Modal parameters can accurately characterize the structural dynamic properties and assess the physical state of the structure.Therefore,it is particularly significant to identify the structural modal parameters accordi...Modal parameters can accurately characterize the structural dynamic properties and assess the physical state of the structure.Therefore,it is particularly significant to identify the structural modal parameters according to the monitoring data information in the structural health monitoring(SHM)system,so as to provide a scientific basis for structural damage identification and dynamic model modification.In view of this,this paper reviews methods for identifying structural modal parameters under environmental excitation and briefly describes how to identify structural damages based on the derived modal parameters.The paper primarily introduces data-driven modal parameter recognition methods(e.g.,time-domain,frequency-domain,and time-frequency-domain methods,etc.),briefly describes damage identification methods based on the variations of modal parameters(e.g.,natural frequency,modal shapes,and curvature modal shapes,etc.)and modal validation methods(e.g.,Stability Diagram and Modal Assurance Criterion,etc.).The current status of the application of artificial intelligence(AI)methods in the direction of modal parameter recognition and damage identification is further discussed.Based on the pre-vious analysis,the main development trends of structural modal parameter recognition and damage identification methods are given to provide scientific references for the optimized design and functional upgrading of SHM systems.展开更多
Investigating the combined effects of mining damage and creep damage on slope stability is crucial,as it can comprehensively reveal the non-linear deformation characteristics of rock under their joint influence.This s...Investigating the combined effects of mining damage and creep damage on slope stability is crucial,as it can comprehensively reveal the non-linear deformation characteristics of rock under their joint influence.This study develops a fractional-order nonlinear creep constitutive model that incorporates the double damage effect and implements a non-linear creep subroutine for soft rock using the threedimensional finite difference method on the FLAC3D platform.Comparative analysis of the theoretical,numerical,and experimental results reveals that the fractional-order constitutive model,which incorporates the double damage effect,accurately reflects the distinct deformation stages of green mudstone during creep failure and effectively captures the non-linear deformation in the accelerated creep phase.The numerical results show a fitting accuracy exceeding 97%with the creep test curves,significantly outperforming the 61%accuracy of traditional creep models.展开更多
Coating microdefects and localized corrosion in coating/metal system are inevitable,accelerating the degradation of metal infrastructure.Early evaluating coating microdefects and detecting corrosion sites are urgent y...Coating microdefects and localized corrosion in coating/metal system are inevitable,accelerating the degradation of metal infrastructure.Early evaluating coating microdefects and detecting corrosion sites are urgent yet remain challenge to achieve.Herein,we propose a robust,universal and efficient fluorescence-based strategy for hierarchical warning of coating damage and metal corrosion by introducing the concepts of damage-induced fluorescence enhancement effect(DIE)and ionic-recognition induced quenching effect(RIQ).The coatings with dualresponsiveness for coating defect and steel corrosion are constructed by incorporating synthesized nanoprobes composed of metal organic frameworks(Ni–Zn-MOFs)loaded with Rhodamine B(RhB@MOFs).The initial damage to the coating causes an immediate intensification of fluorescence,while the specific ionic-recognition characteristic of RhB with Fe3t results in an evident fluorescence quenching,enabling the detection of coating damage and corrosion.Importantly,this nanoprobes are insensitive to the coating matrix and exhibit stable corrosion warning capability across various coating systems.Meanwhile,electrochemical investigations indicate that the impedance values of RM/EP maintain above 10^(8)Ωcm^(2)even after 60 days of immersion.Therefore,the incorporation of fluorescent nanoprobes greatly inhibits the intrusion of electrolytes into polymer and improves the corrosion protection performance of the coating.This powerful strategy towards dual-level damage warning provides insights for the development of long-term smart protective materials.展开更多
Combined pulsed laser(CPL),introduced in 1975 for target damage,integrates different lasers to achieve high peak power and pulse energy.However,despite decades of research,CPL remains unused for long-range target dama...Combined pulsed laser(CPL),introduced in 1975 for target damage,integrates different lasers to achieve high peak power and pulse energy.However,despite decades of research,CPL remains unused for long-range target damage due to the challenge of maintaining high peak power density over long distances.We note that a potential solution lies in leveraging the air filament generated by femtosecond laser,which can transmit peak power densities higher than 1014 W/cm^(2)under the power clamping effect.To address this,a concept of a femtosecond laser induced air filament-CW CPL for surface damage of ceramics was introduced.We found no surface changes in ceramic targets when irradiated with a CW laser alone.By way of contrast,the target can be penetrated in a very short time(20 ms)with the assistance of the femtosecond laser induced air filament.In this context,we employ high-speed shadow imaging,cross-timescale simulation models and macro-microscopic characterization,to elucidate the CPL damage mechanism.The optimal CPL,combining a 1 mJ femtosecond laser and a 500 W CW laser,yields a damage rate of 1.51×10^(7)μm^(3)/J,representing an improvement of approximately 175%compared to single femtosecond laser ablation and around 59%enhancement compared to coating-assisted CW laser ablation.Furthermore,the efficacy of the proposed femtosecond-CW CPL method is demonstrated in causing penetration damage of ceramic/metal composite material or direct damage of sapphire,showcasing its versatility in damaging applications.Consequently,the femtosecond-CW CPL ablation method presented in this paper holds great promise as a new type of damage method for transparent hard and brittle materials.展开更多
The loaded rock experiences multiple stages of deformation.It starts with the formation of microcracks at low stresses(crack initiation,CI)and then transitions into unstable crack propagation(crack damage,CD)near the ...The loaded rock experiences multiple stages of deformation.It starts with the formation of microcracks at low stresses(crack initiation,CI)and then transitions into unstable crack propagation(crack damage,CD)near the ultimate strength.In this study,both the acoustic emission method(AEM)and the ultrasonic testing method(UTM)were used to examine the characteristics of AE parameters(b-value,peak frequency,frequency-band energy ratio,and fractal dimension)and ultrasonic(ULT)properties(velocity,amplitude,energy attenuation,and scattering attenuation)of bedded shale at CI,CD,and ultimate strength.The comparison involved analyzing the strain-based method(SBM),AEM,and UTM to determine the thresholds for damage stress.A fuzzy comprehensive evaluation model(FCEM)was created to describe the damage thresholds and hazard assessment.The results indicate that the optimal AE and ULT parameters for identifying CI and CD stress are ringing count,ultrasonic amplitude,energy attenuation,and scattering attenuation of the S-wave.Besides,damage thresholds were detected earlier by AE monitoring,ranging from 3 MPa to 10 MPa.CI and CD identified by UTM occurred later than SBM and AEM,and were in the range of 12 MPa.The b-value,peak frequency,energy ratio in the low-frequency band(0e62.5 kHz),correlation dimension,and sandbox dimension showed low values at the peak stress,while the energy ratio in a moderate-frequency band(187.5e281.25 kHz)and amplitude showed high values.The successful application of FCEM to laboratory testing of shales has demonstrated its ability to quantitatively identify AE/ULT precursors of seismic hazards associated with rock failure.展开更多
