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UGEA-LMD: A Continuous-Time Dynamic Graph Representation Enhancement Framework for Lateral Movement Detection
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作者 Jizhao Liu Yuanyuan Shao +2 位作者 Shuqin Zhang Fangfang Shan Jun Li 《Computers, Materials & Continua》 2026年第1期1924-1943,共20页
Lateral movement represents the most covert and critical phase of Advanced Persistent Threats(APTs),and its detection still faces two primary challenges:sample scarcity and“cold start”of new entities.To address thes... Lateral movement represents the most covert and critical phase of Advanced Persistent Threats(APTs),and its detection still faces two primary challenges:sample scarcity and“cold start”of new entities.To address these challenges,we propose an Uncertainty-Driven Graph Embedding-Enhanced Lateral Movement Detection framework(UGEA-LMD).First,the framework employs event-level incremental encoding on a continuous-time graph to capture fine-grained behavioral evolution,enabling newly appearing nodes to retain temporal contextual awareness even in the absence of historical interactions and thereby fundamentally mitigating the cold-start problem.Second,in the embedding space,we model the dependency structure among feature dimensions using a Gaussian copula to quantify the uncertainty distribution,and generate augmented samples with consistent structural and semantic properties through adaptive sampling,thus expanding the representation space of sparse samples and enhancing the model’s generalization under sparse sample conditions.Unlike static graph methods that cannot model temporal dependencies or data augmentation techniques that depend on predefined structures,UGEA-LMD offers both superior temporaldynamic modeling and structural generalization.Experimental results on the large-scale LANL log dataset demonstrate that,under the transductive setting,UGEA-LMD achieves an AUC of 0.9254;even when 10%of nodes or edges are withheld during training,UGEA-LMD significantly outperforms baseline methods on metrics such as recall and AUC,confirming its robustness and generalization capability in sparse-sample and cold-start scenarios. 展开更多
关键词 Advanced persistent threat(APTs) lateral movement detection continuous-time dynamic graph data enhancement
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Distributed continuous-time aggregative optimization and its applications to power generation systems
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作者 XIAN Chengxin ZHAO Yu LIU Yongfang 《Journal of Systems Engineering and Electronics》 2026年第1期1-8,共8页
This paper investigates the distributed continuoustime aggregative optimization problem for second-order multiagent systems,where the local cost function is not only related to its own decision variables,but also to t... This paper investigates the distributed continuoustime aggregative optimization problem for second-order multiagent systems,where the local cost function is not only related to its own decision variables,but also to the aggregation of the decision variables of all the agents.By using the gradient descent method,the distributed average tracking(DAT)technique and the time-base generator(TBG)technique,a distributed continuous-time aggregative optimization algorithm is proposed.Subsequently,the optimality of the system's equilibrium point is analyzed,and the convergence of the closed-loop system is proved using the Lyapunov stability theory.Finally,the effectiveness of the proposed algorithm is validated through case studies on multirobot systems and power generation systems. 展开更多
关键词 distributed continuous-time aggregative optimization distributed average tracking(DAT) time-base generator(TBG)
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郭为与他的AI for Process
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作者 姜奇平 端利涛 《互联网周刊》 2026年第2期8-12,共5页
一、作为哲学的AI for Process(一)郭为的哲学思想1.郭为是谁郭为是谁?他是一位哲学家。顺便说,他同时还领导着神州数码。为什么说郭为是哲学家呢?因为他在著作中谈到高深的哲学,如“数据如水,奔流不息,无界融合”。他引述古希腊哲学家... 一、作为哲学的AI for Process(一)郭为的哲学思想1.郭为是谁郭为是谁?他是一位哲学家。顺便说,他同时还领导着神州数码。为什么说郭为是哲学家呢?因为他在著作中谈到高深的哲学,如“数据如水,奔流不息,无界融合”。他引述古希腊哲学家赫拉克利特所说的“万物流转”,又说“你不能两次踏进同一条河流,因为新的水不断地流过你的身旁”,他所表达的意思是“世界上唯一不变的就是变化”。 展开更多
关键词 AI for process 郭为
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Variance minimization for continuous-time Markov decision processes: two approaches 被引量:1
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作者 ZHU Quan-xin 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2010年第4期400-410,共11页
This paper studies the limit average variance criterion for continuous-time Markov decision processes in Polish spaces. Based on two approaches, this paper proves not only the existence of solutions to the variance mi... This paper studies the limit average variance criterion for continuous-time Markov decision processes in Polish spaces. Based on two approaches, this paper proves not only the existence of solutions to the variance minimization optimality equation and the existence of a variance minimal policy that is canonical, but also the existence of solutions to the two variance minimization optimality inequalities and the existence of a variance minimal policy which may not be canonical. An example is given to illustrate all of our conditions. 展开更多
关键词 continuous-time Markov decision process Polish space variance minimization optimality equation optimality inequality.
