Optimization–Error Correction–Prediction)framework,a hybrid forecasting approach that integrates adaptive signal decomposition,machine learning,metaheuristic optimization,and error correction.The PV power signal is first decomposed using CEEMDAN to extract multi-scale temporal features.Subsequently,the hyperparameters and window sizes of the LSSVM are optimized using a Segment-based EBQPSO strategy.The main novelty of the proposed DOEP framework lies in the incorporation of Segment-based EBQPSO as a structured optimization mechanism that balances elite exploitation and population diversity during LSSVM tuning within the CEEMDAN-based forecasting pipeline.This strategy effectively mitigates convergence instability and sensitivity to initialization,which are common limitations in existing hybrid PV forecasting models.Each IMF is then predicted individually and aggregated to generate an initial forecast.In the error-correction stage,the residual error series is modeled using LSTM,and the final prediction is obtained by combining the initial forecast with the predicted error component.The proposed framework is evaluated using two PV power plant datasets with different levels of complexity.The results demonstrate that DOEP consistently outperforms benchmark models across multiple error-based and goodness-of-fit metrics,achieving MSE reductions of approximately 15%–60%on the ResPV-BDG dataset and 37%–92%on the NREL dataset.Analyses of predicted vs.observed values and residual distributions further confirm the superior calibration and robustness of the proposed approach.Although the DOEP framework entails higher computational costs than single model methods,it delivers significantly improved accuracy and stability for PV power forecasting under complex operating conditions.展开更多
In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,eff...In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,efficiently combining the advantages of both images while overcoming their shortcomings is necessary.To handle this challenge,we developed an end-to-end IRI andVI fusionmethod based on frequency decomposition and enhancement.By applying concepts from frequency domain analysis,we used the layering mechanism to better capture the salient thermal targets from the IRIs and the rich textural information from the VIs,respectively,significantly boosting the image fusion quality and effectiveness.In addition,the backbone network combined Restormer Blocks and Dense Blocks;Restormer blocks utilize global attention to extract shallow features.Meanwhile,Dense Blocks ensure the integration between shallow and deep features,thereby avoiding the loss of shallow attributes.Extensive experiments on TNO and MSRS datasets demonstrated that the suggested method achieved state-of-the-art(SOTA)performance in various metrics:Entropy(EN),Mutual Information(MI),Standard Deviation(SD),The Structural Similarity Index Measure(SSIM),Fusion quality(Qabf),MI of the pixel(FMI_(pixel)),and modified Visual Information Fidelity(VIF_(m)).展开更多
Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics i...Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics in this region remains unexplored at finer scales.This study investigates how micro site conditions influence litter decomposition of 15 upper Andean species over time.A reciprocal translocation field experiment was conducted over 18 months in 14 permanent plots within four sites in Colombian Andean mountain forests.Each plot contained three litterbeds(microsites),each with the 15 species,harvested at 3,6,12 and 18 months,totaling 2520 litterbags.Different forest variables,including canopy openness,leaf area index,slope and depth of litter,were measured in each litterbed.ANOVAs and linear mixed models were used to assess variation between sites and plots respectively,while multiple linear regression analyses evaluated the effects of forest variables on decay rates over time at the micro site scale.Results showed differences in absolute decay rates between sites but consistent relative decay rates,indicating varying magnitudes of decomposition,yet maintaining the same order based on their litter quality.Decay rates varied between species,with more variation in labile species compared to recalcitrant ones.Despite substantial variation in forest characteristics within sites,their influence on litter decomposition was minimal and declined over time.This suggests that,at finer spatial scales,the forest microenvironment plays a lesser role in litter decomposition,with litter quality emerging as the primary driver.This study is a step towards understanding the fine-scale dynamics of litter decomposition in upper Andean tropical forests,highlighting the intricate interplay between microenvironmental factors and decomposition processes.展开更多
Battery energy storage systems bolster power grids’absorption capacity,however,battery safety issues remain a formidable challenge.Timely and pre-cise fault diagnosis,coupled with early-stage fault warn-ings,is cruci...Battery energy storage systems bolster power grids’absorption capacity,however,battery safety issues remain a formidable challenge.Timely and pre-cise fault diagnosis,coupled with early-stage fault warn-ings,is crucial.This study introduces an eigen decompo-sition-based multi-fault diagnosis approach for lithi-umion battery packs,enabling online diagnosis of short circuits,electrical connection faults,and voltage sensor malfunctions.By incorporating an interleaved measurement topology,precise fault type differentiation is achieved.Eigenvector matching analysis is employed to increase sensitivity to fault characteristics and enhance robustness.The interleaved topology can be seamlessly integrated using common voltage measurement solutions,eliminating the need for additional design complexities,while sensor number redundancy enhances fault tolerance of battery management systems(BMS).A cloud-side collaboration method is proposed,where the BMS functions as an edge device for specific data computations,while the parameters are fine-tuned by the server through big data analytics.This approach circumvents cumbersome server calculations,thereby curbing server cost escalation.The edge computing process is divided into two steps,with partial calculations often sufficient to evaluate battery safety,thus reducing the computational load on edge devices.Several battery tests are conducted,and the results confirm the method’s capability,feasibility,and validity in early-stage fault diagnosis.展开更多
