Against the backdrop of accelerated development of new forms of trade,the question of whether rapid expansion of cross-border e-commerce(CBEC)can help to reduce carbon emissions among Chinese enterprises is of great s...Against the backdrop of accelerated development of new forms of trade,the question of whether rapid expansion of cross-border e-commerce(CBEC)can help to reduce carbon emissions among Chinese enterprises is of great significance for seizing new opportunities in foreign trade,and advancing firms’green and low-carbon transformation.This study treats the creation of CBEC pilot zones as a quasi-natural experiment,employing panel data from Chinese A-share listed companies matched with city-level information from 2006 to 2021.We construct a multi-period difference-in-differences model to identify the impact of CBEC pilot zone policy on corporate carbon emissions.Our findings indicate the construction of these pilot zones significantly reduces firms’carbon emissions intensity,and the results are robust across multiple tests.We show the pilot zone initiative contributes to emission reductions by enhancing the adoption of digital infrastructure,promoting green technological innovation,and increasing environmental awareness among enterprises.Quantile regressions reveal pilot zones exert a more pronounced carbon-reduction effect on firms characterized by high carbon emissions intensity and advanced levels of digital transformation.Moreover,the policy effect is especially significant in heavily polluting industries,and regions with weaker governmental environmental regulations or lower public environmental concerns.This study makes an innovative contribution to the literature by empirically verifying the environmental governance effect of establishing CBEC pilot zones,and offers practical guidance for governments in formulating cross-border e-commerce policies and for enterprises pursuing low carbon development.展开更多
Lymphatic vessel networks have been identified in the meninges of mice,non-human primates,and humans[1].Meningeal lymphatic vessels(mLVs),composed of meningeal lymphatic endothelial cells(mLECs),are present in both ze...Lymphatic vessel networks have been identified in the meninges of mice,non-human primates,and humans[1].Meningeal lymphatic vessels(mLVs),composed of meningeal lymphatic endothelial cells(mLECs),are present in both zebrafish and mammals,although their anatomical distributions differ;they reside in the dura mater in mice,but are situated within the meninges in zebrafish[2].Moreover,the lymphatic marker genes expressed in these vessels differ between species[2].展开更多
Cross-border e-commerce,as a new form of international trade,has shown great development potential in the context of the“Belt and Road”initiative.Based on the cross-border e-commerce export data from 2015 to 2024,th...Cross-border e-commerce,as a new form of international trade,has shown great development potential in the context of the“Belt and Road”initiative.Based on the cross-border e-commerce export data from 2015 to 2024,this paper analyzes the influencing factors of China's cross-border e-commerce exports to countries along the“Belt and Road”by constructing an econometric model.The study found that factors such as the perfection of digital infrastructure,the efficiency of logistics and transportation,the convenience of payment and settlement,and the penetration rate of consumers online shopping significantly affect the export scale of cross-border e-commerce.Institutional factors such as the development level of e-commerce platforms in countries along the route,market access thresholds,and tariff policies also play an important role.Based on the research results,suggestions are put forward to strengthen the construction of cross-border payment system,optimize the logistics distribution network,promote customs clearance facilitation,and deepen cooperation in the field of e-commerce,to provide references for promoting the development of China's crossborder e-commerce exports to countries along the“Belt and Road.”展开更多
Taxation,the primary source of fiscal revenue,has profound implications in guiding resource allocation,promoting economic growth,adjusting social wealth distribution,and enhancing cultural influence.The development of...Taxation,the primary source of fiscal revenue,has profound implications in guiding resource allocation,promoting economic growth,adjusting social wealth distribution,and enhancing cultural influence.The development of e-taxation provides a enhanced security for taxation,but it still faces the risk of inefficiency and tax data leakage.As a decentralized ledger,blockchain provides an effective solution for protecting tax data and avoiding tax-related errors and fraud.The introduction of blockchain into e-taxation protocols can ensure the public verification of taxes.However,balancing taxpayer identity privacy with regulation remains a challenge.In this paper,we propose a blockchain-based anonymous and regulatory e-taxation protocol.This protocol ensures the supervision and tracking of malicious taxpayers while maintaining honest taxpayer identity privacy,reduces the storage needs for public key certificates in the public key infrastructure,and enables selfcertification of taxpayers’public keys and addresses.We formalize the security model of unforgeability for transactions,anonymity for honest taxpayers,and traceability for malicious taxpayers.Security analysis shows that the proposed protocol satisfies unforgeability,anonymity,and traceability.The experimental results of time consumption show that the protocol is feasible in practical applications.展开更多
Age-related macular degeneration(AMD)represents a predominant cause of blindness among older adults,with limited therapeutic options currently available.Oxidative stress,inflammation,and retinal pigment epithelium inj...Age-related macular degeneration(AMD)represents a predominant cause of blindness among older adults,with limited therapeutic options currently available.Oxidative stress,inflammation,and retinal pigment epithelium injury are recognized as key contributors to the pathogenesis of AMD.Regulated cell death plays a pivotal role in mediating cellular responses to stress,maintaining tissue homeostasis,and contributing to disease progression.Recent research has elucidated several regulated cell death pathwaysdsuch as apoptosis,ferroptosis,pyroptosis,necroptosis,and autophagydthat may contribute to the progression of AMD owing to cell death in the retinal pigment epithelium.These discoveries open new avenues for therapeutic interventions in patients with AMD.In this review,we provide a comprehensive summary and analysis of the latest advancements regarding the relationship between regulated cell death and AMD.Moreover,we examined the therapeutic potential of targeting regulated cell death pathways for the treatment and prevention of AMD,highlighting their roles as promising targets for future therapeutic strategies.展开更多
Cross-border e-commerce has emerged as a new growth point in foreign trade.While the Dalian comprehensive pilot zone has made some progress,its development is constrained by issues such as the global economic slowdown...Cross-border e-commerce has emerged as a new growth point in foreign trade.While the Dalian comprehensive pilot zone has made some progress,its development is constrained by issues such as the global economic slowdown,the relatively small scale of cross-border e-commerce,a high concentration of export commodities,imperfect information mechanisms,and high overall costs.To address these challenges,this paper explores the importance of the construction of the Dalian comprehensive pilot zone for cross-border e-commerce to the transformation and upgrading of exports.Based on my research project,“Research on Path Optimization of Financial Support for the Development of Advanced Manufacturing Clusters in Dalian,”this paper analyzes the current challenges and limiting factors and proposes corresponding countermeasures and suggestions.展开更多