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Development of Optimal Maintenance Policies for Offshore Wind Turbine Gearboxes Based on the Non-homogeneous Continuous-Time Markov Process 被引量:1
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作者 Mingxin Li Jichuan Kang +1 位作者 Liping Sun Mian Wang 《Journal of Marine Science and Application》 CSCD 2019年第1期93-98,共6页
Gearbox in offshore wind turbines is a component with the highest failure rates during operation. Analysis of gearbox repair policy that includes economic considerations is important for the effective operation of off... Gearbox in offshore wind turbines is a component with the highest failure rates during operation. Analysis of gearbox repair policy that includes economic considerations is important for the effective operation of offshore wind farms. From their initial perfect working states, gearboxes degrade with time, which leads to decreased working efficiency. Thus, offshore wind turbine gearboxes can be considered to be multi-state systems with the various levels of productivity for different working states. To efficiently compute the time-dependent distribution of this multi-state system and analyze its reliability, application of the nonhomogeneous continuous-time Markov process(NHCTMP) is appropriate for this type of object. To determine the relationship between operation time and maintenance cost, many factors must be taken into account, including maintenance processes and vessel requirements. Finally, an optimal repair policy can be formulated based on this relationship. 展开更多
关键词 Maintenance policy NON-HOMOGENEOUS continuous-time MARKOV process OFFSHORE wind TURBINE gearboxes Reliability analysis Failure rates System engineering
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Continuous-time hierarchical reinforcement learning for satellite pursuit decision
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作者 Linsen WEI Xin NING +3 位作者 Xiaobin LIAN Feng WANG Gaopeng ZHANG Mingpei LIN 《Chinese Journal of Aeronautics》 2025年第12期363-375,共13页
The satellite orbital pursuit game focuses on studying spacecraft maneuvering strategies in space.Traditional numerical methods often face real-time inadequacies and adaptability limitations when dealing with highly n... The satellite orbital pursuit game focuses on studying spacecraft maneuvering strategies in space.Traditional numerical methods often face real-time inadequacies and adaptability limitations when dealing with highly nonlinear problems.With the advancement of Deep Reinforcement Learning(DRL)technology,continuous-time orbital control capabilities have significantly improved.Despite this,the existing DRL technologies still need adjustments in action delay and discretization structure to better adapt to practical application scenarios.Combining continuous learning and model planning demonstrates the adaptability of these methods in continuous-time decision problems.Additionally,to more effectively handle action delay issues,a new scheduled action execution technique has been developed.This technique optimizes action execution timing through real-time policy adjustments,thus adapting to the dynamic changes in the orbital environment.A Hierarchical Reinforcement Learning(HRL)strategy was also adopted to simplify the decision-making process for long-distance pursuit tasks by setting phased subgoals to gradually approach the target.The effectiveness of the proposed strategy in practical satellite pursuit scenarios has been verified through simulations of two different tasks. 展开更多
关键词 continuous-time decision Hierarchical reinforcement learning Intelligent decision Orbital pursuit game Trajectory planning
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Variance Optimization for Continuous-Time Markov Decision Processes
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作者 Yaqing Fu 《Open Journal of Statistics》 2019年第2期181-195,共15页
This paper considers the variance optimization problem of average reward in continuous-time Markov decision process (MDP). It is assumed that the state space is countable and the action space is Borel measurable space... This paper considers the variance optimization problem of average reward in continuous-time Markov decision process (MDP). It is assumed that the state space is countable and the action space is Borel measurable space. The main purpose of this paper is to find the policy with the minimal variance in the deterministic stationary policy space. Unlike the traditional Markov decision process, the cost function in the variance criterion will be affected by future actions. To this end, we convert the variance minimization problem into a standard (MDP) by introducing a concept called pseudo-variance. Further, by giving the policy iterative algorithm of pseudo-variance optimization problem, the optimal policy of the original variance optimization problem is derived, and a sufficient condition for the variance optimal policy is given. Finally, we use an example to illustrate the conclusion of this paper. 展开更多
