Single-ion magnets(SIMs)and single-molecule magnets(SMMs)are typically made up of 3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal behavior at the molecular level.SMMs/SIMs ...Single-ion magnets(SIMs)and single-molecule magnets(SMMs)are typically made up of 3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal behavior at the molecular level.SMMs/SIMs have various promising applications,including high-density information storage,molecular spintronics,and quantum computers.This article offers an overview of single-ion magnetism in lanthanide(III)-based coordination frameworks that consist of self-assemblies in one-,two-,and threedimensions.The large magnetic moments and magnetic anisotropy of lanthanide(III)ions make them potential candidates for SIMs/SMMs.Additionally,the coordination framework structure enables multifunctionalities such as responsiveness to external stimuli,proton conduction,high structural stability,and host–vip interactions.These multi-functionalities indicate that the lanthanide(III)-based magnetic metal coordination frameworks represent an exciting platform for the development of a new generation of SIMs/SMMs.展开更多
Richard Feynman once stated:“Turbulence is the most important unsolved problem of classical physics.”Due to its chaotic and multiscale nature,a faithful simulation of turbulence presents a formidable challenge for c...Richard Feynman once stated:“Turbulence is the most important unsolved problem of classical physics.”Due to its chaotic and multiscale nature,a faithful simulation of turbulence presents a formidable challenge for classical computers.This computational barrier reflects Feynman's early observations on the limitations of classical computers.Beyond his pioneering remark on quantum simulation,the application of quantum computing to classical problems has also emerged as an active field of research.展开更多
基金supported by the JSPS KAKENHI Grant Number JP19H05631the National Natural Science Foundation of China(NSFC,22150710513)M.Y.Thanks the 111 projects(B18030)from China.
文摘Single-ion magnets(SIMs)and single-molecule magnets(SMMs)are typically made up of 3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal behavior at the molecular level.SMMs/SIMs have various promising applications,including high-density information storage,molecular spintronics,and quantum computers.This article offers an overview of single-ion magnetism in lanthanide(III)-based coordination frameworks that consist of self-assemblies in one-,two-,and threedimensions.The large magnetic moments and magnetic anisotropy of lanthanide(III)ions make them potential candidates for SIMs/SMMs.Additionally,the coordination framework structure enables multifunctionalities such as responsiveness to external stimuli,proton conduction,high structural stability,and host–vip interactions.These multi-functionalities indicate that the lanthanide(III)-based magnetic metal coordination frameworks represent an exciting platform for the development of a new generation of SIMs/SMMs.
文摘Richard Feynman once stated:“Turbulence is the most important unsolved problem of classical physics.”Due to its chaotic and multiscale nature,a faithful simulation of turbulence presents a formidable challenge for classical computers.This computational barrier reflects Feynman's early observations on the limitations of classical computers.Beyond his pioneering remark on quantum simulation,the application of quantum computing to classical problems has also emerged as an active field of research.
