In this article,we conduct a study on mixed quasi-martingale Hardy spaces that are defined by means of the mixed L_(p)-norm.By utilizing Doob’s inequalities,we explore the atomic decomposition and quasi-martingale in...In this article,we conduct a study on mixed quasi-martingale Hardy spaces that are defined by means of the mixed L_(p)-norm.By utilizing Doob’s inequalities,we explore the atomic decomposition and quasi-martingale inequalities of mixed quasi-martingale Hardy spaces.Moreover,we furnish sufficient conditions for the boundedness ofσ-sublinear operators in these spaces.These findings extend the existing conclusions regarding mixed quasi-martingale Hardy spaces defined with the help of the mixed L_(p)-norm.展开更多
Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits ...Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits in the future.However,designing catalysts that simultaneously exhibit high activity and long-term stability remains a significant challenge.Tuning the catalyst’s structure and electronic properties is an effective strategy for enhancing the reaction performance.In this work,a series of NixZr/ZSM-5 catalysts were prepared using the incipient wetness impregnation method,and the effect of Zr loadings on catalyst properties and performance was systematically investigated.The calcined and reduced catalysts were characterized by low-temperature N_(2)adsorption-desorption,XRD,SEM,H_(2)-TPR and XPS.The results showed that the addition of Zr significantly increased the specific surface area of the catalyst and reduced the metal particle size.Smaller NiO particles were found to enter the pores of the HZSM-5 support,and electronic interactions between NiO and ZrO_(2)markedly enhanced the metal-support interaction.The catalyst exhibited optimal catalytic performance at a Zr loading of 5%,achieving a maximum methane conversion of 68%at 625℃,maintaining activity for 900 min,and delivering a carbon yield of 1927%.Further increasing the Zr loading yielded only limited improvements in catalytic performance.Characterization of the spent catalysts and carbon products via TEM,Raman spectroscopy,and TGA revealed that the introduction of ZrO_(2)reduced metal sintering and promoted a shift in carbon nanofibers growth mode from tip-growth to base-growth.The mechanism of base-growth enabled the catalyst to maintain reaction activity for an extended period.展开更多
Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl m...Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl methylphosphonate(DIMP),a commonly used CWA surrogate,is widely studied to enhance our understanding of CWA behavior.The prevailing thermal decomposition model for DIMP,developed approximately 25 years ago,is based on data collected in nitrogen atmospheres at temperatures ranging from 700 K to 800 K.Despite its limitations,this model continues to serve as a foundation for research across various thermal and reactive environments,including combustion studies.Our recent experiments have extended the scope of decomposition analysis by examining DIMP in both nitrogen and zero air across a lower temperature range of 175℃ to 250℃.Infrared spectroscopy results under nitrogen align well with the established model;however,we observed that catalytic effects,stemming from decomposition byproducts and interactions with stainless steel surfaces,alter the reaction kinetics.In zero air environments,we observed a novel infrared absorption band.Spectral fitting suggests this band may represent a combination of propanal and acetone,while GCMS analysis points to vinyl formate and acetone as possible constituents.Although the precise identity of these new products remains unresolved,our findings clearly indicate that the existing decomposition model cannot be reliably extended to lower temperatures or non-nitrogen environments without further revisions.展开更多
The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.A...The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.Accordingly,comprehensive kinetic study by employing thermalgravimetric analysis at various heating rates was presented in this paper.Two main weight loss regions were observed during heating.The initial region corresponded to the dehydration of crystal water,whereas the subsequent region with overlapping peaks involved complex decomposition reactions.The overlapping peaks were separated into two individual reaction peaks and the activation energy of each peak was calculated using isoconversional kinetics methods.The activation energy of peak 1 exhibited a continual increase as the reaction conversion progressed,while that of peak 2 steadily decreased.The optimal kinetic models,identified as belonging to the random nucleation and subsequent growth category,provided valuable insights into the mechanism of the decomposition reactions.Furthermore,the adjustment factor was introduced to reconstruct the kinetic mechanism models,and the reconstructed models described the kinetic mechanism model more accurately for the decomposition reactions.This study enhanced the understanding of the thermochemical behavior and kinetic parameters of the lepidolite sulfation product decomposition reactions,further providing theoretical basis for promoting the selective extraction of lithium.展开更多
Accurate photovoltaic(PV)power generation forecasting is essential for the efficient integration of renewable energy into power grids.However,the nonlinear and non-stationary characteristics of PV power signals,driven...Accurate photovoltaic(PV)power generation forecasting is essential for the efficient integration of renewable energy into power grids.However,the nonlinear and non-stationary characteristics of PV power signals,driven by fluctuating weather conditions,pose significant challenges for reliable prediction.This study proposes a DOEP(Decomposition–Optimization–Error Correction–Prediction)framework,a hybrid forecasting approach that integrates adaptive signal decomposition,machine learning,metaheuristic optimization,and error correction.The PV power signal is first decomposed using CEEMDAN to extract multi-scale temporal features.Subsequently,the hyperparameters and window sizes of the LSSVM are optimized using a Segment-based EBQPSO strategy.The main novelty of the proposed DOEP framework lies in the incorporation of Segment-based EBQPSO as a structured optimization mechanism that balances elite exploitation and population diversity during LSSVM tuning within the CEEMDAN-based forecasting pipeline.This strategy effectively mitigates convergence instability and sensitivity to initialization,which are common limitations in existing hybrid PV forecasting models.Each IMF is then predicted individually and aggregated to generate an initial forecast.In the error-correction stage,the residual error series is modeled using LSTM,and the final prediction is obtained by combining the initial forecast with the predicted error component.The proposed framework is evaluated using two PV power plant datasets with different levels of complexity.The results demonstrate that DOEP consistently outperforms benchmark models across multiple error-based and goodness-of-fit metrics,achieving MSE reductions of approximately 15%–60%on the ResPV-BDG dataset and 37%–92%on the NREL dataset.Analyses of predicted vs.observed values and residual distributions further confirm the superior calibration and robustness of the proposed approach.Although the DOEP framework entails higher computational costs than single model methods,it delivers significantly improved accuracy and stability for PV power forecasting under complex operating conditions.展开更多
In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,eff...In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,efficiently combining the advantages of both images while overcoming their shortcomings is necessary.To handle this challenge,we developed an end-to-end IRI andVI fusionmethod based on frequency decomposition and enhancement.By applying concepts from frequency domain analysis,we used the layering mechanism to better capture the salient thermal targets from the IRIs and the rich textural information from the VIs,respectively,significantly boosting the image fusion quality and effectiveness.In addition,the backbone network combined Restormer Blocks and Dense Blocks;Restormer blocks utilize global attention to extract shallow features.Meanwhile,Dense Blocks ensure the integration between shallow and deep features,thereby avoiding the loss of shallow attributes.Extensive experiments on TNO and MSRS datasets demonstrated that the suggested method achieved state-of-the-art(SOTA)performance in various metrics:Entropy(EN),Mutual Information(MI),Standard Deviation(SD),The Structural Similarity Index Measure(SSIM),Fusion quality(Qabf),MI of the pixel(FMI_(pixel)),and modified Visual Information Fidelity(VIF_(m)).展开更多
Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics i...Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics in this region remains unexplored at finer scales.This study investigates how micro site conditions influence litter decomposition of 15 upper Andean species over time.A reciprocal translocation field experiment was conducted over 18 months in 14 permanent plots within four sites in Colombian Andean mountain forests.Each plot contained three litterbeds(microsites),each with the 15 species,harvested at 3,6,12 and 18 months,totaling 2520 litterbags.Different forest variables,including canopy openness,leaf area index,slope and depth of litter,were measured in each litterbed.ANOVAs and linear mixed models were used to assess variation between sites and plots respectively,while multiple linear regression analyses evaluated the effects of forest variables on decay rates over time at the micro site scale.Results showed differences in absolute decay rates between sites but consistent relative decay rates,indicating varying magnitudes of decomposition,yet maintaining the same order based on their litter quality.Decay rates varied between species,with more variation in labile species compared to recalcitrant ones.Despite substantial variation in forest characteristics within sites,their influence on litter decomposition was minimal and declined over time.This suggests that,at finer spatial scales,the forest microenvironment plays a lesser role in litter decomposition,with litter quality emerging as the primary driver.This study is a step towards understanding the fine-scale dynamics of litter decomposition in upper Andean tropical forests,highlighting the intricate interplay between microenvironmental factors and decomposition processes.展开更多
Fungi play crucial roles in nutrient acquisition,plant growth promotion,and the enhancement of resistance to both abiotic and biotic stresses.However,studies on the fungal communities associated with peas (Pisum sativ...Fungi play crucial roles in nutrient acquisition,plant growth promotion,and the enhancement of resistance to both abiotic and biotic stresses.However,studies on the fungal communities associated with peas (Pisum sativum L.) remain limited.In this study,we systematically investigated the ecological effects of host niches (soil,root,stem,leaf,and pod) and genotypes on the diversity and composition of fungal communities in peas using a multi-level approach that encompassed pattern recognition (β-diversity decomposition),mechanism validation (neutral community model testing),and dynamic tracking methods (migration pathway source-tracking).The results revealed that the dominant fungal phyla across niches and genotypes were Ascomycota,Basidiomycota,and Mortierellomycota,and the community structures of the soil–plant continuum were primarily determined by the pea niches rather than genotypes.β-diversity decomposition was largely attributed to species replacement rather than richness differences,indicating strong niche specificity and microbial replacement across microhabitats.Neutral model analysis revealed that stochastic processes influenced genotypeassociated communities,while deterministic processes played a dominant role in niche-based community assembly.Source-tracking analysis identified niche-to-niche fungal migration,with Erysiphe,Fusarium,Cephaliophora,Ascobolus,Alternaria,and Aspergillus as the key genera.Migration rates from exogenous to endogenous niches were low (1.3–61.5%),whereas those within exogenous (64.4–83.7%) or endogenous (73.9–96.4%) compartments were much higher,suggesting that the pea epidermis acts as a selective barrier that filters and enriches microbial communities prior to internal colonization.This study provides comprehensive insights into the mechanisms of host filtering,enrichment and microbial sourcing,which increases our understanding of the assembly rules of the pea-associated fungal microbiome.展开更多
Particulate matter(PM)emitted by power machinery severely harms air quality and ecological balance,making the development of efficient and green PM-removal technologies a key global environmental challenge.This work b...Particulate matter(PM)emitted by power machinery severely harms air quality and ecological balance,making the development of efficient and green PM-removal technologies a key global environmental challenge.This work built a visualization system for diesel engine PM decomposition via non-thermal plasma(NTP),conducting multi-stage NTP oxidation at 120℃to clarify reaction pathways.The results demonstrate that NTP significantly influences the microcrystalline reconstruction and chemical evolution of PM.Early oxidation removes surface short crystallites,increasing crystallite length,reducing tortuosity,narrowing D1 peak,and boosting graphitization.Mid-stage sees NTP active substances penetrate inside,shortening crystallites and regularizing structure.Late-stage primary particles form“hollow shells”with few long crystallites,and order/graphitization rises again.Chemically,NTP reduces high-carbon components while increasing lowcarbon ones in PM soluble organics,decomposes C=C bonds to form oxygen-containing groups,enhances PM oxidation activity,weakensπ^(*)peaks,and strengthensσ^(*)peaks,clearly confirmed by the carbon K-edge electron energy loss spectra.This study clarifies the mechanistic pathways of NTP-driven PM decomposition,supporting clean energy advancement and atmospheric governance.展开更多
As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises s...As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises structural concerns,and the latter is of aerodynamic interest.Thus,panel aeroelasticity in shock-dominated flow represents a vital topic for the development and optimization of supersonic vehicles and propulsion systems.This review systematically summarizes recent advances in the methodologies applied to capture structural and fluid dynamics,including theoretical models,numerical simulations,and wind tunnel experiments.The application of data-driven modal decomposition,an advanced technique to extract physically crucial features,on the topic is introduced.From the perspective of FSIs,the distinctive aeroelastic behaviors in shock-dominated flow,including hysteresis phenomena and nonlinear responses,are highlighted.From the perspective of SBLIs,the modifications in their spatial and temporal characteristics imposed by the aeroelastic responses are emphasized.Motivated by the interaction between the shock waves and structural response,different strategies have been proposed to implement aeroelastic suppression and shock control,which have the potential to enhance structural safety and aerodynamic performance in the next generation of high-speed flight vehicles.展开更多
Stator vanes especially vane suction sides of transonic turbines are subjected to high frequency excitation forces under many circumstances,and thus are exposed to the risk of high cycle fatigue.Therefore,it is necess...Stator vanes especially vane suction sides of transonic turbines are subjected to high frequency excitation forces under many circumstances,and thus are exposed to the risk of high cycle fatigue.Therefore,it is necessary to reveal the flow mechanism of this kind of excitations for potential prevention measures.In this paper,the traveling shock phenomenon in the transonic turbine stator/rotor gap is observed and the concept of‘Inter-Row Traveling Shock(IRTS)'is proposed through the unsteady Reynolds-Averaged Navier-Stokes(RANS)simulation of a typical highlyloaded transonic turbine stage.The characteristics of an IRTS were described and summarized in aspects of unsteady shock wave system,aerodynamic characteristics and motion.The probable forming mechanism of an IRTS was explained through a theoretical model and it was validated through correct prediction of the flow state parameter change across the IRTS.Since IRTSs would strike onto vane suction sides,the pressure oscillation dynamic modes on vane suction side corresponding to the characteristic frequencies associated with IRTS were extracted through Dynamic Mode Decomposition(DMD),from which the way and extent of the IRTS influences on vane aerodynamic excitation were revealed and evaluated.Over 82%pressure oscillation energy on vane suction side could be brought by the IRTS sweeping along with blade rotation.展开更多
