This study aims to quantify the influence of the amount of cement and chloride salt on the unconfined compression strength （UCS） of Lianyungang marine clay. The clays with various sodium chloride salt concentrations...This study aims to quantify the influence of the amount of cement and chloride salt on the unconfined compression strength （UCS） of Lianyungang marine clay. The clays with various sodium chloride salt concentrations were prepared artificially and stabilized by ordinary Portland cement with various contents. A series of UCS tests of cement stabilized clay specimen after 28 d curing were carried out. The results indicate that the increase of salt concentration results in the decrease in the UCS of cement-treated soil. The negative effect of salt concentration on the strength of cement stabilized clay directly relates to the cement content and salt concentration. The porosity-salt concentration/cement content ratio is a fundamental parameter for assessing the UCS of cement-treated salt-rich clay. An empirical prediction model of UCS is also proposed to take into account the effect of salt concentration. The findings of this study can be referenced for the stabilization improvement of chloride slat- rich soft clay.展开更多
New-type magnesium alloy with prominent solubility and mechanical property lays foundation for preparing fracturing part in petroleum extraction.Herein,Mg-xZn-Zr-SiC alloy is prepared with casting strategy.Electrochem...New-type magnesium alloy with prominent solubility and mechanical property lays foundation for preparing fracturing part in petroleum extraction.Herein,Mg-xZn-Zr-SiC alloy is prepared with casting strategy.Electrochemical and compression tests are conducted to assess the feasibility as decomposable material.Morphology,composition,phase and distribution are characterized to investigate decomposition mechanism.Results indicate that floccule,substrate component and reticulate secondary phase are formed on as-prepared surface.Sample also acts out enhanced compression strength to maintain pressure and guarantee stability in dissolution process.Furthermore,as decomposition time and zinc content increase,couple corrosion intensifies,resulting in gradually enhanced decomposition rate.Rapid sample decomposition is mainly due to basal anode dissolution,micro particle exfoliation and poor decomposition resistance of corroding product.Such work shows profound significance in preparing new-type accessible alloy to ensure rapid dissolution of fracturing part and guarantee stable compression strength in oil-gas reservoir exploitation.展开更多
Quantitatively correcting the unconfined compressive strength for sample disturbance is an important research project in the practice of ocean engineering and geotechnical engineering. In this study, the specimens of ...Quantitatively correcting the unconfined compressive strength for sample disturbance is an important research project in the practice of ocean engineering and geotechnical engineering. In this study, the specimens of undisturbed natural marine clay obtained from the same depth at the same site were deliberately disturbed to different levels. Then, the specimens with different extents of sample disturbance were trimmed for both oedometer tests and unconfined compression tests. The degree of sample disturbance SD is obtained from the oedometer test data. The relationship between the unconfined compressive strength q u and SD is studied for investigating the effect of sample disturbance on q u. It is found that the value of q u decreases linearly with the increase in SD. Then, a simple method of correcting q u for sample disturbance is proposed. Its validity is also verified through analysis of the existing published data.展开更多
The biodegradable polybutylene succinate(PBS)material offers a sustainable solution for a circular economy to address the global issue of marine plastic waste.Its cross-linkage with non-biodegradable xanthan gum(XG)bi...The biodegradable polybutylene succinate(PBS)material offers a sustainable solution for a circular economy to address the global issue of marine plastic waste.Its cross-linkage with non-biodegradable xanthan gum(XG)biopolymer to ameliorate residual granitic soil(RGS)in arid and semiarid regions can significantly mitigate soil erosion.This study investigates the enhancement of RGS by cross-linking the PBS and XG biopolymers.Employing a multitude of geotechnical tests(liquid limit,linear shrinkage,specific gravity,compaction,and UCS tests)at 3 d,28 d,and 90 d of steam-curing at a controlled temperature of 16℃,the outcomes were validated through scanning electron microscopy(SEM),thermogravimetric analysis(TGA),Fourier transform infrared spectroscopy(FTIR),and Brunauer-Emmett-Teller(BET)analyses.In addition,a comprehensive experimental database of 150 tests and nine parameters from the current study was utilized to model the UCS90-d(i.e.unconfined compressive strength after 90 d of curing)of the PBS-XG-treated RGS mixtures by deploying the random forest(RF)and eXtreme Gradient Boost(XGBoost)methods.The results found that the two biopolymers significantly improve the mechanical properties of RGS,with optimal UCS achieved at specific dosages(0.4PBS,1.5XG,and 0.2PBS+1.5XG dosage levels)and curing times.The UCS of PBS-XG-treated RGS showed up to a 57%increase after 90 d of curing.Furthermore,SEM and FTIR analyses revealed the formation of stronger microstructures and chemical bonds,respectively,whereas BET analysis indicated that pore volume and diameter are critical in affecting UCS.The proposed RF model outperformed XGBoost in predictive accuracy and generalization,demonstrating robustness and versatility.Moreover,SHAP values highlighted the significant impact of input parameters on UCS90-d,with curing time and specific material properties being key determinants.The study concludes with the proposal of a novel PyCharm intuitive graphical user interface as a"UCS Prediction App"for engineers and practitioners to forecast the UCS90-d of granitic residual soil.展开更多
In complex geological environments,the analysis of drill cores to determine rock strength can be challenging due to the wide variability in the degree of fracturing,leading to subjectivity in the collection of represe...In complex geological environments,the analysis of drill cores to determine rock strength can be challenging due to the wide variability in the degree of fracturing,leading to subjectivity in the collection of representative samples for uniaxial compressive strength testing.This study evaluates non-destructive techniques on calcareous rocks with different tectonic deformations,including Equotip hardness,ultrasound P-wave velocity,thin section analysis,and calcimetry,integrated with photogrammetric fracture analysis.The investigated carbonate rock samples are sourced from drill cores derived from the Umbria-Marche fold and thrust belt(northern Apennines,Italy),including a gently dipping limb of an anticline,a hinge zone of an anticline,and a fault zone associated with a thrust.Fracture intensity,quantified by the P21 parameter using photogrammetric techniques on pre-loading rock samples,is assessed alongside macroscopic identification of discontinuities(such as stylolites,veins,and joints)using marker colours to monitor failures during uniaxial compression testing.Empirical correlations depicted by single and multi-linear relationships indicate a strong dependence between the mechanical and physical properties of limestones.Both Equotip and P-wave velocity are influenced by fracture intensity,but P-wave velocity varies significantly with discontinuity orientation,especially at 45°-90°.To refine uniaxial compressive strength predictions and mitigate multicollinearity,statistical approaches,including linear and multilinear regression,Principal Component Analysis and Gaussian Process Regression,were tested.Findings improve the reliability of non-destructive techniques for assessing rock strength in structurally complex settings,with implications for geotechnical applications.展开更多