Arsenic-related oxidative stress and resultant diseases have attracted global concern,while longitudinal studies are scarce.To assess the relationship between arsenic exposure and systemic oxidative damage,we performe...Arsenic-related oxidative stress and resultant diseases have attracted global concern,while longitudinal studies are scarce.To assess the relationship between arsenic exposure and systemic oxidative damage,we performed two repeatedmeasures among 5236 observations(4067 participants)in theWuhan-Zhuhai cohort at the baseline and follow-up after 3 years.Urinary total arsenic,biomarkers of DNA oxidative damage(8-hydroxy-2-deoxyguanosine(8-OHdG)),lipid peroxidation(8-isoprostaglandin F2alpha(8-isoPGF2α)),and protein oxidative damage(protein carbonyls(PCO))were detected for all observations.Here we used linearmixed models to estimate the cross-sectional and longitudinal associations between arsenic exposure and oxidative damage.Exposure-response curves were constructed by utilizing the generalized additive mixed models with thin plate regressions.After adjusting for potential confounders,arsenic level was significantly and positively related to the levels of global oxidative damage and their annual increased rates in dose-response manners.In cross-sectional analyses,each 1%increase in arsenic levelwas associated with a 0.406%(95%confidence interval(CI):0.379%to 0.433%),0.360%(0.301%to 0.420%),and 0.079%(0.055%to 0.103%)increase in 8-isoPGF2α,8-OHdG,and PCO,respectively.More importantly,arsenic was further found to be associated with increased annual change rates of 8-isoPGF2α(β:0.147;95%CI:0.130 to 0.164),8-OHdG(0.155;0.118 to 0.192),and PCO(0.050;0.035 to 0.064)in the longitudinal analyses.Our study suggested that arsenic exposurewas not only positively related with global oxidative damage to lipid,DNA,and protein in cross-sectional analyses,but also associated with annual increased rates of these biomarkers in dose-dependent manners.展开更多
The penetration-deflagration coupling damage performance of rod-like reactive shaped charge pene-trator(RRSCP)impacting thick steel plates is investigated by theoretical analysis and experiments.A penetration-deflagra...The penetration-deflagration coupling damage performance of rod-like reactive shaped charge pene-trator(RRSCP)impacting thick steel plates is investigated by theoretical analysis and experiments.A penetration-deflagration coupling damage model is developed to predict the penetration depth and cratering diameter.Four type of aluminum-polytetrafluoroethylene-copper(Al-PTFE-Cu)reactive liners with densities of 2.3,2.7,3.5,and 4.5 g·cm^(-3) are selected to conduct the penetration experiments.The comparison results show that model predictions are in good agreement with the experimental data.By comparing the penetration depth and cratering diameter in the inert penetration mode and the penetration-deflagration coupling mode,the influence mechanism that the penetration-induced chemical response is unfavorable to penetration but has an enhanced cratering effect is revealed.From the formation characteristics,penetration effect and penetration-induced chemical reaction be-haviors,the influence of reactive liner density on the penetration-deflagration performance is further analyzed.The results show that increasing the density of reactive liner significantly increases both the kinetic energy and length of the reactive penetrator,meanwhile effectively reduces the weakened effect of penetration-induced chemical response,resulting in an enhanced penetration capability.However,due to the decreased diameter and potential energy content of reactive penetrator,the cratering capa-bility is weakened significantly.展开更多
This study examines the slug-induced vibration(SIV)response and fatigue behavior of offshore risers subjected to internal slug flow.A structural model incorporating internal slug flow dynamics is developed using the A...This study examines the slug-induced vibration(SIV)response and fatigue behavior of offshore risers subjected to internal slug flow.A structural model incorporating internal slug flow dynamics is developed using the Absolute Nodal Coordinate Formulation(ANCF)and a spatial-temporal density variation equation to analyze how slug flow parameters affect the SIV response of risers.Structural displacement,stress,and fatigue responses are systematically evaluated to characterize the structural behavior under SIV conditions.Longer slugs induce more pronounced traveling wave characteristics,while shorter slugs facilitate a mixed traveling-standing wave mode.Moreover,higher slug frequencies lead to increased fatigue accumulation,especially over an extended touchdown zone,thereby compromising the structural integrity of the riser.The findings yield valuable insights into the dynamic interactions between slug flow and riser response.This research advances the understanding of SIV mechanisms and provides a theoretical foundation for fatigue assessment and structural optimization,contributing to the safe and efficient design of offshore risers in deepwater environments.展开更多
A deep-sea mining riser is a crucial component of the system used to lift seafloor mineral resources to the vessel.It is prone to damage and failure because of harsh environmental conditions and internal fluid erosion...A deep-sea mining riser is a crucial component of the system used to lift seafloor mineral resources to the vessel.It is prone to damage and failure because of harsh environmental conditions and internal fluid erosion.Furthermore,damage can impact the response characteristics of the riser,but varying environmental loadings easily mask it.Thus,distin-guishing between riser damage and environmental effects poses a considerable challenge.To address this issue,a cantilevered model is created for a deep-sea mining riser via the concentrated mass method,and a time-domain analytical strategy is developed.The vortex-induced vibration(VIV)response characteristics of the riser are initially examined,considering various damage conditions and flow velocities.The study results revealed four primary observations:(a)effective tension can serve as a reliable indicator for identifying damage at lower velocities;(b)there are noticeable differences in displacement between the healthy and damaged risers in the in-line direction rather than the cross-flow direction;(c)frequency characteristics can more effectively distinguish the damage conditions at high flow velocities,with the mean square frequency and frequency variance being more effective than the centroid frequency and root variance frequency;(d)displacement differences are more sensitive to damage occurring near the top and bottom of the riser,while both velocity variations and structural damage can influence displacements,especially in regions between modal nodes.The vibrational behavior and damage indicators are clarified for structural health monitoring of deep-sea mining risers during lifting operations.展开更多