The development of high-performance structural and functional materials is vital in many industrial fields.High-and medium-entropy alloys(H/MEAs)with superior comprehensive properties owing to their specific microstru...The development of high-performance structural and functional materials is vital in many industrial fields.High-and medium-entropy alloys(H/MEAs)with superior comprehensive properties owing to their specific microstructures are promising candidates for structural materials.More importantly,multitudinous efforts have been made to regulate the microstructures and the properties of H/MEAs to further expand their industrial applications.The various heterostructures have enormous potential for the development of H/MEAs with outstanding performance.Herein,multiple heterogeneous structures with single and hierarchical heterogeneities were discussed in detail.Moreover,preparation methods for compositional inhomogeneity,bimodal structures,dualphase structures,lamella/layered structures,harmonic structures(core-shell),multiscale precipitates and heterostructures coupled with specific microstructures in H/MEAs were also systematically reviewed.The deformation mechanisms induced by the different heterostructures were thoroughly discussed to explore the relationship between the heterostructures and the optimized properties of H/MEAs.The contributions of the heterostructures and advanced microstructures to the H/MEAs were comprehensively elucidated to further improve the properties of the alloys.Finally,this review discussed the future challenges of high-performance H/MEAs for industrial applications and provides feasible methods for optimizing heterostructures to enhance the comprehensive properties of H/MEAs.展开更多
Against the backdrop of economic globalization and the rapid growth of cross-border e-commerce,the overseas expansion of smart home products heavily relies on the translation quality of technological elements within m...Against the backdrop of economic globalization and the rapid growth of cross-border e-commerce,the overseas expansion of smart home products heavily relies on the translation quality of technological elements within marketing copy.This paper focuses on four core technological elements in smart home marketing copy on cross-border e-commerce platforms.Using Skopos Theory as a framework,it analyzes translation difficulties such as inconsistent terminology and imbalance between technical precision and accessibility.It constructs a five-dimensional translation strategy,“Precision+Accessibility+Localization+Structuring+Standardization”,and validates its effectiveness.This provides guidance for enterprises to enhance overseas marketing efficiency and enriches the research value of translation in the cross-border e-commerce vertical field.展开更多
The Fourth Industrial Revolution has endowed the concept of state sovereignty with new era-specific connotations,leading to the emergence of the theory of data sovereignty.While countries refine their domestic legisla...The Fourth Industrial Revolution has endowed the concept of state sovereignty with new era-specific connotations,leading to the emergence of the theory of data sovereignty.While countries refine their domestic legislation to establish their data sovereignty,they are also actively engaging in the negotiation of cross-border data flow rules within international trade agreements to construct data sovereignty.During these negotiations,countries express differing regulatory claims,with some focusing on safeguarding sovereignty and protecting human rights,some prioritizing economic promotion and security assurance,and others targeting traditional and innovative digital trade barriers.These varied approaches reflect the tension between three pairs of values:collectivism and individualism,freedom and security,and tradition and innovation.Based on their distinct value pursuits,three representative models of data sovereignty construction have emerged globally.At the current juncture,when international rules for digital trade are still in their nascent stages,China should timely establish its data sovereignty rules,actively participate in global data sovereignty competition,and balance its sovereignty interests with other interests.Specifically,China should explore the scope of system-acceptable digital trade barriers through free trade zones;integrate domestic and international legal frameworks to ensure the alignment of China’s data governance legislation with its obligations under international trade agreements;and use the development of the“Digital Silk Road”as a starting point to prioritize the formation of digital trade rules with countries participating in the Belt and Road Initiative,promoting the Chinese solutions internationally.展开更多
Alzheimer's disease,a progressively degenerative neurological disorder,is the most common cause of dementia in the elderly.While its precise etiology remains unclear,researchers have identified diverse pathologica...Alzheimer's disease,a progressively degenerative neurological disorder,is the most common cause of dementia in the elderly.While its precise etiology remains unclear,researchers have identified diverse pathological characteristics and molecular pathways associated with its progression.Advances in scientific research have increasingly highlighted the crucial role of non-coding RNAs in the progression of Alzheimer's disease.These non-coding RNAs regulate several biological processes critical to the advancement of the disease,offering promising potential as therapeutic targets and diagnostic biomarkers.Therefore,this review aims to investigate the underlying mechanisms of Alzheimer's disease onset,with a particular focus on microRNAs,long non-coding RNAs,and circular RNAs associated with the disease.The review elucidates the potential pathogenic processes of Alzheimer's disease and provides a detailed description of the synthesis mechanisms of the three aforementioned non-coding RNAs.It comprehensively summarizes the various non-coding RNAs that have been identified to play key regulatory roles in Alzheimer's disease,as well as how these noncoding RNAs influence the disease's progression by regulating gene expression and protein functions.For example,miR-9 targets the UBE4B gene,promoting autophagy-mediated degradation of Tau protein,thereby reducing Tau accumulation and delaying Alzheimer's disease progression.Conversely,the long non-coding RNA BACE1-AS stabilizes BACE1 mRNA,promoting the generation of amyloid-βand accelerating Alzheimer's disease development.Additionally,circular RNAs play significant roles in regulating neuroinflammatory responses.By integrating insights from these regulatory mechanisms,there is potential to discover new therapeutic targets and potential biomarkers for early detection and management of Alzheimer's disease.This review aims to enhance the understanding of the relationship between Alzheimer's disease and non-coding RNAs,potentially paving the way for early detection and novel treatment strategies.展开更多