Fungi play crucial roles in nutrient acquisition,plant growth promotion,and the enhancement of resistance to both abiotic and biotic stresses.However,studies on the fungal communities associated with peas (Pisum sativ...Fungi play crucial roles in nutrient acquisition,plant growth promotion,and the enhancement of resistance to both abiotic and biotic stresses.However,studies on the fungal communities associated with peas (Pisum sativum L.) remain limited.In this study,we systematically investigated the ecological effects of host niches (soil,root,stem,leaf,and pod) and genotypes on the diversity and composition of fungal communities in peas using a multi-level approach that encompassed pattern recognition (β-diversity decomposition),mechanism validation (neutral community model testing),and dynamic tracking methods (migration pathway source-tracking).The results revealed that the dominant fungal phyla across niches and genotypes were Ascomycota,Basidiomycota,and Mortierellomycota,and the community structures of the soil–plant continuum were primarily determined by the pea niches rather than genotypes.β-diversity decomposition was largely attributed to species replacement rather than richness differences,indicating strong niche specificity and microbial replacement across microhabitats.Neutral model analysis revealed that stochastic processes influenced genotypeassociated communities,while deterministic processes played a dominant role in niche-based community assembly.Source-tracking analysis identified niche-to-niche fungal migration,with Erysiphe,Fusarium,Cephaliophora,Ascobolus,Alternaria,and Aspergillus as the key genera.Migration rates from exogenous to endogenous niches were low (1.3–61.5%),whereas those within exogenous (64.4–83.7%) or endogenous (73.9–96.4%) compartments were much higher,suggesting that the pea epidermis acts as a selective barrier that filters and enriches microbial communities prior to internal colonization.This study provides comprehensive insights into the mechanisms of host filtering,enrichment and microbial sourcing,which increases our understanding of the assembly rules of the pea-associated fungal microbiome.展开更多
Pyrolysis technology has emerged as a promising method for converting waste polyurethane(WPU)from waste refrigerators into high-value chemicals.In this study,the copper(Cu)-assisted pyrolysis strategy was employed to ...Pyrolysis technology has emerged as a promising method for converting waste polyurethane(WPU)from waste refrigerators into high-value chemicals.In this study,the copper(Cu)-assisted pyrolysis strategy was employed to enhance the thermal degradation efficiency and product quality of WPU.Kinetic analysis revealed that the activation energy(E_(a)) of the Cu-assisted pyrolysis was 136.64 kJ·mol^(−1) and Cu-assisted pyrolysis was controlled by the combined processes of diffusion,nucleation and phase boundary reactions.Comprehensive product analysis,including gas chromatography–mass spectrometry and thermogravimetric Fourier transform infrared spectroscopy–mass spectrometry suggested that Cu promoted the cleavage of urethane bonds and accelerated the decarboxylation of isocyanates,increasing the yields of aniline and ethanol at lower temperatures.Meanwhile,Cu effectively suppressed the formation of halogenated and heterocyclic compounds by promoting the cleavage of C–X(X=Cl,F)bonds through electron transfer interactions.Thus,the E_(a) is decreased and the halogenated compounds is reduced.This work provides the theoretical basis for converting waste to high-valued products through co-pyrolysis techniques.展开更多
As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises s...As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises structural concerns,and the latter is of aerodynamic interest.Thus,panel aeroelasticity in shock-dominated flow represents a vital topic for the development and optimization of supersonic vehicles and propulsion systems.This review systematically summarizes recent advances in the methodologies applied to capture structural and fluid dynamics,including theoretical models,numerical simulations,and wind tunnel experiments.The application of data-driven modal decomposition,an advanced technique to extract physically crucial features,on the topic is introduced.From the perspective of FSIs,the distinctive aeroelastic behaviors in shock-dominated flow,including hysteresis phenomena and nonlinear responses,are highlighted.From the perspective of SBLIs,the modifications in their spatial and temporal characteristics imposed by the aeroelastic responses are emphasized.Motivated by the interaction between the shock waves and structural response,different strategies have been proposed to implement aeroelastic suppression and shock control,which have the potential to enhance structural safety and aerodynamic performance in the next generation of high-speed flight vehicles.展开更多
Objective:To evaluate the global,regional,and national burden and determinants of Acute Respiratory Infections(ARIs)among children and adolescents from 1990 to 2021.Methods:We analysed ARI mortality and disability-adj...Objective:To evaluate the global,regional,and national burden and determinants of Acute Respiratory Infections(ARIs)among children and adolescents from 1990 to 2021.Methods:We analysed ARI mortality and disability-adjusted life years(DALYs),stratified by age,sex,and economic development level based on data retrieved from the Global Burden of Disease study 2021.Decomposition and frontier analyses were employed to identify key drivers of burden variation and visualize potential reductions based on development levels.Results:Between 1990 and 2021,the global burden of ARIs showed a significant decline in both achievable age-standardized DALYs rate and age-standardized mortality rates(EAPC=-3.87 and-3.81,respectively).Different age groups and sex witnessed different levels of ARI burden,males experienced heavier burden than females and the 0-4 years-old group experienced heavier burden than other study age groups.Most of the 204 countries and territories experienced a downward trend of ARI burden,with slight increases observed only in Lesotho and Dominica.A negative correlation was found between the Socio-demographic Index and ARI burden.Decomposition analysis indicated that the significant decreases in deaths and DALYs were primarily driven by epidemiological changes.Conclusions:The global burden of ARIs among children and adolescents has declined over the past three decades,but substantial regional disparities persist.Targeted public health strategies are needed to address the continued ARI burden in high-risk regions and vulnerable age groups.展开更多
