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Understanding users’effective use of generative conversational AI from a media naturalness perspective:a hybrid structural equation modeling-artificial neural network(SEM-ANN)approach
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作者 Kun Wang Yaobin Lu Zhao Pan 《Data Science and Management》 2025年第2期147-159,共13页
Although generative conversational artificial intelligence(AI)can answer questions well and hold conversations as a person,the semantic ambiguity inherent in text-based communication poses challenges to effective use.... Although generative conversational artificial intelligence(AI)can answer questions well and hold conversations as a person,the semantic ambiguity inherent in text-based communication poses challenges to effective use.Effective use reflects the users’utilization of generative conversational AI to achieve their goals,which has not been previously studied.Drawing on the media naturalness theory,we examined how generative conversational AI’s content and style naturalness affect effective use.A two-wave survey was conducted to collect data from 565 users of generative conversational AI.Two techniques were used in this study.Initially,partial least squares structural equation modeling(PLS-SEM)was applied to determine the variables that significantly affected the mechanisms(i.e.,cognitive effort and communication ambiguity)and effective use.Secondly,an artificial neural network model was used to evaluate the relative importance of the significant predictors of mechanisms and effective use identified from the PLS-SEM analysis.The results revealed that the naturalness of content and style differed in their effects on cognitive effort and communication ambiguity.Additionally,cognitive effort and communication ambiguity negatively affected effective use.This study advances the literature on effective use by uncovering the psychological mechanisms underlying effective use and their antecedents.In addition,this study offers insights into the design of generative conversational AI. 展开更多
关键词 Generative conversational AI Content naturalness Style naturalness Effective use SEM-ANN method
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Leveraging We-Media for Enhancing English Conversational Skills
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作者 CHEN Yangtao 《Sino-US English Teaching》 2025年第7期217-221,共5页
In the context of globalization and digitalization,English has emerged as the primary language for international communication,making fluent conversational English skills essential for personal and professional growth... In the context of globalization and digitalization,English has emerged as the primary language for international communication,making fluent conversational English skills essential for personal and professional growth.The advent of We-Media,encompassing various online platforms,such as social media,blogs,and video content,has revolutionized the way English learners acquire and practice conversational skills.This paper explores the effective utilization of We-Media to enhance English conversational abilities,proposing practical strategies for both learners and educators.By integrating theories,such as second language acquisition,communicative language teaching,and media richness theory,the study highlights the strengths and challenges of We-Media in English learning.Through case studies and empirical analysis,the paper demonstrates the positive impact of We-Media on learners’speaking skills,emphasizing the importance of self-management,goal-setting,and consistent practice.The findings suggest that We-Media offers a flexible and diverse learning environment,but its effectiveness depends on learners’ability to self-regulate and employ effective learning strategies.The paper concludes with recommendations for future research and practical suggestions for educators and learners to maximize the benefits of We-Media in English education. 展开更多
关键词 We-Media English conversational skills second language acquisition communicative language teaching media richness theory self-directed learning online learning platforms language learning strategies
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Design of Dipoles for the RF Energy Harvesting System Dedicated to GSM Applications
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作者 Abdoul Karim Mbodji Mohamed El Moctar +1 位作者 Malang Kambaye Ousmane Dieme 《Energy and Power Engineering》 2025年第1期1-12,共12页