Theauthor proposes a dual layer source grid load storage collaborative planning model based on Benders decomposition to optimize the low-carbon and economic performance of the distribution network.The model plans the ...Theauthor proposes a dual layer source grid load storage collaborative planning model based on Benders decomposition to optimize the low-carbon and economic performance of the distribution network.The model plans the configuration of photovoltaic(3.8 MW),wind power(2.5 MW),energy storage(2.2 MWh),and SVC(1.2 Mvar)through interaction between upper and lower layers,and modifies lines 2–3,8–9,etc.to improve transmission capacity and voltage stability.The author uses normal distribution and Monte Carlo method to model load uncertainty,and combines Weibull distribution to describe wind speed characteristics.Compared to the traditional three-layer model(TLM),Benders decomposition-based two-layer model(BLBD)has a 58.1%reduction in convergence time(5.36 vs.12.78 h),a 51.1%reduction in iteration times(23 vs.47 times),a 8.07%reduction in total cost(12.436 vs.13.528 million yuan),and a 9.62%reduction in carbon emissions(12,456 vs.13,782 t).After optimization,the peak valley difference decreased from4.1 to 2.9MW,the renewable energy consumption rate reached 93.4%,and the energy storage efficiency was 87.6%.Themodel has been validated in the IEEE 33 node system,demonstrating its superiority in terms of economy,low-carbon,and reliability.展开更多
Litter decomposition is an essential ecosystem process influenced by multiple factors,including substrate quality,climate,edaphic environment,and decomposer communities.However,the role of canopy species identity and ...Litter decomposition is an essential ecosystem process influenced by multiple factors,including substrate quality,climate,edaphic environment,and decomposer communities.However,the role of canopy species identity and diversity on leaf litter decomposition in forests remains understudied.By controlling for macroclimate,soil properties,and litter substrate in a mature common garden,we investigated whether a three-month tea bag incubation of standardized green and rooibos tea substrate is driven by canopy tree species characteristics and diversity.Our study hypothesized two primary pathways:a chemical engineering effect,where trees alter soil properties and decomposer communities through litter input,and a physical engineering effect,where tree canopy structure modulates the local microclimate.The results showed that even under uniform macroclimatic and initial soil conditions,mass loss rates varied widely for green tea(27.4%–73.2%)and rooibos tea(6.1%–34.7%),comparable as found in other research between distinct biomes.While substrate quality was the dominant factor,both engineering pathways and,to a minor extent,tree diversity modulated mass losses.For green tea,tree chemical and physical characteristics seemed equally important,while the physical environment showed an increased importance for rooibos.Incubation depth played a key role,where forest floor decomposition rates are more susceptible to temporal climate variations,and soil-layer decomposition rates are less susceptible to climate variations and more determined by tree species identity.Our findings suggest that tea bag experiments focusing solely on topsoil burial may underestimate processes in the forest floor and the mineralorganic boundary layer.This study underscores the critical role of litter substrate quality in decomposition while demonstrating that tree community composition and the associated herbaceous layer,through both chemical and physical engineering pathways,strongly modulate decomposition rates.展开更多
With the rapid development of digital culture,a large number of cultural texts are presented in the form of digital and network.These texts have significant characteristics such as sparsity,real-time and non-standard ...With the rapid development of digital culture,a large number of cultural texts are presented in the form of digital and network.These texts have significant characteristics such as sparsity,real-time and non-standard expression,which bring serious challenges to traditional classification methods.In order to cope with the above problems,this paper proposes a new ASSC(ALBERT,SVD,Self-Attention and Cross-Entropy)-TextRCNN digital cultural text classification model.Based on the framework of TextRCNN,the Albert pre-training language model is introduced to improve the depth and accuracy of semantic embedding.Combined with the dual attention mechanism,the model’s ability to capture and model potential key information in short texts is strengthened.The Singular Value Decomposition(SVD)was used to replace the traditional Max pooling operation,which effectively reduced the feature loss rate and retained more key semantic information.The cross-entropy loss function was used to optimize the prediction results,making the model more robust in class distribution learning.The experimental results indicate that,in the digital cultural text classification task,as compared to the baseline model,the proposed ASSC-TextRCNN method achieves an 11.85%relative improvement in accuracy and an 11.97%relative increase in the F1 score.Meanwhile,the relative error rate decreases by 53.18%.This achievement not only validates the effectiveness and advanced nature of the proposed approach but also offers a novel technical route and methodological underpinnings for the intelligent analysis and dissemination of digital cultural texts.It holds great significance for promoting the in-depth exploration and value realization of digital culture.展开更多
This letter introduces the novel concept of Painlevé solitons—waves arising from the interaction between Painlevé waves and solitons in integrable systems.Painlevé solitons can also be viewed as solito...This letter introduces the novel concept of Painlevé solitons—waves arising from the interaction between Painlevé waves and solitons in integrable systems.Painlevé solitons can also be viewed as solitons propagating against a Painlevé wave background,in analogy to the established notion of elliptic solitons,which refers to solitons on an elliptic wave background.By employing a novel symmetry decomposition method aided by nonlocal residual symmetries,we explicitly construct (extended) Painlevé Ⅱ solitons for the Korteweg-de Vries equation and (extended) Painlevé Ⅳ solitons for the Boussinesq equation.展开更多
Quantitative detection of sleeve grouting compactness is a technical challenge in civil engineering testing.This study explores a novel quantitative detection method based on ultrasonic time-frequency dual-domain anal...Quantitative detection of sleeve grouting compactness is a technical challenge in civil engineering testing.This study explores a novel quantitative detection method based on ultrasonic time-frequency dual-domain analysis.It establishes a mapping relationship between sleeve grouting compactness and characteristic parameters.First,this study made samples with gradient defects for two types of grouting sleeves,G18 and G20.These included four cases:2D,4D,6D defects(where D is the diameter of the grouting sleeve),and no-defect.Then,an ultrasonic input/output data acquisition system was established.Three-dimensional sound field distribution data were obtained through an orthogonal detection layout and pulse reflection principles.Finally,a novel quantification detection with a comprehensive defect index(DI)was established by comprehensively considering eight feature parameters,such as time-frequency domain Kurtosis factor(KU),Skewness factor(SK),Formfactor(FF),Crest factor(CF),Impulse factor(IF),Clearance factor(CLF),Wavelet packet energy entropy(WPEE),and Hilbert energy peak(HEP).Construct a DI index by quantifying the difference between defect signals and defect free signals in the time-frequency domain.Experimental results show that,under no-defect conditions,the values of feature parameters are significantly lower than those under defect conditions.Among these,the KU,FF,CF,WPEE and HEP exhibit strong correlations with grout sleeve compactness.The proposed DI index in both types of grout sleeves showed good universality with a linear fit goodness of 0.847–0.962.However,G20 the larger inner diameter and length of the sleeve result in a more complex medium effect during ultrasonic propagation,making its DI index more sensitive to defects than the G18 sleeve.Therefore,the presented method is effective for quantitative detection and analysis of the compactness of grouting sleeves.展开更多
