This paper analysis the developing of expendable conductivity temperature depth measuring system(XCTD)and introduce its principle of measuring about temperature,salinity and depth of ocean.Some key techniques are put ...This paper analysis the developing of expendable conductivity temperature depth measuring system(XCTD)and introduce its principle of measuring about temperature,salinity and depth of ocean.Some key techniques are put forward.According to the real needs of XCTD,conductivity sensor with high sensitivity is designed by principle of electromagnetic induce,the ocean conductivity from induced electromotive force has been calculated.Adding temperature correction circuit would help to reduce error of conductivity measurement because of sharply changing temperature.Advanced temperature measuring circuit of high precision and the constant current source is used to weaken effect of self-heating of resistance and fluctuation of the source.On respect of remote data transmission,LVDS is a good choice for the purpose of guarantee the quality of data transmitted and the transmission distance is reaching to thousand meters in the seawater.Modular programming method is also brought into this research aimed at improve the stability,reliability and maintainability of the whole measuring system.In February,2015,the trials in South China Sea demonstrate that the developed XCTD realize effective measurement at a speed of 6 knots and detection depth at 800 m.The consistency coefficient of the acquired data is greater than 0.99 and the success rate of probe launching is above 90%.展开更多
Polymer dielectrics possessing excellent electrical insulation and high thermal conductivity are pivotal for dielectric capacitors at elevated temperatures.However,the integration of electrical insulation and thermal ...Polymer dielectrics possessing excellent electrical insulation and high thermal conductivity are pivotal for dielectric capacitors at elevated temperatures.However,the integration of electrical insulation and thermal conductivity in polymers remains a challenge.In this work,we present a feasible strategy to integrate high electrical insulation and high thermal conductivity by bonding carbon quantum dots(CQDs)with the diamine monomer of polyetherimide(PEI).The CQDs with Coulomb blockade effect serve as traps for the migrating of electrons in the dielectrics,while the bonding networks formed by CQDs and PEI further deepen the traps and augment trap density.As a result,the hybrid dielectrics(PEI-NH_(2)-CQDs)exhibit nearly an order of magnitude higher electrical resistivity than that of pure PEI,leading to an 80%increase in discharge energy density with an energy efficiency of 90%at 200℃ compared to pure counterpart.Additionally,this all-organic dielectric achieves a significantly increased thermal conductivity of 0.65 W m^(-1) K^(-1) compared to 0.26 W m^(-1) K^(-1) of PEI,which supports its cyclic stability at elevated temperatures.We also demonstrate the kilogram-scale production of CQDs,synthesizing over 8 kg in a single batch,paving the way for large-scale production of reliable PEI-NH_(2)-CQDs dielectrics.展开更多
This study focused on the hydraulic conductivity of sand in centrifuge modeling.A self-designed temperature-controlled falling-head permeameter apparatus was used,and a series of falling-head seepage tests were perfor...This study focused on the hydraulic conductivity of sand in centrifuge modeling.A self-designed temperature-controlled falling-head permeameter apparatus was used,and a series of falling-head seepage tests were performed on sand samples with various porosities at different temperatures and centrifugal accelerations.The objectives were to qualitatively and quantitatively investigate the effects of temperature,porosity,and centrifugal acceleration on the hydraulic conductivity of sand and to study the applicability of the Kozeny-Carman equation for the centrifugal environment.Test results showed that in a similar temperature range and under the same porosity,the hydraulic conductivity of the sand is linearly correlated with centrifugal acceleration.When subjected to the same centrifugal acceleration and in a similar temperature range,the hydraulic conductivity of the sand exhibits an almost linear increase in relation to its porosity function(s^(3)/(1−s)^(2));the functional relationships between the hydraulic conductivity of the sand and temperature,centrifugal acceleration level,and porosity were established using two pathways.When the centrifugal acceleration is less than 50g,the Kozeny-Carman equation is effectively accurate in predicting the hydraulic conductivity of sand;however,when the centrifugal acceleration exceeds 50g,it is important to consider a significant error.展开更多
In order to meet the practical needs of all-fiber conductivity-temperature-depth sensors with high sensitivity,compact structure,and easy packaging,this Letter uses a microfiber coupler combined with fiber loop(MCFL)r...In order to meet the practical needs of all-fiber conductivity-temperature-depth sensors with high sensitivity,compact structure,and easy packaging,this Letter uses a microfiber coupler combined with fiber loop(MCFL)reflective photonic device to conduct salinity,temperature,and deep sensing experiments.These MCFLs’dynamic range and resolution of salinity,temperature,and depth can meet the requirements of actual marine environment monitoring.This structure opens up a new design idea for the practical research of microfiber coupler-based marine environmental parameter sensors.展开更多
The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metalli...The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metallic monospirals of small radius curvature with high density and regular distribution of dislocations. Transition into state of SC has been observed experimentally in the range from –50 up to 3000°C at the density of transmitting current up to 2·109 A/cm2. The experimental data confirming the watched phenomenon are represented. The explanations of this phenomenon are being proposed in the framework of the dislocation model.展开更多
