A novel online process monitoring and fault diagnosis method of condenser based on kernel principle component analysis （KPCA） and Fisher discriminant analysis （FDA） is presented. The basic idea of this method is：...A novel online process monitoring and fault diagnosis method of condenser based on kernel principle component analysis （KPCA） and Fisher discriminant analysis （FDA） is presented. The basic idea of this method is： First map data from the original space into high-dimensional feature space via nonlinear kernel function and then extract optimal feature vector and discriminant vector in feature space and calculate the Euclidean distance between feature vectors to perform process monitoring. Similar degree between the present discriminant vector and optimal discriminant vector of fault in historical dataset is used for diagnosis. The proposed method can effectively capture the nonlinear relationship among process variables. Simulating results of the turbo generator＇s fault data set prove that the proposed method is effective.展开更多
In order to increase cooling or heating efficiency,a porous computational fluid dynamics（CFD）model is employed to predict the thermo-fluid status and optimize the placement of outdoor units.A full scale model is est...In order to increase cooling or heating efficiency,a porous computational fluid dynamics（CFD）model is employed to predict the thermo-fluid status and optimize the placement of outdoor units.A full scale model is established to validate the accuracy of CFD simulation in terms of velocity and temperature distributions.The comparison between the measurement and the simulation shows a good agreement.By evaluating the condensers＇ sucked air temperature with CFD for three units installed in a row,it is found that the minimum separation distance among neighboring units is 0.2 m;a vertical wall should be apart from the unit line by at least 0.8 m;and large different operating pressures among units do not impact the flow rate and the heat transfer of the other units meaningfully.展开更多
This paper introduces the development and industrial application of an on-line corrosion monitoring device for condenser tubes. Corrosion sensors are made up of representative condenser tubes chosen by eddy current te...This paper introduces the development and industrial application of an on-line corrosion monitoring device for condenser tubes. Corrosion sensors are made up of representative condenser tubes chosen by eddy current test, which enable the monitoring result to be consistent with the corrosion of actual condenser tubes. Localized corrosion rate of condenser tubes can be measured indirectly by a galvanic couple made up of tube segments with and without pits. Using this technology, corrosion problems can be found in time and accurately, and anticorrosive measures be made more economic and effective. Applications in two power plants showed the corrosion measurements are fast and accurate.展开更多
A new technique to fabricate silicon condenser microphone is presented.The technique is based on the use of oxidized porous silicon as sacrificial layer for the air gap and the heavy p+-doping silicon of approximately...A new technique to fabricate silicon condenser microphone is presented.The technique is based on the use of oxidized porous silicon as sacrificial layer for the air gap and the heavy p+-doping silicon of approximately 15μm thickness for the stiff backplate.The measured sensitivity of the microphone fabricated with this technique is in the range from -45dB(5.6mV/Pa) to -55dB(1.78mV/Pa) under the frequency from 500Hz to 10kHz,and shows a gradual increase at higher frequency.The cut-off frequency is above 20kHz.展开更多
In frequent tree pattern mining, the number of frequent subtrees generated is often too large. To tackle this problem, the concept of condensed frequent subtree base is proposed. The base consists of the maximal frequ...In frequent tree pattern mining, the number of frequent subtrees generated is often too large. To tackle this problem, the concept of condensed frequent subtree base is proposed. The base consists of the maximal frequent subtrees for a series of support thresholds. It is a subset of frequent subtrees, and is used to approximate the support of arbitrary frequent subtrees with guaranteed maximal error bound. In addition, an algorithm is developed to mine such a condensed subtree base in a database of labeled rooted ordered trees. The algorithm adopts the way of fight-most extension to generate systematically all frequent rooted ordered subtrees. Several techniques are proposed to prune the branches that do not correspond to the maximal frequent subtrees. Heuristic techniques are used to arrange the order of computation so that relatively expensive computation is avoided as much as possible. Experimental results show that the size of the base is less than 10% of that of the complete set, and the algorithm outperforms the previous algorithms.展开更多
