In electrochemical energy storage systems,the sodium-ion battery is typically integrated in the form of a“cell-module-cluster”,but its cross-scale thermal runaway triggering risk and the propagation mechanism remain...In electrochemical energy storage systems,the sodium-ion battery is typically integrated in the form of a“cell-module-cluster”,but its cross-scale thermal runaway triggering risk and the propagation mechanism remain unclear.This study reveals the cross-scale thermal runaway triggering and propagation behavior of sodium-ion batteries of“cell-module-cluster”under overcharge conditions,and investigates the effects of key factors,including module spacing,triggering cell location,and heat dissipation condition,on the thermal runaway propagation behavior.Results demonstrate that the thermal runaway propagation in a module containing the overcharged cell follows a sequential triggering mode,while thermal runaway in the downstream module exhibits a simultaneous triggering mode with greater severity.Furthermore,increasing the module spacing or enhancing the heat dissipation capacity can effectively reduce the heat accumulation and prevent the trigger of thermal runaway.On the above basis,the multi-dimensional evaluation strategy is proposed to quantitatively assess the hazard of sodium-ion battery cluster thermal runaway.The findings serve as a foundation for the safe design of sodium-ion batteries in energy storage systems.展开更多
Background:As an important indicator of subjective well-being(SWB),decent work is a key guarantee for the sustainable development of teachers and their psychological health and work quality.Faced with the rapid develo...Background:As an important indicator of subjective well-being(SWB),decent work is a key guarantee for the sustainable development of teachers and their psychological health and work quality.Faced with the rapid development of artificial intelligence and the global labor market,vocational college teachers are facing challenges such as workload pressure and limited career development,which may harm their well-being.This study aims to localize the measurement method of decent work in Chinese vocational education based on the theory of the Psychology of Working Theory,and explore the relationship mechanism between organizational support,career adaptability,decent work,and job satisfaction among vocational college teachers.Methods:A cross-sectional survey was conducted with 422 HVCU teachers in China(202 male,220 female)using the localized Perceived Organizational Support Scale,Career Adaptability Scale,Decent Work Scale,and Job Satisfaction Scale.Results:The overall level of HVCU teachers’decent work was above the median(Mean=4.09,SD=0.69),laying a foundation for their SWB.Decent work significantly and positively predicted job satisfaction(β=0.620,p<0.001).Organizational support(r=0.58,p<0.001)and career adaptability(r=0.82,p<0.001)can positively affect decent work,and further improve job satisfaction(collective R2 rising from 38.3%to 41.1%).Bootstrap analysis confirmed these mediating effects were robust.Conclusions:This study confirms that the combined effects of organizational support and career adaptability can enhance decent work,further improving teachers’job satisfaction and subsequent subjective well-being.Besides,this study provides an empirical basis for improving the well-being of higher vocational teachers and the sustainable development of vocational education,and has practical significance for improving the teacher incentive policy.展开更多
The construction of spot electricity markets plays a pivotal role in power system reforms,where market clearing systems profoundly influence market efficiency and security.Current clearing systems predominantly adopt ...The construction of spot electricity markets plays a pivotal role in power system reforms,where market clearing systems profoundly influence market efficiency and security.Current clearing systems predominantly adopt a single-system architecture,with research focusing primarily on accelerating solution algorithms through techniques such as high-efficiency parallel solvers and staggered decomposition of mixed-integer programming models.Notably absent are systematic studies evaluating the adaptability of primary-backup clearing systems incontingency scenarios—a critical gap given redundant systems’expanding applications in operational environments.This paper proposes a comprehensive evaluation framework for analyzing dual-system adaptability,demonstrated through an in-depth case study of the Inner Mongolia power market.First,we establish the innovative“Dual-Active Heterogeneous”architecture that enables independent parallelized operation and fault-isolated redundancy.Subsequently,key performance indices are quantitatively evaluated across four critical dimensions:unit commitment decisions,generator output constraints,transmission section congestion patterns,and clearing price formation mechanisms.An integrated fuzzy evaluation methodology incorporating grey relational analysis is employed for objective indicator weighting,enabling systematic quantification of system superiority under specific grid operating states.Empirical results based on actual operational data from 200 generation units demonstrate the framework’s efficacy in guiding optimal system selection,with particularly strong performance observed during peak load periods.The proposed approach shows high generalization potential for other regional markets employing redundant clearing mechanisms—particularly those with increasing renewable penetration and associated uncertainty.展开更多
Current spatio-temporal action detection methods lack sufficient capabilities in extracting and comprehending spatio-temporal information. This paper introduces an end-to-end Adaptive Cross-Scale Fusion Encoder-Decode...Current spatio-temporal action detection methods lack sufficient capabilities in extracting and comprehending spatio-temporal information. This paper introduces an end-to-end Adaptive Cross-Scale Fusion Encoder-Decoder (ACSF-ED) network to predict the action and locate the object efficiently. In the Adaptive Cross-Scale Fusion Spatio-Temporal Encoder (ACSF ST-Encoder), the Asymptotic Cross-scale Feature-fusion Module (ACCFM) is designed to address the issue of information degradation caused by the propagation of high-level semantic information, thereby extracting high-quality multi-scale features to provide superior features for subsequent spatio-temporal information modeling. Within the Shared-Head Decoder structure, a shared classification and regression detection head is constructed. A multi-constraint loss function composed of one-to-one, one-to-many, and contrastive denoising losses is designed to address the problem of insufficient constraint force in predicting results with traditional methods. This loss function enhances the accuracy of model classification predictions and improves the proximity of regression position predictions to ground truth objects. The proposed method model is evaluated on the popular dataset UCF101-24 and JHMDB-21. Experimental results demonstrate that the proposed method achieves an accuracy of 81.52% on the Frame-mAP metric, surpassing current existing methods.展开更多
Agricultural pests cause enormous losses in annual agricultural production.Understanding the evolutionary responses and adaptive capacity of agricultural pests under climate change is crucial for establishing sustaina...Agricultural pests cause enormous losses in annual agricultural production.Understanding the evolutionary responses and adaptive capacity of agricultural pests under climate change is crucial for establishing sustainable and environmentally friendly agricultural pest management.In this study,we integrate climate modeling and landscape genomics to investigate the distributional dynamics of the cotton bollworm(Helicoverpa armigera)in the adaptation to local environments and resilience to future climate change.Notably,the predicted inhabitable areas with higher suitability for the cotton bollworm could be eight times larger in the coming decades.Climate change is one of the factors driving the dynamics of distribution and population differentiation of the cotton bollworm.Approximately 19,000 years ago,the cotton bollworm expanded from its ancestral African population,followed by gradual occupations of the European,Asian,Oceanian,and American continents.Furthermore,we identify seven subpopulations with high dispersal and adaptability which may have an increased risk of invasion potential.Additionally,a large number of candidate genes and SNPs linked to climatic adaptation were mapped.These findings could inform sustainable pest management strategies in the face of climate change,aiding future pest forecasting and management planning.展开更多