关键词 continuous-time MARKOV Decision process Variance OPTIMALITY of Average REWARD Optimal POLICY of Variance POLICY ITERATION
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Call for Papers from Agricultural Products Processing and Storage
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《肉类研究》 北大核心 2026年第4期I0011-I0011,共1页
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ... Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of significant,novel,and high-impact research in the fields of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics. 展开更多
关键词 processING Agricultural Products Consumer Demand
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In-Flight Heating Process of Cerium Oxide Powders in Radio Frequency Thermal Plasma Considering Thermal Resistance Effect
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作者 Su Yi Liu Ruizhe +3 位作者 Ahmad Hilal Zhao Peng Jin Xingyue Zhu Hailong 《稀有金属材料与工程》 北大核心 2026年第3期581-594,共14页
The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF... The in-flight heating process of cerium dioxide(CeO_(2))powders was investigated through experiments and numerical simulations.In the experiment,CeO_(2)powder(average size of 30μm)was injected into radio-frequency(RF)argon plasma,and the temperatures were measured using a DPV-2000 monitor.A model combining the electromagnetism,thermal flow,and heat transfer characteristics of powder during in-flight heating in argon plasma was proposed.The melting processes of CeO_(2)powders of different diameters,with and without thermal resistance effect,were investigated.Results show that the heating process of CeO_(2)powder particles consists of three main stages,one of which is relevant to a dimensionless parameter known as the Biot number.When the Biot value≥0.1,thermal resistance increases significantly,especially for the larger powders.The predicted temperature of the particles at the outlet(1800–2880 K)is in good agreement with the experimental result. 展开更多
关键词 RF thermal plasma thermal resistance effect heating process Biot number
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Hot Compression Deformation Behavior and Processing Maps of Mg-Zn-Mn(-Sn)-Ca Alloy
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作者 Chen Xia Zhu Yulong +2 位作者 Liu Quanyi Zhang Dingfei Pan Fusheng 《稀有金属材料与工程》 北大核心 2026年第3期627-635,共9页
The hot compression deformation behavior of Mg-6Zn-1Mn-0.5Ca(ZM61-0.5Ca)and Mg-6Zn-1Mn-2Sn-0.5Ca(ZMT612-0.5Ca)alloys was investigated at deformation temperatures ranging from 250℃to 400℃and strain rates varying from... The hot compression deformation behavior of Mg-6Zn-1Mn-0.5Ca(ZM61-0.5Ca)and Mg-6Zn-1Mn-2Sn-0.5Ca(ZMT612-0.5Ca)alloys was investigated at deformation temperatures ranging from 250℃to 400℃and strain rates varying from 0.001 s^(-1) to 1 s^(-1).The results show that the addition of Sn promotes dynamic recrystallization(DRX),and CaMgSn phases can act as nucleation sites during the compression deformation.Flow stress increases with increasing the strain rate and decreasing the temperature.Both the ZM61-0.5Ca and ZMT612-0.5Ca alloys exhibit obvious DRX characteristics.CaMgSn phases can effectively inhibit dislocation motion with the addition of Sn,thus increasing the peak fl ow stress of the alloy.The addition of Sn increases the hot deformation activation energy of the ZM61-0.5Ca alloy from 199.654 kJ/mol to 276.649 kJ/mol,thus improving the thermal stability of the alloy.For the ZMT612-0.5Ca alloy,the optimal hot deformation parameters are determined to be a deformation temperature range of 350–400℃and a strain rate range of 0.001–0.01 s^(-1). 展开更多
关键词 hot deformation constitutive equation processing map deformation activation energy magnesium alloy
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Research Progress on Process Optimization and Performance Control of Additive Manufacturing for Refractory Metals
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作者 Lu Durui Song Suocheng Lu Bingheng 《稀有金属材料与工程》 北大核心 2026年第2期345-364,共20页
Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durabili... Refractory metals,including tungsten(W),tantalum(Ta),molybdenum(Mo),and niobium(Nb),play a vital role in industries,such as nuclear energy and aerospace,owing to their exceptional melting temperatures,thermal durability,and corrosion resistance.These metals have body-centered cubic crystal structure,characterized by limited slip systems and impeded dislocation motion,resulting in significant low-temperature brittleness,which poses challenges for the conventional processing.Additive manufacturing technique provides an innovative approach,enabling the production of intricate parts without molds,which significantly improves the efficiency of material usage.This review provides a comprehensive overview of the advancements in additive manufacturing techniques for the production of refractory metals,such as W,Ta,Mo,and Nb,particularly the laser powder bed fusion.In this review,the influence mechanisms of key process parameters(laser power,scan strategy,and powder characteristics)on the evolution of material microstructure,the formation of metallurgical defects,and mechanical properties were discussed.Generally,optimizing powder characteristics,such as sphericity,implementing substrate preheating,and formulating alloying strategies can significantly improve the densification and crack resistance of manufactured parts.Meanwhile,strictly controlling the oxygen impurity content and optimizing the energy density input are also the key factors to achieve the simultaneous improvement in strength and ductility of refractory metals.Although additive manufacturing technique provides an innovative solution for processing refractory metals,critical issues,such as residual stress control,microstructure and performance anisotropy,and process stability,still need to be addressed.This review not only provides a theoretical basis for the additive manufacturing of high-performance refractory metals,but also proposes forward-looking directions for their industrial application. 展开更多
关键词 refractory metals additive manufacturing mechanical properties microstructure evolution optimization of printing process
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Call for Papers from Agricultural Products Processing and Storage
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《肉类研究》 北大核心 2026年第1期I0017-I0017,共1页
Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim ... Agricultural Products Processing and Storage(ISSN 3059-4510,Owner:Hunan Academy of Agricultural Sciences,China.Production and hosting:Springer Nature)is an international,peer-reviewed open access journal with the aim to offer a platform for the rapid dissemination of signifi cant,novel,and high-impact research in the fi elds of agricultural product processing science,technology,engineering,and nutrition.Additionally,supplemental issues are curated and published to facilitate in-depth discussions on special topics. 展开更多
关键词 NUTRITION SCIENCE open access journal agricultural products processing STORAGE technology ENGINEERING agricultural product
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A hierarchical and role-driven digital twin system with applications to complex chemical process operation
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作者 Xinyu Tao Runjie Yao +3 位作者 Lingyu Zhu Changrui Xie Muqian Zhang Xi Chen 《Chinese Journal of Chemical Engineering》 2026年第1期302-313,共12页
Digital twin technology brings more opportunities and challenges to chemical engineering in both academic and industry.A complex process could have multiple digitalization needs,including simulation,monitoring,operato... Digital twin technology brings more opportunities and challenges to chemical engineering in both academic and industry.A complex process could have multiple digitalization needs,including simulation,monitoring,operator training,etc.;thus,a hierarchical digital twin would be a comprehensive solution to that.In this study,a novel and general framework of the digital twin is proposed for operations in process industry.With the hierarchical structure,the framework can handle various tasks driven by different roles in process industry,including managers,engineers,and operators.To complete these tasks,the framework consists of three modules:OAS(Operation Analysis System),OMS(Operation Monitoring System),and OTS(Operator Training System).Each module focuses on one unique type of demand from the staff,as well as interactions among them enabling efficient data sharing.Based on the hierarchical framework,a digital twin system is applied for one complex industrial nitration process,which successfully enhances the operation efficiency and safety in several industrial scenarios with different demands. 展开更多
关键词 Digital twin Hierarchical framework Role-driven process operation process modeling&optimization Operator training system
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Numerical Simulation on Thermomechanical Coupling Process in Friction Stir-Assisted Wire Arc Additive Manufacturing