On the basis of the two geological factors rock structure and ground stress environment,a visco elastic plastic model is established to analyze the rock stability of dam foundation and dam abutment during excavation...On the basis of the two geological factors rock structure and ground stress environment,a visco elastic plastic model is established to analyze the rock stability of dam foundation and dam abutment during excavation by a kind of FE condensed method.Rock mechanics is applied in analysing the dynamic process of displacements,stresses,yielding destruction of construction base level,soft interface of dam foundation.Results of the FE analysis indicate that theories and methods in this paper are reasonable and reliable.展开更多
Sodium pyrophosphate （pyro-P, Na4P2OT）, sodium tripolyphosphate （tripoly-P, Na3P3O10）, and sodium hexametaphosphate （meta-P, （NaPO3）6） were selected as the model compounds of condensed phosphate to investigate...Sodium pyrophosphate （pyro-P, Na4P2OT）, sodium tripolyphosphate （tripoly-P, Na3P3O10）, and sodium hexametaphosphate （meta-P, （NaPO3）6） were selected as the model compounds of condensed phosphate to investigate the adsorption behavior of condensed phosphate on aluminum hydroxide. The adsorption was found to be endothermic and divisible into two stages： （1） fast adsorption within 1 h; and （2） slow adsorption between 1 and 24 h. The modified Freundlich model simulated the fast adsorption stage well; the slow adsorption stage was described well by the first-order kinetics. The activation energies of pyro-P, tripoly-P, and meta-P adsorption on aluminum hydroxide were determined to be 20.2, 22.8 and 10.9 kJ/mol P adsorbed, respectively, in the fast adsorption stage and to be 66.3, 53.5 and 72.5 kJ/mol P adsorbed, respectively, in the slow adsorption stage. The adsorption increased the negative charge of the aluminum hydroxide surface. Transmission electron microscopy and energy dispersive X-ray analysis analyses provided evidence that the adsorption was not uniform on the surface and that the small crystals contributed more to the fast adsorption than the normal sites did. The results from X-ray fluorescence spectrometry and X-ray photoelectron spectroscopy tests also revealed the uneven adsorption of condensed phosphate as a function of the penetration depth. More condensed phosphates were adsorbed on the outer surface of aluminum hydroxide than in its inner parts.展开更多
The static flux chamber method was applied to study natural emissions of methane to the atmosphere in the Luntai fault region of Yakela Condensed Oil/Gas Field in the Tarim Basin, Xinjiang Municipality, northwestern C...The static flux chamber method was applied to study natural emissions of methane to the atmosphere in the Luntai fault region of Yakela Condensed Oil/Gas Field in the Tarim Basin, Xinjiang Municipality, northwestern China. Using an online method, which couples together a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry （GC/C/MS）, 13^C/12^C ratios of methane in flux chambers were measured and showed that methane gases are liable to migrate from deep oil/gas reservoirs to the surface through fault regions and that a part of the migrated methane, which remains unoxidized can be emitted into the atmosphere. Methane emission rates were found to be highest in the mornings, lowest in the afternoons and then increase gradually in the evenings. Methane emission rates varied dramatically in different locations in the fault region. The highest methane emission rate was 10.96 mg/m^2·d, the lowest 4.38 mg/m^2, and the average 7.55 mg/ m^2·d. The 13^C/12^C ratios of the methane in the flux chambers became heavier as the enclosed methane concentrations increased gradually, which reveals that methane released from the fault region might come from thermogenic methane of the deep condensed oil/gas reservoir.展开更多
A static flux chamber method was applied to study natural emissions of methane into the atmosphere in the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China. Using an online method, which couples a gas ch...A static flux chamber method was applied to study natural emissions of methane into the atmosphere in the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China. Using an online method, which couples a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry (GC/C/MS) together, the 13C/12C ratios of methane in the flux chambers were measured. The results demonstrated that methane gases were liable to migrate from deep oil/gas reservoir to the surface through microseepage and p...展开更多
A new type of Galerkin finite element for first-order initial-value problems(IVPs)is proposed.Both the trial and test functions employ the same m-degreed polynomials.The adjoint equation is used to eliminate one degre...A new type of Galerkin finite element for first-order initial-value problems(IVPs)is proposed.Both the trial and test functions employ the same m-degreed polynomials.The adjoint equation is used to eliminate one degree of freedom(DOF)from the test function,and then the so-called condensed test function and its consequent condensed Galerkin element are constructed.It is mathematically proved and numerically verified that the condensed element produces the super-convergent nodal solutions of O(h^(2m+2)),which is equivalent to the order of accuracy by the conventional element of degree m+1.Some related properties are addressed,and typical numerical examples of both linear and nonlinear IVPs of both a single equation and a system of equations are presented to show the validity and effectiveness of the proposed element.展开更多