We report first-principles predictions of a cage-like polymeric nitrogen phase(cage-N)composed of interlocked N10 clusters stabilized by mixed sp^(2)/sp^(3) hybridization.Under high pressure,cage-N exhibits exceptiona...We report first-principles predictions of a cage-like polymeric nitrogen phase(cage-N)composed of interlocked N10 clusters stabilized by mixed sp^(2)/sp^(3) hybridization.Under high pressure,cage-N exhibits exceptional mechanical performance,including an ideal compressive strength of 343 GPa at a pressure of 300 GPa,~33% higher than that of diamond.This ultrahigh strength arises from the synergistic interplay between its three-dimensional covalent framework and hybridized bonding topology,which enables isotropic stress accommodation and dynamic electronic rearrangement.These results establish cage-N as a promising non-carbon ultrahard material and provide a bonding-driven route toward designing superhard frameworks under extreme conditions.展开更多
The biological stabilization of soil using microbially induced carbonate precipitation(MICP)employs ureolytic bacteria to precipitate calcium carbonate(CaCO3),which binds soil particles,enhancing strength,stiffness,an...The biological stabilization of soil using microbially induced carbonate precipitation(MICP)employs ureolytic bacteria to precipitate calcium carbonate(CaCO3),which binds soil particles,enhancing strength,stiffness,and erosion resistance.The unconfinedcompressive strength(UCS),a key measure of soil strength,is critical in geotechnical engineering as it directly reflectsthe mechanical stability of treated soils.This study integrates explainable artificialintelligence(XAI)with geotechnical insights to model the UCS of MICP-treated sands.Using 517 experimental data points and a combination of various input variables—including median grain size(D50),coefficientof uniformity(Cu),void ratio(e),urea concentration(Mu),calcium concentration(Mc),optical density(OD)of bacterial solution,pH,and total injection volume(Vt)—fivemachine learning(ML)models,including eXtreme gradient boosting(XGBoost),Light gradient boosting machine(LightGBM),random forest(RF),gene expression programming(GEP),and multivariate adaptive regression splines(MARS),were developed and optimized.The ensemble models(XGBoost,LightGBM,and RF)were optimized using the Chernobyl disaster optimizer(CDO),a recently developed metaheuristic algorithm.Of these,LightGBM-CDO achieved the highest accuracy for UCS prediction.XAI techniques like feature importance analysis(FIA),SHapley additive exPlanations(SHAP),and partial dependence plots(PDPs)were also used to investigate the complex non-linear relationships between the input and output variables.The results obtained have demonstrated that the XAI-driven models can enhance the predictive accuracy and interpretability of MICP processes,offering a sustainable pathway for optimizing geotechnical applications.展开更多
This study investigates the impacts of mixing time,execution procedure,cement dosage(α),and total water-to-cement ratio(W_(Total)/C)on the mixing energy(E)of deep soil mixing(DSM)columns and how E influences the stre...This study investigates the impacts of mixing time,execution procedure,cement dosage(α),and total water-to-cement ratio(W_(Total)/C)on the mixing energy(E)of deep soil mixing(DSM)columns and how E influences the strength of treated sand.Columns with a diameter of 7.5 cm were constructed using three mixing times(130,190,and 250 s),two execution procedures(normal and zigzag),threeαvalues(300,400,and 500 kg/m^(3)),and three W_(Total)/C ratios(2.5,3.0,and 3.5).For comparison,equivalent laboratory samples were also examined.Results revealed that increasing the mixing time andα,adopting the zigzag execution procedure,and reducing the W_(Total)/C ratio increase E.Outcomes indicated that an increase in E from 0.49-0.70 kJ to 0.70-0.90 kJ,0.90-1.10 kJ,and 1.10-1.40 kJ improves the unconfined compressive strength(UCS)of columns on average by 66%,124%,and 179%,respectively,and the secant modulus by 61%,110%,and 152%.Average strain at maximum stress also rises from 0.68%to 0.75%,0.81%,and 0.84%,respectively.The study identified a threshold in the direct relationship between E and the strength ratio(λ),beyond whichλdid not increase significantly with further increases in E.Additionally,at low and high E levels,DSM samples mainly failed by crushing and cracking modes,respectively.In DSM columns withα=500 kg/m^(3)and W_(Total)/C=2.5,increasing average E from 0.77 kJ to 0.95 kJ,1.08 kJ,and 1.28 kJ resulted in a reduction of coefficients of variation of UCS from 30.4%to 27.8%,24.5%,and 21.1%,respectively.展开更多
Biaxial compression tests are performed on 100 mm × 100 mm × 100 mm cubic specimens of plain high-strength highperformance concrete （HSHPC） at seven kinds of stress ratios, σ2：σ3 =0 ： - 1, -0.20 ： - 1...Biaxial compression tests are performed on 100 mm × 100 mm × 100 mm cubic specimens of plain high-strength highperformance concrete （HSHPC） at seven kinds of stress ratios, σ2：σ3 =0 ： - 1, -0.20 ： - 1, -0.30 ： - 1, -0.40 ： - 1, -0.50 ： -1, -0. 75 ： - 1, and - 1.00 ： - 1 after exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600 ℃, using a large static-dynamic true triaxial machine. Frictionreducing pads are three layers of plastic membranes with glycerine in-between for the compressive loading plane. Failure modes of the specimens are described. The two principally static compressive strengths are measured. The influences of the temperatures and stress ratios on the biaxial strengths of HSHPC after exposure to high temperatures are also analyzed. The experimental results show that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease completely with the increase in temperature; the ratios of the biaxial to its uniaxial compressive strengths depend on the stress ratios and brittleness-stiffness of HSHPC after exposure to different high temperatures. The formula of the Kupfer-Gerstle failure criterion modified with the temperature and stress ratio parameters for plain HSHPC is proposed.展开更多
Information on the effect of soil compaction on soil mechanical properties such as degree of compaction,compression and shear strength of tropical soils of Nigeria under different machinery traffic passes is very scar...Information on the effect of soil compaction on soil mechanical properties such as degree of compaction,compression and shear strength of tropical soils of Nigeria under different machinery traffic passes is very scarce.Field experiment was conducted in a tilled and compacted sandy clay loam(Alfisol)in Akure,Nigeria,under different machinery traffic passes to determine compaction effects on bulk density,compression strength,degree of compaction and the shear strength of soil.Four plots,A,B,C and D of area 20 m×50 m each were used for the field experiment.Treatment plot A was tilled with a tractor-mounted disc plough,and the remaining three plots:B,C and D were subjected to 5,10 and 15 to and fro passes,respectively,using heavy duty Mercy Fergusson tractor model 4355(3.82 Mg).The treatments were replicated three times in a randomized complete block design.Compacted plots progressively increased the bulk density from 1.63 g/cm^(3) to 1.90 g/cm^(3),but the highest bulk density was observed in plots under 15 traffic passes with the value of(1.90±0.23)g/cm3.The percentage of soil compaction varies from 90.5%to 97%at the 0-10 cm soil layer.The compression strength of soil increased from 31.00 kPa to 42.05 kPa and from 29.68 to 65.44 kPa at the 0-10 cm and 10-20 cm soil layers,respectively,which resulted in the increased shear strength from 15.79 kPa to 21.03 kPa and 14.8 kPa to 32.72 kPa at the 0-10 cm and 10-20 cm in plots under 5 and 15 traffic passes,respectively.Plot A(tilled soil)had the lowest bulk density,degree of compaction and compression strength with values(1.51±0.19)g/cm^(3),88.2%,and(12.15±0.37)kPa,respectively,and consequently the lowest shear strength of(6.02±1.23)kPa,which enhanced air movement and microbial activities in the soil.Soil under 15 traffic passes,especially at the 10-20 cm soil layer,may result in poor root penetration when cropped but can be very reliable and consistent when used for structural purposes.展开更多
