A pH predictive model based on acid–base equilibria and ion equilibria was proposed to calculate the pH value of the overhead condensing system of crude distillation unit. The pH model could be used to predict the ap...A pH predictive model based on acid–base equilibria and ion equilibria was proposed to calculate the pH value of the overhead condensing system of crude distillation unit. The pH model could be used to predict the appropriate amounts of neutralizers by measuring the Cl-ion concentration of the overhead knockout drum. The pH values of various neutralized streams were estimated by this model. The results showed that the predicted pH values were in good agreement with the experimental ones. The trend of the corrosion inhibition efficiency decreases in the following order: ethylenediamine > N,Ndimethylethanolamine> triethylamine > 3-methoxypropylamine > morpholine. The difficulty in the accurate control of corrosion was solved, and a good instruction was provided for mitigating corrosion in refinery.展开更多
Wet steam condensing flow in low-pressure steam turbine leads to efficiencylosses and blade erosions. In order to investigate this problem by numerical approach, anEulerian/Eulerian model has been developed, in which ...Wet steam condensing flow in low-pressure steam turbine leads to efficiencylosses and blade erosions. In order to investigate this problem by numerical approach, anEulerian/Eulerian model has been developed, in which the wet steam is regarded as mixture comprisingtwo coupled systems: the vapor phase and the liquid phase. These two systems are both described byconservation equations. High resolution TVD scheme is employed to capture condensing phenomena inwet steam flow. This model has been validated by numerical simulations of condensing flows in 1D and2D nozzles. Compared with experimental data, a good agreement is observed. This Eulerian/Eulerianmodel can be extended to 3D calculation of condensing flow.展开更多
In this paper, based on a basic result on condensing mappings satisfying the interior condition, some new fixed point theorems of the condensing mappings of this kind are obtained. As a result, the famous Altman＇s th...In this paper, based on a basic result on condensing mappings satisfying the interior condition, some new fixed point theorems of the condensing mappings of this kind are obtained. As a result, the famous Altman＇s theorem, Roth＇s theorem and Petryshyn＇s theorem are extended to condensing mappings satisfying the interior condition.展开更多
Negative pressure plays a very important role in compact spinning system.To know airflow field and its distribution is helpful to look into the condensing principle of fiber bundle.Therefore,computational fluid dynami...Negative pressure plays a very important role in compact spinning system.To know airflow field and its distribution is helpful to look into the condensing principle of fiber bundle.Therefore,computational fluid dynamics(CFD)software was used to simulate airflow field in this paper.Airflow velocity distributions both in different fiber layers and under different negative pressures were discussed.The results indicate that airflow velocity in upper layer of the fiber bundle is greater than that in lower layer.Airflow velocities in both X and Y axis directions have a positive correlation with negative pressure.It can provide a theoretical base to make high quality compact yarns in productive practice.展开更多
Objective To develop the numerical method for the steady and unsteady wet steam condensing flow in turbine stage. Methods An Eulerian/Eulerian numerical model is used to describe the spontaneous condensation flow in t...Objective To develop the numerical method for the steady and unsteady wet steam condensing flow in turbine stage. Methods An Eulerian/Eulerian numerical model is used to describe the spontaneous condensation flow in the steam turbine. For the steady condensing flow computations, the mixing plane model was used. For the unsteady condensing flow computations, the sliding mesh method was used to simulate the rotor-stator interactions. Results The numerical results showed the obvious differences between non-condensing and condensing flows. The results also showed the unsteadiness effect due to rotor-stator interactions had a deep influence on the formation and growth process of water droplets. Conclusion The numerical methods presented in this paper are valid for the condensing flow in the turbine stage.展开更多
In this article, we introduce the notion of Meir-Keleer condensing operator in a Banach space, a characterization using L-functions and provide a few generalization of Darbo fixed point theorem. Also, we introduce the...In this article, we introduce the notion of Meir-Keleer condensing operator in a Banach space, a characterization using L-functions and provide a few generalization of Darbo fixed point theorem. Also, we introduce the concept of a bivariate Meir-Keleer condensing operator and prove some coupled fixed point theorems. As an application, we prove the existence of solutions for a large class of functional integral equations of Volterra type in two variables.展开更多
