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Coordinating lithium polysulfides to inhibit intrinsic clustering behavior and facilitate sulfur redox conversion in lithium-sulfur batteries
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作者 Qihou Li Jiamin Liu +6 位作者 Fulu Chu Jinwei Zhou Jieshuangyang Chen Zengqiang Guan Xiyun Yang Jie Lei Feixiang Wu 《Chinese Chemical Letters》 2025年第5期673-678,共6页
The intrinsic clustering behavior and kinetically sluggish conversion process of lithium polysulfides seriously limit the electrochemical reversibility of sulfur redox reactions in lithium-sulfur(Li-S)batteries.Here,w... The intrinsic clustering behavior and kinetically sluggish conversion process of lithium polysulfides seriously limit the electrochemical reversibility of sulfur redox reactions in lithium-sulfur(Li-S)batteries.Here,we introduce molybdenum pentachloride(MoCl_(5))into the electrolyte which could coordinate with lithium polysulfides and inhibit their intrinsic clustering behavior,subsequently serving as an improved mediator with the bi-functional catalytic effect for Li_(2)S deposition and activation.Moreover,the coordination bonding and accelerated conversion reaction can also greatly suppress the dissolution and shuttling of polysulfides.Consequently,such polysulfide complexes enable the Li-S coin cell to exhibit good longterm cycling stability with a capacity decay of 0.078%per cycle after 400 cycles at 2 C,and excellent rate performance with a discharge capacity of 589 mAh/g at 4 C.An area capacity of 3.94 mAh/cm^(2)is also achieved with a high sulfur loading of 4.5mg/cm^(2)at 0.2 C.Even at-20℃,the modified cell maintains standard discharge plateaus with low overpotential,delivering a high capacity of 741 mAh/g at 0.2 C after 80 cycles.The low-cost and convenient MoCl_(5)additive opens a new avenue for the effective regulation of polysulfides and significant enhancement in sulfur redox conversion. 展开更多
关键词 Lithium-sulfur(Li-S)battery Polysulfide clustering coordinating reaction Improved mediator Shuttle effect
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Weakly coordinating cationic polymer electrolytes for fast-charging solid-state lithium-metal batteries
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作者 Soohyoung Lee Kyeong-Seok Oh +4 位作者 Ji Eun Lee Sun-Phil Han Hong-I Kim Sang Kyu Kwak Sang-Young Lee 《Journal of Energy Chemistry》 2025年第6期243-251,I0006,共10页
Despite the growing interest in fast-cha rging solid-state lithium(Li)-metal batteries(SSLMBs),their practical implementation has yet to be achieved,primarily due to an incomplete understanding of the disparate and of... Despite the growing interest in fast-cha rging solid-state lithium(Li)-metal batteries(SSLMBs),their practical implementation has yet to be achieved,primarily due to an incomplete understanding of the disparate and often conflicting requirements of the bulk electrolyte and the electrode-electrolyte interphase.Here,we present a weakly coordinating cationic polymer electrolyte(WCPE)specifically designed to regulate the Li^(+)coordination structure,thereby enabling fast-charging SSLMBs.The WCPE comprises an imidazolium-based polycationic matrix combined with a succinonitrile(SN)-based highconcentration electrolyte.Unlike conventional neutral polymer matrices,the polycationic matrix in the WCPE competes with Li^(+)for interactions with SN,weakening the original coordination between SN and Li^(+).This modulation of SN-Li^(+)interaction improves both Li^(+)conductivity of the WCPE(σ_(Li^(+))=1.29mS cm^(-1))and redox kinetics at the electrode-electrolyte interphase.Consequently,SSLMB cells(comprising LiFePO_(4)cathodes and Li-metal anodes)with the WCPE achieve fast-charging capability(reaching over 80%state of charge within 10 min),outperforming those of previously reported polymer electrolytebased SSLMBs. 展开更多
关键词 Cationic polymer electrolytes Weak coordination Electrode-electrolyte interphase Fast-charging Solid-state lithium-metal batteries
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Protection Measures for Buildings Based on Coordinating Action Theory of Ground, Foundation and Structure 被引量:4
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作者 TAN Zhi-xiang DENGKa-zhong 《Journal of China University of Mining and Technology》 EI 2006年第1期17-21,共5页
Based on the theory of coordinating action of building ground, foundation and structure, this paper presents a modified method for calculating additional stresses on buildings in mining areas by considering the joint ... Based on the theory of coordinating action of building ground, foundation and structure, this paper presents a modified method for calculating additional stresses on buildings in mining areas by considering the joint effect of cur- vature deformation and horizontal deformation on buildings. It points out that for buildings over the coal pillar, it is ad- visable to soften the intermediate ground of buildings when they are affected by mining. For buildings over the goaf, it is preferable to soften the ground at both ends of buildings. In order to enhance the ability of a building to resist tensile deformation, the key measure is to reinforce the bottom foundation of the building. In addition, the concept of “angle of break of building” is proposed. It is because of this angle that the protecting coal pillar is left, which is a better solution than prevailing solutions The findings provide a more scientific basis for mining under buildings. 展开更多
