The high-alloyed wrought superalloy GH4975 tends to form coarse MC carbides and eutectic(γ+γ′)phases,which adversely affect the cogging and homogenization process.To provide theoretical guidance for control of MC c...The high-alloyed wrought superalloy GH4975 tends to form coarse MC carbides and eutectic(γ+γ′)phases,which adversely affect the cogging and homogenization process.To provide theoretical guidance for control of MC carbides and eutectic(γ+γ′)formation,differential thermal analysis(DTA)was utilized to investigate the effect of cooing rate(10-90℃·min^(-1))on solidification behavior and micro-segregation of GH4975 alloy.According to the thermodynamic calculation and distribution characteristics of precipitates,the MC carbides can act as nucleation sites forγdendrites,but the nucleation ofγdendrites becomes less dependent on the MC carbide primers at higher cooling rates.As theγdendrites grow,the elements including Ti and Nb gradually accumulate in the residual liquid and leads to the formation of more MC carbides near the interdendritic region.Finally,the solidification is terminated with the formation of eutectic(γ+γ′).With an increase in cooling rate,the liquidus temperature rises,but the solidus temperature decreases,and thus the solidification range is obviously enlarged.The dendritic structure is significantly refined by the increase of cooling rate.The secondary dendrite arm spacing,λ_(2),as a function of cooling rate,T,can be expressed asλ_(2)=216.78T^(-0.42).Moreover,the increasing cooling rate weakens the back diffusion of Al,Ti,and Nb,increases the undercooling,and limits the growth of precipitates.Consequently,the sizes of MC carbides,eutectic(γ+γ′),and primaryγ′significantly decrease,but the area fraction of eutectic(γ+γ′)linerly increases as the cooling rate rises.Thus moderate cooling rate(such as 30℃·min^(-1))should be selected during the solidification process of GH4975 alloy.展开更多
Forests exert significant biogeophysical cooling effects(CE)through processes such as increased evapotranspiration,reduced albedo,and enhanced surface roughness.However,little is known about the extent to which elevat...Forests exert significant biogeophysical cooling effects(CE)through processes such as increased evapotranspiration,reduced albedo,and enhanced surface roughness.However,little is known about the extent to which elevation-induced temperature differences bias the observed CE and how this bias interacts with the underlying biogeophysical mechanisms.In this study,we integrated multisensor remote sensing products and Shuttle Radar Topography Mission(SRTM)elevation data on the Google Earth Engine(GEE)platform,and applied a spatial-temporal window regression approach to quantify and correct the sensitivity of land surface temperature(LST)to elevation for forest pixels across China from 2001 to 2022.First,we found that forest LST exhibited a significant negative relationship with elevation,leading to systematic CE overestimation by 0.61 K during the day and 0.60 K at night compared with altitudecorrected CE values.Second,after correction,the CE showed clear spatial heterogeneity,with stronger daytime cooling in tropical(-0.54 K)and temperate forests(-0.24 K),and warming in cold(+0.11 K)and arid regions(+0.53 K),while most regions experienced nighttime warming.Among forest types,evergreen needleleaf forests(ENF)exhibited the strongest daytime cooling(-0.36 K),whereas deciduous broadleaf(DBF)and open shrublands(OS)tended to warm.Third,mechanism analysis revealed that elevation correction strengthened the correlations of CE with leaf area index(LAI)and evapotranspiration,while maintaining a significant negative correlation with albedo,indicating that both radiative and non-radiative processes jointly shape the unbiased CE.These findings provide a more accurate quantification of forest CE by eliminating elevation-induced bias,which providing a more accurate assessment of the climate mitigation potential of forests,which is crucial for developing more effective forest management and ecological restoration strategies.展开更多
An instrumental assessment and volunteer subjective evaluation method was developed to synchronously measure the actual skin temperature and evaluate the cool sensation,conducting a quantitative analysis of the percei...An instrumental assessment and volunteer subjective evaluation method was developed to synchronously measure the actual skin temperature and evaluate the cool sensation,conducting a quantitative analysis of the perceived coolness.This method was used to evaluate the effect of a self-developed hot flash spray on reducing the skin temperature and inducing the cooling sensation of menopausal individuals.31 healthy menopausal volunteers were recruited as research subjects.Using infrared thermal imaging and electroencephalogram(EEG)measurements,the skin temperature and EEG data of the subjects’cheeks were simultaneously collected at baseline(BL)immediately after simulated hot flashes(HF),1 min(T1),3 mins(T3)and 5 min(T5)after the application of the test sample.The results showed that,compared with HF,the skin temperature of cheek was significantly reduced by 8.75%,8.75%and 6.41%at T1,T3 and T5(P<0.05),respectively.And alpha-1 value of EEG was increased significantly by 59.70%,58.44%,and 51.39%at T1,T3,and T5(P<0.05),respectively.The hot flash spray effectively reduces skin temperature while also provides subjects with a feeling of coolness,which can relieve hot flashes in menopausal women.展开更多
Micro-alloying is an effective approach for improving the corrosion resistance of cast AZ91.However,the effect of micro-alloyed elements on corrosion resistance can be varied depending on the solidification rate influ...Micro-alloying is an effective approach for improving the corrosion resistance of cast AZ91.However,the effect of micro-alloyed elements on corrosion resistance can be varied depending on the solidification rate influencing the diffusion and precipitation behavior of micro-alloying elements.This study investigated the effects of the cooling rate on the microstructure and corrosion behavior of micro-Ca and-Y alloyed cast AZ91 alloy(i.e.,AZXW9100).To achieve various cooling rates,the alloys were prepared using three methods:steel mold casting(SMC),copper step mold casting(CSMC),and high-pressure die casting(HPDC).The corrosion behavior was analyzed through weight loss measurements,electrochemical impedance spectroscopy,and corrosion morphology observations.The results showed that the key microstructural factors influencing corrosion resistance differed between short-and long-term corrosion.As the cooling rate increased,the short-term corrosion rate was lowered from 0.91 mm/y(SMC)to 0.38 mm/y(HPDC),which was attributed to the decrease in the total area fractions of the eutecticαandβphases acting as galvanic corrosion sources.The long-term corrosion rate was reduced from 17.20 mm/y(SMC)to 0.71 mm/y(HPDC),which was revealed to be due to the enhanced connectivity of theβphase acting as corrosion barriers.Meanwhile,the increase in the cooling rate led to a modification of the Zn molar ratio in theβphase,reducing the Volta potential of theβphase from 101.8 m V to 66.9 m V.This reduction in the Volta potential of the main galvanic source also contributed to improved corrosion resistance.The HPDC AZXW9100 alloy produced in this study exhibited the lowest corrosion rate compared to other alloys.These findings suggest that controlling the cooling rate is a promising strategy for enhancing the corrosion resistance of AZXW9100 alloys.展开更多