AIM: To confirm the rarity of this disorder and then to evaluate the effects of antibiotic treatment alone and assess whether this could produce a complete remission of symptoms in children and adolescents.METHODS: We...AIM: To confirm the rarity of this disorder and then to evaluate the effects of antibiotic treatment alone and assess whether this could produce a complete remission of symptoms in children and adolescents.METHODS: We made a retrospective review of all cases of condensing osteitis of the clavicle in children and adolescents between January 2007 and January 2016. Outpatient and inpatient medical records, with radiographs, magnetic resonance imaging, triphasic bone scan and computed tomography scans were retrospectively reviewed. All the patients underwent biopsy of the affected clavicle and were treated with intra venous(IV) antibiotics followed by oral antibiotics.RESULTS: Seven cases of condensing osteitis of the clavicle were identified. All the patients presented with swelling of the medial end of the clavicle, and 5 out of 7 reported persisting pain. The patients' mean age at presentation was 11.5 years(range 10.5-13). Biopsy confirmed the diagnosis in all cases. All the patients completed the treatment with IV and oral antibiotics. At last follow-up visit none of the patients complained of residual pain; all had a clinically evident reduction in the swelling of the medial end of the affected clavicle. The mean follow-up was 4 years(range 2-7).CONCLUSION: Our findings show that condensing osteitis of the clavicle is a rare condition. Biopsy is needed to confirm diagnosis. The condition should be managed with IV and oral antibiotics. Aggressive surgery should be avoided.展开更多
To a kind of centrifugal water chiller with R22 and about 1 745 kW of cooling capacity,a heat exchanger was added between the outlet of compressor and original condenser to get part of or all the condensing heat.Conde...To a kind of centrifugal water chiller with R22 and about 1 745 kW of cooling capacity,a heat exchanger was added between the outlet of compressor and original condenser to get part of or all the condensing heat.Condensing heat can be recovered by compound condensing method,which adopts air-cooling model +water-cooling model or water-cooling model +water-cooling model at the condensing side of the system.By exergy analysis and experiment research on compound condensing heat recovery of centrifugal chiller,the results are obtained that the capability of the whole system increases,the energy efficiency ratio(EER)becomes 3.2～5.0 from 2.2～3.4,which implies the EER increases about 1.0～1.5,the exergy efficiency increases about 10%,and the chiller runs more stably after reformation.展开更多
First, the notions of the measure of noncompactness and condensing setvalued mappings are introduced in locally FC-uniform spaces without convexity structure. A new existence theorem of maximal elements of a family of...First, the notions of the measure of noncompactness and condensing setvalued mappings are introduced in locally FC-uniform spaces without convexity structure. A new existence theorem of maximal elements of a family of set-valued mappings involving condensing mappings is proved in locally FC-uniform spaces. As applications, some new equilibrium existence theorems of generalized game involving condensing mappings are established in locally FC-uniform spaces. These results improve and generalize some known results in literature to locally FC-uniform spaces. Some further applications of our results to the systems of generalized vector quasi-equilibrium problems will be given in a follow-up paper.展开更多
Air-breathing proton exchange membrane fuel cells(PEMFCs) are very promising portable energy with many advantages. However, its power density is low and many additional supporting parts affect its specific power. In t...Air-breathing proton exchange membrane fuel cells(PEMFCs) are very promising portable energy with many advantages. However, its power density is low and many additional supporting parts affect its specific power. In this paper, we aim to improve the air diffusion and fuel cell performance by employing a novel condensing-tower-like curved flow field rather than an additional fan, making the fuel cell more compact and has less internal power consumption. Polarization curve test and galvanostatic discharge test are carried out and proved that curved flow field can strengthen the air diffusion into the PEMFC and improve its performance. With appropriate curved flow field, the fuel cell peak power can be 55.2%higher than that of planar flow field in our study. A four-layer stack with curved cathode flow field is fabricated and has a peak power of 2.35 W(120 W/kg).展开更多
