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Thermodynamic Correlation Between Surface Carboxyl Configuration and Wettability
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作者 GUO Zhuohuan WANG Dayang 《高等学校化学学报》 北大核心 2026年第1期255-266,共12页
In this study,polyacrylic acid(PAA)films were employed as a model system,and a series of PAA films with tunable water wettability was systematically prepared by varying molecular weight and curing temperature.Using at... In this study,polyacrylic acid(PAA)films were employed as a model system,and a series of PAA films with tunable water wettability was systematically prepared by varying molecular weight and curing temperature.Using attenuated total reflectance Fourier-transform infrared spectroscopy(ATR-FTIR),the molecular configurations of surface carboxyl groups(COOH),free carboxyl(COOH_(f))and hydrogen-bonded carboxyl(COOH_(HB),were directly correlated with the polar component of surface energy(γ^(s,p)).By decomposing theγ^(s,p)values of the PAA thin films as a sum of the contributions of COOH_(f)and COOH_(H B),the intrinsic polar component of surface energy of COOH_(H B)(γ_(H B)^(s,p*))was quantified for the first time as 8.34 mN/m,significantly lower than that of COOH_(f)(γ_(f)^(s,p*)=34 mN/m).This result highlights that hydrogen bonding markedly reduces theγ^(s,p),providing a rational explanation for the relatively large water contact angle observed on PAA thin films.Furthermore,it establishes a thermodynamic basis for estimating the fraction of surface COOH_(H B)groups(f H B)from wettability measurements.Further extension of the model to carboxyl-terminated self-assembled monolayers(COOH-SAMs)revealed that surface COOH density(ΣCOOH)critically regulates wetting behavior:whenΣCOOH ranges from 4.30 to 5.25 nm^(-2),COOH groups predominantly exist in a free state and facilitate effective hydration layers,thereby promoting superhydrophilicity.Overall,this study not only establishes a unified thermodynamic framework linking surface COOH configurations to macroscopic wettability,but also validates its universality by extending it to COOH-SAMs systems,thereby providing a unified theoretical framework for the controllable design of hydrophilicity in various COOH-functionalized surfaces. 展开更多
关键词 Polyacrylic acid film Hydrogen bonding Attenuated total reflectance Fourier-transform infrared spectroscopy Quantitative carboxyl configuration Polar component of surface energy
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High-Entropy Oxide Memristors for Neuromorphic Computing:From Material Engineering to Functional Integration
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作者 Jia‑Li Yang Xin‑Gui Tang +4 位作者 Xuan Gu Qi‑Jun Sun Zhen‑Hua Tang Wen‑Hua Li Yan-Ping Jiang 《Nano-Micro Letters》 2026年第2期138-169,共32页
High-entropy oxides(HEOs)have emerged as a promising class of memristive materials,characterized by entropy-stabilized crystal structures,multivalent cation coordination,and tunable defect landscapes.These intrinsic f... High-entropy oxides(HEOs)have emerged as a promising class of memristive materials,characterized by entropy-stabilized crystal structures,multivalent cation coordination,and tunable defect landscapes.These intrinsic features enable forming-free resistive switching,multilevel conductance modulation,and synaptic plasticity,making HEOs attractive for neuromorphic computing.This review outlines recent progress in HEO-based memristors across materials engineering,switching mechanisms,and synaptic emulation.Particular attention is given to vacancy migration,phase transitions,and valence-state dynamics—mechanisms that underlie the switching behaviors observed in both amorphous and crystalline systems.Their relevance to neuromorphic functions such as short-term plasticity and spike-timing-dependent learning is also examined.While encouraging results have been achieved at the device level,challenges remain in conductance precision,variability control,and scalable integration.Addressing these demands a concerted effort across materials design,interface optimization,and task-aware modeling.With such integration,HEO memristors offer a compelling pathway toward energy-efficient and adaptable brain-inspired electronics. 展开更多
关键词 High-entropy oxides MEMRISTORS Neuromorphic computing Configurational entropy Resistive switching
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Optimal Allocation of Multiple Energy Storage Capacity in Industrial Park Considering Demand Response and Laddered Carbon Trading
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作者 Jingshuai Pang Songcen Wang +5 位作者 Hongyin Chen Xiaoqiang Jia YiGuo Ling Cheng Xinhe Zhang Jianfeng Li 《Energy Engineering》 2026年第1期136-152,共17页
