Using rolling-ploughing-extrusion compound processing methods,a 3D integral-fin structure on outside surface of red copper tube with diameter of 16.0 mm and wall thickness of 1.5 mm was obtained. When both rolling dep...Using rolling-ploughing-extrusion compound processing methods,a 3D integral-fin structure on outside surface of red copper tube with diameter of 16.0 mm and wall thickness of 1.5 mm was obtained. When both rolling depth and ploughing-extrusion(P-E) depth were 0.2 mm,rotating speed was 50 r/min,feed speed was 0.16 mm/r,3D fin structures with height of 0.25 mm were gotten. Two different fin structures were obtained in grooves formed with rolling-ploughing-extrusion compound forming technology and observed by scanning electron microscope(SEM). One is the compound structure with V-shaped groove and U-shaped groove,and the other is the single structure with V-shaped grooves. Two kinds of groove structures obtained by rolling processing and ploughing extrusion processing are restricted together by groove interval and rolling depth,and pitch and P-E depth,respectively. Based on the analysis of interaction of rolling and P-E processing,it is found from the result that the outside 3D integral-fin can be achieved by rolling-ploughing-extrusion compound processing when single V-shaped groove structures are formed by both rolling and P-E processing.展开更多
The unusual anodic peak emerging on negative potential scan for copper in concentrated NaOH media was investigated by X ray diffraction, X ray photoelectron spectroscopy techniques, potentiodynamic scan, galvanostatic...The unusual anodic peak emerging on negative potential scan for copper in concentrated NaOH media was investigated by X ray diffraction, X ray photoelectron spectroscopy techniques, potentiodynamic scan, galvanostatic reduction and fast triangular voltage methods. The results show that CuO is formed on the electrode at potentials above this unusual peak A 2,3 , but also produced at peak A 2,3 when copper has been beforehand anodized at high potentials. Longer pre oxidation time and higher pre oxidation potential are advantageous to the formation of CuO at peak A 2,3 . It is presented that the pent up growth of oxide layer in the high potential region occurs at the interface between metal and oxide by the field assisted migration of O 2- ions to electrode, and when potential negatively shifts to the range of peak A 2,3 , the O 2- (or cation vacancies) accumulated in the film could move towards the solution and combine with Cu 2+ ions at the interface between oxide and solution.[展开更多
The mechanism of pre roll ploughing for 3D fins on the outside surface of copper tube was studied systematically, and especially the process and conditions of 3D fin formation were analyzed. The right mathematical mod...The mechanism of pre roll ploughing for 3D fins on the outside surface of copper tube was studied systematically, and especially the process and conditions of 3D fin formation were analyzed. The right mathematical model was also established. Based on the volume of fin ploughed out is equal to the volume of the metal extruded up by the extruding face of the tool, the relations between fin height, pre roll ploughing feed and pre roll ploughing depth have been achieved. With the increase of pre roll ploughing depth which must be equal to groove depth, the fin height gradually becomes larger. There are different critical feeds with the various depths of pre roll ploughing. The pre roll ploughing feed is the critical one, the height of fin is largest. And when the feed is above the critical one, the fin height will reduce with the increase of feed. The theoretical analysis basically accords with experimental results.展开更多
Recovery of carbon monoxide from flue gases by selective absorption of carbon monoxide in an imidazolium chlorocuprate（l） ionic liquid is considered in this work as an alternative to the use of molecular volatile so...Recovery of carbon monoxide from flue gases by selective absorption of carbon monoxide in an imidazolium chlorocuprate（l） ionic liquid is considered in this work as an alternative to the use of molecular volatile solvents such as aromatic hydrocarbons. The present work evaluates the CO mass transfer rates from the gas phase to the ionic liquid solutions in the absence of chemical reaction. To that end, carbon dioxide was employed as an inert model gas and absorption experiments were performed to assess the influence of different process variables in a batch reactor with fiat gas-liquid interface. The experimental mass transfer coefficients showed significant var- iation with temperature, （3.4-10.9） × 10^-7 m·s^-1 between 293 and 313 K; stirring speed, （10.2- 33.1）× 10^-7 m.s 1 between 100 and 300 r·min^-1; and concentration of copper（1）, （6.6-10.2） × 10^-7 m·s^-1 between 0.25 and 2 mol· L^- 1. In addition, the mass transfer coefficients were eventually found to follow a poten- tial proportionality of the type kL ∝μ^-0.5 and the dimensionless correlation that makes the estimation of the mass transfer coefficients possible in the studied range of process variables was obtained： Sh=10^-2.64 Re^1.07 , Sc^0.75,These results constitute the first step in the kinetic analysis of the reaction between CO and imidazolium chlorocuprate（I） ionic liquid that determines the design of the separation units.展开更多