The SiO_2 nanoparticles were coated on the surface of graphene oxide(GO) by sol-gel method to get the SiO_2-G compound.The SiO_2-G was restored and oleophylically modified to prepare hydrophobic modified SiO_2-G(HM-Si...The SiO_2 nanoparticles were coated on the surface of graphene oxide(GO) by sol-gel method to get the SiO_2-G compound.The SiO_2-G was restored and oleophylically modified to prepare hydrophobic modified SiO_2-G(HM-SiO_2-G) which was subsequently added to silicone rubber matrix to prepare two-component room temperature vulcanized(RTV-2) thermal conductive silicone rubber. The morphology, chemical structure and dispersity of the modified graphene were characterized with SEM, FTIR, Raman, and XPS methods.In addition, the heat-resistance behavior, mechanical properties, thermal conductivity, and electrical conductivity of the RTV-2 silicone rubber were also studied systematically. The results showed that the SiO_2 nanoparticles were coated on graphene oxide successfully, and HM-SiO_2-G was uniformly dispersed in RTV-2 silicone rubber. The addition of HM-SiO_2-G could effectively improve the thermal stability, mechanical properties and thermal conductivity of RTV-2 silicone rubber and had no great influence on the electrical insulation performance.展开更多
At presure 1.0-4.0 GPa and temperature 1073-1423 K and under oxygen partial pressure conditions, a YJ-3000t multi-anvil solid high-pressure apparatus and Sarltron-1260 Impedance/Gain-Phase analyzer were employed to co...At presure 1.0-4.0 GPa and temperature 1073-1423 K and under oxygen partial pressure conditions, a YJ-3000t multi-anvil solid high-pressure apparatus and Sarltron-1260 Impedance/Gain-Phase analyzer were employed to conduct an in-situ measurement of the electrical conductivity of orthopyroxene. The buffering reagents consist of Ni＋NiO, Fe＋Fe3O4, Fe＋FeO and Mo＋MoO2 in order to control the environmental oxygen fugacity. Experimental results made clear that： （1） within the measuring frequency range from 10-1 to 106 Hz, the complex impedance （R） is of intensive dependence on the frequency; （2） The electrical conductivity （a） tends to increase along to the rise of temperature （T）, and Log a vs. 1/ T fit the Arrenhius linear relations; （3） Under the control of oxygen buffer Fe＋Fe3O4, with the rise of pressure, the activation enthalpy tends to increase whereas the electrical conductivity tends to decrease. The activation energy and activation volume of the main current carders of orthopyroxene have been obtained, which are （1.715±0.035） eV and （0.03±0.01） cm^3/mol, respectively; （4） Under given pressure and temperature, the electrical conductivity tends to increase with increasing oxygen fugacity, while under given pressure the activation enthalpy tends to decrease with increasing oxygen fugacity; and （5） The sample＇s small polarons mechanism has provided a reasonable explanations to the conduction behavior at high temperature and high pressure.展开更多
Porous ultra-high temperature ceramics(UHTCs) are potential candidates as high-temperature thermal insulation materials. However, high thermal conductivity is the main obstacle to the application of porous UHTCs. In o...Porous ultra-high temperature ceramics(UHTCs) are potential candidates as high-temperature thermal insulation materials. However, high thermal conductivity is the main obstacle to the application of porous UHTCs. In order to address this problem, herein, a new method combining in-situ reaction and partial sintering has been developed for preparing porous Zr C and Hf C with low conductivity. In this process, porous Zr C and Hf C are directly obtained from ZrO2/C and HfO2/C green bodies without adding any pore-forming agents. The release of reaction gas can not only increase the porosity but also block the shrinkage. The asprepared porous Zr C and Hf C exhibit homogeneous porous microstructure with grain sizes in the range of 300–600 nm and 200–500 nm, high porosity of 68.74% and 77.82%, low room temperature thermal conductivity of 1.12 and 1.01 W·m-1 K-1, and compressive strength of 8.28 and 5.51 MPa, respectively.These features render porous Zr C and Hf C promising as light-weight thermal insulation materials for ultrahigh temperature applications. Furthermore, the feasibility of this method has been demonstrated and porous Nb C, Ta C as well as Ti C have been prepared by this method.展开更多
To study the effect of high temperature, rice seedlings 20, 30, 40 and 50 d were kept at 5, 10, 15 and 20 cm water depth in a water pool. Meteorological findings indicated that water temperature varied up to 10 cm but...To study the effect of high temperature, rice seedlings 20, 30, 40 and 50 d were kept at 5, 10, 15 and 20 cm water depth in a water pool. Meteorological findings indicated that water temperature varied up to 10 cm but became stable below this depth. Deep water inflicted higher tiller mortality, minimal increase in dry weight of aerial parts and leaf area, decrease in root length, and decrease in root dry weight especially at 20 cm water depth and produced an unbalanced T/R ratio (top versus root dry weight). However, deep water tended to increase plant length. These parameters, however, excel in shallow water. Older seedlings, with the exception of root dry weight, could not perform well compared to young seedlings in all physiological and morphological aspects. The study revealed that seedlings, particularly young ones, stand well in shallow water and can cope with high temperature.展开更多
The influence of annealing cycles up to 650 °C on the specific conductivity and hardness（HV） of hot-rolled sheets of Al alloys containing up to 0.5% Zr（mass fraction） was studied.Using analytical calculations...The influence of annealing cycles up to 650 °C on the specific conductivity and hardness（HV） of hot-rolled sheets of Al alloys containing up to 0.5% Zr（mass fraction） was studied.Using analytical calculations of phase composition and experimental methods（scanning electron microscopy,transmission electron microscopy,electron microprobe analysis,etc）,it is demonstrated that the conductivity depends on the content of Zr in the Al solid solution which is the minimum after holding at 450 °C for 3 h.On the other hand,the hardness of the alloy is mainly caused by the amount of nanoparticles of the L12（Al3Zr） phase that defines the retention of strain hardening.It is shown that the best combination of electrical conductivity and hardness values can be reached within an acceptable holding time at the temperature about 450 °C.展开更多