To achieve the goals of sustainable development of the energy system and the construction of a lowcarbon society,this study proposes a multi-energy storage collaborative optimization strategy for industrial park that ... To achieve the goals of sustainable development of the energy system and the construction of a lowcarbon society,this study proposes a multi-energy storage collaborative optimization strategy for industrial park that integrates the laddered carbon trading mechanism with demand response.Firstly,a dual dimensional DR model is constructed based on the characteristics of load elasticity.The alternativeDRenables flexible substitution of energy loads through complementary conversion of electricity/heat/cold multi-energy sources,while the price DR relies on timeof-use electricity price signals to guide load spatiotemporal migration;Secondly,the LCT mechanism is introduced to achieve optimal carbon emission costs through a tiered carbon quota allocation mechanism.On this basis,an optimization decision model is established with the core objective of maximizing the annual net profit of the park.The objective function takes into account energy sales revenue,generator unit costs,and investment and operation costs of multiple types of energy storage facilities.Themodel constraint system covers three key dimensions:dynamic operation constraints of power generation units,including unit output limits,ramping capability,and minimum start-stop time;the physical boundary of an electric/hot/cold multi-energy storage system involves energy storage capacity and charge/discharge efficiency;The multi-energy network coupling balance equation ensures that the energy conversion and transmission process satisfies the law of conservation of energy.Using CPLEX mathematical programming solver for simulation verification,construct an energy storage capacity configuration decision process that includes LCT-DR synergistic effect.The research results show that compared with the traditional single energy storage configuration mode,this strategy effectively enhances the economic feasibility and engineering practicality of industrial park operation by coordinating demand side resource scheduling and finely controlling carbon costs,while maintaining stable system operation.Its methodological framework provides a technical path that combines theoretical rigor and practical operability for the low-carbon transformation of regional integrated energy systems. 展开更多
关键词 Demand response laddered carbon trading combined cooling heating and power supply capacity configuration
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Coordination Thermodynamic Control of Magnetic Domain Configuration Evolution toward Low‑Frequency Electromagnetic Attenuation
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作者 Tong Huang Dan Wang +9 位作者 Xue He Zhaobo Feng Zhiqiang Xiong Yuqi Luo Yuhui Peng Guangsheng Luo Xuliang Nie Mingyue Yuan Chongbo Liu Renchao Che 《Nano-Micro Letters》 2026年第3期860-875,共16页
The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)at... The precise tuning of magnetic nanoparticle size and magnetic domains,thereby shaping magnetic properties.However,the dynamic evolution mechanisms of magnetic domain configurations in relation to electromagnetic(EM)attenuation behavior remain poorly understood.To address this gap,a thermodynamically controlled periodic coordination strategy is proposed to achieve precise modulation of magnetic nanoparticle spacing.This approach unveils the evolution of magnetic domain configurations,progressing from individual to coupled and ultimately to crosslinked domain configurations.A unique magnetic coupling phenomenon surpasses the Snoek limit in low-frequency range,which is observed through micromagnetic simulation.The crosslinked magnetic configuration achieves effective low-frequency EM wave absorption at 3.68 GHz,encompassing nearly the entire C-band.This exceptional magnetic interaction significantly enhances radar camouflage and thermal insulation properties.Additionally,a robust gradient metamaterial design extends coverage across the full band(2–40 GHz),effectively mitigating the impact of EM pollution on human health and environment.This comprehensive study elucidates the evolution mechanisms of magnetic domain configurations,addresses gaps in dynamic magnetic modulation,and provides novel insights for the development of high-performance,low-frequency EM wave absorption materials. 展开更多
关键词 Thermodynamically controlled coordination strategy Magnetic domain configuration Low-frequency electromagnetic wave absorption Electrical/magnetic coupling MULTIFUNCTION
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Pressure-Modulated Activation Energy as a Unified Descriptor of Mechanical Behavior in Metallic Glass
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作者 Huanrong Liu Jian Li +1 位作者 Shan Zhang Pengfei Guan 《Chinese Physics Letters》 2026年第1期71-82,共12页
The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ... The functional properties of glasses are governed by their formation history and the complex relaxation processes they undergo.However,under extreme conditions,glass behaviors are still elusive.In this study,we employ simulations with varied protocols to evaluate the effectiveness of different descriptors in predicting mechanical properties across both low-and high-pressure regimes.Our findings demonstrate that conventional structural and configurational descriptors fail to correlate with the mechanical response following pressure release,whereas the activation energy descriptor exhibits robust linearity with shear modulus after correcting for pressure effects.Notably,the soft mode parameter emerges as an ideal and computationally efficient alternative for capturing this mechanical behavior.These findings provide critical insights into the influence of pressure on glassy properties,integrating the distinct features of compressed glasses into a unified theoretical framework. 展开更多