Nanophase iron particles(np-Fe^(0))have multiple formation mechanisms in lunar soil,which are mostly related to meteorite and micro meteorite impacts.Thermal modification of the impact is critical.Metal oxides have un...Nanophase iron particles(np-Fe^(0))have multiple formation mechanisms in lunar soil,which are mostly related to meteorite and micro meteorite impacts.Thermal modification of the impact is critical.Metal oxides have unique chemical and physical properties that allow np-Fe^(0) to form at a lower initial reaction temperature.Through the insitu heating experiment of ilmenite in the Chang'e-5 sample,it was found that ilmenite can form np-Fe^(0) at 400℃under high vacuum(10-6 Pa).This fills in the missing information on the lowest measured temperature at which ilmenite forms np-Fe^(0).At 400-800℃,only np-Fe^(0) and vesicles were formed without new Ti-rich minerals.At the same time,thermodynamic calculations showed that decomposition of ilmenite occurs in two stages.The experiments correspond to the initial stage of ilmenite thermal decomposition under high vacuum.The study explains the thermal decomposition reaction of ilmenite in a vacuum environment,provides a reference for the minimum measured temperature required for the formation of np-Fe^(0),and further improves the formation mechanism of np-Fe^(0).展开更多
The practical application of lithium metal batteries(LMBs)requires electrolytes that simultaneously ensure high safety and interfacial stability.Although locally concentrated ionic liquid electrolytes(LCILEs)exhibit e...The practical application of lithium metal batteries(LMBs)requires electrolytes that simultaneously ensure high safety and interfacial stability.Although locally concentrated ionic liquid electrolytes(LCILEs)exhibit exceptional electrochemical stability and compatibility with electrode electrolyte interfaces(EEIs),two major challenges persist:(i)safety risks caused by excessive low-flash-point diluents,and(ii)insufficient understanding of how diluents modulate solvation structures.Herein,we introduce a low-diluent-content LCILE system composed of lithium bis(fluorosulfonyl)imide(LiFSI)salt,N-methyl-N-propyl-pyrrolidinium bis(fluorosulfonyl)imide(Pyr_(13)FSI)ionic liquid,and trifluoromethanesulfonate(TFS)diluent.The TFS diluent strengthens ion-ion interactions by lowering the dielectric constant of the electrolyte,resulting in the formation of a unique nanometric anion aggregates(N-AGGs)reinforced solvation structure.These large anionic clusters exhibit accelerated redox decomposition kinetics,facilitating the rapid formation of a thin,dense,and low-impedance EEI.Consequently,the Li/LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)coin cell achieves 87.8%capacity retention over 300 cycles at 4.3 V,while a practical 1.4 Ah Li/NCM622 pouch cell retains 84.5%capacity after 80 cycles at 4.5 V.Furthermore,the electrolyte demonstrates exceptional safety,and 2 Ah Li metal pouch cells successfully pass rigorous nail penetration tests without any ignition or explosion.This work not only provides a design strategy for intrinsically safe and high-performance electrolytes but also highlights the critical role of anion cluster decomposition kinetics in shaping EEI formation.展开更多
The microstructural evolution of Cu−19Ni−6Cr−7Mn alloy during aging treatment was investigated.After aging for 120 min at 500℃,the alloy exhibited excellent mechanical properties,including a tensile strength of 978 M...The microstructural evolution of Cu−19Ni−6Cr−7Mn alloy during aging treatment was investigated.After aging for 120 min at 500℃,the alloy exhibited excellent mechanical properties,including a tensile strength of 978 MPa and an elastic modulus of 145.8 GPa.After aging for 240 min at 500℃,the elastic modulus of the alloy reached 149.5 GPa,which was among the highest values reported for Cu alloys.It was worth mentioning that the tensile strength increased rapidly from 740 to 934 MPa after aging for 5 min at 500℃,which was close to the maximum tensile strength(978 MPa).Analysis of the underlying strengthening mechanisms and phase transformation behavior revealed that the Cu−19Ni−6Cr−7Mn alloy underwent spinodal decomposition and DO_(22) ordering during the first 5 min of aging at 500℃,and L1_(2) ordered phases and bcc-Cr precipitates appeared.Therefore,the enhanced mechanical properties of the Cu−19Ni−6Cr−7Mn alloy can be attributed to the stress field generated by spinodal decomposition and the presence of nanoscale ordered phase and Cr precipitates.展开更多
Owing to the harsh conditions,wind turbine bearings are prone to faults,and the resulting fault information is easily submerged by strong noise disturbance,making conventional diagnosis challenging.Therefore,this stud...Owing to the harsh conditions,wind turbine bearings are prone to faults,and the resulting fault information is easily submerged by strong noise disturbance,making conventional diagnosis challenging.Therefore,this study presents an innovative bearing fault diagnosis approach predicated on Parameter⁃Optimized Symplectic Geometry Mode Decomposition(POSGMD)and Improved Convolutional Neural Network(ICNN).Firstly,assisted by the relative entropy⁃based adaptive selection of embedding dimension,a POSGMD is presented to adaptively decompose the collected bearing vibration signals into various Symplectic Geometry Components(SGC),which can solve the problem of manual selection of the embedding dimension in the raw Symplectic Geometry Mode Decomposition(SGMD).Meanwhile,the signal reconstruction on the decomposed SGC is conducted based on kurtosis⁃weighted principle to obtain the reconstructed signals.Subsequently,the Continuous Wavelet Transform(CWT)of the reconstructed signals is calculated to generate the corresponding time⁃frequency images as sample set.Finally,an ICNN is introduced for model training and automatic recognition of bearing faults.Two case studies are used to validate the presented methods efficacy.Comparing the presented method with traditional fault diagnosis methods,experimental results show that it can achieve greater identification accuracy and superior anti⁃noise resilience.This work provides a practical and effective solution for fault diagnosis in wind turbine bearings,contributing to the timely detection of faults and the reliable operation of wind turbines or other rotational machinery in industrial applications.展开更多
基金Supported by the National Natural Science Foundation of China(11871195)。
文摘In this article,we conduct a study on mixed quasi-martingale Hardy spaces that are defined by means of the mixed L_(p)-norm.By utilizing Doob’s inequalities,we explore the atomic decomposition and quasi-martingale inequalities of mixed quasi-martingale Hardy spaces.Moreover,we furnish sufficient conditions for the boundedness ofσ-sublinear operators in these spaces.These findings extend the existing conclusions regarding mixed quasi-martingale Hardy spaces defined with the help of the mixed L_(p)-norm.
基金Supported by Innovative Research Groups of the National Natural Science Foundation of China(22021004)。
文摘Catalytic decomposition of methane,which produces high-purity hydrogen and high-value-added carbon nanomaterials,has shown considerable potential for development and is expected to yield significant economic benefits in the future.However,designing catalysts that simultaneously exhibit high activity and long-term stability remains a significant challenge.Tuning the catalyst’s structure and electronic properties is an effective strategy for enhancing the reaction performance.In this work,a series of NixZr/ZSM-5 catalysts were prepared using the incipient wetness impregnation method,and the effect of Zr loadings on catalyst properties and performance was systematically investigated.The calcined and reduced catalysts were characterized by low-temperature N_(2)adsorption-desorption,XRD,SEM,H_(2)-TPR and XPS.The results showed that the addition of Zr significantly increased the specific surface area of the catalyst and reduced the metal particle size.Smaller NiO particles were found to enter the pores of the HZSM-5 support,and electronic interactions between NiO and ZrO_(2)markedly enhanced the metal-support interaction.The catalyst exhibited optimal catalytic performance at a Zr loading of 5%,achieving a maximum methane conversion of 68%at 625℃,maintaining activity for 900 min,and delivering a carbon yield of 1927%.Further increasing the Zr loading yielded only limited improvements in catalytic performance.Characterization of the spent catalysts and carbon products via TEM,Raman spectroscopy,and TGA revealed that the introduction of ZrO_(2)reduced metal sintering and promoted a shift in carbon nanofibers growth mode from tip-growth to base-growth.The mechanism of base-growth enabled the catalyst to maintain reaction activity for an extended period.
