Addition of N-heterocyclic carbenes(L=1,3-di-tert-butylimidazol-2-ylidene(ItBu),1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene(IiPr_(2)Me_(2)),1,3-mesitylimidazol-2-yildene(IMes)and 1,3-di-(2,6-di-isopropylphenyl)im...Addition of N-heterocyclic carbenes(L=1,3-di-tert-butylimidazol-2-ylidene(ItBu),1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene(IiPr_(2)Me_(2)),1,3-mesitylimidazol-2-yildene(IMes)and 1,3-di-(2,6-di-isopropylphenyl)imidazol-2-yildene(IPr))to the iron half-sandwich complex[Cp’FeI]_(2)(Cp’=η^(5)-1,2,4-(Me_(3)C)_(3)C_(5)H_(2),1)forms the neutral,16VE adducts[Cp’FeI(L)](2–5)in moderate to excellent yields.These complexes were structurally characterised.展开更多
基金the financial support by the Deutsche Forschungsgemeinschaft(DFG)through the Emmy-Noether and the Heisenberg program(WA 2513/2 and WA 2513/6,respectively)。
文摘Addition of N-heterocyclic carbenes(L=1,3-di-tert-butylimidazol-2-ylidene(ItBu),1,3-di-iso-propyl-4,5-dimethylimidazol-2-yildene(IiPr_(2)Me_(2)),1,3-mesitylimidazol-2-yildene(IMes)and 1,3-di-(2,6-di-isopropylphenyl)imidazol-2-yildene(IPr))to the iron half-sandwich complex[Cp’FeI]_(2)(Cp’=η^(5)-1,2,4-(Me_(3)C)_(3)C_(5)H_(2),1)forms the neutral,16VE adducts[Cp’FeI(L)](2–5)in moderate to excellent yields.These complexes were structurally characterised.