In view of the high computational complexity of traditional linear equalization algorithms in Orthogonal Time Frequency Space(OTFS)systems,a minimum mean square error(MMSE)channel equalization algorithm based on Matri...In view of the high computational complexity of traditional linear equalization algorithms in Orthogonal Time Frequency Space(OTFS)systems,a minimum mean square error(MMSE)channel equalization algorithm based on Matrix Chunking Lower and Upper Triangular Decomposition(CLU)is proposed.The proposed algorithm derives the structural properties of the chunked MMSE equalization matrix by leveraging the block diagonal structure of the Cyclic Prefix OTFS(CP-OTFS)time-domain channel matrix and the quasi-band structure of its constituent block matrices.On this basis,triangular decomposition combined with forward and backward substitution is used to avoid matrix inversion.This approach significantly reduces the complexity of the MMSE algorithm without sacrificing its performance.展开更多
Stator vanes especially vane suction sides of transonic turbines are subjected to high frequency excitation forces under many circumstances,and thus are exposed to the risk of high cycle fatigue.Therefore,it is necess...Stator vanes especially vane suction sides of transonic turbines are subjected to high frequency excitation forces under many circumstances,and thus are exposed to the risk of high cycle fatigue.Therefore,it is necessary to reveal the flow mechanism of this kind of excitations for potential prevention measures.In this paper,the traveling shock phenomenon in the transonic turbine stator/rotor gap is observed and the concept of‘Inter-Row Traveling Shock(IRTS)'is proposed through the unsteady Reynolds-Averaged Navier-Stokes(RANS)simulation of a typical highlyloaded transonic turbine stage.The characteristics of an IRTS were described and summarized in aspects of unsteady shock wave system,aerodynamic characteristics and motion.The probable forming mechanism of an IRTS was explained through a theoretical model and it was validated through correct prediction of the flow state parameter change across the IRTS.Since IRTSs would strike onto vane suction sides,the pressure oscillation dynamic modes on vane suction side corresponding to the characteristic frequencies associated with IRTS were extracted through Dynamic Mode Decomposition(DMD),from which the way and extent of the IRTS influences on vane aerodynamic excitation were revealed and evaluated.Over 82%pressure oscillation energy on vane suction side could be brought by the IRTS sweeping along with blade rotation.展开更多
Methyl mercaptan(CH_(3)SH)is notorious for global air pollution owing to its odorous characteristics and adverse health effects.Although CeO_(2) is currently regarded as a promising catalyst for CH_(3)SH decomposition...Methyl mercaptan(CH_(3)SH)is notorious for global air pollution owing to its odorous characteristics and adverse health effects.Although CeO_(2) is currently regarded as a promising catalyst for CH_(3)SH decomposition,the high conversion temperature followed by high energy consumption is still a bottleneck.Herein,the cobalt-doped CeO_(2) catalyst was synthesized by a facile one-pot preparation strategy and successfully reduces the decomposition temperature from 450 to 250℃.Further studies demonstrate that the excellent low-temperature catalytic activity of Co_(0.6)Ce_(0.4)O_(2-σ)is attributed to its abundant oxygen vacancies and reactive oxygen species.Oxygen vacancies promote the adsorption and dissociation of CH_(3)SH,while reactive oxygen species facilitate the decomposition of CH_(3)SH.Moreover,Co acts as a sacrificial agent for the adsorption of sulfur species in CH_(3)SH,while Ce is responsible for the adsorption and activation of CH_(3)SH as the active metal phase.Furthermore,the migration and transformation mechanism of CH_(3)SH on the surface of Co_(0.6)Ce_(0.4)O_(2-δ)was determined via in situ diffuse reflectance infrared Fourier transform spectra(in situ-DRIFTS).This work provides a new strategy to synthesize highperformance catalysts for decomposing sulfur-containing volatile organic compounds(VOCs)at low temperatures,which is beneficial to decreasing the energy consumption.展开更多
Renewable electricity-driven production of value-added sulfur and H_(2)via electrocatalytic H_(2)S decomposition represents a sustainable route to conventional thermocatalysis.Both the electrocatalyst and electrolyte ...Renewable electricity-driven production of value-added sulfur and H_(2)via electrocatalytic H_(2)S decomposition represents a sustainable route to conventional thermocatalysis.Both the electrocatalyst and electrolyte solution strongly impact the H_(2)S decomposition performance.Despite significant progress in developing sophisticated electrocatalysts,a well-designed electrolyte solution in conjunction with industrial catalysts is an attractive strategy to advance the industrialization process of electrocatalytic H_(2)S decomposition,but remains unexplored.Here,for the first time,we design a solid-liquid-gas three-phase indirect electrolysis system based on a kind of CS_(2)-N electrolyte solution and Ni-Mo_(2)C that can efficiently enable H_(2)S decomposition into valuable H_(2)and sulfur.Specifically,the solid-phase Ni-Mo_(2)C as a heterogeneous redox mediator presents excellent electrocatalytic efficiency for the H_(2)S removal efficiency of up to 99%,and the formation of liquid-phase sulfur product(CS_(2)-N electrolyte solution dissolves sulfur,yield up to 95%)with the generation of gas-phase H_(2)product(~1.32 mL min^(-1)),resulting in an interesting three-phase indirect electrolysis system.Remarkably,it enables the scale-up production(~6 g in a batch experiment)of sulfur with continuous operation for 120 h without attenuation.This work may inaugurate a new electrocatalytic H_(2)S decomposition avenue to explore porous metal materials and electrolyte systems in simultaneous production of value-added sulfur and H_(2).展开更多
基金National Natural Science Foundation of China(12372152)Guangdong Basic and Applied Basic Research Foundation(2023A1515011819,2024A1515012469)Shandong Provincial Natural Science Foundation(ZR2023MA058)。
文摘The core-shell structure in bulk TiNb binary alloy was designed and studied by phase-field simulations,where various core-shell structures were obtained by precise control of the initial and boundary conditions of the TiNb binary alloy system during spinodal decomposition,and then the formation mechanism of core-shell structure was revealed.In addition,the influences of initial temperature gradient,average temperature,and initial concentration distribution of the system on the core-shell structure were investigated.Results show that the initial concentration gradient is the key factor for forming the core-shell structure.Besides,larger initial temperature gradient and higher average temperature can promote the formation of core-shell structure,which can be stabilized by adjusting the initial concentration distribution of the Nb-rich region in TiNb binary alloy.As a theoretical basis,this research provides a novel and simple strategy for the preparation of TiNb-based alloys and other materials with peculiar core-shell structures and desirable mechanical and physical properties.