关键词 pressure modulated activation energy predicting mechanical properties metallic glass relaxation processes functional properties mechanical behavior simulations varied protocols structural configurational descriptors
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Optimizing canopy-spacing configuration increases soybean yield under high planting density 被引量:4
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作者 Ruidong Li Cailong Xu +4 位作者 Zongsheng Wu Yifan Xu Shi Sun Wenwen Song Cunxiang Wu 《The Crop Journal》 2025年第1期233-245,共13页
Dense cropping increases crop yield but intensifies resource competition,which reduces single plant yield and limits potential yield growth.Optimizing canopy spacing could enhance resource utilization,support crop mor... Dense cropping increases crop yield but intensifies resource competition,which reduces single plant yield and limits potential yield growth.Optimizing canopy spacing could enhance resource utilization,support crop morphological development and increase yield.Here,a three-year study was performed to verify the feasibility of adjusting row spacing to further enhance yield in densely planted soybeans.Of three row-spacing configurations(40-40,20-40,and 20-60 cm)and two planting densities(normal 180,000 plants ha 1 and high 270,000 plants ha 1).The differences in canopy structure,plant morphological development,photosynthetic capacity and their impact on yield were analyzed.Row spacing configurations have a significant effect on canopy transmittance(CT).The 20-60 cm row spacing configuration increased CT and creates a favorable canopy light environment,in which plant height is reduced,while branching is promoted.This approach reduces plant competition,optimizes the developments of leaf area per plant,specific leaf area,leaf area development rate,leaf area duration and photosynthetic physiological indices(F_(v)/F_(m),ETR,P_(n)).The significant increase of 11.9%-34.2%in canopy apparent photosynthesis(CAP)is attributed to the significant optimization of plant growth and photosynthetic physiology through CT,an important contributing factor to yield increases.The yield in the 20-60 cm treatment is 4.0%higher than in equidistant planting under normal planting density,but 5.9%under high density,primarily driven by CAP and pod number.These findings suggest that suitable row spacing configurations optimize the light environment for plants,promote source-sink transformation in soybeans,and further improve yield.In practice,a 20-60 cm row spacing configuration could be employed for high-density soybean planting to achieve a more substantial yield gain. 展开更多
关键词 Soybean Planting density Row-spacing configuration Canopy transmittance Yield
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Geological characteristics,resource potential,and development direction of shale gas in China 被引量:2
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作者 GUO Xusheng WANG Ruyue +3 位作者 SHEN Baojian WANG Guanping WAN Chengxiang WANG Qianru 《Petroleum Exploration and Development》 2025年第1期17-32,共16页
By reviewing the research progress and exploration practices of shale gas geology in China,analyzing and summarizing the geological characteristics,enrichment laws,and resource potential of different types of shale ga... By reviewing the research progress and exploration practices of shale gas geology in China,analyzing and summarizing the geological characteristics,enrichment laws,and resource potential of different types of shale gas,the following understandings have been obtained:(1)Marine,transitional,and lacustrine shales in China are distributed from old to new in geological age,and the complexity of tectonic reworking and hydrocarbon generation evolution processes gradually decreases.(2)The sedimentary environment controls the type of source-reservoir configuration,which is the basis of“hydrocarbon generation and reservoir formation”.The types of source-reservoir configuration in marine and lacustrine shales are mainly source-reservoir integration,with occasional source-reservoir separation.The configuration types of transitional shale are mainly source-reservoir integration and source-reservoir symbiosis.(3)The resistance of rigid minerals to compression for pore preservation and the overpressure facilitate the enrichment of source-reservoir integrated shale gas.Good source reservoir coupling and preservation conditions are crucial for the shale gas enrichment of source-reservoir symbiosis and source-reservoir separation types.(4)Marine shale remains the main battlefield for increasing shale gas reserves and production in China,while transitional and lacustrine shales are expected to become important replacement areas.It is recommended to carry out the shale gas exploration at three levels:Accelerate the exploration of Silurian,Cambrian,and Permian marine shales in the Upper-Middle Yangtze region;make key exploration breakthroughs in ultra-deep marine shales of the Upper-Middle Yangtze region,the new Ordovician marine shale strata in the North China region,the transitional shales of the Carboniferous and Permian,as well as the Mesozoic lacustrine shale gas in basins such as Sichuan,Ordos and Songliao;explore and prepare for new shale gas exploration areas such as South China and Northwest China,providing technology and resource reserves for the sustainable development of shale gas in China. 展开更多