Metallic glasses(MG)have attracted considerable attention due to their high hardness,high fracture strength,and excellent corrosion resistance.However,their poor room-temperature plasticity limits their widespread app...Metallic glasses(MG)have attracted considerable attention due to their high hardness,high fracture strength,and excellent corrosion resistance.However,their poor room-temperature plasticity limits their widespread application to some extent.To address this issue,researchers have attempted to introduce crystalline phases into MG to enhance their mechanical properties.Molecular dynamics(MD)simulations are a powerful tool for investigating the properties and deformation mechanisms of amorphous/crystalline dual-phase composite materials.In this study,MD simulations were employed to explore the effect of different cooling rates on the tensile properties of B2-CuZr enhanced bulk-metallic glass composites(BMGCs).Molecular dynamics simulations were conducted on B2-CuZr enhanced BMGCs at an ambient temperature of 300 K.The results indicate that as the cooling rate decreases,from 100 K/ps,10 K/ps,1 K/ps,0.5 K/ps,the content of〈0,0,12,0〉polyhedra increases,resulting in improved mechanical strength but reduced plasticity.In this study,as the cooling rate increases from 0.5 K/ps to 100 K/ps,the deformation strain increases from ε=0.407 to ε=0.466.However,the specimens with a cooling rate of 1 K/ps display notably better plasticity,deviating from the trend.This enhancement in plasticity is attributed to the increased presence of〈0,2,8,5〉polyhedra in the 1 K/ps sample.The findings of this study provide valuable insights for the design and fabrication of high-performance metallic glass materials.展开更多
The aluminum(Al)/steel transition joints used in ships are processed from composite plates,and their mechanical properties have a significant impact on the safety of ships.In this paper,the Al/steel composite plate wa...The aluminum(Al)/steel transition joints used in ships are processed from composite plates,and their mechanical properties have a significant impact on the safety of ships.In this paper,the Al/steel composite plate was prepared using rolling,with 5083 aluminum plate as the cladding plate,Q235 steel plate as the substrate,and TA1 titanium(Ti)plate and DT4 pure iron(Fe)plate as the intermediate layers.The heterothermic billet was prepared through induction heating by the magnetic effects of the steel plate and the pure Fe plate,and then the Al/steel composite plate was obtained by rolling.The impacts of post-rolling cooling process on the microstructure and properties of the Al/Ti/pure Fe/steel composite plate were studied.The results manifested that the pure Fe/steel interface had a good composite effect.With the increase in the cooling rate,the bonding strength of the Al/Ti interface was raised,and that of the Ti/Fe interface was increased first and then decreased.When the oil cooling process was adopted,the Al/Ti/pure Fe/steel composite plate exhibited the highest comprehensive performance.The shear strength of the Al/Ti interface and the Ti/Fe interface was 102 MPa and 186 MPa,respectively.The plastic fracture was determined as the mode of interface fracture.展开更多
The cooling rate of the center and edge of vacuum induction melting(VIM)or vacuum arc remelting(VAR)ingots exhibit substantial difference,leading to markedly distinct dendritic structures and precipitates.The current ...The cooling rate of the center and edge of vacuum induction melting(VIM)or vacuum arc remelting(VAR)ingots exhibit substantial difference,leading to markedly distinct dendritic structures and precipitates.The current lack of precise predictions for dendritic segregation and the distribution of precipitates in ingot makes it difficult to determine the annealing and homogenization heat treatment process.Thus,clarifying the impact of cooling rate on the solidification behavior of alloy is significantly important.The dendritic structure and precipitation characteristics of as-cast C-HRA-3 Ni–Cr–Co–Mo-based heat-resistant alloy were investigated using Thermo-Calc thermodynamic calculations,scanning electron microscopy observations,and electron probe microanalyzer.Based on high temperature observation system,the effects of cooling rate on the dendritic structure,dendritic segregation,and precipitation in this alloy were explored.The results showed that the precipitates in the as-cast C-HRA-3 alloy primarily consist of blocky Ti(C,N)phases,large-sized Ti(C,N)–M_(6)C–M_(23)C_(6) symbiotic phases and M_(6)C–M_(23)C_(6) carbides,and small-sized dispersed M_(6)C and M_(23)C_(6) carbides surronding these symbiotic phases.The primary constituent elements of these precipitates are Mo,Cr,C,and Ti,which predominantly concentrate in the interdendritic regions of the as-cast alloy.There is a clear power-law relationship between the secondary dendrite arm spacing and the cooling rate.The dendritic segregation ratio of Mo,Cr,and Ti exhibits a piecewise functional relationship with the cooling rate,under equiaxed dendritic solidification condition.These predictive models and theoretical analyses were validated using numerical simulations and experimental results from the 200 kg grade VIM electrode.展开更多
The water curtain spray system of the ship helps reduce surface thermal load and lowers thermal infrared radiation, notably enhancing the stealth and survivability of naval ships. The performance of the water curtain ...The water curtain spray system of the ship helps reduce surface thermal load and lowers thermal infrared radiation, notably enhancing the stealth and survivability of naval ships. The performance of the water curtain spray system is largely influenced by the density of the nozzles and their installation height. Therefore, a test platform was established to investigate these critical influencing factors, employing an orthogonal design methodology for the experimental study. Specifically, the study evaluated the effects of varying distances to the steel plate target and different injection heights on the cooling performance of the system. Results demonstrate that using one nozzle per 4 square meters of the ship's surface area effectively lowers the surface temperature, bringing it closer to the ambient background temperature. This nozzle configuration creates irregular infrared heat patterns, which complicate the task for infrared detectors to discern the ship's outline, thus enhancing its infrared stealth. Additionally, maintaining the nozzle installation height within 0.6 m to prevent the temperature difference between the steel plate and the background temperature from exceeding 4 K. Moreover, as the infrared imaging distance increases from 3 to 9 m, the temperature difference measured by the thermocouple and the infrared imager increases by 141.27%. Furthermore, with the increase in infrared imaging distance, the infrared temperature of the target steel plate approaches the background temperature, indicating improved detectability. These findings have significantly enhanced the stealth capabilities of naval ships, maximizing their immunity to infrared-guided weapon attacks. Moreover, their importance in improving the survivability of ships on the water surface cannot be underestimated.展开更多
The study of the spallation of thermal barrier coatings on turbine blades and its influence is of great significance for gas turbine safety operation.However,numerical simulation related to thermal barrier coatings is...The study of the spallation of thermal barrier coatings on turbine blades and its influence is of great significance for gas turbine safety operation.However,numerical simulation related to thermal barrier coatings is difficult and time-costly,which makes it hard to meet engineering demands.Therefore,this work establishes a rapid prediction model for the surface temperature and cooling efficiency of turbine blades with localized spallation of thermal barrier coatings based on a thin-wall thermal resistance model.Firstly,the influence of localized spallation of thermal barrier coatings on the cooling efficiency of typical turbine blades is numerically investigated.Then,based on the simulation data set and multi-layer perception(MLP)neural network,an intelligent prediction model for the temperature and cooling efficiency distribution of localized spallation of coatings is constructed,which can rapidly predict the surface temperature and cooling efficiency of the blade under the situation of spallation of coating at any position on the blade surface.The results show that,under a certain spallation area,the shape of localized coating spallation has little influence on the cooling efficiency,while the increase of spallation thickness will cause a linear increase in the average temperature of the blade surface.The prediction error of the proposed rapid prediction model for the average surface temperature and cooling efficiency of blades is within 2%,and the prediction error of the temperature and cooling efficiency at the spallation position is within 6%for 80%of the samples,with an overall average error within 10%.It is concluded from the rapid prediction model that when the depth of coating spallation increases,the closer the spallation position is to the leading edge of the blade,the greater the difference in cooling efficiency is,and the degree of influence of coating spallation on the cooling efficiency also increases.展开更多
