Redox-active organic compounds have received much attention as high-capacity electrodes for rechargeable batteries.However,the high solubility in organic electrolytes during charge and discharge processes hinders the ...Redox-active organic compounds have received much attention as high-capacity electrodes for rechargeable batteries.However,the high solubility in organic electrolytes during charge and discharge processes hinders the practical exploitation of organic compounds.This study presents a cobalt-based metal–organic coordination compound with bifunctional coordinated water(Co-MOC-H_(2)O)for sodium-ion storage.The coordinated water enhances interactions between sodium ions and nitrogen atoms in organic ligands through chelation,activating the inert sodium-ion storage sites(C=N).Moreover,the stable hydrogen bonded framework formed by the coordinated water molecules prevents the active organic compounds from dissolving into the electrolyte,thereby enhancing cycling stability.With the bifunctional coordinated water molecules,the Co-MOC-H_(2)O electrode delivers a high capacity of 403 mAh g^(-1)at 0.2 A g^(-1)over 600 cycles and exhibits a capacity retention of 77.9%at 2 A g^(-1)after 1100 cycles.This work highlights the crucial role of the coordinated water molecules in constructing high capacity and long-life sodium-ion storage materials.展开更多
Pot experiments were carried out to study the effect of nitrogen application on winter wheat under different status of soil moisture, so that the key and sensitive stage of winter wheat responses to water and nitrogen...Pot experiments were carried out to study the effect of nitrogen application on winter wheat under different status of soil moisture, so that the key and sensitive stage of winter wheat responses to water and nitrogen coordination were determined. The results showed that the application of N fertilizer was more effective in early stage than in later stage, and at the lower N rates than at the higher N rates under non-irrigated conditions. N treatments had great effect on spikelet bearing number and grain number per spike, but had no effect on 1 000-grain weight; Grain yield and yield component responses to N treatment were greater under irrigated conditions than under non-irrigated conditions. The joining stage was the key and sensitive stage of winter wheat responses to water and nitrogen coordination, and the grain yield, grain number per spike and 1000-grain weight increased, when water and N Fertilizer were applied at this stage. The mechanism is that water and fertilizer supply at joining stage can speed up the growth of above-ground crops, enhance the abilities to absorb and utilize nitrogen fertilizer, and meanwhile, delay the aging of the root and keep the root vigor for a longer period.展开更多
The title Mn（Ⅱ） coordination polymer,poly{[heptaaqua-（μ4-bi-phenyl-3,3？,5,5？-tetracarboxylate）-bimanganese（Ⅱ）] pentahydrate},[Mn_2（bpta）（H_2O）_7]_n·5n H_2O（I）,is crystallized from a mixture of bi...The title Mn（Ⅱ） coordination polymer,poly{[heptaaqua-（μ4-bi-phenyl-3,3？,5,5？-tetracarboxylate）-bimanganese（Ⅱ）] pentahydrate},[Mn_2（bpta）（H_2O）_7]_n·5n H_2O（I）,is crystallized from a mixture of biphenyl-3,3？,5,5？-tetracarboxylic acid（H_4bpta） and MnCl_2·4H_2O in waterethanol under room temperature. Its asymmetric unit consists of one and two halves of crystallographically independent Mn（Ⅱ） cations,one fully deprotonated H4 bpta ligand,seven coordinated water molecules and five solvent water as vip molecules. In I,each Mn（Ⅱ） atom is octahedrally coordinated by six oxygen atoms from bpta^（4-） anions and coordinated water molecules. In the Mn（Ⅱ） cations,one half Mn（Ⅱ） ion of them located at a 2-fold axis generating a trinuclear [Mn_3（H_2O）_2（RCOO）_2] linker by μ1,1-O（water） and μ1,3-O,O？（carboxylate） bridges and another half Mn（Ⅱ） ion with an inversion is a mononuclear linker. These neighbouring trinuclear and mononuclear Mn（Ⅱ） cations are linked together by biphenyl-3,3？,5,5？-tetracarboxylates to form a three-dimensional framework with a（42.84） topology of a（4,4）-connected net,in which the positions of the trinuclear [Mn_3（H_2O）_2（R-COO）_2] linker as a 4-connector linking four bpta^（4-） ligands in I reproduce an eagle-shaped arrangement. The polymeric structure exhibits a water channel with an accessible void of 797.1 ？~3,amounting to 15.7% of the total unit-cell volume. Each of the cavities in the network is occupied by solvent water molecules.展开更多