关键词 mining under buildings GROUND FOUNDATION coordinating action protective measure
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Two-mode intelligent coordinating control of position for the welding positioner 被引量:2
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作者 樊丁 周万坤 谭伟明 《China Welding》 EI CAS 1998年第1期50-55,共6页
A new intelligent control method for welding positioner is proposed. Applying an improved fuzzy controller and a variable PID controller, a two-mode intelligent coordinating controller ( TMICC ) is designed on basis o... A new intelligent control method for welding positioner is proposed. Applying an improved fuzzy controller and a variable PID controller, a two-mode intelligent coordinating controller ( TMICC ) is designed on basis of fuzzy logic and rules. The simulation and experimental results show that this control system can obtain better dynamic and static characteristics. 展开更多
关键词 AC servo position control two-mode coordinating controller fuzzy control welding positioner
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COORDINATING DEVELOPMENT OF AGRICULTURAL RESOURCES AND ENVIRONMENT OF THE TROPIC REGION IN YUNNAN PROVINCE 被引量:1
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作者 姚建衢 杨焕宗 《Chinese Geographical Science》 SCIE CSCD 1994年第4期345-351,共7页
The tropic region of Yunnan is a treasurable land with rich resources and great development potentials. The natural environment and resources of the region are characterized by a complicated topography, great height d... The tropic region of Yunnan is a treasurable land with rich resources and great development potentials. The natural environment and resources of the region are characterized by a complicated topography, great height deviation, monsoon climate as well as abound biological resources. Therefore, the tropic region becomes an ideal place for developing agricultural production base, though it do exist such problems as adverse location, sparsely distributed land resources, poor traffic conditions and deterioration of ecological environment. In order to further exploit the tropical resources and to implement comprehensive harnessing, we should take the following countermeasures:Working out a comprehensive development planning; restoring ecological environment,establishing agricultural production base; tapping fully water resources; constructing the traffic line and developing the border ports and tourism spots. 展开更多
关键词 TROPIC REGION coordinating DEVELOPMENT YUNNAN PROVINCE
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Local minima-free design of artificial coordinating fields 被引量:1
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作者 XingjianJING YuechaoWANG 《控制理论与应用(英文版)》 EI 2004年第4期371-380,共10页
In order to overcome the drawbacks of conventional artificial potential fields (APF) based methods for the motion planning problems of mobile robots in dynamic uncertain environments, an artificial coordinating fields... In order to overcome the drawbacks of conventional artificial potential fields (APF) based methods for the motion planning problems of mobile robots in dynamic uncertain environments, an artificial coordinating fields (ACF) based method has been proposed recently. This paper deals with the reachability problem of the ACF, that is, how to design and choose the parameters of the ACF and how the environment should be such that the robot can reach its goal without being trapped in local minima. Some sufficient conditions for these purposes are developed theoretically. Theoretical analyses show that, the ACF can effectively remove local minima in dynamic uncertain environments with V-shape or U-shape obstacles, and guide the mobile robot to reach its goal with some necessary environment constraints and based on the methods provided in this paper to properly choose the parameters of the ACF. Comparisons between the ACF and APF, and simulations are provided to illustrate the advantages of the ACF. 展开更多
关键词 Artificial coordinating field (ACF) Artificial potential field Local minima Dynamic uncertain environment ROBOT
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Coordinating control of multiple rigid bodies based on motion primitives 被引量:1
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作者 Fan Wu Zhi-Yong Geng 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2012年第2期482-489,共8页
