Nonprecious transition metal(TM)-based materials have demonstrated tremendous potential as efficient oxygen reduction reaction(ORR)electrocatalysts.However,establishing reliable relationships between geometric/electro...Nonprecious transition metal(TM)-based materials have demonstrated tremendous potential as efficient oxygen reduction reaction(ORR)electrocatalysts.However,establishing reliable relationships between geometric/electronic structures and ORR performances remains a great challenge to design and manufacture high-performance ORR catalysts.In this study,we proposed and validated that reducing the symmetry of the coordination structure of TMs enhanced d-πinteractions,thereby strengthening their adsorption for key intermediates.Then we managed the tuning of the metal center’s spin state by substituents,further optimizing the ORR performance.Such advancements were attributed to the orientation differences in d-orbital interactions as a result of asymmetric electronic structure.Based on the understanding of such structure-activity relationships,we designed a covalent organic framework-(COF)based ORR electrocatalyst,which exhibited high activity,rapid kinetic response,and high four-electron transfer selectivity.This work validates an alternative strategy for enhanced ORR through the management of d-πinteractions utilizing asymmetric coordination structures.It inspires the design of TM-based electrocatalysts by providing mechanistic insights into the precise control of the microchemical environments at TM active centers.展开更多
Developing effective,versatile,and high-precision sensing interfaces remains a crucial challenge in human-machine-environment interaction applications.Despite progress in interaction-oriented sensing skins,limitations...Developing effective,versatile,and high-precision sensing interfaces remains a crucial challenge in human-machine-environment interaction applications.Despite progress in interaction-oriented sensing skins,limitations remain in unit-level reconfiguration,multiaxial force and motion sensing,and robust operation across dynamically changing or irregular surfaces.Herein,we develop a reconfigurable omnidirectional triboelectric whisker sensor array(RO-TWSA)comprising multiple sensing units that integrate a triboelectric whisker structure(TWS)with an untethered hydro-sealing vacuum sucker(UHSVS),enabling reversibly portable deployment and omnidirectional perception across diverse surfaces.Using a simple dual-triangular electrode layout paired with MXene/silicone nanocomposite dielectric layer,the sensor unit achieves precise omnidirectional force and motion sensing with a detection threshold as low as 0.024 N and an angular resolution of 5°,while the UHSVS provides reliable and reversible multi-surface anchoring for the sensor units by involving a newly designed hydrogel combining high mechanical robustness and superior water absorption.Extensive experiments demonstrate the effectiveness of RO-TWSA across various interactive scenarios,including teleoperation,tactile diagnostics,and robotic autonomous exploration.Overall,RO-TWSA presents a versatile and high-resolution tactile interface,offering new avenues for intelligent perception and interaction in complex real-world environments.展开更多
Luminescent metal-organic frameworks(MOFs)have garnered significant attention due to their structural tunability and potential applications in solid-state lighting,bioimaging,sensing,anticounterfeiting,and other field...Luminescent metal-organic frameworks(MOFs)have garnered significant attention due to their structural tunability and potential applications in solid-state lighting,bioimaging,sensing,anticounterfeiting,and other fields.Nevertheless,due to the tendency of1,4-benzenedicarboxylic acid(BDC)to rotate within the framework,MOFs composed of it exhibit significant non-radiative energy dissipation and thus impair the emissive properties.In this study,efficient luminescence of MIL-140A nanocrystals(NCs)with BDC rotors as ligands is achieved by pressure treatment strategy.Pressure treatment effectively modulates the pore structure of the framework,enhancing the interactions between the N,N-dimethylformamide vip molecules and the BDC ligands.The enhanced host-vip interaction contributes to the structural rigidity of the MOF,thereby suppressing the rotation-induced excited-state energy loss.As a result,the pressure-treated MIL-140A NCs displayed bright blue-light emission,with the photoluminescence quantum yield increasing from an initial 6.8%to 69.2%.This study developed an effective strategy to improve the luminescence performance of rotor ligand MOFs,offers a new avenue for the rational design and synthesis of MOFs with superior luminescent properties.展开更多
Oil shale is characterized by a dense structure,low proportion of pores and fissures,and low permeability.Pore-fracture systems serve as crucial channels for shale oil migration,directly influencing the production eff...Oil shale is characterized by a dense structure,low proportion of pores and fissures,and low permeability.Pore-fracture systems serve as crucial channels for shale oil migration,directly influencing the production efficiency of shale oil resources.Effectively stimulating oil shale reservoirs remains a challenging and active research topic.This investigation employed shale specimens obtained from the Longmaxi Formation.Scanning electron microscopy,fluid injection experiments,and fluid-structure interaction simulations were used to comprehensively analyze structural changes and fluid flow behavior under high temperatures from microscopic to macroscopic scales.Experimental results indicate that the temperature has little effect on the structure and permeability of shale before 300℃.However,there are two threshold temperatures within the range of 300 to 600℃that have significant effects on the structure and permeability of oil shale.The first threshold temperature is between 300 and 400℃,which causes the oil shale porosity,pore-fracture ratio,and permeability begin to increase.This is manifested by the decrease in micropores and mesopores,the increase in macropores,and the formation of a large number of isolated pores and fissures within the shale.The permeability increases but not significantly.The second threshold temperature is between 500 and 600℃,which increases the permeability of oil shale significantly.During this stage,micropores and mesopores are further reduced,and macropores are significantly enlarged.A large number of connected and penetrated pores and fissures are formed.More numerous and thicker streamlines appear inside the oil shale.The experimental results demonstrate that high temperatures significantly alter the microstructure and permeability of oil shale.At the same time,the experimental results can provide a reference for the research of in-situ heating techniques in oil shale reservoir transformation.展开更多
Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling ...Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.展开更多
Beryllium-containing sludge(BCS)is a typical hazardous waste from Be smelting,which can cause serious harm to ecology and human health by releasing harmful Be if it is stored long-term in environment.Nonetheless,the o...Beryllium-containing sludge(BCS)is a typical hazardous waste from Be smelting,which can cause serious harm to ecology and human health by releasing harmful Be if it is stored long-term in environment.Nonetheless,the occurrence of Be in BCS is unclear,which seriously hinders the development of pollution control technologies.In order to enhance the understanding of BCS,the occurrence of Be and the microscale interactions with coexisting phases were investigated for the first time.It was found that CaSO_(4)·2H_(2)O and amorphous SiO_(2) are the primary phases of BCS.The simulated experiments of purified materials showed that Be interacted with CaSO_(4)·2H_(2)O and amorphous SiO_(2).Be can enter into the lattice of CaSO_(4)·2H_(2)O mainly as free Be2+.Amorphous SiO_(2) can adsorb Be2+particularly at a pH range of 3–5.The dissolution behavior experiment of BCS shows that about 52%of the Be is readily extracted under acidic conditions,which refers to the Be of independent occurrence.In contrast,the remaining 48%of Be can be extracted only after the CaSO_(4)·2H_(2)O has completely dissolved.Hence,CaSO_(4)·2H_(2)O is identified as the key occurrence phase which determines the highly efficient dissolution of Be.As a result,this study enhances the understanding of BCS and lays the foundation for the development of Be separation technologies.展开更多
