A novel series of liquid crystalline copolyesters with T-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4′-bis(4-hydroxyphenylazo)dibenzo-18-crown-6 was prepared via solution condensation polyme...A novel series of liquid crystalline copolyesters with T-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4′-bis(4-hydroxyphenylazo)dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4′-(α,ω-hexanedioyloxy)dibenzoyl dichloride(M_1),2-(4′-ethoxyphenyl)hydroquinone(M_2)and cis-4,4′-bis(4- hydroxyphenylazo)dibenzo-18-crown-6(M_3).The molecular weights of copolyesters are not high,and the intrinsic viscosity [η]of copolyesters ranges from 0.29-0.43.The monomers ...展开更多
A novel series of main chain liquid crystalline copolyesters with X-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 was prepared via solution conde...A novel series of main chain liquid crystalline copolyesters with X-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4＇-（a;arhexanedioyloxy） dibenzoyl dichloride （MI）, 2,5-bis（p-octyloxybenzoyloxy） hydro-quinone （M2） and cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 （M3）. Monomer MI was synthesized by esterification and substitution of adipoyl chloride with p-hydroxybenzoic acid, monomer M2 was synthesized by esterfication and reduction reaction of 2,5-dihydroxybenzoquinone and p-octanoxybenzoyl chloride and monomer M3 was synthesized by diazotization and coupling reaction of cis-diaminodibenzo-18-crown-6 with phenol. The molecular weights of copolyesters are not high, and the intrinsic viscosity [η] of copolyesters ranges from 0.25-0.35. The monomers＇ structures were identified by using elemental analysis, IR, UV, ^1H-NMR, MS, etc. All the copolyesters are yellowish powders and insoluble in THF and CHC13 at room temperature except cPg. The properties of copolyesters were investigated by using GPC, [η] , DSC, TG, WAXD and POM. It was found that all the copolyesters entered into liquid crystal phase when they were heated to above their melting temperature （Tin）. The typical smectic and nematic phase texture can be observed on POM. Their mesophase transition temperature and thermal stability change regularly with varying the content of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 unit in the copolyesters.展开更多
Over the past 50 years,crown asymmetry of forest trees has been evaluated through several indices constructed from the perspective of projected crown shape or displacement but often on an ad hoc basis to address speci...Over the past 50 years,crown asymmetry of forest trees has been evaluated through several indices constructed from the perspective of projected crown shape or displacement but often on an ad hoc basis to address specifi c objectives related to tree growth and competition,stand dynamics,stem form,crown structure and treefall risks.Although sharing some similarities,these indices are largely incoherent and non-comparable as they diff er not only in the scale but also in the direction of their values in indicating the degree of crown asymmetry.As the fi rst attempt at devising normative measures of crown asymmetry,we adopted a relative scale between 0 for perfect symmetry and 1 for extreme asymmetry.Five existing crown asymmetry indices(CAIs)were brought onto this relative scale after necessary modifi cations.Eight new CAIs were adapted from measures of circularity for digital images in computer graphics,indices of income inequality in economics,and a bilateral symmetry indicator in plant leaf morphology.The performances of the 13 CAIs were compared over diff erent numbers of measured crown radii for 30 projected crowns of mature Eucalyptus pilularis trees through benchmarking statistics and rank order correlation analysis.For each CAI,the index value based on the full measurement of 36 evenly spaced radii of a projected crown was taken as the true value in the benchmarking process.The index(CAI 13)adapted from the simple bilateral symmetry measure proved to be the least biased and most precise.Its performance was closely followed by that of three other CAIs.The minimum number of crown radii that is needed to provide at least an indicative measure of crown asymmetry is four.For more accurate and consistent measures,at least 6 or 8 crown radii are needed.The range of variability in crown morphology of the trees under investigation also needs to be taken into consideration.Although the CAIs are from projected crown radii,they can be readily extended to individual tree crown metrics that are now commonly extracted from LiDAR and other remotely sensed data.Adding a normative measure of crown asymmetry to individual tree crown metrics will facilitate the process of big data analytics and artifi cial intelligence in forestry wherever crown morphology is among the factors to be considered for decision making in forest management.展开更多