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作者 Li Long Xiao Yichen +2 位作者 Shi Lei Chen Ji Wu Chuansong 《稀有金属材料与工程》 北大核心 2026年第1期1-8,共8页
Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing addit... Wire arc additive manufacturing(WAAM)has emerged as a promising approach for fabricating large-scale components.However,conventional WAAM still faces challenges in optimizing microstructural evolution,minimizing additive-induced defects,and alleviating residual stress and deformation,all of which are critical for enhancing the mechanical performance of the manufactured parts.Integrating interlayer friction stir processing(FSP)into WAAM significantly enhances the quality of deposited materials.However,numerical simulation research focusing on elucidating the associated thermomechanical coupling mechanisms remains insufficient.A comprehensive numerical model was developed to simulate the thermomechanical coupling behavior in friction stir-assisted WAAM.The influence of post-deposition FSP on the coupled thermomechanical response of the WAAM process was analyzed quantitatively.Moreover,the residual stress distribution and deformation behavior under both single-layer and multilayer deposition conditions were investigated.Thermal analysis of different deposition layers in WAAM and friction stir-assisted WAAM was conducted.Results show that subsequent layer deposition induces partial remelting of the previously solidified layer,whereas FSP does not cause such remelting.Furthermore,thermal stress and deformation analysis confirm that interlayer FSP effectively mitigates residual stresses and distortion in WAAM components,thereby improving their structural integrity and mechanical properties. 展开更多
关键词 friction stir processing wire arc additive manufacturing numerical simulation thermomechanical coupling temperature field DEFORMATION
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DriftXMiner: A Resilient Process Intelligence Approach for Safe and Transparent Detection of Incremental Concept Drift in Process Mining
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作者 Puneetha B.H Manoj Kumar M.V +1 位作者 Prashanth B.S. Piyush Kumar Pareek 《Computers, Materials & Continua》 2026年第1期1086-1118,共33页
Processes supported by process-aware information systems are subject to continuous and often subtle changes due to evolving operational,organizational,or regulatory factors.These changes,referred to as incremental con... Processes supported by process-aware information systems are subject to continuous and often subtle changes due to evolving operational,organizational,or regulatory factors.These changes,referred to as incremental concept drift,gradually alter the behavior or structure of processes,making their detection and localization a challenging task.Traditional process mining techniques frequently assume process stationarity and are limited in their ability to detect such drift,particularly from a control-flow perspective.The objective of this research is to develop an interpretable and robust framework capable of detecting and localizing incremental concept drift in event logs,with a specific emphasis on the structural evolution of control-flow semantics in processes.We propose DriftXMiner,a control-flow-aware hybrid framework that combines statistical,machine learning,and process model analysis techniques.The approach comprises three key components:(1)Cumulative Drift Scanner that tracks directional statistical deviations to detect early drift signals;(2)a Temporal Clustering and Drift-Aware Forest Ensemble(DAFE)to capture distributional and classification-level changes in process behavior;and(3)Petri net-based process model reconstruction,which enables the precise localization of structural drift using transition deviation metrics and replay fitness scores.Experimental validation on the BPI Challenge 2017 event log demonstrates that DriftXMiner effectively identifies and localizes gradual and incremental process drift over time.The framework achieves a detection accuracy of 92.5%,a localization precision of 90.3%,and an F1-score of 0.91,outperforming competitive baselines such as CUSUM+Histograms and ADWIN+Alpha Miner.Visual analyses further confirm that identified drift points align with transitions in control-flow models and behavioral cluster structures.DriftXMiner offers a novel and interpretable solution for incremental concept drift detection and localization in dynamic,process-aware systems.By integrating statistical signal accumulation,temporal behavior profiling,and structural process mining,the framework enables finegrained drift explanation and supports adaptive process intelligence in evolving environments.Its modular architecture supports extension to streaming data and real-time monitoring contexts. 展开更多
