Accurate crown control is paramount for ensuring the quality of hot-rolled strip products.Given the multitude of influencing parameters and the intricate coupling and genetic relationships among them,the conventional ...Accurate crown control is paramount for ensuring the quality of hot-rolled strip products.Given the multitude of influencing parameters and the intricate coupling and genetic relationships among them,the conventional crown control method is no longer sufficient to meet the precision requirements of schedule-free rolling.To address this limitation,an optimization framework for hot-rolled strip crown control was developed based on model-driven digital twin(MDDT).This framework enhances the strip crown control precision by facilitating collaborative operations among physical entities,virtual models,and functional application layers.In virtual modeling,a data-driven approach that integrates the extreme gradient boosting and the improved Harris hawk optimization algorithm was firstly proposed to fit the relationship between key process parameters and strip crown,and a global-local collaborative training strategy was proposed to enhance the model adaptability to diverse working conditions.Subsequently,the influence of crucial process factors on the virtual model was examined through model responses.Furthermore,a novel optimization mode for crown control based on MDDT was established by aligning and reconstructing both the physical and virtual models,thereby enhancing the crown control precision.Finally,data trials were conducted to validate the effectiveness of the proposed framework.The results indicated that the proposed method exhibited satisfactory performance and could be effectively utilized to improve the crown control precision.展开更多
Eucalyptus forests are grown in many parts of the world for their commercial value and use in construction projects. Density management becomes im- portant as a means to attain the management goals in these forests. C...Eucalyptus forests are grown in many parts of the world for their commercial value and use in construction projects. Density management becomes im- portant as a means to attain the management goals in these forests. Changes in canopy and tree crown structure were quantified for Eucalyptus urophylla x E. grandis forests at different ages to determine when canopy closure occurs and the onset of competition begins. Site index was developed for these forests to determine whether site quality affects the canopy structure. Site index had little effect in the forests sampled, with the forest canopy on the better sites becoming slightly more elongated. Based upon crown projection ratio and crown diameter： dbh （diameter at breast height） ratio, it appears that crown closure occurs by age 4 years in these forests. The age at which this occurs was also checked and verified with the evaluation of relative spacing, RS （the ratio of the mean distance between trees to the average dominant height of the stand）. The RS value displayed a rapid decline until age 4 years, and then became relatively flat through age 21 years. The rapid height growth during the first 3 years with no change in density accounted for this rapid decrease. By age 4 years, reductions in the number of trees due to mortality began to have more of an influence on this value, resulting in a more gradual de- cline. The implications for management are discussed.展开更多
The authors regret that the declaration of Acknowledgement as below is missing in the paper:AcknowledgementWe are grateful to the Department of Biology and Postgraduate Sciences-Biology of the Universidad del Valle,Ca...The authors regret that the declaration of Acknowledgement as below is missing in the paper:AcknowledgementWe are grateful to the Department of Biology and Postgraduate Sciences-Biology of the Universidad del Valle,Cali-Colombia for their support of the project;to Wilmar Torres MSc.for his statistical advice;to the biologist Helen Burnham MSc.for the translation of the document;to Isabel Castro and all the members of the Ornithology and Animal Behaviour Laboratory-OYCA of Universidad del Valle for their invaluable support in the field.We sincerely thank the anonymous re-viewers for their invaluable feedback and contributions to our manuscript.展开更多
The separation of lithium isotopes (^(6)Li and ^(7)Li) is of great importance for the nuclear industry.The lithium amalgam method is the only lithium isotopes separation process in industry,and the extensive use of me...The separation of lithium isotopes (^(6)Li and ^(7)Li) is of great importance for the nuclear industry.The lithium amalgam method is the only lithium isotopes separation process in industry,and the extensive use of mercury has raised concerns about its potential environmental hazards,which have prompted the search for more efficient and environmentally friendly alternatives.Crown ethers can bind lithium ions highly selectively and separate lithium isotopes effectively.A chemical exchange-based lithium isotopes separation method using crown ether decorated materials could be a viable and cost-effective alternative to the lithium amalgam method.In this review,we provide a systematic summary of the recent advances in lithium isotopes separation using crown ethers decorated materials.展开更多