Aqueous zinc-ion batteries are promising candidates as stationary storage systems for power-grid applications due to their high safety and low cost.The practical implementation of Zn-ion batteries currently still face...Aqueous zinc-ion batteries are promising candidates as stationary storage systems for power-grid applications due to their high safety and low cost.The practical implementation of Zn-ion batteries currently still faces formidable challenges because of Zn dendrite growth,hydrogen evolution,and inadequate environmental adaptability.Herein,to address these challenges,a strategy of regulation of water molecules coordination in electrolyte is proposed via developing a cross-linked hydrophilic hydrogel polymer electrolyte.Within this system,the continuous hydrogen bond among H_(2)O molecules is disrupted and the isolated H_(2)O molecules are strongly bound with a polymeric matrix comprised of polyacrylamide,carboxymethyl cellulose,and ethylene glycol,which can restrain the activity of H_(2)O molecules,thus effectively alleviating Zn dendrite growth and hydrogen evolution and enhancing the anti-freezing ability.With this electrolyte,the Zn||Cu cell presents a high coulombic efficiency of 99.4%over 900 cycles and Zn||Zn symmetric cell exhibits high cycling stability,maintaining plating/stripping for over 1,700 h.Moreover,the assembled Zn||PANI device also demonstrates outstanding electrochemical performance over a wide-temperature range,including a long cycling life over 14,120 cycles at room temperature and an ultralong cycling surpassing 30,000 cycles even at−40℃.This showcases the manipulation of water coordination chemistry for advanced,highly adaptable batteries.展开更多
A novel Dy^（3＋） coordination compound,（H_2pipz）（H_3O）[Dy（pydc）_3]·11H_2O（1,pipz = piperazine and H_2pydc = pyridine-2,6-dicarboxylic acid）,has been hydrothermally synthesized and characterized by X-ray...A novel Dy^（3＋） coordination compound,（H_2pipz）（H_3O）[Dy（pydc）_3]·11H_2O（1,pipz = piperazine and H_2pydc = pyridine-2,6-dicarboxylic acid）,has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction,elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O···H···O hydrogen bonding interactions. Furthermore,the luminescent property of compound 1 was also investigated.展开更多
The objective of this study was to explore the effects of different degrees of water and salt stress on the actual water consumption and soil salt accumulation of tomatoes and the salt tolerance characteristics of tom...The objective of this study was to explore the effects of different degrees of water and salt stress on the actual water consumption and soil salt accumulation of tomatoes and the salt tolerance characteristics of tomatoes under brackish water combined with regulated deficit irrigation mode.The greenhouse pot experiment was used to set three influencing factors,the irrigation water salinity S1 was 1.1 g/L(local shallow groundwater),S2 was 2.0 g/L,and S3 was 4.0 g/L,respectively,and different degrees of water deficit(W1 ranged from 65%-75%Field Capacity(FC),W2 ranged from 55%-65%FC,W3 ranged from 45%-55%FC)and seedling stage(T1),blossoming and bearing fruits stage(T2)and mature picking stage(T3).The response of fresh fruit weight,stems and leaves weight,yield and water use efficiency of tomato under water and salt stress were monitored and analyzed.The results showed the coordinated regulation of water and salt can significantly reduce the electrical conductivity of the 0-30 cm soil of the tomato root system.The higher the salinity of irrigation water,the better the salt control effects of the coordinated regulation of water and salt;the coordinated regulation of water and salt at different growth stages had significant effects on the weight of fresh tomato fruits,the weight of stems and leaves and the yield.The salinity of irrigation water was in inverse proportion to the yield of tomatoes;In S1 treatment irrigation(irrigation water salinity was 1.1 g/L)under the mildly regulated deficit in the seedling stage(irrigation water was 55%-65%of the field water capacity)can effectively reduce the irrigation water volume during the whole growth stage while ensuring that there was no significant reduction in yield.The research results provided a scientific and reliable theoretical basis for the increase of local tomato production,the improvement of water use efficiency and the formulation of suitable irrigation patterns.展开更多
基金supported by the National Natural Science Foundation of China(22121005,92372203,92372001,52072186,and 52301278)the National Key Research and Development Program of China(2022YFB2402200)+3 种基金the Science and Technology Plans of Tianjin(23JCYBJC00170)the Fundamental Research Funds for the Central Universities,Nankai University(63241206 and 9242000710)Shanghai Jiao Tong University Shaoxing Research Institute of Renewable Energy and Molecular Engineering(JDSX2023003)the Natural Science Foundation of Jiangsu Province(BK20230937).