Understanding the mesoscopic tensile fracture damage of rock is the basis of evaluating the deterioration process of mechanical properties of heat-damaged rock. For this, tensile tests of rocks under high-temperature ...Understanding the mesoscopic tensile fracture damage of rock is the basis of evaluating the deterioration process of mechanical properties of heat-damaged rock. For this, tensile tests of rocks under high-temperature treatment were conducted with a ϕ75 mm split Hopkinson tension bar (SHTB) to investigate the mesoscopic fracture and damage properties of rock. An improved scanning electron microscopy (SEM) experimental method was used to analyze the tensile fracture surfaces of rock samples. Qualitative and quantitative analyses were performed to assess evolution of mesoscopic damage of heat-damaged rock under tensile loading. A constitutive model describing the mesoscopic fractal damage under thermo-mechanical coupling was established. The results showed that the high temperatures significantly reduced the tensile strength and fracture surface roughness of the red sandstone. The three-dimensional (3D) reconstruction of the fracture surface of the samples that experienced tensile failure at 900 °C showed a flat surface. The standard deviation of elevation and slope angle of specimen fracture surface first increased and then decreased with increasing temperature. The threshold for brittle fracture of the heat-damaged red sandstone specimens was 600 °C. Beyond this threshold temperature, local ductile fracture occurred, resulting in plastic deformation of the fracture surface during tensile fracturing. With increase of temperature, the internal meso-structure of samples was strengthened slightly at first and then deteriorated gradually, which was consistent with the change of macroscopic mechanical properties of red sandstone. The mesoscopic characteristics, such as the number, mean side length, maximum area, porosity, and fractal dimension of crack, exhibited an initial decline, followed by a gradual increase. The development of microcracks in samples had significant influence on mesoscopic fractal dimension. The mesoscopic fractal characteristics were used to establish a mesoscopic fractal damage constitutive model for red sandstone, and the agreement between the theoretical and experimental results validated the proposed model.展开更多
The DDR(DNA damage response)is an essential cellular mechanism that detects and repairs DNA lesions to maintain genomic stability.Dysregulation of DDR pathways is frequently observed in human tumors,leading to increas...The DDR(DNA damage response)is an essential cellular mechanism that detects and repairs DNA lesions to maintain genomic stability.Dysregulation of DDR pathways is frequently observed in human tumors,leading to increased genomic instability and promoting tumor progression.Consequently,targeting DDR mechanisms has emerged as a promising therapeutic strategy in oncology.This review provides an overview of the major DDR pathways,highlighting the roles of key proteins involved in various DDR processes.A detailed understanding of these molecular mechanisms has paved the way for the development of targeted antitumor agents,including inhibitors of PARP1,ATM,ATR,CHK1,CHK2,DNA-PK,and WEE1.Additionally,the significant challenges in the development of DDR inhibitors are examined,including tumor microenvironment heterogeneity,resistance mechanisms,issues with selectivity and toxicity,and the complexities associated with clinical trial design.Finally,future directions and emerging strategies to improve DDR-targeted therapies are discussed.These strategies include biomarker-driven precision medicine,novel combination therapies,advanced drug delivery systems,and the potential application of artificial intelligence to optimize treatment outcomes.展开更多
The Zika virus(ZIKV),a member of the Flaviviridae family,attracted worldwide attention for its connection to severe neurological effects,notably microcephaly in newborns,first reported during the 2015 epidemic in Braz...The Zika virus(ZIKV),a member of the Flaviviridae family,attracted worldwide attention for its connection to severe neurological effects,notably microcephaly in newborns,first reported during the 2015 epidemic in Brazil.Yet,its impact goes beyond fetal and neonatal abnormalities,also affecting the central nervous system(CNS)in both children and adults,leading to enduring cognitive and behavioral impairments.展开更多
The paper presents experimental investigation results of crack pattern change in cement pastes caused by external sulfate attack(ESA).To visualize the formation and development of cracks in cement pastes under ESA,an ...The paper presents experimental investigation results of crack pattern change in cement pastes caused by external sulfate attack(ESA).To visualize the formation and development of cracks in cement pastes under ESA,an X-ray computed tomography(X-ray CT)was used,i e,the tomography system of Zeiss Xradia 510 versa.The results indicate that X-CT can monitor the development process and distribution characteristics of the internal cracks of cement pastes under ESA with attack time.In addition,the C3A content in the cement significantly affects the damage mode of cement paste specimens during sulfate erosion.The damage of ordinary Portland cement(OPC)pastes subjected to sulfate attack with high C3A content are severe,while the damage of sulfate resistant Portland cement(SRPC)pastes is much smaller than that of OPC pastes.Furthermore,a quadratic function describes the correlation between the crack volume fraction and development depth for two cement pastes immermed in sulfate solution.展开更多
To verify the wear resistance and erosion resistance of Ti-doped Ta_(2)O_(5)coating(TTO),a series of TTOs were prepared by magnetron sputtering technology by controlling the power of the Ti target.The change of growth...To verify the wear resistance and erosion resistance of Ti-doped Ta_(2)O_(5)coating(TTO),a series of TTOs were prepared by magnetron sputtering technology by controlling the power of the Ti target.The change of growth structure,microstructure,and tribological properties of TTOs with Ti target power was studied.After the erosion test,the variation of erosion damage behavior of TTOs with mechanical properties under different erosion conditions was further studied.The results show that the TTOs eliminate the roughness,voids,and defects in the material due to the mobility of the adsorbed atoms during the growth process,and a flat and dense smooth surface is obtained.Tribological tests show that the TTOs are mainly characterized by plastic deformation and microcrack wear mechanism.Higher Ti target power can improve the wear resistance of TTOs.Erosion test results reveal that the impact crater,furrow,micro-cutting,brittle spalling,and crack formation are the main wear mechanisms of the TTOs samples under erosion conditions.展开更多
Overview of the DNA damage response(DDR)in tumor cells.DDR is a highly coordinated signaling network that repairs DNA damage caused by intrinsic cellular processes and extrinsic insults,thereby preventing genome insta...Overview of the DNA damage response(DDR)in tumor cells.DDR is a highly coordinated signaling network that repairs DNA damage caused by intrinsic cellular processes and extrinsic insults,thereby preventing genome instability.Depending on the type of damage,distinct DNA damage repair and DNA damage tolerance(DDT)pathways are involved and coordinately regulated.展开更多
Static adsorption and dynamic damage experiments were carried out on typical 8#deep coal rock of the Carboniferous Benxi Formation in the Ordos Basin,NW China,to evaluate the adsorption capacity of hydroxypropyl guar ...Static adsorption and dynamic damage experiments were carried out on typical 8#deep coal rock of the Carboniferous Benxi Formation in the Ordos Basin,NW China,to evaluate the adsorption capacity of hydroxypropyl guar gum and polyacrylamide as fracturing fluid thickeners on deep coal rock surface and the permeability damage caused by adsorption.The adsorption morphology of the thickener was quantitatively characterized by atomic force microscopy,and the main controlling factors of the thickener adsorption were analyzed.Meanwhile,the adsorption mechanism of the thickener was revealed by Zeta potential,Fourier infrared spectroscopy and X-ray photoelectron spectroscopy.The results show that the adsorption capacity of hydroxypropyl guar gum on deep coal surface is 3.86 mg/g,and the permeability of coal rock after adsorption decreases by 35.24%–37.01%.The adsorption capacity of polyacrylamide is 3.29 mg/g,and the permeability of coal rock after adsorption decreases by 14.31%–21.93%.The thickness of the thickener adsorption layer is positively correlated with the mass fraction of thickener and negatively correlated with temperature,and a decrease in pH will reduce the thickness of the hydroxypropyl guar gum adsorption layer and make the distribution frequency of the thickness of polyacrylamide adsorption layer more concentrated.Functional group condensation and intermolecular force are chemical and physical forces for adsorbing fracturing fluid thickener in deep coal rock.Optimization of thickener mass fraction,chemical modification of thickener molecular,oxidative thermal degradation of polymer and addition of desorption agent can reduce the potential damages on micro-nano pores and cracks in coal rock.展开更多