基金sponsored by the Department of Defense,Defense Threat Reduction Agency under the Materials Science in Extreme Environments University Research Alliance,HDTRA1-20-2-0001。
文摘Chemical warfare agents(CWAs)remain a persistent hazard in many parts of the world,necessitating a deeper exploration of their chemical and physical characteristics and reactions under diverse conditions.Diisopropyl methylphosphonate(DIMP),a commonly used CWA surrogate,is widely studied to enhance our understanding of CWA behavior.The prevailing thermal decomposition model for DIMP,developed approximately 25 years ago,is based on data collected in nitrogen atmospheres at temperatures ranging from 700 K to 800 K.Despite its limitations,this model continues to serve as a foundation for research across various thermal and reactive environments,including combustion studies.Our recent experiments have extended the scope of decomposition analysis by examining DIMP in both nitrogen and zero air across a lower temperature range of 175℃ to 250℃.Infrared spectroscopy results under nitrogen align well with the established model;however,we observed that catalytic effects,stemming from decomposition byproducts and interactions with stainless steel surfaces,alter the reaction kinetics.In zero air environments,we observed a novel infrared absorption band.Spectral fitting suggests this band may represent a combination of propanal and acetone,while GCMS analysis points to vinyl formate and acetone as possible constituents.Although the precise identity of these new products remains unresolved,our findings clearly indicate that the existing decomposition model cannot be reliably extended to lower temperatures or non-nitrogen environments without further revisions.
基金financially supported by the National Natural Science Foundation of China(Nos.52034002 and U2202254)the Fundamental Research Funds for the Central Universities,China(No.FRF-TT-19-001)。
文摘The sulfation and decomposition process has proven effective in selectively extracting lithium from lepidolite.It is essential to clarify the thermochemical behavior and kinetic parameters of decomposition reactions.Accordingly,comprehensive kinetic study by employing thermalgravimetric analysis at various heating rates was presented in this paper.Two main weight loss regions were observed during heating.The initial region corresponded to the dehydration of crystal water,whereas the subsequent region with overlapping peaks involved complex decomposition reactions.The overlapping peaks were separated into two individual reaction peaks and the activation energy of each peak was calculated using isoconversional kinetics methods.The activation energy of peak 1 exhibited a continual increase as the reaction conversion progressed,while that of peak 2 steadily decreased.The optimal kinetic models,identified as belonging to the random nucleation and subsequent growth category,provided valuable insights into the mechanism of the decomposition reactions.Furthermore,the adjustment factor was introduced to reconstruct the kinetic mechanism models,and the reconstructed models described the kinetic mechanism model more accurately for the decomposition reactions.This study enhanced the understanding of the thermochemical behavior and kinetic parameters of the lepidolite sulfation product decomposition reactions,further providing theoretical basis for promoting the selective extraction of lithium.
基金support from the Ministry of Science and Technology of Taiwan(Contract Nos.113-2221-E-011-130-MY2 and 113-2218-E-011-002)the support from Intelligent Manufactur-ing Innovation Center(IMIC),National Taiwan University of Science and Technology(NTUST),Taipei,Taiwan.
文摘Accurate photovoltaic(PV)power generation forecasting is essential for the efficient integration of renewable energy into power grids.However,the nonlinear and non-stationary characteristics of PV power signals,driven by fluctuating weather conditions,pose significant challenges for reliable prediction.This study proposes a DOEP(Decomposition–Optimization–Error Correction–Prediction)framework,a hybrid forecasting approach that integrates adaptive signal decomposition,machine learning,metaheuristic optimization,and error correction.The PV power signal is first decomposed using CEEMDAN to extract multi-scale temporal features.Subsequently,the hyperparameters and window sizes of the LSSVM are optimized using a Segment-based EBQPSO strategy.The main novelty of the proposed DOEP framework lies in the incorporation of Segment-based EBQPSO as a structured optimization mechanism that balances elite exploitation and population diversity during LSSVM tuning within the CEEMDAN-based forecasting pipeline.This strategy effectively mitigates convergence instability and sensitivity to initialization,which are common limitations in existing hybrid PV forecasting models.Each IMF is then predicted individually and aggregated to generate an initial forecast.In the error-correction stage,the residual error series is modeled using LSTM,and the final prediction is obtained by combining the initial forecast with the predicted error component.The proposed framework is evaluated using two PV power plant datasets with different levels of complexity.The results demonstrate that DOEP consistently outperforms benchmark models across multiple error-based and goodness-of-fit metrics,achieving MSE reductions of approximately 15%–60%on the ResPV-BDG dataset and 37%–92%on the NREL dataset.Analyses of predicted vs.observed values and residual distributions further confirm the superior calibration and robustness of the proposed approach.Although the DOEP framework entails higher computational costs than single model methods,it delivers significantly improved accuracy and stability for PV power forecasting under complex operating conditions.
基金funded by Anhui Province University Key Science and Technology Project(2024AH053415)Anhui Province University Major Science and Technology Project(2024AH040229)+3 种基金Talent Research Initiation Fund Project of Tongling University(2024tlxyrc019)Tongling University School-Level Scientific Research Project(2024tlxyptZD07)TheUniversity Synergy Innovation Programof Anhui Province(GXXT-2023-050)Tongling City Science and Technology Major Special Project(Unveiling and Commanding Model)(200401JB004).
文摘In the image fusion field,fusing infrared images(IRIs)and visible images(VIs)excelled is a key area.The differences between IRIs and VIs make it challenging to fuse both types into a high-quality image.Accordingly,efficiently combining the advantages of both images while overcoming their shortcomings is necessary.To handle this challenge,we developed an end-to-end IRI andVI fusionmethod based on frequency decomposition and enhancement.By applying concepts from frequency domain analysis,we used the layering mechanism to better capture the salient thermal targets from the IRIs and the rich textural information from the VIs,respectively,significantly boosting the image fusion quality and effectiveness.In addition,the backbone network combined Restormer Blocks and Dense Blocks;Restormer blocks utilize global attention to extract shallow features.Meanwhile,Dense Blocks ensure the integration between shallow and deep features,thereby avoiding the loss of shallow attributes.Extensive experiments on TNO and MSRS datasets demonstrated that the suggested method achieved state-of-the-art(SOTA)performance in various metrics:Entropy(EN),Mutual Information(MI),Standard Deviation(SD),The Structural Similarity Index Measure(SSIM),Fusion quality(Qabf),MI of the pixel(FMI_(pixel)),and modified Visual Information Fidelity(VIF_(m)).