Nowadays, we are witnessing an era marked by the autonomy of wireless devices and sensor networks without the aid of batteries. RF energy harvesting therefore becomes a promising alternative for battery dependence. Th... Nowadays, we are witnessing an era marked by the autonomy of wireless devices and sensor networks without the aid of batteries. RF energy harvesting therefore becomes a promising alternative for battery dependence. This work presents the design of an RF energy harvesting system consisting mainly of a rectenna (antenna and rectification circuit) and an adaptation circuit. First of all, we designed two dipole type antennas. One operates in the GSM 900 MHz band and the other in the GSM 1800 MHz band. The performances of the proposed antennas are provided by the ANSYS HFSS software. Secondly, we proposed two rectification circuits in order to obtain conversion efficiencies at 0 dBm of 64% for the system operating at the frequency of 900 MHz and 37% for the system at the frequency of 1800 MHz RF-DC. The rectifiers used are based on Schottky diodes. For maximum transfer of power between the antenna and the rectification circuit, L-type matching circuits have been proposed. This rectifier offers DC voltage values of 806 mV for the circuit at the frequency of 900 MHz and 616 mV for the circuit at the frequency of 1800 MHz. The adaptation circuits are obtained by carrying out simulations on the ADS (Advanced Design System) software. 展开更多
关键词 RECTENNA ANTENNA RF-DC Conversion Schottky Diode Efficiency RF Energy Harvesting
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Unraveling functional neurological disorder in pediatric populations:A systematic review of diagnosis,treatment,and outcomes
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作者 Mohammed Al-Beltagi Nermin Kamal Saeed +2 位作者 Adel Salah Bediwy Eman A Bediwy Reem Elbeltagi 《World Journal of Clinical Pediatrics》 2025年第3期281-317,共37页
BACKGROUND Functional neurological disorder(FND)in children is a complex and multifaceted condition characterized by neurological symptoms that cannot be explained by organic pathology.Despite its prevalence,FND in pe... BACKGROUND Functional neurological disorder(FND)in children is a complex and multifaceted condition characterized by neurological symptoms that cannot be explained by organic pathology.Despite its prevalence,FND in pediatric populations remains under-researched,with challenges in diagnosis and management AIM To synthesize the current literature on FND in children,focusing on clinical presentation,diagnostic approaches,treatment strategies,and outcomes.METHODS A comprehensive literature search was conducted across multiple databases,including PubMed,Scopus,and Web of Science,for articles published up to August 2024.Studies were included if they addressed FND in pediatric populations,specifically focusing on review articles,research articles,systematic reviews,meta-analyses,case reports,guidelines,expert opinions,and editorials.Data extraction and quality assessment were performed according to PRISMA guidelines.A total of 308 articles were included in the final analysis.RESULTS The analysis included 189 review articles,57 research articles,3 systematic reviews and meta-analyses,5 case reports,2 guidelines,5 expert opinions,and 2 editorials.Key findings revealed a broad spectrum of symptoms,including motor and sensory disturbances and psychological factors contributing to the onset and persistence of FND.Diagnostic challenges were frequently highlighted,emphasizing the need for interdisciplinary approaches.Treatment strategies varied,with cognitive-behavioral therapy(CBT)and multidisciplinary care emerging as the most effective approaches.The outcomes varied,with early intervention being critical for a better prognosis.CONCLUSION Early diagnosis and multidisciplinary care,including CBT,are critical for improving outcomes in pediatric FND.Standardized diagnostic criteria and treatment protocols are needed to enhance clinical management. 展开更多
关键词 Functional neurological disorder CHILDREN Pediatric neurology Conversion disorder Psychogenic disorders Cognitive-behavioral therapy Multidisciplinary care DIAGNOSIS Treatment outcomes
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Chloride ion battery:A new emerged electrochemical system for next-generation energy storage 被引量:1
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作者 Shulin Chen Lu Wu +3 位作者 Yu Liu Peng Zhou Qinyou An Liqiang Mai 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期154-168,I0004,共16页
In the scope of developing new electrochemical concepts to build batteries with high energy density,chloride ion batteries(CIBs)have emerged as a candidate for the next generation of novel electrochemical energy stora... In the scope of developing new electrochemical concepts to build batteries with high energy density,chloride ion batteries(CIBs)have emerged as a candidate for the next generation of novel electrochemical energy storage technologies,which show the potential in matching or even surpassing the current lithium metal batteries in terms of energy density,dendrite-free safety,and elimination of the dependence on the strained lithium and cobalt resources.However,the development of CIBs is still at the initial stage with unsatisfactory performance and several challenges have hindered them from reaching commercialization.In this review,we examine the current advances of CIBs by considering the electrode material design to the electrolyte,thus outlining the new opportunities of aqueous CIBs especially combined with desalination,chloride redox battery,etc.With respect to the developing road of lithium ion and fluoride ion batteries,the possibility of using solid-state chloride ion conductors to replace liquid electrolytes is tentatively discussed.Going beyond,perspectives and clear suggestions are concluded by highlighting the major obstacles and by prescribing specific research topics to inspire more efforts for CIBs in large-scale energy storage applications. 展开更多