Objectives:Teachers are facing unprecedented new challenges leading them to face an increasing number of tasks that are not part of their job,as well as having to cope with the additional skills acquisition that comes...Objectives:Teachers are facing unprecedented new challenges leading them to face an increasing number of tasks that are not part of their job,as well as having to cope with the additional skills acquisition that comes with non-traditional forms of teaching and learning,and increased work pressure leading to an increase in the rate of teachers leaving the profession.Therefore,this study aims to explore the mechanism of the career calling on job burnout through career adaptability and work engagement.Methods:This study conducted a cross-sectional survey of 465 primary and secondary school teachers(PSST)in China's Mainland from the perspective of work adjustment and used structural equation modeling(SEM)to examine the mediating roles of career adaptability and work engagement in the relationship between teachers’career calling and job burnout.Results:The results show that PSSTs are above average in career calling,career adaptability,and work engagement,while job burnout is below average.A significant positive or negative correlation exists between career calling,career adaptability,work engagement,and job burnout.The result of path analysis indicates that career adaptability and work engagement exert an indirect influence on the job burnout of PSST through three paths:namely,the independent intermediary role of career adaptability(EV=−0.144),the independent intermediary role of work engagement(EV=0.172)and the chain intermediary role of the two(EV=0.176).Conclusion:This study emphasizes the importance of career adaptability and work engagement in teacher development in regulating career calling and job burnout.Therefore,on the one hand,we think that if managers want to reduce teachers’job burnout,they need to pay more attention to teachers’career adaptability and work engagement,rather than relying solely on teachers’career calling.On the other hand,it is to remind teachers not to rely on their adjustment to adapt to the work,but also to need outside help as much as possible.展开更多
Flexoelectricity,an electromechanical coupling between strain gradient and electrical polarization in dielectrics or semiconductors,has attracted significant scientific interest.It is reported that large flexoelectric...Flexoelectricity,an electromechanical coupling between strain gradient and electrical polarization in dielectrics or semiconductors,has attracted significant scientific interest.It is reported that large flexoelectric behaviors can be obtained at the nanoscale because of the size effect.However,the flexoelectric responses of centrosymmetric semiconductors(CSs)are extremely weak under a conventional beam-bending approach,owing to weak flexoelectric coefficients and small strain gradients.The flexoelectric-like effect is an enhanced electromechanical effect coupling the flexoelectricity and piezoelectricity.In this paper,a composite structure consisting of piezoelectric dielectric layers and a CS layer is proposed.The electromechanical response of the CS is significantly enhanced via antisymmetric piezoelectric polarization.Consequently,the cross-scale mechanically tuned carrier distribution in the semiconductor is realized.Meanwhile,the significant size dependence of the electromechanical fields in the semiconductor is demonstrated.The flexoelectronics suppression is found when the semiconductor thickness reaches a critical size(0.8μm).In addition,the first-order carrier density of the composite structure under local loads is illustrated.Our results can suggest the structural design for flexoelectric semiconductor devices.展开更多
Qingke,a staple crop grown on the high-altitude Tibetan Plateau,has evolved a metabolomic profile providing both environmental stress resilience and human nutrition.We review the hypothesis that the metabolites that c...Qingke,a staple crop grown on the high-altitude Tibetan Plateau,has evolved a metabolomic profile providing both environmental stress resilience and human nutrition.We review the hypothesis that the metabolites that confer cold and UV resistance on the crop also facilitate human adaptation to high-altitude stresses.Specifically,β-glucans regulate blood glucose primarily via short-chain fatty acids(SCFAs)produced through gut microbiota fermentation,which directly mediate glucose homeostasis.Phenolamides accumulate via the phenylpropanoid pathway,with chalcone isomerase(CHI)serving as a key enzyme in flavonoid biosynthesis and enhancing UV-B resistance.Under low temperatures,β-glucans improve frost tolerance by modulating osmotic balance and inhibiting ice-nucleating proteins,while lipids maintain membrane fluidity to sustain cellular function during cold stress.Importantly,we explore the hypothesis that these same metabolites,upon consumption,may facilitate human adaptation to high-altitude stresses.This hypothesis is supported by preliminary epidemiological associations between Qingke consumption and favorable health outcomes in high-altitude populations,as well as established bioactivities of the implicated metabolites in vitro and in animal models.However,direct causal evidence in humans and a comprehensive understanding of the underlying molecular mechanisms remain key knowledge gaps that warrant future investigation.Qingke as a unique resource at the interface of agricultural resilience and human nutrition.Understanding its metabolic blueprint will inform the development of functional foods and climate-resilient crops.展开更多
Safe and just operating spaces(SJOS)are influenced by complex cross-scale interactions and cascading effects spanning global,regional,and local landscape scales.However,existing SJOS research has often focused on sing...Safe and just operating spaces(SJOS)are influenced by complex cross-scale interactions and cascading effects spanning global,regional,and local landscape scales.However,existing SJOS research has often focused on single-scale assessments,overlooking the impacts of multiscale interactions and within-region heterogeneity on urban SJOS.To address this gap,we developed a cross-scale framework for assessing urban SJOS,explicitly incorporating top-down influences from upper-level constraints and bottom-up effects from lower-level heterogeneity.This approach was applied to China's five major metropolises to examine the states and cross-scale dynamics influencing urban SJOS between 1990 and 2020.Our findings reveal that the SJOS of China's metropolises were primarily influenced by factors at national and local landscape scales,with weaker influences from the global and continental scales.A persistent trade-off between social justice and environmental safety was identified across spatiotemporal scales.For instance,Chongqing in southwestern China lagged behind the eastern four metropolises in social performance but exhibited stronger environmental safety due to its extensive natural landscapes,which mitigated the anthropogenic impacts of urban centers.Regional issues,such as the overshoot of PM_(2.5)and ecological footprints(EF),were primarily driven by the bottom-up accumulation of localized pressures,while the overshoot of CO_(2)was attributed to national policy constraints and the universal exceedance of safe thresholds across scales.Addressing urban sustainability requires avoiding adverse cascading effects from other levels by emphasizing landscape heterogeneity within metropolises and fostering coordinated collaboration across scales,particularly at the regional landscape and national levels.展开更多
We present a vectorial optical field(VOF) framework that surpasses the diffraction limit in both long-range imaging and energy delivery. By jointly engineering spatial and temporal dimensions, reflective Fourier ptych...We present a vectorial optical field(VOF) framework that surpasses the diffraction limit in both long-range imaging and energy delivery. By jointly engineering spatial and temporal dimensions, reflective Fourier ptychography is extended to 3.2 km with 0.37× the classical diffraction limit, while a single-photon Li DAR tomography system achieves centimeter-scale, sub-diffraction imaging at 3.3 km using superconducting nanowire single-photon detectors. These advances demonstrate super-resolution, turbulence-resilient imaging over kilometer-range distances. Beyond super-resolution optical, high power VOFs are able to counteract thermal blooming during atmospheric laser propagation, enhancing on-target power density by a factor larger than 2. Together, these results may outline a cross-scale paradigm that links highpower vector-field structuring, single-photon detection, and adaptive control-offering a pathway toward next-generation optical systems that integrate imaging, sensing, communication and directed energy within a common physical framework.展开更多
In tissue engineering(TE),tissue-inducing scaffolds are a promising solution for organ and tissue repair owing to their ability to attract stem cells in vivo,thereby inducing endogenous tissue regeneration through top...In tissue engineering(TE),tissue-inducing scaffolds are a promising solution for organ and tissue repair owing to their ability to attract stem cells in vivo,thereby inducing endogenous tissue regeneration through topological cues.An ideal TE scaffold should possess biomimetic cross-scale structures,similar to that of natural extracellular matrices,at the nano-to macro-scale level.Although freeform fabrication of TE scaffolds can be achieved through 3D printing,this method is limited in simultaneously building multiscale structures.To address this challenge,low-temperature fields were adopted in the traditional fabrication processes,such as casting and 3D printing.Ice crystals grow during scaffold fabrication and act as a template to control the nano-and micro-structures.These microstructures can be optimized by adjusting various parameters,such as the direction and magnitude of the low-temperature field.By preserving the macro-features fabricated using traditional methods,additional micro-structures with smaller scales can be incorporated simultaneously,realizing cross-scale structures that provide a better mimic of natural organs and tissues.In this paper,we present a state-of-the-art review of three low-temperature-field-assisted fabrication methods—freeze casting,cryogenic3D printing,and freeze spinning.Fundamental working principles,fabrication setups,processes,and examples of biomedical applications are introduced.The challenges and outlook for low-temperature-assisted fabrication are also discussed.展开更多