关键词 shale gas marine shale transitional shale lacustrine shale source-reservoir configuration enrichment mechanism resource potential
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Sedimentary Configuration Evolution and Controlling Factors of Channel-Levee Systems in the Offshore Indus Basin 被引量:1
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作者 LIANG Jie LI Sen +6 位作者 WANG Jianqiang LIAO Jing CHEN Jianwen GONG Jianming INAM Asif SYED Waseem Haider ZHANG Penghui 《Journal of Ocean University of China》 2025年第6期1485-1499,共15页
Recent advances in earth science and exploration have made deepwater channel-levee systems a research focus.We collected and analyzed over 10000 km of two-dimensional multichannel seismic data from the offshore Indus ... Recent advances in earth science and exploration have made deepwater channel-levee systems a research focus.We collected and analyzed over 10000 km of two-dimensional multichannel seismic data from the offshore Indus Basin to identify channellevee systems at various hierarchical levels depending on their seismic reflection characteristics.Seismic facies analysis was integrated with well data to map the spatial distribution of channel-levee systems in the offshore Indus Basin across various geological periods,and the factors influencing their development were discussed.These systems within the basin were identified using a developed,refined three-tier classification method.The first-order system consists of multiple spatially stacked complexes,the second-order system continuously developed multistage channel-levee bodies,and the third-order system represents the smallest identifiable sedimentary units on seismic profiles.Our findings demonstrate the evolution of the offshore Indus Basin from a single-stage channel with lateral migration to multistage vertical channel stacking from the Miocene to the Pleistocene.Tectonic activities exert their effect on channel-levee systems through their influence on the relative sea level.They also trigger volcanic or seismic events and affect siliciclastic supply.Warm and humid climate conditions form large river systems,which aid in the transport of terrestrial debris to the basin margin.Most channel-levee systems are assumed to have formed during low sea-level periods.This study offers new insights into the formation and evolution of turbidite sedimentary systems in the offshore Indus Basin and presents a practical classification method for comprehending gravity-flow sedimentary configurations and deepwater hydrocarbon exploration. 展开更多
关键词 offshore Indus Basin channel-levee system sedimentary configuration seismic facies analysis sedimentary evolution
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High-entropy materials for solid oxide cells 被引量:1
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作者 Qinqin Wang Wei Kong +1 位作者 Shanshan Jiang Daifen Chen 《International Journal of Minerals,Metallurgy and Materials》 2025年第11期2598-2620,共23页
Solid oxide cells(SOCs),which include solid oxide fuel cells(SOFCs),symmetrical solid oxide cells(S-SOCs),and reversible solid oxide cells(R-SOCs),are considered key technologies for driving low-carbon and green revol... Solid oxide cells(SOCs),which include solid oxide fuel cells(SOFCs),symmetrical solid oxide cells(S-SOCs),and reversible solid oxide cells(R-SOCs),are considered key technologies for driving low-carbon and green revolution in the energy sector.Because of their clean,low-cost,and high-efficiency characteristics,SOCs have great potential for energy conversion and storage.However,the further development of SOC technologies faces challenges,such as a lack of long-term operational stability of the cell system,high material cost under high-temperature operating conditions,and limited catalytic effects at low temperatures.Recently,high-entropy materials(HEMs)have demonstrated excellent performance and wide application prospects in catalytic reactions,energy storage,supercapacitors,and other fields owing to their unique atomic arrangement and the four core effects(high mixed entropy stabilization effect,sluggish dif-fusion effect,lattice distortion effect,and“cocktail”effect).HEMs provide a new perspective for solving the aforementioned problems in the field of SOCs.This comprehensive review summarizes the applications of HEMs in the three fundamental components of SOCs:elec-trodes,electrolytes,and interconnects,focusing on the role of HEMs in enhancing catalytic activity and conductivity while mitigating harmful gas poisoning.In addition,this review proposes possible development directions for HEMs in SOCs based on the current re-search progress,providing valuable reference for high-entropy designs aimed at further enhancing the performance of SOCs. 展开更多