基金Supported by the National Natural Science Foundation of China(11871195)。
文摘In this article,we conduct a study on mixed quasi-martingale Hardy spaces that are defined by means of the mixed L_(p)-norm.By utilizing Doob’s inequalities,we explore the atomic decomposition and quasi-martingale inequalities of mixed quasi-martingale Hardy spaces.Moreover,we furnish sufficient conditions for the boundedness ofσ-sublinear operators in these spaces.These findings extend the existing conclusions regarding mixed quasi-martingale Hardy spaces defined with the help of the mixed L_(p)-norm.
文摘Noise interference critically impairs the stability and data accuracy of sensing systems.However,current suppression strategies fail to concurrently mitigate intrinsic system noise and extrinsic environmental noise.This study introduces a composite denoising approach to address this challenge.This method is based on the ameliorated ellipse fitting algorithm(AEFA)and adaptive successive variational mode decomposition(ASVMD).This algorithm employs AEFA to eliminate system noise tightly coupled with direct-current and alternating-current components in the interference signal,thereby obtaining a phase signal containing only environmental noise.The ASVMD technique adaptively extracts environmental noise components predominantly present in the phase signal.To achieve optimal decomposition results automatically,the permutation entropy criterion is employed to refine decomposition parameters.The correlation coefficient is utilized to differentiate effective components from noise components in the decomposition results.Experimental results indicate that the combined AEFA and ASVMD algorithm effectively suppresses both system and environmental noises.When applied to 50 Hz vibration signal processing,the proposed approach achieves a noise reduction of 17.81 dB and a phase resolution of 35.14μrad/√Hz.Given the excellent performance of the noise suppression,the proposed approach holds great application potential in high-performance interferometric sensing systems.
基金Supported by Innovative Research Groups of the National Natural Science Foundation of China(22021004)。
文摘Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits in the future.However,designing catalysts that simultaneously exhibit high activity and long-term stability remains a significant challenge.Tuning the catalyst’s structure and electronic properties is an effective strategy for enhancing the reaction performance.In this work,a series of NixZr/ZSM-5 catalysts were prepared using the incipient wetness impregnation method,and the effect of Zr loadings on catalyst properties and performance was systematically investigated.The calcined and reduced catalysts were characterized by low-temperature N_(2)adsorption-desorption,XRD,SEM,H_(2)-TPR and XPS.The results showed that the addition of Zr significantly increased the specific surface area of the catalyst and reduced the metal particle size.Smaller NiO particles were found to enter the pores of the HZSM-5 support,and electronic interactions between NiO and ZrO_(2)markedly enhanced the metal-support interaction.The catalyst exhibited optimal catalytic performance at a Zr loading of 5%,achieving a maximum methane conversion of 68%at 625℃,maintaining activity for 900 min,and delivering a carbon yield of 1927%.Further increasing the Zr loading yielded only limited improvements in catalytic performance.Characterization of the spent catalysts and carbon products via TEM,Raman spectroscopy,and TGA revealed that the introduction of ZrO_(2)reduced metal sintering and promoted a shift in carbon nanofibers growth mode from tip-growth to base-growth.The mechanism of base-growth enabled the catalyst to maintain reaction activity for an extended period.
基金sponsored by the Department of Defense,Defense Threat Reduction Agency under the Materials Science in Extreme Environments University Research Alliance,HDTRA1-20-2-0001。
文摘Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl methylphosphonate(DIMP),a commonly used CWA surrogate,is widely studied to enhance our understanding of CWA behavior.The prevailing thermal decomposition model for DIMP,developed approximately 25 years ago,is based on data collected in nitrogen atmospheres at temperatures ranging from 700 K to 800 K.Despite its limitations,this model continues to serve as a foundation for research across various thermal and reactive environments,including combustion studies.Our recent experiments have extended the scope of decomposition analysis by examining DIMP in both nitrogen and zero air across a lower temperature range of 175℃ to 250℃.Infrared spectroscopy results under nitrogen align well with the established model;however,we observed that catalytic effects,stemming from decomposition byproducts and interactions with stainless steel surfaces,alter the reaction kinetics.In zero air environments,we observed a novel infrared absorption band.Spectral fitting suggests this band may represent a combination of propanal and acetone,while GCMS analysis points to vinyl formate and acetone as possible constituents.Although the precise identity of these new products remains unresolved,our findings clearly indicate that the existing decomposition model cannot be reliably extended to lower temperatures or non-nitrogen environments without further revisions.
