Thework presents the electronic structure computations and optical spectroscopy studies of half-Heusler ScNiBi and YNiBi compounds.Our first-principles computations of the electronic structures were based on density f...Thework presents the electronic structure computations and optical spectroscopy studies of half-Heusler ScNiBi and YNiBi compounds.Our first-principles computations of the electronic structures were based on density functional theory accounting for spin-orbit coupling.These compounds are computed to be semiconductors.The calculated gap values make ScNiBi and YNiBi valid for thermoelectric and optoelectronic applications and as selective filters.In ScNiBi and YNiBi,an intense peak at the energy of−2 eV is composed of theNi 3d states in the conduction band,and the valence band mostly contains these states with some contributions from the Bi 6p and Sc 3d or Y 4d electronic states.These states participate in the formation of the indirect gap of 0.16 eV(ScNiBi)and 0.18 eV(YNiBi).Within the spectral ellipsometry technique in the interval 0.22–15μm of wavelength,the optical functions of materials are studied,and their dispersion features are revealed.A good matching of the experimental and modeled optical conductivity spectra allowed us to analyze orbital contributions.The abnormally low optical absorption observed in the low-energy region of the spectrum is referred to as the results of band calculations indicating a small density of electronic states near the Fermi energy of these complex materials.展开更多
现有GNSS水汽层析研究主要聚焦于如何提升卫星观测数据利用率,但在卫星信号数据优选方面研究较少,导致穿过同一组网格集的层析观测方程线性近似且方程系数矩阵列向量元素多数为零,水汽层析模型病态严重。针对该现状,本文提出一种GNSS卫...现有GNSS水汽层析研究主要聚焦于如何提升卫星观测数据利用率,但在卫星信号数据优选方面研究较少,导致穿过同一组网格集的层析观测方程线性近似且方程系数矩阵列向量元素多数为零,水汽层析模型病态严重。针对该现状,本文提出一种GNSS卫星信号自适应优选的水汽层析方法,解决层析模型设计矩阵零元素较多和层析模型病态的难题。该方法基于网格覆盖率最大原则确定层析区域水平网格划分,并发展联合卫星高度角与方位角阈值的卫星信号自适应优选方法,克服水汽层析模型观测方程线性近似的难题。本文选取香港地区2013年5月2日—2013年5月7日共6 d 12个GNSS测站及1个无线电探空站数据为例进行试验。与现有方法相比,本文方法能在降低卫星信号利用率的同时保证网格覆盖率,克服相似卫星信号造成层析模型设计矩阵病态的现状。以无线电探空数据为真值,发现本文方法反演水汽密度廓线的平均RMS、MAE和Bias分别为1.03、0.80和0.13 g/m^(3),优于传统方法的1.25、0.97和0.10 g/m^(3),其RMS改善率为20.78%;此外,本文方法在模型解算效率方面也优于传统方法,其模型计算效率平均提升9.51%。展开更多
Complicated changes occur inside the steel parts during quenching process. A three dimensional nonlinear mathematical model for quenching process has been established and the numerical simulation on temperature field,...Complicated changes occur inside the steel parts during quenching process. A three dimensional nonlinear mathematical model for quenching process has been established and the numerical simulation on temperature field, microstructure and stress field has been realized. The alternative technique for the formation of high-strength materials has been developed on the basis of intensification of heat transfer at phase transformations. The technology for the achievement of maximum compressive residual stresses on the hard surface is introduced. It has been shown that there is an optimal depth of hard layer providing the maximum compression stresses on the surface. It has also been established that in the surface hard layer additional strengthening (superstrengthening) of the material is observed. The generalized formula for the determination of the time of reaching maximum compressive stresses on the surface has been proposed.展开更多