A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and...A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and development of the NMI model and then emphasize that the NMI model represents a new tool for identifying the basic physics of how climate change influences mid-to-high latitude weather extremes.The building of the NMI model took place over three main periods.In the 1990s,a nonlinear Schr?dinger(NLS)equation model was presented to describe atmospheric blocking as a wave packet;however,it could not depict the lifetime(10-20 days)of atmospheric blocking.In the 2000s,we proposed an NMI model of atmospheric blocking in a uniform basic flow by making a scale-separation assumption and deriving an eddyforced NLS equation.This model succeeded in describing the life cycle of atmospheric blocking.In the 2020s,the NMI model was extended to include the impact of a changing climate mainly by altering the basic zonal winds and the magnitude of the meridional background potential vorticity gradient(PVy).Model results show that when PVy is smaller,blocking has a weaker dispersion and a stronger nonlinearity,so blocking can be more persistent and have a larger zonal scale and weaker eastward movement,thus favoring stronger weather extremes.However,when PVy is much smaller and below a critical threshold under much stronger winter Arctic warming of global warming,atmospheric blocking becomes locally less persistent and shows a much stronger westward movement,which acts to inhibit local cold extremes.Such a case does not happen in summer under global warming because PVy fails to fall below the critical threshold.Thus,our theory indicates that global warming can render summer-blocking anticyclones and mid-to-high latitude heatwaves more persistent,intense,and widespread.展开更多
This work focuses on the fluid-rigid interaction dynamics in the presence of a magnetic field.A rigid thin rectangular column immersed inside stationary metal liquid vibrates with a fixed small amplitude.The magneto-f...This work focuses on the fluid-rigid interaction dynamics in the presence of a magnetic field.A rigid thin rectangular column immersed inside stationary metal liquid vibrates with a fixed small amplitude.The magneto-fluid-solid interaction(MFSI)dynamics issue is studied based on the complex Green’s function method.Considering either the normal or tangential vibration of a column,two types of semi-analytical solutions expressed by stream function integral equations of magnetic corrections,describing the time-displacement history of the column,flow field and electrical potential field of metal fluid and representing transient coupling effects of multi-physics field,are derived,respectively.Nonuniform discretization schemes and an iterative plan are applied to evaluate added damping and inertial loads.The results show that the main factor affecting normal vibration is pressure load,and the main factor affecting tangential vibration is vorticity load.The nonlinear effects of magnetic fields on the dynamics of fluid-rigid thin columns are revealed.The normal vibration exhibits better stability than the tangential vibration under the magnetic field.The induced electrical potential field and current intensity excited by normal vibration are significantly stronger than that of tangential vibration.These semi-analytical solutions can be applied as benchmarks in future validation and verification works for MFSI numerical algorithms for magnetic confinement nuclear fusion science.展开更多
We explored a distinct mechanism for matter creation via electron-positron pair production during bound-bound transitions in the deexcitation of muonic atoms.For ions with nuclear charges Z≥24,transitions from low-ly...We explored a distinct mechanism for matter creation via electron-positron pair production during bound-bound transitions in the deexcitation of muonic atoms.For ions with nuclear charges Z≥24,transitions from low-lying excited states to the 1s-muon state can lead to the production of electron-positron pairs.We show that the Breit interaction determines the transition probabilities for states with nonzero orbital momentum.We show that the pair production arises mainly from the decay of the 2p states.Thus,the Breit interaction governs electron-positron pair production in bound-bound muon transitions.This process offers a unique opportunity to explore quantum electrodynamics in strong fields,as well as a class of nonradiative transitions involving electron-positron pair production.展开更多
Jadeitites are formed either through direct precipitation from Na-Al-Si rich fluids(P-type),or by replacement of magmatic protoliths(R-type)in subduction zones.They are valuable targets for investigating the mobility ...Jadeitites are formed either through direct precipitation from Na-Al-Si rich fluids(P-type),or by replacement of magmatic protoliths(R-type)in subduction zones.They are valuable targets for investigating the mobility behavior and chemical composition of subduction zone fluids.The Rio San Juan Complex(RSJC)in the northern Dominican Republic hosts both P-and R-type jadeitites and jadeite-rich rocks,which provide ideal samples for addressing such issues.Here,we present trace element and Sr-Nd-O-Si isotope compositions of RSJC jadeitites and related rocks.Most samples show similar REE patterns,trace element distributions and δ^(18)O values to those of plagiogranite protoliths,indicating the predominance of R-type origin in RSJC.The P-type samples exhibit slightly higherδ^(30)Si values(−0.15‰to 0.25‰)than that of R-type samples(−0.20‰to 0.08‰),which place above the igneous array.The low(^(87)Sr/^(86)Sr)_(i)(0.70346 to 0.70505)and highεNd(t)values(4.6 to 6.8)of the P-type jadeitites and quartzites,along with relatively lowδ^(18)O values(4.7‰to 6.4‰)of their forming fluids,indicate that the fluids are likely derived from the altered basaltic crust rather than from oceanic sediment.However,the estimated jadeitite-and quartzite-forming fluids exhibit distinctδ^(30)Si values(0.76‰to 0.99‰and-0.48‰to-0.08‰,respectively),implying an evolution of the fluids that modified the Si isotopic compositions.Since fluid metasomatism and related desilication process could have lowered the whole-rock δ^(30)Si values,the heavy Si isotope compositions of the R-type samples are produced from the external fluids.Combing Rayleigh distillation and binary mixing simulations,we propose that fluids derived from altered oceanic crust obtained high δ^(30)Si values after crystallization of minerals enriched in light Si isotopes.The P-type jadeitites are formed through direct precipitation from this fluid.As the plagiogranite protoliths were continuously replaced by this fluid,the formed R-type samples(jadeitites and quartzites)also exhibit high δ^(30)Si values.Such rocks could significantly alter the Si isotope compositions of local mantle when they are deeply subducted at convergent plate margins.展开更多
Submarine pipelines are critical infrastructures for offshore energy transport and communications. Understanding their structural response to near-field explosions is crucial for enhancing their blast resistance and o...Submarine pipelines are critical infrastructures for offshore energy transport and communications. Understanding their structural response to near-field explosions is crucial for enhancing their blast resistance and operational safety. This study presents a computational study on the interaction between explosion-induced bubbles and a seabed-mounted pipeline. A recently developed computational framework is employed, which couples a compressible fluid solver with a finite element structural solver via a partitioned procedure. An embedded boundary method and a level-set method are employed to handle the fluid-structure and gas-liquid interfaces. Using this framework, we analyze the flow field evolution, bubble dynamics, and transient pipe deformation. Two distinct response modes are identified: periodic oscillation under low-pressure loading and downward collapse triggered by high-pressure loading and bubble jet impact. Specifically, under high-pressure conditions, the pipe initially deforms inward, generating a localized high-pressure zone within the concave region. During structural rebound, the trapped fluid is expelled upward, giving rise to a bubble jet. Further parametric studies on the pipe's internal pressure, wall thickness, and support angle reveal several key insights. A higher internal pressure delays structural collapse, and a greater pipe thickness results in more uniform implosion morphologies. The support angle strongly influences the collapse dynamics, with the shortest collapse time occurring at 60 °. These findings offer new insights for the protective design of submarine pipelines.展开更多