The use of steel slag,which is a by-product of the steel manufacture,in the construction of asphalt pavement would contribute to waste reduction and environment protection.Using rubber asphalt at the same time can imp...The use of steel slag,which is a by-product of the steel manufacture,in the construction of asphalt pavement would contribute to waste reduction and environment protection.Using rubber asphalt at the same time can improve the performance of asphalt mixture.This study investigates the influence of steel slag content on the road performance,thermal conductivity and outdoor temperature distribution of steel slag rubber asphalt mixtures(SSRAM),and calculates the cumulative stress in surface layer.At a certain range of concentration,the steel slag additive improved the deformation resistance and low-temperature cracking resistance of the mixtures.The SSRAM with 40%steel slag content has the best deformation resistance while SSRAM with 60%steel slag content performed well in low-temperature cracking resistance.The thermal conductivity of the SSRAM with different steel slag content(0%,20%,40%,60%,80%,and 100%)was 1.994,2.188,2.239,2.255,2.288,and 2.295 W/(m·K),respectively.Measurements of the outdoor temperature distribution further confirmed that steel slag increased the thermal conductivity of the mixtures,thereby increasing the cumulative temperature difference between the top and bottom layers.The temperature stress and temperature-stress ratio of the SSRAM with 40%steel slag were 0.43 MPa and 0.24,while the SSRAM with 100%steel slag were 0.58 MPa and 0.36.The stress and stress ratio were much higher in the SSRAM with 100%steel slag than in the specimen with 40%steel slag.Accordingly,the maximum accumulated temperature stress aggrandized and caused early temperature cracks in the surface layer.The optimum content of steel slag was 40%.展开更多
This study cross-calibrated the brightness temperatures observed in the Arctic by using the FY-3B/MWRI L1 and the Aqua/AMSR-E L2A.The monthly parameters of the cross-calibration were determined and evaluated using rob...This study cross-calibrated the brightness temperatures observed in the Arctic by using the FY-3B/MWRI L1 and the Aqua/AMSR-E L2A.The monthly parameters of the cross-calibration were determined and evaluated using robust linear regression.The snow depth in case of seasonal ice was calculated by using parameters of the crosscalibration of data from the MWRI Tb.The correlation coefficients of the H/V polarization among all channels Tb of the two sensors were higher than 0.97.The parameters of the monthly cross-calibration were useful for the snow depth retrieval using the MWRI.Data from the MWRI Tb were cross-calibrated to the AMSR-E baseline.Biases in the data of the two sensors were optimized to approximately 0 K through the cross-calibration,the standard deviations decreased significantly in the range of 1.32 K to 2.57 K,and the correlation coefficients were as high as 99%.An analysis of the statistical distributions of the histograms before and after cross-calibration indicated that the FY-3B/MWRI Tb data had been well calibrated.Furthermore,the results of the cross-calibration were evaluated by data on the daily average Tb at 18.7 GHz,23.8 GHz,and 36.5 GHz(V polarization),and at 89 GHz(H/V polarization),and were applied to the snow depths retrieval in the Arctic.The parameters of monthly cross-calibration were found to be effective in terms of correcting the daily average Tb.The results of the snow depths were compared with those of the calibrated MWRI and AMSR-E products.Biases of 0.18 cm to 0.38 cm were observed in the monthly snow depths,with the standard deviations ranging from 4.19 cm to 4.80 cm.展开更多
The dynamic properties of proton conductivity along hydrogen-bonded molecular systems, for example, ice crystal, with structure disorder or damping and finite temperatures exposed in an externally applied electric-fie...The dynamic properties of proton conductivity along hydrogen-bonded molecular systems, for example, ice crystal, with structure disorder or damping and finite temperatures exposed in an externally applied electric-field have been numerically studied by Runge-Kutta way in our soliton model. The results obtained show that the proton-soliton is very robust against the structure disorder including the fluctuation of the force constant and disorder in the sequence of masses and thermal perturbation and damping of medium, the velocity of its conductivity increases with increasing of the externally applied electric-field and decreasing of the damping coefficient of medium, but the proton-soliton disperses for quite great fluctuation of the ＂force constant and damping coefficient. In the numerical simulation we find that the proton-soliton in our model is thermally stable in a large region of temperature of T ≤ 273 K under influences of damping and externally applied electric-field in ice crvstal. This shows that our model is available and appropriate to ice.展开更多
Poly(ethylene oxide)(PEO)is a classic matrix model for solid polymer electrolyte which can not only dissociate lithium-ions(Li^(+)),but also can conduct Li^(+) through segmental motion in long-range.However,the crysta...Poly(ethylene oxide)(PEO)is a classic matrix model for solid polymer electrolyte which can not only dissociate lithium-ions(Li^(+)),but also can conduct Li^(+) through segmental motion in long-range.However,the crystal aggregation state of PEO restricts the conduction of Li^(+) especially at room temperature.In this work,an amorphous polymer electrolyte with ethylene oxide(EO)and propylene oxide(PO)block structure(B-PEG@DMC)synthesized by the transesterification is firstly obtained,showing an ionic conductivity value of 1.1×10^(5) S/cm at room temperature(25℃).According to the molecular dynamics(MD)simulation,the PO segments would lead to an inconsecutive and hampered conduction of Li^(+),which is not beneficial to the short range conduction of Li^(+).Thus the effect of transformation of aggregation state on the improveme nt of ionic conductivity is not eno ugh,it is n ecessary to further consider the differe nt coupled behaviours of EO and PO segments with Li^(+).In this way,we blend this amorphous polymer(B-PEG@DMC)with PEO to obtain a dual range ionic conductive solid polymer electrolyte(D-SPE)with further improved ionic conductivity promoted by constructing a dual range fast ionic conduction,which eventually shows a further improved ionic conductivity value of 2.3×10^(5) S/cm at room temperature.展开更多