The orientation of precipitates was regulated by an improved twinning-aging-detwinning(TAD)process in Mg-Sn sheets.A structure with specific proportions of dual-precipitates was regulated,significantly enhancing the m...The orientation of precipitates was regulated by an improved twinning-aging-detwinning(TAD)process in Mg-Sn sheets.A structure with specific proportions of dual-precipitates was regulated,significantly enhancing the material’s strength.The formation mechanism of the dual-precipitates was investigated,and the evolution of precipitate orientation was confirmed.A combined SEM,EBSD and TEM method was developed to identify the coupling relationship between complex grain orientation and precipitate orientation.The orientation relationship between precipitates and the matrix could be quantitatively analyzed in the same region.Subsequently,the Orowan model was refined to quantify the strength enhancement effect following the orientation regulation of precipitates.The TAD sample containing dual-precipitates exhibited a 99.1%increase in TYS,equivalent to an increase of 108 MPa,compared to unregulated samples A.According to Orowan calculations,the theoretical strength increment from the three strengthening mechanisms was 113 MPa,closely matching the experimental increment of 108 MPa.Notably,the materials with a specific proportion of the dual-precipitates showed a substantial increase in strength.展开更多
Root architecture is crucial for plant survival under drought,yet how water stress signals shape root development has remained unclear.Recently,Roy et al.(Science)revealed that drought-induced accumulation of reactive...Root architecture is crucial for plant survival under drought,yet how water stress signals shape root development has remained unclear.Recently,Roy et al.(Science)revealed that drought-induced accumulation of reactive oxygen species(ROS)in root nuclei triggers the auxin repressor IAA3 to form complexes(multimerization)that enable the recruitment of the co-repressor TOPLESS(TPL),thereby suppressing auxin signaling and blocking lateral root initiation.ROS signaling acts rapidly,within minutes of water deprivation,compared to slower ABA responses,allowing plants to quickly adjust lateral root growth.This discovery reveals a new redoxhormone regulatory mechanism that enables plants to fine-tune root branching during transient drought.Beyond advancing our understanding of adaptive root responses,these insights highlight potential molecular targets for developing crops with improved resilience under water limitation.展开更多
5-Aminolevulinic acid(ALA)is a natural plant growth regulator that promotes plant freezing tolerance.The WRKY family consists of plantspecific transcription factors(TFs)associated with abiotic stress responses.Up to n...5-Aminolevulinic acid(ALA)is a natural plant growth regulator that promotes plant freezing tolerance.The WRKY family consists of plantspecific transcription factors(TFs)associated with abiotic stress responses.Up to now,whether WRKYs are involved in ALA-induced plant freezing tolerance and the underlying mechanism is not clear.In this study,we found that pretreatment with 50 mg·L^(-1) ALA one week earlier significantly increased the freezing tolerance of nectarine(Prunus persica var.nectarina)pistils with higher antioxidant enzyme activity and osmotic solutes when the floral twigs were stressed by-3℃ for 6 h.ALA also enhanced the expression of PpWRKY18,PpCBF1,PpCOR1,and several genes encoding antioxidant enzymes(such as superoxide dismutase,peroxidase,and catalase)and pyrroline-5-carboxylate synthase(P5CS).When PpWRKY18 was overexpressed in tobacco,the transgenic plants exhibited greater freezing tolerance,which was further promoted by exogenous ALA.Y2H,Pull-down,BiFC,and LCI analyses revealed that PpWRKY18 interacts with PpCBF1,promoting the latter transcriptional activity.Additionally,Y1H experiments showed that PpWRKY18 directly binds to the promoter of PpPOD41 while PpCBF1 binds to the promoters of PpP5CS1 and PpCOR1,activating the target gene expressions.Furthermore,we established a yeast library using the promoter of PpWRKY18 as the bait to screen the upstream regulatory factors.By library screening,Y1H,DLR,and EMSA,we found that PpC3H37,a zinc finger protein,was responsive to chilling and ALA treatment,and as a transcription factor,it activated PpWRKY18 expression by directly binding to the promoter.Taken together,we reveal a regulatory network where ALA induces upregulation of PpC3H37 expression,which positively regulates PpWRKY18 expression.Subsequently,the regulatory pathway diverges into two branches.The first is CBF-dependent,where PpCBF1 interacts with PpWRKY18,binding the promoters of PpP5CS1 and PpCOR1.The second is CBF-independent,where PpWRKY18 directly binds the promoter of PpPOD41 to upregulate the gene expression and increase the antioxidant enzyme activity and freezing tolerance.These findings provide a novel insight of the mechanism of ALA in regulating the cold hardiness of nectarine pistil.展开更多
To advance the precise regulation and high-value utilization of halloysite nanotubes(HNTs),this work systematically investigated five treatment strategies,including calcination,acid treatment,alkali treatment,acid tre...To advance the precise regulation and high-value utilization of halloysite nanotubes(HNTs),this work systematically investigated five treatment strategies,including calcination,acid treatment,alkali treatment,acid treatment of calcined HNTs,and alkali treatment of calcined HNTs,to modulate their structural and application properties.The structural characteristics,surface properties,and methylene blue(MB)adsorption capacity of HNTs under multiple treatments were systematically analyzed.Calcination at varying temperatures modified the crystal structure,morphology,and surface properties of HNTs,with higher calcination temperatures reducing their reactivity towards MB.Moderate acid treatment expanded the lumen and decreased the surface potential of HNTs,significantly enhancing MB adsorption capacity.In contrast,alkali treatment dispersed the multilayered walls of HNTs and raised surface potential,reducing MB affinity.Acid treatment of calcined HNTs effectively increased their specific surface areas by leaching most of Al while maintaining the tubular structure,thereby maximizing MB adsorption.Alkali treatment of calcined HNTs destroyed the tubular structure and resulted in poor MB adsorption.HNTs pre-calcined at 600℃ for 3 h and acid-treated at 60℃ for 8 h exhibited an optimal specific surface area of443 m^(2)·g^(-1)and an MB adsorption capacity of 190 mg·g^(-1).Kinetic and Arrhenius equation fittings indicated that chemical reactions control interactions of acids and alkalis with HNTs.This study provides a comprehensive comparison and analysis of five treatment methods,offering insights into regulating the structures and surface properties of HNTs by controlling the treatment condition,thereby laying a foundation for their efficient utilization in practical applications.展开更多
Constructing multi-dimensional hydrogen bond(H-bond)regulated single-molecule systems with multiemission remains a challenge.Herein,we report the design of a new excited-state intramolecular proton transfer(ESIPT)feat...Constructing multi-dimensional hydrogen bond(H-bond)regulated single-molecule systems with multiemission remains a challenge.Herein,we report the design of a new excited-state intramolecular proton transfer(ESIPT)featured chromophore(HBT-DPI)that shows flexible emission tunability via the multidimensional regulation of intra-and intermolecular H-bonds.The feature of switchable intramolecular Hbonds is induced via incorporating several hydrogen bond acceptors and donors into one single HBT-DPI molecule,allowing the“turn on/off”of ESIPT process by forming isomers with distinct intramolecular Hbonds configurations.In response to different external H-bonding environments,the obtained four types of crystal/cocrystals vary in the contents of isomers and the molecular packing modes,which are mainly guided by the intermolecular H-bonds,exhibiting non-emissive features or emissions ranging from green to orange.Utilizing the feature of intermolecular H-bond guided molecular packing,we demonstrate the utility of this fluorescent material for visualizing hydrophobic/hydrophilic areas on large-scale heterogeneous surfaces of modified poly(1,1-difluoroethylene)(PVDF)membranes and quantitatively estimating the surface hydrophobicity,providing a new approach for hydrophobicity/hydrophilicity monitoring and measurement.Overall,this study represents a new design strategy for constructing multi-dimensional hydrogen bond regulated ESIPT-based fluorescent materials that enable multiple emissions and unique applications.展开更多
