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Using crafted features and polar bear optimization algorithm for short-term electric load forecast syste
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作者 Mansi Bhatnagar Gregor Rozinaj Radoslav Vargic 《Energy and AI》 2025年第1期203-217,共15页
Short-term load forecasting(STLF)can be utilized to predict usage fluctuation in a short time period and accurate forecasting can save a big chunk of a country’s economic loss.This paper introduces the crafting of va... Short-term load forecasting(STLF)can be utilized to predict usage fluctuation in a short time period and accurate forecasting can save a big chunk of a country’s economic loss.This paper introduces the crafting of various features for hourly electric load forecasting on three different datasets using four different models XGBoost,LightGBM,Bi-LSTM,and Random Forest.The importance of crafted features over basic features was analysed by different evaluation metrics MAE,RMSE,R-squared,and MAPE.Evaluation metrics showed that prediction accuracy increased significantly with crafted features in comparison to basic features for all four models.We also showcased the ability of the Polar Bear Optimisation(PBO)algorithm for hyperparameter tuning of the machine learning models in STLF.Optimized hyperparameters with PBO effectively decreased RMSE,MAE,and MAPE and improved the model prediction,showcasing the capability of the PBO in hyperparameter tuning for STLF.PBO was compared with commonly used optimization algorithms like particle swarm optimization(PSO)and genetic algorithm(GA).GA was the least performing with XGBoost,LightGBM,and Random Forest.PSO and PBO were comparable with XGBoost LightGBM and Random Forest while PBO highly surpassed PSO with the Bi-LSTM model.Hence PBO was proved to be highly effective for hyperparameter tuning for implementation in short-term electric load forecasting. 展开更多
关键词 Machine learning crafted features Polar bear algorithms Short term load forecast Hyperparameter tunning
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The charm of handcrafted wood carving
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作者 徐静 《疯狂英语(新策略)》 2025年第9期65-65,共1页
I've always been interested in traditional crafts,so when my school organized a workshop on wood carving,an ancient Chinese art form,I signed up right away.The workshop was held in a small studio in the old town.A... I've always been interested in traditional crafts,so when my school organized a workshop on wood carving,an ancient Chinese art form,I signed up right away.The workshop was held in a small studio in the old town.As I walked in,I was greeted by the smell of wood and the sound made by carving wood.The teacher,Mr Zhang,was a master carver with over 30 years of experience.He showed us some of his works-beautiful sculptures of animals and flowers.I was amazed by the skill and patience it must have taken to create them. 展开更多
关键词 skill wood carvingan traditional crafts handcrafted patience carving woodthe Chinese art form wood carving
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CRAFT磁体平台6 kW@4.5 K氦制冷机大型卧式真空绝热冷箱设计与应力分析
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作者 李帅勇 张启勇 +1 位作者 陆小飞 何艺轩 《真空与低温》 2025年第4期428-436,共9页
聚变设施主机关键系统综合研究设施(CRAFT)是国家重大科技基础设施项目,超导磁体研究系统是该设施主要的建设和研究内容之一。为开展全尺寸超导磁体的低温性能测试,设计建设了一套6 kW@4.5 K大型氦制冷机,并对该氦制冷机的卧式真空绝热... 聚变设施主机关键系统综合研究设施(CRAFT)是国家重大科技基础设施项目,超导磁体研究系统是该设施主要的建设和研究内容之一。为开展全尺寸超导磁体的低温性能测试,设计建设了一套6 kW@4.5 K大型氦制冷机,并对该氦制冷机的卧式真空绝热冷箱进行了计算验证。根据氦制冷机的制冷流程及冷箱内各个设备尺寸,完成Φ3.8 m×14.5 m大型卧式冷箱三维模型和结构设计。定义了正常工况,分析了冷箱在正常工况下的应力、质量与壁厚的关系,结合国家标准确定了冷箱壁厚,使用有限元分析法计算得到了冷箱在正常工况下受到的应力和应变情况。定义了吊装工况,计算了冷箱在吊装工况下受到的应力与应变情况。对冷箱进行了模态分析,根据抗震标准,人工生成了一组地震波,最后用响应谱分析的方法模拟计算了复合载荷下冷箱外壳的地震响应。研究结果表明壁厚大小与应力应变大小呈非线性负相关,影响程度递减;地震复合载荷下冷箱径向变形很小,主要是轴向变形;本文设计的卧式真空绝热冷箱在不同情况下的结构强度满足6 kW@4.5 K氦制冷机使用要求。 展开更多
关键词 CRAFT 4.5 K氦制冷机 卧式冷箱 应力分析 地震响应谱
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Rediscovering the Charm of an Old Craft
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作者 LIU CHANG 《China Today》 2025年第7期66-69,共4页