In this study,we used an extensive sampling network established in central Romania to develop tree height and crown length models.Our analysis included more than 18,000 tree measurements from five different species.In...In this study,we used an extensive sampling network established in central Romania to develop tree height and crown length models.Our analysis included more than 18,000 tree measurements from five different species.Instead of building univariate models for each response variable,we employed a multivariate approach using seemingly unrelated mixed-effects models.These models incorporated variables related to species mixture,tree and stand size,competition,and stand structure.With the inclusion of additional variables in the multivariate seemingly unrelated mixed-effects models,the accuracy of the height prediction models improved by over 10% for all species,whereas the improvement in the crown length models was considerably smaller.Our findings indicate that trees in mixed stands tend to have shorter heights but longer crowns than those in pure stands.We also observed that trees in homogeneous stand structures have shorter crown lengths than those in heterogeneous stands.By employing a multivariate mixed-effects modelling framework,we were able to perform cross-model random-effect predictions,leading to a significant increase in accuracy when both responses were used to calibrate the model.In contrast,the improvement in accuracy was marginal when only height was used for calibration.We demonstrate how multivariate mixed-effects models can be effectively used to develop multi-response allometric models that can be easily calibrated with a limited number of observations while simultaneously achieving better-aligned projections.展开更多
CdSe nanoplatelets(NPLs)are promising candidates for on-chip light sources,yet their performance is hindered by surface defects and inefficient optical gain.Herein,we demonstrate that CdSeS crown passivation significa...CdSe nanoplatelets(NPLs)are promising candidates for on-chip light sources,yet their performance is hindered by surface defects and inefficient optical gain.Herein,we demonstrate that CdSeS crown passivation significantly enhances the photophysical property of CdSe NPLs.Laser spectroscopy techniques reveal suppressed electronic and hole trapping at lateral surfaces,leading to a 4.2-fold increase in photoluminescence quantum yield and a shortened emission lifetime from13.5 to 4.8 ns.In addition,amplified spontaneous emission is achieved under nanosecond pulse pumping,with thresholds of0.75 to 0.16 mJ/cm^(2)for CdSe and CdSe/CdSeS NPLs,respectively.By integrating CdSe/CdSeS NPLs with high-refractiveindex SiO2scatters,coherent random lasing is realized at a threshold of 0.21 mJ/cm^(2).These findings highlight the critical role of lateral surface passivation in optimizing optical gain and pave the way for low-cost,multifunctional nanophotonic devices.展开更多
This paper introduces a new method of calculating crown projection area(CPA),the area of level ground covered by a vertical projection of a tree crown from measured crown radii through numerical interpolation and inte...This paper introduces a new method of calculating crown projection area(CPA),the area of level ground covered by a vertical projection of a tree crown from measured crown radii through numerical interpolation and integration.This novel method and other four existing methods of calculating CPA were compared using detailed crown radius measurements from 30 tall trees of Eucalyptus pilularis variable in crown size,shape,and asymmetry.The four existing methods included the polygonal approach and three ways of calculating CPA as the area of a circle using the arithmetic,geometric and quadratic mean radius.Comparisons were made across a sequence of eight non-consecutive numbers(from 2 to 16)of measured crown radii for each tree over the range of crown asymmetry of the 30 trees through generalized linear models and multiple comparisons of means.The sequence covered the range of the number of crown radii measured for calculating the CPA of a tree in the literature.A crown asymmetry index within the unit interval was calculated for each tree to serve as a normative measure.With a slight overestimation of 2.2%on average and an overall mean error size of 7.9%across the numbers of crown radii that were compared,our new method was the least biased and most accurate.Calculating CPA as a circle using the quadratic mean crown radius was the second best,which had an average overestimation of 4.5%and overall mean error size of 8.8%.These two methods remained by and large unbiased as crown asymmetry increased,while the other three methods