A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were c...A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were calculated by the mathematical model.The solution content first increases and then decreases along the solution flow direction.At y/Hr=0.98(where Hr is the height of regenerator),air humidity increases from 1.99% to 2.348% firstly and then decreases.The experimental results were used to validate mathematical model.It is indicated that the simulation results agree with experimental data well.The results not only show that the mathematical model can be used to predict the performance of regenerator,but also has great value in the design and improvement of evaporative condensing regenerator.展开更多
The hydrodynamic research about the droplet condensing of the multi phase liquid state on the surface of the coal glass and water discusses the deepening process of convex shape curve and the formation of S shape, and...The hydrodynamic research about the droplet condensing of the multi phase liquid state on the surface of the coal glass and water discusses the deepening process of convex shape curve and the formation of S shape, and puts emphasis on describing the diagram formation method of the later. In the induction period the active diagram of the micro droplet is decided by pH value forming as convex shape diagram or S shape diagram. When pH value is above 4.0, the damage of convex shape diagram cannot be recovered, in that case produce S shape activity diagram. When pH value is equal to or above 12.0, the hard surface with alkali liquid state loses adhesion, so that the micro droplet condensing of the multi phase liquid state stops completely. The research result shows that the water cleaning conditions of getting rid of the oil micro droplets can be decided by the pH value.展开更多
In this paper,we discuss the calculations of fixed point indexs for multivalued condensing mappings and k-set-contraction mappings,obtain some theorems on the eigenvalues and the fixed points under the suitable condit...In this paper,we discuss the calculations of fixed point indexs for multivalued condensing mappings and k-set-contraction mappings,obtain some theorems on the eigenvalues and the fixed points under the suitable conditions. Our conclusions improve and generalize some well-known results.展开更多
Two existence theorems of maximal elements of condensing preference maps in locally convex Hausdorff spaces are proved which generalize the recent results of Mehta. One of them positively answers the open problem ment...Two existence theorems of maximal elements of condensing preference maps in locally convex Hausdorff spaces are proved which generalize the recent results of Mehta. One of them positively answers the open problem mentioned by Mehta.展开更多
The thermodynamic aspect of a compression type heat pump （HP） is briefly described and special attention is given to investigation of condensing temperature influence on heat pump efficiency in heating mode, express...The thermodynamic aspect of a compression type heat pump （HP） is briefly described and special attention is given to investigation of condensing temperature influence on heat pump efficiency in heating mode, expressed by its coefficient of performance （COP）. Heat pumps are usually applied for the purposes of heating and cooling of energy efficient buildings where they have advantages in low-temperature systems, as it is well documented in the paper. The comparison of real thermodynamic processes with thermodynamically most favorable Camot＇s process is made. The results in the paper show that COP is diminishing with increasing of condensing temperature and also depends on real properties of working fluids. The impact of compressor efficiency for two real working media is also analyzed in the paper. There is significant diminishing of COP with diminishing of compressor efficiency. The intension of the paper is to help better understanding of this very effective and prosperous technology, and to encourage its development, production, and efficient application.展开更多
The paper shows a method of designing a heat exchanger recovering heat from the condensation of water vapour contained in flue gases. A heat exchanger condenses water vapour and SO2 （sulphur dioxide） in the presence...The paper shows a method of designing a heat exchanger recovering heat from the condensation of water vapour contained in flue gases. A heat exchanger condenses water vapour and SO2 （sulphur dioxide） in the presence of inert gases （CO2, CO, N2, O2） contained in flue gases. A mathematical model and a sample design of a heat exchanger were presented. The heat exchange is capable of recovering from a dozen or so to several dozen percent of heat from flue gases escaping into the atmosphere. A second advantage of the heat exchanger is the possibility to reduce the emissions of SO2 considerably. Depending on the parameters, it can be even a sevenfold reduction in the emissions. The main mathematical tool used for designing the condensing heat exchanger is the Colburn-Hougen method. The authors omitted that part of the method which requires iterative calculations. The Mollier diagram was used instead.展开更多