This paper aims to experimentally and numerically probe fatigue behaviours and lifetimes of 3D4D(three-dimensional four-directional)braided composite I-beam under four-point flexure spectrum loading.New fatigue damage...This paper aims to experimentally and numerically probe fatigue behaviours and lifetimes of 3D4D(three-dimensional four-directional)braided composite I-beam under four-point flexure spectrum loading.New fatigue damage models of fibre yarn,matrix and fibre–matrix interface are proposed,and fatigue failure criteria and PFDA(Progressive Fatigue Damage Algorithm)are thus presented for meso-scale fatigue damage modelling of 3D4D braided composite I-beam.To validate the aforementioned model and algorithm,fatigue tests are conducted on the 3D4D braided composite I-beam under four-point flexure spectrum loading,and fatigue failure mechanisms are analyzed and discussed.Novel global–local FE(Finite Element)model based on the PFDA is generated for modelling progressive fatigue failure process and predicting fatigue life of 3D4D braided composite I-beam under four-point flexure spectrum loading.Good agreement has been achieved between experimental results and predictions,demonstrating the effective usage of new model.It is shown that matrix cracking and interfacial debonding initially initiates on top surface of top flange of I-beam,and then gradually propagates from the side surface of top flange to the intermediate web along the braiding angle,and considerable fiber breakage finally causes final fatigue failure of I-beam.展开更多
Localized rock failures,like cracks or shear bands,demand specific attention in modeling for solids and structures.This is due to the uncertainty of conventional continuum-based mechanical models when localized inelas...Localized rock failures,like cracks or shear bands,demand specific attention in modeling for solids and structures.This is due to the uncertainty of conventional continuum-based mechanical models when localized inelastic deformation has emerged.In such scenarios,as macroscopic inelastic reactions are primarily influenced by deformation and microstructural alterations within the localized area,internal variables that signify these microstructural changes should be established within this zone.Thus,localized deformation characteristics of rocks are studied here by the preset angle shear experiment.A method based on shear displacement and shear stress differences is proposed to identify the compaction,yielding,and residual points for enhancing the model's effectiveness and minimizing subjective influences.Next,a mechanical model for the localized shear band is depicted as an elasto-plastic model outlining the stress-displacement relation across both sides of the shear band.Incorporating damage theory and an elasto-plastic model,a proposed damage model is introduced to replicate shear stressdisplacement responses and localized damage evolution in intact rocks experiencing shear failure.Subsequently,a novel nonlinear mathematical model based on modified logistic growth theory is proposed for depicting the shear band's damage evolution pattern.Thereafter,an innovative damage model is proposed to effectively encompass diverse rock material behaviors,including elasticity,plasticity,and softening behaviors.Ultimately,the effects of the preset angles,temperature,normal stresses and the residual shear strength are carefully discussed.This discovery enhances rock research in the proposed damage model,particularly regarding shear failure mode.展开更多
Coral reef limestone(CRL)constitutes a distinctive marine carbonate formation with complex mechanical properties.This study investigates the multiscale damage and fracture mechanisms of CRL through integrated experime...Coral reef limestone(CRL)constitutes a distinctive marine carbonate formation with complex mechanical properties.This study investigates the multiscale damage and fracture mechanisms of CRL through integrated experimental testing,digital core technology,and theoretical modelling.Two CRL types with contrasting mesostructures were characterized across three scales.Macroscopically,CRL-I and CRL-II exhibited mean compressive strengths of 8.46 and 5.17 MPa,respectively.Mesoscopically,CRL-I featured small-scale highly interconnected pores,whilst CRL-II developed larger stratified pores with diminished connectivity.Microscopically,both CRL matrices demonstrated remarkable similarity in mineral composition and mechanical properties.A novel voxel average-based digital core scaling methodology was developed to facilitate numerical simulation of cross-scale damage processes,revealing network-progressive failure in CRL-I versus directional-brittle failure in CRL-II.Furthermore,a damage statistical constitutive model based on digital core technology and mesoscopic homogenisation theory established quantitative relationships between microelement strength distribution and macroscopic mechanical behavior.These findings illuminate the fundamental mechanisms through which mesoscopic structure governs the macroscopic mechanical properties of CRL.展开更多
The trade-off between mechanistic interpretability,operational convenience,and predictive accuracy is challenging for predicting the lifetime of lithium-ion batteries.To resolve this contradiction,we propose a damage ...The trade-off between mechanistic interpretability,operational convenience,and predictive accuracy is challenging for predicting the lifetime of lithium-ion batteries.To resolve this contradiction,we propose a damage model based on fatigue damage theory and electrochemical impedance spectroscopy.The causal relationship of“fatigue damage→resistance increase→capacity fading”is revealed to describe the underlying mechanism.Charge transfer resistance is chosen as the variable to ensure the convenience of data acquisition.To verify the accuracy of the model,the electrochemical impedance spectrum and capacity of a graphene-coated silicon electrode at two charging rates are collected and analyzed.50% and 75% of the measured data are utilized as inputs to compare the prediction capabilities of the proposed damage model and the existing empirical model.The particle filter algorithm is adopted to train the parameters of both models.The maximum prediction error of the damage model is less than 3%,showing better prediction accuracy and medium-term prediction stability than the empirical model.Our work demonstrates that the proposed damage model is an effective way to resolve contradictions in lifetime prediction.展开更多
基金supported by the Innovation Foundation of Provincial Education Department of Gansu(2024B-005)the Gansu Province National Science Foundation(22YF7GA182)the Fundamental Research Funds for the Central Universities(No.lzujbky2022-kb01)。
文摘Modal parameters can accurately characterize the structural dynamic properties and assess the physical state of the structure.Therefore,it is particularly significant to identify the structural modal parameters according to the monitoring data information in the structural health monitoring(SHM)system,so as to provide a scientific basis for structural damage identification and dynamic model modification.In view of this,this paper reviews methods for identifying structural modal parameters under environmental excitation and briefly describes how to identify structural damages based on the derived modal parameters.The paper primarily introduces data-driven modal parameter recognition methods(e.g.,time-domain,frequency-domain,and time-frequency-domain methods,etc.),briefly describes damage identification methods based on the variations of modal parameters(e.g.,natural frequency,modal shapes,and curvature modal shapes,etc.)and modal validation methods(e.g.,Stability Diagram and Modal Assurance Criterion,etc.).The current status of the application of artificial intelligence(AI)methods in the direction of modal parameter recognition and damage identification is further discussed.Based on the pre-vious analysis,the main development trends of structural modal parameter recognition and damage identification methods are given to provide scientific references for the optimized design and functional upgrading of SHM systems.