The ductile-to-brittle transition temperature(DBTT)of high strength steels can be optimized by tailoring microstructure and crystallographic orientation characteristics,where the start cooling temperature plays a key ...The ductile-to-brittle transition temperature(DBTT)of high strength steels can be optimized by tailoring microstructure and crystallographic orientation characteristics,where the start cooling temperature plays a key role.In this work,X70 steels with different start cooling temperatures were prepared through thermo-mechanical control process.The quasi-polygonal ferrite(QF),granular bainite(GB),bainitic ferrite(BF)and martensite-austenite constituents were formed at the start cooling temperatures of 780℃(C1),740℃(C2)and 700℃(C3).As start cooling temperature decreased,the amount of GB decreased,the microstructure of QF and BF increased.Microstructure characteristics of the three samples,such as high-angle grain boundaries(HAGBs),MA constituents and crystallographic orientation,also varied with the start cooling temperatures.C2 sample had the lowest DBTT value(−86℃)for its highest fraction of HAGBs,highest content of<110>oriented grains and lowest content of<001>oriented grains parallel to TD.The high density of{332}<113>and low density of rotated cube{001}<110>textures also contributed to the best impact toughness of C2 sample.In addition,a modified model was used in this paper to quantitatively predict the approximate DBTT value of steels.展开更多
By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,t...By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,the interior heating power would increase the working temperature and fire risk,which would suppress their above-ambient heat dissipation capabilities and passive water cycle properties.In this work,we introduced a REC design based on an all-in-one photonic hydrogel for above-ambient heat dissipation and flame retardancy.Unlike conventional design RC film for heat dissipation with limited cooling power and fire risk,REC hydrogel can greatly improve the heat dissipation performance in the daytime with a high workload,indicating a 12.0℃lower temperature than the RC film under the same conditions in the outdoor experiment.In the nighttime with a low workload,RC-assisted adsorption can improve atmospheric water harvesting to ensure EC in the daytime.In addition,our REC hydrogel significantly enhanced flame retardancy by absorbing heat without a corresponding temperature rise,thus mitigating fire risks.Thus,our design shows a promising solution for the thermal management of outdoor devices,delivering outstanding performance in both heat dissipation and flame retardancy.展开更多
In this study,a Gaussian Process Regression(GPR)surrogate model coupled with a Bayesian optimization algorithm was employed for the single-objective design optimization of fan-shaped film cooling holes on a concave wa...In this study,a Gaussian Process Regression(GPR)surrogate model coupled with a Bayesian optimization algorithm was employed for the single-objective design optimization of fan-shaped film cooling holes on a concave wall.Fan-shaped holes,commonly used in gas turbines and aerospace applications,flare toward the exit to form a protective cooling film over hot surfaces,enhancing thermal protection compared to cylindrical holes.An initial hole configuration was used to improve adiabatic cooling efficiency.Design variables included the hole injection angle,forward expansion angle,lateral expansion angle,and aperture ratio,while the objective function was the average adiabatic cooling efficiency of the concave wall surface.Optimization was performed at two representative blowing ratios,M=1.0 and M=1.5,using the GPR-based surrogate model to accelerate exploration,with the Bayesian algorithm identifying optimal configurations.Results indicate that the optimized fan-shaped holes increased cooling efficiency by 15.2%and 12.3%at low and high blowing ratios,respectively.Analysis of flow and thermal fields further revealed how the optimized geometry influenced coolant distribution and heat transfer,providing insight into the mechanisms driving the improved cooling performance.展开更多
Methods allowing passive daytime radiative cooling(PDRC)to be carried out in an energy-efficient and scalable way are potentially important for various disciplines.Here,we report a sustainable strategy for scalable-de...Methods allowing passive daytime radiative cooling(PDRC)to be carried out in an energy-efficient and scalable way are potentially important for various disciplines.Here,we report a sustainable strategy for scalable-designed and color-regulating PDRC coating based on high-crystallinity photonic metamaterial(crystallinity:71.5%;enhanced assembly efficiency:72%),that is derived from the as-prepared 55 wt%solid content poly(methyl methacrylate-butyl acrylate-methacrylic acid)P(MMA-BA-MAA)monodispersed latexes(approaching theoretical limit:59 wt%).Robust meter-scale PDRC coatings are constructed by various industrial modes onto diverse surfaces,addressing bottlenecks like dull appearance,high cost,low efficiency,and hard construction.Notably,the solar reflectance,long-wave infrared emittance,and calculated theoretical cooling power of the designed PDRC coating,respectively,reach~0.94,~0.97,and~95.5 W m^(-2)under solar radiation,which can achieve an average 5.3℃ sub-ambient daytime temperature drop in the summer in Nanjing.The cooling performance,scale preparation,and cost-effectiveness of the PDRC coating have extended into leading position compared with those of state-of-the-art designs.This work provides promising route to reduce carbon emissions and energy consumption for global sustainability.展开更多
Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emissi...Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emission of these textiles significantly hinders their efficient radiative heat exchange with self-heated objects,thereby posing a significant challenge to their versatile cooling applicability.Herein,we present a bicomponent blow spinning strategy for the production of scalable,ultra-flexible,and healable textiles featuring a tailored dual gradient in both chemical composition and fiber diameter.The gradient in the fiber diameter of this textile introduces a hierarchically porous structure across the sunlight incident area,thereby achieving a competitive solar reflectivity of 98.7%on its outer surface.Additionally,the gradient in the chemical composition of this textile contributes to the formation of Janus infrared-absorbing surfaces:The outer surface demonstrates a high mid-infrared emission,whereas the inner surface shows a broad infrared absorptivity,facilitating radiative heat exchange with underlying self-heated objects.Consequently,this textile demonstrates multi-scenario radiative cooling capabilities,enabling versatile outdoor cooling for unheated objects by 7.8℃ and self-heated objects by 13.6℃,compared to commercial sunshade fabrics.展开更多