It is of great significance for safety reason to obtain the triaxial compressive properties of cemented tailings backfill(CTB).The influence of cement content,curing age and confining pressure on strength and deformat...It is of great significance for safety reason to obtain the triaxial compressive properties of cemented tailings backfill(CTB).The influence of cement content,curing age and confining pressure on strength and deformation properties of CTB was examined and discussed.Results indicate that the triaxial compressive and deformation behavior of CTB is strongly affected by the cement content,curing age and confining pressure.The increase in cement content,curing age and confining pressure leads to a change in stress−strain behavior and an increase in the axial strain at failure and post-peak strength loss.The cohesion of CTB rises as the curing age and cement content increase.However,the enhancement in internal friction angle is trivial and negligible.It should be noted that the failure pattern of CTB samples in triaxial compression is mainly along a shear plane,the confining pressure restrains the lateral expansion and the bulging failure pattern is dominantly detected in CTB samples as curing age length and cement content increase.The results will help to better understand the triaxial mechanical and deformation behavior of CTB.展开更多
The failure criterion of rocks is a critical factor involved in reliability design and stability analysis of geotechnical engineering.In order to accurately evaluate the triaxial compressive strength of rocks under di...The failure criterion of rocks is a critical factor involved in reliability design and stability analysis of geotechnical engineering.In order to accurately evaluate the triaxial compressive strength of rocks under different confining pressures,a nonlinear empirical strength criterion based on Mohr-Coulomb criterion was proposed in this paper.Through the analysis of triaxial test strength of 11 types of rock materials,the feasibility and validity of proposed criterion was discussed.For a further verification,six typical strength criteria were selected,and the prediction results of each criterion and test results were statistically analyzed.The comparative comparison results show that the prediction results obtained by applying this new criterion to 97 conventional triaxial compression tests of 11 different rock materials are highly consistent with the experimental data.Statistical analysis was executed to assess the application of the new criterion and other classical criteria in predicting the failure behavior of rock.This proposed empirical criterion provides a new reference and method for the determination of triaxial compressive strength of rock materials.展开更多
Rubberized concrete is one of the most studied applications of discarded tires and offers a promising approach to developing materials with enhanced properties.The rubberized concrete mixture results in a reduced modu...Rubberized concrete is one of the most studied applications of discarded tires and offers a promising approach to developing materials with enhanced properties.The rubberized concrete mixture results in a reduced modulus of elasticity and a reduced compressive and tensile strength compared to traditional concrete.This study employs finite element simulations to investigate the elastic properties of rubberized mortar(RuM),considering the influence of inclusion stiffness and interfacial debonding.Different homogenization schemes,including Voigt,Reuss,and mean-field approaches,are implemented using DIGIMAT and ANSYS.Furthermore,the influence of the interfacial transition zone(ITZ)between mortar and rubber is analyzed by periodic homogenization.Subsequently,the influence of the ITZ is examined through a linear fracture analysis with the stress intensity factor as a key parameter,using the ANSYS SMART crack growth tool.Finally,a non-linear study in FEniCS is carried out to predict the strength of the composite material through a compression test.Comparisons with high density polyethylene(HDPE)and gravel inclusions show that increasing inclusion stiffness enhances compressive strength far more effectively than simply improving the mortar/rubber bond.Indeed,when the inclusions are much softer than the surrounding matrix,any benefit gained on the elastic modulus or strength from stronger interfacial adhesion becomes almost negligible.This study provide numerical evidence that tailoring the rubber’s intrinsic stiffness—not merely strengthening the rubber/mortar interface—is a decisive factor for improving the mechanical performance of RuM.展开更多
An orthotropic constitutive relationship with temperature parameters for plain highstrength high-performance concrete （HSHPC） under biaxial compression is developed. It is based on the experiments performed for char...An orthotropic constitutive relationship with temperature parameters for plain highstrength high-performance concrete （HSHPC） under biaxial compression is developed. It is based on the experiments performed for characterizing the strength and deformation behavior at two strength levels of HSHPC at 7 different stress ratios including a=σs ： σ3=0.00：-1,-0.20：-1,-0.30 ： -1,-0.40：-1,-0.50：-1,-0.75：-1,-1.00：-1, after the exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600℃, and using a large static-dynamic true triaxial machine. The biaxial tests were performed on 100 mm×100 mm×100 mm cubic specimens, and friction-reducing pads were used consisting of three layers of plastic membrane with glycerine in-between for the compressive loading plane. Based on the experimental results, failure modes of HSHPC specimens were described. The principal static compressive strengths, strains at the peak stress and stress-strain curves were measured; and the influence of the temperature and stress ratios on them was also analyzed. The experimental results showed that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease dramatically with the increase of temperature. The ratio of the biaxial to its uniaxial compressive strength depends on the stress ratios and brittleness-stiffness of HSHPC after exposure to different temperature levels. Comparison of the stress-strain results obtained from the theoretical model and the experimental data indicates good agreement.展开更多
The strength asymmetry between tension and compression is a typical case of mechanical response of materials.Here we achieve the intrinsic strength asymmetry of six face-centered-cubic perfect crystals（Cu,Au,Ni,Pt,Al...The strength asymmetry between tension and compression is a typical case of mechanical response of materials.Here we achieve the intrinsic strength asymmetry of six face-centered-cubic perfect crystals（Cu,Au,Ni,Pt,Al and Ir）through calculating the ideal tensile and compressive strength with considering the normal stress effect and the competition between different crystallographic planes.The results show that both the intrinsic factors（the ideal shear strength and cleavage strength of low-index planes）and the orientation could affect the strength asymmetry,which may provide insights into understanding the strength of ultra-strong materials.展开更多
