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Impact of Oxygen Vacancy on Performance of Amorphous InGaZnO Based Schottky Barrier Diode 被引量:1
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作者 JIA Bin TONG Xiaowen +3 位作者 HAN Zikang QIN Ming WANG Lifeng HUANG Xiaodong 《发光学报》 北大核心 2025年第3期412-420,共9页
Rectifying circuit,as a crucial component for converting alternating current into direct current,plays a pivotal role in energy harvesting microsystems.Traditional silicon-based or germanium-based rectifier diodes hin... Rectifying circuit,as a crucial component for converting alternating current into direct current,plays a pivotal role in energy harvesting microsystems.Traditional silicon-based or germanium-based rectifier diodes hinder system integration due to their specific manufacturing processes.Conversely,metal oxide diodes,with their simple fabrication techniques,offer advantages for system integration.The oxygen vacancy defect of oxide semiconductor will greatly affect the electrical performance of the device,so the performance of the diode can be effectively controlled by adjusting the oxygen vacancy concentration.This study centers on optimizing the performance of diodes by modulating the oxygen vacancy concentration within InGaZnO films through control of oxygen flows during the sputtering process.Experimental results demonstrate that the diode exhibits a forward current density of 43.82 A·cm^(−2),with a rectification ratio of 6.94×10^(4),efficiently rectifying input sine signals with 1 kHz frequency and 5 V magnitude.These results demonstrate its potential in energy conversion and management.By adjusting the oxygen vacancy,a methodology is provided for optimizing the performance of rectifying diodes. 展开更多
关键词 INGAZNO Schottky barrier diode oxygen vacancy rectifying performance
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Functionalized Separators Boosting Electrochemical Performances for Lithium Batteries 被引量:2
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作者 Zixin Fan Xiaoyu Chen +5 位作者 Jingjing Shi Hui Nie Xiaoming Zhang Xingping Zhou Xiaolin Xie Zhigang Xue 《Nano-Micro Letters》 2025年第6期55-92,共38页
The growing demands for energy storage systems,electric vehicles,and portable electronics have significantly pushed forward the need for safe and reliable lithium batteries.It is essential to design functional separat... The growing demands for energy storage systems,electric vehicles,and portable electronics have significantly pushed forward the need for safe and reliable lithium batteries.It is essential to design functional separators with improved mechanical and electrochemical characteristics.This review covers the improved mechanical and electrochemical performances as well as the advancements made in the design of separators utilizing a variety of techniques.In terms of electrolyte wettability and adhesion of the coating materials,we provide an overview of the current status of research on coated separators,in situ modified separators,and grafting modified separators,and elaborate additional performance parameters of interest.The characteristics of inorganics coated separators,organic framework coated separators and inorganic-organic coated separators from different fabrication methods are compared.Future directions regarding new modified materials,manufacturing process,quantitative analysis of adhesion and so on are proposed toward next-generation advanced lithium batteries. 展开更多
关键词 SEPARATORS Polymer electrolytes Lithium batteries Electrochemical performances FUNCTIONALIZATION
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Improvement of Cold Recycled Mixture Performance Based on Improved Density Test Method and RAP Characteristics
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作者 HAN Zhanchuang PANG Yafeng LIN Hongwei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2025年第1期79-87,共9页
The available test methods for optimal moisture content of cold recycled mixture(CRM)as well as its bulk specific gravity,and theoretical maximum relative density were analyzed in this work.Some test improvements were... The available test methods for optimal moisture content of cold recycled mixture(CRM)as well as its bulk specific gravity,and theoretical maximum relative density were analyzed in this work.Some test improvements were suggested to improve test control of the CRM road performance based on the discovered flaws.Besides,the properties of reclaimed asphalt pavement(RAP),including the content of old asphalt,penetration index,passing rate of 4.75 mm sieve,and gradation change rate after extraction,were examined.The effects of RAP characteristics on splitting tensile strength,water stability,the high-and low-temperature performance of emulsified asphalt CRM were studied.The results show that the optimum moisture