A young artist reinvents an old sartorial skill from rural ethnic communities into globally recognized high fashion.LACKING a unified writing system,the ancestors of the Miao people,an ethnic group primarily living in... A young artist reinvents an old sartorial skill from rural ethnic communities into globally recognized high fashion.LACKING a unified writing system,the ancestors of the Miao people,an ethnic group primarily living in mountainous areas in central and southwestern China,encoded their history in the exquisite design of traditional clothing,especially embroidery.They express reverence for nature and appreciation of life with needles and threads. 展开更多
关键词 young artist reinventing high fashion Miao people traditional clothing needles threads old craft rediscovering
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Strengths use and thriving at work: The role of job crafting and job embeddedness
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作者 Zhong Li Xia Wang +1 位作者 Xixi Chu Run Guo 《Journal of Psychology in Africa》 2025年第2期173-178,共6页
This study explored the role of job crafting and job embeddedness in the relationship between employee strengths use and thriving at work.Participants were 260 nurses from Beijing,China(99.2%female,54.6%aged 26–35 ye... This study explored the role of job crafting and job embeddedness in the relationship between employee strengths use and thriving at work.Participants were 260 nurses from Beijing,China(99.2%female,54.6%aged 26–35 years,and 62%with a bachelor’s degree or above).Data were collected at two different time points,with a two-week interval between them.Regression analysis and path analysis were applied to test the hypotheses.Results showed that strengths use was associated with thriving at work.Job crafting partially mediated this relationship for higher thriving at work.Job embeddedness weakened the relationship between strengths use and job crafting,and also lowered job crafting effects on work thriving.These findings provide insights into the mechanisms by which strengths use influences thriving at work,highlighting the significance of job crafting and job embeddedness. 展开更多
关键词 strengths use job embeddedness job crafting thriving at work
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Six-Degree-of-Freedom Motion Analysis of High-Speed Craft Navigating through Variable Marine Environments
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作者 Xiaoyang Wu Wenchao Han +2 位作者 Min Kuang Xinqi Wang Wenhao Xie 《Fluid Dynamics & Materials Processing》 2025年第9期2201-2223,共23页
The dynamic behavior of high-speed craft navigating through variable sea states plays a pivotal role in ensuring maritime safety.However,many existing simulation approaches rely on linear or overly simplified represen... The dynamic behavior of high-speed craft navigating through variable sea states plays a pivotal role in ensuring maritime safety.However,many existing simulation approaches rely on linear or overly simplified representations of the marine environment,thereby limiting the fidelity of motion predictions.This study explores the motion characteristics of a 4.5-t high-speed vessel by conducting fully coupled numerical simulations using the STAR-CCM+software.The analysis considers both calm and varying sea conditions,incorporating fluctuations in wave height,wavelength,and wind speed to reflect more realistic operating scenarios.Simulation results reveal that the vessel’s hydrodynamic response is highly sensitive to changes in sea state.As conditions deteriorate,the free surface becomes increasingly complex,with higher wave amplitudes and more pronounced interactions between the waves generated by the vessel and those imposed by the external environment.These effects lead to significant increases in roll,pitch,heave,and sway motions,thereby imposing greater demands on the vessel’s dynamic stability and operational safety.Furthermore,both hydrodynamic resistance and propulsive thrust exhibit notable dependence on sea state and vessel speed.Total resistance generally increases with rougher sea conditions,while thrust tends to rise with increasing forward speed.Under calm or mildly disturbed waters,a Froude number(Fr)of 0.5 appears to offer an optimal balance for initiating and controlling primary motions such as roll,pitch,heave,and sway.Conversely,in more challenging conditions-such as those represented by a Sea State 3-effective motion control is better achieved at a higher Froude number of approximately 1.0. 展开更多