Against the background of“carbon peak and carbon neutrality,”it is of great practical significance to develop non-blast furnace ironmaking technology for the sustainable development of steel industry.Carbon-bearing ...Against the background of“carbon peak and carbon neutrality,”it is of great practical significance to develop non-blast furnace ironmaking technology for the sustainable development of steel industry.Carbon-bearing iron ore pellet is an innovative burden of direct reduction ironmaking due to its excellent self-reducing property,and the thermal strength of pellet is a crucial metallurgical property that affects its wide application.The carbon-bearing iron ore pellet without binders(CIPWB)was prepared using iron concentrate and anthracite,and the effects of reducing agent addition amount,size of pellet,reduction temperature and time on the thermal compressive strength of CIPWB during the reduction process were studied.Simultaneously,the mechanism of the thermal strength evolution of CIPWB was revealed.The results showed that during the low-temperature reduction process(300-500℃),the thermal compressive strength of CIPWB linearly increases with increasing the size of pellet,while it gradually decreases with increasing the anthracite ratio.When the CIPWB with 8%anthracite is reduced at 300℃for 60 min,the thermal strength of pellet is enhanced from 13.24 to 31.88 N as the size of pellet increases from 8.04 to 12.78 mm.Meanwhile,as the temperature is 500℃,with increasing the anthracite ratio from 2%to 8%,the thermal compressive strength of pellet under reduction for 60 min remarkably decreases from 41.47 to 8.94 N.Furthermore,in the high-temperature reduction process(600-1150℃),the thermal compressive strength of CIPWB firstly increases and then reduces with increasing the temperature,while it as well as the temperature corresponding to the maximum strength decreases with increasing the anthracite ratio.With adding 18%anthracite,the thermal compressive strength of pellet reaches the maximum value at 800℃,namely 35.00 N,and obtains the minimum value at 1050℃,namely 8.60 N.The thermal compressive strength of CIPWB significantly depends on the temperature,reducing agent dosage,and pellet size.展开更多
Three types of activators such as sodium hydroxide,calcium oxide and triethanolamine(TEA)are used to establish different activation environments to address the problems associated with the process of activating fly as...Three types of activators such as sodium hydroxide,calcium oxide and triethanolamine(TEA)are used to establish different activation environments to address the problems associated with the process of activating fly ash paste.We conducted mechanical tests and numerical simulations to understand the evolution of microstructure,and used environmental scanning electron microscopy(ESEM)and energy dispersive spectroscopy(EDS)techniques to analyze the microenvironments of the samples.The mechanical properties of fly ash paste under different activation conditions and the changes in the microstructure and composition were investigated.The results revealed that under conditions of low NaOH content(1%-3%),the strength of the sample increased significantly.When the content exceeded 4%,the rate of increase in strength decreased.Based on the results,the optimal NaOH content was identified,which was about 4%.A good activation effect,especially for short-term activation(3-7 d),was achieved using TEA under high doping conditions.The activation effect was poor for long-term strength after 28 days.The CaO content did not significantly affect the degree of activation achieved.The maximum effect was exerted when the content of CaO was 2%.The virtual cement and concrete testing laboratory(VCCTL)was used to simulate the hydration process,and the results revealed that the use of the three types of activators accelerated the formation of Ca(OH)_(2) in the system.The activators also corroded the surface of the fly ash particles,resulting in a pozzolanic reaction.The active substances in fly ash were released efficiently,and hydration was realized.The pores were filled with hydration products,and the microstructure changed to form a new frame of paste filling that helped improve the strength of fly ash paste.展开更多
In order to study the characteristics of pure fly ash-based geopolymer concrete(PFGC)conveniently,we used a machine learning method that can quantify the perception of characteristics to predict its compressive streng...In order to study the characteristics of pure fly ash-based geopolymer concrete(PFGC)conveniently,we used a machine learning method that can quantify the perception of characteristics to predict its compressive strength.In this study,505 groups of data were collected,and a new database of compressive strength of PFGC was constructed.In order to establish an accurate prediction model of compressive strength,five different types of machine learning networks were used for comparative analysis.The five machine learning models all showed good compressive strength prediction performance on PFGC.Among them,R2,MSE,RMSE and MAE of decision tree model(DT)are 0.99,1.58,1.25,and 0.25,respectively.While R2,MSE,RMSE and MAE of random forest model(RF)are 0.97,5.17,2.27 and 1.38,respectively.The two models have high prediction accuracy and outstanding generalization ability.In order to enhance the interpretability of model decision-making,we used importance ranking to obtain the perception of machine learning model to 13 variables.These 13 variables include chemical composition of fly ash(SiO_(2)/Al_(2)O_(3),Si/Al),the ratio of alkaline liquid to the binder,curing temperature,curing durations inside oven,fly ash dosage,fine aggregate dosage,coarse aggregate dosage,extra water dosage and sodium hydroxide dosage.Curing temperature,specimen ages and curing durations inside oven have the greatest influence on the prediction results,indicating that curing conditions have more prominent influence on the compressive strength of PFGC than ordinary Portland cement concrete.The importance of curing conditions of PFGC even exceeds that of the concrete mix proportion,due to the low reactivity of pure fly ash.展开更多
Traditional machine learning(ML)encounters the challenge of parameter adjustment when predicting the compressive strength of reclaimed concrete.To address this issue,we introduce two optimized hybrid models:the Bayesi...Traditional machine learning(ML)encounters the challenge of parameter adjustment when predicting the compressive strength of reclaimed concrete.To address this issue,we introduce two optimized hybrid models:the Bayesian optimization model(B-RF)and the optimal model(Stacking model).These models are applied to a data set comprising 438 observations with five input variables,with the aim of predicting the compressive strength of reclaimed concrete.Furthermore,we evaluate the performance of the optimized models in comparison to traditional machine learning models,such as support vector regression(SVR),decision tree(DT),and random forest(RF).The results reveal that the Stacking model exhibits superior predictive performance,with evaluation indices including R2=0.825,MAE=2.818 and MSE=14.265,surpassing the traditional models.Moreover,we also performed a characteristic importance analysis on the input variables,and we concluded that cement had the greatest influence on the compressive strength of reclaimed concrete,followed by water.Therefore,the Stacking model can be recommended as a compressive strength prediction tool to partially replace laboratory compressive strength testing,resulting in time and cost savings.展开更多
Introduction It is necessary for an ideal bioceramic scaffold to have a suitable structure.The structure can affect the mechanical properties of the scaffold(i.e.,elastic modulus and compressive strength)and the biolo...Introduction It is necessary for an ideal bioceramic scaffold to have a suitable structure.The structure can affect the mechanical properties of the scaffold(i.e.,elastic modulus and compressive strength)and the biological properties of the scaffold(i.e.,degradability and cell growth rate).Lattice structure is a kind of periodic porous structure,which has some advantages of light weight and high strength,and is widely used in the preparation of bioceramic scaffolders.For the structure of the scaffold,high porosity and large pore size are important for bone growth,bone integration and promoting good mechanical interlocking between neighboring bones and the scaffold.However,scaffolds with a high porosity often lack mechanical strength.In addition,different parts of the bone have different structural requirements.In this paper,scaffolds with a non-uniform structure or a hierarchical structure were designed,with loose and porous exterior to facilitate cell adhesion,osteogenic differentiation and vascularization as well as relatively dense interior to provide sufficient mechanical support for bone repair.Methods In this work,composite ceramics scaffolds with 10%akermanite content were prepared by DLP technology.The scaffold had a high porosity outside to promote the growth of bone tissue,and a low porosity inside to withstand external forces.The compressive strength,fracture form,in-vitro degradation performance and bioactivity of graded