showed larger bias of underestimation.For the conventional method of using the arithmetic mean crown radius to calculate CPA as a circle,bias correction factors were developed as a function of crown asymmetry index to delineate the increasing magnitude of bias associated with greater degrees of crown asymmetry.This study reveals and demonstrates such relationships between the accuracy of CPA calculations and crown asymmetry and will help increase awareness among researchers and practitioners on the existence of bias in their CPA calculations and for the need to use an unbiased method in the future.Our new method is recommended for calculating CPA where at least four crown radius measurements per tree are available because that is the minimum number required for its use.展开更多
The cross-linking of crown ether-SE-54 in fused-silica capillary columns were initiated by dicumyl peroxide(DCUP),azo-bis-isobutyronitrile (AIBN)and ozone(O_3).Parameters of evaluation such as polarity,selectivity, ph...The cross-linking of crown ether-SE-54 in fused-silica capillary columns were initiated by dicumyl peroxide(DCUP),azo-bis-isobutyronitrile (AIBN)and ozone(O_3).Parameters of evaluation such as polarity,selectivity, phase transition temperature and thermal stability were studied and compared with those of poly(crown ether)stationary phase.展开更多
In modeling forest stand growth and yield,crown width,a measure for stand density,is among the parameters that allows for estimating stand timber volumes.However,accurately measuring tree crown size in the field,in pa...In modeling forest stand growth and yield,crown width,a measure for stand density,is among the parameters that allows for estimating stand timber volumes.However,accurately measuring tree crown size in the field,in particular for mature trees,is challenging.This study demonstrated a novel method of applying machine learning algorithms to aerial imagery acquired by an unmanned aerial vehicle(UAV)to identify tree crowns and their widths in two loblolly pine plantations in eastern Texas,USA.An ortho mosaic image derived from UAV-captured aerial photos was acquired for each plantation(a young stand before canopy closure,a mature stand with a closed canopy).For each site,the images were split into two subsets:one for training and one for validation purposes.Three widely used object detection methods in deep learning,the Faster region-based convolutional neural network(Faster R-CNN),You Only Look Once version 3(YOLOv3),and single shot detection(SSD),were applied to the training data,respectively.Each was used to train the model for performing crown recognition and crown extraction.Each model output was evaluated using an independent test data set.All three models were successful in detecting tree crowns with an accuracy greater than 93%,except the Faster R-CNN model that failed on the mature site.On the young site,the SSD model performed the best for crown extraction with a coefficient of determination(R^(2))of 0.92,followed by Faster R-CNN(0.88)and YOLOv3(0.62).As to the mature site,the SSD model achieved a R^(2)as high as 0.94,follow by YOLOv3(0.69).These deep leaning algorithms,in particular the SSD model,proved to be successfully in identifying tree crowns and estimating crown widths with satisfactory accuracy.For the purpose of forest inventory on loblolly pine plantations,using UAV-captured imagery paired with the SSD object detention application is a cost-effective alternative to traditional ground measurement.展开更多
A novel Pd(II) Benzo-15-crown-5 complex [Na(B15CS)]_2[Pd(SCN)_4] has been isolated and characterized by IR and X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P2_1,/n with cell dim...A novel Pd(II) Benzo-15-crown-5 complex [Na(B15CS)]_2[Pd(SCN)_4] has been isolated and characterized by IR and X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P2_1,/n with cell dimensions, a = l.0164(6), b = l.3743(3), c = l.4987(7) nm, β = 95.248(6) °, V = 2.0847 'nm_3, Z = 2, F(000) = 944, R = 0.053, Rw = 0.072. The compound consists of two [Na(B15CS)]+ complex canons and a [Pd(SCN)4_]^(2-) complex anion. Each sodium ion is coordinated by five crown ether oxygen atoms and one N atom from the SCN group of [Pd(SCN)_4]^(2-) to form stable neutral complex.展开更多
3,3′-Dimethyl-dibenzo-18-crown-6 was synthesized and characterized by elemental analysis, FT-IR, ^1H NMR, UV, MS spectra and X-ray single-crystal diffraction. It belongs to orthorhombic, space group Pna21 with a = 8....3,3′-Dimethyl-dibenzo-18-crown-6 was synthesized and characterized by elemental analysis, FT-IR, ^1H NMR, UV, MS spectra and X-ray single-crystal diffraction. It belongs to orthorhombic, space group Pna21 with a = 8.0790（18）, b = 16.780（4）, c = 15.222（3） .A, Z= 4, V= 2063.6（8） A3 Dc = 1.250 g/cm^3,μ = 0.090 mm^-1, F（000） = 832, R = 0.0474 and wR = 0.1103. According to structural analysis, the title compound possesses a boat-like configuration.展开更多