关键词 High-speed craft sea conditions six degrees of freedom free navigation
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Review of the“New Crafts”International Exhibition of Arts and Crafts:Focusing on an Integrated Innovation Perspective
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作者 Ji Dong 《Journal of Contemporary Educational Research》 2025年第3期55-60,共6页
This article explores the transformative process of the philosophical concepts in new craft arts,along with the interactive relationship between technological logic and cultural expression,within the context of digita... This article explores the transformative process of the philosophical concepts in new craft arts,along with the interactive relationship between technological logic and cultural expression,within the context of digital intelligence empowerment.Through an analysis of specific artworks,it aims to reveal the potential value of digital intelligence technologies in shaping contemporary craft arts,particularly in terms of artistic expression,cultural heritage,and social responsibility. 展开更多
关键词 Traditional craft innovation Academic exhibition Integrated innovation
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超临界氦循环泵隔热结构热设计及热沉位置的热分析
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作者 朱迎秋 张子健 +1 位作者 张启勇 成安义 《真空与低温》 2025年第1期74-79,共6页
聚变堆主机关键系统综合研究设施(Comprehensive Research Facility for Fusion Technology,CRAFT)超临界氦阀箱内的超临界氦循环泵为超导磁体提供大流量超临界氦,根据功能要求对超临界氦泵体的隔热区域进行了隔热设计。确定了氦循环泵... 聚变堆主机关键系统综合研究设施(Comprehensive Research Facility for Fusion Technology,CRAFT)超临界氦阀箱内的超临界氦循环泵为超导磁体提供大流量超临界氦,根据功能要求对超临界氦泵体的隔热区域进行了隔热设计。确定了氦循环泵的隔热结构,计算分析了热沉位置范围,对氦循环泵的漏热量进行了核算;采用仿真软件ANSYS,数值分析了氦循环泵的隔热性能和热沉位置对泵体漏热的影响,结果显示热沉位置H为0.064 m时,可保证液氦质量流量,泵体漏热达到最小值8.71 W,满足此值小于10 W的指标要求。 展开更多
关键词 CRAFT超导磁体平台 超临界氦泵 隔热结构 热沉
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CRAFT TF线圈匝间绝缘包绕机运动控制
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作者 何建 吴杰峰 +3 位作者 文伟 闫朝辉 武玉 文军 《核聚变与等离子体物理》 CAS CSCD 北大核心 2024年第4期444-449,共6页
根据CRAFTTF线圈的尺寸、绝缘结构、恒节距和恒张力包绕的要求,建立了单匝导体D形螺旋线方程。针对包绕机沿导体运动的匀速控制,在传统三相永磁同步电机(PMSM)矢量控制的基础上,设计了自适应神经模糊推理控制器(ANFIC),并对包绕机的运... 根据CRAFTTF线圈的尺寸、绝缘结构、恒节距和恒张力包绕的要求,建立了单匝导体D形螺旋线方程。针对包绕机沿导体运动的匀速控制,在传统三相永磁同步电机(PMSM)矢量控制的基础上,设计了自适应神经模糊推理控制器(ANFIC),并对包绕机的运动控制进行了优化仿真。结果表明,使用ANFIC的三相PMSM具有更好的转速和转矩的跟随性,同时三相电流波动较小,为CRAFT TF线圈匝间绝缘包绕系统的调试与优化提供参考。 展开更多
关键词 CRAFT TF线圈 包绕机 自适应神经模糊推理
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NNBI加速极电源控制系统分析与设计
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作者 王邓辉 冯虎林 何宝灿 《电工技术》 2024年第16期4-7,11,共5页
聚变堆主机关键系统综合研究设施(Comprehensive Research Facility for Fusion Technology,CRAFT)负离子源中性束注入(Negative Neutral Beam Injection,NNBI)电源首次采用逆变型整流方案,但离子源的时变、非线性及高可控等负荷特征给... 聚变堆主机关键系统综合研究设施(Comprehensive Research Facility for Fusion Technology,CRAFT)负离子源中性束注入(Negative Neutral Beam Injection,NNBI)电源首次采用逆变型整流方案,但离子源的时变、非线性及高可控等负荷特征给电源电压和纹波控制带来了挑战。采用傅里叶变换分析逆变型直流高压电源拓扑,针对低频开关信号,提出一种新的逆变型直流高压电源传递函数分析方法以快速建立系统近似模型。通过PWM方式控制逆变器开关管占空比,相控整流控制直流母线电压,实现系统输出电压闭环控制以及提升纹波抑制能力,并设计1200 V/5 A实验测试平台验证控制方法的有效性。 展开更多
关键词 CRAFT NNBI加速极电源 逆变型直流电源 闭环控制 傅里叶变换
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Ethnocultural heritage of the North-Eastern Caucasus as a factor of eco-tourism development
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作者 Zaburaeva Khava Sh. 《Journal of Mountain Science》 SCIE CSCD 2024年第8期2810-2824,共15页