关键词 process mining concept drift gradual drift incremental drift clustering ensemble techniques process model event log
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Source-Text Processing in Xu-Argument-Based Continuation Writing:An Eye-Tracking Study
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作者 Wei Gao Jinyang Li Duanhui Yuan 《Chinese Journal of Applied Linguistics》 2026年第1期21-37,159,共18页
This study investigated the effects of xu-argument-based continuation writing on learners’processing of source texts.Seventy-five participants were randomly assigned to three conditions:(1)continuation writing,(2)sum... This study investigated the effects of xu-argument-based continuation writing on learners’processing of source texts.Seventy-five participants were randomly assigned to three conditions:(1)continuation writing,(2)summary writing,or(3)reading comprehension.Eye-tracking data were collected during reading,measuring early(first fixation duration,first pass duration)and late(go-past time,total fixation duration)eye movements.During writing,source-text rereading was tracked via fixation counts and durations.Results showed that task type did not affect initial lexical access,as first fixation duration showed no group differences.However,both production groups exhibited significantly longer first pass durations than the reading comprehension group.Late measures revealed a gradient pattern:the continuation writing group spent significantly longer gopast time and total fixation duration than the summary writing group,which exceeded the reading comprehension group.This indicates that continuation tasks promoted deeper cognitive engagement during reading.During writing,the continuation writing group spent more time rereading the source text with higher fixation counts than the summary writing group.These findings suggest that continuation writing triggers more intensive reader-text interaction during pre-writing and enhances comprehension-production coupling through sustained attention to input during writing.This study sheds light on the cognitive mechanisms underlying the theoretical and pedagogical value of xu-argument. 展开更多
关键词 xu-argument continuation writing source-text processing EYE-TRACKING
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Basic research and industrial development status of suancai in Northeast China:history,microflora diversity,processing technology,nutrition and safety
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作者 Qianqian Wang Jingbo Yang +7 位作者 Yuqi Wang Meiru Xie Xiaoxi Qi Ramnarain Ramakrishna Libo Liu Wenkui Guo Guofang Zhang Chun Li 《Food Science and Human Wellness》 2026年第1期13-27,共15页
Suancai has a lengthy history and a wide range of categories,which has some influence on the pickled diet culture around the world.Suancai production is transitioning to a large-scale,standardized production due to th... Suancai has a lengthy history and a wide range of categories,which has some influence on the pickled diet culture around the world.Suancai production is transitioning to a large-scale,standardized production due to the growth of the market.It has a unique flavor and is rich in nutrients,and its abundance of free amino acids,vitamins and phenolics has many positive effects on the human body.This review gives the types and history of suancai,as well as its impact on the world’s pickled culture.The changes in nutritional composition and flavor of suancai during fermentation are summarized.It presented the production technology and influencing factors of the northeast suancai,examined the quality and safety issues in suancai,and put forth some ideas and opinions on the standardization development of the suancai industry.It also summarized the geographic distribution and flora diversity of pickles around the world.In order to provide some knowledge and guidance for the promotion of modern industrial production in the suancai industry. 展开更多
关键词 Fermented vegetables Microbial community process NUTRITION SAFETY
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Neurodegenerative processes of aging: A perspective of restoration through insulin-like growth factor-1
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作者 Rosana Crespo Claudia Herenu 《Neural Regeneration Research》 2026年第4期1562-1563,共2页
The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurode... The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurodegenerative diseases are characterized by the progressive loss of neuronal structure and function. 展开更多
关键词 neurodegenerative diseases neurodegenerative processes cognitive impairments progressive loss neuronal structure function develo ping neurological dysfunctions insulin growth factor RESTORATION aging process