A comprehensive fishery-independent survey generally incorporates various specialized surveys and integrates different survey objectives to maximize benefits while accounting for cost limitations.It is important to ev...A comprehensive fishery-independent survey generally incorporates various specialized surveys and integrates different survey objectives to maximize benefits while accounting for cost limitations.It is important to evaluate the adaptability of the comprehensive survey for different taxon to get the optimal design.However,the validity and adaptability of ichthyoplankton sampling incorporated in a comprehensive fishery-independent survey program in estimating abundance of ichthyoplankton species is little known.This study included ichthyoplankton sampling in an integrated survey and assessed the appropriateness of survey design.The Kriging interpolation based on Gaussian models was used to estimate the values at unsurveyed locations based on the original ichthyoplankton survey data in the Haizhou Bay as the“true”values.The sampling performances of the ongoing stratified random sampling(StRS),simple random sampling(SRS),cluster sampling(CS),hexagonal systematic sampling(SYS h),and regular systematic sampling(SYS r)with different sample sizes in estimating ichthyoplankton abundance were compared in relative estimation error(REE),relative bias(RB),and coefficient of variation(CV)by computer simulation.The ongoing StRS performed better than CS and SRS,but not as good as the two systematic sampling methods,and the current sample size in StRS design was insufficient to estimate ichthyoplankton abundance.The average REE values(meanREE)were significantly smaller in two systematic sampling designs than those in other three sampling designs,and the two systematic sampling designs could maintain good inter-annual stability of sampling performances.It is suggested that incorporating ichthyoplankton survey directly into stratified random fishery-independent surveys could not achieve the desired level of accuracy for survey objectives,but the accuracy can be improved by setting additional stations.The assessment framework presented in this study serves as a reference for evaluating the adaptability of integrated surveys to different objectives in other waters.展开更多
With the deepening of cross-cultural educational cooperation between China and Malaysia,the cross-cultural challenges that Chinese overseas students face in Malaysia due to language and cultural differences have becom...With the deepening of cross-cultural educational cooperation between China and Malaysia,the cross-cultural challenges that Chinese overseas students face in Malaysia due to language and cultural differences have become increasingly prominent.Focusing on Chinese graduate students at a public university in Malaysia where English is the medium of instruction,this study employs a scale survey method in conjunction with IBM SPSS 26.0 and Smart PLS 4.0 for data analysis to quantitatively explore the level of language anxiety and its relationship with cross-cultural adaptability and learning motivation.The results indicate that most Chinese graduate students experience notable language anxiety,which is significantly negatively correlated with cross-cultural adaptability,especially academic adaptability,but is not related to learning motivation.Furthermore,the study reveals the complex influencing mechanism of language anxiety within multicultural educational environments and offers suggestions for improvement tailored to Malaysia’s unique educational context.These include utilizing technological tools for language interventions,optimizing classroom teaching strategies,enhancing language learning motivation through external incentives,strengthening training for cross-cultural adaptation skills,and promoting deeper cross-cultural communication.This study provides theoretical support and practical references for alleviating language anxiety and enhancing the cross-cultural adaptability of Chinese overseas students.展开更多
Covalent organic frameworks(COFs)are promising materials for mitigating polysulfide shuttling in lithium-sulfur(Li-S)batteries,but enhancing their ability to convert polysulfides across a wide temperature range remain...Covalent organic frameworks(COFs)are promising materials for mitigating polysulfide shuttling in lithium-sulfur(Li-S)batteries,but enhancing their ability to convert polysulfides across a wide temperature range remains a challenge,Herein,we introduce a redox-active COF(RaCOF)that functions as both a physical barrier and a kinetic enhancer to improve the temperature adaptability of Li-S batteries,The RaCOF constructed from redox-active anthraquinone units accelerates polysulfide conversion kinetics through reversible C=O/C-OLi transformations within a voltage range of 1,7 to 2.8 V(vs.Li^(+)/Li),optimizing sulfur redox reactions in ether-based electrolytes.Unlike conventional COFs,RaCOF provides bidentate trapping of polysulfides,increasing binding energy and facilitating more effective polysulfide management.In-situ XRD and ToF-SIMS analyses confirm that RaCOF enhances polysulfide adsorption and promotes the transformation of lithium sulfide(Li_(2)S),leading to better sulfur cathode reutilization.Consequently,RaCOF-modified Li-S batteries demonstrate low self-discharge(4.0%decay over a 7-day rest),excellent wide-temperature performance(stable from-10 to+60℃),and high-rate cycling stability(94%capacity retention over 500 cycles at 5.0 C).This work offers valuable insights for designing COF structures aimed at achieving temperature-adaptive performance in rechargeable batteries.展开更多
This study examines how organizational support influences the career adaptability of novice university teachers in Guangdong,China,and the mediating role of teacher self-efficacy.Drawing on social cognitive theory and...This study examines how organizational support influences the career adaptability of novice university teachers in Guangdong,China,and the mediating role of teacher self-efficacy.Drawing on social cognitive theory and organizational support theory,we hypothesized that organizational support would positively predict career adaptability through self-efficacy.A cross-sectional survey was conducted with 326 novice teachers(with 1–3 years of teaching experience)from 12 universities in Guangdong.Data were analyzed using correlation analysis,hierarchical regression,and bootstrap.Results showed that:(1)organizational support was positively associated with both self-efficacy(r=0.62,P<0.001)and career adaptability(r=0.58,P<0.001);(2)self-efficacy fully mediated the relationship between organizational support and career adaptability(indirect effect=0.24,95%CI[0.18,0.31]),with a partial reduction in the direct effect fromβ=0.35 toβ=0.17(P<0.05);(3)female teachers reported higher self-efficacy than males(P<0.05),and teachers with 2 years of experience showed significantly higher adaptability than those with 1 year(P<0.05).The findings highlight the critical role of self-efficacy in translating organizational support into adaptability,providing empirical evidence for universities to design targeted support strategies.展开更多
To understand career adaptability among undergraduates majoring in Primary Education in provincial normal universities,this study surveyed 257 such students and analyzed the current state and characteristics of their ...To understand career adaptability among undergraduates majoring in Primary Education in provincial normal universities,this study surveyed 257 such students and analyzed the current state and characteristics of their career adaptability.The results indicate that their overall career adaptability is moderately high.Significant differences in career adaptability were found by program type.Maternal education exerted a notable influence on overall career adaptability and on the“career confidence”dimension,whereas paternal education only showed a highly significant effect on“career confidence.”Therefore,schools should consolidate their role as the main arena for education,while families should provide supportive environments,jointly addressing the career adaptation and development needs of Primary Education undergraduates and further enhancing their career adaptability.展开更多