content of CRM should be determined when the compaction work matches the specimen’s molding work.Among the analyzed methods of bulk specific gravity assessment,the dry-surface and CoreLok methods provide more robust and accurate results than the wax-sealing method,while the dry-surface method is the most cost-efficient.The modified theoretical maximum relative density test method is proposed,which can reduce the systematic error of the vacuum test method.The following RAP-CRM trends can be observed.The lower the content of old asphalt and the smaller the change rate of gradation,the smaller the voids and the better the water stability of CRM.The greater the penetration of old asphalt,the higher the fracture work and low-temperature splitting strength.The greater the penetration,the higher the passing rate of 4.75 mm sieve after extraction,and the worse the high-temperature performance of CRM. 展开更多
关键词 RAP volume parameters high-temperature performance low-temperature performance water stability
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From Static and Dynamic Perspectives:A Survey on Historical Data Benchmarks of Control Performance Monitoring 被引量:1
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作者 Pengyu Song Jie Wang +1 位作者 Chunhui Zhao Biao Huang 《IEEE/CAA Journal of Automatica Sinica》 2025年第2期300-316,共17页
In recent decades,control performance monitoring(CPM)has experienced remarkable progress in research and industrial applications.While CPM research has been investigated using various benchmarks,the historical data be... In recent decades,control performance monitoring(CPM)has experienced remarkable progress in research and industrial applications.While CPM research has been investigated using various benchmarks,the historical data benchmark(HIS)has garnered the most attention due to its practicality and effectiveness.However,existing CPM reviews usually focus on the theoretical benchmark,and there is a lack of an in-depth review that thoroughly explores HIS-based methods.In this article,a comprehensive overview of HIS-based CPM is provided.First,we provide a novel static-dynamic perspective on data-level manifestations of control performance underlying typical controller capacities including regulation and servo:static and dynamic properties.The static property portrays time-independent variability in system output,and the dynamic property describes temporal behavior driven by closed-loop feedback.Accordingly,existing HIS-based CPM approaches and their intrinsic motivations are classified and analyzed from these two perspectives.Specifically,two mainstream solutions for CPM methods are summarized,including static analysis and dynamic analysis,which match data-driven techniques with actual controlling behavior.Furthermore,this paper also points out various opportunities and challenges faced in CPM for modern industry and provides promising directions in the context of artificial intelligence for inspiring future research. 展开更多
关键词 Control performance monitoring(CPM) datadriven method historical data benchmark(HIS) industrial process performance index static and dynamic analysis.
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Machine learning approaches for predicting impact sensitivity and detonation performances of energetic materials 被引量:2
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作者 Wei-Hong Liu Qi-Jun Liu +1 位作者 Fu-Sheng Liu Zheng-Tang Liu 《Journal of Energy Chemistry》 2025年第3期161-171,共11页
Excellent detonation performances and low sensitivity are prerequisites for the deployment of energetic materials.Exploring the underlying factors that affect impact sensitivity and detonation performances as well as ... Excellent detonation performances and low sensitivity are prerequisites for the deployment of energetic materials.Exploring the underlying factors that affect impact sensitivity and detonation performances as well as exploring how to obtain materials with desired properties remains a long-term challenge.Machine learning with its ability to solve complex tasks and perform robust data processing can reveal the relationship between performance and descriptive indicators,potentially accelerating the development process of energetic materials.In this background,impact sensitivity,detonation performances,and 28 physicochemical parameters for 222 energetic materials from density functional theory calculations and published literature were sorted out.Four machine learning algorithms were employed to predict various properties of energetic materials,including impact sensitivity,detonation velocity,detonation pressure,and Gurney energy.Analysis of Pearson coefficients and feature importance showed that the heat of explosion,oxygen balance,decomposition products,and HOMO energy levels have a strong correlation with the impact