A significant amount of research is concerned with dynamic modal parameters for damage detection of structural conditions due to their simplicity in use and feasibility.However,their use for damage detection should be...A significant amount of research is concerned with dynamic modal parameters for damage detection of structural conditions due to their simplicity in use and feasibility.However,their use for damage detection should be performed with special attention,particularly in operational and environmental conditions subjected to temperature changes.Beams in construction industries experience different loading types,such as temperature changes leading to crack initiation and propagation.Changed physical and dynamic properties such as natural frequencies and mode shapes indicate that damage has occurred within the structures.In this study,vibration analysis of cantilever and cantilever simply supported beams has been carried out on intact and damaged beams to investigate the coupled effect of temperature changes and damage depth on natural frequencies.A numerical analysis of beams is completed using ANSYS software.The results of numerical simulation are validated using two other studies from literature.Numerical results revealed that in order to perform a successful damage assessment using the frequency shift,the vibration modes should be selected properly.In addition,an increase in temperature results in a decrease in structural frequencies.The assessment of the effect of damage depth on natural frequencies also confirms that when damage depth is increased,there is a significant decrease in natural frequency responses.展开更多
Electrical conductivity of chromium polyacrylate with dopant concentration 30, 40 and 50 wt-% of chromium has been measured over a broad range of temperatures (303 K to 383 K).The electrical conductivity shows depende...Electrical conductivity of chromium polyacrylate with dopant concentration 30, 40 and 50 wt-% of chromium has been measured over a broad range of temperatures (303 K to 383 K).The electrical conductivity shows dependence on temperature, as well as, level of doping. The conductivity is considered to be due to thermal hopping motion of localized charge carriers,which are believed to be polarons, in the temperature range 303 K to 323 K and for T>343 K,whereas. it is metal-like in the temperature range 323 K to 343 K展开更多
A new practical equation is derived from the Miller-Abrahams theory for different site-energies,and the temperaturedependent conductivity of Fibonacci lattice is calculated by a real-space renormalization-group approa...A new practical equation is derived from the Miller-Abrahams theory for different site-energies,and the temperaturedependent conductivity of Fibonacci lattice is calculated by a real-space renormalization-group approach.It is shown that there exist two types of temperature-dependent conductivity at low-and high-frequencies.Furthermore,it is found that the low-frequency conductivity oscillates dramatically with temperature.展开更多
Li_(1.5)Ga_(0.5)Ti_(1.5)PO_(4))_(3)(LGTP)is recognized as a promising solid electrolyte material for lithium ions.In this work,LGTP solid electrolyte materials were prepared under different process conditions to explo...Li_(1.5)Ga_(0.5)Ti_(1.5)PO_(4))_(3)(LGTP)is recognized as a promising solid electrolyte material for lithium ions.In this work,LGTP solid electrolyte materials were prepared under different process conditions to explore the effects of sintering temperature and holding time on relative density,phase composition,microstructure,bulk conductivity,and total conductivity.In the impedance test under frequency of 1-10^(6) Hz,the bulk conductivity of the samples increased with increasing sintering temperature,and the total conductivity first increased and then decreased.SEM results showed that the average grain size in the ceramics was controlled by the sintering temperature,which increased from(0.54±0.01)μm to(1.21±0.01)μm when the temperature changed from 750 to 950°C.The relative density of the ceramics increased and then decreased with increasing temperature as the porosity increased.The holding time had little effect on the grain size growth or sample density,but an extended holding time resulted in crack generation that served to reduce the conductivity of the solid electrolyte.展开更多
Investigating the thermal transport properties of materials is of great importance in the field of earth science and for the development of materials under extremely high temperatures and pressures.However,it is an en...Investigating the thermal transport properties of materials is of great importance in the field of earth science and for the development of materials under extremely high temperatures and pressures.However,it is an enormous challenge to characterize the thermal and physical properties of materials using the diamond anvil cell(DAC)platform.In the present study,a steady-state method is used with a DAC and a combination of thermocouple temperature measurement and numerical analysis is performed to calculate the thermal conductivity of the material.To this end,temperature distributions in the DAC under high pressure are analyzed.We propose a three-dimensional radiative-conductive coupled heat transfer model to simulate the temperature field in the main components of the DAC and calculate in situ thermal conductivity under high-temperature and high-pressure conditions.The proposed model is based on the finite volume method.The obtained results show that heat radiation has a great impact on the temperature field of the DAC,so that ignoring the radiation effect leads to large errors in calculating the heat transport properties of materials.Furthermore,the feasibility of studying the thermal conductivity of different materials is discussed through a numerical model combined with locally measured temperature in the DAC.This article is expected to become a reference for accurate measurement of in situ thermal conductivity in DACs at high-temperature and high-pressure conditions.展开更多
文摘This paper analysis the developing of expendable conductivity temperature depth measuring system(XCTD)and introduce its principle of measuring about temperature,salinity and depth of ocean.Some key techniques are put forward.According to the real needs of XCTD,conductivity sensor with high sensitivity is designed by principle of electromagnetic induce,the ocean conductivity from induced electromotive force has been calculated.Adding temperature correction circuit would help to reduce error of conductivity measurement because of sharply changing temperature.Advanced temperature measuring circuit of high precision and the constant current source is used to weaken effect of self-heating of resistance and fluctuation of the source.On respect of remote data transmission,LVDS is a good choice for the purpose of guarantee the quality of data transmitted and the transmission distance is reaching to thousand meters in the seawater.Modular programming method is also brought into this research aimed at improve the stability,reliability and maintainability of the whole measuring system.In February,2015,the trials in South China Sea demonstrate that the developed XCTD realize effective measurement at a speed of 6 knots and detection depth at 800 m.The consistency coefficient of the acquired data is greater than 0.99 and the success rate of probe launching is above 90%.