There are very few researches on the shape standard curve currently,and they merely remain on the level of description of the general concept and production experiences,lacking of the in-depth theoretical analysis,and...There are very few researches on the shape standard curve currently,and they merely remain on the level of description of the general concept and production experiences,lacking of the in-depth theoretical analysis,and the concrete principle,method and steps for determining the shape standard curve are not put forward,therefore,they are not applicable in industrial production.This is the weakest spot in the research on the basic shape theory.In this paper,the basic shape standard curve and the transverse distribution curve of the exit thickness are attained with stepwise optimization,which is based on the theoretical calculation method of the shape standard curve of strip mills proposed by authors.By calculating the shape discrimination model and the shape forecast model separately,the simultaneous iterative calculation by the previous method is avoided,and the speed and stability of calculation are improved.The compensation models of the transverse temperature difference of the strip,the shape detection roller deflection and the shape of the strip coil are established,respectively,meantime,the basic shape standard curves are compensated,and the relatively perfect theoretical establishment method of the shape standard curve is formed.The simulation and calculation are done on a 1 220 mm five-stand cold strip tandem mill.The simulation and calculation result shows that the principle,method and steps for determining the shape standard curve are correct and feasible,and the correctness of theoretical analysis and calculation is verified.This paper proposes an idea and a method for the establishment of the shape standard curve in the rolling processes of cold strip mills,which develop the theory and model of the shape standard curve and improve the quality and efficiency of the shape control in the rolling processes of cold strip mills.展开更多
The strip flatness and crown control model is the foundation of automatic strip shape control. Considering the metal transverse flows and the inter stand second deformation, the trip flatness and crown control model h...The strip flatness and crown control model is the foundation of automatic strip shape control. Considering the metal transverse flows and the inter stand second deformation, the trip flatness and crown control model has been developed, which can be applied to CVC mills and PC mills as well as normal four-high mills. The strip flatness and crown control model has high precision, and has been successfully applied to the automatic strip shape control system reconstruction of Tangshan Ganglu 1 250 mm hot strip plant.展开更多
The computation model of shape and crown on 4-high CVC mill was established by combining the stream surface strip element method for analyzing three-dimensional plastic deformation of strip and the influence coefficie...The computation model of shape and crown on 4-high CVC mill was established by combining the stream surface strip element method for analyzing three-dimensional plastic deformation of strip and the influence coefficient method for elastic deformation of rolls, and the simulation of the shape and crown control on 4-high CVC hot strip mill was conducted. The simulated results indicate that the influence of the shifting of CVC work roll on shape and crown is very large, and the shifting of work roll can be used to preset shape and crown. The influence of the bending force of work roll on shape and crown is smaller, and it is suitable to use the bending force of work roll for shape and crown adjustment on line. With the increase of strip width, the exit crown of strip increases firstly and decreases then, and the roll gap becomes smoother increasingly. Meanwhile, the transverse difference of front tension stress decreases firstly and increases then.展开更多
AGC system can improve the plate gauge precision,and damage the plate shape if the shape control loop is left quite open.This damage will cause wave during rolling wide-thin plate.A control strategy named shape lock-o...AGC system can improve the plate gauge precision,and damage the plate shape if the shape control loop is left quite open.This damage will cause wave during rolling wide-thin plate.A control strategy named shape lock-on method is afforded for plate shape control.This method requires APC instead of AGC at last one or two passes during rolling wide-thin plate.Approved by theory and on-line application,this method is good for the plate shape and crown control with small effect on gauge control.展开更多
Crown feedback control is one part of the automatic shape control （ASC） system. On the basis of large simulation researches conducted, a linear crown feedback control model was put forward and applied in actual stri...Crown feedback control is one part of the automatic shape control （ASC） system. On the basis of large simulation researches conducted, a linear crown feedback control model was put forward and applied in actual strip rolling. According to its successful op- eration in the ASP 1700 hot strip mill of Angang Group for one year and also from the statistical results of several crown measurements, it can be definitely said that this control model is highly effective and shows stable performance. The control effectiveness of different gauges of strips with the feedback control is found to increase by 10%-30% compared with that without feedback control.展开更多
The elasticity deformation of rolls was analyzed by means of two-dimensional finite element method （FEM） with variable thickness. Three typical mills were used as objects for analysis. A thorough study was done on t...The elasticity deformation of rolls was analyzed by means of two-dimensional finite element method （FEM） with variable thickness. Three typical mills were used as objects for analysis. A thorough study was done on the control capabilities of these mills on the strip shape. Then the strip shape control capabilities of the three mills was compared synthetically. 2008 University of Science and Technology Beijing. All rights reserved.展开更多
基金This work was supported by the National Natural Science Foundation of China(No.29974026)the Natural Science Foundation of Henan Province(No.0211021100)the Education Department Foundation of Henan Province(No.20021500004).
