In this work,we develop an extended dissipaton theory that generalizes the environmental couplings beyond the conventional linear and quadratic forms,enabling the treatment of ar-bitrary order of bath couplings.Ap-ply...In this work,we develop an extended dissipaton theory that generalizes the environmental couplings beyond the conventional linear and quadratic forms,enabling the treatment of ar-bitrary order of bath couplings.Ap-plying this theoretical framework to the condensed-phase non-Condon spectroscopy,we demonstrate the in-terplay of anharmonicity,non-Con-don and solvent effects on optical spectra,where the higher-order cou-plings arise from the anharmonicity of nuclear potential surface of the excited state.Precise simulations are carried out with high efficiency on linear absorption spectra involving the above mentioned correlated effects.We exhibit how an anharmonic potential modulates the vibronic feature,offering insights into the role of nonlinear environmental couplings in spectroscopic signatures and exemplifying the success of the extended dissipaton formalism as an exact and efficient method for higher-or-der bath couplings.展开更多
Gold,unlike other transition metals such as Pd,Ni,and Cu,offers unique reactivity profiles and has emerged as an attractive area of research in organic chemistry over the last two decades.Initially,gold catalysts were...Gold,unlike other transition metals such as Pd,Ni,and Cu,offers unique reactivity profiles and has emerged as an attractive area of research in organic chemistry over the last two decades.Initially,gold catalysts were widely used for theπ-activation of unsaturated carbon−carbon bonds,particularly alkynes.Moreover,they exhibit favorable functional-group compatibility,good biocompatibility,and,generally,gold-catalyzed reactions are not sensitive to air or water.展开更多
This study employs Principal Component Analysis(PCA)and 13 years of SD-WACCM-X model data(2007-2019)to investigate the characteristics and mechanisms of Inter-hemispheric Coupling(IHC)triggered by sudden stratospheric...This study employs Principal Component Analysis(PCA)and 13 years of SD-WACCM-X model data(2007-2019)to investigate the characteristics and mechanisms of Inter-hemispheric Coupling(IHC)triggered by sudden stratospheric warming(SSW)events.IHC in both hemispheres leads to a cold anomaly in the equatorial stratosphere,a warm anomaly in the equatorial mesosphere,and increased temperatures in the mesosphere and lower thermosphere(MLT)region of the summer hemisphere.However,the IHC features during boreal winter period are significantly weaker than during the austral winter period,primarily due to weaker stationary planetary wave activity in the Southern Hemisphere(SH).During the austral winter period,IHC results in a warm anomaly in the polar mesosphere of the SH,which does not occur in the NH during boreal winter period.This study also examines the possible influence of quasi-two-day waves(QTDWs)on IHC.We found that the largest temperature anomaly in the summer polar MLT region is associated with a large wind instability area,and a well-developed critical layer structure of QTDW in January.In contrast,during July,despite favorable conditions for QTDW propagation in the Northern Hemisphere,weaker IHC response is observed,suggesting that IHC features and the relationship with QTDWs during July would be more complex than during January.展开更多
随着分布式电源渗透率不断上升,多扰动耦合效应持续增强,新型配电网稳定性分析以及优化运行面临着巨大的挑战。对此,该文依据新型配电网节点电压方程建立多扰动耦合等值电路,并基于多扰动耦合等值电路的潮流可解性提出耦合电压稳定约束(...随着分布式电源渗透率不断上升,多扰动耦合效应持续增强,新型配电网稳定性分析以及优化运行面临着巨大的挑战。对此,该文依据新型配电网节点电压方程建立多扰动耦合等值电路,并基于多扰动耦合等值电路的潮流可解性提出耦合电压稳定约束(coupling voltage stability constraint,CVSC),以实现多扰动耦合影响下的电压稳定性量化约束;同时,通过Bonferroni不等式将CVSC和联合机会约束结合,提出耦合电压稳定联合机会约束(coupling voltage stability joint chance constraint,CVS-JCC);进一步,对CVS-JCC进行确定性转化,得到CVS-JCC的解析表达式,并提出考虑CVS-JCC的配电网优化运行方法,以提高配电网安全、稳定、经济运行能力;最后,通过浙江台州某配电网模型进行仿真实验,证明CVS-JCC的有效性以及不同场景下优化运行方法的先进性。展开更多
基金supported by the National Natural Sci-ence Foundation of China(Nos.22373091,224B2305,and 22573099).