基金support from the National Natural Science Foundation of China(No.52308316)the Scientific Research Foundation of Weifang University(Grant No.2024BS42)+2 种基金China Postdoctoral Science Foundation(No.2022M721885)the Key Laboratory of Rock Mechanics and Geohazards of Zhejiang Province(No.ZJRMG-2022-01)supported by Open Research Fund of State Key Laboratory of Geomechanics and Geotechnical Engineering,Institute of Rock and Soil Mechanics,Chinese Academy of Sciences(NO.SKLGME023017).
文摘Investigating the combined effects of mining damage and creep damage on slope stability is crucial,as it can comprehensively reveal the non-linear deformation characteristics of rock under their joint influence.This study develops a fractional-order nonlinear creep constitutive model that incorporates the double damage effect and implements a non-linear creep subroutine for soft rock using the threedimensional finite difference method on the FLAC3D platform.Comparative analysis of the theoretical,numerical,and experimental results reveals that the fractional-order constitutive model,which incorporates the double damage effect,accurately reflects the distinct deformation stages of green mudstone during creep failure and effectively captures the non-linear deformation in the accelerated creep phase.The numerical results show a fitting accuracy exceeding 97%with the creep test curves,significantly outperforming the 61%accuracy of traditional creep models.
基金support by the National Natural Science Foundation of China(52201077)the Natural Science Foundation of Shandong Province(ZR2022QE191)+1 种基金Elite Scheme of Shandong University of Science and Technology(0104060541123)Talent introduction and Research Start-up Fund of Shandong University of Science and Technology(0104060510124).
文摘Coating microdefects and localized corrosion in coating/metal system are inevitable,accelerating the degradation of metal infrastructure.Early evaluating coating microdefects and detecting corrosion sites are urgent yet remain challenge to achieve.Herein,we propose a robust,universal and efficient fluorescence-based strategy for hierarchical warning of coating damage and metal corrosion by introducing the concepts of damage-induced fluorescence enhancement effect(DIE)and ionic-recognition induced quenching effect(RIQ).The coatings with dualresponsiveness for coating defect and steel corrosion are constructed by incorporating synthesized nanoprobes composed of metal organic frameworks(Ni–Zn-MOFs)loaded with Rhodamine B(RhB@MOFs).The initial damage to the coating causes an immediate intensification of fluorescence,while the specific ionic-recognition characteristic of RhB with Fe3t results in an evident fluorescence quenching,enabling the detection of coating damage and corrosion.Importantly,this nanoprobes are insensitive to the coating matrix and exhibit stable corrosion warning capability across various coating systems.Meanwhile,electrochemical investigations indicate that the impedance values of RM/EP maintain above 10^(8)Ωcm^(2)even after 60 days of immersion.Therefore,the incorporation of fluorescent nanoprobes greatly inhibits the intrusion of electrolytes into polymer and improves the corrosion protection performance of the coating.This powerful strategy towards dual-level damage warning provides insights for the development of long-term smart protective materials.
基金supports from National Natural Science Foundation of China(Grant No.52105498)The science and technology innovation Program of Hunan Province(Grant No.2021RC3074)+2 种基金Advanced Laser Technology Laboratory of Anhui Province(AHL2022KF04)National Key R&D Program of China(Grant No.2023YFB14605500)Changsha Natural Science Foundation(kq2402089).
文摘Combined pulsed laser(CPL),introduced in 1975 for target damage,integrates different lasers to achieve high peak power and pulse energy.However,despite decades of research,CPL remains unused for long-range target damage due to the challenge of maintaining high peak power density over long distances.We note that a potential solution lies in leveraging the air filament generated by femtosecond laser,which can transmit peak power densities higher than 1014 W/cm^(2)under the power clamping effect.To address this,a concept of a femtosecond laser induced air filament-CW CPL for surface damage of ceramics was introduced.We found no surface changes in ceramic targets when irradiated with a CW laser alone.By way of contrast,the target can be penetrated in a very short time(20 ms)with the assistance of the femtosecond laser induced air filament.In this context,we employ high-speed shadow imaging,cross-timescale simulation models and macro-microscopic characterization,to elucidate the CPL damage mechanism.The optimal CPL,combining a 1 mJ femtosecond laser and a 500 W CW laser,yields a damage rate of 1.51×10^(7)μm^(3)/J,representing an improvement of approximately 175%compared to single femtosecond laser ablation and around 59%enhancement compared to coating-assisted CW laser ablation.Furthermore,the efficacy of the proposed femtosecond-CW CPL method is demonstrated in causing penetration damage of ceramic/metal composite material or direct damage of sapphire,showcasing its versatility in damaging applications.Consequently,the femtosecond-CW CPL ablation method presented in this paper holds great promise as a new type of damage method for transparent hard and brittle materials.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.U20A20266 and 12302503)Scientific and technological research projects in Sichuan province(Grant No.2024NSFSC0973).