As a kind of low-cost and readily available industrial byproduct, ethylene tar （ET） was for the first time utilized for the preparation of heat-resistant condensed polynuclear aromatic resin （COPNAR）. The basic pr...As a kind of low-cost and readily available industrial byproduct, ethylene tar （ET） was for the first time utilized for the preparation of heat-resistant condensed polynuclear aromatic resin （COPNAR）. The basic properties of ET and the resulted COPNAR were characterized by FT-IR, IH-NMR, TGA and elemental analysis. The test results showed that ET with high aromatic content （〉50%） was suitable for the synthesis of COPNAR with superior heat resistance. The average molecular structure of ET was obtained by means of the improved Brown-Ladner method, and the reaction mechanism was considered as an acid-catalyzed positive ion-typed polymerization. Our findings have provided a new route to develop ET into technology-added heat-resistant resins.展开更多
Aluminum(Al) particles are commonly added to energetic materials including propellants,explosives and pyrotechnics to increase the overall energy density of the composite,but aluminum agglomeration on the combustion s...Aluminum(Al) particles are commonly added to energetic materials including propellants,explosives and pyrotechnics to increase the overall energy density of the composite,but aluminum agglomeration on the combustion surface may lower the combustion efficiency of propellants,resulting in a loss in twophase flow.Therefore,it is necessary to understand the agglomeration mechanism of aluminum particles on the combustion surface.In this paper,a high-pressure sealed combustion chamber is constructed,and high-speed camera is used to capture the whole process of aluminum accumulation,aggregation and agglomeration on the combustion surface,and the secondary agglomeration process near the combustion surface.The microscopic morphology and chemical composition of the condensed combustion products(CCPs) are then studied by using scanning electron microscopy coupled with energy dispersive(SEM-EDS) method.Results show that there are three main types of condensed combustion products:small smoke oxide particles oxidized by aluminum vapor,usually less than 1 μm;typical agglomerates formed by the combustion of aluminum agglomerates;carbonized agglomerates that are widely distributed,usually formed by irregular movements of aluminum agglomerates.The particle size of condensed combustion products is measured by laser particle size meter.As the pressure increases from 0.5 MPa to 1.0 MPa in nitrogen,the mass average particle size of aluminum agglomerates decreases by 49.7%.As the ambient gas is changed from 0.5 MPa nitrogen to 0.5 MPa air,the mass average particle size of aluminum agglomerates decreases by 67.3%.Results show that as the ambient pressure increases,the higher oxygen content can improve combustion efficiency and reduce the average agglomeration size of aluminum particles.展开更多
This paper presented an entropy evaluation method for the influences of condense heat recovery system on the environment.Aiming at the damage of the condense heat to the environment,an entropy of resource loss and an ...This paper presented an entropy evaluation method for the influences of condense heat recovery system on the environment.Aiming at the damage of the condense heat to the environment,an entropy of resource loss and an emission entropy from the condense heat recovery system in the air conditioning refrigerating machine were introduced.For the evaluation of the entropies,we developed a new algorithm for the parameter identification,called the composite influence coefficient,based on the Least Squares Support Vector Machine method.By simulation,the numerical experiments shows that the Least Squares Support Vector Machine method is one of the powerful methods for the parameter identification to compute the damage entropy of the condense heat,with the largest training error being-0.025(the relative error being-3.56%),and the biggest test error being 0.015(the relative error being 2.5%).展开更多
A statistical signal processing technique was proposed and verified as independent component analysis(ICA) for fault detection and diagnosis of industrial systems without exact and detailed model.Actually,the aim is t...A statistical signal processing technique was proposed and verified as independent component analysis(ICA) for fault detection and diagnosis of industrial systems without exact and detailed model.Actually,the aim is to utilize system as a black box.The system studied is condenser system of one of MAPNA's power plants.At first,principal component analysis(PCA) approach was applied to reduce the dimensionality of the real acquired data set and to identify the essential and useful ones.Then,the fault sources were diagnosed by ICA technique.The results show that ICA approach is valid and effective for faults detection and diagnosis even in noisy states,and it can distinguish main factors of abnormality among many diverse parts of a power plant's condenser system.This selectivity problem is left unsolved in many plants,because the main factors often become unnoticed by fault expansion through other parts of the plants.展开更多