Radiative cooling passively emits heat to outer space without energy input,offering promise for energy-efficient thermal management.It is an important solution to promote the low-carbon environmental protection strate...Radiative cooling passively emits heat to outer space without energy input,offering promise for energy-efficient thermal management.It is an important solution to promote the low-carbon environmental protection strategy.With the continuous development of radiative cooling technologies,the material selection,preparation process,structural design,and applica-tion fields have also made more diverse progress.Therefore,this review aims to systematically introduce the fundamental concepts and underlying principles of radiative cooling.A summary of the commonly used materials for radiative cooling is provided.In addition,the advanced fabrication processes and structural designs of radiative cooling materials are further explored and discussed.Subsequently,the unique functions of radiative cooling materials are highlighted to enhance their applicability and usefulness across various fields.An overview of combining radiative cooling materials with different fields is also provided.In reality,these applications hold the potential to improve thermal management across a range of fields.Finally,it summarizes the shortcomings and great potential of radiative cooling materials in various fields.It also looks forward to the future,aiming to promote the progress and widespread adoption of radiative cooling technologies.展开更多
The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF...The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF)argon plasma,and the temperatures were measured using a DPV-2000 monitor.A model combining the electromagnetism,thermal flow,and heat transfer characteristics of powder during in-flight heating in argon plasma was proposed.The melting processes of CeO_(2)powders of different diameters,with and without thermal resistance effect,were investigated.Results show that the heating process of CeO_(2)powder particles consists of three main stages,one of which is relevant to a dimensionless parameter known as the Biot number.When the Biot value≥0.1,thermal resistance increases significantly,especially for the larger powders.The predicted temperature of the particles at the outlet(1800–2880 K)is in good agreement with the experimental result.展开更多
The influences of silicon addition to commercially pure magnesium(CP Mg)and cooling rate during solidification on the as-cast microstructure and shear mechanical properties of Mg-Si alloys were systematically investig...The influences of silicon addition to commercially pure magnesium(CP Mg)and cooling rate during solidification on the as-cast microstructure and shear mechanical properties of Mg-Si alloys were systematically investigated.For this purpose,the Mg-0.6Si,Mg-1.34Si,and Mg-3Si(wt%)alloys were considered as hypoeutectic,eutectic,and hypereutectic alloys,respectively.By decreasing the geometrical modulus of the solidifying section(increasing cooling rate),remarkable grain refinement,refining the dendrite arm spacing(DAS),and modification of Mg_(2)Si particles were achieved.Moreover,the grain size was refined via Si addition in the hypoeutectic range,while coarsening of grain size at high Si concentrations was observed.The results of shear punch testing and hardness measurements demonstrated that the ultimate shear strength(USS)and hardness increased by increasing the cooling rate during solidification.Moreover,Si addition generally improved hardness,while the highest USS level was achieved for the eutectic alloy due to the fine grain size and strengthening effect of the eutectic constituent.However,regarding the hypereutectic Mg-3Si alloy that exhibited high hardness,the shear properties were inferior due to the detrimental effect of the primary Mg_(2)Si particles.Finally,the results were discussed with consideration of the relationship between strength and hardness,for which the critical effect of Si was clarified.展开更多
Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for...Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for mitigating the energy crisis.A comprehensive review connecting the advancements in engineered radiative cooling systems(ERCSs),encompassing material and structural design as well as thermal and energy-related applications,is currently absent.Herein,this review begins with a concise summary of the essential concepts of ERCSs,followed by an introduction to engineered materials and structures,containing nature-inspired designs,chromatic materials,meta-structural configurations,and multilayered constructions.It subsequently encapsulates the primary applications,including thermal-regulating textiles and energy-saving devices.Next,it highlights the challenges of ERCSs,including maximized thermoregulatory effects,environmental adaptability,scalability and sustainability,and interdisciplinary integration.It seeks to offer direction for forthcoming fundamental research and industrial advancement of radiative cooling systems in real-world applications.展开更多
This work examines the microstructure and corrosion properties of fine-grained Al 7075 across different regions under varying cooling conditions during friction stir welding.The findings demonstrate that forced coolin...This work examines the microstructure and corrosion properties of fine-grained Al 7075 across different regions under varying cooling conditions during friction stir welding.The findings demonstrate that forced cooling significantly improves the corrosion resistance of the welded joints.Specifically,the corrosion resistance was the highest in the stir zone,followed by the thermo-mechanical affected zone,and then the heat affected zone.Forced cooling mitigates grain growth by controlling the welding thermal effects,thereby increasing the proportion ofΣ3 grain boundaries.The modification of these microstructural characteristics promotes the formation of a dense oxide layer,thereby enhancing the corrosion resistance.Furthermore,forced cooling mitigates the precipitation and coarsening of the anodic phase in the stir zone,which in turn reduces the susceptibility of the joint to pitting corrosion.Additionally,the lower recrystallization texture content in the joint,resulting from forced cooling,contributes to a reduction in the number of corrosion-active sites,thereby further improving the corrosion performance of the welded joint.展开更多
Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electro...Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis.展开更多
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52474362,52174317 and 51904146)the General Project Funded by Liaoning Province Education Department(Grant No.JYTMS20230943)。
文摘The high-alloyed wrought superalloy GH4975 tends to form coarse MC carbides and eutectic(γ+γ′)phases,which adversely affect the cogging and homogenization process.To provide theoretical guidance for control of MC carbides and eutectic(γ+γ′)formation,differential thermal analysis(DTA)was utilized to investigate the effect of cooing rate(10-90℃·min^(-1))on solidification behavior and micro-segregation of GH4975 alloy.According to the thermodynamic calculation and distribution characteristics of precipitates,the MC carbides can act as nucleation sites forγdendrites,but the nucleation ofγdendrites becomes less dependent on the MC carbide primers at higher cooling rates.As theγdendrites grow,the elements including Ti and Nb gradually accumulate in the residual liquid and leads to the formation of more MC carbides near the interdendritic region.Finally,the solidification is terminated with the formation of eutectic(γ+γ′).With an increase in cooling rate,the liquidus temperature rises,but the solidus temperature decreases,and thus the solidification range is obviously enlarged.The dendritic structure is significantly refined by the increase of cooling rate.The secondary dendrite arm spacing,λ_(2),as a function of cooling rate,T,can be expressed asλ_(2)=216.78T^(-0.42).Moreover,the increasing cooling rate weakens the back diffusion of Al,Ti,and Nb,increases the undercooling,and limits the growth of precipitates.Consequently,the sizes of MC carbides,eutectic(γ+γ′),and primaryγ′significantly decrease,but the area fraction of eutectic(γ+γ′)linerly increases as the cooling rate rises.Thus moderate cooling rate(such as 30℃·min^(-1))should be selected during the solidification process of GH4975 alloy.