This paper studies the problem of coordinated motion generation for a group of rigid bodies. Two classes of coordinated motion primitives, relative equilibria and ma- neuvers, are given as building blocks for generati... This paper studies the problem of coordinated motion generation for a group of rigid bodies. Two classes of coordinated motion primitives, relative equilibria and ma- neuvers, are given as building blocks for generating coordi- nated motions. In a motion-primitive based planning frame- work, a control method is proposed for the robust execution of a coordinated motion plan in the presence of perturba- tions. The control method combines the relative equilibria stabilization with maneuver design, and results in a close- loop motion planning framework. The performance of the control method has been illustrated through a numerical sim- ulation. 展开更多
关键词 coordinating control Motion plan execution Motion primitive. Relative equilibrium. Maneuver
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Advanced Coordinating Control System for Power Plant
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作者 WU Peng~1 WEI Shuangying~2 1.Automation School,Chongqing University,Campus A,Chongqin 400044,China 2.Management School,Wuhan University of Technology,Wuhan 430070,China, 《武汉理工大学学报》 CAS CSCD 北大核心 2006年第S3期962-968,共7页
The coordinating control system is popular used in power plant.This paper describes the advanced coordinating control by control methods and optimal operation,introduces their principals and features by using the exam... The coordinating control system is popular used in power plant.This paper describes the advanced coordinating control by control methods and optimal operation,introduces their principals and features by using the examples of power plant op- eration.It is wealthy for automation application in optimal power plant operation. 展开更多
关键词 POWER PLANT coordinating CONTROL system AUTOMATION operation
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Weakly coordinating group directed rhodium-catalyzed unconventional site-selective C-H olefination of indolizines at the 8-position
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作者 Xue Feng Jiaxin Tian +5 位作者 Ying Sun Huayou Hu Mingzhu Lu Yuhe Kan Danjun Fang Chao Wang 《Chinese Chemical Letters》 SCIE CAS CSCD 2021年第1期470-474,共5页
A rhodium-catalyzed directing group promoted selective C-H olefination reaction of indolizines at the 8-position is re ported.Di-olefination at 2,8-positions also achieved with silver hexafluoroantimonate as an additi... A rhodium-catalyzed directing group promoted selective C-H olefination reaction of indolizines at the 8-position is re ported.Di-olefination at 2,8-positions also achieved with silver hexafluoroantimonate as an additive under similar reaction conditions.Weakly coordinating groups,such as ketone,alde hyde,amide and ester,were used as directing groups.The ester group can be removed under acid conditions and therefore is used as a traceless directing group. 展开更多
关键词 RHODIUM-CATALYZED C–H olefination INDOLIZINE Weakly coordinating directing group Unconventional site-selectivity
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Coordinating optimization-based sliding mode variable structure control for electro-hydraulic servo system
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作者 Yong YANG An LUO Hua HAN 《控制理论与应用(英文版)》 EI 2006年第2期168-174,共7页
A sliding mode variable structure control (SMVSC) based on a coordinating optimization algorithm has been developed. Steady state error and control switching frequency are used to constitute the system performance i... A sliding mode variable structure control (SMVSC) based on a coordinating optimization algorithm has been developed. Steady state error and control switching frequency are used to constitute the system performance indexes in the coordinating optimization, while the tuning rate of boundary layer width (BLW) is employed as the optimization parameter. Based on the mathematical relationship between the BLW and steady-state error, an optimized BLW tuning rate is added to the nonlinear control term of SMVSC. Simulation experiment results applied to the positioning control of an electro-hydraulic servo system show the comprehensive superiority in dynamical and static state performance by using the proposed controller is better than that by using SMVSC without optimized BLW tuning rate. This succeeds in coordinately considering both chattering reduction and high-precision control realization in SMVSC. 展开更多
关键词 Sliding mode variable structure control(SMVSC) Varying boundary layer Chattering reduction Steady-state performance coordinating optimization(CO) Electro-hydraulic servo system (EHSS)
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Coordinating rural-urban education and institution innovation
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作者 WANG Xiaodong 《Journal of Northeast Agricultural University(English Edition)》 CAS 2007年第4期374-379,共6页