In this paper,a detailed investigation of water(Pr=7.0)convection in a chemical condenser is carried out.Two openings are located along one side of the cavity.The Navier-Stokes equations are solved in the frame of a c...In this paper,a detailed investigation of water(Pr=7.0)convection in a chemical condenser is carried out.Two openings are located along one side of the cavity.The Navier-Stokes equations are solved in the frame of a control volume method using the SIMPLEC algorithm to implement adequate coupling of pressure and velocity.Special emphasis is given to the influence of the Reynolds number,the tilt of the channel and the Rayleigh number on the convective heat transfer.Results are presented and discussed allowing the control parameters to span relatively wide intervals:Rayleigh number(10^(4)≤Ra≤5×10^(5)),channel inclination(0°≤90°)and Reynolds number(10≤Re≤1000).On the basis of these results,a new correlation of the Nusselt number is elaborated.展开更多
Lead has caused serious environmental pollution due to its toxicity, accumulation in food chains and persistence in nature. In this paper, removal of lead from aqueous solutions is investigated using a novel gel adsor...Lead has caused serious environmental pollution due to its toxicity, accumulation in food chains and persistence in nature. In this paper, removal of lead from aqueous solutions is investigated using a novel gel adsorbent synthesized from natural condensed tannin. The novel adsorbent performs in aqueous solutions as a weak base with valid basic groups of 1.2mmol·g-1 tannin gel particles and therefore results in the elevation of pH value of aqueous solutions. Even when initial pH is 3.6, final pH at equilibrium can climb up to 6.5 that is above the pH value for Pb(OH)2 precipitation formation and then lead can be removed from wastewater by this so-called surface precipitation. The adsorption isotherm can be expressed by the Langmuir equation and the maximum capacity for adsorption of Pb is up to 92 mg·g-1 (based on dry adsorbent) when initial pH value is 3.6. Hence, the adsorbent does offer favorable properties in lead removal with respect to its high adsorption capacity at low initial pH value, which is advantageous to lead removal from acidic wastewater. A model is put forward to describe the individual adsorption phenomenon of the tannin gel adsorbent.展开更多
Single crystals of LaP3O9·3H2O were prepared using a classical method of aqueous chemistry whereas those of the ultraphosphate LaP5O14 were obtained by flux method.Thermal treatment of LaP3O9·3H2O up to 700 ...Single crystals of LaP3O9·3H2O were prepared using a classical method of aqueous chemistry whereas those of the ultraphosphate LaP5O14 were obtained by flux method.Thermal treatment of LaP3O9·3H2O up to 700 °C allowed us to obtain the lanthanum polyphosphate La(PO3)3.The conductivity as well as the vibrational study of the lanthanum ultraphosphate and polyphosphate were analysed in order to explain the mechanism of conduction.Activation energies of 0.45 and 0.84 eV,deduced from the Arrhenius relation,were r...展开更多
This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'g...This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'geometric linearity on their photocatalytic properties.Herein,the Mg O film,obtained by plasma electrolysis of AZ31 Mg alloys,was modified by growing an LDH film,which was further functionalized using cyclic sodium hexametaphosphate(CP)and linear sodium tripolyphosphate(LP).CP acted as an enhancer for flake spacing within the LDH structure,while LP changed flake dispersion and orientation.Consequently,CP@LDH demonstrated exceptional efficiency in heterogeneous photocatalysis,effectively degrading organic dyes like Methylene blue(MB),Congo red(CR),and Methyl orange(MO).The unique cyclic structure of CP likely enhances surface reactions and improves the catalyst's interaction with dye molecules.Furthermore,the condensed phosphate structure contributes to a higher surface area and reactivity in CP@LDH,leading to its superior photocatalytic performance compared to LP@LDH.Specifically,LP@LDH demonstrated notable degradation efficiencies of 93.02%,92.89%,and 88.81%for MB,MO,and CR respectively,over a 40 min duration.The highest degradation efficiencies were observed in the case of the CP@LDH sample,reporting 99.99%for MB,98.88%for CR,and 99.70%for MO.This underscores the potential of CP@LDH as a highly effective photocatalyst for organic dye degradation,offering promising prospects for environmental remediation and water detoxification applications.展开更多