关键词 Chloride ion battery Anion shuttling Conversion reaction Chloride redox
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BERT for Conversational Question Answering Systems Using Semantic Similarity Estimation
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作者 Abdulaziz Al-Besher Kailash Kumar +1 位作者 M.Sangeetha Tinashe Butsa 《Computers, Materials & Continua》 SCIE EI 2022年第3期4763-4780,共18页
Most of the questions from users lack the context needed to thoroughly understand the problemat hand,thus making the questions impossible to answer.Semantic Similarity Estimation is based on relating user’s questions... Most of the questions from users lack the context needed to thoroughly understand the problemat hand,thus making the questions impossible to answer.Semantic Similarity Estimation is based on relating user’s questions to the context from previous Conversational Search Systems(CSS)to provide answers without requesting the user’s context.It imposes constraints on the time needed to produce an answer for the user.The proposed model enables the use of contextual data associated with previous Conversational Searches(CS).While receiving a question in a new conversational search,the model determines the question that refers tomore pastCS.Themodel then infers past contextual data related to the given question and predicts an answer based on the context inferred without engaging in multi-turn interactions or requesting additional data from the user for context.This model shows the ability to use the limited information in user queries for best context inferences based on Closed-Domain-based CS and Bidirectional Encoder Representations from Transformers for textual representations. 展开更多
关键词 Semantic similarity estimation conversational search multi-turn interactions context inference BERT user intent
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Low-power system model for quantum entangled photon-pair source
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作者 FENG Tianxuan ZHANG Hanyi +3 位作者 FAN Rong MA Honghao DONG Mengcheng LI Lijing 《Journal of Systems Engineering and Electronics》 SCIE CSCD 2024年第5期1287-1294,共8页
The quantum entangled photon-pair source,as an essential component of optical quantum systems,holds great potential for applications such as quantum teleportation,quan-tum computing,and quantum imaging.The current wor... The quantum entangled photon-pair source,as an essential component of optical quantum systems,holds great potential for applications such as quantum teleportation,quan-tum computing,and quantum imaging.The current workhorse technique for preparing photon pairs involves performing spon-taneous parametric down conversion(SPDC)in bulk nonlinear crystals.However,the current power consumption and cost of preparing entangled photon-pair sources are relatively high,pos-ing challenges to their integration and scalability.In this paper,we propose a low-power system model for the quantum entan-gled photon-pair source based on SPDC theory and phase matching technology.This model allows us to analyze the per-formance of each module and the influence of component cha-racteristics on the overall system.In our experimental setup,we utilize a 5 mW laser diode and a typical type-II barium metabo-rate(BBO)crystal to prepare an entangled photon-pair source.The experimental results are in excellent agreement with the model,indicating a significant step towards achieving the goal of low-power and low-cost entangled photon-pair sources.This achievement not only contributes to the practical application of quantum entanglement lighting,but also paves the way for the widespread adoption of optical quantum systems in the future. 展开更多
关键词 low-power system model optical quantum system entangled photon-pair source spontaneous parametric down conversion
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IoT Enabled Microgrid Framework Using a Novel Dispersal Diffusion Artificial Neural Network Controller for PV Systems and Wind Energy to Minimize Electrical Faults
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作者 V V Vijetha Inti V S Vakula 《China Communications》 SCIE CSCD 2024年第12期217-230,共14页