In order to implement the spirit of the Sixteenth National People's Congress to accelerate development of rural education, deepen reform of rural education, guarantee a well-off society, and harmonize rural and urban... In order to implement the spirit of the Sixteenth National People's Congress to accelerate development of rural education, deepen reform of rural education, guarantee a well-off society, and harmonize rural and urban development, coordinating ruralurban education is the key to China's development. At present, the rural-urban coordinating education is influenced by many factors, including rural-urban income difference, rural-urban educational resources difference, rural-urban background difference, and rural- urban institutional difference. In order to realize the coordinating development of rural-urban education, we need innovation in "Hukou" institution, land institution, financial institution and rural education institution. Institution innovation would be the guarantee to the coordinating rural-urban education. 展开更多
关键词 coordinating rural-urban education institution innovation
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SYNTHESIS AND CHARACTERIZATION OF PALLADIUM COORDINATING IMINE SIDE CHAIN LIQUID CRYSTALLINE POLYSILOXANES
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作者 陈刚 张榕本 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1991年第4期339-346,共8页
New thermotropic chloro-bridged dinuclear palladium coordinating imine side chain liquid crystalline polysiloxanes have been synthesized. Their mesomorphic properties have been investigated by DSC, X-ray diffraction a... New thermotropic chloro-bridged dinuclear palladium coordinating imine side chain liquid crystalline polysiloxanes have been synthesized. Their mesomorphic properties have been investigated by DSC, X-ray diffraction and polarizing microscopy. The polymeric complexes show nematicdiscotic (Nd) mesophase. It is found that the temperature range of liquid crystalline state of chloro- bridged polymeric complexes is much wider than that of acetato- bridged ones and imine side chain polysiloxane. This indicates that the disc-like chloro-bridged palladium complexing units play a role as mesogen in mesophase. 展开更多
关键词 Metal coordinating imine side chain Liquid crystal polysiloxanes
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Protect Sick Prisoners' Rights Through Regulation and Innovation——Chengdu launches coordinating mechanism for sick prisoners with major diseases
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作者 WANG XIAOBING, YAN HUAJU AND FU SHAOHUA 《The Journal of Human Rights》 2012年第5期5-7,共3页
In May 2011, the Prison Management Bureau of Sichuan Province in Southwest China held a conference in its capital city Chengdu to discuss the management of severely sick prisoners. Coordinating Management on Major Dis... In May 2011, the Prison Management Bureau of Sichuan Province in Southwest China held a conference in its capital city Chengdu to discuss the management of severely sick prisoners. Coordinating Management on Major Diseases of Sick Prisoners in Sichuan (Trial) was issued then, marking the start of an overall deployment. 展开更多
关键词 Protect Sick Prisoners Rights Through Regulation and Innovation Chengdu launches coordinating mechanism for sick prisoners with major diseases
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Multi-objective intelligent coordinating optimization blending system based on qualitative and quantitative synthetic model 被引量:3
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作者 王雅琳 马杰 +2 位作者 桂卫华 阳春华 张传福 《Journal of Central South University of Technology》 EI 2006年第5期552-557,共6页
A multi-objective intelligent coordinating optimization strategy based on qualitative and quantitative synthetic model for Pb-Zn sintering blending process was proposed to obtain optimal mixture ratio. The mechanism a... A multi-objective intelligent coordinating optimization strategy based on qualitative and quantitative synthetic model for Pb-Zn sintering blending process was proposed to obtain optimal mixture ratio. The mechanism and neural network quantitative models for predicting compositions and rule models for expert reasoning were constructed based on statistical data and empirical knowledge. An expert reasoning method based on these models were proposed to solve blending optimization problem, including multi-objective optimization for the first blending process and area optimization for the second blending process, and to determine optimal mixture ratio which will meet the requirement of intelligent coordination. The results show that the qualified rates of agglomerate Pb, Zn and S compositions are increased by 7.1%, 6.5% and 6.9%, respectively, and the fluctuation of sintering permeability is reduced by 7.0%, which effectively stabilizes the agglomerate compositions and the permeability. 展开更多
关键词 Pb-Zn sintering blending process qualitative and quantitative synthetic model multi-objectiveoptimization area optimization intelligent coordination