In order to improve the thermal stability of condensed polynuclear aromatic(COPNA) resin synthesized from vacuum residue, 1,4-benzenedimethanol was added to cure COPNA resin. The curing mechanism was investigated by p...In order to improve the thermal stability of condensed polynuclear aromatic(COPNA) resin synthesized from vacuum residue, 1,4-benzenedimethanol was added to cure COPNA resin. The curing mechanism was investigated by proton nuclear magnetic resonance spectrometry, solid carbon-13 nuclear magnetic resonance spectrometry and Fourier transform infrared spectroscopy. Microstructures of the uncured and the cured COPNA resins were studied by scanning electron microscopy and X-ray diffractometry. The thermal stability of COPNA resins before and after curing was tested by thermogravimetric analysis. The element composition of the cured COPNA resin heated at different temperatures was analyzed by an element analyzer. The results showed that the uncured COPNA resin reacted with the cross-linking agent during the curing process, and the curing mechanism was confirmed to be the electrophilic substitution reaction. Compared with the uncured COPNA resin, the cured COPNA resin had a smooth surface, well-ordered and streamlined sheet structure with more crystalline solids, better molecular arrangement and orientation. The weight loss process of the uncured and cured COPNA resins was divided into three stages. Carbon residue of the cured COPNA resin was 41.65% at 600 ℃, which was much higher than 25.02% of the uncured COPNA resin, which indicated that the cured COPNA resin had higher thermal stability.展开更多
基金The National Natural Science Foundation of China(No60504033)
文摘A novel online process monitoring and fault diagnosis method of condenser based on kernel principle component analysis （KPCA） and Fisher discriminant analysis （FDA） is presented. The basic idea of this method is： First map data from the original space into high-dimensional feature space via nonlinear kernel function and then extract optimal feature vector and discriminant vector in feature space and calculate the Euclidean distance between feature vectors to perform process monitoring. Similar degree between the present discriminant vector and optimal discriminant vector of fault in historical dataset is used for diagnosis. The proposed method can effectively capture the nonlinear relationship among process variables. Simulating results of the turbo generator＇s fault data set prove that the proposed method is effective.
文摘In order to increase cooling or heating efficiency,a porous computational fluid dynamics（CFD）model is employed to predict the thermo-fluid status and optimize the placement of outdoor units.A full scale model is established to validate the accuracy of CFD simulation in terms of velocity and temperature distributions.The comparison between the measurement and the simulation shows a good agreement.By evaluating the condensers＇ sucked air temperature with CFD for three units installed in a row,it is found that the minimum separation distance among neighboring units is 0.2 m;a vertical wall should be apart from the unit line by at least 0.8 m;and large different operating pressures among units do not impact the flow rate and the heat transfer of the other units meaningfully.
文摘This paper introduces the development and industrial application of an on-line corrosion monitoring device for condenser tubes. Corrosion sensors are made up of representative condenser tubes chosen by eddy current test, which enable the monitoring result to be consistent with the corrosion of actual condenser tubes. Localized corrosion rate of condenser tubes can be measured indirectly by a galvanic couple made up of tube segments with and without pits. Using this technology, corrosion problems can be found in time and accurately, and anticorrosive measures be made more economic and effective. Applications in two power plants showed the corrosion measurements are fast and accurate.
文摘A new technique to fabricate silicon condenser microphone is presented.The technique is based on the use of oxidized porous silicon as sacrificial layer for the air gap and the heavy p+-doping silicon of approximately 15μm thickness for the stiff backplate.The measured sensitivity of the microphone fabricated with this technique is in the range from -45dB(5.6mV/Pa) to -55dB(1.78mV/Pa) under the frequency from 500Hz to 10kHz,and shows a gradual increase at higher frequency.The cut-off frequency is above 20kHz.
文摘In frequent tree pattern mining, the number of frequent subtrees generated is often too large. To tackle this problem, the concept of condensed frequent subtree base is proposed. The base consists of the maximal frequent subtrees for a series of support thresholds. It is a subset of frequent subtrees, and is used to approximate the support of arbitrary frequent subtrees with guaranteed maximal error bound. In addition, an algorithm is developed to mine such a condensed subtree base in a database of labeled rooted ordered trees. The algorithm adopts the way of fight-most extension to generate systematically all frequent rooted ordered subtrees. Several techniques are proposed to prune the branches that do not correspond to the maximal frequent subtrees. Heuristic techniques are used to arrange the order of computation so that relatively expensive computation is avoided as much as possible. Experimental results show that the size of the base is less than 10% of that of the complete set, and the algorithm outperforms the previous algorithms.
文摘On the basis of the two geological factors rock structure and ground stress environment,a visco elastic plastic model is established to analyze the rock stability of dam foundation and dam abutment during excavation by a kind of FE condensed method.Rock mechanics is applied in analysing the dynamic process of displacements,stresses,yielding destruction of construction base level,soft interface of dam foundation.Results of the FE analysis indicate that theories and methods in this paper are reasonable and reliable.