The North-East Caucasus is a multi-ethnic mountain macroregion with a rich cultural heritage,insufficiently studied in the context of the ecotourism development.To fill this gap and identify promising directions of en... The North-East Caucasus is a multi-ethnic mountain macroregion with a rich cultural heritage,insufficiently studied in the context of the ecotourism development.To fill this gap and identify promising directions of environmentally safe forms of tourism,the author used in-depth review of modern literature to investigate the features of ecological tourism and the problems of preserving ethno-cultural heritage,and used historical and comparative-geographical methods to analyze the development of the tangible and intangible cultural heritage of the indigenous peoples of the North-Eastern Caucasus in different historical periods and to identify the geographical peculiarities of the distribution of historical and cultural monuments(tower buildings),pilgrimage sites and centers of traditional crafts and trades.As part of the planned expeditions,the author personally visited some historical monuments and handicraft centers for a deeper study of ethno-cultural heritage.The cartographic method made it possible to visualize the results.The results of the research show that the ethnocultural heritage of the North-East Caucasus is formed by material(historical and cultural monuments)and immaterial elements of culture(language,customs,traditions,ethnic identification)of those peoples,who live here.The ethnocultural heritage is considered as the most important factor in the development of the tourism industry.It is revealed that this region has a large potential for development in various areas of eco-tourism.The highest concentration of religious buildings focused in mountainous areas.Medieval tower structures were erected in mountainous and high-altitude areas.From ancient times to the present day there have been preserved various types of crafts and trades(pottery,metalworking,burka making,jewelry making,carpet weaving,gold embroidery,wood and stone carving,etc.),which can become objects of ecotourism.The ethnocultural heritage of the North-East Caucasus needs to be preserved and protected.To solve this problem,the author recommends to focus on a balanced combination of traditions and innovations in this industry,also considering the current state and development of the tourism industry in the country and in the world.The research highlights that the development of scientific approaches to plan and manage tourism development can contribute to the preservation of tangible and intangible cultural heritage of indigenous peoples.This is a complex and labour-intensive task,but its solution will have a multiplier effect in the social sphere,in economic development and in environmental security,which is in line with the principles and concept of sustainable development. 展开更多
关键词 Mountainous districts Sustainable development Prospects Stone Towers Folk crafts
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Analysis and verification of electrodynamic force,thermal stress and current sharing for CRAFT converter structure design
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作者 王重马 石朝毅 +6 位作者 张秀青 卢文武 张胜 高先和 许涛 邵兴星 黄连生 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第8期104-111,共8页
In the design realm of fusion power supplies,structural components play a pivotal role in ensuring the safety of fusion devices.To verify the reliability of the converter structure design at the Comprehensive Research... In the design realm of fusion power supplies,structural components play a pivotal role in ensuring the safety of fusion devices.To verify the reliability of the converter structure design at the Comprehensive Research Facility for Fusion Technology(CRAFT),meticulous analysis of the converter's dynamic impact is carefully performed based on the worst fault current(400k A),firstly.Subsequently,the thermal stress analysis based on the maximum allowable steadystate temperature is finished,and the equivalent thermal stress,thermal deformation,maximum shear stress of a single bridge arm and the whole converter are studied.Furthermore,a simple research method involving the current-sharing characteristics of a bridge arm with multithyristor parallel connection is proposed using a combination of Simplorer with Q3D in ANSYS.The results show that the current-sharing characteristics are excellent.Finally,the structural design has been meticulously tailored to meet the established requirements. 展开更多