A system based on a PV-Wind will ensure better efficiency and flexibility using lower energy production.Today,plenty of work is being focussed on Doubly Fed Induction Generators(DFIG)utilized in wind energy systems.DF... A system based on a PV-Wind will ensure better efficiency and flexibility using lower energy production.Today,plenty of work is being focussed on Doubly Fed Induction Generators(DFIG)utilized in wind energy systems.DFIG is found to be the best option in the Wind Energy Conversion Systems(WECS)to mitigate the issues caused by power converters.In this work,a new Artificial Neural Network(ANN)is proposed with the Diffusion and Dispersal strategy that works on Maximum Power Point Tracking(MPPT)along with Wind Energy Conversion System(WECS)to minimize electrical faults.The controller focus was not just to increase performance but also to reduce damage owing to any phase to phase fault or Phase to phase to ground fault.To ensure optimal MPPT for the proposed WECS,ANN achieves the optimal PI controller parameters for the indirect control of active and reactive power of DFIG.The optimal allocation and size of the DGs within the distributed system and for MPPT control are obtained using a population of agents.The generated solutions are evaluated and on being successful,the agents test their hypothesis again to create a positive feedback mechanism.Simulations are carried out,and the proposed IoT framework efficiency indicates performance improvement and faster recovery against faults by 9 percent for phase to ground fault and by 7.35 percent for phase to phase fault. 展开更多
关键词 dispersal diffusion search and artificial neural network maximum power point tracking(MPPT) photovoltaic(PV)array wind energy conversion system(WECS)
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Classification of Conversational Sentences Using an Ensemble Pre-Trained Language Model with the Fine-Tuned Parameter
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作者 R.Sujatha K.Nimala 《Computers, Materials & Continua》 SCIE EI 2024年第2期1669-1686,共18页
Sentence classification is the process of categorizing a sentence based on the context of the sentence.Sentence categorization requires more semantic highlights than other tasks,such as dependence parsing,which requir... Sentence classification is the process of categorizing a sentence based on the context of the sentence.Sentence categorization requires more semantic highlights than other tasks,such as dependence parsing,which requires more syntactic elements.Most existing strategies focus on the general semantics of a conversation without involving the context of the sentence,recognizing the progress and comparing impacts.An ensemble pre-trained language model was taken up here to classify the conversation sentences from the conversation corpus.The conversational sentences are classified into four categories:information,question,directive,and commission.These classification label sequences are for analyzing the conversation progress and predicting the pecking order of the conversation.Ensemble of Bidirectional Encoder for Representation of Transformer(BERT),Robustly Optimized BERT pretraining Approach(RoBERTa),Generative Pre-Trained Transformer(GPT),DistilBERT and Generalized Autoregressive Pretraining for Language Understanding(XLNet)models are trained on conversation corpus with hyperparameters.Hyperparameter tuning approach is carried out for better performance on sentence classification.This Ensemble of Pre-trained Language Models with a Hyperparameter Tuning(EPLM-HT)system is trained on an annotated conversation dataset.The proposed approach outperformed compared to the base BERT,GPT,DistilBERT and XLNet transformer models.The proposed ensemble model with the fine-tuned parameters achieved an F1_score of 0.88. 展开更多
关键词 Bidirectional encoder for representation of transformer conversation ensemble model fine-tuning generalized autoregressive pretraining for language understanding generative pre-trained transformer hyperparameter tuning natural language processing robustly optimized BERT pretraining approach sentence classification transformer models
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Optimizing Enterprise Conversational AI: Accelerating Response Accuracy with Custom Dataset Fine-Tuning
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作者 Yash Kishore 《Intelligent Information Management》 2024年第2期65-76,共12页
As the realm of enterprise-level conversational AI continues to evolve, it becomes evident that while generalized Large Language Models (LLMs) like GPT-3.5 bring remarkable capabilities, they also bring forth formidab... As the realm of enterprise-level conversational AI continues to evolve, it becomes evident that while generalized Large Language Models (LLMs) like GPT-3.5 bring remarkable capabilities, they also bring forth formidable challenges. These models, honed on vast and diverse datasets, have undoubtedly pushed the boundaries of natural language understanding and generation. However, they often stumble when faced with the intricate demands of nuanced enterprise applications. This research advocates for a strategic paradigm shift, urging enterprises to embrace a fine-tuning approach as a means to optimize conversational AI. While generalized LLMs are linguistic marvels, their inability to cater to the specific needs of businesses across various industries poses a critical challenge. This strategic shift involves empowering enterprises to seamlessly integrate their own datasets into LLMs, a process that extends beyond linguistic enhancement. The core concept of this approach centers on customization, enabling businesses to fine-tune the AI’s functionality to fit precisely within their unique business landscapes. By immersing the LLM in industry-specific documents, customer interaction records, internal reports, and regulatory