基金supported by the National Natural Science Foundation of China(52172265)Excellent Youth Science Foundation of Hunan Province(2022JJ20067)+1 种基金The Science and Technology Innovation Program of Hunan Province(2022RC1074)Central South University Innovation-Driven Research Program(2023CXQD010).
文摘Polymer dielectrics possessing excellent electrical insulation and high thermal conductivity are pivotal for dielectric capacitors at elevated temperatures.However,the integration of electrical insulation and thermal conductivity in polymers remains a challenge.In this work,we present a feasible strategy to integrate high electrical insulation and high thermal conductivity by bonding carbon quantum dots(CQDs)with the diamine monomer of polyetherimide(PEI).The CQDs with Coulomb blockade effect serve as traps for the migrating of electrons in the dielectrics,while the bonding networks formed by CQDs and PEI further deepen the traps and augment trap density.As a result,the hybrid dielectrics(PEI-NH_(2)-CQDs)exhibit nearly an order of magnitude higher electrical resistivity than that of pure PEI,leading to an 80%increase in discharge energy density with an energy efficiency of 90%at 200℃ compared to pure counterpart.Additionally,this all-organic dielectric achieves a significantly increased thermal conductivity of 0.65 W m^(-1) K^(-1) compared to 0.26 W m^(-1) K^(-1) of PEI,which supports its cyclic stability at elevated temperatures.We also demonstrate the kilogram-scale production of CQDs,synthesizing over 8 kg in a single batch,paving the way for large-scale production of reliable PEI-NH_(2)-CQDs dielectrics.
基金supported by the Basic Science Center Program for Multiphase Media Evolution in Hypergravity of the National Natural Science Foundation of China(No.51988101)。
文摘This study focused on the hydraulic conductivity of sand in centrifuge modeling.A self-designed temperature-controlled falling-head permeameter apparatus was used,and a series of falling-head seepage tests were performed on sand samples with various porosities at different temperatures and centrifugal accelerations.The objectives were to qualitatively and quantitatively investigate the effects of temperature,porosity,and centrifugal acceleration on the hydraulic conductivity of sand and to study the applicability of the Kozeny-Carman equation for the centrifugal environment.Test results showed that in a similar temperature range and under the same porosity,the hydraulic conductivity of the sand is linearly correlated with centrifugal acceleration.When subjected to the same centrifugal acceleration and in a similar temperature range,the hydraulic conductivity of the sand exhibits an almost linear increase in relation to its porosity function(s^(3)/(1−s)^(2));the functional relationships between the hydraulic conductivity of the sand and temperature,centrifugal acceleration level,and porosity were established using two pathways.When the centrifugal acceleration is less than 50g,the Kozeny-Carman equation is effectively accurate in predicting the hydraulic conductivity of sand;however,when the centrifugal acceleration exceeds 50g,it is important to consider a significant error.
基金supported by the National Key R&D Program of China(No.2017YFB0405503)the National Natural Science Foundation of China(No.61805278)+1 种基金the Equipment Pre-Research Field Foundation(No.61404140304)the China Postdoctoral Science Foundation(No.2018M633704).
文摘In order to meet the practical needs of all-fiber conductivity-temperature-depth sensors with high sensitivity,compact structure,and easy packaging,this Letter uses a microfiber coupler combined with fiber loop(MCFL)reflective photonic device to conduct salinity,temperature,and deep sensing experiments.These MCFLs’dynamic range and resolution of salinity,temperature,and depth can meet the requirements of actual marine environment monitoring.This structure opens up a new design idea for the practical research of microfiber coupler-based marine environmental parameter sensors.