Objective] The study was aimed to improve the yield and quality of cashew. [Method] Through the comparative analysis, the survival rate, new germi-nation and yield characteristics of the cutting stems with different h...Objective] The study was aimed to improve the yield and quality of cashew. [Method] Through the comparative analysis, the survival rate, new germi-nation and yield characteristics of the cutting stems with different heights by stem grafting and bark grafting. [Result] The best cutting stem height of cashew should be in 100-150 cm, when the number of new germinated shoots was 85.5-87.7. Stem grafting could significantly improve the survival rate of the shooting branch （92.7%）, growth condition of which was better than that of bark grafting, and it also had no clip cortex. The yield of stem grafting was significantly higher than that of bark grafting, and it could reach up to 18.1 kg/plant in 4 years. The branches from stem grafting had significantly better ability in resisting the wind damage than those from bark grafting. [Conclusion] The study provided references for the crown grafting of cashew planting in China.展开更多
The program of the plate crown optimal prediction applied in the plate mill of Wuhan Iron and Steel(Group) Co. Ltd. is described. Optimal prediction is programmed in ALPHA 4000. The original profile, wear, expansion ...The program of the plate crown optimal prediction applied in the plate mill of Wuhan Iron and Steel(Group) Co. Ltd. is described. Optimal prediction is programmed in ALPHA 4000. The original profile, wear, expansion and deformation of work rolls are introduced into the program. The plate crown is controlled by the original profile of work rolls and the draft whose objective is the optimal plate crown. The run schedule is also optimized through the optimal prediction of the plate crown.展开更多
A flexible and adaptable design method for the tooth crown is presented based on the direct manipulation of free-form deformation （FFD）. The correct shape of the tooth crown can be obtained by adding, modifying, and...A flexible and adaptable design method for the tooth crown is presented based on the direct manipulation of free-form deformation （FFD）. The correct shape of the tooth crown can be obtained by adding, modifying, and deleting constraint points or load points based on stretching and compressing operation. Finally, an example is given to illustrate the method to be efficient.展开更多
Network crewn ether polymer with pendant sulfide side ohain in the networkstructure units has been synthesized via ring- opening copolymerization of β-ethylthioethyl glycidyl ether and diethylene glycol bisglycidyl e...Network crewn ether polymer with pendant sulfide side ohain in the networkstructure units has been synthesized via ring- opening copolymerization of β-ethylthioethyl glycidyl ether and diethylene glycol bisglycidyl ether. A kind of active catalyst suitable for this reaction was suggested. The title polymer was found tobe a good ligand for platinous chloride, and the platinous complex could catalyze thehydrosilylation of olefins with triethoxysilane efficiently.展开更多
基金financially supported by the National Key Research and Development Program of China(Grant No.2023YFB3710204)Guangxi Science and Technology Major Program(Grant No.AA23023028-1)+1 种基金Natural Science Foundation of Heilongjiang Province of China for Distinguished Young Scientists(Grant No.JQ2022E007)Xinjiang Production and Construction Corps Science and Technology Plan(Grant No.2023AA003).
文摘Accurate crown control is paramount for ensuring the quality of hot-rolled strip products.Given the multitude of influencing parameters and the intricate coupling and genetic relationships among them,the conventional crown control method is no longer sufficient to meet the precision requirements of schedule-free rolling.To address this limitation,an optimization framework for hot-rolled strip crown control was developed based on model-driven digital twin(MDDT).This framework enhances the strip crown control precision by facilitating collaborative operations among physical entities,virtual models,and functional application layers.In virtual modeling,a data-driven approach that integrates the extreme gradient boosting and the improved Harris hawk optimization algorithm was firstly proposed to fit the relationship between key process parameters and strip crown,and a global-local collaborative training strategy was proposed to enhance the model adaptability to diverse working conditions.Subsequently,the influence of crucial process factors on the virtual model was examined through model responses.Furthermore,a novel optimization mode for crown control based on MDDT was established by aligning and reconstructing both the physical and virtual models,thereby enhancing the crown control precision.Finally,data trials were conducted to validate the effectiveness of the proposed framework.The results indicated that the proposed method exhibited satisfactory performance and could be effectively utilized to improve the crown control precision.