guidelines, the AI transcends its generic capabilities to become a sophisticated conversational partner aligned with the intricacies of the enterprise’s domain. The transformative potential of this fine-tuning approach cannot be overstated. It enables a transition from a universal AI solution to a highly customizable tool. The AI evolves from being a linguistic powerhouse to a contextually aware, industry-savvy assistant. As a result, it not only responds with linguistic accuracy but also with depth, relevance, and resonance, significantly elevating user experiences and operational efficiency. In the subsequent sections, this paper delves into the intricacies of fine-tuning, exploring the multifaceted challenges and abundant opportunities it presents. It addresses the technical intricacies of data integration, ethical considerations surrounding data usage, and the broader implications for the future of enterprise AI. The journey embarked upon in this research holds the potential to redefine the role of conversational AI in enterprises, ushering in an era where AI becomes a dynamic, deeply relevant, and highly effective tool, empowering businesses to excel in an ever-evolving digital landscape. 展开更多
关键词 Fine-Tuning DATASET AI conversational ENTERPRISE LLM
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Language Assessment Feedback Towards Pedagogical Conversational Agent
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作者 Bhagya Prabhashini C M.Latha 《Sino-US English Teaching》 2024年第5期201-216,共16页
Continuous development of technology provides an opportunity to incorporate feedback in online assessments.The mode of online instruction during the pandemic was the most significant survival change.Technology enabled... Continuous development of technology provides an opportunity to incorporate feedback in online assessments.The mode of online instruction during the pandemic was the most significant survival change.Technology enabled every teacher and student to enter a virtual classroom to make sense of education.Feedback is part of language instruction and is a powerful key to improving students’learning performance.Feedback plays an influential and crucial role in teaching and learning.Feedback is an invaluable,ultimate learning tool for learners that aids them in not committing the same error again and creates impetus.Thus,knowing about formative exam feedback is students’right because quality feedback allures them.Given students’eagerness,providing feedback is considered a good practice to be followed by all the teaching faculty.Apropos of online feedback,the present study attempts to study how pedagogical agents provide online feedback in language assessments.The study also considers the characteristics of pedagogical conversational agents that are suitable for providing feedback in online language assessment.Simply put,the study encapsulates that screen agents play an essential role in students’motivation and acceptability of learning through feedback. 展开更多
关键词 FEEDBACK learning performance online language assessment pedagogical conversational agents
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Numerical Assessment of the Thermal Efficiency of a Concentrated Photovoltaic/Thermal (CPV/T) Hybrid System Using Air as Heat Transfer Fluid
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作者 Amadou Konfe Boureima Kabore +2 位作者 Yves Christian Nonguierma Fatimata Ouedraogo Sié Kam 《Smart Grid and Renewable Energy》 2024年第1期1-14,共14页
In this paper, we propose a thermal model of a hybrid photovoltaic/thermal concentration system. Starting from the thermal balance of the model, the equation is solved and simulated with a MATLAB code, considering air... In this paper, we propose a thermal model of a hybrid photovoltaic/thermal concentration system. Starting from the thermal balance of the model, the equation is solved and simulated with a MATLAB code, considering air as the cooling fluid. This enabled us to evaluate some of the parameters influencing the electrical and thermal performance of this device. The results showed that the temperature, thermal efficiency and electrical efficiency delivered depend on the air mass flow rate. The electrical and thermal efficiencies for different values of air mass flow are encouraging, and demonstrate the benefits of cooling photovoltaic cells. The results show that thermal efficiency decreases air flow rate greater than 0.7 kg/s, whatever the value of the light concentration used. The thermal efficiency of the solar cell increases as the light concentration increases, whatever the air flow rate used. For a concentration equal to 30 sun, the thermal efficiency is 0.16 with an air flow rate equal to 0.005 kg/s;the thermal efficiency increases to 0.19 with an air flow rate equal to 0.1 kg/s at the same concentration. An interesting and useful finding was that the proposed numerical model allows the determination of the electrical as well as thermal efficiency of the hybrid CPV/T with air flow as cooling fluid. 展开更多
关键词 PV Cell CONCENTRATING THERMAL Energy Conversion COOLING Hybrid system