Supersolidity is a counterintuitive quantum phase of matter where the long-range spatial order of a solid coexists with the frictionless flow characteristic of a superfluid.Recently,evidence of supersolidity has been ...Supersolidity is a counterintuitive quantum phase of matter where the long-range spatial order of a solid coexists with the frictionless flow characteristic of a superfluid.Recently,evidence of supersolidity has been demonstrated in polariton condensates in III-V photonic crystal microcavities by condensing into a topological bound state in the continuum,offering a new light-matter hybrid platform for exploring such quantum phase.In this work,we propose a theoretical scheme for realizing room-temperature supersolidity based on halide perovskite exciton polaritons operating in the optical parametric oscillation regime.By employing a waveguide microcavity geometry,we confine polariton scattering direction in reciprocal space,enabling controlled momentum selection.Leveraging the intrinsic nonlinear interactions among polaritons,we theoretically demonstrate the spontaneous breaking of both continuous translational symmetry and global phase symmetry,i.e.,the evidence of supersolidity.Furthermore,we identify a tunable phase transition sequence in our system:from a Bose-Einstein condensate to a supersolid phase,and ultimately to an insulating phase,as the nonlinear interaction strength increases.展开更多
(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under...(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4.展开更多
基金supported by the PetroChina Company Limited (20151191)
文摘A pH predictive model based on acid–base equilibria and ion equilibria was proposed to calculate the pH value of the overhead condensing system of crude distillation unit. The pH model could be used to predict the appropriate amounts of neutralizers by measuring the Cl-ion concentration of the overhead knockout drum. The pH values of various neutralized streams were estimated by this model. The results showed that the predicted pH values were in good agreement with the experimental ones. The trend of the corrosion inhibition efficiency decreases in the following order: ethylenediamine > N,Ndimethylethanolamine> triethylamine > 3-methoxypropylamine > morpholine. The difficulty in the accurate control of corrosion was solved, and a good instruction was provided for mitigating corrosion in refinery.
基金This project is supported by National Natural Science Foundation of China (No.50176035)Doctorate Foundation of Xi'an Jiaotong University,China (No.DFXJU2000-18)
文摘Wet steam condensing flow in low-pressure steam turbine leads to efficiencylosses and blade erosions. In order to investigate this problem by numerical approach, anEulerian/Eulerian model has been developed, in which the wet steam is regarded as mixture comprisingtwo coupled systems: the vapor phase and the liquid phase. These two systems are both described byconservation equations. High resolution TVD scheme is employed to capture condensing phenomena inwet steam flow. This model has been validated by numerical simulations of condensing flows in 1D and2D nozzles. Compared with experimental data, a good agreement is observed. This Eulerian/Eulerianmodel can be extended to 3D calculation of condensing flow.
基金Supported in part by the Foundation of Education Ministry, Anhui Province, China (No: KJ2008A028)Educa-tion Ministry, Hubei Province, China (No: D20072202)
文摘In this paper, based on a basic result on condensing mappings satisfying the interior condition, some new fixed point theorems of the condensing mappings of this kind are obtained. As a result, the famous Altman＇s theorem, Roth＇s theorem and Petryshyn＇s theorem are extended to condensing mappings satisfying the interior condition.
基金Key Project in National Science & Technology Pillar Program,China(No.2007BAE41B04)
文摘Negative pressure plays a very important role in compact spinning system.To know airflow field and its distribution is helpful to look into the condensing principle of fiber bundle.Therefore,computational fluid dynamics(CFD)software was used to simulate airflow field in this paper.Airflow velocity distributions both in different fiber layers and under different negative pressures were discussed.The results indicate that airflow velocity in upper layer of the fiber bundle is greater than that in lower layer.Airflow velocities in both X and Y axis directions have a positive correlation with negative pressure.It can provide a theoretical base to make high quality compact yarns in productive practice.