基金Supported by Undergraduate Research Abroad Program,Ohio State University,USA(11731-011000)~~
文摘Eucalyptus forests are grown in many parts of the world for their commercial value and use in construction projects. Density management becomes im- portant as a means to attain the management goals in these forests. Changes in canopy and tree crown structure were quantified for Eucalyptus urophylla x E. grandis forests at different ages to determine when canopy closure occurs and the onset of competition begins. Site index was developed for these forests to determine whether site quality affects the canopy structure. Site index had little effect in the forests sampled, with the forest canopy on the better sites becoming slightly more elongated. Based upon crown projection ratio and crown diameter： dbh （diameter at breast height） ratio, it appears that crown closure occurs by age 4 years in these forests. The age at which this occurs was also checked and verified with the evaluation of relative spacing, RS （the ratio of the mean distance between trees to the average dominant height of the stand）. The RS value displayed a rapid decline until age 4 years, and then became relatively flat through age 21 years. The rapid height growth during the first 3 years with no change in density accounted for this rapid decrease. By age 4 years, reductions in the number of trees due to mortality began to have more of an influence on this value, resulting in a more gradual de- cline. The implications for management are discussed.
文摘The authors regret that the declaration of Acknowledgement as below is missing in the paper:AcknowledgementWe are grateful to the Department of Biology and Postgraduate Sciences-Biology of the Universidad del Valle,Cali-Colombia for their support of the project;to Wilmar Torres MSc.for his statistical advice;to the biologist Helen Burnham MSc.for the translation of the document;to Isabel Castro and all the members of the Ornithology and Animal Behaviour Laboratory-OYCA of Universidad del Valle for their invaluable support in the field.We sincerely thank the anonymous re-viewers for their invaluable feedback and contributions to our manuscript.
基金support from the National Natural Science Foundation of China (Grant No.U21B2094 and Grant No.U2067212)。
文摘The separation of lithium isotopes (^(6)Li and ^(7)Li) is of great importance for the nuclear industry.The lithium amalgam method is the only lithium isotopes separation process in industry,and the extensive use of mercury has raised concerns about its potential environmental hazards,which have prompted the search for more efficient and environmentally friendly alternatives.Crown ethers can bind lithium ions highly selectively and separate lithium isotopes effectively.A chemical exchange-based lithium isotopes separation method using crown ether decorated materials could be a viable and cost-effective alternative to the lithium amalgam method.In this review,we provide a systematic summary of the recent advances in lithium isotopes separation using crown ethers decorated materials.
基金supported by the European Union and the Romanian Government through the Competitiveness Operational Programme 2014–2020, under the project“Increasing the economic competitiveness of the forestry sector and the quality of life through knowledge transfer,technology and CDI skills”(CRESFORLIFE),ID P 40 380/105506, subsidiary contract no. 17/2020partially by the FORCLIMSOC Nucleu Programme (Contract 12N/2023)+2 种基金project PN 23090101CresPerfInst project (Contract 34PFE/December 30, 2021)“Increasing the institutional capacity and performance of INCDS ‘Marin Drǎcea’in RDI activities-CresPer”LM was financially supported by the Research Council of Finland's flagship ecosystem for Forest-Human-Machine Interplay–Building Resilience, Redefining Value Networks and Enabling Meaningful Experiences (UNITE)(decision number 357909)
文摘In this study,we used an extensive sampling network established in central Romania to develop tree height and crown length models.Our analysis included more than 18,000 tree measurements from five different species.Instead of building univariate models for each response variable,we employed a multivariate approach using seemingly unrelated mixed-effects models.These models incorporated variables related to species mixture,tree and stand size,competition,and stand structure.With the inclusion of additional variables in the multivariate seemingly unrelated mixed-effects models,the accuracy of the height prediction models improved by over 10% for all species,whereas the improvement in the crown length models was considerably smaller.Our findings indicate that trees in mixed stands tend to have shorter heights but longer crowns than those in pure stands.We also observed that trees in homogeneous stand structures have shorter crown lengths than those in heterogeneous stands.By employing a multivariate mixed-effects modelling framework,we were able to perform cross-model random-effect predictions,leading to a significant increase in accuracy when both responses were used to calibrate the model.In contrast,the improvement in accuracy was marginal when only height was used for calibration.We demonstrate how multivariate mixed-effects models can be effectively used to develop multi-response allometric models that can be easily calibrated with a limited number of observations while simultaneously achieving better-aligned projections.