文摘Sodium pyrophosphate （pyro-P, Na4P2OT）, sodium tripolyphosphate （tripoly-P, Na3P3O10）, and sodium hexametaphosphate （meta-P, （NaPO3）6） were selected as the model compounds of condensed phosphate to investigate the adsorption behavior of condensed phosphate on aluminum hydroxide. The adsorption was found to be endothermic and divisible into two stages： （1） fast adsorption within 1 h; and （2） slow adsorption between 1 and 24 h. The modified Freundlich model simulated the fast adsorption stage well; the slow adsorption stage was described well by the first-order kinetics. The activation energies of pyro-P, tripoly-P, and meta-P adsorption on aluminum hydroxide were determined to be 20.2, 22.8 and 10.9 kJ/mol P adsorbed, respectively, in the fast adsorption stage and to be 66.3, 53.5 and 72.5 kJ/mol P adsorbed, respectively, in the slow adsorption stage. The adsorption increased the negative charge of the aluminum hydroxide surface. Transmission electron microscopy and energy dispersive X-ray analysis analyses provided evidence that the adsorption was not uniform on the surface and that the small crystals contributed more to the fast adsorption than the normal sites did. The results from X-ray fluorescence spectrometry and X-ray photoelectron spectroscopy tests also revealed the uneven adsorption of condensed phosphate as a function of the penetration depth. More condensed phosphates were adsorbed on the outer surface of aluminum hydroxide than in its inner parts.
基金This study was supported by the Natural Science Foundation of China （grant No. 40273034）the Science Foundation of Hongzhou Danzi University.
文摘The static flux chamber method was applied to study natural emissions of methane to the atmosphere in the Luntai fault region of Yakela Condensed Oil/Gas Field in the Tarim Basin, Xinjiang Municipality, northwestern China. Using an online method, which couples together a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry （GC/C/MS）, 13^C/12^C ratios of methane in flux chambers were measured and showed that methane gases are liable to migrate from deep oil/gas reservoirs to the surface through fault regions and that a part of the migrated methane, which remains unoxidized can be emitted into the atmosphere. Methane emission rates were found to be highest in the mornings, lowest in the afternoons and then increase gradually in the evenings. Methane emission rates varied dramatically in different locations in the fault region. The highest methane emission rate was 10.96 mg/m^2·d, the lowest 4.38 mg/m^2, and the average 7.55 mg/ m^2·d. The 13^C/12^C ratios of the methane in the flux chambers became heavier as the enclosed methane concentrations increased gradually, which reveals that methane released from the fault region might come from thermogenic methane of the deep condensed oil/gas reservoir.
基金the National Natural Sci-ence Foundation of China (No. 40273034)the Science Foundation of Hangzhou Dianzi University
文摘A static flux chamber method was applied to study natural emissions of methane into the atmosphere in the Yakela condensed oil/gas field in Talimu Basin, Xinjiang, China. Using an online method, which couples a gas chromatography/high-temperature conversion/isotope ratio mass spectrometry (GC/C/MS) together, the 13C/12C ratios of methane in the flux chambers were measured. The results demonstrated that methane gases were liable to migrate from deep oil/gas reservoir to the surface through microseepage and p...
基金Project supported by the National Natural Science Foundation of China(Nos.51878383 and51378293)。
文摘A new type of Galerkin finite element for first-order initial-value problems(IVPs)is proposed.Both the trial and test functions employ the same m-degreed polynomials.The adjoint equation is used to eliminate one degree of freedom(DOF)from the test function,and then the so-called condensed test function and its consequent condensed Galerkin element are constructed.It is mathematically proved and numerically verified that the condensed element produces the super-convergent nodal solutions of O(h^(2m+2)),which is equivalent to the order of accuracy by the conventional element of degree m+1.Some related properties are addressed,and typical numerical examples of both linear and nonlinear IVPs of both a single equation and a system of equations are presented to show the validity and effectiveness of the proposed element.
基金supported by the Program for New Century Excellent Talents in University, China Ministry of Education, 2009 (No. NCET-10-0768)the National Natural Science Foundation of China (Nos. 20876176 and 51172285)the Natural Science Foundation of Shandong Province (ZR2011EL031, ZR2011EL030)
文摘As a kind of low-cost and readily available industrial byproduct, ethylene tar （ET） was for the first time utilized for the preparation of heat-resistant condensed polynuclear aromatic resin （COPNAR）. The basic properties of ET and the resulted COPNAR were characterized by FT-IR, IH-NMR, TGA and elemental analysis. The test results showed that ET with high aromatic content （〉50%） was suitable for the synthesis of COPNAR with superior heat resistance. The average molecular structure of ET was obtained by means of the improved Brown-Ladner method, and the reaction mechanism was considered as an acid-catalyzed positive ion-typed polymerization. Our findings have provided a new route to develop ET into technology-added heat-resistant resins.