基金supported by the Universidad del Rosario(Small grant ID:IV-FPD003)。
文摘Upper Andean tropical forests are renowned for their extraordinary biodiversity and heterogeneous environmental conditions.Despite the critical role of litter decomposition in carbon and nutrient cycles,its dynamics in this region remains unexplored at finer scales.This study investigates how micro site conditions influence litter decomposition of 15 upper Andean species over time.A reciprocal translocation field experiment was conducted over 18 months in 14 permanent plots within four sites in Colombian Andean mountain forests.Each plot contained three litterbeds(microsites),each with the 15 species,harvested at 3,6,12 and 18 months,totaling 2520 litterbags.Different forest variables,including canopy openness,leaf area index,slope and depth of litter,were measured in each litterbed.ANOVAs and linear mixed models were used to assess variation between sites and plots respectively,while multiple linear regression analyses evaluated the effects of forest variables on decay rates over time at the micro site scale.Results showed differences in absolute decay rates between sites but consistent relative decay rates,indicating varying magnitudes of decomposition,yet maintaining the same order based on their litter quality.Decay rates varied between species,with more variation in labile species compared to recalcitrant ones.Despite substantial variation in forest characteristics within sites,their influence on litter decomposition was minimal and declined over time.This suggests that,at finer spatial scales,the forest microenvironment plays a lesser role in litter decomposition,with litter quality emerging as the primary driver.This study is a step towards understanding the fine-scale dynamics of litter decomposition in upper Andean tropical forests,highlighting the intricate interplay between microenvironmental factors and decomposition processes.
基金financial y supported by the National Key Research and Development Program of China (2023YFD1900902)the Joint Funds of the Zhejiang Provincial Natural Science Foundation of China (LLSSZ24C030001)+1 种基金the Earmarked Fund for China Agriculture Research System (CARS-08-G-09)sponsored by the K.C.Wong Magna Fund of Ningbo University,China。
文摘Fungi play crucial roles in nutrient acquisition,plant growth promotion,and the enhancement of resistance to both abiotic and biotic stresses.However,studies on the fungal communities associated with peas (Pisum sativum L.) remain limited.In this study,we systematically investigated the ecological effects of host niches (soil,root,stem,leaf,and pod) and genotypes on the diversity and composition of fungal communities in peas using a multi-level approach that encompassed pattern recognition (β-diversity decomposition),mechanism validation (neutral community model testing),and dynamic tracking methods (migration pathway source-tracking).The results revealed that the dominant fungal phyla across niches and genotypes were Ascomycota,Basidiomycota,and Mortierellomycota,and the community structures of the soil–plant continuum were primarily determined by the pea niches rather than genotypes.β-diversity decomposition was largely attributed to species replacement rather than richness differences,indicating strong niche specificity and microbial replacement across microhabitats.Neutral model analysis revealed that stochastic processes influenced genotypeassociated communities,while deterministic processes played a dominant role in niche-based community assembly.Source-tracking analysis identified niche-to-niche fungal migration,with Erysiphe,Fusarium,Cephaliophora,Ascobolus,Alternaria,and Aspergillus as the key genera.Migration rates from exogenous to endogenous niches were low (1.3–61.5%),whereas those within exogenous (64.4–83.7%) or endogenous (73.9–96.4%) compartments were much higher,suggesting that the pea epidermis acts as a selective barrier that filters and enriches microbial communities prior to internal colonization.This study provides comprehensive insights into the mechanisms of host filtering,enrichment and microbial sourcing,which increases our understanding of the assembly rules of the pea-associated fungal microbiome.
基金supported by the National Natural Science Foundation of China(Grant Nos.52276115,62004143)the Open Fund for Anhui Provincial Key Laboratory of Advanced Internal Combustion Engines,the Key R&D Program of Hubei Province(Grant No.2022BAA084)+2 种基金the Key Project of Scientific Research Plan of Hubei Provincial Department of Education(Grant No.D20241501)the National College Students Innovation and Entrepreneurship Training Program(Grant No.202410299069Z)the Innovation Project of Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education(Grant No.LCX202404)。
文摘Particulate matter(PM)emitted by power machinery severely harms air quality and ecological balance,making the development of efficient and green PM-removal technologies a key global environmental challenge.This work built a visualization system for diesel engine PM decomposition via non-thermal plasma(NTP),conducting multi-stage NTP oxidation at 120℃to clarify reaction pathways.The results demonstrate that NTP significantly influences the microcrystalline reconstruction and chemical evolution of PM.Early oxidation removes surface short crystallites,increasing crystallite length,reducing tortuosity,narrowing D1 peak,and boosting graphitization.Mid-stage sees NTP active substances penetrate inside,shortening crystallites and regularizing structure.Late-stage primary particles form“hollow shells”with few long crystallites,and order/graphitization rises again.Chemically,NTP reduces high-carbon components while increasing lowcarbon ones in PM soluble organics,decomposes C=C bonds to form oxygen-containing groups,enhances PM oxidation activity,weakensπ^(*)peaks,and strengthensσ^(*)peaks,clearly confirmed by the carbon K-edge electron energy loss spectra.This study clarifies the mechanistic pathways of NTP-driven PM decomposition,supporting clean energy advancement and atmospheric governance.
基金supported by the National Natural Science Foundation of China(No.12372233)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University,China(No.25GH01020005)the“111 Project”of China(No.B17037)。
文摘As a multidisciplinary phenomenon,panel aeroelasticity in shock-dominated flow is featured by two primary interactions:Fluid-Structure Interactions(FSIs)and Shock-Boundary Layer Interactions(SBLIs).The former raises structural concerns,and the latter is of aerodynamic interest.Thus,panel aeroelasticity in shock-dominated flow represents a vital topic for the development and optimization of supersonic vehicles and propulsion systems.This review systematically summarizes recent advances in the methodologies applied to capture structural and fluid dynamics,including theoretical models,numerical simulations,and wind tunnel experiments.The application of data-driven modal decomposition,an advanced technique to extract physically crucial features,on the topic is introduced.From the perspective of FSIs,the distinctive aeroelastic behaviors in shock-dominated flow,including hysteresis phenomena and nonlinear responses,are highlighted.From the perspective of SBLIs,the modifications in their spatial and temporal characteristics imposed by the aeroelastic responses are emphasized.Motivated by the interaction between the shock waves and structural response,different strategies have been proposed to implement aeroelastic suppression and shock control,which have the potential to enhance structural safety and aerodynamic performance in the next generation of high-speed flight vehicles.
文摘Stator vanes especially vane suction sides of transonic turbines are subjected to high frequency excitation forces under many circumstances,and thus are exposed to the risk of high cycle fatigue.Therefore,it is necessary to reveal the flow mechanism of this kind of excitations for potential prevention measures.In this paper,the traveling shock phenomenon in the transonic turbine stator/rotor gap is observed and the concept of‘Inter-Row Traveling Shock(IRTS)'is proposed through the unsteady Reynolds-Averaged Navier-Stokes(RANS)simulation of a typical highlyloaded transonic turbine stage.The characteristics of an IRTS were described and summarized in aspects of unsteady shock wave system,aerodynamic characteristics and motion.The probable forming mechanism of an IRTS was explained through a theoretical model and it was validated through correct prediction of the flow state parameter change across the IRTS.Since IRTSs would strike onto vane suction sides,the pressure oscillation dynamic modes on vane suction side corresponding to the characteristic frequencies associated with IRTS were extracted through Dynamic Mode Decomposition(DMD),from which the way and extent of the IRTS influences on vane aerodynamic excitation were revealed and evaluated.Over 82%pressure oscillation energy on vane suction side could be brought by the IRTS sweeping along with blade rotation.