文摘A novel series of liquid crystalline copolyesters with T-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4′-bis(4-hydroxyphenylazo)dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4′-(α,ω-hexanedioyloxy)dibenzoyl dichloride(M_1),2-(4′-ethoxyphenyl)hydroquinone(M_2)and cis-4,4′-bis(4- hydroxyphenylazo)dibenzo-18-crown-6(M_3).The molecular weights of copolyesters are not high,and the intrinsic viscosity [η]of copolyesters ranges from 0.29-0.43.The monomers ...
基金This work was supported by the National Natural Science Foundation of China(No.29974026)the Natural Science Foundation of Henan Province.
文摘A novel series of main chain liquid crystalline copolyesters with X-shaped two-dimensional mesogenic unit and crown ether cycle of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 was prepared via solution condensation polymerization from 4,4＇-（a;arhexanedioyloxy） dibenzoyl dichloride （MI）, 2,5-bis（p-octyloxybenzoyloxy） hydro-quinone （M2） and cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 （M3）. Monomer MI was synthesized by esterification and substitution of adipoyl chloride with p-hydroxybenzoic acid, monomer M2 was synthesized by esterfication and reduction reaction of 2,5-dihydroxybenzoquinone and p-octanoxybenzoyl chloride and monomer M3 was synthesized by diazotization and coupling reaction of cis-diaminodibenzo-18-crown-6 with phenol. The molecular weights of copolyesters are not high, and the intrinsic viscosity [η] of copolyesters ranges from 0.25-0.35. The monomers＇ structures were identified by using elemental analysis, IR, UV, ^1H-NMR, MS, etc. All the copolyesters are yellowish powders and insoluble in THF and CHC13 at room temperature except cPg. The properties of copolyesters were investigated by using GPC, [η] , DSC, TG, WAXD and POM. It was found that all the copolyesters entered into liquid crystal phase when they were heated to above their melting temperature （Tin）. The typical smectic and nematic phase texture can be observed on POM. Their mesophase transition temperature and thermal stability change regularly with varying the content of cis-4,4＇-bis（4-hydroxyphenylazo） dibenzo-18-crown-6 unit in the copolyesters.
基金the Heilongjiang Touyan Innovation Team 747 Program(Technology Development Team for High-effi cient Silviculture of Forest Resources).
文摘Over the past 50 years,crown asymmetry of forest trees has been evaluated through several indices constructed from the perspective of projected crown shape or displacement but often on an ad hoc basis to address specifi c objectives related to tree growth and competition,stand dynamics,stem form,crown structure and treefall risks.Although sharing some similarities,these indices are largely incoherent and non-comparable as they diff er not only in the scale but also in the direction of their values in indicating the degree of crown asymmetry.As the fi rst attempt at devising normative measures of crown asymmetry,we adopted a relative scale between 0 for perfect symmetry and 1 for extreme asymmetry.Five existing crown asymmetry indices(CAIs)were brought onto this relative scale after necessary modifi cations.Eight new CAIs were adapted from measures of circularity for digital images in computer graphics,indices of income inequality in economics,and a bilateral symmetry indicator in plant leaf morphology.The performances of the 13 CAIs were compared over diff erent numbers of measured crown radii for 30 projected crowns of mature Eucalyptus pilularis trees through benchmarking statistics and rank order correlation analysis.For each CAI,the index value based on the full measurement of 36 evenly spaced radii of a projected crown was taken as the true value in the benchmarking process.The index(CAI 13)adapted from the simple bilateral symmetry measure proved to be the least biased and most precise.Its performance was closely followed by that of three other CAIs.The minimum number of crown radii that is needed to provide at least an indicative measure of crown asymmetry is four.For more accurate and consistent measures,at least 6 or 8 crown radii are needed.The range of variability in crown morphology of the trees under investigation also needs to be taken into consideration.Although the CAIs are from projected crown radii,they can be readily extended to individual tree crown metrics that are now commonly extracted from LiDAR and other remotely sensed data.Adding a normative measure of crown asymmetry to individual tree crown metrics will facilitate the process of big data analytics and artifi cial intelligence in forestry wherever crown morphology is among the factors to be considered for decision making in forest management.