sensitivity of energetic materials.Oxygen balance,decomposition products,and density have a strong correlation with detonation performances.Utilizing impact sensitivity of 2,3,4-trinitrotoluene and the detonation performances of 2,4,6-trinitrobenzene-1,3,5-triamine as the benchmark,the analysis of feature importance rankings and statistical data revealed the optimal range of key features balancing impact sensitivity and detonation performances:oxygen balance values should be between-40%and-30%,density should range from 1.66 to 1.72 g/cm^(3),HOMO energy levels should be between-6.34 and-6.31 eV,and lipophilicity should be between-1.0 and 0.1,4.49 and 5.59.These findings not only offer important insights into the impact sensitivity and detonation performances of energetic materials,but also provide a theoretical guidance paradigm for the design and development of new energetic materials with optimal detonation performances and reduced sensitivity. 展开更多
关键词 Energetic materials Machine learning Impact sensitivity Detonation performances Feature descriptors Balancing strategy
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The sow vaginal and gut microbiota associated with longevity and reproductive performance 被引量:1
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作者 Ziyu Liu Tsungcheng Tsai +5 位作者 Bin Zuo Samantha Howe Jason EFarrar Christopher ERandolph Charles VMaxwell Jiangchao Zhao 《Journal of Animal Science and Biotechnology》 2025年第2期577-595,共19页
Background Sow longevity and reproductivity are essential in the modern swine industry.Although many studies have focused on the genetic and genomic factors for selection,little is known about the associations between... Background Sow longevity and reproductivity are essential in the modern swine industry.Although many studies have focused on the genetic and genomic factors for selection,little is known about the associations between the microbiome and sows with longevity in reproduction.Results In this study,we collected and sequenced rectal and vaginal swabs from 48 sows,nine of which completed up to four parities(U4P group),exhibiting reproductive longevity.We first identified predictors of sow longevity in the rectum(e.g.,Akkermansia)and vagina(e.g.,Lactobacillus)of the U4P group using RandomForest in the early breeding stage of the first parity.Interestingly,these bacteria in the U4P group showed decreased predicted KEGG gene abundance involved in the biosynthesis of amino acids.Then,we tracked the longitudinal changes of the micro-biome over four parities in the U4P sows.LEfSe analysis revealed parity-associated bacteria that existed in both the rectum and vagina(e.g.,Streptococcus in Parity 1,Lactobacillus in Parity 2,Veillonella in Parity 4).We also identi-fied patterns of bacterial change between the early breeding stage(d 0)and d 110,such as Streptococcus,which was decreased in all four parties.Furthermore,sows in the U4P group with longevity potential also showed better reproductive performance.Finally,we discovered bacterial predictors(e.g.,Prevotellaceae NK3B31 group)for the total number of piglets born throughout the four parities in both the rectum and vagina.Conclusions This study highlights how the rectal and vaginal microbiome in sows with longevity in reproduc-tion changes within four parities.The identification of parity-associated,pregnancy-related,and reproductive performance-correlated bacteria provides the foundation for targeted microbiome modulation to improve animal production. 展开更多
关键词 LONGEVITY Parity Rectal microbiome Reproductive performance SOWS Vaginal microbiome
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Flexural Performance of UHPC-Reinforced Concrete T-Beams:Experimental and Numerical Investigations 被引量:1
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作者 Guangqing Xiao Xilong Chen +2 位作者 Lihai Xu Feilong Kuang Shaohua He 《Structural Durability & Health Monitoring》 2025年第5期1167-1181,共15页
This study investigates the flexural performance of ultra-high performance concrete(UHPC)in reinforced concrete T-beams,focusing on the effects of interfacial treatments.Three concrete T-beam specimens were fabricated... This study investigates the flexural performance of ultra-high performance concrete(UHPC)in reinforced concrete T-beams,focusing on the effects of interfacial treatments.Three concrete T-beam specimens were fabricated and tested:a control beam(RC-T),a UHPC-reinforced beam with a chiseled interface(UN-C-50F),and a UHPC-reinforced beam featuring both a chiseled interface and anchored steel rebars(UN-CS-50F).The test results indicated that both chiseling and the incorporation of anchored rebars effectively created a synergistic combination between the concrete T-beam and the UHPC reinforcement layer,with the UN-CS-50F exhibiting the highest flexural