基金supported by the National Natural Science Foundation of China (Grant No.52006099)the Fundamental Research Funds of the Central Universities (Grant No.30920021102,No.309181B8812)the Six Talent Peaks Project of Jiangsu Province of China (Grant No.2016-HKHT-017)。
文摘Aluminum(Al) particles are commonly added to energetic materials including propellants,explosives and pyrotechnics to increase the overall energy density of the composite,but aluminum agglomeration on the combustion surface may lower the combustion efficiency of propellants,resulting in a loss in twophase flow.Therefore,it is necessary to understand the agglomeration mechanism of aluminum particles on the combustion surface.In this paper,a high-pressure sealed combustion chamber is constructed,and high-speed camera is used to capture the whole process of aluminum accumulation,aggregation and agglomeration on the combustion surface,and the secondary agglomeration process near the combustion surface.The microscopic morphology and chemical composition of the condensed combustion products(CCPs) are then studied by using scanning electron microscopy coupled with energy dispersive(SEM-EDS) method.Results show that there are three main types of condensed combustion products:small smoke oxide particles oxidized by aluminum vapor,usually less than 1 μm;typical agglomerates formed by the combustion of aluminum agglomerates;carbonized agglomerates that are widely distributed,usually formed by irregular movements of aluminum agglomerates.The particle size of condensed combustion products is measured by laser particle size meter.As the pressure increases from 0.5 MPa to 1.0 MPa in nitrogen,the mass average particle size of aluminum agglomerates decreases by 49.7%.As the ambient gas is changed from 0.5 MPa nitrogen to 0.5 MPa air,the mass average particle size of aluminum agglomerates decreases by 67.3%.Results show that as the ambient pressure increases,the higher oxygen content can improve combustion efficiency and reduce the average agglomeration size of aluminum particles.
基金Supported by Program of Science and Technology of Hunan Province(2007FJ2006)Project the Program of Science and Tech-nology of Hunan Province(2007TP4030)Hunan Provincial Natural Science Foundation of China(08JJ3093)
文摘This paper presented an entropy evaluation method for the influences of condense heat recovery system on the environment.Aiming at the damage of the condense heat to the environment,an entropy of resource loss and an emission entropy from the condense heat recovery system in the air conditioning refrigerating machine were introduced.For the evaluation of the entropies,we developed a new algorithm for the parameter identification,called the composite influence coefficient,based on the Least Squares Support Vector Machine method.By simulation,the numerical experiments shows that the Least Squares Support Vector Machine method is one of the powerful methods for the parameter identification to compute the damage entropy of the condense heat,with the largest training error being-0.025(the relative error being-3.56%),and the biggest test error being 0.015(the relative error being 2.5%).
基金Project(217/s/458)supported by Azarbaijan Shahid Madani University,Iran
文摘A statistical signal processing technique was proposed and verified as independent component analysis(ICA) for fault detection and diagnosis of industrial systems without exact and detailed model.Actually,the aim is to utilize system as a black box.The system studied is condenser system of one of MAPNA's power plants.At first,principal component analysis(PCA) approach was applied to reduce the dimensionality of the real acquired data set and to identify the essential and useful ones.Then,the fault sources were diagnosed by ICA technique.The results show that ICA approach is valid and effective for faults detection and diagnosis even in noisy states,and it can distinguish main factors of abnormality among many diverse parts of a power plant's condenser system.This selectivity problem is left unsolved in many plants,because the main factors often become unnoticed by fault expansion through other parts of the plants.
文摘In this paper,a detailed investigation of water(Pr=7.0)convection in a chemical condenser is carried out.Two openings are located along one side of the cavity.The Navier-Stokes equations are solved in the frame of a control volume method using the SIMPLEC algorithm to implement adequate coupling of pressure and velocity.Special emphasis is given to the influence of the Reynolds number,the tilt of the channel and the Rayleigh number on the convective heat transfer.Results are presented and discussed allowing the control parameters to span relatively wide intervals:Rayleigh number(10^(4)≤Ra≤5×10^(5)),channel inclination(0°≤90°)and Reynolds number(10≤Re≤1000).On the basis of these results,a new correlation of the Nusselt number is elaborated.