The oceanic mixed layer in the Southern Ocean is characterized by numerous fronts due to the stirring of freshwater influxes arising from ice melting.The interaction of these fronts with winds modulates the evolution ...The oceanic mixed layer in the Southern Ocean is characterized by numerous fronts due to the stirring of freshwater influxes arising from ice melting.The interaction of these fronts with winds modulates the evolution of the mixed layer and affects atmosphere−ocean energy exchanges.However,the underlying mechanism behind the wind-front interaction remains obscure due to a lack of three-dimensional observations of the ocean,particularly in terms of velocities.To address this issue,this study investigates the dynamics of fronts within the mixed layer during a storm by employing a subset of the global submesoscale-permitting simulation,Northeast Weddell Sea Pre-SWOT Level-4 Hourly MITgcm LLC4320 Native Grid 2km Oceanographic Dataset(ROAM_MIZ).We first compare the ROAM_MIZ data to glider data to assess the performance of the model simulation and find that the ROAM_MIZ can,to a large degree,capture sub-mesoscale features within a mixed layer.Subsequent analyses based on a subset of ROAM_MIZ show that lateral density gradients within the mixed layer rapidly decrease during high winds associated with the storm.Down-front winds accelerate this process as the Ekman buoyancy transport responsible for enhancing the instability of the fronts is primarily dominated by horizontal baroclinic components.After the storm,the fronts strengthen again in the presence of weaker winds due to the frontogenesis by the larger-scale strain.Moreover,the non-geostrophic turbulence induces a modification of the relative vorticity,affecting the instability within the mixed layer.These findings offer valuable guidance for the deployment of observational instruments and subsequent analysis,as well as deepen the understanding of air−sea interactions in the Southern Ocean.展开更多
The flow control at low Reynolds numbers is one of the most promising technologies in the field of aerodynamics,and it is also an important source of the innovation for novel aircraft.In this study,a new way of nonlin...The flow control at low Reynolds numbers is one of the most promising technologies in the field of aerodynamics,and it is also an important source of the innovation for novel aircraft.In this study,a new way of nonlinear flow control by interaction between two flexible flaps is proposed,and their flow control mechanism is studied employing the self-constructed immersed boundary-lattice Boltzmann-finite element method(IB-LB-FEM).The effects of the difference in material properties and flap length between the two flexible flaps on the nonlinear flow control of the airfoil are discussed.It is suggested that the relationship between the deformation of the two flexible flaps and the evolution of the vortex under the fluid-structure interaction(FSI).It is shown that the upstream flexible flap plays a key role in the flow control of the two flexible flaps.The FSI effect of the upstream flexible flap will change the unsteady flow behind it and affect the deformation of the downstream flexible flap.Two flexible flaps with different material properties and different lengths will change their own FSI characteristics by the induced vortex,effectively suppressing the flow separation on the airfoil’s upper surface.The interaction of two flexible flaps plays an extremely important role in improving the autonomy and adjustability of flow control.The numerical results will provide a theoretical basis and technical guidance for the development and application of a new flap passive control technology.展开更多
Geochemistry of the fault gouge record information on fault behaviors and environmental conditions.We investigated variations in the mineralogical and geochemical compositions of the fault gouge sampled from the margi...Geochemistry of the fault gouge record information on fault behaviors and environmental conditions.We investigated variations in the mineralogical and geochemical compositions of the fault gouge sampled from the margin zone(MZ)to the slip central zone(CZ)of the fault gouge in the Beichuan-Yingxiu surface rupture zone of the Wenchuan Earthquake.Results show that the clay minerals contents increase from the MZ to CZ,and the quartz and plagioclase contents slight decrease.An increasing enrichment in Al_(2)O_(3),Fe_(2)O_(3),and K_(2)O are observed toward the CZ;the decomposition of quartz and plagioclase,as well as the depletion of Si O_(2),Ca O,Na_2O,and P_(2)O_(5)suggest that the alkaline-earth elements are carried away by the fluids.It can be explained that the stronger coseismic actions in the CZ allow more clay minerals to form,decompose quartz and plagioclase,and alter plagioclase to chlorite.The mass loss in the CZ is larger than that in MZ,which is maybe due to the more concentrated stress in the strongly deformed CZ,however other causes will not be excluded.展开更多
We propose a suite of strategies for the parallel solution of fully implicit monolithic fluid-structure interaction(FSI).The solver is based on a modeling approach that uses the velocity and pressure as the primitive ...We propose a suite of strategies for the parallel solution of fully implicit monolithic fluid-structure interaction(FSI).The solver is based on a modeling approach that uses the velocity and pressure as the primitive variables,which offers a bridge between computational fluid dynamics(CFD)and computational structural dynamics.The spatiotemporal discretization leverages the variational multiscale formulation and the generalized-αmethod as a means of providing a robust discrete scheme.In particular,the time integration scheme does not suffer from the overshoot phenomenon and optimally dissipates high-frequency spurious modes in both subproblems of FSI.Based on the chosen fully implicit scheme,we systematically develop a combined suite of nonlinear and linear solver strategies.Invoking a block factorization of the Jacobian matrix,the Newton-Raphson procedure is reduced to solving two smaller linear systems in the multi-corrector stage.The first is of the elliptic type,indicating that the algebraic multigrid method serves as a well-suited option.The second exhibits a two-by-two block structure that is analogous to the system arising in CFD.Inspired by prior studies,the additive Schwarz domain decomposition method and the block-factorization-based preconditioners are invoked to address the linear problem.Since the number of unknowns matches in both subdomains,it is straightforward to balance loads when parallelizing the algorithm for distributed-memory architectures.We use two representative FSI benchmarks to demonstrate the robustness,efficiency,and scalability of the overall FSI solver framework.In particular,it is found that the developed FSI solver is comparable to the CFD solver in several aspects,including fixed-size and isogranular scalability as well as robustness.展开更多
Lithium metal batteries,with their light mass anode and high theoretical specific capacity of 3860 m Ah/g,have great potential for development in achieving high energy density.However,the generation of lithium dendrit...Lithium metal batteries,with their light mass anode and high theoretical specific capacity of 3860 m Ah/g,have great potential for development in achieving high energy density.However,the generation of lithium dendrites and the loss of dead lithium pose a serious threat to the safety and long-cycle stability of batteries.Herein,we utilize the Lewis acid-base interaction principle for lithium-ion migration regulation.Through loading solid-acids onto molecular sieves to immobilize Lewis base(PF_(6^(-))),we achieve accelerated dissociation of lithium salts and successfully increase the lithium ion transference number to 0.44.Lewis acid-base interaction helps lithium metal batteries achieve more uniform lithium deposition,with an average CE improved to 92.8%.The symmetrical cells can be plated/stripped stably for more than 800 h of cycling.Full cell with high surface-loaded LFP cathode(14 mg/cm^(2))exhibits impressively high capacity retention of 90.7%after 120 cycles at 0.5 C.展开更多
