The effect of cathodic hydrogen charging on the tensile and constant load properties was deter- mined for an austenitic stainless steel weldment comprising a 304L steel in the solution treated condition as a base meta...The effect of cathodic hydrogen charging on the tensile and constant load properties was deter- mined for an austenitic stainless steel weldment comprising a 304L steel in the solution treated condition as a base metal and a 308L filler steel as a weld metal. Part of the 304L solution treated steel was separately given additional sensitization treatment to simulate the microstructure that would develop in the heat affected zone. Tests were performed at room temperature on notched round bar specimens. Hydrogen charging resulted in a pronounced embrittlement of the tested materials. This was manifested mainly as a considerable loss in the ductility of tensile specimens and a decrease in the time to failure and threshold stress of constant load specimens. The 308L weld metal exhibited the highest, and the 304L solution treated steel the lowest, resistance to hydrogen embrittlement. Hydrogen embrittlement was associated with the formation of strain induced martensite as well as a transition from brittle to ductile fracture morphology onwards the centre of the specimens.展开更多
This work investigates the relative aggressiveness of nitrate solutions at different pH values on mild steel towards stress corrosion cracking (SCC) and general corrosion. Electrochemical behavior and stress corrosion...This work investigates the relative aggressiveness of nitrate solutions at different pH values on mild steel towards stress corrosion cracking (SCC) and general corrosion. Electrochemical behavior and stress corrosion cracking sus-ceptibility measurements were carried out in 52 Wt% ammonium nitrate solutions at 368° K and various pH values ranging from 0.77 to 9.64. Constant load stress corrosion test at 90% yield stress was conducted. Tested specimens were prepared and examined using the scanning electron microscope (SEM). The potentiodynamic polarization curves for different pH values again emphasized the validity of the gravimetric measurements and hence the mechanism of cracking was attributed to the stress that assisted the dissolution process.展开更多
The effect of varying the temperature and the concentration of ammonium nitrate solution on the stress corrosion cracking (SCC) susceptibility of mild steel is studied. An increase in the temperature causes a decrease...The effect of varying the temperature and the concentration of ammonium nitrate solution on the stress corrosion cracking (SCC) susceptibility of mild steel is studied. An increase in the temperature causes a decrease in the stress corrosion life. It appears that the susceptibility in the range 368 K to 380 K was greater than at other temperatures. Near the boiling point corrosion and stress corrosion occurs, at the boiling point, the cracking was associated with a high rate of general corrosion. Microscopic examination after stress corrosion testing in 10Wt%, 20Wt%, and 52Wt% NH4NO3 solution revealed that in all cases there was severe intergranular attack, especially at the high concentration.展开更多
文摘The effect of cathodic hydrogen charging on the tensile and constant load properties was deter- mined for an austenitic stainless steel weldment comprising a 304L steel in the solution treated condition as a base metal and a 308L filler steel as a weld metal. Part of the 304L solution treated steel was separately given additional sensitization treatment to simulate the microstructure that would develop in the heat affected zone. Tests were performed at room temperature on notched round bar specimens. Hydrogen charging resulted in a pronounced embrittlement of the tested materials. This was manifested mainly as a considerable loss in the ductility of tensile specimens and a decrease in the time to failure and threshold stress of constant load specimens. The 308L weld metal exhibited the highest, and the 304L solution treated steel the lowest, resistance to hydrogen embrittlement. Hydrogen embrittlement was associated with the formation of strain induced martensite as well as a transition from brittle to ductile fracture morphology onwards the centre of the specimens.
文摘This work investigates the relative aggressiveness of nitrate solutions at different pH values on mild steel towards stress corrosion cracking (SCC) and general corrosion. Electrochemical behavior and stress corrosion cracking sus-ceptibility measurements were carried out in 52 Wt% ammonium nitrate solutions at 368° K and various pH values ranging from 0.77 to 9.64. Constant load stress corrosion test at 90% yield stress was conducted. Tested specimens were prepared and examined using the scanning electron microscope (SEM). The potentiodynamic polarization curves for different pH values again emphasized the validity of the gravimetric measurements and hence the mechanism of cracking was attributed to the stress that assisted the dissolution process.
文摘The effect of varying the temperature and the concentration of ammonium nitrate solution on the stress corrosion cracking (SCC) susceptibility of mild steel is studied. An increase in the temperature causes a decrease in the stress corrosion life. It appears that the susceptibility in the range 368 K to 380 K was greater than at other temperatures. Near the boiling point corrosion and stress corrosion occurs, at the boiling point, the cracking was associated with a high rate of general corrosion. Microscopic examination after stress corrosion testing in 10Wt%, 20Wt%, and 52Wt% NH4NO3 solution revealed that in all cases there was severe intergranular attack, especially at the high concentration.