基金funded by the National Key Lab Foundation,China(No.2020KLF030101)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University,China(No.CX2025031)Shaanxi Innovative Research Team of Artificial Intelligence for Fluid Mechanics,China(No.2024RS-CXTD-16)。
文摘Improved delay detached eddy simulation is performed to explore the flow features and aero-optical effects of turrets with different bottom cylinder height at a freestream Mach number Ma=0.7.Analysis of both the time-averaged and instantaneous flow features demonstrate that the shock motion causes the oscillation of separated shear layer.In flow analysis,two unsteady shock-wake-correlated modes are discerned:the asymmetric shifting mode and the symmetric breathing mode.With the increase of cylinder height,the relative energy of shock gradually increases,which goes from 26%to 59%.The proper orthogonal decomposition analysis yields the single frequency peak for the two dominant modes.The frequency peaks of shifting mode are generally at StD<0.23,while the frequency peaks of breathing mode are generally at StD>0.26.The dynamic mode decomposition analysis gives range of frequency peak.The frequency peaks of shifting mode are in the range of StD=0.11-0.23,and the frequency peaks of breathing mode are in range of StD=0.26-0.41.Optical distortion analysis indicates that the distortion calculated in five cases is linked to the breathing mode.When the beam passes through the turbulent wake,it exhibits the high-frequency and high-amplitude characteristics.
文摘Succession is one of the most extensively studied ecological phenomena,yet debates persist about the importance of dispersal and external factors in driving this process.We aimed to quantify the influence of these factors by investigating how wing-related traits evolve across succession of blowfly(Diptera:Calliphoridae)communities in South Brazil.Rat carrion was placed in both forest and grassland habitats,and the associated blowfly communities were documented throughout the decomposition process.Using morphometric analysis,we measured wing and thorax traits and assessed trait changes over succession through mixed models.Our findings revealed that carrion succession follows distinct trajectories in forest and grassland environments.Specifically,we observed that Calliphora lopesi predominantly visited carcasses during the final phase of decomposition,resulting in significant differences in species composition and wing size between habitats.In forests,wing size increased toward the later stages of succession,whereas an opposite trend was observed in grasslands.Notably,these trait patterns were only evident at the species level,indicating that intraspecific trait variation is irrelevant.Stronger dispersers tend to arrive during the later stages of succession,suggesting that dispersal has a negligible role in shaping successional dynamics.Instead,environmental differences between habitats drive trait patterns throughout succession.Our results suggest that community composition in ephemeral resources is governed by deterministic processes and that successional stages can be predicted based on blowfly wing traits.Specifically,the presence of the large-winged C.lopesi indicates late decay,while the small-winged Chrysomia albiceps and Lucilia eximia are indicative of early decay.
基金financially supported by the National Natural Science Foundation of China(Nos.52034002 and U2202254)the Fundamental Research Funds for the Central Universities,China(No.FRF-TT-19-001)。
文摘The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.Accordingly,comprehensive kinetic study by employing thermalgravimetric analysis at various heating rates was presented in this paper.Two main weight loss regions were observed during heating.The initial region corresponded to the dehydration of crystal water,whereas the subsequent region with overlapping peaks involved complex decomposition reactions.The overlapping peaks were separated into two individual reaction peaks and the activation energy of each peak was calculated using isoconversional kinetics methods.The activation energy of peak 1 exhibited a continual increase as the reaction conversion progressed,while that of peak 2 steadily decreased.The optimal kinetic models,identified as belonging to the random nucleation and subsequent growth category,provided valuable insights into the mechanism of the decomposition reactions.Furthermore,the adjustment factor was introduced to reconstruct the kinetic mechanism models,and the reconstructed models described the kinetic mechanism model more accurately for the decomposition reactions.This study enhanced the understanding of the thermochemical behavior and kinetic parameters of the lepidolite sulfation product decomposition reactions,further providing theoretical basis for promoting the selective extraction of lithium.
基金support from the Ministry of Science and Technology of Taiwan(Contract Nos.113-2221-E-011-130-MY2 and 113-2218-E-011-002)the support from Intelligent Manufactur-ing Innovation Center(IMIC),National Taiwan University of Science and Technology(NTUST),Taipei,Taiwan.