文摘Theauthor proposes a dual layer source grid load storage collaborative planning model based on Benders decomposition to optimize the low-carbon and economic performance of the distribution network.The model plans the configuration of photovoltaic(3.8 MW),wind power(2.5 MW),energy storage(2.2 MWh),and SVC(1.2 Mvar)through interaction between upper and lower layers,and modifies lines 2–3,8–9,etc.to improve transmission capacity and voltage stability.The author uses normal distribution and Monte Carlo method to model load uncertainty,and combines Weibull distribution to describe wind speed characteristics.Compared to the traditional three-layer model(TLM),Benders decomposition-based two-layer model(BLBD)has a 58.1%reduction in convergence time(5.36 vs.12.78 h),a 51.1%reduction in iteration times(23 vs.47 times),a 8.07%reduction in total cost(12.436 vs.13.528 million yuan),and a 9.62%reduction in carbon emissions(12,456 vs.13,782 t).After optimization,the peak valley difference decreased from4.1 to 2.9MW,the renewable energy consumption rate reached 93.4%,and the energy storage efficiency was 87.6%.Themodel has been validated in the IEEE 33 node system,demonstrating its superiority in terms of economy,low-carbon,and reliability.
基金funded by the Global PhD Scholarship between KU Leuven and UCLouvain。
文摘Litter decomposition is an essential ecosystem process influenced by multiple factors,including substrate quality,climate,edaphic environment,and decomposer communities.However,the role of canopy species identity and diversity on leaf litter decomposition in forests remains understudied.By controlling for macroclimate,soil properties,and litter substrate in a mature common garden,we investigated whether a three-month tea bag incubation of standardized green and rooibos tea substrate is driven by canopy tree species characteristics and diversity.Our study hypothesized two primary pathways:a chemical engineering effect,where trees alter soil properties and decomposer communities through litter input,and a physical engineering effect,where tree canopy structure modulates the local microclimate.The results showed that even under uniform macroclimatic and initial soil conditions,mass loss rates varied widely for green tea(27.4%–73.2%)and rooibos tea(6.1%–34.7%),comparable as found in other research between distinct biomes.While substrate quality was the dominant factor,both engineering pathways and,to a minor extent,tree diversity modulated mass losses.For green tea,tree chemical and physical characteristics seemed equally important,while the physical environment showed an increased importance for rooibos.Incubation depth played a key role,where forest floor decomposition rates are more susceptible to temporal climate variations,and soil-layer decomposition rates are less susceptible to climate variations and more determined by tree species identity.Our findings suggest that tea bag experiments focusing solely on topsoil burial may underestimate processes in the forest floor and the mineralorganic boundary layer.This study underscores the critical role of litter substrate quality in decomposition while demonstrating that tree community composition and the associated herbaceous layer,through both chemical and physical engineering pathways,strongly modulate decomposition rates.
基金funded by China National Innovation and Entrepreneurship Project Fund Innovation Training Program(202410451009).
文摘With the rapid development of digital culture,a large number of cultural texts are presented in the form of digital and network.These texts have significant characteristics such as sparsity,real-time and non-standard expression,which bring serious challenges to traditional classification methods.In order to cope with the above problems,this paper proposes a new ASSC(ALBERT,SVD,Self-Attention and Cross-Entropy)-TextRCNN digital cultural text classification model.Based on the framework of TextRCNN,the Albert pre-training language model is introduced to improve the depth and accuracy of semantic embedding.Combined with the dual attention mechanism,the model’s ability to capture and model potential key information in short texts is strengthened.The Singular Value Decomposition(SVD)was used to replace the traditional Max pooling operation,which effectively reduced the feature loss rate and retained more key semantic information.The cross-entropy loss function was used to optimize the prediction results,making the model more robust in class distribution learning.The experimental results indicate that,in the digital cultural text classification task,as compared to the baseline model,the proposed ASSC-TextRCNN method achieves an 11.85%relative improvement in accuracy and an 11.97%relative increase in the F1 score.Meanwhile,the relative error rate decreases by 53.18%.This achievement not only validates the effectiveness and advanced nature of the proposed approach but also offers a novel technical route and methodological underpinnings for the intelligent analysis and dissemination of digital cultural texts.It holds great significance for promoting the in-depth exploration and value realization of digital culture.
基金supported by the National Natural Science Foundations of China (Grant Nos.12235007,12001424,12271324,and 12501333)the Natural Science Basic research program of Shaanxi Province (Grant Nos.2021JZ-21 and 2024JC-YBQN-0069)+3 种基金the China Postdoctoral Science Foundation (Grant Nos.2020M673332 and 2024M751921)the Fundamental Research Funds for the Central Universities (Grant No.GK202304028)the 2023 Shaanxi Province Postdoctoral Research Project (Grant No.2023BSHEDZZ186)Xi’an University,Xi’an Science and Technology Plan Wutongshu Technology Transfer Action Innovation Team(Grant No.25WTZD07)。
文摘This letter introduces the novel concept of Painlevé solitons—waves arising from the interaction between Painlevé waves and solitons in integrable systems.Painlevé solitons can also be viewed as solitons propagating against a Painlevé wave background,in analogy to the established notion of elliptic solitons,which refers to solitons on an elliptic wave background.By employing a novel symmetry decomposition method aided by nonlocal residual symmetries,we explicitly construct (extended) Painlevé Ⅱ solitons for the Korteweg-de Vries equation and (extended) Painlevé Ⅳ solitons for the Boussinesq equation.
基金supported in part by the National Natural Science Foundation of China Grant 11962006the Natural Science Foundation of Jiangxi Province of China Grant 20232BAB204067.
文摘Quantitative detection of sleeve grouting compactness is a technical challenge in civil engineering testing.This study explores a novel quantitative detection method based on ultrasonic time-frequency dual-domain analysis.It establishes a mapping relationship between sleeve grouting compactness and characteristic parameters.First,this study made samples with gradient defects for two types of grouting sleeves,G18 and G20.These included four cases:2D,4D,6D defects(where D is the diameter of the grouting sleeve),and no-defect.Then,an ultrasonic input/output data acquisition system was established.Three-dimensional sound field distribution data were obtained through an orthogonal detection layout and pulse reflection principles.Finally,a novel quantification detection with a comprehensive defect index(DI)was established by comprehensively considering eight feature parameters,such as time-frequency domain Kurtosis factor(KU),Skewness factor(SK),Formfactor(FF),Crest factor(CF),Impulse factor(IF),Clearance factor(CLF),Wavelet packet energy entropy(WPEE),and Hilbert energy peak(HEP).Construct a DI index by quantifying the difference between defect signals and defect free signals in the time-frequency domain.Experimental results show that,under no-defect conditions,the values of feature parameters are significantly lower than those under defect conditions.Among these,the KU,FF,CF,WPEE and HEP exhibit strong correlations with grout sleeve compactness.The proposed DI index in both types of grout sleeves showed good universality with a linear fit goodness of 0.847–0.962.However,G20 the larger inner diameter and length of the sleeve result in a more complex medium effect during ultrasonic propagation,making its DI index more sensitive to defects than the G18 sleeve.Therefore,the presented method is effective for quantitative detection and analysis of the compactness of grouting sleeves.