Regulatory T cells,a subset of CD4^(+)T cells,play a critical role in maintaining immune tolerance and tissue homeostasis due to their potent immunosuppressive properties.Recent advances in research have highlighted t...Regulatory T cells,a subset of CD4^(+)T cells,play a critical role in maintaining immune tolerance and tissue homeostasis due to their potent immunosuppressive properties.Recent advances in research have highlighted the important therapeutic potential of Tregs in neurological diseases and tissue repair,emphasizing their multifaceted roles in immune regulation.This review aims to summarize and analyze the mechanisms of action and therapeutic potential of Tregs in relation to neurological diseases and neural regeneration.Beyond their classical immune-regulatory functions,emerging evidence points to non-immune mechanisms of regulatory T cells,particularly their interactions with stem cells and other non-immune cells.These interactions contribute to optimizing the repair microenvironment and promoting tissue repair and nerve regeneration,positioning non-immune pathways as a promising direction for future research.By modulating immune and non-immune cells,including neurons and glia within neural tissues,Tregs have demonstrated remarkable efficacy in enhancing regeneration in the central and peripheral nervous systems.Preclinical studies have revealed that Treg cells interact with neurons,glial cells,and other neural components to mitigate inflammatory damage and support functional recovery.Current mechanistic studies show that Tregs can significantly promote neural repair and functional recovery by regulating inflammatory responses and the local immune microenvironment.However,research on the mechanistic roles of regulatory T cells in other diseases remains limited,highlighting substantial gaps and opportunities for exploration in this field.Laboratory and clinical studies have further advanced the application of regulatory T cells.Technical advances have enabled efficient isolation,ex vivo expansion and functionalization,and adoptive transfer of regulatory T cells,with efficacy validated in animal models.Innovative strategies,including gene editing,cell-free technologies,biomaterial-based recruitment,and in situ delivery have expanded the therapeutic potential of regulatory T cells.Gene editing enables precise functional optimization,while biomaterial and in situ delivery technologies enhance their accumulation and efficacy at target sites.These advancements not only improve the immune-regulatory capacity of regulatory T cells but also significantly enhance their role in tissue repair.By leveraging the pivotal and diverse functions of Tregs in immune modulation and tissue repair,regulatory T cells–based therapies may lead to transformative breakthroughs in the treatment of neurological diseases.展开更多
With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challe...With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challenge of improving the frequency regulation performance of a thermal-storage primary frequency regulation system while reducing its associated losses,this paper proposes a multi-dimensional cooperative optimization strategy for the control parameters of a combined thermal-storage system,considering regulation losses.First,the frequency regulation losses of various components within the thermal power unit are quantified,and a calculation method for energy storage regulation loss is proposed,based on Depth of Discharge(DOD)and C-rate.Second,a thermal-storage cooperative control method based on series compensation is developed to improve the system’s frequency regulation performance.Third,targeting system regulation loss cost and regulation output,and considering constraints on output overshoot and system parameters,an improved Particle Swarm Optimization(PSO)algorithm is employed to tune the parameters of the low-pass filter and the series compensator,thereby reducing regulation losses while enhancing performance.Finally,simulation results demonstrate that the total loss cost of the proposed control strategy is comparable to that of a system with only thermal power participation.However,the thermal power loss cost is reduced by 42.16%compared to the thermal-only case,while simultaneously improving system frequency stability.Thus,the proposed strategy effectively balances system frequency stability and economic efficiency.展开更多
Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2...Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2)O(1)was synthesized as a 2D structure using Coas the metal source,methanol‑water(4∶6,V/V)as the solvent,and specific concentrations of 2,5‑furandicarboxylic acid(H_(2)FDCA)and 1,3,5‑triimidazole benzene(L).Adjusting to pure water and lowering the concentration of L yielded the 1D chain structure of[Co(HL)2(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(2).Using Cu(Ⅱ)as the metal source,methanol/water(9∶1,V/V)as the solvent,and specific concentrations of L and H2FDCA,the 1D chain structure of[Cu(L)(FDCA)(H_(2)O)]·2H_(2)O(3)was synthesized.Upon increasing the concentrations of L and H2FDCA,and switching the solvent to pure water,the 1D chain structure of[Cu(HL)_(2)(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(4)was obtained.This shows that changing the solvent and ligand concentrations can affect the structural changes of CPs.In addition,the solid‑state photoluminescence of CPs 1‑4 at room temperature was studied,and their morphological changes were observed via scanning electron microscopy.Density functional theory calculations revealed that the negative charge concentrates on the O and N atoms of the ligand,facilitating ligand‑metal ion coordination.CCDC:2403934,1;2403935,2;2403936,3;2403938,4.展开更多
Anthocyanin-rich foliage plants hold important applications in the pharmaceutical industry and the tea sector,beyond their significant ornamental value.These plants also possess biological and ecological importance,co...Anthocyanin-rich foliage plants hold important applications in the pharmaceutical industry and the tea sector,beyond their significant ornamental value.These plants also possess biological and ecological importance,contributing to reproduction,defense against natural enemies,and adaptation to environmental changes.Thus,a deeper understanding of their leaf coloration will be essential for both practical applications and theoretical understanding.The present study comprehensively reviews the factors influencing anthocyanin metabolism,including biosynthesis,transport,degradation,transcription factors(TF_(S)),post-transcriptional regulation,post translation regulation.Next,we summarize the application of omics technologies in unveiling the mechanisms of anthocyanin synthesis in leaves.Furthermore,we review the molecular mechanisms by which environmental factors regulate leaf coloration by inducing anthocyanin biosynthesis.Lastly,the study addresses unresolved issues in the research of plant leaf coloration and proposes future research directions in this field.This study is anticipated to provide a valuable reference for the study of plant leaf coloration.展开更多
基金support provided by the National Natural Science Foundation of China[Grant No.72204202]2025 Annual Research Program of the China Society for Commercial Statistics[Grant No.2025STY10]General Project of Philosophy Society in Jiangsu Province Universities[Grant Nos.2023SJYB0923 and 2025SJYB0708].