文摘Lead has caused serious environmental pollution due to its toxicity, accumulation in food chains and persistence in nature. In this paper, removal of lead from aqueous solutions is investigated using a novel gel adsorbent synthesized from natural condensed tannin. The novel adsorbent performs in aqueous solutions as a weak base with valid basic groups of 1.2mmol·g-1 tannin gel particles and therefore results in the elevation of pH value of aqueous solutions. Even when initial pH is 3.6, final pH at equilibrium can climb up to 6.5 that is above the pH value for Pb(OH)2 precipitation formation and then lead can be removed from wastewater by this so-called surface precipitation. The adsorption isotherm can be expressed by the Langmuir equation and the maximum capacity for adsorption of Pb is up to 92 mg·g-1 (based on dry adsorbent) when initial pH value is 3.6. Hence, the adsorbent does offer favorable properties in lead removal with respect to its high adsorption capacity at low initial pH value, which is advantageous to lead removal from acidic wastewater. A model is put forward to describe the individual adsorption phenomenon of the tannin gel adsorbent.
基金supported by the Ministry of Higher Education,Scientific Research and Technology of Tunisia
文摘Single crystals of LaP3O9·3H2O were prepared using a classical method of aqueous chemistry whereas those of the ultraphosphate LaP5O14 were obtained by flux method.Thermal treatment of LaP3O9·3H2O up to 700 °C allowed us to obtain the lanthanum polyphosphate La(PO3)3.The conductivity as well as the vibrational study of the lanthanum ultraphosphate and polyphosphate were analysed in order to explain the mechanism of conduction.Activation energies of 0.45 and 0.84 eV,deduced from the Arrhenius relation,were r...
基金the National Research Foundation of Korea(NRF)funded by the Korean Government(MSIT)(No.2022R1A2C1006743)。
文摘This study presents a facile and rapid method for synthesizing novel Layered Double Hydroxide(LDH)nanoflakes,exploring their application as a photocatalyst,and investigating the influence of condensed phosphates'geometric linearity on their photocatalytic properties.Herein,the Mg O film,obtained by plasma electrolysis of AZ31 Mg alloys,was modified by growing an LDH film,which was further functionalized using cyclic sodium hexametaphosphate(CP)and linear sodium tripolyphosphate(LP).CP acted as an enhancer for flake spacing within the LDH structure,while LP changed flake dispersion and orientation.Consequently,CP@LDH demonstrated exceptional efficiency in heterogeneous photocatalysis,effectively degrading organic dyes like Methylene blue(MB),Congo red(CR),and Methyl orange(MO).The unique cyclic structure of CP likely enhances surface reactions and improves the catalyst's interaction with dye molecules.Furthermore,the condensed phosphate structure contributes to a higher surface area and reactivity in CP@LDH,leading to its superior photocatalytic performance compared to LP@LDH.Specifically,LP@LDH demonstrated notable degradation efficiencies of 93.02%,92.89%,and 88.81%for MB,MO,and CR respectively,over a 40 min duration.The highest degradation efficiencies were observed in the case of the CP@LDH sample,reporting 99.99%for MB,98.88%for CR,and 99.70%for MO.This underscores the potential of CP@LDH as a highly effective photocatalyst for organic dye degradation,offering promising prospects for environmental remediation and water detoxification applications.
基金supported by the National Natural Science Foundation of China(51172285 and 51372277)the Fundamental Research Funds for the Central Universities(14CX02060A,15CX02084A)the Natural Science Foundation of Shandong Province(ZR2011EL030)
文摘In order to improve the thermal stability of condensed polynuclear aromatic(COPNA) resin synthesized from vacuum residue, 1,4-benzenedimethanol was added to cure COPNA resin. The curing mechanism was investigated by proton nuclear magnetic resonance spectrometry, solid carbon-13 nuclear magnetic resonance spectrometry and Fourier transform infrared spectroscopy. Microstructures of the uncured and the cured COPNA resins were studied by scanning electron microscopy and X-ray diffractometry. The thermal stability of COPNA resins before and after curing was tested by thermogravimetric analysis. The element composition of the cured COPNA resin heated at different temperatures was analyzed by an element analyzer. The results showed that the uncured COPNA resin reacted with the cross-linking agent during the curing process, and the curing mechanism was confirmed to be the electrophilic substitution reaction. Compared with the uncured COPNA resin, the cured COPNA resin had a smooth surface, well-ordered and streamlined sheet structure with more crystalline solids, better molecular arrangement and orientation. The weight loss process of the uncured and cured COPNA resins was divided into three stages. Carbon residue of the cured COPNA resin was 41.65% at 600 ℃, which was much higher than 25.02% of the uncured COPNA resin, which indicated that the cured COPNA resin had higher thermal stability.