基金This work was supported by the National Natural Science Foundation of China (No50336050)
文摘Objective To develop the numerical method for the steady and unsteady wet steam condensing flow in turbine stage. Methods An Eulerian/Eulerian numerical model is used to describe the spontaneous condensation flow in the steam turbine. For the steady condensing flow computations, the mixing plane model was used. For the unsteady condensing flow computations, the sliding mesh method was used to simulate the rotor-stator interactions. Results The numerical results showed the obvious differences between non-condensing and condensing flows. The results also showed the unsteadiness effect due to rotor-stator interactions had a deep influence on the formation and growth process of water droplets. Conclusion The numerical methods presented in this paper are valid for the condensing flow in the turbine stage.
文摘In this article, we introduce the notion of Meir-Keleer condensing operator in a Banach space, a characterization using L-functions and provide a few generalization of Darbo fixed point theorem. Also, we introduce the concept of a bivariate Meir-Keleer condensing operator and prove some coupled fixed point theorems. As an application, we prove the existence of solutions for a large class of functional integral equations of Volterra type in two variables.
文摘AIM: To confirm the rarity of this disorder and then to evaluate the effects of antibiotic treatment alone and assess whether this could produce a complete remission of symptoms in children and adolescents.METHODS: We made a retrospective review of all cases of condensing osteitis of the clavicle in children and adolescents between January 2007 and January 2016. Outpatient and inpatient medical records, with radiographs, magnetic resonance imaging, triphasic bone scan and computed tomography scans were retrospectively reviewed. All the patients underwent biopsy of the affected clavicle and were treated with intra venous(IV) antibiotics followed by oral antibiotics.RESULTS: Seven cases of condensing osteitis of the clavicle were identified. All the patients presented with swelling of the medial end of the clavicle, and 5 out of 7 reported persisting pain. The patients' mean age at presentation was 11.5 years(range 10.5-13). Biopsy confirmed the diagnosis in all cases. All the patients completed the treatment with IV and oral antibiotics. At last follow-up visit none of the patients complained of residual pain; all had a clinically evident reduction in the swelling of the medial end of the affected clavicle. The mean follow-up was 4 years(range 2-7).CONCLUSION: Our findings show that condensing osteitis of the clavicle is a rare condition. Biopsy is needed to confirm diagnosis. The condition should be managed with IV and oral antibiotics. Aggressive surgery should be avoided.
文摘To a kind of centrifugal water chiller with R22 and about 1 745 kW of cooling capacity,a heat exchanger was added between the outlet of compressor and original condenser to get part of or all the condensing heat.Condensing heat can be recovered by compound condensing method,which adopts air-cooling model +water-cooling model or water-cooling model +water-cooling model at the condensing side of the system.By exergy analysis and experiment research on compound condensing heat recovery of centrifugal chiller,the results are obtained that the capability of the whole system increases,the energy efficiency ratio(EER)becomes 3.2～5.0 from 2.2～3.4,which implies the EER increases about 1.0～1.5,the exergy efficiency increases about 10%,and the chiller runs more stably after reformation.
基金the Natural Science Foundation of Sichuan Education Department of China (Nos.2003A081 and SZD0406)
文摘First, the notions of the measure of noncompactness and condensing setvalued mappings are introduced in locally FC-uniform spaces without convexity structure. A new existence theorem of maximal elements of a family of set-valued mappings involving condensing mappings is proved in locally FC-uniform spaces. As applications, some new equilibrium existence theorems of generalized game involving condensing mappings are established in locally FC-uniform spaces. These results improve and generalize some known results in literature to locally FC-uniform spaces. Some further applications of our results to the systems of generalized vector quasi-equilibrium problems will be given in a follow-up paper.