resistance.The cracking load and ultimate load of UN-CS-50F were 221.5%and 40.8%,respectively,higher than those of the RC-T.Finite element(FE)models were developed to provide further insights into the behavior of the UHPCreinforced T-beams,showing a maximumdeviation of just 8%when validated against experimental data.A parametric analysis varied the height,thickness,andmaterial strength of the UHPC reinforcement layer based on the validated FE model,revealing that increasing the UHPC layer thickness from 30 to 50 mm improved the ultimate resistance by 20%while reducing the UHPC reinforcement height from 440 to 300 mm led to a 10%decrease in bending resistance.The interfacial anchoring rebars significantly reduced crack propagation and enhanced stress redistribution,highlighting the importance of strengthening interfacial bonds and optimizing geometric parameters ofUHPCfor improved T-beam performance.These findings offer valuable insights for the design and retrofitting of UHPC-reinforced bridge girders. 展开更多
关键词 UHPC thin layer T-BEAM REINFORCEMENT bending performance numerical simulation
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Artificial Intelligence Empowers Solid‑State Batteries for Material Screening and Performance Evaluation 被引量:1
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作者 Sheng Wang Jincheng Liu +5 位作者 Xiaopan Song Huajian Xu Yang Gu Junyu Fan Bin Sun Linwei Yu 《Nano-Micro Letters》 2025年第11期599-629,共31页
Solid-state batteries are widely recognized as the next-generation energy storage devices with high specific energy,high safety,and high environmental adaptability.However,the research and development of solid-state b... Solid-state batteries are widely recognized as the next-generation energy storage devices with high specific energy,high safety,and high environmental adaptability.However,the research and development of solid-state batteries are resource-intensive and time-consuming due to their complex chemical environment,rendering performance prediction arduous and delaying large-scale industrialization.Artificial intelligence serves as an accelerator for solid-state battery development by enabling efficient material screening and performance prediction.This review will systematically examine how the latest progress in using machine learning(ML)algorithms can be used to mine extensive material databases and accelerate the discovery of high-performance cathode,anode,and electrolyte materials suitable for solid-state batteries.Furthermore,the use of ML technology to accurately estimate and predict key performance indicators in the solid-state battery management system will be discussed,among which are state of charge,state of health,remaining useful life,and battery capacity.Finally,we will summarize the main challenges encountered in the current research,such as data quality issues and poor code portability,and propose possible solutions and development paths.These will provide clear guidance for future research and technological reiteration. 展开更多
关键词 Solid-state batteries Artificial intelligence Deep learning Material screening performance evaluation
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Preparation of spherical HMX@PDA-based PBX by co-axial droplet microfluidic technology:Enhancing the interfacial effect and safety performance of composite microspheres 被引量:1
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作者 Yunyan Guo Yi Liu +6 位作者 Jiani Xie Jiawei Li Fan Wang Jinshan Lei Chongwei An Zhongliang Ma Bidong Wu 《Defence Technology(防务技术)》 2025年第3期73-83,共11页
Surface engineering plays a crucial role in improving the performance of high energy materials,and polydopamine(PDA)is widely used in the field of energetic materials for surface modification and functionalization.In ... Surface engineering plays a crucial role in improving the performance of high energy materials,and polydopamine(PDA)is widely used in the field of energetic materials for surface modification and functionalization.In order to obtain high-quality HMX@PDA-based PBX explosives with high sphericity and a narrow particle size distribution,composite microspheres were prepared using co-axial droplet microfluidic technology.The formation mechanism,thermal behavior,mechanical sensitivity,electrostatic spark sensitivity,compressive strength,and combustion performance of the microspheres were investigated.The results show that PDA can effectively enhance the interfacial interaction between the explosive particles and the binder under the synergistic effect of chemical bonds and the physical"mechanical interlocking"structure.Interface reinforcement causes the thermal decomposition temperature of the sample microspheres to move to a higher temperature,with the sensitivity to impact,friction,and electrostatic sparks(for S-1)increasing by 12.5%,31.3%,and 81.5%respectively,and the compressive strength also increased by 30.7%,effectively enhancing the safety performance of the microspheres.Therefore,this study provides an effective and universal strategy for preparing high-quality functional explosives,and also provides some reference for the safe use of energetic materials in practical applications. 展开更多