An unusual form of localized corrsion in copper tubes was detected early in service and in leakage tests after manufacturing.The morphology of this corrosion is similar to that of an ant's nest when viewed in cros...An unusual form of localized corrsion in copper tubes was detected early in service and in leakage tests after manufacturing.The morphology of this corrosion is similar to that of an ant's nest when viewed in cross section. The corrosion mechanisms, cases ofant's nest corrosion, and preventive measures are presented.展开更多
Aluminium-copper hybrid parts, as a substitution to copper parts, result in weight and cost reduction, and are relevant in applications related to the electronic, heating and cooling sector. However, aluminium to copp...Aluminium-copper hybrid parts, as a substitution to copper parts, result in weight and cost reduction, and are relevant in applications related to the electronic, heating and cooling sector. However, aluminium to copper joined by thermal welding processes presents challenges in terms of achieving good joint quality. This is attributed to their dissimilar mechanical and thermal properties which result in large stress gradients during heating. This study investigated joining of aluminium to copper sheets by electromagnetic pulse welding, which is a solid-state process that uses electromagnetic forces for joining of dissimilar materials. Hybrid sheet welds were obtained for all parameters conditions, selected according to a Taguchi L18 design. The structural and mechanical characteristics were examined and related to the welding parameters by means of a Pareto analysis and response graphs. The welded zone started with a wavy interface with interfacial layers and defects and evolved to a flat interface without interfacial layers. The maximum transferable force depended on the minimum specimen thickness and the strength of the hybrid sheet weld. In case of aluminium sheet thickness reduction, the maximum transferable force was linearly correlated with the aluminium sheet thickness. High quality joints were obtained for no aluminium sheet thickness reduction and for a sheet weld strength which was at least as high as that of the base material. The most effective way to increase the transferable force was to lower the initial gap and to increase the free length, which resulted in no aluminium sheet thickness reduction. Alternatively, the use of a rounded spacer decreased the effect of the aluminium sheet thickness on the transferable force. An increase in weld width was achieved for an increase in capacitor charging energy and gap, whereas an increase in weld length was obtained for a decrease in gap. An increase in weld width did not necessarily result in an increase in the transferable force. In the regarded cases, a hybrid sheet with narrow weld width could therefore have higher quality.展开更多
基金Projects(50436010, 50675070) supported by the National Natural Science Foundation of ChinaProject(07118064) supported by the Natural Science Foundation of Guangdong Province, China
文摘Using rolling-ploughing-extrusion compound processing methods,a 3D integral-fin structure on outside surface of red copper tube with diameter of 16.0 mm and wall thickness of 1.5 mm was obtained. When both rolling depth and ploughing-extrusion(P-E) depth were 0.2 mm,rotating speed was 50 r/min,feed speed was 0.16 mm/r,3D fin structures with height of 0.25 mm were gotten. Two different fin structures were obtained in grooves formed with rolling-ploughing-extrusion compound forming technology and observed by scanning electron microscope(SEM). One is the compound structure with V-shaped groove and U-shaped groove,and the other is the single structure with V-shaped grooves. Two kinds of groove structures obtained by rolling processing and ploughing extrusion processing are restricted together by groove interval and rolling depth,and pitch and P-E depth,respectively. Based on the analysis of interaction of rolling and P-E processing,it is found from the result that the outside 3D integral-fin can be achieved by rolling-ploughing-extrusion compound processing when single V-shaped groove structures are formed by both rolling and P-E processing.