bioceramic scaffolds were investigated.The models of scaffolds were imported into the DLP printer with a 405 nm light.The samples were printed with the intensity of 8 mJ/cm^(2)and a layer thickness of 50μm.Finally,the ceramic samples were sintered at 1100℃.The degradability of the hierarchical gyroid bioceramic scaffolds was evaluated through immersion in Tris-HCl solution and SBF solution at a ratio of 200 mL/g.The bioactivity of bioceramic was obtained via immersing them in SBF solution for two weeks.The concentrations of calcium,phosphate,silicon,and magnesium ions in the soaking solution were determined by an inductively coupled plasma optical emission spectrometer.Results and discussion In this work,a hierarchical Gyroid structure HA-AK10 scaffold(sintered at 1100℃)with a radial internal porosity of 50%and an external porosity of 70%is prepared,and the influence of structural form on the compressive strength and degradation performance of the scaffold is investigated.The biological activity of the bioceramics in vitro is also verified.The mechanical simulation results show that the stress distribution corresponds to the porosity distribution of the structure,and the low porosity is larger and the overall stress concentration phenomenon does not appear.After soaking in SBF solution,Si—OH is firstly formed on the surface of bioceramics,and then silicon gel layer is produced due to the presence of calcium and silicon ions.The silicon gel layer is dissociated into negatively charged groups under alkaline environment secondary adsorption of calcium ions and phosphate ions,forming amorphous calcium phosphate,and finally amorphous calcium phosphate crystals and adsorption of carbonate ions,forming carbonate hydroxyapatite.This indicates that the composite bioceramics have a good biological activity in-vitro and can provide a good environment for the growth of bone cells.A hierarchical Gyroid ceramic scaffold with a bone geometry is prepared via applying the hierarchical structure to the bone contour scaffold.The maximum load capacity of the hierarchical Gyroid ceramic scaffold is 8 times that of the uniform structure.Conclusions The hierarchical structure scaffold designed had good overall compressive performance,good degradation performance,and still maintained a good mechanical stability during degradation.In addition,in-vitro biological experimental results showed that the surface graded composite scaffold could have a good in-vitro biological activity and provide a good environment for bone cells.Compared to the heterosexual structure,the graded scaffold had greater mechanical properties.展开更多
基金The Natural Science Foundation of Jiangsu Province(No.BK2011618)the National Key Technology R&D Program of China during the12th Five-Year Plan Period(No.2012BAJ01B02)
文摘This study aims to quantify the influence of the amount of cement and chloride salt on the unconfined compression strength （UCS） of Lianyungang marine clay. The clays with various sodium chloride salt concentrations were prepared artificially and stabilized by ordinary Portland cement with various contents. A series of UCS tests of cement stabilized clay specimen after 28 d curing were carried out. The results indicate that the increase of salt concentration results in the decrease in the UCS of cement-treated soil. The negative effect of salt concentration on the strength of cement stabilized clay directly relates to the cement content and salt concentration. The porosity-salt concentration/cement content ratio is a fundamental parameter for assessing the UCS of cement-treated salt-rich clay. An empirical prediction model of UCS is also proposed to take into account the effect of salt concentration. The findings of this study can be referenced for the stabilization improvement of chloride slat- rich soft clay.
基金supported by the National Natural Science Foundation of China(No.51905417)China Postdoctoral Science Foundation(No.2020M670306).
文摘New-type magnesium alloy with prominent solubility and mechanical property lays foundation for preparing fracturing part in petroleum extraction.Herein,Mg-xZn-Zr-SiC alloy is prepared with casting strategy.Electrochemical and compression tests are conducted to assess the feasibility as decomposable material.Morphology,composition,phase and distribution are characterized to investigate decomposition mechanism.Results indicate that floccule,substrate component and reticulate secondary phase are formed on as-prepared surface.Sample also acts out enhanced compression strength to maintain pressure and guarantee stability in dissolution process.Furthermore,as decomposition time and zinc content increase,couple corrosion intensifies,resulting in gradually enhanced decomposition rate.Rapid sample decomposition is mainly due to basal anode dissolution,micro particle exfoliation and poor decomposition resistance of corroding product.Such work shows profound significance in preparing new-type accessible alloy to ensure rapid dissolution of fracturing part and guarantee stable compression strength in oil-gas reservoir exploitation.
文摘Quantitatively correcting the unconfined compressive strength for sample disturbance is an important research project in the practice of ocean engineering and geotechnical engineering. In this study, the specimens of undisturbed natural marine clay obtained from the same depth at the same site were deliberately disturbed to different levels. Then, the specimens with different extents of sample disturbance were trimmed for both oedometer tests and unconfined compression tests. The degree of sample disturbance SD is obtained from the oedometer test data. The relationship between the unconfined compressive strength q u and SD is studied for investigating the effect of sample disturbance on q u. It is found that the value of q u decreases linearly with the increase in SD. Then, a simple method of correcting q u for sample disturbance is proposed. Its validity is also verified through analysis of the existing published data.
基金supported by the National Natural Science Foundation of China(Grant Nos.52379104 and 52090084).
文摘The biodegradable polybutylene succinate(PBS)material offers a sustainable solution for a circular economy to address the global issue of marine plastic waste.Its cross-linkage with non-biodegradable xanthan gum(XG)biopolymer to ameliorate residual granitic soil(RGS)in arid and semiarid regions can significantly mitigate soil erosion.This study investigates the enhancement of RGS by cross-linking the PBS and XG biopolymers.Employing a multitude of geotechnical tests(liquid limit,linear shrinkage,specific gravity,compaction,and UCS tests)at 3 d,28 d,and 90 d of steam-curing at a controlled temperature of 16℃,the outcomes were validated through scanning electron microscopy(SEM),thermogravimetric analysis(TGA),Fourier transform infrared spectroscopy(FTIR),and Brunauer-Emmett-Teller(BET)analyses.In addition,a comprehensive experimental database of 150 tests and nine parameters from the current study was utilized to model the UCS90-d(i.e.unconfined compressive strength after 90 d of curing)of the PBS-XG-treated RGS mixtures by deploying the random forest(RF)and eXtreme Gradient Boost(XGBoost)methods.The results found that the two biopolymers significantly improve the mechanical properties of RGS,with optimal UCS achieved at specific dosages(0.4PBS,1.5XG,and 0.2PBS+1.5XG dosage levels)and curing times.The UCS of PBS-XG-treated RGS showed up to a 57%increase after 90 d of curing.Furthermore,SEM and FTIR analyses revealed the formation of stronger microstructures and chemical bonds,respectively,whereas BET analysis indicated that pore volume and diameter are critical in affecting UCS.The proposed RF model outperformed XGBoost in predictive accuracy and generalization,demonstrating robustness and versatility.Moreover,SHAP values highlighted the significant impact of input parameters on UCS90-d,with curing time and specific material properties being key determinants.The study concludes with the proposal of a novel PyCharm intuitive graphical user interface as a"UCS Prediction App"for engineers and practitioners to forecast the UCS90-d of granitic residual soil.