基金supported by the National Natural Science Foundation of China(Grant No.62174079)Guangdong Provincial Quantum Science Strategic Initiative(Grant No.GDZX2404006)Science,Technology and Innovation Commission of Shenzhen Municipality(Grant No.JCYJ20220530113015035)。
文摘CdSe nanoplatelets(NPLs)are promising candidates for on-chip light sources,yet their performance is hindered by surface defects and inefficient optical gain.Herein,we demonstrate that CdSeS crown passivation significantly enhances the photophysical property of CdSe NPLs.Laser spectroscopy techniques reveal suppressed electronic and hole trapping at lateral surfaces,leading to a 4.2-fold increase in photoluminescence quantum yield and a shortened emission lifetime from13.5 to 4.8 ns.In addition,amplified spontaneous emission is achieved under nanosecond pulse pumping,with thresholds of0.75 to 0.16 mJ/cm^(2)for CdSe and CdSe/CdSeS NPLs,respectively.By integrating CdSe/CdSeS NPLs with high-refractiveindex SiO2scatters,coherent random lasing is realized at a threshold of 0.21 mJ/cm^(2).These findings highlight the critical role of lateral surface passivation in optimizing optical gain and pave the way for low-cost,multifunctional nanophotonic devices.
基金supported by the Natural Science Foundation of China (32071758)the Fundamental Research Funds for the Central Universities of China (No. 2572020BA01)
文摘This paper introduces a new method of calculating crown projection area(CPA),the area of level ground covered by a vertical projection of a tree crown from measured crown radii through numerical interpolation and integration.This novel method and other four existing methods of calculating CPA were compared using detailed crown radius measurements from 30 tall trees of Eucalyptus pilularis variable in crown size,shape,and asymmetry.The four existing methods included the polygonal approach and three ways of calculating CPA as the area of a circle using the arithmetic,geometric and quadratic mean radius.Comparisons were made across a sequence of eight non-consecutive numbers(from 2 to 16)of measured crown radii for each tree over the range of crown asymmetry of the 30 trees through generalized linear models and multiple comparisons of means.The sequence covered the range of the number of crown radii measured for calculating the CPA of a tree in the literature.A crown asymmetry index within the unit interval was calculated for each tree to serve as a normative measure.With a slight overestimation of 2.2%on average and an overall mean error size of 7.9%across the numbers of crown radii that were compared,our new method was the least biased and most accurate.Calculating CPA as a circle using the quadratic mean crown radius was the second best,which had an average overestimation of 4.5%and overall mean error size of 8.8%.These two methods remained by and large unbiased as crown asymmetry increased,while the other three methods showed larger bias of underestimation.For the conventional method of using the arithmetic mean crown radius to calculate CPA as a circle,bias correction factors were developed as a function of crown asymmetry index to delineate the increasing magnitude of bias associated with greater degrees of crown asymmetry.This study reveals and demonstrates such relationships between the accuracy of CPA calculations and crown asymmetry and will help increase awareness among researchers and practitioners on the existence of bias in their CPA calculations and for the need to use an unbiased method in the future.Our new method is recommended for calculating CPA where at least four crown radius measurements per tree are available because that is the minimum number required for its use.
文摘The cross-linking of crown ether-SE-54 in fused-silica capillary columns were initiated by dicumyl peroxide(DCUP),azo-bis-isobutyronitrile (AIBN)and ozone(O_3).Parameters of evaluation such as polarity,selectivity, phase transition temperature and thermal stability were studied and compared with those of poly(crown ether)stationary phase.
基金supported by the Mc IntireStennis program and East Texas Pine Plantation Research Project at Stephen F.Austin State UniversityPart of the research was also supported by Zhejiang Provincial Key Science and Technology Project(2018C02013)。
文摘In modeling forest stand growth and yield,crown width,a measure for stand density,is among the parameters that allows for estimating stand timber volumes.However,accurately measuring tree crown size in the field,in particular for mature trees,is challenging.This study demonstrated a novel method of applying machine learning algorithms to aerial imagery acquired by an unmanned aerial vehicle(UAV)to identify tree crowns and their widths in two loblolly pine plantations in eastern Texas,USA.An ortho mosaic image derived from UAV-captured aerial photos was acquired for each plantation(a young stand before canopy closure,a mature stand with a closed canopy).For each site,the images were split into two subsets:one for training and one for validation purposes.Three widely used object detection methods in deep learning,the Faster region-based convolutional neural network(Faster R-CNN),You Only Look Once version 3(YOLOv3),and single shot detection(SSD),were applied to the training data,respectively.Each was used to train the model for performing crown recognition and crown extraction.Each model output was evaluated using an independent test data set.All three models were successful in detecting tree crowns with an accuracy greater than 93%,except the Faster R-CNN model that failed on the mature site.On the young site,the SSD model performed the best for crown extraction with a coefficient of determination(R^(2))of 0.92,followed by Faster R-CNN(0.88)and YOLOv3(0.62).As to the mature site,the SSD model achieved a R^(2)as high as 0.94,follow by YOLOv3(0.69).These deep leaning algorithms,in particular the SSD model,proved to be successfully in identifying tree crowns and estimating crown widths with satisfactory accuracy.For the purpose of forest inventory on loblolly pine plantations,using UAV-captured imagery paired with the SSD object detention application is a cost-effective alternative to traditional ground measurement.