基金financial support granted by National Key R&D Program of China from Ministry of Science and Technology of China (Nos. 2020YFB1505700, 2016YFA0200700)China Postdoctoral Science Foundation (No. 2021M702408)+4 种基金the National Natural Science Foundation of China (No. 22172191)Dongyue Polymer Material Company of Dongyue FederationState Key Laboratory of Fluorinated Functional Membrane Materials(Dongyue Group institute)Dongyue Future Hydrogen Energy Materials Companysponsored by the Collaborative Innovation Center of Suzhou Nano Science and Technology。
文摘Air-breathing proton exchange membrane fuel cells(PEMFCs) are very promising portable energy with many advantages. However, its power density is low and many additional supporting parts affect its specific power. In this paper, we aim to improve the air diffusion and fuel cell performance by employing a novel condensing-tower-like curved flow field rather than an additional fan, making the fuel cell more compact and has less internal power consumption. Polarization curve test and galvanostatic discharge test are carried out and proved that curved flow field can strengthen the air diffusion into the PEMFC and improve its performance. With appropriate curved flow field, the fuel cell peak power can be 55.2%higher than that of planar flow field in our study. A four-layer stack with curved cathode flow field is fabricated and has a peak power of 2.35 W(120 W/kg).
基金Project(PHR201007127) supported by Academic Human Resources Development Fund of Institutions of Higher Learning under the Jurisdiction of Beijing Municipality, China Project(bsbe2010-05) supported by the Opening Funds of State Key Laboratory of Building Safety and Built Environment, China Project supported by the Doctoral Startup Foundation of Beijing University of Civil Engineering and Architecture, China
文摘A two-dimensional steady state model was developed and solved numerically to predict the performance of evaporative condensing regenerator.Two-dimensional parameter distributions of air,solution and refrigerant were calculated by the mathematical model.The solution content first increases and then decreases along the solution flow direction.At y/Hr=0.98(where Hr is the height of regenerator),air humidity increases from 1.99% to 2.348% firstly and then decreases.The experimental results were used to validate mathematical model.It is indicated that the simulation results agree with experimental data well.The results not only show that the mathematical model can be used to predict the performance of regenerator,but also has great value in the design and improvement of evaporative condensing regenerator.
文摘The hydrodynamic research about the droplet condensing of the multi phase liquid state on the surface of the coal glass and water discusses the deepening process of convex shape curve and the formation of S shape, and puts emphasis on describing the diagram formation method of the later. In the induction period the active diagram of the micro droplet is decided by pH value forming as convex shape diagram or S shape diagram. When pH value is above 4.0, the damage of convex shape diagram cannot be recovered, in that case produce S shape activity diagram. When pH value is equal to or above 12.0, the hard surface with alkali liquid state loses adhesion, so that the micro droplet condensing of the multi phase liquid state stops completely. The research result shows that the water cleaning conditions of getting rid of the oil micro droplets can be decided by the pH value.
文摘In this paper,we discuss the calculations of fixed point indexs for multivalued condensing mappings and k-set-contraction mappings,obtain some theorems on the eigenvalues and the fixed points under the suitable conditions. Our conclusions improve and generalize some well-known results.
基金Project Supported by the National Natural Science Foundation of China
文摘Two existence theorems of maximal elements of condensing preference maps in locally convex Hausdorff spaces are proved which generalize the recent results of Mehta. One of them positively answers the open problem mentioned by Mehta.
文摘The thermodynamic aspect of a compression type heat pump （HP） is briefly described and special attention is given to investigation of condensing temperature influence on heat pump efficiency in heating mode, expressed by its coefficient of performance （COP）. Heat pumps are usually applied for the purposes of heating and cooling of energy efficient buildings where they have advantages in low-temperature systems, as it is well documented in the paper. The comparison of real thermodynamic processes with thermodynamically most favorable Camot＇s process is made. The results in the paper show that COP is diminishing with increasing of condensing temperature and also depends on real properties of working fluids. The impact of compressor efficiency for two real working media is also analyzed in the paper. There is significant diminishing of COP with diminishing of compressor efficiency. The intension of the paper is to help better understanding of this very effective and prosperous technology, and to encourage its development, production, and efficient application.