基金funding support from the National Natural Science Foundation of China(Grant Nos.42441804,42403043,42273042,42303041,and U24A2008)Youth Innovation Promotion Association CAS awards+5 种基金"From 0 to 1"Original Exploration Cultivation Project,Institute of Geochemistry,Chinese Academy of Sciences(Grant No.DHSZZ2023.3)Bureau of Frontier Sciences and Basic Research,CAS,(Grant No.QYJ-2025-0103)Guizhou Provincial Foundation for Excellent Scholars Program(Grant No.GCC[2023]088)Provincial Key Research and Development(R&D)Plan Projects of Heilongjiang(Grant No.2024ZXDXB52)The Innovation and Development Fund of Science and Technology of Institute of Geochemistry,Chinese Academy of SciencesGuizhou Province Basic Research Program Project(QKHJC-ZK[2023]-General 473)。
文摘Nanophase iron particles(np-Fe^(0))have multiple formation mechanisms in lunar soil,which are mostly related to meteorite and micro meteorite impacts.Thermal modification of the impact is critical.Metal oxides have unique chemical and physical properties that allow np-Fe^(0) to form at a lower initial reaction temperature.Through the insitu heating experiment of ilmenite in the Chang'e-5 sample,it was found that ilmenite can form np-Fe^(0) at 400℃under high vacuum(10-6 Pa).This fills in the missing information on the lowest measured temperature at which ilmenite forms np-Fe^(0).At 400-800℃,only np-Fe^(0) and vesicles were formed without new Ti-rich minerals.At the same time,thermodynamic calculations showed that decomposition of ilmenite occurs in two stages.The experiments correspond to the initial stage of ilmenite thermal decomposition under high vacuum.The study explains the thermal decomposition reaction of ilmenite in a vacuum environment,provides a reference for the minimum measured temperature required for the formation of np-Fe^(0),and further improves the formation mechanism of np-Fe^(0).
基金supported by the National Key R&D Program of China(Grant No.2022YFE0207300)the National Natural Science Foundation of China(Grant Nos.22179142 and 22075314)+1 种基金Jiangsu Provincial Science and Technology Program(Grant No.BG 2024020).XPSWAXS and TOF-SIMS characterizations were supported by Nano-X(Vacuum Interconnected Nanotech Workstation,Suzhou Institute of Nano-Tech and Nano-Bionics,Chinese Academy of Sciences(SINANO),Suzhou 215123,China)。
文摘The practical application of lithium metal batteries(LMBs)requires electrolytes that simultaneously ensure high safety and interfacial stability.Although locally concentrated ionic liquid electrolytes(LCILEs)exhibit exceptional electrochemical stability and compatibility with electrode electrolyte interfaces(EEIs),two major challenges persist:(i)safety risks caused by excessive low-flash-point diluents,and(ii)insufficient understanding of how diluents modulate solvation structures.Herein,we introduce a low-diluent-content LCILE system composed of lithium bis(fluorosulfonyl)imide(LiFSI)salt,N-methyl-N-propyl-pyrrolidinium bis(fluorosulfonyl)imide(Pyr_(13)FSI)ionic liquid,and trifluoromethanesulfonate(TFS)diluent.The TFS diluent strengthens ion-ion interactions by lowering the dielectric constant of the electrolyte,resulting in the formation of a unique nanometric anion aggregates(N-AGGs)reinforced solvation structure.These large anionic clusters exhibit accelerated redox decomposition kinetics,facilitating the rapid formation of a thin,dense,and low-impedance EEI.Consequently,the Li/LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)coin cell achieves 87.8%capacity retention over 300 cycles at 4.3 V,while a practical 1.4 Ah Li/NCM622 pouch cell retains 84.5%capacity after 80 cycles at 4.5 V.Furthermore,the electrolyte demonstrates exceptional safety,and 2 Ah Li metal pouch cells successfully pass rigorous nail penetration tests without any ignition or explosion.This work not only provides a design strategy for intrinsically safe and high-performance electrolytes but also highlights the critical role of anion cluster decomposition kinetics in shaping EEI formation.
基金supported by the National Key R&D Program of China (No. 2021YFB3700700)the Henan Province Top Talent Training Program Project, China (No. 244500510020)the High-level Talent Research Start-up Project Funding of Henan Academy of Sciences, China (No. 242017001)。
文摘The microstructural evolution of Cu−19Ni−6Cr−7Mn alloy during aging treatment was investigated.After aging for 120 min at 500℃,the alloy exhibited excellent mechanical properties,including a tensile strength of 978 MPa and an elastic modulus of 145.8 GPa.After aging for 240 min at 500℃,the elastic modulus of the alloy reached 149.5 GPa,which was among the highest values reported for Cu alloys.It was worth mentioning that the tensile strength increased rapidly from 740 to 934 MPa after aging for 5 min at 500℃,which was close to the maximum tensile strength(978 MPa).Analysis of the underlying strengthening mechanisms and phase transformation behavior revealed that the Cu−19Ni−6Cr−7Mn alloy underwent spinodal decomposition and DO_(22) ordering during the first 5 min of aging at 500℃,and L1_(2) ordered phases and bcc-Cr precipitates appeared.Therefore,the enhanced mechanical properties of the Cu−19Ni−6Cr−7Mn alloy can be attributed to the stress field generated by spinodal decomposition and the presence of nanoscale ordered phase and Cr precipitates.
基金Jiangsu Association for Science and Technology Youth Talent Support Project(Grant No.JSTJ-2024-031)National Natural Science Foundation of China(Grant No.52005265)Natural Science Fund for Colleges and Universities in Jiangsu Province(Grant No.20KJB460002)。
文摘Owing to the harsh conditions,wind turbine bearings are prone to faults,and the resulting fault information is easily submerged by strong noise disturbance,making conventional diagnosis challenging.Therefore,this study presents an innovative bearing fault diagnosis approach predicated on Parameter⁃Optimized Symplectic Geometry Mode Decomposition(POSGMD)and Improved Convolutional Neural Network(ICNN).Firstly,assisted by the relative entropy⁃based adaptive selection of embedding dimension,a POSGMD is presented to adaptively decompose the collected bearing vibration signals into various Symplectic Geometry Components(SGC),which can solve the problem of manual selection of the embedding dimension in the raw Symplectic Geometry Mode Decomposition(SGMD).Meanwhile,the signal reconstruction on the decomposed SGC is conducted based on kurtosis⁃weighted principle to obtain the reconstructed signals.Subsequently,the Continuous Wavelet Transform(CWT)of the reconstructed signals is calculated to generate the corresponding time⁃frequency images as sample set.Finally,an ICNN is introduced for model training and automatic recognition of bearing faults.Two case studies are used to validate the presented methods efficacy.Comparing the presented method with traditional fault diagnosis methods,experimental results show that it can achieve greater identification accuracy and superior anti⁃noise resilience.This work provides a practical and effective solution for fault diagnosis in wind turbine bearings,contributing to the timely detection of faults and the reliable operation of wind turbines or other rotational machinery in industrial applications.