The vapor diffusion and transport resulting from steam generator tube rupture(SGTR)accidents are a major concern threatening lead-based reactor core safety.In this study,a high-parameter SGTR experimental platform and...The vapor diffusion and transport resulting from steam generator tube rupture(SGTR)accidents are a major concern threatening lead-based reactor core safety.In this study,a high-parameter SGTR experimental platform and the multi-phase multi-physics processes numerical simulation were developed to investigate the phase behavior and interaction mechanisms.This study revealed the interaction mechanisms of lead-bismuth liquid metal and water driven by flash vaporization,jet impingement boiling,and moderate boiling.The migration and evolution of the discrete phases(vapor-water mixture)were inferred from the temperature transient laws and a numerical simulation.The results revealed that the evolution of the discrete phases consists of three stages:cavity formation,flanking diffusion,and stable up-floating.The jet pressure significantly extended the disturbance period.Variations in the water temperature mainly affected the depressurization boiling process,altering the diffusion region of the discrete phases.The temperature of the liquid metal and the duration of the jet had a minimal impact on the behavior of the discrete phases.This study provides a crucial reference for constructing a complete picture of accident evolution.展开更多
One effective approach to strike the balance between ionic conductivity and mechanical strength in polymer electrolytes involves the design of a coupled polymer molecular structure comprising both rigid and flexible p...One effective approach to strike the balance between ionic conductivity and mechanical strength in polymer electrolytes involves the design of a coupled polymer molecular structure comprising both rigid and flexible phases.Nevertheless,the regulation of intermolecular interactions between plasticizers and rigid and flexible phases has been largely overlooked.Here,an intermolecular interaction engineering strategy is carried out with well-chosen dual-plasticize within qua si-sol id-state polymer electrolytes(QSPEs).Succinonitrile exhibits a stronger affinity towards rigid phase hydrogenated nitrile butadiene rubber(HNBR),while propene carbonate demonstrates a stronger affinity towards flexible segments poly(propylene carbonate)(PPC).This tailored intermolecular interaction engineering allows for differential plasticization of the polymer's rigid and flexible phases,thereby achieving a balance between ionic conductivity and mechanical strength.The QSPE have both higher ionic conductivity(1.04×10^(-4)S cm^(-1)at 30℃),t_(Li+)(0.55),and tensile strength(0.76 MPa).Li//Li symmetric cells maintaining performance over1100 h at 0.1 mA cm^(-2)and Li//LiFePO_(4)cells retaining 85.0%capacity after 700 cycles at 1.0 C.It is a unique angle to employ intermolecular interaction engineering in QSPEs through dual-plasticizer approach combined with CO_(2)-based polymer materials.This sustainable strategy combining dual-plasticizer engineering with CO_(2)-based polymers,offers insights for designing high-performance,eco-friendly lithium metal batteries.展开更多
Photocatalytic CO_(2)reduction using atomically dispersed catalysts holds significant potential for addressing global energy and environmental challenges.However,the influence of d-d orbital interactions between metal...Photocatalytic CO_(2)reduction using atomically dispersed catalysts holds significant potential for addressing global energy and environmental challenges.However,the influence of d-d orbital interactions between metal centers and coordinated atoms remains under explored.Herein,nickel phthalocyanine is anchored to the metalexposed crystal face of TiO_(2),forming Ti-Ni-N_(4)coordination.This configuration reveals that the axially coordinated Ti atoms serve as a novel electron channel with electron-donating ability,transferring electrons to the Ni center through d-d coupling.It is found that the dynamic adjustment of bond lengths and d-band centers in Ti-Ni bonding during CO_(2)photoreduction process can effectively modulate the adsorption strengths of the Ni center for different intermediates.This leads to a significant enhancement in the photocatalytic performance for CO_(2)reduction to CO without a sacrificial reagent,achieving an exceptional CO evolution rate of 378.5μmol g^(-1).Furthermore,the d-d coupling mediated by Ti-Ni-N_(4)coordination increases the vacancy formation energy of active sites,preventing the leaching of Ni active centers.This study provides a strategy for the precise design of d-d orbital regulation and resistance to demetallization in photocatalysts for efficient CO_(2)conversion.展开更多
This research presents the square root sum of squares response of displacements and tunnel moments under the Kobe and Loma Prieta seismic excitations with a peak ground acceleration of 0.05 g for various dry relative ...This research presents the square root sum of squares response of displacements and tunnel moments under the Kobe and Loma Prieta seismic excitations with a peak ground acceleration of 0.05 g for various dry relative densities of local sand in Bangladesh.For this reason,a one-dimensional gravitational shake table test was performed after calibration to determine the seismic performance of the concrete tunnel-sand-pile interaction model.A vertical 40 kg load was applied on each pile cap along with the seismic excitations.The experimental results obtained were compared with the previous numerical study conducted by using field data so as to better interpret the variations of results.In the case of vertical sand displacement,the ratio between the previous field data obtained through numerical study and the present study is found to be 0.96.Moreover,the experimental results were compared with the 3D full-scale numerical analysis results of Plaxis considering the Mohr-Coulomb constitutive model of sand.Variations of experimental and numerical results show a satisfactory level of alignment with the previously published work.According to the shake table test results,the lateral displacement of the tunnel is greater than the vertical displacement because of the transverse directional seismic excitation on the tunnel body.The minimum difference between lateral and vertical displacements of the tunnel is found to be 31%for a relative density of 27%under the Loma Prieta earthquake.However,this research may be advanced in the future by considering various peak ground accelerations,tunnel-pile clearance,and geometric properties.展开更多
基金supported by the National Natural Science Foundation of China(grant no.22271114)and“111 Center”(grant no.B17020).
文摘Nonprecious transition metal(TM)-based materials have demonstrated tremendous potential as efficient oxygen reduction reaction(ORR)electrocatalysts.However,establishing reliable relationships between geometric/electronic structures and ORR performances remains a great challenge to design and manufacture high-performance ORR catalysts.In this study,we proposed and validated that reducing the symmetry of the coordination structure of TMs enhanced d-πinteractions,thereby strengthening their adsorption for key intermediates.Then we managed the tuning of the metal center’s spin state by substituents,further optimizing the ORR performance.Such advancements were attributed to the orientation differences in d-orbital interactions as a result of asymmetric electronic structure.Based on the understanding of such structure-activity relationships,we designed a covalent organic framework-(COF)based ORR electrocatalyst,which exhibited high activity,rapid kinetic response,and high four-electron transfer selectivity.This work validates an alternative strategy for enhanced ORR through the management of d-πinteractions utilizing asymmetric coordination structures.It inspires the design of TM-based electrocatalysts by providing mechanistic insights into the precise control of the microchemical environments at TM active centers.
基金supported by the National Natural Science Foundation of China(General Program)under Grant 52571385National Key R&D Program of China(Grant No.2024YFC2815000 and No.2024YFB3816000)+12 种基金Open Fund of State Key Laboratory of Deep-sea Manned Vehicles(Grant No.2025SKLDMV07)Shenzhen Science and Technology Program(WDZC20231128114452001,JCYJ20240813112107010 and JCYJ20240813111910014)the Tsinghua SIGS Scientific Research Startup Fund(QD2022021C)the Dreams Foundation of Jianghuai Advance Technology Center(2023-ZM 01 Z006)the Ocean Decade International Cooperation Center(ODCC)(GHZZ3702840002024020000026)Shenzhen Key Laboratory of Advanced Technology for Marine Ecology(ZDSYS20230626091459009)Shenzhen Science and Technology Program(No.KJZD20240903100905008)the National Natural Science Foundation of China(No.22305141)Pearl River Talent Program(No.2023QN10C114)General Program of Guangdong Province(No.2025A1515011700)the Guangdong Innovative and Entrepreneurial Research Team Program(2023ZT10C040)Scientific Research Foundation from Shenzhen Finance Bureau(No.GJHZ20240218113600002)Tsinghua University(JC2023001).