The environments of tropical and subtropical coral reef regions(CRR)differ from each other;however,it is not known if these environmental differences influence coral polyp and skeleton microbiome composition.In this s...The environments of tropical and subtropical coral reef regions(CRR)differ from each other;however,it is not known if these environmental differences influence coral polyp and skeleton microbiome composition.In this study,Coelastrea palauensis corals were collected from tropical and subtropical CRR in the South China Sea,and bacterial,archaeal,and fungal communities in polyps and skeletons were analyzed.Results showed that the microbial diversity and composition of C.palauensis significantly differed between the polyps and skeletons,and between the tropical and subtropical CRR.Regarding bacteria associated with corals,C.palauensis was mainly associated with bacteria closely related to the nitrogen cycle in the subtropical CRR.The relative abundances of Terasakiellaceae and Chlorobium in both coral polyps and skeletons in the subtropical CRR were higher than those in the tropical CRR.In the tropical CRR,C.palauensis was mainly associated with opportunistic pathogenic bacteria.The relative abundances of Tenacibaculum and Vibrio in coral polyps and skeletons in the tropical CRR were higher than those in the subtropical CRR.Regarding archaea associated with corals,polyps and skeletons of C.palauensis in both tropical and subtropical reef areas were dominated by n_Woesearchaeales,and the relative abundance of n_Woesearchaeales in skeletons is significantly higher than that in polyps.In addition,the relative abundances of n_Woesearchaeales in polyps and skeletons in the subtropical CRR were significantly higher than those in the tropical CRR.Regarding fungi associated with corals,Ascomycota was dominant in polyps and skeletons in the subtropical CRR,while Sordariomycetes,Periconia,Cladosporium,and Aspergillus were dominant in polyps and skeletons in the tropical CRR.Besides,the diversity differences of coral-associated microorganisms were related to environmental factors such as nutrients and temperature that may affect the survival of coral-associated microorganisms.These results implied that corals may adjust the composition of microorganisms,conducive the coral holobiont to better adapting the environment.Our research will be beneficial in understanding the differences and adaptations of coral polyp and skeletal microbiome.展开更多
Mechanically interlocked molecules (MIMs) have unique properties with broad applications, yet constructing both knotted and linked topologies from the same ligand remains challenging due to their distinct geometric de...Mechanically interlocked molecules (MIMs) have unique properties with broad applications, yet constructing both knotted and linked topologies from the same ligand remains challenging due to their distinct geometric demands. To address this, we design and synthesize a conformationally adaptive ligand 4,7-bis(3-(pyridin-4-yl) phenyl) benzo[c][1,2,5]thiadiazole (L1) with a tunable torsional angle θ of N1C1C2N2 ranging from 7.5° to 108.9°. Utilizing coordination-driven self-assembly at ambient temperature, L1 selectively assembles with binuclear half-sandwich units RhB1, RhB2, RhB3, and RhB4 featuring Cp*^(Rh^(Ⅲ)) (Cp* = η^(5)-pentam-ethylcyclopentadienyl) into distinct topologies: Solomon links Rh-1, trefoil knots Rh-2, molecular tweezers Rh 3, and Rh-4, respectively. Crucially, the self-adaptability of ligand L1 directs topology formation through pro-gramming different combination of noncovalent interactions (π-x stacking, CH..π interaction, and lone pair-π interaction), thus navigating divergent assembly pathways by conformational switching, as evidenced by X-ray crystallography analysis, independent gradient model (IGM) analysis, detailed nuclear magnetic resonance (NMR) spectroscopy and electrospray ionization time-of-flight/mass spectrometry (ESI-TOF/MS). This strategy can also be extended to construct Cp*^(Irl^(Ⅲ)) analogs (Solomon links Ir-1, trefoil knots Ir-2, molecular tweezers Ir-3 and Ir-4), demonstrating metal-independent control and achieving intricate topologies in a high yield.展开更多
Background:This study addresses the pressing need to understand the nuanced relationship between‘mattering’—the perception of being significant to others—and problematic internet use(PIU)among university students....Background:This study addresses the pressing need to understand the nuanced relationship between‘mattering’—the perception of being significant to others—and problematic internet use(PIU)among university students.Unlike previous research that has primarily employed variable-centered approaches,this study first adopts a person-centered approach using Latent Profile Analysis(LPA)to identify distinct mattering profiles.Subsequently,through variable-centered analyses,these profiles are examined in relation to different types of PIU—specifically problematic social media use(PSMU)and problematic gaming(PG)—as well as adaptability.Methods:Data were collected from 3587 university students across 19 universities in China.Participants completed three mattering-related scales(General Mattering Scale,Anti-Mattering Scale,and Fear of Not Mattering Inventory),along with the Bergen Social Media Addiction Scale,the Internet Gaming Disorder Scale-Short Form,and the Nine-item Adaptability Scale.Results:A four-class model identified by LPA was optimally selected:Class 1(high general mattering,low anti-mattering,low fear of not mattering),Class 2(moderate levels),Class 3(moderate general mattering,high antimattering,high fear of not mattering),and Class 4(low general mattering,low fear of not mattering,moderate anti-mattering).Significant differences were found among these classes in both PIU types(PSMU:F=139.66,p<0.001;PG:F=162.96,p<0.001).The pattern of mean differences consistently showed:Class 3>Class 2>Class 4>Class 1.Class 3 participants demonstrated the highest likelihood of meeting the addiction criteria,Class 2 showed moderate probability,while Classes 1 and 4 exhibited lower probabilities(χ^(2)=113.38 to 408.87,all p<0.001).Additionally,Class 3 reported the lowest adaptability(F=131.67,p<0.001).Conclusion:This study reveals that the unique influence of three ways of assessing feelings of mattering and the fear of not mattering on university students’PIU at the personal level,concluding that these factors are integral to understanding PIU among this demographic.展开更多
With the development and changes of society and the further iteration and renewal of parents’concepts,the importance and influence of future career planning of primary school students have become increasingly promine...With the development and changes of society and the further iteration and renewal of parents’concepts,the importance and influence of future career planning of primary school students have become increasingly prominent.Parental expectation is a very important part of influencing proactive personality,and it is also an important part of improving career adaptability,personal quality and comprehensive ability.This study explores the relationship between parents’expectation,proactive personality and career adaptability of primary school students.This paper deeply analyzes the influence of proactive personality on career adaptability,so as to provide theoretical support for improving the career adaptability of primary school students.In this study,the Chinese version of“Career Resilience”,“Parental Expectation Questionnaire”and“Proactive Personality Measurement”(PPS)were used as research tools to conduct psychological measurement on 287 students in grade 5 and 6 of a primary school in Beijing.SPSS29.0 and Process statistical software were used to explore the status quo and relationship of proactive personality,parents’expectation and career adaptability of primary school students.The conclusions of this study are as follows:(1)The correlation analysis results between parental expectation and proactive personality are significant,and there is a significant positive correlation.(2)The correlation analysis results between parents’expectations and career adaptability are significant,and there is a significant positive correlation.(3)The correlation analysis results between career adaptability and proactive personality were significant,showing a significant positive correlation.(4)Both parents’expectation and proactive personality have significant direct and positive effects on career adaptability,and proactive personality plays a partial mediating role between parents’expectation and career adaptability.展开更多
基金supported by the Anhui Quality Infrastructure Standardization Project(Grant No.2024MKSO7)the Science and Technology Project of State Grid(SGAHDK00DJJS2310027)the Anhui Provincial Natural Science Foundation(Grant No.2208085UD03).
文摘In electrochemical energy storage systems,the sodium-ion battery is typically integrated in the form of a“cell-module-cluster”,but its cross-scale thermal runaway triggering risk and the propagation mechanism remain unclear.This study reveals the cross-scale thermal runaway triggering and propagation behavior of sodium-ion batteries of“cell-module-cluster”under overcharge conditions,and investigates the effects of key factors,including module spacing,triggering cell location,and heat dissipation condition,on the thermal runaway propagation behavior.Results demonstrate that the thermal runaway propagation in a module containing the overcharged cell follows a sequential triggering mode,while thermal runaway in the downstream module exhibits a simultaneous triggering mode with greater severity.Furthermore,increasing the module spacing or enhancing the heat dissipation capacity can effectively reduce the heat accumulation and prevent the trigger of thermal runaway.On the above basis,the multi-dimensional evaluation strategy is proposed to quantitatively assess the hazard of sodium-ion battery cluster thermal runaway.The findings serve as a foundation for the safe design of sodium-ion batteries in energy storage systems.