关键词 high-entropy materials solid oxide cells configurational entropy electrochemical reaction structural stability
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Novel entropy-stabilized spinel materials and their potential application in high-temperature industry:[(Mg_(x)Zn_((1-x)/2)Cu_((1-x)/2))(Al_(0.9)Fe_(0.1))_(2)O_(4)](x=0.5,0.6,0.7,and 0.8) 被引量:1
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作者 Bo-Kang Li Lv-Ping Fu +2 位作者 Hua-Zhi Gu Ao Huang Shuang Yang 《Rare Metals》 2025年第8期5844-5858,共15页
High-temperature industries,as the primary consumers of energy,are greatly concerned with energy savings.Designing refractory linings with low thermal conductivity to reduce heat dissipation through high-temperature f... High-temperature industries,as the primary consumers of energy,are greatly concerned with energy savings.Designing refractory linings with low thermal conductivity to reduce heat dissipation through high-temperature furnace linings is a critical concern.In this study,a series of novel entropy-stabilized spinel materials are reported,and their potential applications in high-temperature industries are investigated.XRD and TEM results indicate that all materials possess a cubic spinel crystal structure with the■space group.Furthermore,these materials exhibit good phase stability at high temperatures.All entropy-stabilized spinel aggregates demonstrated high refractoriness(>1800℃)and a high load softening temperature(>1700℃).The impact of configurational entropy on the properties of entropy-stabilized spinel materials was also studied.As configurational entropy increased,the thermal conductivity of the entropy-stabilized spinel decreased,while slag corrosion resistance deteriorated.For the entropy-stabilized spinel with a configurational entropy value of 1.126R,it showed good high-temperature stability,reliable resistance to slag attack,and a low thermal conductivity of 2.776 W·m^(-1)·K^(-1)at 1000℃. 展开更多
关键词 Entropy-stabilized spinel Thermal conductivity High-temperature performance Configurational entropy
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Influence of geometric configurations on friction characteristics during incremental forming process of AA5052 sheet metal 被引量:1
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作者 Guang-can YANG Da-wei ZHANG +1 位作者 Chong TIAN Sheng-dun ZHAO 《Transactions of Nonferrous Metals Society of China》 2025年第3期715-733,共19页
The influence of geometric configuration on the friction characteristics during incremental sheet forming of AA5052 was analyzed by integrating surface morphology and its characteristic parameters,along with plastic s... The influence of geometric configuration on the friction characteristics during incremental sheet forming of AA5052 was analyzed by integrating surface morphology and its characteristic parameters,along with plastic strain,contact pressure,and area.The interface promotes lubrication and support when wall angles were≤40°,a 0.5 mm-thin sheet was used,and a 10 mm-large tool radius was employed.This mainly results in micro-plowing and plastic extrusion flow,leading to lower friction coefficient.However,when wall angles exceed 40°,significant plastic strain roughening occurs,leading to inadequate lubrication on the newly formed surface.Increased sheet thickness and decreased tool radius elevate contact pressure.These actions trigger micro-cutting and adhesion,potentially leading to localized scuffing and dimple tears,and higher friction coefficient.The friction mechanisms remain unaffected by the part’s plane curve features.As the forming process progresses,abrasive wear intensifies,and surface morphology evolves unfavorably for lubrication and friction reduction. 展开更多
关键词 AA5052 sheet metal incremental forming process geometric configurations surface morphology characteristics friction mechanism
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Design and experimental study of a field-reversed configuration plasma thruster prototype 被引量:1
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作者 Yuxuan HUANG Ming ZHANG +5 位作者 Yong YANG Fangwei LYU Xiaopeng YI Chaofan LYU Yisong ZHANG Bo RAO 《Plasma Science and Technology》 2025年第3期118-126,共9页