文摘The unusual anodic peak emerging on negative potential scan for copper in concentrated NaOH media was investigated by X ray diffraction, X ray photoelectron spectroscopy techniques, potentiodynamic scan, galvanostatic reduction and fast triangular voltage methods. The results show that CuO is formed on the electrode at potentials above this unusual peak A 2,3 , but also produced at peak A 2,3 when copper has been beforehand anodized at high potentials. Longer pre oxidation time and higher pre oxidation potential are advantageous to the formation of CuO at peak A 2,3 . It is presented that the pent up growth of oxide layer in the high potential region occurs at the interface between metal and oxide by the field assisted migration of O 2- ions to electrode, and when potential negatively shifts to the range of peak A 2,3 , the O 2- (or cation vacancies) accumulated in the film could move towards the solution and combine with Cu 2+ ions at the interface between oxide and solution.[
文摘The mechanism of pre roll ploughing for 3D fins on the outside surface of copper tube was studied systematically, and especially the process and conditions of 3D fin formation were analyzed. The right mathematical model was also established. Based on the volume of fin ploughed out is equal to the volume of the metal extruded up by the extruding face of the tool, the relations between fin height, pre roll ploughing feed and pre roll ploughing depth have been achieved. With the increase of pre roll ploughing depth which must be equal to groove depth, the fin height gradually becomes larger. There are different critical feeds with the various depths of pre roll ploughing. The pre roll ploughing feed is the critical one, the height of fin is largest. And when the feed is above the critical one, the fin height will reduce with the increase of feed. The theoretical analysis basically accords with experimental results.
基金the projects ENE2010-15585 and CTQ2012-31639the FPI postgraduate research grant(BES-2011-046279)
文摘Recovery of carbon monoxide from flue gases by selective absorption of carbon monoxide in an imidazolium chlorocuprate（l） ionic liquid is considered in this work as an alternative to the use of molecular volatile solvents such as aromatic hydrocarbons. The present work evaluates the CO mass transfer rates from the gas phase to the ionic liquid solutions in the absence of chemical reaction. To that end, carbon dioxide was employed as an inert model gas and absorption experiments were performed to assess the influence of different process variables in a batch reactor with fiat gas-liquid interface. The experimental mass transfer coefficients showed significant var- iation with temperature, （3.4-10.9） × 10^-7 m·s^-1 between 293 and 313 K; stirring speed, （10.2- 33.1）× 10^-7 m.s 1 between 100 and 300 r·min^-1; and concentration of copper（1）, （6.6-10.2） × 10^-7 m·s^-1 between 0.25 and 2 mol· L^- 1. In addition, the mass transfer coefficients were eventually found to follow a poten- tial proportionality of the type kL ∝μ^-0.5 and the dimensionless correlation that makes the estimation of the mass transfer coefficients possible in the studied range of process variables was obtained： Sh=10^-2.64 Re^1.07 , Sc^0.75,These results constitute the first step in the kinetic analysis of the reaction between CO and imidazolium chlorocuprate（I） ionic liquid that determines the design of the separation units.
文摘An unusual form of localized corrsion in copper tubes was detected early in service and in leakage tests after manufacturing.The morphology of this corrosion is similar to that of an ant's nest when viewed in cross section. The corrosion mechanisms, cases ofant's nest corrosion, and preventive measures are presented.
文摘Aluminium-copper hybrid parts, as a substitution to copper parts, result in weight and cost reduction, and are relevant in applications related to the electronic, heating and cooling sector. However, aluminium to copper joined by thermal welding processes presents challenges in terms of achieving good joint quality. This is attributed to their dissimilar mechanical and thermal properties which result in large stress gradients during heating. This study investigated joining of aluminium to copper sheets by electromagnetic pulse welding, which is a solid-state process that uses electromagnetic forces for joining of dissimilar materials. Hybrid sheet welds were obtained for all parameters conditions, selected according to a Taguchi L18 design. The structural and mechanical characteristics were examined and related to the welding parameters by means of a Pareto analysis and response graphs. The welded zone started with a wavy interface with interfacial layers and defects and evolved to a flat interface without interfacial layers. The maximum transferable force depended on the minimum specimen thickness and the strength of the hybrid sheet weld. In case of aluminium sheet thickness reduction, the maximum transferable force was linearly correlated with the aluminium sheet thickness. High quality joints were obtained for no aluminium sheet thickness reduction and for a sheet weld strength which was at least as high as that of the base material. The most effective way to increase the transferable force was to lower the initial gap and to increase the free length, which resulted in no aluminium sheet thickness reduction. Alternatively, the use of a rounded spacer decreased the effect of the aluminium sheet thickness on the transferable force. An increase in weld width was achieved for an increase in capacitor charging energy and gap, whereas an increase in weld length was obtained for a decrease in gap. An increase in weld width did not necessarily result in an increase in the transferable force. In the regarded cases, a hybrid sheet with narrow weld width could therefore have higher quality.