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Characteristic changes in astrocyte properties during astrocyte-to-neuron conversion induced by NeuroD1/Ascl1/Dlx2 被引量:1
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作者 Qing He Zhen Wang +5 位作者 Yuchen Wang Mengjie Zhu Zhile Liang Kanghong Zhang Yuge Xu Gong Chen 《Neural Regeneration Research》 SCIE CAS 2025年第6期1801-1815,共15页
Direct in vivo conversion of astrocytes into functional new neurons induced by neural transcription factors has been recognized as a potential new therapeutic intervention for neural injury and degenerative disorders.... Direct in vivo conversion of astrocytes into functional new neurons induced by neural transcription factors has been recognized as a potential new therapeutic intervention for neural injury and degenerative disorders. However, a few recent studies have claimed that neural transcription factors cannot convert astrocytes into neurons, attributing the converted neurons to pre-existing neurons mis-expressing transgenes. In this study, we overexpressed three distinct neural transcription factors––NeuroD1, Ascl1, and Dlx2––in reactive astrocytes in mouse cortices subjected to stab injury, resulting in a series of significant changes in astrocyte properties. Initially, the three neural transcription factors were exclusively expressed in the nuclei of astrocytes. Over time, however, these astrocytes gradually adopted neuronal morphology, and the neural transcription factors was gradually observed in the nuclei of neuron-like cells instead of astrocytes. Furthermore,we noted that transcription factor-infected astrocytes showed a progressive decrease in the expression of astrocytic markers AQP4(astrocyte endfeet signal), CX43(gap junction signal), and S100β. Importantly, none of these changes could be attributed to transgene leakage into preexisting neurons. Therefore, our findings suggest that neural transcription factors such as NeuroD1, Ascl1, and Dlx2 can effectively convert reactive astrocytes into neurons in the adult mammalian brain. 展开更多
关键词 AQUAPORIN-4 Ascl1 ASTROCYTE cortex Dlx2 gap junction glia-to-neuron conversion neural regeneration NeuroD1 REPROGRAMMING
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Conversion treatment for advanced intrahepatic cholangiocarcinoma:Opportunities and challenges 被引量:2
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作者 Jun-Jie Liu Mi Zhou +2 位作者 Tong Yuan Zhi-Yong Huang Zun-Yi Zhang 《World Journal of Gastroenterology》 2025年第15期24-41,共18页
The prevalence of intrahepatic cholangiocarcinoma(ICC)is increasing globally.Despite advancements in comprehending this intricate malignancy and formulating novel therapeutic approaches over the past few decades,the p... The prevalence of intrahepatic cholangiocarcinoma(ICC)is increasing globally.Despite advancements in comprehending this intricate malignancy and formulating novel therapeutic approaches over the past few decades,the prognosis for ICC remains poor.Owing to the high degree of malignancy and insidious onset of ICC,numerous cases are detected at intermediate or advanced stages of the disease,hence eliminating the chance for surgical intervention.Moreover,because of the highly invasive characteristics of ICC,recurrence and metastasis postresection are prevalent,leading to a 5-year survival rate of only 20%-35%following surgery.In the past decade,different methods of treatment have been investigated,including transarterial chemoembolization,transarterial radioembolization,radiotherapy,systemic therapy,and combination therapies.For certain patients with advanced ICC,conversion treatment may be utilized to facilitate surgical resection and manage disease progression.This review summarizes the definition of downstaging conversion treatment and presents the clinical experience and evidence concerning conversion treatment for advanced ICC. 展开更多
关键词 Intrahepatic cholangiocarcinoma Conversion treatment DOWNSTAGING Combination therapy Chemotherapy IMMUNOTHERAPY Locoregional therapies
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Unveiling the photocatalytic marvels:Recent advances in solar heterojunctions for environmental remediation and energy harvesting 被引量:2
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作者 Najmeh Askari Mansoureh Jamalzadeh +6 位作者 Aghil Askari Naiyun Liu Bijan Samali Mika Sillanpaa Leigh Sheppard Haitao Li Raf Dewil 《Journal of Environmental Sciences》 2025年第2期283-297,共15页