文摘The loaded rock experiences multiple stages of deformation.It starts with the formation of microcracks at low stresses(crack initiation,CI)and then transitions into unstable crack propagation(crack damage,CD)near the ultimate strength.In this study,both the acoustic emission method(AEM)and the ultrasonic testing method(UTM)were used to examine the characteristics of AE parameters(b-value,peak frequency,frequency-band energy ratio,and fractal dimension)and ultrasonic(ULT)properties(velocity,amplitude,energy attenuation,and scattering attenuation)of bedded shale at CI,CD,and ultimate strength.The comparison involved analyzing the strain-based method(SBM),AEM,and UTM to determine the thresholds for damage stress.A fuzzy comprehensive evaluation model(FCEM)was created to describe the damage thresholds and hazard assessment.The results indicate that the optimal AE and ULT parameters for identifying CI and CD stress are ringing count,ultrasonic amplitude,energy attenuation,and scattering attenuation of the S-wave.Besides,damage thresholds were detected earlier by AE monitoring,ranging from 3 MPa to 10 MPa.CI and CD identified by UTM occurred later than SBM and AEM,and were in the range of 12 MPa.The b-value,peak frequency,energy ratio in the low-frequency band(0e62.5 kHz),correlation dimension,and sandbox dimension showed low values at the peak stress,while the energy ratio in a moderate-frequency band(187.5e281.25 kHz)and amplitude showed high values.The successful application of FCEM to laboratory testing of shales has demonstrated its ability to quantitatively identify AE/ULT precursors of seismic hazards associated with rock failure.
基金supported by the National Natural Science Foundation of China(Nos.82241088 and 82203996)the China Postdoctoral Science Foundation(Nos.2022T150230 and 2021M691131).
文摘Arsenic-related oxidative stress and resultant diseases have attracted global concern,while longitudinal studies are scarce.To assess the relationship between arsenic exposure and systemic oxidative damage,we performed two repeatedmeasures among 5236 observations(4067 participants)in theWuhan-Zhuhai cohort at the baseline and follow-up after 3 years.Urinary total arsenic,biomarkers of DNA oxidative damage(8-hydroxy-2-deoxyguanosine(8-OHdG)),lipid peroxidation(8-isoprostaglandin F2alpha(8-isoPGF2α)),and protein oxidative damage(protein carbonyls(PCO))were detected for all observations.Here we used linearmixed models to estimate the cross-sectional and longitudinal associations between arsenic exposure and oxidative damage.Exposure-response curves were constructed by utilizing the generalized additive mixed models with thin plate regressions.After adjusting for potential confounders,arsenic level was significantly and positively related to the levels of global oxidative damage and their annual increased rates in dose-response manners.In cross-sectional analyses,each 1%increase in arsenic levelwas associated with a 0.406%(95%confidence interval(CI):0.379%to 0.433%),0.360%(0.301%to 0.420%),and 0.079%(0.055%to 0.103%)increase in 8-isoPGF2α,8-OHdG,and PCO,respectively.More importantly,arsenic was further found to be associated with increased annual change rates of 8-isoPGF2α(β:0.147;95%CI:0.130 to 0.164),8-OHdG(0.155;0.118 to 0.192),and PCO(0.050;0.035 to 0.064)in the longitudinal analyses.Our study suggested that arsenic exposurewas not only positively related with global oxidative damage to lipid,DNA,and protein in cross-sectional analyses,but also associated with annual increased rates of these biomarkers in dose-dependent manners.
基金supported by the National Natural Science Foundation of China(Grant No.12172052)the Foundation of State Key Laboratory of Explosion Science and Safety Protection(Grant No.QKKT24-02).
文摘The penetration-deflagration coupling damage performance of rod-like reactive shaped charge pene-trator(RRSCP)impacting thick steel plates is investigated by theoretical analysis and experiments.A penetration-deflagration coupling damage model is developed to predict the penetration depth and cratering diameter.Four type of aluminum-polytetrafluoroethylene-copper(Al-PTFE-Cu)reactive liners with densities of 2.3,2.7,3.5,and 4.5 g·cm^(-3) are selected to conduct the penetration experiments.The comparison results show that model predictions are in good agreement with the experimental data.By comparing the penetration depth and cratering diameter in the inert penetration mode and the penetration-deflagration coupling mode,the influence mechanism that the penetration-induced chemical response is unfavorable to penetration but has an enhanced cratering effect is revealed.From the formation characteristics,penetration effect and penetration-induced chemical reaction be-haviors,the influence of reactive liner density on the penetration-deflagration performance is further analyzed.The results show that increasing the density of reactive liner significantly increases both the kinetic energy and length of the reactive penetrator,meanwhile effectively reduces the weakened effect of penetration-induced chemical response,resulting in an enhanced penetration capability.However,due to the decreased diameter and potential energy content of reactive penetrator,the cratering capa-bility is weakened significantly.
基金financially supported by the National Natural Science Foundation of China(Grant No.52222111)the Science Foundation of China University of Petroleum,Beijing(Grant No.2462025SZBH002)。
文摘This study examines the slug-induced vibration(SIV)response and fatigue behavior of offshore risers subjected to internal slug flow.A structural model incorporating internal slug flow dynamics is developed using the Absolute Nodal Coordinate Formulation(ANCF)and a spatial-temporal density variation equation to analyze how slug flow parameters affect the SIV response of risers.Structural displacement,stress,and fatigue responses are systematically evaluated to characterize the structural behavior under SIV conditions.Longer slugs induce more pronounced traveling wave characteristics,while shorter slugs facilitate a mixed traveling-standing wave mode.Moreover,higher slug frequencies lead to increased fatigue accumulation,especially over an extended touchdown zone,thereby compromising the structural integrity of the riser.The findings yield valuable insights into the dynamic interactions between slug flow and riser response.This research advances the understanding of SIV mechanisms and provides a theoretical foundation for fatigue assessment and structural optimization,contributing to the safe and efficient design of offshore risers in deepwater environments.
基金financially supported by the National Key Research and Development Program of China(Grant No.2023YFC2811600)the National Natural Science Foundation of China(Grant Nos.52301349 and 52088102)+1 种基金the Qingdao Post-Doctorate Science Fund(No.QDBSH20220202070)the Major Scientific and Technological Innovation Project of Shandong Province(Grant No.2019JZZY010820).