近三年,以大语言模型(large language models,LLMs)为代表的人工智能技术和产业得到快速发展,实际应用也取得显著效果。为应对国家和行业发展的需求,国内许多高校纷纷设置人工智能学院、学科和专业,但与计算机学院、学科及专业的边界仍...近三年,以大语言模型(large language models,LLMs)为代表的人工智能技术和产业得到快速发展,实际应用也取得显著效果。为应对国家和行业发展的需求,国内许多高校纷纷设置人工智能学院、学科和专业,但与计算机学院、学科及专业的边界仍不够明晰。为此,本文描述了人工智能的含义、组成,并试图厘清与计算机学科及专业的关系,提出人工智能学院与计算机学院学科、专业发展的一些建议,期望为后续相关研究提供参考。展开更多
文摘Thework presents the electronic structure computations and optical spectroscopy studies of half-Heusler ScNiBi and YNiBi compounds.Our first-principles computations of the electronic structures were based on density functional theory accounting for spin-orbit coupling.These compounds are computed to be semiconductors.The calculated gap values make ScNiBi and YNiBi valid for thermoelectric and optoelectronic applications and as selective filters.In ScNiBi and YNiBi,an intense peak at the energy of−2 eV is composed of theNi 3d states in the conduction band,and the valence band mostly contains these states with some contributions from the Bi 6p and Sc 3d or Y 4d electronic states.These states participate in the formation of the indirect gap of 0.16 eV(ScNiBi)and 0.18 eV(YNiBi).Within the spectral ellipsometry technique in the interval 0.22–15μm of wavelength,the optical functions of materials are studied,and their dispersion features are revealed.A good matching of the experimental and modeled optical conductivity spectra allowed us to analyze orbital contributions.The abnormally low optical absorption observed in the low-energy region of the spectrum is referred to as the results of band calculations indicating a small density of electronic states near the Fermi energy of these complex materials.
文摘现有GNSS水汽层析研究主要聚焦于如何提升卫星观测数据利用率,但在卫星信号数据优选方面研究较少,导致穿过同一组网格集的层析观测方程线性近似且方程系数矩阵列向量元素多数为零,水汽层析模型病态严重。针对该现状,本文提出一种GNSS卫星信号自适应优选的水汽层析方法,解决层析模型设计矩阵零元素较多和层析模型病态的难题。该方法基于网格覆盖率最大原则确定层析区域水平网格划分,并发展联合卫星高度角与方位角阈值的卫星信号自适应优选方法,克服水汽层析模型观测方程线性近似的难题。本文选取香港地区2013年5月2日—2013年5月7日共6 d 12个GNSS测站及1个无线电探空站数据为例进行试验。与现有方法相比,本文方法能在降低卫星信号利用率的同时保证网格覆盖率,克服相似卫星信号造成层析模型设计矩阵病态的现状。以无线电探空数据为真值,发现本文方法反演水汽密度廓线的平均RMS、MAE和Bias分别为1.03、0.80和0.13 g/m^(3),优于传统方法的1.25、0.97和0.10 g/m^(3),其RMS改善率为20.78%;此外,本文方法在模型解算效率方面也优于传统方法,其模型计算效率平均提升9.51%。
文摘Complicated changes occur inside the steel parts during quenching process. A three dimensional nonlinear mathematical model for quenching process has been established and the numerical simulation on temperature field, microstructure and stress field has been realized. The alternative technique for the formation of high-strength materials has been developed on the basis of intensification of heat transfer at phase transformations. The technology for the achievement of maximum compressive residual stresses on the hard surface is introduced. It has been shown that there is an optimal depth of hard layer providing the maximum compression stresses on the surface. It has also been established that in the surface hard layer additional strengthening (superstrengthening) of the material is observed. The generalized formula for the determination of the time of reaching maximum compressive stresses on the surface has been proposed.
文摘近三年,以大语言模型(large language models,LLMs)为代表的人工智能技术和产业得到快速发展,实际应用也取得显著效果。为应对国家和行业发展的需求,国内许多高校纷纷设置人工智能学院、学科和专业,但与计算机学院、学科及专业的边界仍不够明晰。为此,本文描述了人工智能的含义、组成,并试图厘清与计算机学科及专业的关系,提出人工智能学院与计算机学院学科、专业发展的一些建议,期望为后续相关研究提供参考。