文摘Developing effective,versatile,and high-precision sensing interfaces remains a crucial challenge in human-machine-environment interaction applications.Despite progress in interaction-oriented sensing skins,limitations remain in unit-level reconfiguration,multiaxial force and motion sensing,and robust operation across dynamically changing or irregular surfaces.Herein,we develop a reconfigurable omnidirectional triboelectric whisker sensor array(RO-TWSA)comprising multiple sensing units that integrate a triboelectric whisker structure(TWS)with an untethered hydro-sealing vacuum sucker(UHSVS),enabling reversibly portable deployment and omnidirectional perception across diverse surfaces.Using a simple dual-triangular electrode layout paired with MXene/silicone nanocomposite dielectric layer,the sensor unit achieves precise omnidirectional force and motion sensing with a detection threshold as low as 0.024 N and an angular resolution of 5°,while the UHSVS provides reliable and reversible multi-surface anchoring for the sensor units by involving a newly designed hydrogel combining high mechanical robustness and superior water absorption.Extensive experiments demonstrate the effectiveness of RO-TWSA across various interactive scenarios,including teleoperation,tactile diagnostics,and robotic autonomous exploration.Overall,RO-TWSA presents a versatile and high-resolution tactile interface,offering new avenues for intelligent perception and interaction in complex real-world environments.
基金supported by the National Key R&D Program of China(Grant No.2023YFA1406200)the National Natural Science Foundation of China(No.12274177 and 12304261)the China Postdoctoral Science Foundation(No.2024M751076)。
文摘Luminescent metal-organic frameworks(MOFs)have garnered significant attention due to their structural tunability and potential applications in solid-state lighting,bioimaging,sensing,anticounterfeiting,and other fields.Nevertheless,due to the tendency of1,4-benzenedicarboxylic acid(BDC)to rotate within the framework,MOFs composed of it exhibit significant non-radiative energy dissipation and thus impair the emissive properties.In this study,efficient luminescence of MIL-140A nanocrystals(NCs)with BDC rotors as ligands is achieved by pressure treatment strategy.Pressure treatment effectively modulates the pore structure of the framework,enhancing the interactions between the N,N-dimethylformamide vip molecules and the BDC ligands.The enhanced host-vip interaction contributes to the structural rigidity of the MOF,thereby suppressing the rotation-induced excited-state energy loss.As a result,the pressure-treated MIL-140A NCs displayed bright blue-light emission,with the photoluminescence quantum yield increasing from an initial 6.8%to 69.2%.This study developed an effective strategy to improve the luminescence performance of rotor ligand MOFs,offers a new avenue for the rational design and synthesis of MOFs with superior luminescent properties.
基金supported by the Chongqing Natural Science Foundation of Chongqing,China(No.CSTB2022NSCQ-MSX0333)the Science and Technology Research Program of Chongqing Municipal Education Commission(Grant No.KJZD-K202401205)+1 种基金Chongqing Three Gorges University Graduate Research and Innovation Project Funding(No.YJSKY24045)Chongqing Engineering Research Center of Disaster Prevention&Control for Banks and Structures in Three Gorges Reservoir Area(No.SXAPGC24YB14,No.SXAPGC24YB03,No.SXAPGC24YB12)。
文摘Oil shale is characterized by a dense structure,low proportion of pores and fissures,and low permeability.Pore-fracture systems serve as crucial channels for shale oil migration,directly influencing the production efficiency of shale oil resources.Effectively stimulating oil shale reservoirs remains a challenging and active research topic.This investigation employed shale specimens obtained from the Longmaxi Formation.Scanning electron microscopy,fluid injection experiments,and fluid-structure interaction simulations were used to comprehensively analyze structural changes and fluid flow behavior under high temperatures from microscopic to macroscopic scales.Experimental results indicate that the temperature has little effect on the structure and permeability of shale before 300℃.However,there are two threshold temperatures within the range of 300 to 600℃that have significant effects on the structure and permeability of oil shale.The first threshold temperature is between 300 and 400℃,which causes the oil shale porosity,pore-fracture ratio,and permeability begin to increase.This is manifested by the decrease in micropores and mesopores,the increase in macropores,and the formation of a large number of isolated pores and fissures within the shale.The permeability increases but not significantly.The second threshold temperature is between 500 and 600℃,which increases the permeability of oil shale significantly.During this stage,micropores and mesopores are further reduced,and macropores are significantly enlarged.A large number of connected and penetrated pores and fissures are formed.More numerous and thicker streamlines appear inside the oil shale.The experimental results demonstrate that high temperatures significantly alter the microstructure and permeability of oil shale.At the same time,the experimental results can provide a reference for the research of in-situ heating techniques in oil shale reservoir transformation.
基金supported by the National Key Research and Development Program of China (MOST)(Grant No.2022YFA1402800)the Chinese Academy of Sciences (CAS) Presidents International Fellowship Initiative (PIFI)(Grant No.2025PG0006)+3 种基金the National Natural Science Foundation of China (NSFC)(Grant Nos.51831012,12274437,and 52161160334)the CAS Project for Young Scientists in Basic Research (Grant No.YSBR-084)the CAS Youth Interdisciplinary Teamthe China Postdoctoral Science Foundation (Grant No.2025M773402)。
文摘Based on the Smit-Suhl formula,we propose a universal approach for solving the magnon-magnon coupling problem in bilayer coupled systems(e.g.,antiferromagnets).This method requires only the energy expression,enabling the automatic derivation of analytical expressions for the eigenmatrix elements via symbolic computation,eliminating the need for tedious manual calculations.Using this approach,we investigate the impact of magnetic hysteresis on magnon-magnon coupling in a system with interlayer Dzyaloshinskii-Moriya interaction(DMI).The magnetic hysteresis leads to an asymmetric magnetic field dependence of the resonance frequency and alters the number of degeneracy points between the pure optical and acoustic modes.Moreover,it can result in the coupling strength at the gap of the f–H phase diagram being nearly vanishing,contrary to the conventionally expected maximum.These results deepen the understanding of the effect of interlayer DMI on magnon–magnon coupling and the proposed universal method significantly streamlines the solving process of magnon–magnon coupling problems.
基金supported by the National Natural Science Foundation of China(No.22276219)the foundation for Innovative Research Groups of the National Natural Science Foundation of China(No.52121004)+1 种基金the major program Natural Science Foundation of Hunan Province of China(No.2021JC0001)the Fundamental Research Funds for the Central Universities of Central South University(No.2024ZZTS0063).