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A joint inventory–finance model for coordinating a capital‑constrained supply chain with financing limitations 被引量:2
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作者 Faranak Emtehani Nasim Nahavandi Farimah Mokhatab Rafiei 《Financial Innovation》 2021年第1期115-153,共39页
Faced with economic recession,firms struggle to find ways to stay competitive and maintain market share.Effective coordination of the supply chain can solve this problem,but this may fail if existing capital constrain... Faced with economic recession,firms struggle to find ways to stay competitive and maintain market share.Effective coordination of the supply chain can solve this problem,but this may fail if existing capital constraints and financial flows are ignored.This study addresses the challenge by exploiting coordination through joint decision-making on the physical and financial flows of a capital-constrained supply chain.We also consider the capital-constrained member’s financing limitations that lead to lost sales.Two scenarios based on non-coordinated and coordinated structures are modeled in the form of bi-objective optimization problems that simultaneously optimize system costs and service levels.The models are solved using the-constraint method.The results indicate that the non-coordinated model cannot satisfy more than about 50%of the demand due to capital shortage and financing limitations,while the coordinated model can satisfy all of the demand via internal financing.Furthermore,the proposed coordination scheme leads to cost reduction for the members and the total system.To motivate all members to accept the proposed coordination scheme,a cost-sharing mechanism is applied to the coordination procedure.Finally,a sensitivity analysis concerning financial parameters is provided for validating the coordination model. 展开更多
关键词 Supply chain coordination Inventory-finance model Capital shortage Financing limitation Service level Bi-objective optimization
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An optimal strategy for coordinating and dispatching “source-load” in power system based on multiple time scales 被引量:2
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作者 LIU Yan-feng DONG Hai-ying +1 位作者 WANG Ning-bo MA Ming 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2018年第4期388-396,共9页
Due to the phenomenon of abandoning wind power and photo voltage(PV)power in the“Three Northern Areas”in China,this paper presents an optimal strategy for coordinating and dispatching“source-load”in power system b... Due to the phenomenon of abandoning wind power and photo voltage(PV)power in the“Three Northern Areas”in China,this paper presents an optimal strategy for coordinating and dispatching“source-load”in power system based on multiple time scales.On the basis of the analysis of the uncertainty of wind power and PV power as well as the characteristics of load side resource dispatching,the optimal model of coordinating and dispatching“source-load”in power system based on multiple time scales is established.It can simultaneously and effectively dispatch conventional generators,wind plant,PV power station,pumped-storage power station and load side resources by optimally using three time scales:day-ahead,intra-day and real-time.According to the latest predicted information of wind power,PV power and load,the original generation schedule can be rolled and amended by using the corresponding time scale.The effectiveness of the model can be verified by a real system.The simulation results show that the proposed model can make full use of“source-load”resources to improve the ability to consume wind power and PV power of the grid-connected system. 展开更多
关键词 multiple time scales "source-load"coordination pumped-storage power station wind plant photovoltaic(PV)power station
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The Problems of Coordinating Urban-rural Development of Chongqing City and Corresponding Measures of Financial System 被引量:1
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作者 DENG Li1,RAN Guang-he2,LI Jie3 1.College of Management,Chongqing Technology and Business University,Chongqing 400067,China 2.College of Economics and Business Administration,Chongqing University,Chongqing 400030,China 3.Chongqing Branch,Agricultural Bank of China,Chongqing 400041,China 《Asian Agricultural Research》 2011年第2期109-115,共7页
The thesis researches urban-rural coordination which is incorporated into the framework of "agriculture,rural areas and farmers",and it focuses on farmers' human resources development,agricultural indust... The thesis researches urban-rural coordination which is incorporated into the framework of "agriculture,rural areas and farmers",and it focuses on farmers' human resources development,agricultural industrial adjustment,rural regional coordinated development and so on.The main problems existing in the process of coordinating urban-rural development of Chongqing City are discussed under the foregoing framework.We find that input and flow direction of capital deviating from "agriculture,rural areas and farmers" is the direct cause of insufficient rural educational input,insufficient agricultural input,and irrational rural input,while the fundamental reason lies in the irrational financial policy.Based on this,the measures of innovating upon financial policy and financial system are put forward. 展开更多