文摘Accurate photovoltaic(PV)power generation forecasting is essential for the efficient integration of renewable energy into power grids.However,the nonlinear and non-stationary characteristics of PV power signals,driven by fluctuating weather conditions,pose significant challenges for reliable prediction.This study proposes a DOEP(Decomposition–Optimization–Error Correction–Prediction)framework,a hybrid forecasting approach that integrates adaptive signal decomposition,machine learning,metaheuristic optimization,and error correction.The PV power signal is first decomposed using CEEMDAN to extract multi-scale temporal features.Subsequently,the hyperparameters and window sizes of the LSSVM are optimized using a Segment-based EBQPSO strategy.The main novelty of the proposed DOEP framework lies in the incorporation of Segment-based EBQPSO as a structured optimization mechanism that balances elite exploitation and population diversity during LSSVM tuning within the CEEMDAN-based forecasting pipeline.This strategy effectively mitigates convergence instability and sensitivity to initialization,which are common limitations in existing hybrid PV forecasting models.Each IMF is then predicted individually and aggregated to generate an initial forecast.In the error-correction stage,the residual error series is modeled using LSTM,and the final prediction is obtained by combining the initial forecast with the predicted error component.The proposed framework is evaluated using two PV power plant datasets with different levels of complexity.The results demonstrate that DOEP consistently outperforms benchmark models across multiple error-based and goodness-of-fit metrics,achieving MSE reductions of approximately 15%–60%on the ResPV-BDG dataset and 37%–92%on the NREL dataset.Analyses of predicted vs.observed values and residual distributions further confirm the superior calibration and robustness of the proposed approach.Although the DOEP framework entails higher computational costs than single model methods,it delivers significantly improved accuracy and stability for PV power forecasting under complex operating conditions.
基金funded by Anhui Province University Key Science and Technology Project(2024AH053415)Anhui Province University Major Science and Technology Project(2024AH040229)+3 种基金Talent Research Initiation Fund Project of Tongling University(2024tlxyrc019)Tongling University School-Level Scientific Research Project(2024tlxyptZD07)TheUniversity Synergy Innovation Programof Anhui Province(GXXT-2023-050)Tongling City Science and Technology Major Special Project(Unveiling and Commanding Model)(200401JB004).
文摘In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,efficiently combining the advantages of both images while overcoming their shortcomings is necessary.To handle this challenge,we developed an end-to-end IRI andVI fusionmethod based on frequency decomposition and enhancement.By applying concepts from frequency domain analysis,we used the layering mechanism to better capture the salient thermal targets from the IRIs and the rich textural information from the VIs,respectively,significantly boosting the image fusion quality and effectiveness.In addition,the backbone network combined Restormer Blocks and Dense Blocks;Restormer blocks utilize global attention to extract shallow features.Meanwhile,Dense Blocks ensure the integration between shallow and deep features,thereby avoiding the loss of shallow attributes.Extensive experiments on TNO and MSRS datasets demonstrated that the suggested method achieved state-of-the-art(SOTA)performance in various metrics:Entropy(EN),Mutual Information(MI),Standard Deviation(SD),The Structural Similarity Index Measure(SSIM),Fusion quality(Qabf),MI of the pixel(FMI_(pixel)),and modified Visual Information Fidelity(VIF_(m)).
基金supported by the Universidad del Rosario(Small grant ID:IV-FPD003)。
文摘Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics in this region remains unexplored at finer scales.This study investigates how micro site conditions influence litter decomposition of 15 upper Andean species over time.A reciprocal translocation field experiment was conducted over 18 months in 14 permanent plots within four sites in Colombian Andean mountain forests.Each plot contained three litterbeds(microsites),each with the 15 species,harvested at 3,6,12 and 18 months,totaling 2520 litterbags.Different forest variables,including canopy openness,leaf area index,slope and depth of litter,were measured in each litterbed.ANOVAs and linear mixed models were used to assess variation between sites and plots respectively,while multiple linear regression analyses evaluated the effects of forest variables on decay rates over time at the micro site scale.Results showed differences in absolute decay rates between sites but consistent relative decay rates,indicating varying magnitudes of decomposition,yet maintaining the same order based on their litter quality.Decay rates varied between species,with more variation in labile species compared to recalcitrant ones.Despite substantial variation in forest characteristics within sites,their influence on litter decomposition was minimal and declined over time.This suggests that,at finer spatial scales,the forest microenvironment plays a lesser role in litter decomposition,with litter quality emerging as the primary driver.This study is a step towards understanding the fine-scale dynamics of litter decomposition in upper Andean tropical forests,highlighting the intricate interplay between microenvironmental factors and decomposition processes.
基金supported in part by the National Natural Science Foundation of China(No.62133007)Shandong Provincial Key Research and Development Program(No.2024CXPT052).
文摘Battery energy storage systems bolster power grids’absorption capacity,however,battery safety issues remain a formidable challenge.Timely and pre-cise fault diagnosis,coupled with early-stage fault warn-ings,is crucial.This study introduces an eigen decompo-sition-based multi-fault diagnosis approach for lithi-umion battery packs,enabling online diagnosis of short circuits,electrical connection faults,and voltage sensor malfunctions.By incorporating an interleaved measurement topology,precise fault type differentiation is achieved.Eigenvector matching analysis is employed to increase sensitivity to fault characteristics and enhance robustness.The interleaved topology can be seamlessly integrated using common voltage measurement solutions,eliminating the need for additional design complexities,while sensor number redundancy enhances fault tolerance of battery management systems(BMS).A cloud-side collaboration method is proposed,where the BMS functions as an edge device for specific data computations,while the parameters are fine-tuned by the server through big data analytics.This approach circumvents cumbersome server calculations,thereby curbing server cost escalation.The edge computing process is divided into two steps,with partial calculations often sufficient to evaluate battery safety,thus reducing the computational load on edge devices.Several battery tests are conducted,and the results confirm the method’s capability,feasibility,and validity in early-stage fault diagnosis.
