The dark oxidation reactions of ethers including aether, isopropyl ether, phenyl isopropyl ether, and benzyl isopropyl ether have been studied by using density functional theory calculations. The structures of initial...The dark oxidation reactions of ethers including aether, isopropyl ether, phenyl isopropyl ether, and benzyl isopropyl ether have been studied by using density functional theory calculations. The structures of initial Contact charge transfer complexes （CCTCs）, transition states and caged radical intermediates have been located at the B3LYP/6-31G （d） level, The bonding nature of ethers with triplet 02 in CCTCs has been analyzed, and the detailed mechanism of dark oxidation reactions of ether is presented clearly.展开更多
The work has the characters of a philosophical note, in which a new exotic version of the atom structure is discussed. According to this, the atomic nucleus consists of “normal” and “special” neutrons. Electrons a...The work has the characters of a philosophical note, in which a new exotic version of the atom structure is discussed. According to this, the atomic nucleus consists of “normal” and “special” neutrons. Electrons are internal part of both types of neutron. Electrons can leave “normal” neutrons of the nucleus and return back with a certain probability. These processes lead to the appearance of protons in the nucleus and form the electron orbits of the atom. At the same time, it is possible that the Coulomb’s barriers of atoms and nucleus disappear at some point in time and cold nuclear reactions pass through. This assumption leads to a new exotic model of the Universe structure, namely, the existence of neutron ether, consisting of special neutrons that do not emit their own electrons. In this ethereal ocean of special neutrons, periodically provoked disturbances arise. After that, it creates pockets, clusters of our normal neutrons inherent in our world, which can already emit electrons and, consequently, create atoms. The ether gets sick from time to time. However, as a result of this disease, stars arise. Some possible stages in the creation of our world are also discussed in this paper.展开更多
基金Project supported by the National Natural Science Foundation of China (No. 20473047) and the Major State Basic Research Development Program of China (973 Program, No. 2004CB719902)
文摘The dark oxidation reactions of ethers including aether, isopropyl ether, phenyl isopropyl ether, and benzyl isopropyl ether have been studied by using density functional theory calculations. The structures of initial Contact charge transfer complexes （CCTCs）, transition states and caged radical intermediates have been located at the B3LYP/6-31G （d） level, The bonding nature of ethers with triplet 02 in CCTCs has been analyzed, and the detailed mechanism of dark oxidation reactions of ether is presented clearly.
文摘The work has the characters of a philosophical note, in which a new exotic version of the atom structure is discussed. According to this, the atomic nucleus consists of “normal” and “special” neutrons. Electrons are internal part of both types of neutron. Electrons can leave “normal” neutrons of the nucleus and return back with a certain probability. These processes lead to the appearance of protons in the nucleus and form the electron orbits of the atom. At the same time, it is possible that the Coulomb’s barriers of atoms and nucleus disappear at some point in time and cold nuclear reactions pass through. This assumption leads to a new exotic model of the Universe structure, namely, the existence of neutron ether, consisting of special neutrons that do not emit their own electrons. In this ethereal ocean of special neutrons, periodically provoked disturbances arise. After that, it creates pockets, clusters of our normal neutrons inherent in our world, which can already emit electrons and, consequently, create atoms. The ether gets sick from time to time. However, as a result of this disease, stars arise. Some possible stages in the creation of our world are also discussed in this paper.
文摘以黑茶为底物,研究了黑茶-Br O3--Mn2+-H+-丙酮组成的振荡反应体系在恒温条件下进行的振荡反应.探讨了温度、黑茶浓度、碘酸钾干扰物对振荡反应的扰动,建立了利用此振荡体系检测加碘黑茶中碘酸根离子的方法.结果表明:反应体系有典型的振荡波形;诱导期的表观活化能为76.54 k J/mol;IO3-浓度与振荡诱导期tin有良好的线性关系,线性范围为(8.3×10-5-1.2×10-3)mol/L,线性关系回归方程为tin=4.2×102-2.5×105[IO3-],相关系数为0.995,检出限为2.8×10-5 mol/L.为加碘黑茶中碘含量的测定提供了一种新方法.