文摘The description of experimentally observed phenomenon of abnormally high electrical conductivity—'superconductivity' (SC) at the room and higher temperatures is represented. The effect was observed in metallic monospirals of small radius curvature with high density and regular distribution of dislocations. Transition into state of SC has been observed experimentally in the range from –50 up to 3000°C at the density of transmitting current up to 2·109 A/cm2. The experimental data confirming the watched phenomenon are represented. The explanations of this phenomenon are being proposed in the framework of the dislocation model.
基金the Guangdong Province Science and Technology projects(No.2017A040402005)Guangdong Bureau of Quality and Technical Supervision Science and Technology projects(No.2017CT30)for financial support of this work
文摘The SiO_2 nanoparticles were coated on the surface of graphene oxide(GO) by sol-gel method to get the SiO_2-G compound.The SiO_2-G was restored and oleophylically modified to prepare hydrophobic modified SiO_2-G(HM-SiO_2-G) which was subsequently added to silicone rubber matrix to prepare two-component room temperature vulcanized(RTV-2) thermal conductive silicone rubber. The morphology, chemical structure and dispersity of the modified graphene were characterized with SEM, FTIR, Raman, and XPS methods.In addition, the heat-resistance behavior, mechanical properties, thermal conductivity, and electrical conductivity of the RTV-2 silicone rubber were also studied systematically. The results showed that the SiO_2 nanoparticles were coated on graphene oxide successfully, and HM-SiO_2-G was uniformly dispersed in RTV-2 silicone rubber. The addition of HM-SiO_2-G could effectively improve the thermal stability, mechanical properties and thermal conductivity of RTV-2 silicone rubber and had no great influence on the electrical insulation performance.
基金This research project was granted by the Knowledge-Innovation Program sponsored by the Chinese Academy of Sciences(KZCX3-SW-124).
文摘At presure 1.0-4.0 GPa and temperature 1073-1423 K and under oxygen partial pressure conditions, a YJ-3000t multi-anvil solid high-pressure apparatus and Sarltron-1260 Impedance/Gain-Phase analyzer were employed to conduct an in-situ measurement of the electrical conductivity of orthopyroxene. The buffering reagents consist of Ni＋NiO, Fe＋Fe3O4, Fe＋FeO and Mo＋MoO2 in order to control the environmental oxygen fugacity. Experimental results made clear that： （1） within the measuring frequency range from 10-1 to 106 Hz, the complex impedance （R） is of intensive dependence on the frequency; （2） The electrical conductivity （a） tends to increase along to the rise of temperature （T）, and Log a vs. 1/ T fit the Arrenhius linear relations; （3） Under the control of oxygen buffer Fe＋Fe3O4, with the rise of pressure, the activation enthalpy tends to increase whereas the electrical conductivity tends to decrease. The activation energy and activation volume of the main current carders of orthopyroxene have been obtained, which are （1.715±0.035） eV and （0.03±0.01） cm^3/mol, respectively; （4） Under given pressure and temperature, the electrical conductivity tends to increase with increasing oxygen fugacity, while under given pressure the activation enthalpy tends to decrease with increasing oxygen fugacity; and （5） The sample＇s small polarons mechanism has provided a reasonable explanations to the conduction behavior at high temperature and high pressure.
基金financially supported by the National Natural Science Foundation of China under Grant Nos. 51672064 and U1435206the Beijing Municipal Science & Technology Commission under Grant No. D161100002416001
文摘Porous ultra-high temperature ceramics(UHTCs) are potential candidates as high-temperature thermal insulation materials. However, high thermal conductivity is the main obstacle to the application of porous UHTCs. In order to address this problem, herein, a new method combining in-situ reaction and partial sintering has been developed for preparing porous Zr C and Hf C with low conductivity. In this process, porous Zr C and Hf C are directly obtained from ZrO2/C and HfO2/C green bodies without adding any pore-forming agents. The release of reaction gas can not only increase the porosity but also block the shrinkage. The asprepared porous Zr C and Hf C exhibit homogeneous porous microstructure with grain sizes in the range of 300–600 nm and 200–500 nm, high porosity of 68.74% and 77.82%, low room temperature thermal conductivity of 1.12 and 1.01 W·m-1 K-1, and compressive strength of 8.28 and 5.51 MPa, respectively.These features render porous Zr C and Hf C promising as light-weight thermal insulation materials for ultrahigh temperature applications. Furthermore, the feasibility of this method has been demonstrated and porous Nb C, Ta C as well as Ti C have been prepared by this method.
文摘To study the effect of high temperature, rice seedlings 20, 30, 40 and 50 d were kept at 5, 10, 15 and 20 cm water depth in a water pool. Meteorological findings indicated that water temperature varied up to 10 cm but became stable below this depth. Deep water inflicted higher tiller mortality, minimal increase in dry weight of aerial parts and leaf area, decrease in root length, and decrease in root dry weight especially at 20 cm water depth and produced an unbalanced T/R ratio (top versus root dry weight). However, deep water tended to increase plant length. These parameters, however, excel in shallow water. Older seedlings, with the exception of root dry weight, could not perform well compared to young seedlings in all physiological and morphological aspects. The study revealed that seedlings, particularly young ones, stand well in shallow water and can cope with high temperature.