基金Under the auspices of National Social Sciences Foundation of China(No.21BJY114)。
文摘Forests exert significant biogeophysical cooling effects(CE)through processes such as increased evapotranspiration,reduced albedo,and enhanced surface roughness.However,little is known about the extent to which elevation-induced temperature differences bias the observed CE and how this bias interacts with the underlying biogeophysical mechanisms.In this study,we integrated multisensor remote sensing products and Shuttle Radar Topography Mission(SRTM)elevation data on the Google Earth Engine(GEE)platform,and applied a spatial-temporal window regression approach to quantify and correct the sensitivity of land surface temperature(LST)to elevation for forest pixels across China from 2001 to 2022.First,we found that forest LST exhibited a significant negative relationship with elevation,leading to systematic CE overestimation by 0.61 K during the day and 0.60 K at night compared with altitudecorrected CE values.Second,after correction,the CE showed clear spatial heterogeneity,with stronger daytime cooling in tropical(-0.54 K)and temperate forests(-0.24 K),and warming in cold(+0.11 K)and arid regions(+0.53 K),while most regions experienced nighttime warming.Among forest types,evergreen needleleaf forests(ENF)exhibited the strongest daytime cooling(-0.36 K),whereas deciduous broadleaf(DBF)and open shrublands(OS)tended to warm.Third,mechanism analysis revealed that elevation correction strengthened the correlations of CE with leaf area index(LAI)and evapotranspiration,while maintaining a significant negative correlation with albedo,indicating that both radiative and non-radiative processes jointly shape the unbiased CE.These findings provide a more accurate quantification of forest CE by eliminating elevation-induced bias,which providing a more accurate assessment of the climate mitigation potential of forests,which is crucial for developing more effective forest management and ecological restoration strategies.
文摘An instrumental assessment and volunteer subjective evaluation method was developed to synchronously measure the actual skin temperature and evaluate the cool sensation,conducting a quantitative analysis of the perceived coolness.This method was used to evaluate the effect of a self-developed hot flash spray on reducing the skin temperature and inducing the cooling sensation of menopausal individuals.31 healthy menopausal volunteers were recruited as research subjects.Using infrared thermal imaging and electroencephalogram(EEG)measurements,the skin temperature and EEG data of the subjects’cheeks were simultaneously collected at baseline(BL)immediately after simulated hot flashes(HF),1 min(T1),3 mins(T3)and 5 min(T5)after the application of the test sample.The results showed that,compared with HF,the skin temperature of cheek was significantly reduced by 8.75%,8.75%and 6.41%at T1,T3 and T5(P<0.05),respectively.And alpha-1 value of EEG was increased significantly by 59.70%,58.44%,and 51.39%at T1,T3,and T5(P<0.05),respectively.The hot flash spray effectively reduces skin temperature while also provides subjects with a feeling of coolness,which can relieve hot flashes in menopausal women.
基金supported by the Materials and Components Technology Development Program of the Ministry of Trade,Industry,and Energy(MOTIE,South Korea)(No.20024843)。
文摘Micro-alloying is an effective approach for improving the corrosion resistance of cast AZ91.However,the effect of micro-alloyed elements on corrosion resistance can be varied depending on the solidification rate influencing the diffusion and precipitation behavior of micro-alloying elements.This study investigated the effects of the cooling rate on the microstructure and corrosion behavior of micro-Ca and-Y alloyed cast AZ91 alloy(i.e.,AZXW9100).To achieve various cooling rates,the alloys were prepared using three methods:steel mold casting(SMC),copper step mold casting(CSMC),and high-pressure die casting(HPDC).The corrosion behavior was analyzed through weight loss measurements,electrochemical impedance spectroscopy,and corrosion morphology observations.The results showed that the key microstructural factors influencing corrosion resistance differed between short-and long-term corrosion.As the cooling rate increased,the short-term corrosion rate was lowered from 0.91 mm/y(SMC)to 0.38 mm/y(HPDC),which was attributed to the decrease in the total area fractions of the eutecticαandβphases acting as galvanic corrosion sources.The long-term corrosion rate was reduced from 17.20 mm/y(SMC)to 0.71 mm/y(HPDC),which was revealed to be due to the enhanced connectivity of theβphase acting as corrosion barriers.Meanwhile,the increase in the cooling rate led to a modification of the Zn molar ratio in theβphase,reducing the Volta potential of theβphase from 101.8 m V to 66.9 m V.This reduction in the Volta potential of the main galvanic source also contributed to improved corrosion resistance.The HPDC AZXW9100 alloy produced in this study exhibited the lowest corrosion rate compared to other alloys.These findings suggest that controlling the cooling rate is a promising strategy for enhancing the corrosion resistance of AZXW9100 alloys.
基金supported by the National Natural Science Foundation of China(Grant No.52471005)the Guangdong Basic and Applied Basic Research Foundation(Grant No.2024A1515010878)。
文摘Metallic glasses(MG)have attracted considerable attention due to their high hardness,high fracture strength,and excellent corrosion resistance.However,their poor room-temperature plasticity limits their widespread application to some extent.To address this issue,researchers have attempted to introduce crystalline phases into MG to enhance their mechanical properties.Molecular dynamics(MD)simulations are a powerful tool for investigating the properties and deformation mechanisms of amorphous/crystalline dual-phase composite materials.In this study,MD simulations were employed to explore the effect of different cooling rates on the tensile properties of B2-CuZr enhanced bulk-metallic glass composites(BMGCs).Molecular dynamics simulations were conducted on B2-CuZr enhanced BMGCs at an ambient temperature of 300 K.The results indicate that as the cooling rate decreases,from 100 K/ps,10 K/ps,1 K/ps,0.5 K/ps,the content of〈0,0,12,0〉polyhedra increases,resulting in improved mechanical strength but reduced plasticity.In this study,as the cooling rate increases from 0.5 K/ps to 100 K/ps,the deformation strain increases from ε=0.407 to ε=0.466.However,the specimens with a cooling rate of 1 K/ps display notably better plasticity,deviating from the trend.This enhancement in plasticity is attributed to the increased presence of〈0,2,8,5〉polyhedra in the 1 K/ps sample.The findings of this study provide valuable insights for the design and fabrication of high-performance metallic glass materials.