基金financial y supported by the National Key Research and Development Program of China (2023YFD1900902)the Joint Funds of the Zhejiang Provincial Natural Science Foundation of China (LLSSZ24C030001)+1 种基金the Earmarked Fund for China Agriculture Research System (CARS-08-G-09)sponsored by the K.C.Wong Magna Fund of Ningbo University,China。
文摘Fungi play crucial roles in nutrient acquisition,plant growth promotion,and the enhancement of resistance to both abiotic and biotic stresses.However,studies on the fungal communities associated with peas (Pisum sativum L.) remain limited.In this study,we systematically investigated the ecological effects of host niches (soil,root,stem,leaf,and pod) and genotypes on the diversity and composition of fungal communities in peas using a multi-level approach that encompassed pattern recognition (β-diversity decomposition),mechanism validation (neutral community model testing),and dynamic tracking methods (migration pathway source-tracking).The results revealed that the dominant fungal phyla across niches and genotypes were Ascomycota,Basidiomycota,and Mortierellomycota,and the community structures of the soil–plant continuum were primarily determined by the pea niches rather than genotypes.β-diversity decomposition was largely attributed to species replacement rather than richness differences,indicating strong niche specificity and microbial replacement across microhabitats.Neutral model analysis revealed that stochastic processes influenced genotypeassociated communities,while deterministic processes played a dominant role in niche-based community assembly.Source-tracking analysis identified niche-to-niche fungal migration,with Erysiphe,Fusarium,Cephaliophora,Ascobolus,Alternaria,and Aspergillus as the key genera.Migration rates from exogenous to endogenous niches were low (1.3–61.5%),whereas those within exogenous (64.4–83.7%) or endogenous (73.9–96.4%) compartments were much higher,suggesting that the pea epidermis acts as a selective barrier that filters and enriches microbial communities prior to internal colonization.This study provides comprehensive insights into the mechanisms of host filtering,enrichment and microbial sourcing,which increases our understanding of the assembly rules of the pea-associated fungal microbiome.
基金supported by the Natural Science Foundation of Shandong Province(ZR2022QE042)China Postdoctoral Science Foundation(2023M741856)the National Natural Science Foundation of China(52172093).
文摘Pyrolysis technology has emerged as a promising method for converting waste polyurethane(WPU)from waste refrigerators into high-value chemicals.In this study,the copper(Cu)-assisted pyrolysis strategy was employed to enhance the thermal degradation efficiency and product quality of WPU.Kinetic analysis revealed that the activation energy(E_(a)) of the Cu-assisted pyrolysis was 136.64 kJ·mol^(−1) and Cu-assisted pyrolysis was controlled by the combined processes of diffusion,nucleation and phase boundary reactions.Comprehensive product analysis,including gas chromatography–mass spectrometry and thermogravimetric Fourier transform infrared spectroscopy–mass spectrometry suggested that Cu promoted the cleavage of urethane bonds and accelerated the decarboxylation of isocyanates,increasing the yields of aniline and ethanol at lower temperatures.Meanwhile,Cu effectively suppressed the formation of halogenated and heterocyclic compounds by promoting the cleavage of C–X(X=Cl,F)bonds through electron transfer interactions.Thus,the E_(a) is decreased and the halogenated compounds is reduced.This work provides the theoretical basis for converting waste to high-valued products through co-pyrolysis techniques.
基金supported by the National Natural Science Foundation of China(No.12372233)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University,China(No.25GH01020005)the“111 Project”of China(No.B17037)。
文摘As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises structural concerns,and the latter is of aerodynamic interest.Thus,panel aeroelasticity in shock-dominated flow represents a vital topic for the development and optimization of supersonic vehicles and propulsion systems.This review systematically summarizes recent advances in the methodologies applied to capture structural and fluid dynamics,including theoretical models,numerical simulations,and wind tunnel experiments.The application of data-driven modal decomposition,an advanced technique to extract physically crucial features,on the topic is introduced.From the perspective of FSIs,the distinctive aeroelastic behaviors in shock-dominated flow,including hysteresis phenomena and nonlinear responses,are highlighted.From the perspective of SBLIs,the modifications in their spatial and temporal characteristics imposed by the aeroelastic responses are emphasized.Motivated by the interaction between the shock waves and structural response,different strategies have been proposed to implement aeroelastic suppression and shock control,which have the potential to enhance structural safety and aerodynamic performance in the next generation of high-speed flight vehicles.
文摘Objective:To evaluate the global,regional,and national burden and determinants of Acute Respiratory Infections(ARIs)among children and adolescents from 1990 to 2021.Methods:We analysed ARI mortality and disability-adjusted life years(DALYs),stratified by age,sex,and economic development level based on data retrieved from the Global Burden of Disease study 2021.Decomposition and frontier analyses were employed to identify key drivers of burden variation and visualize potential reductions based on development levels.Results:Between 1990 and 2021,the global burden of ARIs showed a significant decline in both achievable age-standardized DALYs rate and age-standardized mortality rates(EAPC=-3.87 and-3.81,respectively).Different age groups and sex witnessed different levels of ARI burden,males experienced heavier burden than females and the 0-4 years-old group experienced heavier burden than other study age groups.Most of the 204 countries and territories experienced a downward trend of ARI burden,with slight increases observed only in Lesotho and Dominica.A negative correlation was found between the Socio-demographic Index and ARI burden.Decomposition analysis indicated that the significant decreases in deaths and DALYs were primarily driven by epidemiological changes.Conclusions:The global burden of ARIs among children and adolescents has declined over the past three decades,but substantial regional disparities persist.Targeted public health strategies are needed to address the continued ARI burden in high-risk regions and vulnerable age groups.
