The Kagome metal CsV3Sb5 transitions from a weakly correlated state to a strongly correlated state upon Cr substitution;however,the mechanism driving this enhancement remains an open question.Here,we employed a combin...The Kagome metal CsV3Sb5 transitions from a weakly correlated state to a strongly correlated state upon Cr substitution;however,the mechanism driving this enhancement remains an open question.Here,we employed a combination of density functional theory and dynamical mean-field theory(DFT+DMFT)to systematically investigate the evolution of electronic correlations in the CsV_(3−x)Cr_(x)Sb_(5)(x=0,1,and 3)series.Our calculations revealed that Cr doping drives the system into a strongly correlated Hund’s metal phase,which is characterized by significant and orbital-dependent enhancements in the quasiparticle effective masses and electronic scattering rates.We trace the origin of this transition to the doping-induced shift from low-to high-spin atomic configurations.This preference for high-spin states,which is promoted by near-half-filling of the Cr-d orbitals,induces a pronounced orbital blocking effect that strengthens the correlations.Our findings establish that Hund’s coupling is the decisive factor governing the rich correlation physics in the CsV_(3−x)Cr_(x)Sb_(5) family,providing a tunable platform for exploring Hund’s metallicity.展开更多
在高电压-大电流的大功率牵引传动系统中,驱动逆变器受到开关损耗和散热条件等的限制,逆变器的最高工作开关频率通常只有几百赫兹。为了提高逆变器的输出性能,通常在中频段采用同步调制策略。针对同步SVPWM,总结了满足半周期奇对称HWS(h...在高电压-大电流的大功率牵引传动系统中,驱动逆变器受到开关损耗和散热条件等的限制,逆变器的最高工作开关频率通常只有几百赫兹。为了提高逆变器的输出性能,通常在中频段采用同步调制策略。针对同步SVPWM,总结了满足半周期奇对称HWS(half-wave odd symmetry)、1/4周期偶对称QWS(quarter-wave even symmetry)和三相对称3PS(quarter-wave even symmetry)的对称性规律,介绍了其中的同步CSVS的脉冲生成规律及发波方式。通过阻感负载下的仿真和实验,对同步CSVS的电流谐波特性进行分析,得到了电流谐波含量随调制比的变化规律以及电流谐波主要集中次数的分布规律,为同步CSVS的应用提供了一定的参考价值。展开更多
基金supported by the Development Program of China and the National Key Research (Grant Nos.2023YFA1406200 and 2022YFA1402304)the National Natural Science Foundation of China (Grant Nos.12274169 and 12122405)+3 种基金the Fundamental Research Funds for the Central Universitiesthe Innovation Team for Functional Materials and Devices for Informatics at Anhui Higher Education Institutes (Grant No.2024AH010024)the Natural Science Research Project of Education Department of Anhui Province (Grant No.2025AHGXZK31203)the PHD Research Startup Foundation of Fuyang Normal University (Grant No.2025KYQD0072)。
文摘The Kagome metal CsV3Sb5 transitions from a weakly correlated state to a strongly correlated state upon Cr substitution;however,the mechanism driving this enhancement remains an open question.Here,we employed a combination of density functional theory and dynamical mean-field theory(DFT+DMFT)to systematically investigate the evolution of electronic correlations in the CsV_(3−x)Cr_(x)Sb_(5)(x=0,1,and 3)series.Our calculations revealed that Cr doping drives the system into a strongly correlated Hund’s metal phase,which is characterized by significant and orbital-dependent enhancements in the quasiparticle effective masses and electronic scattering rates.We trace the origin of this transition to the doping-induced shift from low-to high-spin atomic configurations.This preference for high-spin states,which is promoted by near-half-filling of the Cr-d orbitals,induces a pronounced orbital blocking effect that strengthens the correlations.Our findings establish that Hund’s coupling is the decisive factor governing the rich correlation physics in the CsV_(3−x)Cr_(x)Sb_(5) family,providing a tunable platform for exploring Hund’s metallicity.
文摘在高电压-大电流的大功率牵引传动系统中,驱动逆变器受到开关损耗和散热条件等的限制,逆变器的最高工作开关频率通常只有几百赫兹。为了提高逆变器的输出性能,通常在中频段采用同步调制策略。针对同步SVPWM,总结了满足半周期奇对称HWS(half-wave odd symmetry)、1/4周期偶对称QWS(quarter-wave even symmetry)和三相对称3PS(quarter-wave even symmetry)的对称性规律,介绍了其中的同步CSVS的脉冲生成规律及发波方式。通过阻感负载下的仿真和实验,对同步CSVS的电流谐波特性进行分析,得到了电流谐波含量随调制比的变化规律以及电流谐波主要集中次数的分布规律,为同步CSVS的应用提供了一定的参考价值。