文摘Against the backdrop of accelerated development of new forms of trade,the question of whether rapid expansion of cross-border e-commerce(CBEC)can help to reduce carbon emissions among Chinese enterprises is of great significance for seizing new opportunities in foreign trade,and advancing firms’green and low-carbon transformation.This study treats the creation of CBEC pilot zones as a quasi-natural experiment,employing panel data from Chinese A-share listed companies matched with city-level information from 2006 to 2021.We construct a multi-period difference-in-differences model to identify the impact of CBEC pilot zone policy on corporate carbon emissions.Our findings indicate the construction of these pilot zones significantly reduces firms’carbon emissions intensity,and the results are robust across multiple tests.We show the pilot zone initiative contributes to emission reductions by enhancing the adoption of digital infrastructure,promoting green technological innovation,and increasing environmental awareness among enterprises.Quantile regressions reveal pilot zones exert a more pronounced carbon-reduction effect on firms characterized by high carbon emissions intensity and advanced levels of digital transformation.Moreover,the policy effect is especially significant in heavily polluting industries,and regions with weaker governmental environmental regulations or lower public environmental concerns.This study makes an innovative contribution to the literature by empirically verifying the environmental governance effect of establishing CBEC pilot zones,and offers practical guidance for governments in formulating cross-border e-commerce policies and for enterprises pursuing low carbon development.
基金supported by the National Natural Science Foundation of China(32220103006 and 82271524).
文摘Lymphatic vessel networks have been identified in the meninges of mice,non-human primates,and humans[1].Meningeal lymphatic vessels(mLVs),composed of meningeal lymphatic endothelial cells(mLECs),are present in both zebrafish and mammals,although their anatomical distributions differ;they reside in the dura mater in mice,but are situated within the meninges in zebrafish[2].Moreover,the lymphatic marker genes expressed in these vessels differ between species[2].
文摘Cross-border e-commerce,as a new form of international trade,has shown great development potential in the context of the“Belt and Road”initiative.Based on the cross-border e-commerce export data from 2015 to 2024,this paper analyzes the influencing factors of China's cross-border e-commerce exports to countries along the“Belt and Road”by constructing an econometric model.The study found that factors such as the perfection of digital infrastructure,the efficiency of logistics and transportation,the convenience of payment and settlement,and the penetration rate of consumers online shopping significantly affect the export scale of cross-border e-commerce.Institutional factors such as the development level of e-commerce platforms in countries along the route,market access thresholds,and tariff policies also play an important role.Based on the research results,suggestions are put forward to strengthen the construction of cross-border payment system,optimize the logistics distribution network,promote customs clearance facilitation,and deepen cooperation in the field of e-commerce,to provide references for promoting the development of China's crossborder e-commerce exports to countries along the“Belt and Road.”
文摘Taxation,the primary source of fiscal revenue,has profound implications in guiding resource allocation,promoting economic growth,adjusting social wealth distribution,and enhancing cultural influence.The development of e-taxation provides a enhanced security for taxation,but it still faces the risk of inefficiency and tax data leakage.As a decentralized ledger,blockchain provides an effective solution for protecting tax data and avoiding tax-related errors and fraud.The introduction of blockchain into e-taxation protocols can ensure the public verification of taxes.However,balancing taxpayer identity privacy with regulation remains a challenge.In this paper,we propose a blockchain-based anonymous and regulatory e-taxation protocol.This protocol ensures the supervision and tracking of malicious taxpayers while maintaining honest taxpayer identity privacy,reduces the storage needs for public key certificates in the public key infrastructure,and enables selfcertification of taxpayers’public keys and addresses.We formalize the security model of unforgeability for transactions,anonymity for honest taxpayers,and traceability for malicious taxpayers.Security analysis shows that the proposed protocol satisfies unforgeability,anonymity,and traceability.The experimental results of time consumption show that the protocol is feasible in practical applications.
基金supported by the Natural Science Foundation of Sichuan Province(Grant No.:2023NSFSC1783)the National Natural Science Foundation of China(Grant No.:82274372).
文摘Age-related macular degeneration(AMD)represents a predominant cause of blindness among older adults,with limited therapeutic options currently available.Oxidative stress,inflammation,and retinal pigment epithelium injury are recognized as key contributors to the pathogenesis of AMD.Regulated cell death plays a pivotal role in mediating cellular responses to stress,maintaining tissue homeostasis,and contributing to disease progression.Recent research has elucidated several regulated cell death pathwaysdsuch as apoptosis,ferroptosis,pyroptosis,necroptosis,and autophagydthat may contribute to the progression of AMD owing to cell death in the retinal pigment epithelium.These discoveries open new avenues for therapeutic interventions in patients with AMD.In this review,we provide a comprehensive summary and analysis of the latest advancements regarding the relationship between regulated cell death and AMD.Moreover,we examined the therapeutic potential of targeting regulated cell death pathways for the treatment and prevention of AMD,highlighting their roles as promising targets for future therapeutic strategies.
文摘Cross-border e-commerce has emerged as a new growth point in foreign trade.While the Dalian comprehensive pilot zone has made some progress,its development is constrained by issues such as the global economic slowdown,the relatively small scale of cross-border e-commerce,a high concentration of export commodities,imperfect information mechanisms,and high overall costs.To address these challenges,this paper explores the importance of the construction of the Dalian comprehensive pilot zone for cross-border e-commerce to the transformation and upgrading of exports.Based on my research project,“Research on Path Optimization of Financial Support for the Development of Advanced Manufacturing Clusters in Dalian,”this paper analyzes the current challenges and limiting factors and proposes corresponding countermeasures and suggestions.
基金National Natural Science Foundation of China(52261032,51861021,51661016)Science and Technology Plan of Gansu Province(21YF5GA074)+2 种基金Public Welfare Project of Zhejiang Natural Science Foundation(LGG22E010008)Wenzhou Basic Public Welfare Scientific Research Project(G2023020)Incubation Program of Excellent Doctoral Dissertation-Lanzhou University of Technology。
文摘The development of high-performance structural and functional materials is vital in many industrial fields.High-and medium-entropy alloys(H/MEAs)with superior comprehensive properties owing to their specific microstructures are promising candidates for structural materials.More importantly,multitudinous efforts have been made to regulate the microstructures and the properties of H/MEAs to further expand their industrial applications.The various heterostructures have enormous potential for the development of H/MEAs with outstanding performance.Herein,multiple heterogeneous structures with single and hierarchical heterogeneities were discussed in detail.Moreover,preparation methods for compositional inhomogeneity,bimodal structures,dualphase structures,lamella/layered structures,harmonic structures(core-shell),multiscale precipitates and heterostructures coupled with specific microstructures in H/MEAs were also systematically reviewed.The deformation mechanisms induced by the different heterostructures were thoroughly discussed to explore the relationship between the heterostructures and the optimized properties of H/MEAs.The contributions of the heterostructures and advanced microstructures to the H/MEAs were comprehensively elucidated to further improve the properties of the alloys.Finally,this review discussed the future challenges of high-performance H/MEAs for industrial applications and provides feasible methods for optimizing heterostructures to enhance the comprehensive properties of H/MEAs.