文摘In complex geological environments,the analysis of drill cores to determine rock strength can be challenging due to the wide variability in the degree of fracturing,leading to subjectivity in the collection of representative samples for uniaxial compressive strength testing.This study evaluates non-destructive techniques on calcareous rocks with different tectonic deformations,including Equotip hardness,ultrasound P-wave velocity,thin section analysis,and calcimetry,integrated with photogrammetric fracture analysis.The investigated carbonate rock samples are sourced from drill cores derived from the Umbria-Marche fold and thrust belt(northern Apennines,Italy),including a gently dipping limb of an anticline,a hinge zone of an anticline,and a fault zone associated with a thrust.Fracture intensity,quantified by the P21 parameter using photogrammetric techniques on pre-loading rock samples,is assessed alongside macroscopic identification of discontinuities(such as stylolites,veins,and joints)using marker colours to monitor failures during uniaxial compression testing.Empirical correlations depicted by single and multi-linear relationships indicate a strong dependence between the mechanical and physical properties of limestones.Both Equotip and P-wave velocity are influenced by fracture intensity,but P-wave velocity varies significantly with discontinuity orientation,especially at 45°-90°.To refine uniaxial compressive strength predictions and mitigate multicollinearity,statistical approaches,including linear and multilinear regression,Principal Component Analysis and Gaussian Process Regression,were tested.Findings improve the reliability of non-destructive techniques for assessing rock strength in structurally complex settings,with implications for geotechnical applications.
基金supported by the Natural Science Foundation of China(Grant Nos.T2325013,52288102,52090024,12034009,12474004,and 12304036)the National Key R&D Program of China Grant No.2023YFA1610000+1 种基金the Fundamental Research Funds for the Central Universitiesthe Program for Jilin University and Sun Yat-sen University.
文摘We report first-principles predictions of a cage-like polymeric nitrogen phase(cage-N)composed of interlocked N10 clusters stabilized by mixed sp^(2)/sp^(3) hybridization.Under high pressure,cage-N exhibits exceptional mechanical performance,including an ideal compressive strength of 343 GPa at a pressure of 300 GPa,~33% higher than that of diamond.This ultrahigh strength arises from the synergistic interplay between its three-dimensional covalent framework and hybridized bonding topology,which enables isotropic stress accommodation and dynamic electronic rearrangement.These results establish cage-N as a promising non-carbon ultrahard material and provide a bonding-driven route toward designing superhard frameworks under extreme conditions.
文摘The biological stabilization of soil using microbially induced carbonate precipitation(MICP)employs ureolytic bacteria to precipitate calcium carbonate(CaCO3),which binds soil particles,enhancing strength,stiffness,and erosion resistance.The unconfinedcompressive strength(UCS),a key measure of soil strength,is critical in geotechnical engineering as it directly reflectsthe mechanical stability of treated soils.This study integrates explainable artificialintelligence(XAI)with geotechnical insights to model the UCS of MICP-treated sands.Using 517 experimental data points and a combination of various input variables—including median grain size(D50),coefficientof uniformity(Cu),void ratio(e),urea concentration(Mu),calcium concentration(Mc),optical density(OD)of bacterial solution,pH,and total injection volume(Vt)—fivemachine learning(ML)models,including eXtreme gradient boosting(XGBoost),Light gradient boosting machine(LightGBM),random forest(RF),gene expression programming(GEP),and multivariate adaptive regression splines(MARS),were developed and optimized.The ensemble models(XGBoost,LightGBM,and RF)were optimized using the Chernobyl disaster optimizer(CDO),a recently developed metaheuristic algorithm.Of these,LightGBM-CDO achieved the highest accuracy for UCS prediction.XAI techniques like feature importance analysis(FIA),SHapley additive exPlanations(SHAP),and partial dependence plots(PDPs)were also used to investigate the complex non-linear relationships between the input and output variables.The results obtained have demonstrated that the XAI-driven models can enhance the predictive accuracy and interpretability of MICP processes,offering a sustainable pathway for optimizing geotechnical applications.
文摘This study investigates the impacts of mixing time,execution procedure,cement dosage(α),and total water-to-cement ratio(W_(Total)/C)on the mixing energy(E)of deep soil mixing(DSM)columns and how E influences the strength of treated sand.Columns with a diameter of 7.5 cm were constructed using three mixing times(130,190,and 250 s),two execution procedures(normal and zigzag),threeαvalues(300,400,and 500 kg/m^(3)),and three W_(Total)/C ratios(2.5,3.0,and 3.5).For comparison,equivalent laboratory samples were also examined.Results revealed that increasing the mixing time andα,adopting the zigzag execution procedure,and reducing the W_(Total)/C ratio increase E.Outcomes indicated that an increase in E from 0.49-0.70 kJ to 0.70-0.90 kJ,0.90-1.10 kJ,and 1.10-1.40 kJ improves the unconfined compressive strength(UCS)of columns on average by 66%,124%,and 179%,respectively,and the secant modulus by 61%,110%,and 152%.Average strain at maximum stress also rises from 0.68%to 0.75%,0.81%,and 0.84%,respectively.The study identified a threshold in the direct relationship between E and the strength ratio(λ),beyond whichλdid not increase significantly with further increases in E.Additionally,at low and high E levels,DSM samples mainly failed by crushing and cracking modes,respectively.In DSM columns withα=500 kg/m^(3)and W_(Total)/C=2.5,increasing average E from 0.77 kJ to 0.95 kJ,1.08 kJ,and 1.28 kJ resulted in a reduction of coefficients of variation of UCS from 30.4%to 27.8%,24.5%,and 21.1%,respectively.