文摘Beryllium-containing sludge(BCS)is a typical hazardous waste from Be smelting,which can cause serious harm to ecology and human health by releasing harmful Be if it is stored long-term in environment.Nonetheless,the occurrence of Be in BCS is unclear,which seriously hinders the development of pollution control technologies.In order to enhance the understanding of BCS,the occurrence of Be and the microscale interactions with coexisting phases were investigated for the first time.It was found that CaSO_(4)·2H_(2)O and amorphous SiO_(2) are the primary phases of BCS.The simulated experiments of purified materials showed that Be interacted with CaSO_(4)·2H_(2)O and amorphous SiO_(2).Be can enter into the lattice of CaSO_(4)·2H_(2)O mainly as free Be2+.Amorphous SiO_(2) can adsorb Be2+particularly at a pH range of 3–5.The dissolution behavior experiment of BCS shows that about 52%of the Be is readily extracted under acidic conditions,which refers to the Be of independent occurrence.In contrast,the remaining 48%of Be can be extracted only after the CaSO_(4)·2H_(2)O has completely dissolved.Hence,CaSO_(4)·2H_(2)O is identified as the key occurrence phase which determines the highly efficient dissolution of Be.As a result,this study enhances the understanding of BCS and lays the foundation for the development of Be separation technologies.
基金supported by the National Natural Science Foundation of China(Grant Nos.42150204 and 2288101)supported by the China National Postdoctoral Program for Innovative Talents(BX20230045)the China Postdoctoral Science Foundation(2023M730279)。
文摘A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and development of the NMI model and then emphasize that the NMI model represents a new tool for identifying the basic physics of how climate change influences mid-to-high latitude weather extremes.The building of the NMI model took place over three main periods.In the 1990s,a nonlinear Schr?dinger(NLS)equation model was presented to describe atmospheric blocking as a wave packet;however,it could not depict the lifetime(10-20 days)of atmospheric blocking.In the 2000s,we proposed an NMI model of atmospheric blocking in a uniform basic flow by making a scale-separation assumption and deriving an eddyforced NLS equation.This model succeeded in describing the life cycle of atmospheric blocking.In the 2020s,the NMI model was extended to include the impact of a changing climate mainly by altering the basic zonal winds and the magnitude of the meridional background potential vorticity gradient(PVy).Model results show that when PVy is smaller,blocking has a weaker dispersion and a stronger nonlinearity,so blocking can be more persistent and have a larger zonal scale and weaker eastward movement,thus favoring stronger weather extremes.However,when PVy is much smaller and below a critical threshold under much stronger winter Arctic warming of global warming,atmospheric blocking becomes locally less persistent and shows a much stronger westward movement,which acts to inhibit local cold extremes.Such a case does not happen in summer under global warming because PVy fails to fall below the critical threshold.Thus,our theory indicates that global warming can render summer-blocking anticyclones and mid-to-high latitude heatwaves more persistent,intense,and widespread.
基金supported by the National Natural Science Foundation of China(Grant Nos.52176089 and U23B20110).
文摘This work focuses on the fluid-rigid interaction dynamics in the presence of a magnetic field.A rigid thin rectangular column immersed inside stationary metal liquid vibrates with a fixed small amplitude.The magneto-fluid-solid interaction(MFSI)dynamics issue is studied based on the complex Green’s function method.Considering either the normal or tangential vibration of a column,two types of semi-analytical solutions expressed by stream function integral equations of magnetic corrections,describing the time-displacement history of the column,flow field and electrical potential field of metal fluid and representing transient coupling effects of multi-physics field,are derived,respectively.Nonuniform discretization schemes and an iterative plan are applied to evaluate added damping and inertial loads.The results show that the main factor affecting normal vibration is pressure load,and the main factor affecting tangential vibration is vorticity load.The nonlinear effects of magnetic fields on the dynamics of fluid-rigid thin columns are revealed.The normal vibration exhibits better stability than the tangential vibration under the magnetic field.The induced electrical potential field and current intensity excited by normal vibration are significantly stronger than that of tangential vibration.These semi-analytical solutions can be applied as benchmarks in future validation and verification works for MFSI numerical algorithms for magnetic confinement nuclear fusion science.
基金supported by the National Key Research and Development Program of China(Grant No.2022YFA1602501)the National Natural Science Foundation of China(Grant No.12011530060)+1 种基金supported solely by the Russian Science Foundation(Grant No.22-12-00043)supported by the Chinese Academy of Sciences(CAS)Presidents International Fellowship Initiative(PIFI)(Grant Nos.2018VMB0016 and 2022VMC0002),respectively。
文摘We explored a distinct mechanism for matter creation via electron-positron pair production during bound-bound transitions in the deexcitation of muonic atoms.For ions with nuclear charges Z≥24,transitions from low-lying excited states to the 1s-muon state can lead to the production of electron-positron pairs.We show that the Breit interaction determines the transition probabilities for states with nonzero orbital momentum.We show that the pair production arises mainly from the decay of the 2p states.Thus,the Breit interaction governs electron-positron pair production in bound-bound muon transitions.This process offers a unique opportunity to explore quantum electrodynamics in strong fields,as well as a class of nonradiative transitions involving electron-positron pair production.
基金supported by funds from the National Key Research and Development Program of China(Grant No.2024YFF0807302)National Natural Science Foundation of China(42273043,42173003)the International Visiting Professorship of USTC(2024BVR23).
文摘Jadeitites are formed either through direct precipitation from Na-Al-Si rich fluids(P-type),or by replacement of magmatic protoliths(R-type)in subduction zones.They are valuable targets for investigating the mobility behavior and chemical composition of subduction zone fluids.The Rio San Juan Complex(RSJC)in the northern Dominican Republic hosts both P-and R-type jadeitites and jadeite-rich rocks,which provide ideal samples for addressing such issues.Here,we present trace element and Sr-Nd-O-Si isotope compositions of RSJC jadeitites and related rocks.Most samples show similar REE patterns,trace element distributions and δ^(18)O values to those of plagiogranite protoliths,indicating the predominance of R-type origin in RSJC.The P-type samples exhibit slightly higherδ^(30)Si values(−0.15‰to 0.25‰)than that of R-type samples(−0.20‰to 0.08‰),which place above the igneous array.The low(^(87)Sr/^(86)Sr)_(i)(0.70346 to 0.70505)and highεNd(t)values(4.6 to 6.8)of the P-type jadeitites and quartzites,along with relatively lowδ^(18)O values(4.7‰to 6.4‰)of their forming fluids,indicate that the fluids are likely derived from the altered basaltic crust rather than from oceanic sediment.However,the estimated jadeitite-and quartzite-forming fluids exhibit distinctδ^(30)Si values(0.76‰to 0.99‰and-0.48‰to-0.08‰,respectively),implying an evolution of the fluids that modified the Si isotopic compositions.Since fluid metasomatism and related desilication process could have lowered the whole-rock δ^(30)Si values,the heavy Si isotope compositions of the R-type samples are produced from the external fluids.Combing Rayleigh distillation and binary mixing simulations,we propose that fluids derived from altered oceanic crust obtained high δ^(30)Si values after crystallization of minerals enriched in light Si isotopes.The P-type jadeitites are formed through direct precipitation from this fluid.As the plagiogranite protoliths were continuously replaced by this fluid,the formed R-type samples(jadeitites and quartzites)also exhibit high δ^(30)Si values.Such rocks could significantly alter the Si isotope compositions of local mantle when they are deeply subducted at convergent plate margins.