关键词 Urban-rural COORDINATION PROBLEMS of "agriculture
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Coordinating Preventive Strategies and Restoration under Extreme Weather Conditions 被引量:1
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作者 Gang Chen En Lu +4 位作者 Chaoyi Peng Yunhe Hou Zhijun Qin Shaowei Huang Feng Liu 《Journal of Power and Energy Engineering》 2015年第4期313-318,共6页
It has been well identified that the extreme events significantly impact the system operation. In this work, a comprehensive operating strategy, which coordinates the preventive strategies and system restoration, was ... It has been well identified that the extreme events significantly impact the system operation. In this work, a comprehensive operating strategy, which coordinates the preventive strategies and system restoration, was proposed. A re-dispatch model that limits the potential loss under extreme events, as well as provides adequate resources for system restoration after the extreme events, was proposed. An optimal power flow based method was established to solve the proposed model. The availabilities of components and the remaining system due to the extreme events were restored by extending the EPRI’s System Restoration Navigator (SRN) with a little modification. Case studies demonstrate the proposed model and methods. 展开更多
关键词 EXTREME WEATHER EVENT PREVENTIVE Strategy RESTORATION COORDINATION
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Coordinating and Evaluating of Multiple Key Performance Indicators for Manufacturing Equipment: Case Study of Distillation Column
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作者 朱理 苏宏业 +2 位作者 卢山 王越 张泉灵 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2014年第7期805-811,共7页
Manufacturing equipment takes the task of operation and directly effects on the manufacturing process. One single Key Performance Indicator (KPI) is mainly employed to evaluate equipment in most studies, neither int... Manufacturing equipment takes the task of operation and directly effects on the manufacturing process. One single Key Performance Indicator (KPI) is mainly employed to evaluate equipment in most studies, neither integrating the KPIs into a completed evaluation system nor considering the impact and conflict among KPIs. In this paper, a KPI evaluation architecture is presented to define and analyze KPIs, and then a common structure for KPI to obtain the KPI set of manufacturing equipment is introduced. An available multi-KPl coordination model is proposed to discern and balance the relationship among multi-KPl. Finally, a case study is introduced to illustrate the applicability of the coordination model by using multi-objective optimization strategy and an efficient solution is obtained. 展开更多
关键词 performance indicator COORDINATION Manufacturing equipment EVALUATION
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Evaluation on the Efficiency and Fairness of Coordinating Public Goods Supply in Urban and Rural Areas
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作者 Shan YU Zhongmin DING 《Asian Agricultural Research》 2015年第4期4-9,共6页
By setting the urban-rural public goods supply model,this paper evaluates the effects of coordinating supply public goods on resource allocation and welfare from efficiency and fairness,and examines the necessity and ... By setting the urban-rural public goods supply model,this paper evaluates the effects of coordinating supply public goods on resource allocation and welfare from efficiency and fairness,and examines the necessity and possibility of coordinating public goods supply in urban and rural areas. The model assumes that the population size of urban and rural areas is different,and the population can not flow freely between urban and rural areas; there are different degrees of spillover in the public goods supply. Model results show that coordinating public goods supply in urban and rural areas is the result of optimizing resource allocation efficiency,but the residents' individual utility level will not necessarily improve,so residents' willingness to support coordinated urban-rural supply is different,and public goods spillover and different tax systems are the factors that affect the residents' utility level. Finally,this paper uses the practice of coordinating urban and rural compulsory education in Chengdu City to confirm the above conclusions. 展开更多
关键词 PUBLIC GOODS supply Urban-rural COORDINATION Effic
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