关键词 Droplet microfluidic technology Interfacial reinforcement Safety performance Surface modification POLYDOPAMINE HMX
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Ultrafine-grained refractory high-entropy alloy with oxygen control and high mechanical performance 被引量:1
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作者 Yaping Sun Chao Hou +3 位作者 Yurong Li Tielong Han Xuemei Liu Xiaoyan Song 《Journal of Materials Science & Technology》 2025年第12期45-57,共13页
Grain boundary engineering plays a significant role in the improvement of strength and plasticity of alloys. However, in refractory high-entropy alloys, the susceptibility of grain boundaries to oxygen presents a bott... Grain boundary engineering plays a significant role in the improvement of strength and plasticity of alloys. However, in refractory high-entropy alloys, the susceptibility of grain boundaries to oxygen presents a bottleneck in achieving high mechanical performance. Creating a large number of clean grain boundaries in refractory high-entropy alloys is a challenge. In this study, an ultrafine-grained (UFG) NbMoTaW alloy with high grain-boundary cohesion was prepared by powder metallurgy, taking advantages of rapid hot-pressing sintering and full-process inert atmosphere protection from powder synthesis to sintering. By oxygen control and an increase in the proportion of grain boundaries, the segregation of oxygen and formation of oxides at grain boundaries were strongly mitigated, thus the intrinsic high cohesion of the interfaces was preserved. Compared to the coarse-grained alloys prepared by arc-melting and those sintered by traditional powder metallurgy methods, the UFG NbMoTaW alloy demonstrated simultaneously increased strength and plasticity at ambient temperature. The highly cohesive grain boundaries not only reduce brittle fractures effectively but also promote intragranular deformation. Consequently, the UFG NbMoTaW alloy achieved a high yield strength even at elevated temperatures, with a remarkable performance of 1117 MPa at 1200 ℃. This work provides a feasible solution for producing refractory high-entropy alloys with low impurity content, refined microstructure, and excellent mechanical performance. 展开更多
关键词 Refractory high-entropy alloy Ultrafine-grained structure Grain boundary cohesion Mechanical performance High-temperature strength
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Investigation of mixing performance and safety characteristics of polymer-based energetic materials simulant via screw-pressing blending extrusion charges 被引量:1
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作者 Gaoming Lin Huzeng Zong +6 位作者 Suwei Wang Huang Chen Siyu Yu Xiaojie Hao Kang Wang Yuanyuan Li Guohui Zhang 《Defence Technology(防务技术)》 2025年第2期287-305,共19页
The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experim... The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process. 展开更多
关键词 Polymer-based energetic materials Screw-pressing charging process Structural design Process safety Mixing performance
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Preparation of Si/NC/CL-20 Composite Explosives by Electrostatic Spraying Method and Its Performance Characterization
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作者 DUAN Yi-long WANG Ling-xin +3 位作者 DONG Jun LI Xiu-long HE Xi JI Wei 《火炸药学报》 北大核心 2025年第5期424-429,I0001,共7页
To study the influence of silicon(Si)on 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane(CL-20),NC/CL-20 composite explosives and Si/NC/CL-20 composite explosives were prepared by the electrostatic spraying ... To study the influence of silicon(Si)on 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane(CL-20),NC/CL-20 composite explosives and Si/NC/CL-20 composite explosives were prepared by the electrostatic spraying method.The morphology,structure and thermal decomposition properties of the samples were analyzed using scanning electron microscopy(SEM),X-ray energy spectroscopy(EDS),infrared spectroscopy(FT-IR),and simultaneous thermal analyzer(TG-DSC).Additionally,the combustion process of the samples was tested using a high-speed camera.The results show that the addition of nano-Si contributes to the formation of composite explosives with regular morphology and smaller particle size.The Si/NC/CL-20 composite explosive has better and more uniform sphericity,with an average particle size of 73.4 nm,compared to the NC/CL-20 composite explosive.The Si/NC/CL-20 composite explosive which produced by the electrostatic spraying method,achieves physically uniform distribution of the components including NC,CL-20,Si.The addition of Si promotes the thermal decomposition of CL-20.In comparison to the NC/CL-20 composite explosive,the activation energy of the Si/NC/CL-20 composite explosive decreases by 16.78 kJ/mol,and the self-accelerated decomposition temperature and the critical temperature of thermal explosion decreases by 3.12 K and 2.61 K,respectively.Furthermore,Si/NC/CL-20 composite explosive has shorter ignition delay time and faster combustion rate compared to the NC/CL-20 composite explosive,which shows that Si can improve the combustion performance of CL-20. 展开更多