基金supported by the National Key R&D Program of China(Grant No.2024YFC3013200)the Shenzhen Peacock Plan(Grant No.QD2023006C).
文摘Submarine pipelines are critical infrastructures for offshore energy transport and communications. Understanding their structural response to near-field explosions is crucial for enhancing their blast resistance and operational safety. This study presents a computational study on the interaction between explosion-induced bubbles and a seabed-mounted pipeline. A recently developed computational framework is employed, which couples a compressible fluid solver with a finite element structural solver via a partitioned procedure. An embedded boundary method and a level-set method are employed to handle the fluid-structure and gas-liquid interfaces. Using this framework, we analyze the flow field evolution, bubble dynamics, and transient pipe deformation. Two distinct response modes are identified: periodic oscillation under low-pressure loading and downward collapse triggered by high-pressure loading and bubble jet impact. Specifically, under high-pressure conditions, the pipe initially deforms inward, generating a localized high-pressure zone within the concave region. During structural rebound, the trapped fluid is expelled upward, giving rise to a bubble jet. Further parametric studies on the pipe's internal pressure, wall thickness, and support angle reveal several key insights. A higher internal pressure delays structural collapse, and a greater pipe thickness results in more uniform implosion morphologies. The support angle strongly influences the collapse dynamics, with the shortest collapse time occurring at 60 °. These findings offer new insights for the protective design of submarine pipelines.
基金supported by the National Natural Science Foundation of China (Grant Nos. 42406241,42325604,42227901)the Ministry of Science and Technology of China (No. 2021YFC2803304)+2 种基金the Program of Shanghai Academic/Technology Research Leader (22XD1403600)supported by the Swedish Research Council (Nos. 2020–03190 and 2024-04209)the Swedish Research Council for the Environment, Agricultural Sciences and Spatial Planning (No. 202400375)
文摘The oceanic mixed layer in the Southern Ocean is characterized by numerous fronts due to the stirring of freshwater influxes arising from ice melting.The interaction of these fronts with winds modulates the evolution of the mixed layer and affects atmosphere−ocean energy exchanges.However,the underlying mechanism behind the wind-front interaction remains obscure due to a lack of three-dimensional observations of the ocean,particularly in terms of velocities.To address this issue,this study investigates the dynamics of fronts within the mixed layer during a storm by employing a subset of the global submesoscale-permitting simulation,Northeast Weddell Sea Pre-SWOT Level-4 Hourly MITgcm LLC4320 Native Grid 2km Oceanographic Dataset(ROAM_MIZ).We first compare the ROAM_MIZ data to glider data to assess the performance of the model simulation and find that the ROAM_MIZ can,to a large degree,capture sub-mesoscale features within a mixed layer.Subsequent analyses based on a subset of ROAM_MIZ show that lateral density gradients within the mixed layer rapidly decrease during high winds associated with the storm.Down-front winds accelerate this process as the Ekman buoyancy transport responsible for enhancing the instability of the fronts is primarily dominated by horizontal baroclinic components.After the storm,the fronts strengthen again in the presence of weaker winds due to the frontogenesis by the larger-scale strain.Moreover,the non-geostrophic turbulence induces a modification of the relative vorticity,affecting the instability within the mixed layer.These findings offer valuable guidance for the deployment of observational instruments and subsequent analysis,as well as deepen the understanding of air−sea interactions in the Southern Ocean.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.92371201,52192633,11872293,and 92152301)the Natural Science Basic Research Program of Shaanxi(Grant Nos.2024JC-YBQN-0008,and 2022JC-03)+1 种基金Shaanxi Key Research and Development Program(Grant No.2022ZDLGY02-07)the Joint Natural Science Foundation of China with Guangdong Province for TianHe-II Supercomputer Resources,and the Research Start-up Foundation of Xi’an University of Science and Technology for the High-Level Talent.
文摘The flow control at low Reynolds numbers is one of the most promising technologies in the field of aerodynamics,and it is also an important source of the innovation for novel aircraft.In this study,a new way of nonlinear flow control by interaction between two flexible flaps is proposed,and their flow control mechanism is studied employing the self-constructed immersed boundary-lattice Boltzmann-finite element method(IB-LB-FEM).The effects of the difference in material properties and flap length between the two flexible flaps on the nonlinear flow control of the airfoil are discussed.It is suggested that the relationship between the deformation of the two flexible flaps and the evolution of the vortex under the fluid-structure interaction(FSI).It is shown that the upstream flexible flap plays a key role in the flow control of the two flexible flaps.The FSI effect of the upstream flexible flap will change the unsteady flow behind it and affect the deformation of the downstream flexible flap.Two flexible flaps with different material properties and different lengths will change their own FSI characteristics by the induced vortex,effectively suppressing the flow separation on the airfoil’s upper surface.The interaction of two flexible flaps plays an extremely important role in improving the autonomy and adjustability of flow control.The numerical results will provide a theoretical basis and technical guidance for the development and application of a new flap passive control technology.
基金supported by the research grant from Institute of Crustal Dynamics,China Earthquake Administration(No.ZDJ2019-02)。
文摘Geochemistry of the fault gouge record information on fault behaviors and environmental conditions.We investigated variations in the mineralogical and geochemical compositions of the fault gouge sampled from the margin zone(MZ)to the slip central zone(CZ)of the fault gouge in the Beichuan-Yingxiu surface rupture zone of the Wenchuan Earthquake.Results show that the clay minerals contents increase from the MZ to CZ,and the quartz and plagioclase contents slight decrease.An increasing enrichment in Al_(2)O_(3),Fe_(2)O_(3),and K_(2)O are observed toward the CZ;the decomposition of quartz and plagioclase,as well as the depletion of Si O_(2),Ca O,Na_2O,and P_(2)O_(5)suggest that the alkaline-earth elements are carried away by the fluids.It can be explained that the stronger coseismic actions in the CZ allow more clay minerals to form,decompose quartz and plagioclase,and alter plagioclase to chlorite.The mass loss in the CZ is larger than that in MZ,which is maybe due to the more concentrated stress in the strongly deformed CZ,however other causes will not be excluded.
基金This work was supported by the National Natural Science Foundation of China(Grant No.12172160)Shenzhen Science and Technology Program(Grant No.JCYJ20220818100600002)+1 种基金South-ern University of Science and Technology(Grant No.Y01326127)the Department of Science and Technology of Guangdong Province(Grant Nos.2020B1212030001 and 2021QN020642).