基金supported by National Hi-tech Research and Development Program of China(863Program,Grant No.2009AA04Z143)National Science and Technology Support Plan of China(Grant No.2007BAF02B10)Hebei Provincial Great Natural Science Foundation of China(Grant No.E2006001038)
文摘There are very few researches on the shape standard curve currently,and they merely remain on the level of description of the general concept and production experiences,lacking of the in-depth theoretical analysis,and the concrete principle,method and steps for determining the shape standard curve are not put forward,therefore,they are not applicable in industrial production.This is the weakest spot in the research on the basic shape theory.In this paper,the basic shape standard curve and the transverse distribution curve of the exit thickness are attained with stepwise optimization,which is based on the theoretical calculation method of the shape standard curve of strip mills proposed by authors.By calculating the shape discrimination model and the shape forecast model separately,the simultaneous iterative calculation by the previous method is avoided,and the speed and stability of calculation are improved.The compensation models of the transverse temperature difference of the strip,the shape detection roller deflection and the shape of the strip coil are established,respectively,meantime,the basic shape standard curves are compensated,and the relatively perfect theoretical establishment method of the shape standard curve is formed.The simulation and calculation are done on a 1 220 mm five-stand cold strip tandem mill.The simulation and calculation result shows that the principle,method and steps for determining the shape standard curve are correct and feasible,and the correctness of theoretical analysis and calculation is verified.This paper proposes an idea and a method for the establishment of the shape standard curve in the rolling processes of cold strip mills,which develop the theory and model of the shape standard curve and improve the quality and efficiency of the shape control in the rolling processes of cold strip mills.
基金Item Sponsored by National Natural Science Foundation of China (50534020)
文摘The strip flatness and crown control model is the foundation of automatic strip shape control. Considering the metal transverse flows and the inter stand second deformation, the trip flatness and crown control model has been developed, which can be applied to CVC mills and PC mills as well as normal four-high mills. The strip flatness and crown control model has high precision, and has been successfully applied to the automatic strip shape control system reconstruction of Tangshan Ganglu 1 250 mm hot strip plant.
文摘The computation model of shape and crown on 4-high CVC mill was established by combining the stream surface strip element method for analyzing three-dimensional plastic deformation of strip and the influence coefficient method for elastic deformation of rolls, and the simulation of the shape and crown control on 4-high CVC hot strip mill was conducted. The simulated results indicate that the influence of the shifting of CVC work roll on shape and crown is very large, and the shifting of work roll can be used to preset shape and crown. The influence of the bending force of work roll on shape and crown is smaller, and it is suitable to use the bending force of work roll for shape and crown adjustment on line. With the increase of strip width, the exit crown of strip increases firstly and decreases then, and the roll gap becomes smoother increasingly. Meanwhile, the transverse difference of front tension stress decreases firstly and increases then.
基金Item Sponsored by National Natural Science Foundation of China(50104004)
文摘AGC system can improve the plate gauge precision,and damage the plate shape if the shape control loop is left quite open.This damage will cause wave during rolling wide-thin plate.A control strategy named shape lock-on method is afforded for plate shape control.This method requires APC instead of AGC at last one or two passes during rolling wide-thin plate.Approved by theory and on-line application,this method is good for the plate shape and crown control with small effect on gauge control.
文摘Crown feedback control is one part of the automatic shape control （ASC） system. On the basis of large simulation researches conducted, a linear crown feedback control model was put forward and applied in actual strip rolling. According to its successful op- eration in the ASP 1700 hot strip mill of Angang Group for one year and also from the statistical results of several crown measurements, it can be definitely said that this control model is highly effective and shows stable performance. The control effectiveness of different gauges of strips with the feedback control is found to increase by 10%-30% compared with that without feedback control.
文摘The elasticity deformation of rolls was analyzed by means of two-dimensional finite element method （FEM） with variable thickness. Three typical mills were used as objects for analysis. A thorough study was done on the control capabilities of these mills on the strip shape. Then the strip shape control capabilities of the three mills was compared synthetically. 2008 University of Science and Technology Beijing. All rights reserved.