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Processability and Structure of Dynamically Modified Linear Low-density Polyethylene with Different Branching Contents Using a High Peroxide Content
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作者 Jun-Jin Duan Yan-Qin Huang +3 位作者 Fu-Qing Wei Yan Gao Fu-Shan Wang Jia-Chun Feng 《Chinese Journal of Polymer Science》 2026年第1期87-99,I0011,共14页
Dynamic melt modification of polyethylene via the direct grafting of peroxide fragments shows promise for the development of processable functionalized materials.In this study,four linear low-density polyethylenes(LLD... Dynamic melt modification of polyethylene via the direct grafting of peroxide fragments shows promise for the development of processable functionalized materials.In this study,four linear low-density polyethylenes(LLDPEs)with comparable molecular weights but different short-chain branch(SCB)contents(ranging of 5-66 per 1000 carbon atoms)were modified via dynamic melt mixing using 2 wt% benzoyl peroxide at 145℃ and 50 r/min for 30 min.The influence of SCB content on the processability and structure of the resulting products was systematically investigated.All modified products exhibited good melt processability with melt flow rates(MFR)ranging from 0.46 g/10min to 1.07 g/10min.Products derived from low-SCB LLDPEs showed a lower MFR,higher cross-linking content,a larger number of long-chain branches,and a higher degree of benzoyl grafting.In contrast,those produced from high-SCB LLDPEs exhibited improved processability,reduced cross-linking,fewer long-chain branches,and lower benzoyl grafting levels.A detailed structural investigation of the soluble and insoluble fractions,which were separated using trichlorobenzene fractionation,was conducted to analyze the structural features of various modified products and demonstrate that the SCB content(i.e.,tertiary carbon density)significantly influences radical coupling during dynamic modification.Elevated tertiary carbon density,by introducing greater steric hindrance,suppresses radical coupling during dynamic modification,thereby reducing the efficiency of both crosslinking and peroxide fragment grafting.These findings provide new insights into the structure-reactivity relationships in peroxide-induced polyethylene modification and lay the foundation for tailoring material properties via dynamic processing. 展开更多
关键词 POLYETHYLENE PEROXIDE Short-chain branching Dynamical modification processABILITY
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Transformation of Verbal Descriptions of Process Flows into Business Process Modelling and Notation Models Using Multimodal Artificial Intelligence:Application in Justice
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作者 Silvia Alayón Carlos Martín +3 位作者 Jesús Torres Manuel Bacallado Rosa Aguilar Guzmán Savirón 《Computer Modeling in Engineering & Sciences》 2026年第2期870-892,共23页
Business Process Modelling(BPM)is essential for analyzing,improving,and automating the flow of information within organizations,but traditional approaches based on manual interpretation are slow,error-prone,and requir... Business Process Modelling(BPM)is essential for analyzing,improving,and automating the flow of information within organizations,but traditional approaches based on manual interpretation are slow,error-prone,and require a high level of expertise.This article proposes an innovative alternative solution that overcomes these limitations by automatically generating comprehensive Business Process Modelling and Notation(BPMN)diagrams solely from verbal descriptions of the processes to be modeled,utilizing Large Language Models(LLMs)and multimodal Artificial Intelligence(AI).Experimental results,based on video recordings of process explanations provided by an expert from an organization(in this case,the Commercial Courts of a public justice administration),demonstrate that the proposed methodology successfully enables the automatic generation of complete and accurate BPMN diagrams,leading to significant improvements in the speed,accuracy,and accessibility of process modeling.This research makes a substantial contribution to the field of business process modeling,as its methodology is groundbreaking in its use of LLMs and multimodal AI capabilities to handle different types of source material(text and video),combining several tools to minimize the number of queries and reduce the complexity of the prompts required for the automatic generation of successful BPMN diagrams. 展开更多
关键词 process modelling verbal description BPMN LLM multimodal AI
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