文摘Biaxial compression tests are performed on 100 mm × 100 mm × 100 mm cubic specimens of plain high-strength highperformance concrete （HSHPC） at seven kinds of stress ratios, σ2：σ3 =0 ： - 1, -0.20 ： - 1, -0.30 ： - 1, -0.40 ： - 1, -0.50 ： -1, -0. 75 ： - 1, and - 1.00 ： - 1 after exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600 ℃, using a large static-dynamic true triaxial machine. Frictionreducing pads are three layers of plastic membranes with glycerine in-between for the compressive loading plane. Failure modes of the specimens are described. The two principally static compressive strengths are measured. The influences of the temperatures and stress ratios on the biaxial strengths of HSHPC after exposure to high temperatures are also analyzed. The experimental results show that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease completely with the increase in temperature; the ratios of the biaxial to its uniaxial compressive strengths depend on the stress ratios and brittleness-stiffness of HSHPC after exposure to different high temperatures. The formula of the Kupfer-Gerstle failure criterion modified with the temperature and stress ratio parameters for plain HSHPC is proposed.
文摘Information on the effect of soil compaction on soil mechanical properties such as degree of compaction,compression and shear strength of tropical soils of Nigeria under different machinery traffic passes is very scarce.Field experiment was conducted in a tilled and compacted sandy clay loam(Alfisol)in Akure,Nigeria,under different machinery traffic passes to determine compaction effects on bulk density,compression strength,degree of compaction and the shear strength of soil.Four plots,A,B,C and D of area 20 m×50 m each were used for the field experiment.Treatment plot A was tilled with a tractor-mounted disc plough,and the remaining three plots:B,C and D were subjected to 5,10 and 15 to and fro passes,respectively,using heavy duty Mercy Fergusson tractor model 4355(3.82 Mg).The treatments were replicated three times in a randomized complete block design.Compacted plots progressively increased the bulk density from 1.63 g/cm^(3) to 1.90 g/cm^(3),but the highest bulk density was observed in plots under 15 traffic passes with the value of(1.90±0.23)g/cm3.The percentage of soil compaction varies from 90.5%to 97%at the 0-10 cm soil layer.The compression strength of soil increased from 31.00 kPa to 42.05 kPa and from 29.68 to 65.44 kPa at the 0-10 cm and 10-20 cm soil layers,respectively,which resulted in the increased shear strength from 15.79 kPa to 21.03 kPa and 14.8 kPa to 32.72 kPa at the 0-10 cm and 10-20 cm in plots under 5 and 15 traffic passes,respectively.Plot A(tilled soil)had the lowest bulk density,degree of compaction and compression strength with values(1.51±0.19)g/cm^(3),88.2%,and(12.15±0.37)kPa,respectively,and consequently the lowest shear strength of(6.02±1.23)kPa,which enhanced air movement and microbial activities in the soil.Soil under 15 traffic passes,especially at the 10-20 cm soil layer,may result in poor root penetration when cropped but can be very reliable and consistent when used for structural purposes.
基金Projects(2018YFC0808403,2018YFE0123000)supported by the National Key Technologies Research&Development Program of ChinaProject(800015Z1185)supported by the Yueqi Young Scholar Project,ChinaProject(2020YJSNY04)supported by the Fundamental Research Funds for the Central Universities,China。
文摘It is of great significance for safety reason to obtain the triaxial compressive properties of cemented tailings backfill(CTB).The influence of cement content,curing age and confining pressure on strength and deformation properties of CTB was examined and discussed.Results indicate that the triaxial compressive and deformation behavior of CTB is strongly affected by the cement content,curing age and confining pressure.The increase in cement content,curing age and confining pressure leads to a change in stress−strain behavior and an increase in the axial strain at failure and post-peak strength loss.The cohesion of CTB rises as the curing age and cement content increase.However,the enhancement in internal friction angle is trivial and negligible.It should be noted that the failure pattern of CTB samples in triaxial compression is mainly along a shear plane,the confining pressure restrains the lateral expansion and the bulging failure pattern is dominantly detected in CTB samples as curing age length and cement content increase.The results will help to better understand the triaxial mechanical and deformation behavior of CTB.
基金Project(51774322)supported by the National Natural Science Foundation of ChinaProject(2018JJ2500)supported by Natural Science Foundation of Hunan Province,China+1 种基金Project(2020JGB135)supported by Degree and Postgraduate Education Reform Project of Central South University,ChinaProject(2018zzts209)supported by the Fundamental Research Funds for the Central Universities,China。
文摘The failure criterion of rocks is a critical factor involved in reliability design and stability analysis of geotechnical engineering.In order to accurately evaluate the triaxial compressive strength of rocks under different confining pressures,a nonlinear empirical strength criterion based on Mohr-Coulomb criterion was proposed in this paper.Through the analysis of triaxial test strength of 11 types of rock materials,the feasibility and validity of proposed criterion was discussed.For a further verification,six typical strength criteria were selected,and the prediction results of each criterion and test results were statistically analyzed.The comparative comparison results show that the prediction results obtained by applying this new criterion to 97 conventional triaxial compression tests of 11 different rock materials are highly consistent with the experimental data.Statistical analysis was executed to assess the application of the new criterion and other classical criteria in predicting the failure behavior of rock.This proposed empirical criterion provides a new reference and method for the determination of triaxial compressive strength of rock materials.
基金financial support from the Chilean National Agency for Research and Development(ANID),National Doctorate No.21212028financial support from ANID,FONDECYT Regular Research Project No.1221793.
文摘Rubberized concrete is one of the most studied applications of discarded tires and offers a promising approach to developing materials with enhanced properties.The rubberized concrete mixture results in a reduced modulus of elasticity and a reduced compressive and tensile strength compared to traditional concrete.This study employs finite element simulations to investigate the elastic properties of rubberized mortar(RuM),considering the influence of inclusion stiffness and interfacial debonding.Different homogenization schemes,including Voigt,Reuss,and mean-field approaches,are implemented using DIGIMAT and ANSYS.Furthermore,the influence of the interfacial transition zone(ITZ)between mortar and rubber is analyzed by periodic homogenization.Subsequently,the influence of the ITZ is examined through a linear fracture analysis with the stress intensity factor as a key parameter,using the ANSYS SMART crack growth tool.Finally,a non-linear study in FEniCS is carried out to predict the strength of the composite material through a compression test.Comparisons with high density polyethylene(HDPE)and gravel inclusions show that increasing inclusion stiffness enhances compressive strength far more effectively than simply improving the mortar/rubber bond.Indeed,when the inclusions are much softer than the surrounding matrix,any benefit gained on the elastic modulus or strength from stronger interfacial adhesion becomes almost negligible.This study provide numerical evidence that tailoring the rubber’s intrinsic stiffness—not merely strengthening the rubber/mortar interface—is a decisive factor for improving the mechanical performance of RuM.