关键词 applied chemistry electrostatic spraying method SI Si/NC/CL-20 thermal decomposition performance combustion performance
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Experimental and Numerical Study of Bonding Capacity of Interface between Ultra-High Performance Concrete and Steel Tube 被引量:1
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作者 Ruikun Xu Jiu Li +1 位作者 Wenjie Li Wei Zhang 《Structural Durability & Health Monitoring》 2025年第2期285-305,共21页
This study investigates the bond performance at the interfacial region shared by Ultra-High Performance Concrete(UHPC)and steel tubes through push-out tests.This study examines how changes in steel fiber volumetric ra... This study investigates the bond performance at the interfacial region shared by Ultra-High Performance Concrete(UHPC)and steel tubes through push-out tests.This study examines how changes in steel fiber volumetric ratio and thickness of steel tube influence the bond strength characteristics.The results show that as the enhancement of the steel tube wall thickness,the ultimate bond strength at the interface improves significantly,whereas the initial bond strength exhibits only slight variations.The influence of steel fiber volumetric ratio presents a nonlinear trend,with initial bond strength decreasing at low fiber content and increasing significantly as fiber content rises.Additionally,finite element(FE)simulations were applied to replicate the experimental conditions,and the outcomes showed strong correlation with the experimental data,confirming the exactitude of the FE model in predicting the bond behavior at the UHPC-Steel interface.These findings provide valuable insights for optimizing the design of UHPC-Filled steel tubes in high-performance structure. 展开更多
关键词 Ultra-high performance concrete filled steel tube(UHPCFST) push-out test bonding capacity cohesive zone model
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Insights into the effect of Y substitution on superlattice structure and electrochemical performance of A_(5)B_(19)-type La-Mg-Ni-based hydrogen storage alloy for nickel metal hydride battery 被引量:1
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作者 Yanan Guo Wenfeng Wang +5 位作者 Huanhuan Su Hang Lu Yuan Li Qiuming Peng Shumin Han Lu Zhang 《Journal of Materials Science & Technology》 2025年第4期60-69,共10页
La-Mg-Ni-based hydrogen storage alloys with superlattice structures are the new generation anode material for nickel metal hydride(Ni-MH)batteries owing to the advantages of high capacity and exceptional activation pr... La-Mg-Ni-based hydrogen storage alloys with superlattice structures are the new generation anode material for nickel metal hydride(Ni-MH)batteries owing to the advantages of high capacity and exceptional activation properties.However,the cycling stability is not currently satisfactory enough which plagues its application.Herein,a strategy of partially substituting La with the Y element is proposed to boost the capacity durability of La-Mg-Ni-based alloys.Furthermore,phase structure regulation is implemented simultaneously to obtain the A5 B19-type alloy with good crystal stability specifically.It is found that Y promotes the phase formation of the Pr5 Co19-type phase after annealing at 985℃.The alloy containing Y contributes to the superior rate capability resulting from the promoted hydrogen diffusion rate.Notably,Y substitution enables strengthening the anti-pulverization ability of the alloy in terms of increasing the volume match between[A_(2)B_(4)]and[AB5]subunits,and effectively enhances the anti-corrosion ability of the alloy due to high electronegativity,realizing improved long-term cycling stability of the alloy from 74.2%to 78.5%after cycling 300 times.The work is expected to shed light on the composition and structure design of the La-Mg-Ni-based hydrogen storage alloy for Ni-MH batteries. 展开更多
关键词 Nickel metal hydride battery Y element La-Mg-Ni-based alloy A5 B19-type superlattice structure Electrochemical performance
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Regulation of Zn^(2+) solvation shell by a novel N-methylacetamide based eutectic electrolyte toward high-performance zinc-ion batteries 被引量:1
