Sodium-ion batteries(SIBs)have recently gained wildly interest due to the abundance of sodium,lower production costs,and better low-temperature performance compared to lithium-ion batteries(LIBs).Among various cathode...Sodium-ion batteries(SIBs)have recently gained wildly interest due to the abundance of sodium,lower production costs,and better low-temperature performance compared to lithium-ion batteries(LIBs).Among various cathode materials of SIBs,O_(3)-type NaNi_(0.4)Fe_(0.2)Mn_(0.4)O_(2)(NFM424)demonstrates high capacity and ease of synthesis,yet suffers from structural degradation and sluggish Na^(+)kinetics caused by large ionic radius and strong electrostatic interactions.To overcome these issues,a configuration strategy combined with TiO_(2) and Co_(3)O_(4) by a simple solid-state reaction method was introduced to improve structural and electrochemical stability.XRD,SEM,TEM,and various electrochemical characterizations as well as TGA/DSC tests were conducted.The resulting NaNi_(0.4)Fe_(0.2)Mn_(0.3)Co_(0.05)Ti_(0.05)O_(2)(NFMCT)cathode mitigated Jahn-Teller distortions and Na^(+)/vacancy ordering while enhancing phase integrity and diffusion pathways.The obtained NFMCT maintained 93.7 mAh·g^(−1) after 550 cycles at 1 C,with superior rate capabilities at 2 C and 5 C.These findings deepen the understanding of configuration strategy by using multi-element oxide and highlight a practical strategy for designing high-performance SIB cathodes.展开更多
Unified power quality conditioner(UPQC)with energy storage is commonly based on conventional capacity configuration strategy with power angle control.It has problems such as phase jumping before and after compensation...Unified power quality conditioner(UPQC)with energy storage is commonly based on conventional capacity configuration strategy with power angle control.It has problems such as phase jumping before and after compensation.DC-link cannot continuously emit active power externally.Therefore,this paper presents the compensation strategy of full load voltage magnitude and phase in capacity configuration of UPQC.The topology of UPQC is integrated a series active power filter(SAPF),a shunt active power filter(PAPF)and a photovoltaic-battery energy storage system(PV-BESS).The principle of full load voltage compensation is analyzed based on the PV-BESS-UPQC topology.Themagnitude constant of load voltage ismaintained by controlling the appropriate shunt compensation current.Then the UPQC capacity configuration is carried out using the full load voltage compensation strategy.The compensation capacity of UPQC series and shunt units are reduced.Finally,the simulation results show that the proposed compensation strategy reduces the capacity configuration by 5.11 kVA(36.4%)compared to the conventional compensation strategy.The proposed strategy can achieve full compensation of the load voltage,which can effectively reduce the capacity allocation and improve the economy of UPQC.It also has the PV-BESS units’ability of providing active power and can stabilize the DC-link voltage.展开更多
基金funded by the National Natural Science Foundation of China(Grants 21701083 and 22179054)Jiangsu Provincial Key Research and Development Program(BZ2023010)2023 Jiangsu Government Scholarship for Overseas Studies.
文摘Sodium-ion batteries(SIBs)have recently gained wildly interest due to the abundance of sodium,lower production costs,and better low-temperature performance compared to lithium-ion batteries(LIBs).Among various cathode materials of SIBs,O_(3)-type NaNi_(0.4)Fe_(0.2)Mn_(0.4)O_(2)(NFM424)demonstrates high capacity and ease of synthesis,yet suffers from structural degradation and sluggish Na^(+)kinetics caused by large ionic radius and strong electrostatic interactions.To overcome these issues,a configuration strategy combined with TiO_(2) and Co_(3)O_(4) by a simple solid-state reaction method was introduced to improve structural and electrochemical stability.XRD,SEM,TEM,and various electrochemical characterizations as well as TGA/DSC tests were conducted.The resulting NaNi_(0.4)Fe_(0.2)Mn_(0.3)Co_(0.05)Ti_(0.05)O_(2)(NFMCT)cathode mitigated Jahn-Teller distortions and Na^(+)/vacancy ordering while enhancing phase integrity and diffusion pathways.The obtained NFMCT maintained 93.7 mAh·g^(−1) after 550 cycles at 1 C,with superior rate capabilities at 2 C and 5 C.These findings deepen the understanding of configuration strategy by using multi-element oxide and highlight a practical strategy for designing high-performance SIB cathodes.
基金Supported by Open Project of Jiangsu Key Laboratory of Power Transmission&Distribution Equipment Technology(2021JSSPD12)Supported by Talent Projects of Jiangsu University of Technology(KYY20018)Supported by Graduate Practice Innovation Program of Jiangsu University of Technology(XSJCX21_32).
文摘Unified power quality conditioner(UPQC)with energy storage is commonly based on conventional capacity configuration strategy with power angle control.It has problems such as phase jumping before and after compensation.DC-link cannot continuously emit active power externally.Therefore,this paper presents the compensation strategy of full load voltage magnitude and phase in capacity configuration of UPQC.The topology of UPQC is integrated a series active power filter(SAPF),a shunt active power filter(PAPF)and a photovoltaic-battery energy storage system(PV-BESS).The principle of full load voltage compensation is analyzed based on the PV-BESS-UPQC topology.Themagnitude constant of load voltage ismaintained by controlling the appropriate shunt compensation current.Then the UPQC capacity configuration is carried out using the full load voltage compensation strategy.The compensation capacity of UPQC series and shunt units are reduced.Finally,the simulation results show that the proposed compensation strategy reduces the capacity configuration by 5.11 kVA(36.4%)compared to the conventional compensation strategy.The proposed strategy can achieve full compensation of the load voltage,which can effectively reduce the capacity allocation and improve the economy of UPQC.It also has the PV-BESS units’ability of providing active power and can stabilize the DC-link voltage.