基金Project(RMEF157814X0004)supported by the Ministry of Education and Science of the Russian Federation
文摘The influence of annealing cycles up to 650 °C on the specific conductivity and hardness（HV） of hot-rolled sheets of Al alloys containing up to 0.5% Zr（mass fraction） was studied.Using analytical calculations of phase composition and experimental methods（scanning electron microscopy,transmission electron microscopy,electron microprobe analysis,etc）,it is demonstrated that the conductivity depends on the content of Zr in the Al solid solution which is the minimum after holding at 450 °C for 3 h.On the other hand,the hardness of the alloy is mainly caused by the amount of nanoparticles of the L12（Al3Zr） phase that defines the retention of strain hardening.It is shown that the best combination of electrical conductivity and hardness values can be reached within an acceptable holding time at the temperature about 450 °C.
基金This research was funded by the Department of Transportation of Hebei Province(Grant No.TH1-202019).
文摘The use of steel slag,which is a by-product of the steel manufacture,in the construction of asphalt pavement would contribute to waste reduction and environment protection.Using rubber asphalt at the same time can improve the performance of asphalt mixture.This study investigates the influence of steel slag content on the road performance,thermal conductivity and outdoor temperature distribution of steel slag rubber asphalt mixtures(SSRAM),and calculates the cumulative stress in surface layer.At a certain range of concentration,the steel slag additive improved the deformation resistance and low-temperature cracking resistance of the mixtures.The SSRAM with 40%steel slag content has the best deformation resistance while SSRAM with 60%steel slag content performed well in low-temperature cracking resistance.The thermal conductivity of the SSRAM with different steel slag content(0%,20%,40%,60%,80%,and 100%)was 1.994,2.188,2.239,2.255,2.288,and 2.295 W/(m·K),respectively.Measurements of the outdoor temperature distribution further confirmed that steel slag increased the thermal conductivity of the mixtures,thereby increasing the cumulative temperature difference between the top and bottom layers.The temperature stress and temperature-stress ratio of the SSRAM with 40%steel slag were 0.43 MPa and 0.24,while the SSRAM with 100%steel slag were 0.58 MPa and 0.36.The stress and stress ratio were much higher in the SSRAM with 100%steel slag than in the specimen with 40%steel slag.Accordingly,the maximum accumulated temperature stress aggrandized and caused early temperature cracks in the surface layer.The optimum content of steel slag was 40%.
基金The National Key Research and Development Program of China under contract Nos 2019YFA0607001 and2016YFC1402704the Global Change Research Program of China under contract No.2015CB9539011
文摘This study cross-calibrated the brightness temperatures observed in the Arctic by using the FY-3B/MWRI L1 and the Aqua/AMSR-E L2A.The monthly parameters of the cross-calibration were determined and evaluated using robust linear regression.The snow depth in case of seasonal ice was calculated by using parameters of the crosscalibration of data from the MWRI Tb.The correlation coefficients of the H/V polarization among all channels Tb of the two sensors were higher than 0.97.The parameters of the monthly cross-calibration were useful for the snow depth retrieval using the MWRI.Data from the MWRI Tb were cross-calibrated to the AMSR-E baseline.Biases in the data of the two sensors were optimized to approximately 0 K through the cross-calibration,the standard deviations decreased significantly in the range of 1.32 K to 2.57 K,and the correlation coefficients were as high as 99%.An analysis of the statistical distributions of the histograms before and after cross-calibration indicated that the FY-3B/MWRI Tb data had been well calibrated.Furthermore,the results of the cross-calibration were evaluated by data on the daily average Tb at 18.7 GHz,23.8 GHz,and 36.5 GHz(V polarization),and at 89 GHz(H/V polarization),and were applied to the snow depths retrieval in the Arctic.The parameters of monthly cross-calibration were found to be effective in terms of correcting the daily average Tb.The results of the snow depths were compared with those of the calibrated MWRI and AMSR-E products.Biases of 0.18 cm to 0.38 cm were observed in the monthly snow depths,with the standard deviations ranging from 4.19 cm to 4.80 cm.
基金The project supported by National Natural Science Foundation of China under Grant No. 90306015
文摘The dynamic properties of proton conductivity along hydrogen-bonded molecular systems, for example, ice crystal, with structure disorder or damping and finite temperatures exposed in an externally applied electric-field have been numerically studied by Runge-Kutta way in our soliton model. The results obtained show that the proton-soliton is very robust against the structure disorder including the fluctuation of the force constant and disorder in the sequence of masses and thermal perturbation and damping of medium, the velocity of its conductivity increases with increasing of the externally applied electric-field and decreasing of the damping coefficient of medium, but the proton-soliton disperses for quite great fluctuation of the ＂force constant and damping coefficient. In the numerical simulation we find that the proton-soliton in our model is thermally stable in a large region of temperature of T ≤ 273 K under influences of damping and externally applied electric-field in ice crvstal. This shows that our model is available and appropriate to ice.