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作者 Yong Liu Kaijia Feng +7 位作者 Junmei Han Fei Wang Yibo Xing Feng Tao Haoming Li Binrui Xu Jiangtao Ji Hongxia Li 《Journal of Materials Science & Technology》 2025年第8期53-61,共9页
Aqueous Zn-ion batteries(AZIBs)have been regarded as promising alternatives to Li-ion batteries due to their advantages,such as low cost,high safety,and environmental friendliness.However,AZIBs face significant challe... Aqueous Zn-ion batteries(AZIBs)have been regarded as promising alternatives to Li-ion batteries due to their advantages,such as low cost,high safety,and environmental friendliness.However,AZIBs face significant challenges in limited stability and lifetime owing to zinc dendrite growth and serious side reactions caused by water molecules in the aqueous electrolyte during cycling.To address these issues,a new eutectic electrolyte based on Zn(ClO_(4))_(2)·6H_(2)O-N-methylacetamide(ZN)is proposed in this work.Compared with aqueous electrolyte,the ZN eutectic electrolyte containing organic N-methylacetamide could regulate the solvated structure of Zn^(2+),effectively suppressing zinc dendrite growth and side reactions.As a result,the Zn//NH4 V4 O10 full cell with the eutectic ZN-1-3 electrolyte demonstrates significantly enhanced cycling stability after 1000 cycles at 1 A g^(-1).Therefore,this study not only presents a new eutectic electrolyte for zinc-ion batteries but also provides a deep understanding of the influence of Zn^(2+)solvation structure on the cycle stability,contributing to the exploration of novel electrolytes for high-performance AZIBs. 展开更多
关键词 Zinc-ion batteries Eutectic electrolyte Zn dendrites Suppressed side reactions Zn^(2+)solvation structure Electrochemical performance
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Performance analysis of scramjet including magnetohydrodynamic power generation after combustor
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作者 LIU Chenyuan WU Shaoxun MENG Hao 《推进技术》 北大核心 2025年第8期15-28,共14页
To investigate the overall performance of reverse energy bypass scramjet,firstly a variable spe⁃cific heat method combined with a chemical balance calculation module for combustion products were used to es⁃tablish a b... To investigate the overall performance of reverse energy bypass scramjet,firstly a variable spe⁃cific heat method combined with a chemical balance calculation module for combustion products were used to es⁃tablish a benchmark scramjet performance evaluation model.Based on the test data of typical flying point of Mach 7 with the altitude of 29 km,the reliability of the model was verified.The deviations of parameters such as the to⁃tal pressure loss of combustor between the model and the test data were analyzed.Furtherly,an analytical method for post-combustion magnetohydrodynamic power generation was established;by embedding the above method into the overall performance evaluation model,performance prediction considering the power generation effect was realized.Finally,based on the above model,variety regulations of the inlet and the outlet parameters of the power generation channel and performance parameters including the engine specific impulse and the unit thrust under different enthalpy extraction ratios and load factors were analyzed.It could be concluded that the model can reliably predict the variations of key parameters.As the value of the load factor increases,the value of the conduc⁃tivity required to reach the specified enthalpy extraction ratio first decreases and then increases,which is approxi⁃mately parabolic.In order to reduce the demand for the gas conductivity for MHD power generation,the load fac⁃tor should be around 0.5.When the load factor is 0.4 and the magnetic induction intensity is 2.5 T,if the enthalpy extraction ratio reaches 0.5%,the engine specific impulse performance reduces about 3.58%. 展开更多
关键词 SCRAMJET Energy bypass Magnetohydrodynamic power generation Chemical balance performance evaluation
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Effect of Magnetron Sputtered Gas on Microstructure and Hydrogen Adsorption Performance of ZrCoRE Films
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作者 Zhou Chao Ma Zhanji +2 位作者 Li Gang Yang Lamaocao Zhang Huzhong 《稀有金属材料与工程》 北大核心 2025年第6期1451-1456,共6页