基金funded by Nanjing University of Posts and Telecommunications Humanities and Social Sciences Research Fund Project(NYY222055)Special research project on teaching reform of innovation and entrepreneurship education in Nanjing University of Posts and Telecommunications(GCSJG202528)+2 种基金General Subject of Educational Science Planning in Jiangsu Province(C/2024/01/76)General project of educational science research in Shanghai(C24288)Key funded project of Shandong Vocational Education Teaching Reform Research in 2022(2022052).
文摘Background:As an important indicator of subjective well-being(SWB),decent work is a key guarantee for the sustainable development of teachers and their psychological health and work quality.Faced with the rapid development of artificial intelligence and the global labor market,vocational college teachers are facing challenges such as workload pressure and limited career development,which may harm their well-being.This study aims to localize the measurement method of decent work in Chinese vocational education based on the theory of the Psychology of Working Theory,and explore the relationship mechanism between organizational support,career adaptability,decent work,and job satisfaction among vocational college teachers.Methods:A cross-sectional survey was conducted with 422 HVCU teachers in China(202 male,220 female)using the localized Perceived Organizational Support Scale,Career Adaptability Scale,Decent Work Scale,and Job Satisfaction Scale.Results:The overall level of HVCU teachers’decent work was above the median(Mean=4.09,SD=0.69),laying a foundation for their SWB.Decent work significantly and positively predicted job satisfaction(β=0.620,p<0.001).Organizational support(r=0.58,p<0.001)and career adaptability(r=0.82,p<0.001)can positively affect decent work,and further improve job satisfaction(collective R2 rising from 38.3%to 41.1%).Bootstrap analysis confirmed these mediating effects were robust.Conclusions:This study confirms that the combined effects of organizational support and career adaptability can enhance decent work,further improving teachers’job satisfaction and subsequent subjective well-being.Besides,this study provides an empirical basis for improving the well-being of higher vocational teachers and the sustainable development of vocational education,and has practical significance for improving the teacher incentive policy.
基金supported by NARI Relays Electric Co.,Ltd.under the Project“Research on Evaluation of Clearing Results and Switching Criteria for Primary-Backup Systems in Electricity SpotMarkets”(Project No.CGSQ240800443).
文摘The construction of spot electricity markets plays a pivotal role in power system reforms,where market clearing systems profoundly influence market efficiency and security.Current clearing systems predominantly adopt a single-system architecture,with research focusing primarily on accelerating solution algorithms through techniques such as high-efficiency parallel solvers and staggered decomposition of mixed-integer programming models.Notably absent are systematic studies evaluating the adaptability of primary-backup clearing systems incontingency scenarios—a critical gap given redundant systems’expanding applications in operational environments.This paper proposes a comprehensive evaluation framework for analyzing dual-system adaptability,demonstrated through an in-depth case study of the Inner Mongolia power market.First,we establish the innovative“Dual-Active Heterogeneous”architecture that enables independent parallelized operation and fault-isolated redundancy.Subsequently,key performance indices are quantitatively evaluated across four critical dimensions:unit commitment decisions,generator output constraints,transmission section congestion patterns,and clearing price formation mechanisms.An integrated fuzzy evaluation methodology incorporating grey relational analysis is employed for objective indicator weighting,enabling systematic quantification of system superiority under specific grid operating states.Empirical results based on actual operational data from 200 generation units demonstrate the framework’s efficacy in guiding optimal system selection,with particularly strong performance observed during peak load periods.The proposed approach shows high generalization potential for other regional markets employing redundant clearing mechanisms—particularly those with increasing renewable penetration and associated uncertainty.
基金support for this work was supported by Key Lab of Intelligent and Green Flexographic Printing under Grant ZBKT202301.
文摘Current spatio-temporal action detection methods lack sufficient capabilities in extracting and comprehending spatio-temporal information. This paper introduces an end-to-end Adaptive Cross-Scale Fusion Encoder-Decoder (ACSF-ED) network to predict the action and locate the object efficiently. In the Adaptive Cross-Scale Fusion Spatio-Temporal Encoder (ACSF ST-Encoder), the Asymptotic Cross-scale Feature-fusion Module (ACCFM) is designed to address the issue of information degradation caused by the propagation of high-level semantic information, thereby extracting high-quality multi-scale features to provide superior features for subsequent spatio-temporal information modeling. Within the Shared-Head Decoder structure, a shared classification and regression detection head is constructed. A multi-constraint loss function composed of one-to-one, one-to-many, and contrastive denoising losses is designed to address the problem of insufficient constraint force in predicting results with traditional methods. This loss function enhances the accuracy of model classification predictions and improves the proximity of regression position predictions to ground truth objects. The proposed method model is evaluated on the popular dataset UCF101-24 and JHMDB-21. Experimental results demonstrate that the proposed method achieves an accuracy of 81.52% on the Frame-mAP metric, surpassing current existing methods.
基金funded by the National Natural Science Foundation of China(32372546)Shenzhen Science and Technology Program(KQTD20180411143628272)+1 种基金the Agricultural Science and Technology Innovation Program of Chinese Academy of Agricultural Sciences and STI 2030-Major Projects(2022ZD04021)the National Key Research and Development Program of China(2023YFD2200700)。
文摘Agricultural pests cause enormous losses in annual agricultural production.Understanding the evolutionary responses and adaptive capacity of agricultural pests under climate change is crucial for establishing sustainable and environmentally friendly agricultural pest management.In this study,we integrate climate modeling and landscape genomics to investigate the distributional dynamics of the cotton bollworm(Helicoverpa armigera)in the adaptation to local environments and resilience to future climate change.Notably,the predicted inhabitable areas with higher suitability for the cotton bollworm could be eight times larger in the coming decades.Climate change is one of the factors driving the dynamics of distribution and population differentiation of the cotton bollworm.Approximately 19,000 years ago,the cotton bollworm expanded from its ancestral African population,followed by gradual occupations of the European,Asian,Oceanian,and American continents.Furthermore,we identify seven subpopulations with high dispersal and adaptability which may have an increased risk of invasion potential.Additionally,a large number of candidate genes and SNPs linked to climatic adaptation were mapped.These findings could inform sustainable pest management strategies in the face of climate change,aiding future pest forecasting and management planning.
基金funded by Humanities and Social Sciences Foundation and Natural Science Foundation of Nanjing University of Posts and Telecommunications(NYY222055,NY224176)General Subject of Educational Science Planning in Jiangsu Province(C/2024/01/76)National Natural Science Foundation of China(62307025).
文摘Objectives:Teachers are facing unprecedented new challenges leading them to face an increasing number of tasks that are not part of their job,as well as having to cope with the additional skills acquisition that comes with non-traditional forms of teaching and learning,and increased work pressure leading to an increase in the rate of teachers leaving the profession.Therefore,this study aims to explore the mechanism of the career calling on job burnout through career adaptability and work engagement.Methods:This study conducted a cross-sectional survey of 465 primary and secondary school teachers(PSST)in China's Mainland from the perspective of work adjustment and used structural equation modeling(SEM)to examine the mediating roles of career adaptability and work engagement in the relationship between teachers’career calling and job burnout.Results:The results show that PSSTs are above average in career calling,career adaptability,and work engagement,while job burnout is below average.A significant positive or negative correlation exists between career calling,career adaptability,work engagement,and job burnout.The result of path analysis indicates that career adaptability and work engagement exert an indirect influence on the job burnout of PSST through three paths:namely,the independent intermediary role of career adaptability(EV=−0.144),the independent intermediary role of work engagement(EV=0.172)and the chain intermediary role of the two(EV=0.176).Conclusion:This study emphasizes the importance of career adaptability and work engagement in teacher development in regulating career calling and job burnout.Therefore,on the one hand,we think that if managers want to reduce teachers’job burnout,they need to pay more attention to teachers’career adaptability and work engagement,rather than relying solely on teachers’career calling.On the other hand,it is to remind teachers not to rely on their adjustment to adapt to the work,but also to need outside help as much as possible.