文摘Against the backdrop of economic globalization and the rapid growth of cross-border e-commerce,the overseas expansion of smart home products heavily relies on the translation quality of technological elements within marketing copy.This paper focuses on four core technological elements in smart home marketing copy on cross-border e-commerce platforms.Using Skopos Theory as a framework,it analyzes translation difficulties such as inconsistent terminology and imbalance between technical precision and accessibility.It constructs a five-dimensional translation strategy,“Precision+Accessibility+Localization+Structuring+Standardization”,and validates its effectiveness.This provides guidance for enterprises to enhance overseas marketing efficiency and enriches the research value of translation in the cross-border e-commerce vertical field.
基金This paper is a phased result of the“Research on the Issue of China’s Data Export System”(24SFB3035)a research project of the Ministry of Justice of China on the construction of the rule of law and the study of legal theories at the ministerial level in 2024.
文摘The Fourth Industrial Revolution has endowed the concept of state sovereignty with new era-specific connotations,leading to the emergence of the theory of data sovereignty.While countries refine their domestic legislation to establish their data sovereignty,they are also actively engaging in the negotiation of cross-border data flow rules within international trade agreements to construct data sovereignty.During these negotiations,countries express differing regulatory claims,with some focusing on safeguarding sovereignty and protecting human rights,some prioritizing economic promotion and security assurance,and others targeting traditional and innovative digital trade barriers.These varied approaches reflect the tension between three pairs of values:collectivism and individualism,freedom and security,and tradition and innovation.Based on their distinct value pursuits,three representative models of data sovereignty construction have emerged globally.At the current juncture,when international rules for digital trade are still in their nascent stages,China should timely establish its data sovereignty rules,actively participate in global data sovereignty competition,and balance its sovereignty interests with other interests.Specifically,China should explore the scope of system-acceptable digital trade barriers through free trade zones;integrate domestic and international legal frameworks to ensure the alignment of China’s data governance legislation with its obligations under international trade agreements;and use the development of the“Digital Silk Road”as a starting point to prioritize the formation of digital trade rules with countries participating in the Belt and Road Initiative,promoting the Chinese solutions internationally.
文摘Alzheimer's disease,a progressively degenerative neurological disorder,is the most common cause of dementia in the elderly.While its precise etiology remains unclear,researchers have identified diverse pathological characteristics and molecular pathways associated with its progression.Advances in scientific research have increasingly highlighted the crucial role of non-coding RNAs in the progression of Alzheimer's disease.These non-coding RNAs regulate several biological processes critical to the advancement of the disease,offering promising potential as therapeutic targets and diagnostic biomarkers.Therefore,this review aims to investigate the underlying mechanisms of Alzheimer's disease onset,with a particular focus on microRNAs,long non-coding RNAs,and circular RNAs associated with the disease.The review elucidates the potential pathogenic processes of Alzheimer's disease and provides a detailed description of the synthesis mechanisms of the three aforementioned non-coding RNAs.It comprehensively summarizes the various non-coding RNAs that have been identified to play key regulatory roles in Alzheimer's disease,as well as how these noncoding RNAs influence the disease's progression by regulating gene expression and protein functions.For example,miR-9 targets the UBE4B gene,promoting autophagy-mediated degradation of Tau protein,thereby reducing Tau accumulation and delaying Alzheimer's disease progression.Conversely,the long non-coding RNA BACE1-AS stabilizes BACE1 mRNA,promoting the generation of amyloid-βand accelerating Alzheimer's disease development.Additionally,circular RNAs play significant roles in regulating neuroinflammatory responses.By integrating insights from these regulatory mechanisms,there is potential to discover new therapeutic targets and potential biomarkers for early detection and management of Alzheimer's disease.This review aims to enhance the understanding of the relationship between Alzheimer's disease and non-coding RNAs,potentially paving the way for early detection and novel treatment strategies.
基金National Natural Science Foundation of China(52374405)Joint Innovaion Fund Project of Lanzhou Jiaotong University and Corresponding Supporting University(LH2024018)State Key Laboratory Open Project(Q110824Q02001)。
文摘The orientation of precipitates was regulated by an improved twinning-aging-detwinning(TAD)process in Mg-Sn sheets.A structure with specific proportions of dual-precipitates was regulated,significantly enhancing the material’s strength.The formation mechanism of the dual-precipitates was investigated,and the evolution of precipitate orientation was confirmed.A combined SEM,EBSD and TEM method was developed to identify the coupling relationship between complex grain orientation and precipitate orientation.The orientation relationship between precipitates and the matrix could be quantitatively analyzed in the same region.Subsequently,the Orowan model was refined to quantify the strength enhancement effect following the orientation regulation of precipitates.The TAD sample containing dual-precipitates exhibited a 99.1%increase in TYS,equivalent to an increase of 108 MPa,compared to unregulated samples A.According to Orowan calculations,the theoretical strength increment from the three strengthening mechanisms was 113 MPa,closely matching the experimental increment of 108 MPa.Notably,the materials with a specific proportion of the dual-precipitates showed a substantial increase in strength.
文摘Root architecture is crucial for plant survival under drought,yet how water stress signals shape root development has remained unclear.Recently,Roy et al.(Science)revealed that drought-induced accumulation of reactive oxygen species(ROS)in root nuclei triggers the auxin repressor IAA3 to form complexes(multimerization)that enable the recruitment of the co-repressor TOPLESS(TPL),thereby suppressing auxin signaling and blocking lateral root initiation.ROS signaling acts rapidly,within minutes of water deprivation,compared to slower ABA responses,allowing plants to quickly adjust lateral root growth.This discovery reveals a new redoxhormone regulatory mechanism that enables plants to fine-tune root branching during transient drought.Beyond advancing our understanding of adaptive root responses,these insights highlight potential molecular targets for developing crops with improved resilience under water limitation.
