With the help of the redox mediator, decoupled water-splitting allows O_(2)and H_(2)to be produced at different times, at different rates, and even in different cells, which promotes both the operation safety and the ...With the help of the redox mediator, decoupled water-splitting allows O_(2)and H_(2)to be produced at different times, at different rates, and even in different cells, which promotes both the operation safety and the utilization of renewable power sources. However, the current densities and stabilities of these redox mediators are commonly low, which require further improvements for practical applications. Here, we propose to use supercapacitors as solid state redox mediators for decoupled water splitting. For demonstration, Na_(0.5)MnO_(2)(pseudocapacitor) and active carbon(double layer capacitor), are both used as the redox mediator. These supercapacitors show superior current density(1 A/cm^(2)) and ultralong cycle-life(8000 cycles) compared with commonly investigated battery-based mediators(NiOOH/Ni(OH)_(2)). Our research proves supercapacitors can be used as redox relay with high current density and stability, which may bring new insights in the design of decoupled water splitting systems.展开更多
Six-phase permanent magnet linear synchronous motor(PMLSM)for electromagnetic launch(EML)system presents the characteristics of a high order,nonlinearity,multivariable,strong coupling,and nonperiodic transient operati...Six-phase permanent magnet linear synchronous motor(PMLSM)for electromagnetic launch(EML)system presents the characteristics of a high order,nonlinearity,multivariable,strong coupling,and nonperiodic transient operation in the synchronous rotating coordinate system,posing a great challenge to the dynamic response ability of the current loop.Existing research on current decoupling control(CDC)mainly focuses on cross decoupling within a three-phase system,even though there are neither decoupling methods for multiphase systems nor effective evaluation criteria for the decoupling and dynamic response performances.From this perspective,this paper first presents an equivalent reduced-order complex-matrix dynamic mathematical model of six-phase PMLSM and analyze its transient coupling characteristics during the process of EML.Then,the CDC methods of six-phase PMLSM based on direct compensation and matrix diagonalization principles are realized,respectively,to accomplish the cross decoupling and back electromotive force decoupling within and between different three-phase windings.Finally,an all-round method is proposed,for the first time,to evaluate the decoupling performances and dynamic response performances of different CDC strategies for six-phase PMLSM.Significant superiority of deviation decoupling regulator in decoupling performance and robustness are verified based on high-speed EML experimental platform of six-phase PMLSM.展开更多
基金supported by the Shandong Provincial Natural Science Foundation, China (Nos. 2019GSF109029, ZR2021QB190)funded by the National Natural Science Foundation of China (Nos. 21771118, 21701098, 21875128 and 22109077)+1 种基金the Taishan Scholars Climbing Program of Shandong Province (No. tspd20150201)by the Yantai Double-hundred Talents Project。
文摘With the help of the redox mediator, decoupled water-splitting allows O_(2)and H_(2)to be produced at different times, at different rates, and even in different cells, which promotes both the operation safety and the utilization of renewable power sources. However, the current densities and stabilities of these redox mediators are commonly low, which require further improvements for practical applications. Here, we propose to use supercapacitors as solid state redox mediators for decoupled water splitting. For demonstration, Na_(0.5)MnO_(2)(pseudocapacitor) and active carbon(double layer capacitor), are both used as the redox mediator. These supercapacitors show superior current density(1 A/cm^(2)) and ultralong cycle-life(8000 cycles) compared with commonly investigated battery-based mediators(NiOOH/Ni(OH)_(2)). Our research proves supercapacitors can be used as redox relay with high current density and stability, which may bring new insights in the design of decoupled water splitting systems.
基金This study was supported by the National Natural Science Foundation of China(No.52077219).
文摘Six-phase permanent magnet linear synchronous motor(PMLSM)for electromagnetic launch(EML)system presents the characteristics of a high order,nonlinearity,multivariable,strong coupling,and nonperiodic transient operation in the synchronous rotating coordinate system,posing a great challenge to the dynamic response ability of the current loop.Existing research on current decoupling control(CDC)mainly focuses on cross decoupling within a three-phase system,even though there are neither decoupling methods for multiphase systems nor effective evaluation criteria for the decoupling and dynamic response performances.From this perspective,this paper first presents an equivalent reduced-order complex-matrix dynamic mathematical model of six-phase PMLSM and analyze its transient coupling characteristics during the process of EML.Then,the CDC methods of six-phase PMLSM based on direct compensation and matrix diagonalization principles are realized,respectively,to accomplish the cross decoupling and back electromotive force decoupling within and between different three-phase windings.Finally,an all-round method is proposed,for the first time,to evaluate the decoupling performances and dynamic response performances of different CDC strategies for six-phase PMLSM.Significant superiority of deviation decoupling regulator in decoupling performance and robustness are verified based on high-speed EML experimental platform of six-phase PMLSM.