文摘A novel Pd(II) Benzo-15-crown-5 complex [Na(B15CS)]_2[Pd(SCN)_4] has been isolated and characterized by IR and X-ray diffraction analysis. The crystal structure belongs to monoclinic, space group P2_1,/n with cell dimensions, a = l.0164(6), b = l.3743(3), c = l.4987(7) nm, β = 95.248(6) °, V = 2.0847 'nm_3, Z = 2, F(000) = 944, R = 0.053, Rw = 0.072. The compound consists of two [Na(B15CS)]+ complex canons and a [Pd(SCN)4_]^(2-) complex anion. Each sodium ion is coordinated by five crown ether oxygen atoms and one N atom from the SCN group of [Pd(SCN)_4]^(2-) to form stable neutral complex.
基金This project was supported by the Natural Science Foundation of Shandong Province (No.Y2003 D01)
文摘3,3′-Dimethyl-dibenzo-18-crown-6 was synthesized and characterized by elemental analysis, FT-IR, ^1H NMR, UV, MS spectra and X-ray single-crystal diffraction. It belongs to orthorhombic, space group Pna21 with a = 8.0790（18）, b = 16.780（4）, c = 15.222（3） .A, Z= 4, V= 2063.6（8） A3 Dc = 1.250 g/cm^3,μ = 0.090 mm^-1, F（000） = 832, R = 0.0474 and wR = 0.1103. According to structural analysis, the title compound possesses a boat-like configuration.
基金Supported by the National Nonprofit Institute Research Grant of CATAS-TCGRI(163003201503316300320140322016+1 种基金pzsfyl-201613)the Ministry of Agriculture Tropical Crop Germplasm Resources Protection(16RZZY-101)~~
文摘Objective] The study was aimed to improve the yield and quality of cashew. [Method] Through the comparative analysis, the survival rate, new germi-nation and yield characteristics of the cutting stems with different heights by stem grafting and bark grafting. [Result] The best cutting stem height of cashew should be in 100-150 cm, when the number of new germinated shoots was 85.5-87.7. Stem grafting could significantly improve the survival rate of the shooting branch （92.7%）, growth condition of which was better than that of bark grafting, and it also had no clip cortex. The yield of stem grafting was significantly higher than that of bark grafting, and it could reach up to 18.1 kg/plant in 4 years. The branches from stem grafting had significantly better ability in resisting the wind damage than those from bark grafting. [Conclusion] The study provided references for the crown grafting of cashew planting in China.
文摘The program of the plate crown optimal prediction applied in the plate mill of Wuhan Iron and Steel(Group) Co. Ltd. is described. Optimal prediction is programmed in ALPHA 4000. The original profile, wear, expansion and deformation of work rolls are introduced into the program. The plate crown is controlled by the original profile of work rolls and the draft whose objective is the optimal plate crown. The run schedule is also optimized through the optimal prediction of the plate crown.
文摘A flexible and adaptable design method for the tooth crown is presented based on the direct manipulation of free-form deformation （FFD）. The correct shape of the tooth crown can be obtained by adding, modifying, and deleting constraint points or load points based on stretching and compressing operation. Finally, an example is given to illustrate the method to be efficient.
文摘Network crewn ether polymer with pendant sulfide side ohain in the networkstructure units has been synthesized via ring- opening copolymerization of β-ethylthioethyl glycidyl ether and diethylene glycol bisglycidyl ether. A kind of active catalyst suitable for this reaction was suggested. The title polymer was found tobe a good ligand for platinous chloride, and the platinous complex could catalyze thehydrosilylation of olefins with triethoxysilane efficiently.