基金supported by the Natural Science Foundation of China(Grant Nos.32230097 and 32172512)the Jiangsu Special Fund for Frontier Foundation Research of Carbon Peaking and Carbon Neutralization(Grant No.BK20220005)+1 种基金the Jiangsu Agricultural Science and Technology Innovation Fund[Grant No.CX(20)2023]a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions.
文摘5-Aminolevulinic acid(ALA)is a natural plant growth regulator that promotes plant freezing tolerance.The WRKY family consists of plantspecific transcription factors(TFs)associated with abiotic stress responses.Up to now,whether WRKYs are involved in ALA-induced plant freezing tolerance and the underlying mechanism is not clear.In this study,we found that pretreatment with 50 mg·L^(-1) ALA one week earlier significantly increased the freezing tolerance of nectarine(Prunus persica var.nectarina)pistils with higher antioxidant enzyme activity and osmotic solutes when the floral twigs were stressed by-3℃ for 6 h.ALA also enhanced the expression of PpWRKY18,PpCBF1,PpCOR1,and several genes encoding antioxidant enzymes(such as superoxide dismutase,peroxidase,and catalase)and pyrroline-5-carboxylate synthase(P5CS).When PpWRKY18 was overexpressed in tobacco,the transgenic plants exhibited greater freezing tolerance,which was further promoted by exogenous ALA.Y2H,Pull-down,BiFC,and LCI analyses revealed that PpWRKY18 interacts with PpCBF1,promoting the latter transcriptional activity.Additionally,Y1H experiments showed that PpWRKY18 directly binds to the promoter of PpPOD41 while PpCBF1 binds to the promoters of PpP5CS1 and PpCOR1,activating the target gene expressions.Furthermore,we established a yeast library using the promoter of PpWRKY18 as the bait to screen the upstream regulatory factors.By library screening,Y1H,DLR,and EMSA,we found that PpC3H37,a zinc finger protein,was responsive to chilling and ALA treatment,and as a transcription factor,it activated PpWRKY18 expression by directly binding to the promoter.Taken together,we reveal a regulatory network where ALA induces upregulation of PpC3H37 expression,which positively regulates PpWRKY18 expression.Subsequently,the regulatory pathway diverges into two branches.The first is CBF-dependent,where PpCBF1 interacts with PpWRKY18,binding the promoters of PpP5CS1 and PpCOR1.The second is CBF-independent,where PpWRKY18 directly binds the promoter of PpPOD41 to upregulate the gene expression and increase the antioxidant enzyme activity and freezing tolerance.These findings provide a novel insight of the mechanism of ALA in regulating the cold hardiness of nectarine pistil.
基金Tural Science Foundation of China(No.52274255)the Young Scientists Fund of the National Natural ScienceFoundation of China(No.52404276)+3 种基金Fundamental Re-search Funds for the Central Universities,China(Nos.N2301003,N2201008,N2201004,and N2301025)Liaon-ingRevitalizationTalentsProgram,China(No.XLYC2202028)Postdoctoral Foundation of NortheasternUniversity,Young Elite Scientists Sponsorship Program byChina Association for Science and Technology(No.2022QNRC001)and China Postdoctoral Science Founda-tion(No.2022M720025)。
文摘To advance the precise regulation and high-value utilization of halloysite nanotubes(HNTs),this work systematically investigated five treatment strategies,including calcination,acid treatment,alkali treatment,acid treatment of calcined HNTs,and alkali treatment of calcined HNTs,to modulate their structural and application properties.The structural characteristics,surface properties,and methylene blue(MB)adsorption capacity of HNTs under multiple treatments were systematically analyzed.Calcination at varying temperatures modified the crystal structure,morphology,and surface properties of HNTs,with higher calcination temperatures reducing their reactivity towards MB.Moderate acid treatment expanded the lumen and decreased the surface potential of HNTs,significantly enhancing MB adsorption capacity.In contrast,alkali treatment dispersed the multilayered walls of HNTs and raised surface potential,reducing MB affinity.Acid treatment of calcined HNTs effectively increased their specific surface areas by leaching most of Al while maintaining the tubular structure,thereby maximizing MB adsorption.Alkali treatment of calcined HNTs destroyed the tubular structure and resulted in poor MB adsorption.HNTs pre-calcined at 600℃ for 3 h and acid-treated at 60℃ for 8 h exhibited an optimal specific surface area of443 m^(2)·g^(-1)and an MB adsorption capacity of 190 mg·g^(-1).Kinetic and Arrhenius equation fittings indicated that chemical reactions control interactions of acids and alkalis with HNTs.This study provides a comprehensive comparison and analysis of five treatment methods,offering insights into regulating the structures and surface properties of HNTs by controlling the treatment condition,thereby laying a foundation for their efficient utilization in practical applications.
基金supported by the National Key R&D Program of China(No.2021YFC2103600)the National Natural Science Foundation of China(Nos.21878156,21978131,22275085,and 22278224)+2 种基金the Natural Science Foundation of Jiangsu Province(Nos.BK20200089 and BK20200691)the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)the State Key Laboratory of Materials-Oriented Chemical Engineering(No.KL21-08).
文摘Constructing multi-dimensional hydrogen bond(H-bond)regulated single-molecule systems with multiemission remains a challenge.Herein,we report the design of a new excited-state intramolecular proton transfer(ESIPT)featured chromophore(HBT-DPI)that shows flexible emission tunability via the multidimensional regulation of intra-and intermolecular H-bonds.The feature of switchable intramolecular Hbonds is induced via incorporating several hydrogen bond acceptors and donors into one single HBT-DPI molecule,allowing the“turn on/off”of ESIPT process by forming isomers with distinct intramolecular Hbonds configurations.In response to different external H-bonding environments,the obtained four types of crystal/cocrystals vary in the contents of isomers and the molecular packing modes,which are mainly guided by the intermolecular H-bonds,exhibiting non-emissive features or emissions ranging from green to orange.Utilizing the feature of intermolecular H-bond guided molecular packing,we demonstrate the utility of this fluorescent material for visualizing hydrophobic/hydrophilic areas on large-scale heterogeneous surfaces of modified poly(1,1-difluoroethylene)(PVDF)membranes and quantitatively estimating the surface hydrophobicity,providing a new approach for hydrophobicity/hydrophilicity monitoring and measurement.Overall,this study represents a new design strategy for constructing multi-dimensional hydrogen bond regulated ESIPT-based fluorescent materials that enable multiple emissions and unique applications.