基金supported by ZTE Industry-University-Institute Cooperation Funds under Grant No.KY10800230005。
文摘In view of the high computational complexity of traditional linear equalization algorithms in Orthogonal Time Frequency Space(OTFS)systems,a minimum mean square error(MMSE)channel equalization algorithm based on Matrix Chunking Lower and Upper Triangular Decomposition(CLU)is proposed.The proposed algorithm derives the structural properties of the chunked MMSE equalization matrix by leveraging the block diagonal structure of the Cyclic Prefix OTFS(CP-OTFS)time-domain channel matrix and the quasi-band structure of its constituent block matrices.On this basis,triangular decomposition combined with forward and backward substitution is used to avoid matrix inversion.This approach significantly reduces the complexity of the MMSE algorithm without sacrificing its performance.
文摘Stator vanes especially vane suction sides of transonic turbines are subjected to high frequency excitation forces under many circumstances,and thus are exposed to the risk of high cycle fatigue.Therefore,it is necessary to reveal the flow mechanism of this kind of excitations for potential prevention measures.In this paper,the traveling shock phenomenon in the transonic turbine stator/rotor gap is observed and the concept of‘Inter-Row Traveling Shock(IRTS)'is proposed through the unsteady Reynolds-Averaged Navier-Stokes(RANS)simulation of a typical highlyloaded transonic turbine stage.The characteristics of an IRTS were described and summarized in aspects of unsteady shock wave system,aerodynamic characteristics and motion.The probable forming mechanism of an IRTS was explained through a theoretical model and it was validated through correct prediction of the flow state parameter change across the IRTS.Since IRTSs would strike onto vane suction sides,the pressure oscillation dynamic modes on vane suction side corresponding to the characteristic frequencies associated with IRTS were extracted through Dynamic Mode Decomposition(DMD),from which the way and extent of the IRTS influences on vane aerodynamic excitation were revealed and evaluated.Over 82%pressure oscillation energy on vane suction side could be brought by the IRTS sweeping along with blade rotation.
基金Project supported by the National Natural Science Foundation of China(22306081,42030712,42477109,21966018 and 22106055)National Key R&D Program of China(2023YFB3810800)Yunnan Major Scientific and Technological Projects(202302AG050002)。
文摘Methyl mercaptan(CH_(3)SH)is notorious for global air pollution owing to its odorous characteristics and adverse health effects.Although CeO_(2) is currently regarded as a promising catalyst for CH_(3)SH decomposition,the high conversion temperature followed by high energy consumption is still a bottleneck.Herein,the cobalt-doped CeO_(2) catalyst was synthesized by a facile one-pot preparation strategy and successfully reduces the decomposition temperature from 450 to 250℃.Further studies demonstrate that the excellent low-temperature catalytic activity of Co_(0.6)Ce_(0.4)O_(2-σ)is attributed to its abundant oxygen vacancies and reactive oxygen species.Oxygen vacancies promote the adsorption and dissociation of CH_(3)SH,while reactive oxygen species facilitate the decomposition of CH_(3)SH.Moreover,Co acts as a sacrificial agent for the adsorption of sulfur species in CH_(3)SH,while Ce is responsible for the adsorption and activation of CH_(3)SH as the active metal phase.Furthermore,the migration and transformation mechanism of CH_(3)SH on the surface of Co_(0.6)Ce_(0.4)O_(2-δ)was determined via in situ diffuse reflectance infrared Fourier transform spectra(in situ-DRIFTS).This work provides a new strategy to synthesize highperformance catalysts for decomposing sulfur-containing volatile organic compounds(VOCs)at low temperatures,which is beneficial to decreasing the energy consumption.
基金supported by the National Natural Science Foundation of China(No.22278439 and 21776313).
文摘Renewable electricity-driven production of value-added sulfur and H_(2)via electrocatalytic H_(2)S decomposition represents a sustainable route to conventional thermocatalysis.Both the electrocatalyst and electrolyte solution strongly impact the H_(2)S decomposition performance.Despite significant progress in developing sophisticated electrocatalysts,a well-designed electrolyte solution in conjunction with industrial catalysts is an attractive strategy to advance the industrialization process of electrocatalytic H_(2)S decomposition,but remains unexplored.Here,for the first time,we design a solid-liquid-gas three-phase indirect electrolysis system based on a kind of CS_(2)-N electrolyte solution and Ni-Mo_(2)C that can efficiently enable H_(2)S decomposition into valuable H_(2)and sulfur.Specifically,the solid-phase Ni-Mo_(2)C as a heterogeneous redox mediator presents excellent electrocatalytic efficiency for the H_(2)S removal efficiency of up to 99%,and the formation of liquid-phase sulfur product(CS_(2)-N electrolyte solution dissolves sulfur,yield up to 95%)with the generation of gas-phase H_(2)product(~1.32 mL min^(-1)),resulting in an interesting three-phase indirect electrolysis system.Remarkably,it enables the scale-up production(~6 g in a batch experiment)of sulfur with continuous operation for 120 h without attenuation.This work may inaugurate a new electrocatalytic H_(2)S decomposition avenue to explore porous metal materials and electrolyte systems in simultaneous production of value-added sulfur and H_(2).