The field-reversed configuration(FRC)plasma thruster driven by rotating magnetic field(RMF),abbreviated as the RMF-FRC thruster,is a new type of electric propulsion technology that is expected to accelerate the deep s... The field-reversed configuration(FRC)plasma thruster driven by rotating magnetic field(RMF),abbreviated as the RMF-FRC thruster,is a new type of electric propulsion technology that is expected to accelerate the deep space exploration.An experimental prototype,including diagnostic devices,was designed and constructed based on the principles of the RMF-FRC thruster,with an RMF frequency of 210 kHz and a maximum peak current of 2 kA.Under the rated operating conditions,the initial plasma density was measured to be 5×10^(17)m^(-3),and increased to 2.2×10^(19)m^(-3)after the action of RMF.The coupling efficiency of RMF was about 53%,and the plasma current reached 1.9 kA.The axial magnetic field changed in reverse by 155 Gauss,successfully reversing the bias magnetic field of 60 Gauss,which verifies the formation of FRC plasma.After optimization research,it was found that when the bias magnetic field is 100 Gauss,the axial magnetic field reverse variation caused by FRC is the highest at 164 Gauss.The experimental results are discussed and strategies are proposed to improve the performance of the prototype. 展开更多
关键词 rotating magnetic field(RMF) field-reversed configuration(FRC) plasma thrusters plasma current
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Simulation and Optimization of Coupling Dynamic Response of Steel Catenary Riser for a Semi-Submersible Platform Under Harsh Conditions in the South China Sea 被引量:1
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作者 YIN Qi-shuai YAN Xin-ye +6 位作者 ZHU Hong CHEN Ke-jin YANG Jin LIU Lu-yao GAO Bing-zhen GUO Ying-ying MA Yong-qi 《China Ocean Engineering》 2025年第5期917-927,共11页
Steel catenary riser represents the pioneering riser technology implemented in China’s deep-sea oil and gas opera-tions.Given the complex mechanical conditions of the riser,extensive research has been conducted on it... Steel catenary riser represents the pioneering riser technology implemented in China’s deep-sea oil and gas opera-tions.Given the complex mechanical conditions of the riser,extensive research has been conducted on its dynamic analysis and structural design.This study investigates a deep-sea oil and gas field by developing a coupled model of a semi-submersible platform and steel catenary riser to analyze it mechanical behavior under extreme marine condi-tions.Through multi-objective optimization methodology,the study compares and analyzes suspension point tension and touchdown point stress under various conditions by modifying the suspension position,suspension angle,and catenary length.The optimal configuration parameters were determined:a suspension angle of 12°,suspension position in the southwest direction of the column,and a catenary length of approximately 2000 m.These findings elucidate the impact of configuration parameters on riser dynamic response and establish reasonable parameter layout ranges for adverse sea conditions,offering valuable optimization strategies for steel catenary riser deployment in domestic deep-sea oil and gas fields. 展开更多
关键词 steel catenary riser(SCR) multi-objective optimization riser configuration parameters harsh condi-tions dynamic analysis South China Sea
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Electrocatalytic CO_(2)reduction for the selective production of liquid oxygenates 被引量:1
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作者 Jiapeng Ji Junnan Chen +2 位作者 Juxia Xiong Xiaolong Zhang Hui-Ming Cheng 《Journal of Energy Chemistry》 2025年第4期568-600,共33页
Electrocatalytic CO_(2)reduction(ECR)to produce value-added fuels and chemicals using renewable electricity is an emerging strategy to mitigate global warming and decrease reliance on fossil fuels.Among various ECR pr... Electrocatalytic CO_(2)reduction(ECR)to produce value-added fuels and chemicals using renewable electricity is an emerging strategy to mitigate global warming and decrease reliance on fossil fuels.Among various ECR products,liquid oxygenates(Oxys)are especially attractive due to their high energy density,high safety and transportability that could be adapted to the existing infrastructure and transportation system.However,efficiently generating these highly reduced oxygen-containing products by ECR remains challenging due to the complexity of coupled proton and electron transfer processes.In recent years,in-depth studies of reaction mechanisms have advanced the design of catalysts and the regulation of reaction systems for ECR to produce Oxys,Here,by focusing on the production of typical Oxys,such as methanol,acetic acid,ethanol,acetone,n-propanol,and isopropanol,we outline various reaction paths and key intermediates for the electrochemical conversion of CO_(2)into these target products.We also summarize the current research status and recent advances in catalysts based on their elemental composition,and consider recent studies on the change of catalyst geometry and electronic structure,as well as the optimization of reaction systems to increase ECR performance.Finally,we analyze the challenges in the field of ECR to Oxys and provide an outlook on future directions for high-efficiency catalyst prediction and design,as well as the development of advanced reaction systems. 展开更多
关键词 Electrocatalytic CO_(2)reduction Geometry and electronic structure Parameters and system configurations Liquid oxygenates
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The work hardening and softening behavior of spherical Ti_(p)/Mg-5Zn-0.3Ca composite 被引量:1