ZrCoRE(RE denotes rare earth elements)non-evaporable getter films have significant applications in vacuum packaging of micro-electro mechanical system devices because of their excellent gas adsorption performance,low ... ZrCoRE(RE denotes rare earth elements)non-evaporable getter films have significant applications in vacuum packaging of micro-electro mechanical system devices because of their excellent gas adsorption performance,low activation temperature and environmental friendliness.The films were deposited using DC magnetron sputtering with argon and krypton gases under various deposition pressures.The effects of sputtering gas type and pressure on the morphology and hydrogen adsorption performance of ZrCoRE films were investigated.Results show that the films prepared in Ar exhibit a relatively dense structure with fewer grain boundaries.The increase in Ar pressure results in more grain boundaries and gap structures in the films.In contrast,films deposited in Kr display a higher density of grain boundaries and cluster structures,and the films have an obvious columnar crystal structure,with numerous interfaces and gaps distributed between the columnar structures,providing more paths for gas diffusion.As Kr pressure increases,the film demonstrates more pronounced continuous columnar structure growth,accompanied by deeper and wider grain boundaries.This structural configuration provides a larger specific surface area,which significantly improves the hydrogen adsorption speed and capacity.Consequently,high Ar and Kr pressures are beneficial to improve the adsorption performance. 展开更多
关键词 NEG film magnetron sputtering KRYPTON sputtering pressure hydrogen adsorption performance
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High-performance supercapacitor based on 1D cobalt-based coordination polymer
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作者 RONG Hongren GAO Gexiang +5 位作者 LIU Zhiwei ZHOU Ke SU Lixin HUANG Hao LIU Wenlong LIU Qi 《无机化学学报》 北大核心 2025年第6期1183-1195,共13页
A low-cost 1D cobalt-based coordination polymer(CP)[Co(BGPD)(DMSO)_(2)(H_(2)O)_(2)](Co-BD;H2BGPD=N,N'-bis(glycinyl)pyromellitic diimide;DMSO=dimethyl sulfoxide)was synthesized by a simple method,and its crystal st... A low-cost 1D cobalt-based coordination polymer(CP)[Co(BGPD)(DMSO)_(2)(H_(2)O)_(2)](Co-BD;H2BGPD=N,N'-bis(glycinyl)pyromellitic diimide;DMSO=dimethyl sulfoxide)was synthesized by a simple method,and its crystal structure was characterized.In a three-electrode system,Co-BD,as the electrode material for supercapacitors,achieved a specific capacitance of 830 F·g^(-1)at 1 A·g^(-1),equivalent to a specific capacity of 116.4 mAh·g^(-1),and exhibited high-rate capability,reaching 212 F·g^(-1)at 20 A·g^(-1).Impressively,Co-BD||rGO(reduced graphene oxide),representing an asymmetrical supercapacitor,owns a higher energy density of 14.2 Wh·kg^(-1)at 0.80 kW·kg^(-1),and an excellent cycle performance(After 4000 cycles at 1 A·g^(-1),the capacitance retention was up to 94%).CCDC:2418872. 展开更多
关键词 SUPERCAPACITOR cobalt compound coordination polymers crystal structure electrode materials electrochemical performances
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Impact of Climate Change on the Economic Performance of Farms in the Tillabéri Department, Niger: Statistic Modeling
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作者 Idrissa Saidou Mahamadou 《Journal of Environmental Protection》 2025年第1期1-19,共19页
The department of Tillabéri is primarily affected by climatic phenomena, impacting crop yields, growing cycles, and consequently, the economic outcomes of agricultural operations. The objective of this study is t... The department of Tillabéri is primarily affected by climatic phenomena, impacting crop yields, growing cycles, and consequently, the economic outcomes of agricultural operations. The objective of this study is to analyze these impacts of climate disruption on the economic performance of farms. The methodology adopted for this study combined documentary research with field surveys conducted on a sample of 250 randomly selected farmers. The analytical methods used mainly consisted of linear regression, profitability calculations, and linear programming. The findings indicate that all productions across different crops have experienced a decrease over the past 30 years. For instance, the production of millet, sorghum, and cowpea, which were respectively 812 kg/ha, 260 kg/ha, and 100 kg/ha between the last 30 and 20 years, has now dropped to 412 kg/ha, 106 kg/ha, and 46 kg/ha respectively. A negative and significant effect on agricultural net margin was observed due to variables such as flooding, drought, pest invasion in rice fields, and temperature changes. Smallholder farms show a relatively low margin (46%) to cover their fixed costs, which may indicate a risk if fixed expenses are high. Furthermore, the analysis results from linear programming reveal that farmers could achieve an additional net profit per hectare of 116,861 FCFA, 217201.5 FCFA, and 291988.2 FCFA respectively for small, medium, and large producers by managing variable costs and health-related expenses for households. 展开更多
关键词 Farms Climate Change Economic performance Tillaberi
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