基金supported by the National Key Research and Development Program of China(Grant No.2021YFB2011400)the National Natural Science Foundation of China(Grant No.52375081).
文摘Flexoelectricity,an electromechanical coupling between strain gradient and electrical polarization in dielectrics or semiconductors,has attracted significant scientific interest.It is reported that large flexoelectric behaviors can be obtained at the nanoscale because of the size effect.However,the flexoelectric responses of centrosymmetric semiconductors(CSs)are extremely weak under a conventional beam-bending approach,owing to weak flexoelectric coefficients and small strain gradients.The flexoelectric-like effect is an enhanced electromechanical effect coupling the flexoelectricity and piezoelectricity.In this paper,a composite structure consisting of piezoelectric dielectric layers and a CS layer is proposed.The electromechanical response of the CS is significantly enhanced via antisymmetric piezoelectric polarization.Consequently,the cross-scale mechanically tuned carrier distribution in the semiconductor is realized.Meanwhile,the significant size dependence of the electromechanical fields in the semiconductor is demonstrated.The flexoelectronics suppression is found when the semiconductor thickness reaches a critical size(0.8μm).In addition,the first-order carrier density of the composite structure under local loads is illustrated.Our results can suggest the structural design for flexoelectric semiconductor devices.
基金supported by the Financial Special Fund,grant number XZ202401JD0027National Barley Industry Technology System(CARS-05-01A-08)+3 种基金the Xizang Agri-Tech Innovation Project(XZNKY-2025-CXGC-T01)the Joint Funds of the National Natural Science Foundation of China(No.U20A2026)the Financial Special Fund,grant number(32401784,2017CZZX001/2,XZNKY-2018-C-021 and NYSTC202401)the China Agriculture Research System of Barley(CARS-05).
文摘Qingke,a staple crop grown on the high-altitude Tibetan Plateau,has evolved a metabolomic profile providing both environmental stress resilience and human nutrition.We review the hypothesis that the metabolites that confer cold and UV resistance on the crop also facilitate human adaptation to high-altitude stresses.Specifically,β-glucans regulate blood glucose primarily via short-chain fatty acids(SCFAs)produced through gut microbiota fermentation,which directly mediate glucose homeostasis.Phenolamides accumulate via the phenylpropanoid pathway,with chalcone isomerase(CHI)serving as a key enzyme in flavonoid biosynthesis and enhancing UV-B resistance.Under low temperatures,β-glucans improve frost tolerance by modulating osmotic balance and inhibiting ice-nucleating proteins,while lipids maintain membrane fluidity to sustain cellular function during cold stress.Importantly,we explore the hypothesis that these same metabolites,upon consumption,may facilitate human adaptation to high-altitude stresses.This hypothesis is supported by preliminary epidemiological associations between Qingke consumption and favorable health outcomes in high-altitude populations,as well as established bioactivities of the implicated metabolites in vitro and in animal models.However,direct causal evidence in humans and a comprehensive understanding of the underlying molecular mechanisms remain key knowledge gaps that warrant future investigation.Qingke as a unique resource at the interface of agricultural resilience and human nutrition.Understanding its metabolic blueprint will inform the development of functional foods and climate-resilient crops.
基金supported by the National Natural Science Foundation of China(Grant No.42101296)the Natural Science Foundation of Chongqing(Grant No.CSTB2023NSCQ-MSX0041)Chongqing Municipal Training Program of Innovation and Entrepreneurship Project(Grants No.S202410635155 and X202410635116)。
文摘Safe and just operating spaces(SJOS)are influenced by complex cross-scale interactions and cascading effects spanning global,regional,and local landscape scales.However,existing SJOS research has often focused on single-scale assessments,overlooking the impacts of multiscale interactions and within-region heterogeneity on urban SJOS.To address this gap,we developed a cross-scale framework for assessing urban SJOS,explicitly incorporating top-down influences from upper-level constraints and bottom-up effects from lower-level heterogeneity.This approach was applied to China's five major metropolises to examine the states and cross-scale dynamics influencing urban SJOS between 1990 and 2020.Our findings reveal that the SJOS of China's metropolises were primarily influenced by factors at national and local landscape scales,with weaker influences from the global and continental scales.A persistent trade-off between social justice and environmental safety was identified across spatiotemporal scales.For instance,Chongqing in southwestern China lagged behind the eastern four metropolises in social performance but exhibited stronger environmental safety due to its extensive natural landscapes,which mitigated the anthropogenic impacts of urban centers.Regional issues,such as the overshoot of PM_(2.5)and ecological footprints(EF),were primarily driven by the bottom-up accumulation of localized pressures,while the overshoot of CO_(2)was attributed to national policy constraints and the universal exceedance of safe thresholds across scales.Addressing urban sustainability requires avoiding adverse cascading effects from other levels by emphasizing landscape heterogeneity within metropolises and fostering coordinated collaboration across scales,particularly at the regional landscape and national levels.
基金supported by Temporal-spatial manipulation Infrastructure for vector Fields in Optics-Test Facility(TIFO-TF)the National Natural Science Foundation of China(U24A6010,62222513)。
文摘We present a vectorial optical field(VOF) framework that surpasses the diffraction limit in both long-range imaging and energy delivery. By jointly engineering spatial and temporal dimensions, reflective Fourier ptychography is extended to 3.2 km with 0.37× the classical diffraction limit, while a single-photon Li DAR tomography system achieves centimeter-scale, sub-diffraction imaging at 3.3 km using superconducting nanowire single-photon detectors. These advances demonstrate super-resolution, turbulence-resilient imaging over kilometer-range distances. Beyond super-resolution optical, high power VOFs are able to counteract thermal blooming during atmospheric laser propagation, enhancing on-target power density by a factor larger than 2. Together, these results may outline a cross-scale paradigm that links highpower vector-field structuring, single-photon detection, and adaptive control-offering a pathway toward next-generation optical systems that integrate imaging, sensing, communication and directed energy within a common physical framework.
基金National Natural Science Foundation Council of China(Grant No.52305359)Hubei Provincial Natural Science Foundation of China(Grant No.2023AFB141)National Medical Products Administration Key Laboratory for Dental Materials(PKUSS20240401)。
文摘In tissue engineering(TE),tissue-inducing scaffolds are a promising solution for organ and tissue repair owing to their ability to attract stem cells in vivo,thereby inducing endogenous tissue regeneration through topological cues.An ideal TE scaffold should possess biomimetic cross-scale structures,similar to that of natural extracellular matrices,at the nano-to macro-scale level.Although freeform fabrication of TE scaffolds can be achieved through 3D printing,this method is limited in simultaneously building multiscale structures.To address this challenge,low-temperature fields were adopted in the traditional fabrication processes,such as casting and 3D printing.Ice crystals grow during scaffold fabrication and act as a template to control the nano-and micro-structures.These microstructures can be optimized by adjusting various parameters,such as the direction and magnitude of the low-temperature field.By preserving the macro-features fabricated using traditional methods,additional micro-structures with smaller scales can be incorporated simultaneously,realizing cross-scale structures that provide a better mimic of natural organs and tissues.In this paper,we present a state-of-the-art review of three low-temperature-field-assisted fabrication methods—freeze casting,cryogenic3D printing,and freeze spinning.Fundamental working principles,fabrication setups,processes,and examples of biomedical applications are introduced.The challenges and outlook for low-temperature-assisted fabrication are also discussed.