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作者 Cui-ju Wang Jin-Kai Zhang +2 位作者 Kai-bo Nie Chao Xu Kun-kun Deng 《Journal of Magnesium and Alloys》 2025年第6期2752-2768,共17页
To obtain the Ti_(p)with different aspect ratios,the Ti_(p)/Mg-5Zn-0.3Ca composite prepared by semi-solid stir casting was subjected to extrusion at 220℃,180℃,and 140℃,respectively.Then,the effect of the Ti_(p)’s ... To obtain the Ti_(p)with different aspect ratios,the Ti_(p)/Mg-5Zn-0.3Ca composite prepared by semi-solid stir casting was subjected to extrusion at 220℃,180℃,and 140℃,respectively.Then,the effect of the Ti_(p)’s aspect ratio on the microstructure,mechanical properties,work hardening and softening behaviors of Ti_(p)/Mg-5Zn-0.3Ca composites was investigated.The results indicated that the Ti_(p)could be elongated obviously after low-temperature extrusion,and the aspect ratio of which would reach to 13.7:1 as the extrusion temperature deceased to 140℃.Then the“Ti/Mg”layer-like structure was formed in the Ti_(p)/Mg-5Zn-0.3Ca composite.Accompanied with the elongation of Ti_(p),the dynamic recrystallized grains and dynamic precipitates were both refined significantly,however,the dynamic recrystallization rate changed a little.The elongated Ti_(p)endowed the Ti_(p)/Mg-5Zn-0.3Ca composites with better matching of strength and toughness without the sacrifice of elongation and bending strain.Both the work hardening rate and softening rate of Ti_(p)/Mg-5Zn-0.3Ca composites increased with the increasing aspect ratio of Ti_(p).The formation of“Ti/Mg”layer-like structure contributed to the redistribution of strain from large aggregations to a network-like distribution,which effectively suppresses the initiation and propagation of micro-cracks,thus enhancing the plasticity of the Ti_(p)/Mg-5Zn-0.3Ca composites. 展开更多
关键词 Ti_(p) Particle reinforced magnesium matrix composites Work hardening and softening behavior Laminar-like configuration
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Modeling and Capacity Configuration Optimization of CRH5 EMU On-Board Energy Storage System
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作者 Mingxing Tian Weiyuan Zhang Zhaoxu Su 《Energy Engineering》 EI 2025年第1期307-329,共23页
In the context of the“dual carbon”goals,to address issues such as high energy consumption,high costs,and low power quality in the rapid development of electrified railways,this study focused on the China Railways Hi... In the context of the“dual carbon”goals,to address issues such as high energy consumption,high costs,and low power quality in the rapid development of electrified railways,this study focused on the China Railways High-Speed 5 Electric Multiple Unit and proposed a mathematical model and capacity optimization method for an onboard energy storage system using lithium batteries and supercapacitors as storage media.Firstly,considering the electrical characteristics,weight,and volume of the storage media,a mathematical model of the energy storage system was established.Secondly,to tackle problems related to energy consumption and power quality,an energy management strategy was proposed that comprehensively considers peak shaving and valley filling and power quality by controlling the charge/discharge thresholds of the storage system.Thecapacity optimization adopted a bilevel programming model,with the series/parallel number of storage modules as variables,considering constraints imposed by the Direct Current to Direct Current converter,train load,and space.An improved Particle Swarm Optimization algorithm and linear programming solver were used to solve specific cases.The results show that the proposed onboard energy storage system can effectively achieve energy savings,reduce consumption,and improve power qualitywhile meeting the load and space limitations of the train. 展开更多
关键词 Electrified railway regenerative braking bi-level programming on-board energy storage power quality capacity configuration
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Dual-surface capped hydroxyapatite nano-amendment with tuned alternate long-short chain configuration for efficient adsorption towards multi-heavy metal ions in complex-contaminated systems
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作者 GAO Mochou MENG Shan +7 位作者 ZHANG Jinzhong FENG Wenhua DONG Shuo CHEN Jianping ZHAO Yanbao YU Laigui YING Rongrong ZOU Xueyan 《无机化学学报》 北大核心 2025年第7期1427-1438,共12页
Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)an... Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides. 展开更多
关键词 heavy metal HYDROXYAPATITE nano-amendment configuration tuning synergistic adsorption
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A review of ultrafast supercapacitors for AC-line filtering
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作者 SUN Qian FAN Ya-feng +4 位作者 XIE Li-jing WANG Zhen-bing HUANG Xian-hong SU Fang-yuan CHEN Cheng-meng 《新型炭材料(中英文)》 北大核心 2025年第2期243-269,共27页