文摘In this work,we develop an extended dissipaton theory that generalizes the environmental couplings beyond the conventional linear and quadratic forms,enabling the treatment of ar-bitrary order of bath couplings.Ap-plying this theoretical framework to the condensed-phase non-Condon spectroscopy,we demonstrate the in-terplay of anharmonicity,non-Con-don and solvent effects on optical spectra,where the higher-order cou-plings arise from the anharmonicity of nuclear potential surface of the excited state.Precise simulations are carried out with high efficiency on linear absorption spectra involving the above mentioned correlated effects.We exhibit how an anharmonic potential modulates the vibronic feature,offering insights into the role of nonlinear environmental couplings in spectroscopic signatures and exemplifying the success of the extended dissipaton formalism as an exact and efficient method for higher-or-der bath couplings.
文摘Gold,unlike other transition metals such as Pd,Ni,and Cu,offers unique reactivity profiles and has emerged as an attractive area of research in organic chemistry over the last two decades.Initially,gold catalysts were widely used for theπ-activation of unsaturated carbon−carbon bonds,particularly alkynes.Moreover,they exhibit favorable functional-group compatibility,good biocompatibility,and,generally,gold-catalyzed reactions are not sensitive to air or water.
基金supported by the National Natural Science Foundation of China(Grant Numbers 42374195 and 42188101)the fellowship of China National Postdoctoral Program for Innovative Talents(Grant Number BX20230273)+1 种基金the Hubei Provincial Natural Science Foundation of China(Grant Number 2024AFB-097)the Postdoctor Project of Hubei Province(Grant Number 2024HBBHCXA054).
文摘This study employs Principal Component Analysis(PCA)and 13 years of SD-WACCM-X model data(2007-2019)to investigate the characteristics and mechanisms of Inter-hemispheric Coupling(IHC)triggered by sudden stratospheric warming(SSW)events.IHC in both hemispheres leads to a cold anomaly in the equatorial stratosphere,a warm anomaly in the equatorial mesosphere,and increased temperatures in the mesosphere and lower thermosphere(MLT)region of the summer hemisphere.However,the IHC features during boreal winter period are significantly weaker than during the austral winter period,primarily due to weaker stationary planetary wave activity in the Southern Hemisphere(SH).During the austral winter period,IHC results in a warm anomaly in the polar mesosphere of the SH,which does not occur in the NH during boreal winter period.This study also examines the possible influence of quasi-two-day waves(QTDWs)on IHC.We found that the largest temperature anomaly in the summer polar MLT region is associated with a large wind instability area,and a well-developed critical layer structure of QTDW in January.In contrast,during July,despite favorable conditions for QTDW propagation in the Northern Hemisphere,weaker IHC response is observed,suggesting that IHC features and the relationship with QTDWs during July would be more complex than during January.
文摘随着分布式电源渗透率不断上升,多扰动耦合效应持续增强,新型配电网稳定性分析以及优化运行面临着巨大的挑战。对此,该文依据新型配电网节点电压方程建立多扰动耦合等值电路,并基于多扰动耦合等值电路的潮流可解性提出耦合电压稳定约束(coupling voltage stability constraint,CVSC),以实现多扰动耦合影响下的电压稳定性量化约束;同时,通过Bonferroni不等式将CVSC和联合机会约束结合,提出耦合电压稳定联合机会约束(coupling voltage stability joint chance constraint,CVS-JCC);进一步,对CVS-JCC进行确定性转化,得到CVS-JCC的解析表达式,并提出考虑CVS-JCC的配电网优化运行方法,以提高配电网安全、稳定、经济运行能力;最后,通过浙江台州某配电网模型进行仿真实验,证明CVS-JCC的有效性以及不同场景下优化运行方法的先进性。