文摘The paper shows a method of designing a heat exchanger recovering heat from the condensation of water vapour contained in flue gases. A heat exchanger condenses water vapour and SO2 （sulphur dioxide） in the presence of inert gases （CO2, CO, N2, O2） contained in flue gases. A mathematical model and a sample design of a heat exchanger were presented. The heat exchange is capable of recovering from a dozen or so to several dozen percent of heat from flue gases escaping into the atmosphere. A second advantage of the heat exchanger is the possibility to reduce the emissions of SO2 considerably. Depending on the parameters, it can be even a sevenfold reduction in the emissions. The main mathematical tool used for designing the condensing heat exchanger is the Colburn-Hougen method. The authors omitted that part of the method which requires iterative calculations. The Mollier diagram was used instead.
基金supported by the National Natural Science Foundation of China(Grant No.12434011 obtained by Q X)the China Postdoctoral Science Foundation(Grant No.Y24PJ2425214 obtained by L T).
文摘Supersolidity is a counterintuitive quantum phase of matter where the long-range spatial order of a solid coexists with the frictionless flow characteristic of a superfluid.Recently,evidence of supersolidity has been demonstrated in polariton condensates in III-V photonic crystal microcavities by condensing into a topological bound state in the continuum,offering a new light-matter hybrid platform for exploring such quantum phase.In this work,we propose a theoretical scheme for realizing room-temperature supersolidity based on halide perovskite exciton polaritons operating in the optical parametric oscillation regime.By employing a waveguide microcavity geometry,we confine polariton scattering direction in reciprocal space,enabling controlled momentum selection.Leveraging the intrinsic nonlinear interactions among polaritons,we theoretically demonstrate the spontaneous breaking of both continuous translational symmetry and global phase symmetry,i.e.,the evidence of supersolidity.Furthermore,we identify a tunable phase transition sequence in our system:from a Bose-Einstein condensate to a supersolid phase,and ultimately to an insulating phase,as the nonlinear interaction strength increases.
文摘(2E,6E)-4-methyl-2,6-bis(pyridin-3-ylmethylene)cyclohexan-1-one(L_(1))and 4-methyl-2,6-bis[(E)-4-(pyridin-4-yl)benzylidene]cyclohexan-1-one(L_(2))were synthesized and combined with isophthalic acid(H_(2)IP),then under solvothermal conditions,to react with transition metals achieving four novel metal-organic frameworks(MOFs):[Zn(IP)(L_(1))]_(n)(1),{[Cd(IP)(L_(1))]·H_(2)O}_(n)(2),{[Co(IP)(L_(1))]·H_(2)O}_(n)(3),and[Zn(IP)(L_(2))(H_(2)O)]_(n)(4).MOFs 1-4 have been characterized by single-crystal X-ray diffraction,powder X-ray diffraction,thermogravimetry,and elemental analysis.Single-crystal X-ray diffraction shows that MOF 1 crystallizes in the monoclinic crystal system with space group P2_(1)/n,and MOFs 2-4 belong to the triclinic system with the P1 space group.1-3 are 2D sheet structures,2 and 3 have similar structural characters,whereas 4 is a 1D chain structure.Furthermore,1-3 exhibited certain photocatalytic capability in the degradation of rhodamine B(Rh B)and pararosaniline hydrochloride(PH).4could be used as a heterogeneous catalyst for the Knoevenagel reaction starting with benzaldehyde derivative and malononitrile.4 could promote the reaction to achieve corresponding products in moderate yields within 3 h.Moreover,the catalyst exhibited recyclability for up to three cycles without significantly dropping its activity.A mechanism for MOF 4 catalyzed Knoevenagel condensation reaction of aromatic aldehyde and malononitrile has been initially proposed.CCDC:2356488,1;2356497,2;2356499,3;2356498,4.