关键词 electrodynamic analysis thermal stress current-sharing characteristics CRAFT
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CRAFT背场线圈磁体及杜瓦的力学特性分析
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作者 李晨阳 许爱华 +2 位作者 韩厚祥 赵海阔 汪献伟 《低温与超导》 CAS 北大核心 2024年第2期32-39,共8页
背场线圈和杜瓦对CRAFT系统的运行具有重要影响。为了确保系统运行的稳定性,本文基于无力矩理论、线性振动理论和随机振动理论并采用有限元法,对杜瓦和背场线圈的静力学特性、模态响应和随机振动特性进行了研究,研究结果表明磁体系统在... 背场线圈和杜瓦对CRAFT系统的运行具有重要影响。为了确保系统运行的稳定性,本文基于无力矩理论、线性振动理论和随机振动理论并采用有限元法,对杜瓦和背场线圈的静力学特性、模态响应和随机振动特性进行了研究,研究结果表明磁体系统在地震载荷的冲击下将会产生较大的变形。为此,以磁体及杜瓦的变形为优化目标,采用优化设计方法对磁体及杜瓦在不同载荷下的响应进行研究,从而获得最优设计方案。该研究工作将为后续超导磁体测试平台的加工制造以及抗震优化设计提供理论指导。 展开更多
关键词 CRAFT 背场线圈 杜瓦 地震分析
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Ship Propeller Rotation Threshold to Prevent Erosion and Sedimentation in Coastal Waters
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作者 Abdul Kadir I.Istadi +9 位作者 Agus Subagio I.Iskendar W.Waluyo Abdul Muis Dewi Kartikasari Siti Sadiah A.B Widagdo M.P Helios Mochammad Nasir N.Nurhadi 《哈尔滨工程大学学报(英文版)》 CSCD 2024年第4期798-811,共14页
The rotation of a ship’s propeller can accelerate the water flow around it,which puts pressure on seabed particles.Continuous pressure on the seabed can significantly trigger erosion and sedimentation of coastal wate... The rotation of a ship’s propeller can accelerate the water flow around it,which puts pressure on seabed particles.Continuous pressure on the seabed can significantly trigger erosion and sedimentation of coastal waters.Considering the impact that can be caused,the ship’s propeller rotation limit needs to be determined to avoid damage to the aquatic ecosystem.This research determines the threshold of ship propeller rotation based on the water flow velocity characteristic.Research has been carried out at the Hydrodynamics Laboratory on several variations of propeller rotation R_(rmp)(r/min)and water depth using empirical approaches,numerical simulations,and scale model experiments.Analysis based on general standard criteria for erosion and sedimentation shows that a propeller with a diameter(D_(p))of 1.5 m is safe for propeller rotation at 25 r/min at all water depths.Then,the propeller rotation of 75 r/min is safe for a distance between the propeller axis and the bottom of the water equal to D_(p).Meanwhile,rotation at 120 r/min is safe at a minimum distance of 1.5 D_(p),and 230 r/min is safe for a minimum distance of 2.0 D_(p).The propeller rotation threshold criteria are essential to determining the new under-keel clearance for environmentally friendly ship operations.Threshold values vary based on seabed particle type and water depth. 展开更多
关键词 Landing craft tank Water flow velocity Seabed erosion Under keel clearance
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Stay on board——revised safety standard for small craft: EN ISO 15085:2024
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《China Standardization》 2024年第S1期47-47,共1页
A critical update in the world of small craft safety was introduced with the release of EN ISO 15085:2024,focusing on preventing man-overboard accidents and providing solutions for reboarding.Developed by ISO/TC 188,S... A critical update in the world of small craft safety was introduced with the release of EN ISO 15085:2024,focusing on preventing man-overboard accidents and providing solutions for reboarding.Developed by ISO/TC 188,Small craft,mirrored at the European level by CEN/TC 464,this standard sets out detailed requirements to enhance the safety of small craft,providing a safer environment for users and reducing risks of falling in the water. 展开更多
关键词 MIRROR CRAFT SAFETY
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Li brocade stitches together history and elegance
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作者 戴家妹 《疯狂英语(新悦读)》 2024年第10期52-53,78,共3页
Activity 1.Think about the following questions and write down your answers before reading the text.1.Do you know any traditional crafts?2.How can young people be encouraged to learn traditional crafts?