基金supported by the National Natural Science Foundation of China,Nos.32271389,31900987(both to PY)the Natural Science Foundation of Jiangsu Province,No.BK20230608(to JJ)。
文摘Regulatory T cells,a subset of CD4^(+)T cells,play a critical role in maintaining immune tolerance and tissue homeostasis due to their potent immunosuppressive properties.Recent advances in research have highlighted the important therapeutic potential of Tregs in neurological diseases and tissue repair,emphasizing their multifaceted roles in immune regulation.This review aims to summarize and analyze the mechanisms of action and therapeutic potential of Tregs in relation to neurological diseases and neural regeneration.Beyond their classical immune-regulatory functions,emerging evidence points to non-immune mechanisms of regulatory T cells,particularly their interactions with stem cells and other non-immune cells.These interactions contribute to optimizing the repair microenvironment and promoting tissue repair and nerve regeneration,positioning non-immune pathways as a promising direction for future research.By modulating immune and non-immune cells,including neurons and glia within neural tissues,Tregs have demonstrated remarkable efficacy in enhancing regeneration in the central and peripheral nervous systems.Preclinical studies have revealed that Treg cells interact with neurons,glial cells,and other neural components to mitigate inflammatory damage and support functional recovery.Current mechanistic studies show that Tregs can significantly promote neural repair and functional recovery by regulating inflammatory responses and the local immune microenvironment.However,research on the mechanistic roles of regulatory T cells in other diseases remains limited,highlighting substantial gaps and opportunities for exploration in this field.Laboratory and clinical studies have further advanced the application of regulatory T cells.Technical advances have enabled efficient isolation,ex vivo expansion and functionalization,and adoptive transfer of regulatory T cells,with efficacy validated in animal models.Innovative strategies,including gene editing,cell-free technologies,biomaterial-based recruitment,and in situ delivery have expanded the therapeutic potential of regulatory T cells.Gene editing enables precise functional optimization,while biomaterial and in situ delivery technologies enhance their accumulation and efficacy at target sites.These advancements not only improve the immune-regulatory capacity of regulatory T cells but also significantly enhance their role in tissue repair.By leveraging the pivotal and diverse functions of Tregs in immune modulation and tissue repair,regulatory T cells–based therapies may lead to transformative breakthroughs in the treatment of neurological diseases.
基金supported by the Science and Technology Development Project of Jilin Province(Project No.YDZJ202301ZYTS284).
文摘With the increasing penetration of renewable energy,the coordination of energy storage with thermal power for frequency regulation has become an effective means to enhance grid frequency security.Addressing the challenge of improving the frequency regulation performance of a thermal-storage primary frequency regulation system while reducing its associated losses,this paper proposes a multi-dimensional cooperative optimization strategy for the control parameters of a combined thermal-storage system,considering regulation losses.First,the frequency regulation losses of various components within the thermal power unit are quantified,and a calculation method for energy storage regulation loss is proposed,based on Depth of Discharge(DOD)and C-rate.Second,a thermal-storage cooperative control method based on series compensation is developed to improve the system’s frequency regulation performance.Third,targeting system regulation loss cost and regulation output,and considering constraints on output overshoot and system parameters,an improved Particle Swarm Optimization(PSO)algorithm is employed to tune the parameters of the low-pass filter and the series compensator,thereby reducing regulation losses while enhancing performance.Finally,simulation results demonstrate that the total loss cost of the proposed control strategy is comparable to that of a system with only thermal power participation.However,the thermal power loss cost is reduced by 42.16%compared to the thermal-only case,while simultaneously improving system frequency stability.Thus,the proposed strategy effectively balances system frequency stability and economic efficiency.
文摘Four distinct coordination polymers(CPs)were successfully synthesized by altering solvent types and adjusting ligand concentrations,and their crystal structures were investigated.[Co(L)(FDCA)(H_(2)O)_(2)]·0.5H_(2)O(1)was synthesized as a 2D structure using Coas the metal source,methanol‑water(4∶6,V/V)as the solvent,and specific concentrations of 2,5‑furandicarboxylic acid(H_(2)FDCA)and 1,3,5‑triimidazole benzene(L).Adjusting to pure water and lowering the concentration of L yielded the 1D chain structure of[Co(HL)2(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(2).Using Cu(Ⅱ)as the metal source,methanol/water(9∶1,V/V)as the solvent,and specific concentrations of L and H2FDCA,the 1D chain structure of[Cu(L)(FDCA)(H_(2)O)]·2H_(2)O(3)was synthesized.Upon increasing the concentrations of L and H2FDCA,and switching the solvent to pure water,the 1D chain structure of[Cu(HL)_(2)(H_(2)O)_(2)](FDCA)_(2)·6H_(2)O(4)was obtained.This shows that changing the solvent and ligand concentrations can affect the structural changes of CPs.In addition,the solid‑state photoluminescence of CPs 1‑4 at room temperature was studied,and their morphological changes were observed via scanning electron microscopy.Density functional theory calculations revealed that the negative charge concentrates on the O and N atoms of the ligand,facilitating ligand‑metal ion coordination.CCDC:2403934,1;2403935,2;2403936,3;2403938,4.
基金supported by Central Finance for the Forestry Science and Technology Promotion Demonstration Project([2024]TG13)the National Science Foundation of China(Grant No.32201643)the Key research projects of Yibin,Research and Integrated Demonstration and Key Technologies for Smart Bamboo Industry(Grant No.YBZD2024-1).
文摘Anthocyanin-rich foliage plants hold important applications in the pharmaceutical industry and the tea sector,beyond their significant ornamental value.These plants also possess biological and ecological importance,contributing to reproduction,defense against natural enemies,and adaptation to environmental changes.Thus,a deeper understanding of their leaf coloration will be essential for both practical applications and theoretical understanding.The present study comprehensively reviews the factors influencing anthocyanin metabolism,including biosynthesis,transport,degradation,transcription factors(TF_(S)),post-transcriptional regulation,post translation regulation.Next,we summarize the application of omics technologies in unveiling the mechanisms of anthocyanin synthesis in leaves.Furthermore,we review the molecular mechanisms by which environmental factors regulate leaf coloration by inducing anthocyanin biosynthesis.Lastly,the study addresses unresolved issues in the research of plant leaf coloration and proposes future research directions in this field.This study is anticipated to provide a valuable reference for the study of plant leaf coloration.