基金Supported by the National Key R&D Program of China(No.2022YFD2401301)the Special Financial Fund of Spawning Ground Survey in the Bohai Sea and the Yellow Sea from the Ministry of Agriculture and Rural Affairs,China(No.125C0505)。
文摘A comprehensive fishery-independent survey generally incorporates various specialized surveys and integrates different survey objectives to maximize benefits while accounting for cost limitations.It is important to evaluate the adaptability of the comprehensive survey for different taxon to get the optimal design.However,the validity and adaptability of ichthyoplankton sampling incorporated in a comprehensive fishery-independent survey program in estimating abundance of ichthyoplankton species is little known.This study included ichthyoplankton sampling in an integrated survey and assessed the appropriateness of survey design.The Kriging interpolation based on Gaussian models was used to estimate the values at unsurveyed locations based on the original ichthyoplankton survey data in the Haizhou Bay as the“true”values.The sampling performances of the ongoing stratified random sampling(StRS),simple random sampling(SRS),cluster sampling(CS),hexagonal systematic sampling(SYS h),and regular systematic sampling(SYS r)with different sample sizes in estimating ichthyoplankton abundance were compared in relative estimation error(REE),relative bias(RB),and coefficient of variation(CV)by computer simulation.The ongoing StRS performed better than CS and SRS,but not as good as the two systematic sampling methods,and the current sample size in StRS design was insufficient to estimate ichthyoplankton abundance.The average REE values(meanREE)were significantly smaller in two systematic sampling designs than those in other three sampling designs,and the two systematic sampling designs could maintain good inter-annual stability of sampling performances.It is suggested that incorporating ichthyoplankton survey directly into stratified random fishery-independent surveys could not achieve the desired level of accuracy for survey objectives,but the accuracy can be improved by setting additional stations.The assessment framework presented in this study serves as a reference for evaluating the adaptability of integrated surveys to different objectives in other waters.
基金funded by the 2022 Annual Key Research Project on Theoretical and Practical Studies of Ideological and Political Education for University Students in GuangxiSpecial Focus on University Counselors:Exploration and Practice of a Cultivation Ecosystem for Cultivating Both Moral Character and Talent Through “One Virtue+Two Lines+Three Stages+Four Micro-Education Methods” for Ideological and Political Education in Universities from the Perspective of Peer Language Systems,Project No.:2022MSZ031
文摘With the deepening of cross-cultural educational cooperation between China and Malaysia,the cross-cultural challenges that Chinese overseas students face in Malaysia due to language and cultural differences have become increasingly prominent.Focusing on Chinese graduate students at a public university in Malaysia where English is the medium of instruction,this study employs a scale survey method in conjunction with IBM SPSS 26.0 and Smart PLS 4.0 for data analysis to quantitatively explore the level of language anxiety and its relationship with cross-cultural adaptability and learning motivation.The results indicate that most Chinese graduate students experience notable language anxiety,which is significantly negatively correlated with cross-cultural adaptability,especially academic adaptability,but is not related to learning motivation.Furthermore,the study reveals the complex influencing mechanism of language anxiety within multicultural educational environments and offers suggestions for improvement tailored to Malaysia’s unique educational context.These include utilizing technological tools for language interventions,optimizing classroom teaching strategies,enhancing language learning motivation through external incentives,strengthening training for cross-cultural adaptation skills,and promoting deeper cross-cultural communication.This study provides theoretical support and practical references for alleviating language anxiety and enhancing the cross-cultural adaptability of Chinese overseas students.
基金funding supporting from the National Natural Science Foundation of China(22309003,22379001)the Natural Science Research Project of Anhui Province Education Department(2023AH051119)+3 种基金the open project funding from Shanghai Key Laboratory of Multi phase Materials Chemical Engineering(MMCE2024001)the National Key Research and Development Program of China(2022YFB2402201)the Shanghai Pilot Program for Basic Research-Fudan University 21TQ1400100(21TQ009)the Fundamental Research Funds for the Central Universities(20720220010).
文摘Covalent organic frameworks(COFs)are promising materials for mitigating polysulfide shuttling in lithium-sulfur(Li-S)batteries,but enhancing their ability to convert polysulfides across a wide temperature range remains a challenge,Herein,we introduce a redox-active COF(RaCOF)that functions as both a physical barrier and a kinetic enhancer to improve the temperature adaptability of Li-S batteries,The RaCOF constructed from redox-active anthraquinone units accelerates polysulfide conversion kinetics through reversible C=O/C-OLi transformations within a voltage range of 1,7 to 2.8 V(vs.Li^(+)/Li),optimizing sulfur redox reactions in ether-based electrolytes.Unlike conventional COFs,RaCOF provides bidentate trapping of polysulfides,increasing binding energy and facilitating more effective polysulfide management.In-situ XRD and ToF-SIMS analyses confirm that RaCOF enhances polysulfide adsorption and promotes the transformation of lithium sulfide(Li_(2)S),leading to better sulfur cathode reutilization.Consequently,RaCOF-modified Li-S batteries demonstrate low self-discharge(4.0%decay over a 7-day rest),excellent wide-temperature performance(stable from-10 to+60℃),and high-rate cycling stability(94%capacity retention over 500 cycles at 5.0 C).This work offers valuable insights for designing COF structures aimed at achieving temperature-adaptive performance in rechargeable batteries.
基金supported by the Teaching Quality and Teaching Reform Project of Dongguan City University(JY2022022301).
文摘This study examines how organizational support influences the career adaptability of novice university teachers in Guangdong,China,and the mediating role of teacher self-efficacy.Drawing on social cognitive theory and organizational support theory,we hypothesized that organizational support would positively predict career adaptability through self-efficacy.A cross-sectional survey was conducted with 326 novice teachers(with 1–3 years of teaching experience)from 12 universities in Guangdong.Data were analyzed using correlation analysis,hierarchical regression,and bootstrap.Results showed that:(1)organizational support was positively associated with both self-efficacy(r=0.62,P<0.001)and career adaptability(r=0.58,P<0.001);(2)self-efficacy fully mediated the relationship between organizational support and career adaptability(indirect effect=0.24,95%CI[0.18,0.31]),with a partial reduction in the direct effect fromβ=0.35 toβ=0.17(P<0.05);(3)female teachers reported higher self-efficacy than males(P<0.05),and teachers with 2 years of experience showed significantly higher adaptability than those with 1 year(P<0.05).The findings highlight the critical role of self-efficacy in translating organizational support into adaptability,providing empirical evidence for universities to design targeted support strategies.
基金supported by the School-Level Teaching Reform Research Project of Qilu Normal University(JG202304Z)the Research Project and Platform Cultivation Project for Education and Teaching Reform of Qilu Normal University(BP202416).
文摘To understand career adaptability among undergraduates majoring in Primary Education in provincial normal universities,this study surveyed 257 such students and analyzed the current state and characteristics of their career adaptability.The results indicate that their overall career adaptability is moderately high.Significant differences in career adaptability were found by program type.Maternal education exerted a notable influence on overall career adaptability and on the“career confidence”dimension,whereas paternal education only showed a highly significant effect on“career confidence.”Therefore,schools should consolidate their role as the main arena for education,while families should provide supportive environments,jointly addressing the career adaptation and development needs of Primary Education undergraduates and further enhancing their career adaptability.