In the quest for effective solutions to address Environ.Pollut.and meet the escalating energy demands,heterojunction photocatalysts have emerged as a captivating and versatile technology.These photocatalysts have garn... In the quest for effective solutions to address Environ.Pollut.and meet the escalating energy demands,heterojunction photocatalysts have emerged as a captivating and versatile technology.These photocatalysts have garnered significant interest due to their wideranging applications,including wastewater treatment,air purification,CO_(2) capture,and hydrogen generation via water splitting.This technique harnesses the power of semiconductors,which are activated under light illumination,providing the necessary energy for catalytic reactions.With visible light constituting a substantial portion(46%)of the solar spectrum,the development of visible-light-driven semiconductors has become imperative.Heterojunction photocatalysts offer a promising strategy to overcome the limitations associated with activating semiconductors under visible light.In this comprehensive review,we present the recent advancements in the field of photocatalytic degradation of contaminants across diverse media,as well as the remarkable progress made in renewable energy production.Moreover,we delve into the crucial role played by various operating parameters in influencing the photocatalytic performance of heterojunction systems.Finally,we address emerging challenges and propose novel perspectives to provide valuable insights for future advancements in this dynamic research domain.By unraveling the potential of heterojunction photocatalysts,this reviewcontributes to the broader understanding of their applications and paves the way for exciting avenues of exploration and innovation. 展开更多
关键词 Heterojunction photocatalysts Solar photocatalysis Environmental depollution Energy conversion Visible-light-driven semiconductors
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Boosting bidirectional sulfur conversion enabled by introducing boron-doped atoms and phosphorus vacancies in Ni_(2)P for lithium-sulfur batteries 被引量:2
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作者 Lin Peng Yu Bai +3 位作者 Hang Li Meixiu Qu Zhenhua Wang Kening Sun 《Journal of Energy Chemistry》 2025年第1期760-769,共10页
Lithium-sulfur (Li-S) batteries have gained great attention due to the high theoretical energy density and low cost,yet their further commercialization has been obstructed by the notorious shuttle effect and sluggish ... Lithium-sulfur (Li-S) batteries have gained great attention due to the high theoretical energy density and low cost,yet their further commercialization has been obstructed by the notorious shuttle effect and sluggish redox dynamics.Herein,we supply a strategy to optimize the electron structure of Ni_(2)P by concurrently introducing B-doped atoms and P vacancies in Ni_(2)P (Vp-B-Ni_(2)P),thereby enhancing the bidirectional sulfur conversion.The study indicates that the simultaneous introduction of B-doped atoms and P vacancies in Ni_(2)P causes the redistribution of electron around Ni atoms,bringing about the upward shift of d-band center of Ni atoms and effective d-p orbital hybridization between Ni atoms and sulfur species,thus strengthening the chemical anchoring for lithium polysulfides (LiPSs) as well as expediting the bidirectional conversion kinetics of sulfur species.Meanwhile,theoretical calculations reveal that the incorporation of B-doped atoms and P vacancies in Ni_(2)P selectively promotes Li2S dissolution and nucleation processes.Thus,the Li-S batteries with Vp-B-Ni_(2)P-separators present outstanding rate ability of 777 m A h g^(-1)at 5 C and high areal capacity of 8.03 mA h cm^(-2)under E/S of 5μL mg^(-1)and sulfur loading of 7.20 mg cm^(-2).This work elucidates that introducing heteroatom and vacancy in metal phosphide collaboratively regulates the electron structure to accelerate bidirectional sulfur conversion. 展开更多
关键词 B-doped atoms P vacancies Nickel phosphide Bidirectional sulfur conversion Lithium-sulfur batteries
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Solvent engineering in perovskite nanocrystal colloid inks for super-fine electrohydrodynamic inkjet printing of color conversion microstructures in micro-LED displays 被引量:2
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作者 Shuli Wang Xuemin Kong +7 位作者 Siting Cai Yunshu Luo Yuxuan Gu Xiaotong Fan Guolong Chen Xiao Yang Zhong Chen Yue Lin 《Chinese Chemical Letters》 2025年第8期554-559,共6页
Super-fine electrohydrodynamic inkjet(SIJ)printing of perovskite nanocrystal(PNC)colloid ink exhibits significant potential in the fabrication of high-resolution color conversion microstructures arrays for fullcolor m... Super-fine electrohydrodynamic inkjet(SIJ)printing of perovskite nanocrystal(PNC)colloid ink exhibits significant potential in the fabrication of high-resolution color conversion microstructures arrays for fullcolor micro-LED displays.However,the impact of solvent on both the printing process and the morphology of SIJ-printed PNC color conversion microstructures remains underexplored.In this study,we prepared samples of CsPbBr3PNC colloid inks in various solvents and investigated the solvent's impact on SIJ printed PNC microstructures.Our findings reveal that the boiling point of the solvent is crucial to the SIJ printing process of PNC colloid inks.Only does the boiling point of the solvent fall in the optimal range,the regular positioned,micron-scaled,conical PNC microstructures can be successfully printed.Below this optimal range,the ink is unable to be ejected from the nozzle;while above this range,irregular positioned microstructures with nanoscale height and coffee-ring-like morphology are produced.Based on these observations,high-resolution color conversion PNC microstructures were effectively prepared using SIJ printing of PNC colloid ink dispersed in dimethylbenzene solvent. 展开更多