基金Supported by Science Research Project of Hebei Education Department(Grant No.BJK2024138)Hebei Provincial Natural Science Foundation(Grant No.E2023203129)National Natural Science Foundation of China(Grant Nos.52004242,52075472).
文摘The aluminum(Al)/steel transition joints used in ships are processed from composite plates,and their mechanical properties have a significant impact on the safety of ships.In this paper,the Al/steel composite plate was prepared using rolling,with 5083 aluminum plate as the cladding plate,Q235 steel plate as the substrate,and TA1 titanium(Ti)plate and DT4 pure iron(Fe)plate as the intermediate layers.The heterothermic billet was prepared through induction heating by the magnetic effects of the steel plate and the pure Fe plate,and then the Al/steel composite plate was obtained by rolling.The impacts of post-rolling cooling process on the microstructure and properties of the Al/Ti/pure Fe/steel composite plate were studied.The results manifested that the pure Fe/steel interface had a good composite effect.With the increase in the cooling rate,the bonding strength of the Al/Ti interface was raised,and that of the Ti/Fe interface was increased first and then decreased.When the oil cooling process was adopted,the Al/Ti/pure Fe/steel composite plate exhibited the highest comprehensive performance.The shear strength of the Al/Ti interface and the Ti/Fe interface was 102 MPa and 186 MPa,respectively.The plastic fracture was determined as the mode of interface fracture.
基金funded by the National Key R&D Program Funded Projects(No.2021YFB3704102).
文摘The cooling rate of the center and edge of vacuum induction melting(VIM)or vacuum arc remelting(VAR)ingots exhibit substantial difference,leading to markedly distinct dendritic structures and precipitates.The current lack of precise predictions for dendritic segregation and the distribution of precipitates in ingot makes it difficult to determine the annealing and homogenization heat treatment process.Thus,clarifying the impact of cooling rate on the solidification behavior of alloy is significantly important.The dendritic structure and precipitation characteristics of as-cast C-HRA-3 Ni–Cr–Co–Mo-based heat-resistant alloy were investigated using Thermo-Calc thermodynamic calculations,scanning electron microscopy observations,and electron probe microanalyzer.Based on high temperature observation system,the effects of cooling rate on the dendritic structure,dendritic segregation,and precipitation in this alloy were explored.The results showed that the precipitates in the as-cast C-HRA-3 alloy primarily consist of blocky Ti(C,N)phases,large-sized Ti(C,N)–M_(6)C–M_(23)C_(6) symbiotic phases and M_(6)C–M_(23)C_(6) carbides,and small-sized dispersed M_(6)C and M_(23)C_(6) carbides surronding these symbiotic phases.The primary constituent elements of these precipitates are Mo,Cr,C,and Ti,which predominantly concentrate in the interdendritic regions of the as-cast alloy.There is a clear power-law relationship between the secondary dendrite arm spacing and the cooling rate.The dendritic segregation ratio of Mo,Cr,and Ti exhibits a piecewise functional relationship with the cooling rate,under equiaxed dendritic solidification condition.These predictive models and theoretical analyses were validated using numerical simulations and experimental results from the 200 kg grade VIM electrode.
基金Supported by the Research Fund of Key Laboratory of Aircraft Environment Control and Life Support,MIIT,Nanjing University of Aeronautics and Astronautics (Grant No. KLAECLSE-202201)。
文摘The water curtain spray system of the ship helps reduce surface thermal load and lowers thermal infrared radiation, notably enhancing the stealth and survivability of naval ships. The performance of the water curtain spray system is largely influenced by the density of the nozzles and their installation height. Therefore, a test platform was established to investigate these critical influencing factors, employing an orthogonal design methodology for the experimental study. Specifically, the study evaluated the effects of varying distances to the steel plate target and different injection heights on the cooling performance of the system. Results demonstrate that using one nozzle per 4 square meters of the ship's surface area effectively lowers the surface temperature, bringing it closer to the ambient background temperature. This nozzle configuration creates irregular infrared heat patterns, which complicate the task for infrared detectors to discern the ship's outline, thus enhancing its infrared stealth. Additionally, maintaining the nozzle installation height within 0.6 m to prevent the temperature difference between the steel plate and the background temperature from exceeding 4 K. Moreover, as the infrared imaging distance increases from 3 to 9 m, the temperature difference measured by the thermocouple and the infrared imager increases by 141.27%. Furthermore, with the increase in infrared imaging distance, the infrared temperature of the target steel plate approaches the background temperature, indicating improved detectability. These findings have significantly enhanced the stealth capabilities of naval ships, maximizing their immunity to infrared-guided weapon attacks. Moreover, their importance in improving the survivability of ships on the water surface cannot be underestimated.
基金supported by the National Natural Science Foundation of China(No.52206090)the Jiangsu Provincial Natural Science Foundation(No.BK20220901)+2 种基金the National Major Science and Technology Projects of China(No.Y2022-Ⅲ-0004-0013)Engineering Research Center of Low-Carbon Aerospace Power Ministry of Education(No.CEPE2024020)the China Postdoctoral Science Foundation(No.2022TQ0149).
文摘The study of the spallation of thermal barrier coatings on turbine blades and its influence is of great significance for gas turbine safety operation.However,numerical simulation related to thermal barrier coatings is difficult and time-costly,which makes it hard to meet engineering demands.Therefore,this work establishes a rapid prediction model for the surface temperature and cooling efficiency of turbine blades with localized spallation of thermal barrier coatings based on a thin-wall thermal resistance model.Firstly,the influence of localized spallation of thermal barrier coatings on the cooling efficiency of typical turbine blades is numerically investigated.Then,based on the simulation data set and multi-layer perception(MLP)neural network,an intelligent prediction model for the temperature and cooling efficiency distribution of localized spallation of coatings is constructed,which can rapidly predict the surface temperature and cooling efficiency of the blade under the situation of spallation of coating at any position on the blade surface.The results show that,under a certain spallation area,the shape of localized coating spallation has little influence on the cooling efficiency,while the increase of spallation thickness will cause a linear increase in the average temperature of the blade surface.The prediction error of the proposed rapid prediction model for the average surface temperature and cooling efficiency of blades is within 2%,and the prediction error of the temperature and cooling efficiency at the spallation position is within 6%for 80%of the samples,with an overall average error within 10%.It is concluded from the rapid prediction model that when the depth of coating spallation increases,the closer the spallation position is to the leading edge of the blade,the greater the difference in cooling efficiency is,and the degree of influence of coating spallation on the cooling efficiency also increases.