文摘Redox-active organic compounds have received much attention as high-capacity electrodes for rechargeable batteries.However,the high solubility in organic electrolytes during charge and discharge processes hinders the practical exploitation of organic compounds.This study presents a cobalt-based metal–organic coordination compound with bifunctional coordinated water(Co-MOC-H_(2)O)for sodium-ion storage.The coordinated water enhances interactions between sodium ions and nitrogen atoms in organic ligands through chelation,activating the inert sodium-ion storage sites(C=N).Moreover,the stable hydrogen bonded framework formed by the coordinated water molecules prevents the active organic compounds from dissolving into the electrolyte,thereby enhancing cycling stability.With the bifunctional coordinated water molecules,the Co-MOC-H_(2)O electrode delivers a high capacity of 403 mAh g^(-1)at 0.2 A g^(-1)over 600 cycles and exhibits a capacity retention of 77.9%at 2 A g^(-1)after 1100 cycles.This work highlights the crucial role of the coordinated water molecules in constructing high capacity and long-life sodium-ion storage materials.
基金supported by the Key Program(30230230)Major Program(49890330)+1 种基金Special Program for Agriculture(30070429)of National Natural Science Foundation of ChinaNational Special Foundation for Key Basic Research,China(G1999011707).
文摘Pot experiments were carried out to study the effect of nitrogen application on winter wheat under different status of soil moisture, so that the key and sensitive stage of winter wheat responses to water and nitrogen coordination were determined. The results showed that the application of N fertilizer was more effective in early stage than in later stage, and at the lower N rates than at the higher N rates under non-irrigated conditions. N treatments had great effect on spikelet bearing number and grain number per spike, but had no effect on 1 000-grain weight; Grain yield and yield component responses to N treatment were greater under irrigated conditions than under non-irrigated conditions. The joining stage was the key and sensitive stage of winter wheat responses to water and nitrogen coordination, and the grain yield, grain number per spike and 1000-grain weight increased, when water and N Fertilizer were applied at this stage. The mechanism is that water and fertilizer supply at joining stage can speed up the growth of above-ground crops, enhance the abilities to absorb and utilize nitrogen fertilizer, and meanwhile, delay the aging of the root and keep the root vigor for a longer period.
基金supported by the National Natural Science Foundation of China(No.21571118)
文摘The title Mn（Ⅱ） coordination polymer,poly{[heptaaqua-（μ4-bi-phenyl-3,3？,5,5？-tetracarboxylate）-bimanganese（Ⅱ）] pentahydrate},[Mn_2（bpta）（H_2O）_7]_n·5n H_2O（I）,is crystallized from a mixture of biphenyl-3,3？,5,5？-tetracarboxylic acid（H_4bpta） and MnCl_2·4H_2O in waterethanol under room temperature. Its asymmetric unit consists of one and two halves of crystallographically independent Mn（Ⅱ） cations,one fully deprotonated H4 bpta ligand,seven coordinated water molecules and five solvent water as vip molecules. In I,each Mn（Ⅱ） atom is octahedrally coordinated by six oxygen atoms from bpta^（4-） anions and coordinated water molecules. In the Mn（Ⅱ） cations,one half Mn（Ⅱ） ion of them located at a 2-fold axis generating a trinuclear [Mn_3（H_2O）_2（RCOO）_2] linker by μ1,1-O（water） and μ1,3-O,O？（carboxylate） bridges and another half Mn（Ⅱ） ion with an inversion is a mononuclear linker. These neighbouring trinuclear and mononuclear Mn（Ⅱ） cations are linked together by biphenyl-3,3？,5,5？-tetracarboxylates to form a three-dimensional framework with a（42.84） topology of a（4,4）-connected net,in which the positions of the trinuclear [Mn_3（H_2O）_2（R-COO）_2] linker as a 4-connector linking four bpta^（4-） ligands in I reproduce an eagle-shaped arrangement. The polymeric structure exhibits a water channel with an accessible void of 797.1 ？~3,amounting to 15.7% of the total unit-cell volume. Each of the cavities in the network is occupied by solvent water molecules.