基金The National Natural Science Foundation of China under contract Nos 42206157,42030502,and 42090041the Natural Science Foundation of Guangxi Province under contract No.2022GXNSFBA035449the Self-Topic Project of Guangxi Laboratory on the Study of Coral Reefs in the South China Sea under contract No.GXLSCRSCS2022103.
文摘The environments of tropical and subtropical coral reef regions(CRR)differ from each other;however,it is not known if these environmental differences influence coral polyp and skeleton microbiome composition.In this study,Coelastrea palauensis corals were collected from tropical and subtropical CRR in the South China Sea,and bacterial,archaeal,and fungal communities in polyps and skeletons were analyzed.Results showed that the microbial diversity and composition of C.palauensis significantly differed between the polyps and skeletons,and between the tropical and subtropical CRR.Regarding bacteria associated with corals,C.palauensis was mainly associated with bacteria closely related to the nitrogen cycle in the subtropical CRR.The relative abundances of Terasakiellaceae and Chlorobium in both coral polyps and skeletons in the subtropical CRR were higher than those in the tropical CRR.In the tropical CRR,C.palauensis was mainly associated with opportunistic pathogenic bacteria.The relative abundances of Tenacibaculum and Vibrio in coral polyps and skeletons in the tropical CRR were higher than those in the subtropical CRR.Regarding archaea associated with corals,polyps and skeletons of C.palauensis in both tropical and subtropical reef areas were dominated by n_Woesearchaeales,and the relative abundance of n_Woesearchaeales in skeletons is significantly higher than that in polyps.In addition,the relative abundances of n_Woesearchaeales in polyps and skeletons in the subtropical CRR were significantly higher than those in the tropical CRR.Regarding fungi associated with corals,Ascomycota was dominant in polyps and skeletons in the subtropical CRR,while Sordariomycetes,Periconia,Cladosporium,and Aspergillus were dominant in polyps and skeletons in the tropical CRR.Besides,the diversity differences of coral-associated microorganisms were related to environmental factors such as nutrients and temperature that may affect the survival of coral-associated microorganisms.These results implied that corals may adjust the composition of microorganisms,conducive the coral holobiont to better adapting the environment.Our research will be beneficial in understanding the differences and adaptations of coral polyp and skeletal microbiome.
基金Department of Chemistry,Fudan Uni-versity,the National Natural Science Foundation of China(22031003,21720102004)the Shanghai Science Technology Committee(19DZ227010O)the Alexander von Humboldt Foundation for a Humboldt Research Award.
文摘Mechanically interlocked molecules (MIMs) have unique properties with broad applications, yet constructing both knotted and linked topologies from the same ligand remains challenging due to their distinct geometric demands. To address this, we design and synthesize a conformationally adaptive ligand 4,7-bis(3-(pyridin-4-yl) phenyl) benzo[c][1,2,5]thiadiazole (L1) with a tunable torsional angle θ of N1C1C2N2 ranging from 7.5° to 108.9°. Utilizing coordination-driven self-assembly at ambient temperature, L1 selectively assembles with binuclear half-sandwich units RhB1, RhB2, RhB3, and RhB4 featuring Cp*^(Rh^(Ⅲ)) (Cp* = η^(5)-pentam-ethylcyclopentadienyl) into distinct topologies: Solomon links Rh-1, trefoil knots Rh-2, molecular tweezers Rh 3, and Rh-4, respectively. Crucially, the self-adaptability of ligand L1 directs topology formation through pro-gramming different combination of noncovalent interactions (π-x stacking, CH..π interaction, and lone pair-π interaction), thus navigating divergent assembly pathways by conformational switching, as evidenced by X-ray crystallography analysis, independent gradient model (IGM) analysis, detailed nuclear magnetic resonance (NMR) spectroscopy and electrospray ionization time-of-flight/mass spectrometry (ESI-TOF/MS). This strategy can also be extended to construct Cp*^(Irl^(Ⅲ)) analogs (Solomon links Ir-1, trefoil knots Ir-2, molecular tweezers Ir-3 and Ir-4), demonstrating metal-independent control and achieving intricate topologies in a high yield.
基金supported by a special grant from the Taishan Scholars Project(Project No.tsqn202211130).
文摘Background:This study addresses the pressing need to understand the nuanced relationship between‘mattering’—the perception of being significant to others—and problematic internet use(PIU)among university students.Unlike previous research that has primarily employed variable-centered approaches,this study first adopts a person-centered approach using Latent Profile Analysis(LPA)to identify distinct mattering profiles.Subsequently,through variable-centered analyses,these profiles are examined in relation to different types of PIU—specifically problematic social media use(PSMU)and problematic gaming(PG)—as well as adaptability.Methods:Data were collected from 3587 university students across 19 universities in China.Participants completed three mattering-related scales(General Mattering Scale,Anti-Mattering Scale,and Fear of Not Mattering Inventory),along with the Bergen Social Media Addiction Scale,the Internet Gaming Disorder Scale-Short Form,and the Nine-item Adaptability Scale.Results:A four-class model identified by LPA was optimally selected:Class 1(high general mattering,low anti-mattering,low fear of not mattering),Class 2(moderate levels),Class 3(moderate general mattering,high antimattering,high fear of not mattering),and Class 4(low general mattering,low fear of not mattering,moderate anti-mattering).Significant differences were found among these classes in both PIU types(PSMU:F=139.66,p<0.001;PG:F=162.96,p<0.001).The pattern of mean differences consistently showed:Class 3>Class 2>Class 4>Class 1.Class 3 participants demonstrated the highest likelihood of meeting the addiction criteria,Class 2 showed moderate probability,while Classes 1 and 4 exhibited lower probabilities(χ^(2)=113.38 to 408.87,all p<0.001).Additionally,Class 3 reported the lowest adaptability(F=131.67,p<0.001).Conclusion:This study reveals that the unique influence of three ways of assessing feelings of mattering and the fear of not mattering on university students’PIU at the personal level,concluding that these factors are integral to understanding PIU among this demographic.
基金Beijing Shidayidu Cultural Development Co.,Ltd:Research on the influencing factors and curriculum intervention of middle school students’career adaptability(No.BUU2023026).
文摘With the development and changes of society and the further iteration and renewal of parents’concepts,the importance and influence of future career planning of primary school students have become increasingly prominent.Parental expectation is a very important part of influencing proactive personality,and it is also an important part of improving career adaptability,personal quality and comprehensive ability.This study explores the relationship between parents’expectation,proactive personality and career adaptability of primary school students.This paper deeply analyzes the influence of proactive personality on career adaptability,so as to provide theoretical support for improving the career adaptability of primary school students.In this study,the Chinese version of“Career Resilience”,“Parental Expectation Questionnaire”and“Proactive Personality Measurement”(PPS)were used as research tools to conduct psychological measurement on 287 students in grade 5 and 6 of a primary school in Beijing.SPSS29.0 and Process statistical software were used to explore the status quo and relationship of proactive personality,parents’expectation and career adaptability of primary school students.The conclusions of this study are as follows:(1)The correlation analysis results between parental expectation and proactive personality are significant,and there is a significant positive correlation.(2)The correlation analysis results between parents’expectations and career adaptability are significant,and there is a significant positive correlation.(3)The correlation analysis results between career adaptability and proactive personality were significant,showing a significant positive correlation.(4)Both parents’expectation and proactive personality have significant direct and positive effects on career adaptability,and proactive personality plays a partial mediating role between parents’expectation and career adaptability.