关键词 CRAFT encouraged WRITE
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Evolution of Handicraft Industries in the Textile Sector in Saudi Arabia: A Comprehensive Analysis of Trends and Innovations
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作者 Mona A. Alfawaz 《Journal of Textile Science and Technology》 2024年第3期82-100,共19页
This review explores the evolution of the textile handicraft industry in Saudi Arabia, emphasizing its cultural and economic significance. The study highlights the transition from traditional practices to modern innov... This review explores the evolution of the textile handicraft industry in Saudi Arabia, emphasizing its cultural and economic significance. The study highlights the transition from traditional practices to modern innovations and examines the impact of globalization and technological advancements on the industry. Key innovations are discussed, demonstrating their role in enhancing textile production while preserving cultural heritage. Major challenges, such as competition from industrial textiles and the need for sustainable practices, are identified. Opportunities for growth are explored, including leveraging tourism and international markets to promote Saudi handicrafts. The social and cultural impacts of the sector are underscored, particularly in sustaining community traditions and providing economic opportunities for artisans. Strategic recommendations for supporting and advancing the industry are offered, ensuring its continued relevance and sustainability in a rapidly changing global market. This analysis provides a robust framework for understanding the current state and future potential of Saudi Arabia’s textile handicraft industry. 展开更多
关键词 Handicraft Industries Textile Sector Saudi Arabia Cultural Heritage Traditional Crafts Modern Technology Sustainability Global Market Innovation Artisanal Products
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Research on the Integration of Batik Technology as Intangible Cultural Heritage and Cultural Tourism--Example of Miao People in Guizhou,China
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作者 Lilin Pan Sharul Azim Bin Sharudin 《Journal of Sustainable Business and Economics》 2024年第4期39-43,共5页
Miao batik in Guizhou region of China has a long history,and the batik process is also a kind of inheritance of intangible cultural heritage,which contains the longing and pursuit of the minority people for a better l... Miao batik in Guizhou region of China has a long history,and the batik process is also a kind of inheritance of intangible cultural heritage,which contains the longing and pursuit of the minority people for a better life,and it is an indispensable treasure of the national folk culture,which is deeply loved by the people for its unique form showing its own unique value.At the same time,batik has become an important tourism resource to attract consumption because of its exquisite pattern modelling,iconic colour effect and deep cultural connotation. 展开更多
关键词 Miao batik Craft symbols Cultural heritage Culture and tourism integration
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路易斯酸用量对POE/PS间Friedel-Crafts烷基化反应及共混物力学性能的影响 被引量:13
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作者 徐建平 承民联 +2 位作者 龚方红 刘建忠 陈建定 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2006年第6期145-148,共4页
用IR,DSC,GPC研究了聚苯乙烯(PS)与聚烯烃弹性体(POE)大分子之间的F riede l-crafts烷基化反应。结果表明:在无水A lC l3催化作用下,PS与POE间可发生质子取代反应生成接枝共聚物POE-g-PS,其接枝百分比随A lC l3用量增加先上升后下降;过... 用IR,DSC,GPC研究了聚苯乙烯(PS)与聚烯烃弹性体(POE)大分子之间的F riede l-crafts烷基化反应。结果表明:在无水A lC l3催化作用下,PS与POE间可发生质子取代反应生成接枝共聚物POE-g-PS,其接枝百分比随A lC l3用量增加先上升后下降;过量的催化剂会导致聚合物降解;接枝共聚物对POE/PS共混物具有明显的就地增容作用,对于POE/PS/A lC l3=50/50/0.2(质量比)共混物,其拉伸强度与简单共混体系相比,提高了4倍,断裂伸长率提高了10倍。 展开更多
关键词 聚烯烃弹性体(POE) 聚苯乙烯(PS) Friedel—crafts烷基化反应 就地增容
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2-羟基-4-甲氧基-3′-氨基二苯甲酮与其烷基化物合成研究 被引量:5
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作者 孙岩峰 宫国梁 +1 位作者 盛学斌 赵德丰 《大连理工大学学报》 EI CAS CSCD 北大核心 2006年第6期792-796,共5页
以间苯二甲醚(1)与间硝基苯甲酰氯(2)为原料,经F riede l-C rafts反应得到2-羟基-4-甲氧基-3′-硝基二苯甲酮(3).以CH2C l2为溶剂,40℃,回流反应3 h,n(A lC l3)∶n(间苯二甲醚)∶n(间硝基苯甲酰氯)=3∶1.1∶1时,产品的收率为71.8%.化合... 以间苯二甲醚(1)与间硝基苯甲酰氯(2)为原料,经F riede l-C rafts反应得到2-羟基-4-甲氧基-3′-硝基二苯甲酮(3).以CH2C l2为溶剂,40℃,回流反应3 h,n(A lC l3)∶n(间苯二甲醚)∶n(间硝基苯甲酰氯)=3∶1.1∶1时,产品的收率为71.8%.化合物3用5%Pd/C催化氢化得到对应的氨基物4,收率为90.2%.最后,用对甲基苯磺酸酯做烷基化试剂,又得到化合物4的单烷基化产物(91.4%)与双烷基化产物(88.9%).利用IR、1H NM R及M S等手段对合成的最终产物及一些关键中间体进行了结构表征,结果正确. 展开更多
关键词 Friedel—Crafts反应 二苯甲酮 紫外吸收剂 染料中间体
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