基金Project(2018XK2301) supported by the Change-Zhu-Tan National Independent Innavation Demonstration Zone Special Program,China。
文摘The ductile-to-brittle transition temperature(DBTT)of high strength steels can be optimized by tailoring microstructure and crystallographic orientation characteristics,where the start cooling temperature plays a key role.In this work,X70 steels with different start cooling temperatures were prepared through thermo-mechanical control process.The quasi-polygonal ferrite(QF),granular bainite(GB),bainitic ferrite(BF)and martensite-austenite constituents were formed at the start cooling temperatures of 780℃(C1),740℃(C2)and 700℃(C3).As start cooling temperature decreased,the amount of GB decreased,the microstructure of QF and BF increased.Microstructure characteristics of the three samples,such as high-angle grain boundaries(HAGBs),MA constituents and crystallographic orientation,also varied with the start cooling temperatures.C2 sample had the lowest DBTT value(−86℃)for its highest fraction of HAGBs,highest content of<110>oriented grains and lowest content of<001>oriented grains parallel to TD.The high density of{332}<113>and low density of rotated cube{001}<110>textures also contributed to the best impact toughness of C2 sample.In addition,a modified model was used in this paper to quantitatively predict the approximate DBTT value of steels.
基金financially supported by the Science and Technology Innovation Program of Hunan Province(2024RC3003)the Central South University Innovation-Driven Research Programme(2023CXQD012)the Initiative for Sustainable Energy for its financial support。
文摘By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,the interior heating power would increase the working temperature and fire risk,which would suppress their above-ambient heat dissipation capabilities and passive water cycle properties.In this work,we introduced a REC design based on an all-in-one photonic hydrogel for above-ambient heat dissipation and flame retardancy.Unlike conventional design RC film for heat dissipation with limited cooling power and fire risk,REC hydrogel can greatly improve the heat dissipation performance in the daytime with a high workload,indicating a 12.0℃lower temperature than the RC film under the same conditions in the outdoor experiment.In the nighttime with a low workload,RC-assisted adsorption can improve atmospheric water harvesting to ensure EC in the daytime.In addition,our REC hydrogel significantly enhanced flame retardancy by absorbing heat without a corresponding temperature rise,thus mitigating fire risks.Thus,our design shows a promising solution for the thermal management of outdoor devices,delivering outstanding performance in both heat dissipation and flame retardancy.
基金supported by the Jiangsu Association for Science and Technology,grant number SKX 0225089the National Natural Science Foundation of China,grant number 52476027.
文摘In this study,a Gaussian Process Regression(GPR)surrogate model coupled with a Bayesian optimization algorithm was employed for the single-objective design optimization of fan-shaped film cooling holes on a concave wall.Fan-shaped holes,commonly used in gas turbines and aerospace applications,flare toward the exit to form a protective cooling film over hot surfaces,enhancing thermal protection compared to cylindrical holes.An initial hole configuration was used to improve adiabatic cooling efficiency.Design variables included the hole injection angle,forward expansion angle,lateral expansion angle,and aperture ratio,while the objective function was the average adiabatic cooling efficiency of the concave wall surface.Optimization was performed at two representative blowing ratios,M=1.0 and M=1.5,using the GPR-based surrogate model to accelerate exploration,with the Bayesian algorithm identifying optimal configurations.Results indicate that the optimized fan-shaped holes increased cooling efficiency by 15.2%and 12.3%at low and high blowing ratios,respectively.Analysis of flow and thermal fields further revealed how the optimized geometry influenced coolant distribution and heat transfer,providing insight into the mechanisms driving the improved cooling performance.
基金support of the National Natural Science Foundation of China(grant 22508184 to X.Q.Y.,grant 21736006 to S.C.,and grant 22278225 to S.C.)supported by the Natural Funding Program of Jiangsu Province(grant BK20250610 to X.Q.Y.).
文摘Methods allowing passive daytime radiative cooling(PDRC)to be carried out in an energy-efficient and scalable way are potentially important for various disciplines.Here,we report a sustainable strategy for scalable-designed and color-regulating PDRC coating based on high-crystallinity photonic metamaterial(crystallinity:71.5%;enhanced assembly efficiency:72%),that is derived from the as-prepared 55 wt%solid content poly(methyl methacrylate-butyl acrylate-methacrylic acid)P(MMA-BA-MAA)monodispersed latexes(approaching theoretical limit:59 wt%).Robust meter-scale PDRC coatings are constructed by various industrial modes onto diverse surfaces,addressing bottlenecks like dull appearance,high cost,low efficiency,and hard construction.Notably,the solar reflectance,long-wave infrared emittance,and calculated theoretical cooling power of the designed PDRC coating,respectively,reach~0.94,~0.97,and~95.5 W m^(-2)under solar radiation,which can achieve an average 5.3℃ sub-ambient daytime temperature drop in the summer in Nanjing.The cooling performance,scale preparation,and cost-effectiveness of the PDRC coating have extended into leading position compared with those of state-of-the-art designs.This work provides promising route to reduce carbon emissions and energy consumption for global sustainability.
基金financial support from the National Natural Science Foundation of China(Grant No.52273067,52233006)the Fundamental Research Funds for the Central Universities(Grant No.2232023A-03)+3 种基金the Shuguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission(Grant No.23SG29)the Natural Science Foundation of Shanghai(Grant No.24ZR1402400)the Shanghai Scientific and Technological Innovation Project(Grant No.24520713000)Innovation Program of Shanghai Municipal Education Commission(Grant No.2021-01-07-00-03-E00108).
文摘Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emission of these textiles significantly hinders their efficient radiative heat exchange with self-heated objects,thereby posing a significant challenge to their versatile cooling applicability.Herein,we present a bicomponent blow spinning strategy for the production of scalable,ultra-flexible,and healable textiles featuring a tailored dual gradient in both chemical composition and fiber diameter.The gradient in the fiber diameter of this textile introduces a hierarchically porous structure across the sunlight incident area,thereby achieving a competitive solar reflectivity of 98.7%on its outer surface.Additionally,the gradient in the chemical composition of this textile contributes to the formation of Janus infrared-absorbing surfaces:The outer surface demonstrates a high mid-infrared emission,whereas the inner surface shows a broad infrared absorptivity,facilitating radiative heat exchange with underlying self-heated objects.Consequently,this textile demonstrates multi-scenario radiative cooling capabilities,enabling versatile outdoor cooling for unheated objects by 7.8℃ and self-heated objects by 13.6℃,compared to commercial sunshade fabrics.