文摘A deep-sea mining riser is a crucial component of the system used to lift seafloor mineral resources to the vessel.It is prone to damage and failure because of harsh environmental conditions and internal fluid erosion.Furthermore,damage can impact the response characteristics of the riser,but varying environmental loadings easily mask it.Thus,distin-guishing between riser damage and environmental effects poses a considerable challenge.To address this issue,a cantilevered model is created for a deep-sea mining riser via the concentrated mass method,and a time-domain analytical strategy is developed.The vortex-induced vibration(VIV)response characteristics of the riser are initially examined,considering various damage conditions and flow velocities.The study results revealed four primary observations:(a)effective tension can serve as a reliable indicator for identifying damage at lower velocities;(b)there are noticeable differences in displacement between the healthy and damaged risers in the in-line direction rather than the cross-flow direction;(c)frequency characteristics can more effectively distinguish the damage conditions at high flow velocities,with the mean square frequency and frequency variance being more effective than the centroid frequency and root variance frequency;(d)displacement differences are more sensitive to damage occurring near the top and bottom of the riser,while both velocity variations and structural damage can influence displacements,especially in regions between modal nodes.The vibrational behavior and damage indicators are clarified for structural health monitoring of deep-sea mining risers during lifting operations.
基金supported by The National Natural Science Foundation of China(Grant Nos.12272411 and 42007259).
文摘Understanding the mesoscopic tensile fracture damage of rock is the basis of evaluating the deterioration process of mechanical properties of heat-damaged rock. For this, tensile tests of rocks under high-temperature treatment were conducted with a ϕ75 mm split Hopkinson tension bar (SHTB) to investigate the mesoscopic fracture and damage properties of rock. An improved scanning electron microscopy (SEM) experimental method was used to analyze the tensile fracture surfaces of rock samples. Qualitative and quantitative analyses were performed to assess evolution of mesoscopic damage of heat-damaged rock under tensile loading. A constitutive model describing the mesoscopic fractal damage under thermo-mechanical coupling was established. The results showed that the high temperatures significantly reduced the tensile strength and fracture surface roughness of the red sandstone. The three-dimensional (3D) reconstruction of the fracture surface of the samples that experienced tensile failure at 900 °C showed a flat surface. The standard deviation of elevation and slope angle of specimen fracture surface first increased and then decreased with increasing temperature. The threshold for brittle fracture of the heat-damaged red sandstone specimens was 600 °C. Beyond this threshold temperature, local ductile fracture occurred, resulting in plastic deformation of the fracture surface during tensile fracturing. With increase of temperature, the internal meso-structure of samples was strengthened slightly at first and then deteriorated gradually, which was consistent with the change of macroscopic mechanical properties of red sandstone. The mesoscopic characteristics, such as the number, mean side length, maximum area, porosity, and fractal dimension of crack, exhibited an initial decline, followed by a gradual increase. The development of microcracks in samples had significant influence on mesoscopic fractal dimension. The mesoscopic fractal characteristics were used to establish a mesoscopic fractal damage constitutive model for red sandstone, and the agreement between the theoretical and experimental results validated the proposed model.
文摘The DDR(DNA damage response)is an essential cellular mechanism that detects and repairs DNA lesions to maintain genomic stability.Dysregulation of DDR pathways is frequently observed in human tumors,leading to increased genomic instability and promoting tumor progression.Consequently,targeting DDR mechanisms has emerged as a promising therapeutic strategy in oncology.This review provides an overview of the major DDR pathways,highlighting the roles of key proteins involved in various DDR processes.A detailed understanding of these molecular mechanisms has paved the way for the development of targeted antitumor agents,including inhibitors of PARP1,ATM,ATR,CHK1,CHK2,DNA-PK,and WEE1.Additionally,the significant challenges in the development of DDR inhibitors are examined,including tumor microenvironment heterogeneity,resistance mechanisms,issues with selectivity and toxicity,and the complexities associated with clinical trial design.Finally,future directions and emerging strategies to improve DDR-targeted therapies are discussed.These strategies include biomarker-driven precision medicine,novel combination therapies,advanced drug delivery systems,and the potential application of artificial intelligence to optimize treatment outcomes.
文摘The Zika virus(ZIKV),a member of the Flaviviridae family,attracted worldwide attention for its connection to severe neurological effects,notably microcephaly in newborns,first reported during the 2015 epidemic in Brazil.Yet,its impact goes beyond fetal and neonatal abnormalities,also affecting the central nervous system(CNS)in both children and adults,leading to enduring cognitive and behavioral impairments.
基金Funded by Chinese National Natural Science Foundation of China(No.U2006224)。
文摘The paper presents experimental investigation results of crack pattern change in cement pastes caused by external sulfate attack(ESA).To visualize the formation and development of cracks in cement pastes under ESA,an X-ray computed tomography(X-ray CT)was used,i e,the tomography system of Zeiss Xradia 510 versa.The results indicate that X-CT can monitor the development process and distribution characteristics of the internal cracks of cement pastes under ESA with attack time.In addition,the C3A content in the cement significantly affects the damage mode of cement paste specimens during sulfate erosion.The damage of ordinary Portland cement(OPC)pastes subjected to sulfate attack with high C3A content are severe,while the damage of sulfate resistant Portland cement(SRPC)pastes is much smaller than that of OPC pastes.Furthermore,a quadratic function describes the correlation between the crack volume fraction and development depth for two cement pastes immermed in sulfate solution.
文摘To verify the wear resistance and erosion resistance of Ti-doped Ta_(2)O_(5)coating(TTO),a series of TTOs were prepared by magnetron sputtering technology by controlling the power of the Ti target.The change of growth structure,microstructure,and tribological properties of TTOs with Ti target power was studied.After the erosion test,the variation of erosion damage behavior of TTOs with mechanical properties under different erosion conditions was further studied.The results show that the TTOs eliminate the roughness,voids,and defects in the material due to the mobility of the adsorbed atoms during the growth process,and a flat and dense smooth surface is obtained.Tribological tests show that the TTOs are mainly characterized by plastic deformation and microcrack wear mechanism.Higher Ti target power can improve the wear resistance of TTOs.Erosion test results reveal that the impact crater,furrow,micro-cutting,brittle spalling,and crack formation are the main wear mechanisms of the TTOs samples under erosion conditions.
基金the National Natural Science Foundation of China(Grant No.82330090 and Grant No.82341006 to C.G.)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA0460403 to C.G.)the Natural Science Foundation of Shanxi Province(Grant No.202203021211155 to X.M.).
文摘Overview of the DNA damage response(DDR)in tumor cells.DDR is a highly coordinated signaling network that repairs DNA damage caused by intrinsic cellular processes and extrinsic insults,thereby preventing genome instability.Depending on the type of damage,distinct DNA damage repair and DNA damage tolerance(DDT)pathways are involved and coordinately regulated.
基金Supported by National Natural Science Foundation of China(51674209)Sichuan Province Youth Science and Technology Innovation Team(2021JDTD0017).
