The activity and stability of Cu nanostructures strongly depend on their sizes,morphology and structures.Here we report the preparation of two-dimensional(2 D)Cu@Cu-BTC core-shell nanosheets(NSs).The thickness of the ...The activity and stability of Cu nanostructures strongly depend on their sizes,morphology and structures.Here we report the preparation of two-dimensional(2 D)Cu@Cu-BTC core-shell nanosheets(NSs).The thickness of the Cu NSs could be tuned to sub-10 nm through a mild etching process,in which the Cu-BTC in situ grow along with the oxidation on the surface of the Cu NSs.This unique strategy can also be extended to synthesize one-dimensional(1 D)Cu@Cu-BTC nanowires(NWs).Furthermore,the obtained Cu@Cu-BTC NSs could be applied as an effective material to the memory device with the write-onceread-many times(WORM)behavior and the high ION/I(OFF)ratio(>2.7×103).展开更多
基金supported by the National Key R&D Program of China(No.2017YFA0700104)National Natural Science Foundation of China(Nos.21571169,21871238)+2 种基金Fundamental Research Funds for the Central Universities(No.WK2060190081)Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2018494)Young Elite Scientists Sponsorship Program by CAST(No.2016QNRC001)
文摘The activity and stability of Cu nanostructures strongly depend on their sizes,morphology and structures.Here we report the preparation of two-dimensional(2 D)Cu@Cu-BTC core-shell nanosheets(NSs).The thickness of the Cu NSs could be tuned to sub-10 nm through a mild etching process,in which the Cu-BTC in situ grow along with the oxidation on the surface of the Cu NSs.This unique strategy can also be extended to synthesize one-dimensional(1 D)Cu@Cu-BTC nanowires(NWs).Furthermore,the obtained Cu@Cu-BTC NSs could be applied as an effective material to the memory device with the write-onceread-many times(WORM)behavior and the high ION/I(OFF)ratio(>2.7×103).
基金financially supported by the National Natural Science Foundation of China(No.51204011)the Science and Technology Project for the Guidance Teacher of Beijing Excellent Doctoral Dissertation(No.20121000803)