文摘We propose a suite of strategies for the parallel solution of fully implicit monolithic fluid-structure interaction(FSI).The solver is based on a modeling approach that uses the velocity and pressure as the primitive variables,which offers a bridge between computational fluid dynamics(CFD)and computational structural dynamics.The spatiotemporal discretization leverages the variational multiscale formulation and the generalized-αmethod as a means of providing a robust discrete scheme.In particular,the time integration scheme does not suffer from the overshoot phenomenon and optimally dissipates high-frequency spurious modes in both subproblems of FSI.Based on the chosen fully implicit scheme,we systematically develop a combined suite of nonlinear and linear solver strategies.Invoking a block factorization of the Jacobian matrix,the Newton-Raphson procedure is reduced to solving two smaller linear systems in the multi-corrector stage.The first is of the elliptic type,indicating that the algebraic multigrid method serves as a well-suited option.The second exhibits a two-by-two block structure that is analogous to the system arising in CFD.Inspired by prior studies,the additive Schwarz domain decomposition method and the block-factorization-based preconditioners are invoked to address the linear problem.Since the number of unknowns matches in both subdomains,it is straightforward to balance loads when parallelizing the algorithm for distributed-memory architectures.We use two representative FSI benchmarks to demonstrate the robustness,efficiency,and scalability of the overall FSI solver framework.In particular,it is found that the developed FSI solver is comparable to the CFD solver in several aspects,including fixed-size and isogranular scalability as well as robustness.
基金supported by the National Natural Science Foundation of China(No.22179007)。
文摘Lithium metal batteries,with their light mass anode and high theoretical specific capacity of 3860 m Ah/g,have great potential for development in achieving high energy density.However,the generation of lithium dendrites and the loss of dead lithium pose a serious threat to the safety and long-cycle stability of batteries.Herein,we utilize the Lewis acid-base interaction principle for lithium-ion migration regulation.Through loading solid-acids onto molecular sieves to immobilize Lewis base(PF_(6^(-))),we achieve accelerated dissociation of lithium salts and successfully increase the lithium ion transference number to 0.44.Lewis acid-base interaction helps lithium metal batteries achieve more uniform lithium deposition,with an average CE improved to 92.8%.The symmetrical cells can be plated/stripped stably for more than 800 h of cycling.Full cell with high surface-loaded LFP cathode(14 mg/cm^(2))exhibits impressively high capacity retention of 90.7%after 120 cycles at 0.5 C.
基金supported by the National Natural Science Foundation of China(Nos.U20B2011 and 123B2086)。
文摘The vapor diffusion and transport resulting from steam generator tube rupture(SGTR)accidents are a major concern threatening lead-based reactor core safety.In this study,a high-parameter SGTR experimental platform and the multi-phase multi-physics processes numerical simulation were developed to investigate the phase behavior and interaction mechanisms.This study revealed the interaction mechanisms of lead-bismuth liquid metal and water driven by flash vaporization,jet impingement boiling,and moderate boiling.The migration and evolution of the discrete phases(vapor-water mixture)were inferred from the temperature transient laws and a numerical simulation.The results revealed that the evolution of the discrete phases consists of three stages:cavity formation,flanking diffusion,and stable up-floating.The jet pressure significantly extended the disturbance period.Variations in the water temperature mainly affected the depressurization boiling process,altering the diffusion region of the discrete phases.The temperature of the liquid metal and the duration of the jet had a minimal impact on the behavior of the discrete phases.This study provides a crucial reference for constructing a complete picture of accident evolution.
基金supported by the National Key Research and Development Program(2019YFA0705701)National Natural Science Foundation of China(22075329,22008267,21978332 and 22179149)+1 种基金Research and Development Project of Henan Academy Sciences China(232018002)Guangdong Basic and Applied Basic Research Foundation(2021A1515010731)。
文摘One effective approach to strike the balance between ionic conductivity and mechanical strength in polymer electrolytes involves the design of a coupled polymer molecular structure comprising both rigid and flexible phases.Nevertheless,the regulation of intermolecular interactions between plasticizers and rigid and flexible phases has been largely overlooked.Here,an intermolecular interaction engineering strategy is carried out with well-chosen dual-plasticize within qua si-sol id-state polymer electrolytes(QSPEs).Succinonitrile exhibits a stronger affinity towards rigid phase hydrogenated nitrile butadiene rubber(HNBR),while propene carbonate demonstrates a stronger affinity towards flexible segments poly(propylene carbonate)(PPC).This tailored intermolecular interaction engineering allows for differential plasticization of the polymer's rigid and flexible phases,thereby achieving a balance between ionic conductivity and mechanical strength.The QSPE have both higher ionic conductivity(1.04×10^(-4)S cm^(-1)at 30℃),t_(Li+)(0.55),and tensile strength(0.76 MPa).Li//Li symmetric cells maintaining performance over1100 h at 0.1 mA cm^(-2)and Li//LiFePO_(4)cells retaining 85.0%capacity after 700 cycles at 1.0 C.It is a unique angle to employ intermolecular interaction engineering in QSPEs through dual-plasticizer approach combined with CO_(2)-based polymer materials.This sustainable strategy combining dual-plasticizer engineering with CO_(2)-based polymers,offers insights for designing high-performance,eco-friendly lithium metal batteries.
基金financially supported by the National Natural Science Foundation of China(No.22476042)the Natural Science Foundation of Hena.(No.242300421189)
文摘Photocatalytic CO_(2)reduction using atomically dispersed catalysts holds significant potential for addressing global energy and environmental challenges.However,the influence of d-d orbital interactions between metal centers and coordinated atoms remains under explored.Herein,nickel phthalocyanine is anchored to the metalexposed crystal face of TiO_(2),forming Ti-Ni-N_(4)coordination.This configuration reveals that the axially coordinated Ti atoms serve as a novel electron channel with electron-donating ability,transferring electrons to the Ni center through d-d coupling.It is found that the dynamic adjustment of bond lengths and d-band centers in Ti-Ni bonding during CO_(2)photoreduction process can effectively modulate the adsorption strengths of the Ni center for different intermediates.This leads to a significant enhancement in the photocatalytic performance for CO_(2)reduction to CO without a sacrificial reagent,achieving an exceptional CO evolution rate of 378.5μmol g^(-1).Furthermore,the d-d coupling mediated by Ti-Ni-N_(4)coordination increases the vacancy formation energy of active sites,preventing the leaching of Ni active centers.This study provides a strategy for the precise design of d-d orbital regulation and resistance to demetallization in photocatalysts for efficient CO_(2)conversion.
文摘This research presents the square root sum of squares response of displacements and tunnel moments under the Kobe and Loma Prieta seismic excitations with a peak ground acceleration of 0.05 g for various dry relative densities of local sand in Bangladesh.For this reason,a one-dimensional gravitational shake table test was performed after calibration to determine the seismic performance of the concrete tunnel-sand-pile interaction model.A vertical 40 kg load was applied on each pile cap along with the seismic excitations.The experimental results obtained were compared with the previous numerical study conducted by using field data so as to better interpret the variations of results.In the case of vertical sand displacement,the ratio between the previous field data obtained through numerical study and the present study is found to be 0.96.Moreover,the experimental results were compared with the 3D full-scale numerical analysis results of Plaxis considering the Mohr-Coulomb constitutive model of sand.Variations of experimental and numerical results show a satisfactory level of alignment with the previously published work.According to the shake table test results,the lateral displacement of the tunnel is greater than the vertical displacement because of the transverse directional seismic excitation on the tunnel body.The minimum difference between lateral and vertical displacements of the tunnel is found to be 31%for a relative density of 27%under the Loma Prieta earthquake.However,this research may be advanced in the future by considering various peak ground accelerations,tunnel-pile clearance,and geometric properties.