基金National Natural Science Foundation of China Excellent Youth Fund(No.52222509)the Foundation for Innovative Research Groups of the National Natural Science Foundation of China(No.52021003)+3 种基金National Key Research and Development Program of China(No.2018YFA0703300)National Natural Science Foundation of China(No.52105298)Science and Technology Development Program of Jilin Province(No.SKL202402005)"Fundamental Research Funds for the Central Universities".
文摘Radiative cooling passively emits heat to outer space without energy input,offering promise for energy-efficient thermal management.It is an important solution to promote the low-carbon environmental protection strategy.With the continuous development of radiative cooling technologies,the material selection,preparation process,structural design,and applica-tion fields have also made more diverse progress.Therefore,this review aims to systematically introduce the fundamental concepts and underlying principles of radiative cooling.A summary of the commonly used materials for radiative cooling is provided.In addition,the advanced fabrication processes and structural designs of radiative cooling materials are further explored and discussed.Subsequently,the unique functions of radiative cooling materials are highlighted to enhance their applicability and usefulness across various fields.An overview of combining radiative cooling materials with different fields is also provided.In reality,these applications hold the potential to improve thermal management across a range of fields.Finally,it summarizes the shortcomings and great potential of radiative cooling materials in various fields.It also looks forward to the future,aiming to promote the progress and widespread adoption of radiative cooling technologies.
基金National Natural Science Foundation of China(11875039)Shanxi Scholarship Council of China(2023-033)+2 种基金Fundamental Research Program of Shanxi Province(202303021221071)China Baowu Low Carbon Metallurgical Innovation Foundation(2022)2023 Anhui Major Industrial Innovation Plan Project。
文摘The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF)argon plasma,and the temperatures were measured using a DPV-2000 monitor.A model combining the electromagnetism,thermal flow,and heat transfer characteristics of powder during in-flight heating in argon plasma was proposed.The melting processes of CeO_(2)powders of different diameters,with and without thermal resistance effect,were investigated.Results show that the heating process of CeO_(2)powder particles consists of three main stages,one of which is relevant to a dimensionless parameter known as the Biot number.When the Biot value≥0.1,thermal resistance increases significantly,especially for the larger powders.The predicted temperature of the particles at the outlet(1800–2880 K)is in good agreement with the experimental result.
文摘The influences of silicon addition to commercially pure magnesium(CP Mg)and cooling rate during solidification on the as-cast microstructure and shear mechanical properties of Mg-Si alloys were systematically investigated.For this purpose,the Mg-0.6Si,Mg-1.34Si,and Mg-3Si(wt%)alloys were considered as hypoeutectic,eutectic,and hypereutectic alloys,respectively.By decreasing the geometrical modulus of the solidifying section(increasing cooling rate),remarkable grain refinement,refining the dendrite arm spacing(DAS),and modification of Mg_(2)Si particles were achieved.Moreover,the grain size was refined via Si addition in the hypoeutectic range,while coarsening of grain size at high Si concentrations was observed.The results of shear punch testing and hardness measurements demonstrated that the ultimate shear strength(USS)and hardness increased by increasing the cooling rate during solidification.Moreover,Si addition generally improved hardness,while the highest USS level was achieved for the eutectic alloy due to the fine grain size and strengthening effect of the eutectic constituent.However,regarding the hypereutectic Mg-3Si alloy that exhibited high hardness,the shear properties were inferior due to the detrimental effect of the primary Mg_(2)Si particles.Finally,the results were discussed with consideration of the relationship between strength and hardness,for which the critical effect of Si was clarified.
基金support from the Contract Research(“Development of Breathable Fabrics with Nano-Electrospun Membrane”,CityU ref.:9231419“Research and application of antibacterial and healing-promoting smart nanofiber dressing for children’s burn wounds”,CityU ref:PJ9240111)+1 种基金the National Natural Science Foundation of China(“Study of Multi-Responsive Shape Memory Polyurethane Nanocomposites Inspired by Natural Fibers”,Grant No.51673162)Startup Grant of CityU(“Laboratory of Wearable Materials for Healthcare”,Grant No.9380116).
文摘Radiative cooling systems(RCSs)possess the distinctive capability to dissipate heat energy via solar and thermal radiation,making them suitable for thermal regulation and energy conservation applications,essential for mitigating the energy crisis.A comprehensive review connecting the advancements in engineered radiative cooling systems(ERCSs),encompassing material and structural design as well as thermal and energy-related applications,is currently absent.Herein,this review begins with a concise summary of the essential concepts of ERCSs,followed by an introduction to engineered materials and structures,containing nature-inspired designs,chromatic materials,meta-structural configurations,and multilayered constructions.It subsequently encapsulates the primary applications,including thermal-regulating textiles and energy-saving devices.Next,it highlights the challenges of ERCSs,including maximized thermoregulatory effects,environmental adaptability,scalability and sustainability,and interdisciplinary integration.It seeks to offer direction for forthcoming fundamental research and industrial advancement of radiative cooling systems in real-world applications.
基金Project(ASM-20240)supported by the Key Laboratory of Advanced Structural Materials(Changchun University of Technology),Ministry of Education,ChinaProject(2022TD-30)supported by the Scientific and Technological Innovation Team Project of Shaanxi Innovation Capability Support Plan,China。
文摘This work examines the microstructure and corrosion properties of fine-grained Al 7075 across different regions under varying cooling conditions during friction stir welding.The findings demonstrate that forced cooling significantly improves the corrosion resistance of the welded joints.Specifically,the corrosion resistance was the highest in the stir zone,followed by the thermo-mechanical affected zone,and then the heat affected zone.Forced cooling mitigates grain growth by controlling the welding thermal effects,thereby increasing the proportion ofΣ3 grain boundaries.The modification of these microstructural characteristics promotes the formation of a dense oxide layer,thereby enhancing the corrosion resistance.Furthermore,forced cooling mitigates the precipitation and coarsening of the anodic phase in the stir zone,which in turn reduces the susceptibility of the joint to pitting corrosion.Additionally,the lower recrystallization texture content in the joint,resulting from forced cooling,contributes to a reduction in the number of corrosion-active sites,thereby further improving the corrosion performance of the welded joint.
基金supported by the National Natural Science Foundation of China(No.62464010)Spring City Plan-Special Program for Young Talents(K202005007)+2 种基金Yunnan Talents Support Plan for Young Talents(XDYC-QNRC-2022-0482)Yunnan Local Colleges Applied Basic Research Projects(202101BA070001-138)Frontier Research Team of Kunming University 2023.
文摘Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis.