文摘Static adsorption and dynamic damage experiments were carried out on typical 8#deep coal rock of the Carboniferous Benxi Formation in the Ordos Basin,NW China,to evaluate the adsorption capacity of hydroxypropyl guar gum and polyacrylamide as fracturing fluid thickeners on deep coal rock surface and the permeability damage caused by adsorption.The adsorption morphology of the thickener was quantitatively characterized by atomic force microscopy,and the main controlling factors of the thickener adsorption were analyzed.Meanwhile,the adsorption mechanism of the thickener was revealed by Zeta potential,Fourier infrared spectroscopy and X-ray photoelectron spectroscopy.The results show that the adsorption capacity of hydroxypropyl guar gum on deep coal surface is 3.86 mg/g,and the permeability of coal rock after adsorption decreases by 35.24%–37.01%.The adsorption capacity of polyacrylamide is 3.29 mg/g,and the permeability of coal rock after adsorption decreases by 14.31%–21.93%.The thickness of the thickener adsorption layer is positively correlated with the mass fraction of thickener and negatively correlated with temperature,and a decrease in pH will reduce the thickness of the hydroxypropyl guar gum adsorption layer and make the distribution frequency of the thickness of polyacrylamide adsorption layer more concentrated.Functional group condensation and intermolecular force are chemical and physical forces for adsorbing fracturing fluid thickener in deep coal rock.Optimization of thickener mass fraction,chemical modification of thickener molecular,oxidative thermal degradation of polymer and addition of desorption agent can reduce the potential damages on micro-nano pores and cracks in coal rock.
基金supported by the National Natural Science Foundation of China(No.12472340).
文摘This paper aims to experimentally and numerically probe fatigue behaviours and lifetimes of 3D4D(three-dimensional four-directional)braided composite I-beam under four-point flexure spectrum loading.New fatigue damage models of fibre yarn,matrix and fibre–matrix interface are proposed,and fatigue failure criteria and PFDA(Progressive Fatigue Damage Algorithm)are thus presented for meso-scale fatigue damage modelling of 3D4D braided composite I-beam.To validate the aforementioned model and algorithm,fatigue tests are conducted on the 3D4D braided composite I-beam under four-point flexure spectrum loading,and fatigue failure mechanisms are analyzed and discussed.Novel global–local FE(Finite Element)model based on the PFDA is generated for modelling progressive fatigue failure process and predicting fatigue life of 3D4D braided composite I-beam under four-point flexure spectrum loading.Good agreement has been achieved between experimental results and predictions,demonstrating the effective usage of new model.It is shown that matrix cracking and interfacial debonding initially initiates on top surface of top flange of I-beam,and then gradually propagates from the side surface of top flange to the intermediate web along the braiding angle,and considerable fiber breakage finally causes final fatigue failure of I-beam.
基金supported by the China Scholarship Council Program(Grant No.202008320274)it is also supported by Technical University of Munich.
文摘Localized rock failures,like cracks or shear bands,demand specific attention in modeling for solids and structures.This is due to the uncertainty of conventional continuum-based mechanical models when localized inelastic deformation has emerged.In such scenarios,as macroscopic inelastic reactions are primarily influenced by deformation and microstructural alterations within the localized area,internal variables that signify these microstructural changes should be established within this zone.Thus,localized deformation characteristics of rocks are studied here by the preset angle shear experiment.A method based on shear displacement and shear stress differences is proposed to identify the compaction,yielding,and residual points for enhancing the model's effectiveness and minimizing subjective influences.Next,a mechanical model for the localized shear band is depicted as an elasto-plastic model outlining the stress-displacement relation across both sides of the shear band.Incorporating damage theory and an elasto-plastic model,a proposed damage model is introduced to replicate shear stressdisplacement responses and localized damage evolution in intact rocks experiencing shear failure.Subsequently,a novel nonlinear mathematical model based on modified logistic growth theory is proposed for depicting the shear band's damage evolution pattern.Thereafter,an innovative damage model is proposed to effectively encompass diverse rock material behaviors,including elasticity,plasticity,and softening behaviors.Ultimately,the effects of the preset angles,temperature,normal stresses and the residual shear strength are carefully discussed.This discovery enhances rock research in the proposed damage model,particularly regarding shear failure mode.
基金the National Key Research and Development Program of China(No.2021YFC3100800)the National Natural Science Foundation of China(Nos.42407235 and 42271026)the Project of Sanya Yazhou Bay Science and Technology City(No.SCKJ-JYRC-2023-54).
文摘Coral reef limestone(CRL)constitutes a distinctive marine carbonate formation with complex mechanical properties.This study investigates the multiscale damage and fracture mechanisms of CRL through integrated experimental testing,digital core technology,and theoretical modelling.Two CRL types with contrasting mesostructures were characterized across three scales.Macroscopically,CRL-I and CRL-II exhibited mean compressive strengths of 8.46 and 5.17 MPa,respectively.Mesoscopically,CRL-I featured small-scale highly interconnected pores,whilst CRL-II developed larger stratified pores with diminished connectivity.Microscopically,both CRL matrices demonstrated remarkable similarity in mineral composition and mechanical properties.A novel voxel average-based digital core scaling methodology was developed to facilitate numerical simulation of cross-scale damage processes,revealing network-progressive failure in CRL-I versus directional-brittle failure in CRL-II.Furthermore,a damage statistical constitutive model based on digital core technology and mesoscopic homogenisation theory established quantitative relationships between microelement strength distribution and macroscopic mechanical behavior.These findings illuminate the fundamental mechanisms through which mesoscopic structure governs the macroscopic mechanical properties of CRL.
基金supported by the National Natural Science Foundation of China(12021002,12472183,and 12041201).
文摘The trade-off between mechanistic interpretability,operational convenience,and predictive accuracy is challenging for predicting the lifetime of lithium-ion batteries.To resolve this contradiction,we propose a damage model based on fatigue damage theory and electrochemical impedance spectroscopy.The causal relationship of“fatigue damage→resistance increase→capacity fading”is revealed to describe the underlying mechanism.Charge transfer resistance is chosen as the variable to ensure the convenience of data acquisition.To verify the accuracy of the model,the electrochemical impedance spectrum and capacity of a graphene-coated silicon electrode at two charging rates are collected and analyzed.50% and 75% of the measured data are utilized as inputs to compare the prediction capabilities of the proposed damage model and the existing empirical model.The particle filter algorithm is adopted to train the parameters of both models.The maximum prediction error of the damage model is less than 3%,showing better prediction accuracy and medium-term prediction stability than the empirical model.Our work demonstrates that the proposed damage model is an effective way to resolve contradictions in lifetime prediction.