Filter capacitors play an important role in altern-ating current(AC)-line filtering for stabilizing voltage,sup-pressing harmonics,and improving power quality.However,traditional aluminum electrolytic capacitors(AECs)... Filter capacitors play an important role in altern-ating current(AC)-line filtering for stabilizing voltage,sup-pressing harmonics,and improving power quality.However,traditional aluminum electrolytic capacitors(AECs)suffer from a large size,short lifespan,low power density,and poor reliability,which limits their use.In contrast,ultrafast supercapacitors(SCs)are ideal for replacing commercial AECs because of their extremely high power densities,fast charging and discharging,and excellent high-frequency re-sponse.We review the design principles and key parameters for ultrafast supercapacitors and summarize research pro-gress in recent years from the aspects of electrode materials,electrolytes,and device configurations.The preparation,structures,and frequency response performance of electrode materials mainly consisting of carbon materials such as graphene and carbon nanotubes,conductive polymers,and transition metal compounds,are focused on.Finally,future research directions for ultrafast SCs are suggested. 展开更多
关键词 Ultrafast supercapacitors AC-line filtering Electrode materials Electrolytes Cell configuration design
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Conformation and Dynamics of a Long Active Polymer Chain Confined in a Circular Cavity
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作者 Xiao Yang Yan-Li Zhou +2 位作者 Bin Zhao Chao Wang Meng-Bo Luo 《Chinese Journal of Polymer Science》 2025年第1期225-234,I0014,共11页
The conformational and dynamical properties of a long semi-flexible active polymer chain confined in a circular cavity are studied by using Langevin dynamics simulation method.Results show that the steady radius of gy... The conformational and dynamical properties of a long semi-flexible active polymer chain confined in a circular cavity are studied by using Langevin dynamics simulation method.Results show that the steady radius of gyration of the polymer decreases monotonically with increasing the active force.Interestingly,the polymer forms stable compact spiral with directional rotation at the steady state when the active force is large.Both the radius of gyration and the angular velocity of the spiral are nearly independent of the cavity size,but show scaling relations with the active force and the polymer length.It is further found that the formation of the stable compact spiral in most cases is a two-step relaxation process,where the polymer first forms a metastable swelling quasi spiral and then transforms into the stable compacted spiral near the wall of the cavity.The relaxation time is mainly determined by the transformation of the swelling quasi spiral,and shows remarkable dependence on the size of the cavity.Specially,when the circumference of the circular is nearly equivalent to the polymer length,it is difficult for the polymer to form the compacted spiral,leading to a large relaxation time.The underlying mechanism of the formation of the compacted spiral is revealed. 展开更多
关键词 Active polymer CONFINEMENT CONFIGURATION DYNAMICS Simulation
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An Improved LZO Compression Algorithm for FPGA Configuration Bitstream Files
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作者 Xiaoling Lai Jian Zhang +3 位作者 Yangming Guo Ting Ju Qi Zhu Guochang Zhou 《Computers, Materials & Continua》 2025年第2期3091-3109,共19页
With the increase in the quantity and scale of Static Random-Access Memory Field Programmable Gate Arrays (SRAM-based FPGAs) for aerospace application, the volume of FPGA configuration bit files that must be stored ha... With the increase in the quantity and scale of Static Random-Access Memory Field Programmable Gate Arrays (SRAM-based FPGAs) for aerospace application, the volume of FPGA configuration bit files that must be stored has increased dramatically. The use of compression techniques for these bitstream files is emerging as a key strategy to alleviate the burden on storage resources. Due to the severe resource constraints of space-based electronics and the unique application environment, the simplicity, efficiency and robustness of the decompression circuitry is also a key design consideration. Through comparative analysis current bitstream file compression technologies, this research suggests that the Lempel Ziv Oberhumer (LZO) compression algorithm is more suitable for satellite applications. This paper also delves into the compression process and format of the LZO compression algorithm, as well as the inherent characteristics of configuration bitstream files. We propose an improved algorithm based on LZO for bitstream file compression, which optimises the compression process by refining the format and reducing the offset. Furthermore, a low-cost, robust decompression hardware architecture is proposed based on this method. Experimental results show that the compression speed of the improved LZO algorithm is increased by 3%, the decompression hardware cost is reduced by approximately 60%, and the compression ratio is slightly reduced by 0.47%. 展开更多
关键词 FPGA configuration bitstream file LZO compression DECOMPRESSION
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