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液相连续法生产丙烯酸乙酯的合成工艺研究
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作者 高军 沈伟 +4 位作者 陈京奥 丁成荣 桑志旻 张国富 亓虎 《合成化学》 CAS 2024年第9期846-852,共7页
近些年,丙烯酸乙酯相关产业多采用气相固定床法,该方法存在能耗较高、设备投资大、生产切换不方便、丙烯酸单程转化率低和生产成本高等一系列问题。因此,本文研究了一种液相连续法生产丙烯酸乙酯的合成工艺路线以解决上述问题。以丙烯酸... 近些年,丙烯酸乙酯相关产业多采用气相固定床法,该方法存在能耗较高、设备投资大、生产切换不方便、丙烯酸单程转化率低和生产成本高等一系列问题。因此,本文研究了一种液相连续法生产丙烯酸乙酯的合成工艺路线以解决上述问题。以丙烯酸和95%乙醇为原料,采用液相连续法合成丙烯酸乙酯,其结构经^(1)H NMR,^(13)C NMR和HR-MS(EI)确证。研究了反应温度、停留时间、 95%(质量分数)乙醇用量、催化剂用量(质量分数)和萃取剂用量对于液相连续法生产丙烯酸乙酯的影响。结果表明:在丙烯酸与95%乙醇物质的量之比为1.0∶2.0,第一级反应釜反应温度为75℃、第二级反应釜反应温度为80℃、第三级反应釜反应温度为90℃、反应停留时间为4 h、催化剂物质的量分数为0.4%(催化剂相对于丙烯酸原料的物质的量分数)和萃取液和萃取剂质量比为1.0∶2.0的条件下丙烯酸乙酯单程收率达到95.0%,经工业级放大后丙烯酸乙酯单程收率达到95.3%。上述研究在一定程度上解决了气相固定床方法的一系列缺陷,为丙烯酸乙酯的工业生产提供了一种较为优异的生产方式。 展开更多
关键词 丙烯酸 95%乙醇 丙烯酸乙酯 液相连续化法 工业放大
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Cross-sectional structure, microstructure and mechanical property evolutions of brass cladding pure copper stranded wire composite during drawing 被引量:9
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作者 Yan-bin JIANG Yong-shuai LI +1 位作者 Yu LEI Jian-xin XIE 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第7期1857-1872,共16页
A solid/liquid continuous casting and composite technology was used to produce d8.5 mm brass cladding pure copper stranded wire composite billet and the composite billet was then drawn. The results showed that the com... A solid/liquid continuous casting and composite technology was used to produce d8.5 mm brass cladding pure copper stranded wire composite billet and the composite billet was then drawn. The results showed that the composite billet had good surface quality, metallurgical bonding interface between brass and pure copper as well as elongation of 53.1%. Synergistic deformation degree between pure copper wire and brass cladding layer was high during drawing. With an increase of the total deformation amount, the plastic deformation of the pure copper wire reduced triangular arc gaps between the pure copper wires and the triangular arc gaps were fully filled at 50%. When the total deformation amount was increased to 63%, dislocation cells and microbands successively formed in the pure copper wire. In the brass cladding layer, planar dislocation networks, twins and shear bands formed successively, and the main deformation mechanisms were dislocation sliding, twinning and shear deformation. The tensile strength increased from 240 MPa of the composite billet to 519 MPa of the one with the deformation amount of 63%, but the elongation decreased from 53.1% to 3.2%. A process of solid/liquid continuous casting and composite forming→drawing can work as a new compact method to produce brass cladding pure copper stranded wire composite as railway through grounding wire. 展开更多
关键词 solid/liquid continuous casting composite wire deformation microstructure evolution mechanical properties
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