基金support from the National Natural Science Foundation of China[22021001,21875195]the Fundamental Research Funds for the Central Universities[20720190040]the Key Project of Science and Technology of Xiamen[3502Z20201013]。
文摘Poly(ethylene oxide)(PEO)is a classic matrix model for solid polymer electrolyte which can not only dissociate lithium-ions(Li^(+)),but also can conduct Li^(+) through segmental motion in long-range.However,the crystal aggregation state of PEO restricts the conduction of Li^(+) especially at room temperature.In this work,an amorphous polymer electrolyte with ethylene oxide(EO)and propylene oxide(PO)block structure(B-PEG@DMC)synthesized by the transesterification is firstly obtained,showing an ionic conductivity value of 1.1×10^(5) S/cm at room temperature(25℃).According to the molecular dynamics(MD)simulation,the PO segments would lead to an inconsecutive and hampered conduction of Li^(+),which is not beneficial to the short range conduction of Li^(+).Thus the effect of transformation of aggregation state on the improveme nt of ionic conductivity is not eno ugh,it is n ecessary to further consider the differe nt coupled behaviours of EO and PO segments with Li^(+).In this way,we blend this amorphous polymer(B-PEG@DMC)with PEO to obtain a dual range ionic conductive solid polymer electrolyte(D-SPE)with further improved ionic conductivity promoted by constructing a dual range fast ionic conduction,which eventually shows a further improved ionic conductivity value of 2.3×10^(5) S/cm at room temperature.
基金This work is partially supported by the Anhui Provincial International Joint Research Center of Data Diagnosis and Smart Maintenance on Bridge Structures(No.2021AHGHZD01)the Nanjing Science and Technology Project(No.202002014)the Nantong Science and Technology Opening Cooperation Project in 2021(No.BW2021001).
文摘A significant amount of research is concerned with dynamic modal parameters for damage detection of structural conditions due to their simplicity in use and feasibility.However,their use for damage detection should be performed with special attention,particularly in operational and environmental conditions subjected to temperature changes.Beams in construction industries experience different loading types,such as temperature changes leading to crack initiation and propagation.Changed physical and dynamic properties such as natural frequencies and mode shapes indicate that damage has occurred within the structures.In this study,vibration analysis of cantilever and cantilever simply supported beams has been carried out on intact and damaged beams to investigate the coupled effect of temperature changes and damage depth on natural frequencies.A numerical analysis of beams is completed using ANSYS software.The results of numerical simulation are validated using two other studies from literature.Numerical results revealed that in order to perform a successful damage assessment using the frequency shift,the vibration modes should be selected properly.In addition,an increase in temperature results in a decrease in structural frequencies.The assessment of the effect of damage depth on natural frequencies also confirms that when damage depth is increased,there is a significant decrease in natural frequency responses.
文摘Electrical conductivity of chromium polyacrylate with dopant concentration 30, 40 and 50 wt-% of chromium has been measured over a broad range of temperatures (303 K to 383 K).The electrical conductivity shows dependence on temperature, as well as, level of doping. The conductivity is considered to be due to thermal hopping motion of localized charge carriers,which are believed to be polarons, in the temperature range 303 K to 323 K and for T>343 K,whereas. it is metal-like in the temperature range 323 K to 343 K
基金Supported by the National Natural Science Foundation of China under Grant No.59871044the Hu'nan Provincial Natural Science Foundation of China under Grant No.96WLX001010.
文摘A new practical equation is derived from the Miller-Abrahams theory for different site-energies,and the temperaturedependent conductivity of Fibonacci lattice is calculated by a real-space renormalization-group approach.It is shown that there exist two types of temperature-dependent conductivity at low-and high-frequencies.Furthermore,it is found that the low-frequency conductivity oscillates dramatically with temperature.
基金funded by the National Natural Science Foundation of China(Nos.51672310,51272288,51972344)。
文摘Li_(1.5)Ga_(0.5)Ti_(1.5)PO_(4))_(3)(LGTP)is recognized as a promising solid electrolyte material for lithium ions.In this work,LGTP solid electrolyte materials were prepared under different process conditions to explore the effects of sintering temperature and holding time on relative density,phase composition,microstructure,bulk conductivity,and total conductivity.In the impedance test under frequency of 1-10^(6) Hz,the bulk conductivity of the samples increased with increasing sintering temperature,and the total conductivity first increased and then decreased.SEM results showed that the average grain size in the ceramics was controlled by the sintering temperature,which increased from(0.54±0.01)μm to(1.21±0.01)μm when the temperature changed from 750 to 950°C.The relative density of the ceramics increased and then decreased with increasing temperature as the porosity increased.The holding time had little effect on the grain size growth or sample density,but an extended holding time resulted in crack generation that served to reduce the conductivity of the solid electrolyte.
基金Project supported by the National Key Research and Development Program of China(Grant No.2018YFA0702700)the National Natural Science Foundation of China(Grant Nos.11674404 and 11774126)。
文摘Investigating the thermal transport properties of materials is of great importance in the field of earth science and for the development of materials under extremely high temperatures and pressures.However,it is an enormous challenge to characterize the thermal and physical properties of materials using the diamond anvil cell(DAC)platform.In the present study,a steady-state method is used with a DAC and a combination of thermocouple temperature measurement and numerical analysis is performed to calculate the thermal conductivity of the material.To this end,temperature distributions in the DAC under high pressure are analyzed.We propose a three-dimensional radiative-conductive coupled heat transfer model to simulate the temperature field in the main components of the DAC and calculate in situ thermal conductivity under high-temperature and high-pressure conditions.The proposed model is based on the finite volume method.The obtained results show that heat radiation has a great impact on the temperature field of the DAC,so that ignoring the radiation effect leads to large errors in calculating the heat transport properties of materials.Furthermore,the feasibility of studying the thermal conductivity of different materials is discussed through a numerical model combined with locally measured temperature in the DAC.This article is expected to become a reference for accurate measurement of in situ thermal conductivity in DACs at high-temperature and high-pressure conditions.