关键词 SOLVENT Perovskite nanocrystal Electrohydrodynamic inkjet printing Color conversion microstructures arrays Micro-LED display
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Flash-PEO of magnesium:Phosphate precursor driven functionalization 被引量:2
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作者 M.H.Guerra-Mutis J.M.Vega +2 位作者 M.I.Barrena E.Matykina R.Arrabal 《Journal of Magnesium and Alloys》 2025年第2期592-612,共21页
In this study,a phosphate-based conversion coating(PCC)was applied as a precursor before forming silicate-fluoride(SiF)and silicate-phosphate-fluoride(SiPF)based flash-plasma electrolytic oxidation(Flash-PEO)coatings ... In this study,a phosphate-based conversion coating(PCC)was applied as a precursor before forming silicate-fluoride(SiF)and silicate-phosphate-fluoride(SiPF)based flash-plasma electrolytic oxidation(Flash-PEO)coatings on AZ31B magnesium alloy.The main novelty is the successful incorporation of calcium,zinc,manganese and phosphate species into the Flash-PEO coatings via a precursor layer rather than using the electrolyte.The precursor also led to longer lasting and more intense discharges during the PEO process,resulting in increased pore size.Corrosion studies revealed similar short-term performance for all coatings,with impedance modulus at low frequencies above 10^(7)Ωcm^(2),and slightly better performance for the SiPF-based coating.Nonetheless,the enlarged pores in the PEO coatings functionalized with the PCC precursor compromised the effectiveness of self-healing mechanisms by creating diffusion pathways for corrosive species,leading to earlier failure.These phenomena were effectively monitored by recording the open circuit potential during immersion in 0.5 wt.%NaCl solution.In summary,this study demonstrates that conversion coatings are a viable option for the functionalization of PEO coatings on magnesium alloys,as they allow for the incorporation of cationic and other species.However,it is crucial to maintain a small pore size to facilitate effective blockage through self-healing mechanisms. 展开更多
关键词 AZ31B magnesium alloy PHOSPHATES Chemical conversion coating Flash plasma electrolytic oxidation Electrochemical impedance spectroscopy Transmission electron microscopy
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Not all reoperative laparoscopic liver resection procedures are feasible for hepatolithiasis patients with a history of biliary surgery 被引量:1
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作者 Wen-Jun Zhang Guang Chen +1 位作者 Da-Fei Dai Xiao-Peng Chen 《World Journal of Hepatology》 2025年第5期158-168,共11页
BACKGROUND Laparoscopic hepatectomy(LH)has been applied in the treatment of hepatolithiasisa in patients with a history of biliary surgery and has already achieved good clinical outcomes.However,reoperative LH(rLH)inc... BACKGROUND Laparoscopic hepatectomy(LH)has been applied in the treatment of hepatolithiasisa in patients with a history of biliary surgery and has already achieved good clinical outcomes.However,reoperative LH(rLH)includes multiple procedures,and the no studies have examined the clinical value of individual laparoscopic procedures.AIM To evaluate the safety and feasibility of each rLH procedure for hepatolithiasisa in patients with a history of biliary surgery.METHODS Patients with previous biliary surgery who underwent reoperative hepatectomy for hepatolithiasis were studied.Liver resection procedures were divided into three categories:(1)Laparoscopic/open left lateral sectionectomy[reoperative laparoscopic left lateral sectionectomy(rLLLS)/reoperative open left lateral sectionectomy(rOLLS)];(2)Laparoscopic/open left hemihepatectomy[reoperative laparoscopic left hemihepatectomy(rLLH)/reoperative open left hemihepatectomy(rOLH)];and(3)Laparoscopic/open complex hepatectomy[reoperative laparoscopic complex hepatectomy(rLCH)/reoperative open complex hepate ctomy(rOCH)].The clinical outcomes were compared between the rLLLS,rLLH,and rLCH groups,and subgroup analyses were performed for the rLLLS/rOLLS,rLLH/rOLH,and rLCH/rOCH subgroups.RESULTS A total of 185 patients were studied,including 101 rLH patients(40 rLLLS,50 rLLH,and 11 rLCH)and 84 reoperative open hepatectomy(40 rOLLS,33 rOLH,and 11 rOCH).Among the three types of rLH procedure,rLLLS required the shortest operation time(240.0 minutes vs 325.0 minutes vs 350.0 minutes,P=0.001)and the lowest blood transfusion rate(10.0%vs 22.0%vs 54.5%,P=0.005),followed by rLLH.The rLCH had the highest conversion rate(P<0.05)and postoperative intensive care unit stay rate(P=0.001).Most clinical outcomes in rLLLS and rLLH were superior or similar to those in the corresponding open surgery,while there were no differences in all outcomes between the rLCH and rOCH subgroups.CONCLUSION The rLH is safe for hepatolithiasis patients with a history of biliary surgery.The rLLLS and rLLH can be recommended for these patients,whereas rLCH should be applied with caution. 展开更多
关键词 HEPATOLITHIASIS Laparoscopic hepatectomy Previous biliary surgery REOPERATION CONVERSION
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