The regulation of the intermediate adsorption strength is the key for boosting the catalytic performance,while it is still a challenge to achieve this in a facile manner.Herein,CoPc complex was anchored on an MXene su...The regulation of the intermediate adsorption strength is the key for boosting the catalytic performance,while it is still a challenge to achieve this in a facile manner.Herein,CoPc complex was anchored on an MXene support bearing different terminal groups(–F or–OH)to systematically investigate the effect of the terminal groups of the MXene support on the performance of the electrochemical CO_(2)reduction reaction(ECRR).By forming Co–O axial coordination,the anchoring of CoPc was facilitated and the electronic states of Co were tuned.展开更多
基金supported by the National Natural Science Foundation of China(No.22278108 and 22008048)the Hundred Talents Project of Hebei Province(No.E2019050015)+3 种基金the Natural Science Foundation of Tianjin(22JCYBJC00250)the Natural Science Foundation for Outstanding Youth Scholars of Hebei Province(No.B2021202061)the Natural Science Foundation of Hebei Province(No.B2021202010)the State Key Laboratory of Fine Chemicals,Dalian University of Technology(KF 2108).
文摘The regulation of the intermediate adsorption strength is the key for boosting the catalytic performance,while it is still a challenge to achieve this in a facile manner.Herein,CoPc complex was anchored on an MXene support bearing different terminal groups(–F or–OH)to systematically investigate the effect of the terminal groups of the MXene support on the performance of the electrochemical CO_(2)reduction reaction(ECRR).By forming Co–O axial coordination,the anchoring of CoPc was facilitated and the electronic states of Co were tuned.
