We herein reported a design strategy for the construction of resorcin[4]arene-based metal–organic complexes through adjusting auxiliary linkers.By precisely tuning 1,4-benzenedicarboxylic acid analogs,a series of iso...We herein reported a design strategy for the construction of resorcin[4]arene-based metal–organic complexes through adjusting auxiliary linkers.By precisely tuning 1,4-benzenedicarboxylic acid analogs,a series of isostructural resorcin[4]arene-based metal–organic dimers,namely,[Zn_(4)(TIC_(4)R)_(2)·(L)2·(OH)_(2)]·2HCOO·solvent(1–9)(L=1,4-benzenedicarboxylic acid analogs and TIC4R=tetra(imidazole)resorcin[4]arene),were rationally prepared under solvothermal conditions.Considering the amino groups on the backbone of dimer 2,Pd nanoparticles were prepared to uniformly disperse on the substrate of 2 to give Pd@2.Most importantly,the Pd@2 catalyst was applied for nitroarene hydrogenation with efficient catalytic performance and high selectivity under mild conditions.This work afforded a possible method for precisely controlling the target complex assemblies and their further application.展开更多
基金supported by the Science and Technology Research Planning Project of the Education Department of Jilin Province(Grant No.JJKH20231297KJ)the Open Project Program of the Key Laboratory of Preparation and Application of Environmental Friendly Materials,Ministry of Education,China(No.2020006).
文摘We herein reported a design strategy for the construction of resorcin[4]arene-based metal–organic complexes through adjusting auxiliary linkers.By precisely tuning 1,4-benzenedicarboxylic acid analogs,a series of isostructural resorcin[4]arene-based metal–organic dimers,namely,[Zn_(4)(TIC_(4)R)_(2)·(L)2·(OH)_(2)]·2HCOO·solvent(1–9)(L=1,4-benzenedicarboxylic acid analogs and TIC4R=tetra(imidazole)resorcin[4]arene),were rationally prepared under solvothermal conditions.Considering the amino groups on the backbone of dimer 2,Pd nanoparticles were prepared to uniformly disperse on the substrate of 2 to give Pd@2.Most importantly,the Pd@2 catalyst was applied for nitroarene hydrogenation with efficient catalytic performance and high selectivity under mild conditions.This work afforded a possible method for precisely controlling the target complex assemblies and their further application.