基金the financial support from Guangdong Basic and Applied Basic Research Foundation(Grant No.2025A1515012077)National Natural Science Foundation of China(No.52401296)+3 种基金the financial support by Guangdong Provincial Pearl River Talents Program(Grant No.2023CX10L019)Bureau of Science and Technology of Jiangmen Municipality(Grant No.2320002001062)And this work is also partly supported by Guangdong S&T Programme(No.2022B1212040001)Guangdong-Hong Kong-Macao joint Laboratory(No.2023B1212120003).
文摘Aqueous zinc-ion batteries are promising candidates as stationary storage systems for power-grid applications due to their high safety and low cost.The practical implementation of Zn-ion batteries currently still faces formidable challenges because of Zn dendrite growth,hydrogen evolution,and inadequate environmental adaptability.Herein,to address these challenges,a strategy of regulation of water molecules coordination in electrolyte is proposed via developing a cross-linked hydrophilic hydrogel polymer electrolyte.Within this system,the continuous hydrogen bond among H_(2)O molecules is disrupted and the isolated H_(2)O molecules are strongly bound with a polymeric matrix comprised of polyacrylamide,carboxymethyl cellulose,and ethylene glycol,which can restrain the activity of H_(2)O molecules,thus effectively alleviating Zn dendrite growth and hydrogen evolution and enhancing the anti-freezing ability.With this electrolyte,the Zn||Cu cell presents a high coulombic efficiency of 99.4%over 900 cycles and Zn||Zn symmetric cell exhibits high cycling stability,maintaining plating/stripping for over 1,700 h.Moreover,the assembled Zn||PANI device also demonstrates outstanding electrochemical performance over a wide-temperature range,including a long cycling life over 14,120 cycles at room temperature and an ultralong cycling surpassing 30,000 cycles even at−40℃.This showcases the manipulation of water coordination chemistry for advanced,highly adaptable batteries.
基金financially supported by the Foundation of Fujian Educational Committee(JA14348)
文摘A novel Dy^（3＋） coordination compound,（H_2pipz）（H_3O）[Dy（pydc）_3]·11H_2O（1,pipz = piperazine and H_2pydc = pyridine-2,6-dicarboxylic acid）,has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction,elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O···H···O hydrogen bonding interactions. Furthermore,the luminescent property of compound 1 was also investigated.
基金This work was financially supported by the Applied Basic Research General Project of Yunnan Science and Technology Department(Grant No.2019FB075).[References][1]Siddiqui M N,Mostofa M G,Akter M M,Srivastava A K,Sayed M A,。
文摘The objective of this study was to explore the effects of different degrees of water and salt stress on the actual water consumption and soil salt accumulation of tomatoes and the salt tolerance characteristics of tomatoes under brackish water combined with regulated deficit irrigation mode.The greenhouse pot experiment was used to set three influencing factors,the irrigation water salinity S1 was 1.1 g/L(local shallow groundwater),S2 was 2.0 g/L,and S3 was 4.0 g/L,respectively,and different degrees of water deficit(W1 ranged from 65%-75%Field Capacity(FC),W2 ranged from 55%-65%FC,W3 ranged from 45%-55%FC)and seedling stage(T1),blossoming and bearing fruits stage(T2)and mature picking stage(T3).The response of fresh fruit weight,stems and leaves weight,yield and water use efficiency of tomato under water and salt stress were monitored and analyzed.The results showed the coordinated regulation of water and salt can significantly reduce the electrical conductivity of the 0-30 cm soil of the tomato root system.The higher the salinity of irrigation water,the better the salt control effects of the coordinated regulation of water and salt;the coordinated regulation of water and salt at different growth stages had significant effects on the weight of fresh tomato fruits,the weight of stems and leaves and the yield.The salinity of irrigation water was in inverse proportion to the yield of tomatoes;In S1 treatment irrigation(irrigation water salinity was 1.1 g/L)under the mildly regulated deficit in the seedling stage(irrigation water was 55%-65%of the field water capacity)can effectively reduce the irrigation water volume during the whole growth stage while ensuring that there was no significant reduction in yield.The research results provided a scientific and reliable theoretical basis for the increase of local tomato production,the improvement of water use efficiency and the formulation of suitable irrigation patterns.