文摘An orthotropic constitutive relationship with temperature parameters for plain highstrength high-performance concrete （HSHPC） under biaxial compression is developed. It is based on the experiments performed for characterizing the strength and deformation behavior at two strength levels of HSHPC at 7 different stress ratios including a=σs ： σ3=0.00：-1,-0.20：-1,-0.30 ： -1,-0.40：-1,-0.50：-1,-0.75：-1,-1.00：-1, after the exposure to normal and high temperatures of 20, 200, 300, 400, 500 and 600℃, and using a large static-dynamic true triaxial machine. The biaxial tests were performed on 100 mm×100 mm×100 mm cubic specimens, and friction-reducing pads were used consisting of three layers of plastic membrane with glycerine in-between for the compressive loading plane. Based on the experimental results, failure modes of HSHPC specimens were described. The principal static compressive strengths, strains at the peak stress and stress-strain curves were measured; and the influence of the temperature and stress ratios on them was also analyzed. The experimental results showed that the uniaxial compressive strength of plain HSHPC after exposure to high temperatures does not decrease dramatically with the increase of temperature. The ratio of the biaxial to its uniaxial compressive strength depends on the stress ratios and brittleness-stiffness of HSHPC after exposure to different temperature levels. Comparison of the stress-strain results obtained from the theoretical model and the experimental data indicates good agreement.
基金financial support from the National Natural Science Foundation of China under Grant Nos.51331007,51301174 and 51501190
文摘The strength asymmetry between tension and compression is a typical case of mechanical response of materials.Here we achieve the intrinsic strength asymmetry of six face-centered-cubic perfect crystals（Cu,Au,Ni,Pt,Al and Ir）through calculating the ideal tensile and compressive strength with considering the normal stress effect and the competition between different crystallographic planes.The results show that both the intrinsic factors（the ideal shear strength and cleavage strength of low-index planes）and the orientation could affect the strength asymmetry,which may provide insights into understanding the strength of ultra-strong materials.
基金support of the National Natural Science Foundation of China(52074080,52004001,and 51574002).
文摘Against the background of“carbon peak and carbon neutrality,”it is of great practical significance to develop non-blast furnace ironmaking technology for the sustainable development of steel industry.Carbon-bearing iron ore pellet is an innovative burden of direct reduction ironmaking due to its excellent self-reducing property,and the thermal strength of pellet is a crucial metallurgical property that affects its wide application.The carbon-bearing iron ore pellet without binders(CIPWB)was prepared using iron concentrate and anthracite,and the effects of reducing agent addition amount,size of pellet,reduction temperature and time on the thermal compressive strength of CIPWB during the reduction process were studied.Simultaneously,the mechanism of the thermal strength evolution of CIPWB was revealed.The results showed that during the low-temperature reduction process(300-500℃),the thermal compressive strength of CIPWB linearly increases with increasing the size of pellet,while it gradually decreases with increasing the anthracite ratio.When the CIPWB with 8%anthracite is reduced at 300℃for 60 min,the thermal strength of pellet is enhanced from 13.24 to 31.88 N as the size of pellet increases from 8.04 to 12.78 mm.Meanwhile,as the temperature is 500℃,with increasing the anthracite ratio from 2%to 8%,the thermal compressive strength of pellet under reduction for 60 min remarkably decreases from 41.47 to 8.94 N.Furthermore,in the high-temperature reduction process(600-1150℃),the thermal compressive strength of CIPWB firstly increases and then reduces with increasing the temperature,while it as well as the temperature corresponding to the maximum strength decreases with increasing the anthracite ratio.With adding 18%anthracite,the thermal compressive strength of pellet reaches the maximum value at 800℃,namely 35.00 N,and obtains the minimum value at 1050℃,namely 8.60 N.The thermal compressive strength of CIPWB significantly depends on the temperature,reducing agent dosage,and pellet size.
基金Supported by Yunnan Major Scientific and Technological Projects(No.202403AA080001)National Natural Science Foundation of China(No.52074137)Yunnan Fundamental Research Projects(No.202201AT070151)。
文摘Three types of activators such as sodium hydroxide,calcium oxide and triethanolamine(TEA)are used to establish different activation environments to address the problems associated with the process of activating fly ash paste.We conducted mechanical tests and numerical simulations to understand the evolution of microstructure,and used environmental scanning electron microscopy(ESEM)and energy dispersive spectroscopy(EDS)techniques to analyze the microenvironments of the samples.The mechanical properties of fly ash paste under different activation conditions and the changes in the microstructure and composition were investigated.The results revealed that under conditions of low NaOH content(1%-3%),the strength of the sample increased significantly.When the content exceeded 4%,the rate of increase in strength decreased.Based on the results,the optimal NaOH content was identified,which was about 4%.A good activation effect,especially for short-term activation(3-7 d),was achieved using TEA under high doping conditions.The activation effect was poor for long-term strength after 28 days.The CaO content did not significantly affect the degree of activation achieved.The maximum effect was exerted when the content of CaO was 2%.The virtual cement and concrete testing laboratory(VCCTL)was used to simulate the hydration process,and the results revealed that the use of the three types of activators accelerated the formation of Ca(OH)_(2) in the system.The activators also corroded the surface of the fly ash particles,resulting in a pozzolanic reaction.The active substances in fly ash were released efficiently,and hydration was realized.The pores were filled with hydration products,and the microstructure changed to form a new frame of paste filling that helped improve the strength of fly ash paste.
基金Funded by the Natural Science Foundation of China(No.52109168)。
文摘In order to study the characteristics of pure fly ash-based geopolymer concrete(PFGC)conveniently,we used a machine learning method that can quantify the perception of characteristics to predict its compressive strength.In this study,505 groups of data were collected,and a new database of compressive strength of PFGC was constructed.In order to establish an accurate prediction model of compressive strength,five different types of machine learning networks were used for comparative analysis.The five machine learning models all showed good compressive strength prediction performance on PFGC.Among them,R2,MSE,RMSE and MAE of decision tree model(DT)are 0.99,1.58,1.25,and 0.25,respectively.While R2,MSE,RMSE and MAE of random forest model(RF)are 0.97,5.17,2.27 and 1.38,respectively.The two models have high prediction accuracy and outstanding generalization ability.In order to enhance the interpretability of model decision-making,we used importance ranking to obtain the perception of machine learning model to 13 variables.These 13 variables include chemical composition of fly ash(SiO_(2)/Al_(2)O_(3),Si/Al),the ratio of alkaline liquid to the binder,curing temperature,curing durations inside oven,fly ash dosage,fine aggregate dosage,coarse aggregate dosage,extra water dosage and sodium hydroxide dosage.Curing temperature,specimen ages and curing durations inside oven have the greatest influence on the prediction results,indicating that curing conditions have more prominent influence on the compressive strength of PFGC than ordinary Portland cement concrete.The importance of curing conditions of PFGC even exceeds that of the concrete mix proportion,due to the low reactivity of pure fly ash.
基金Funded by China National Key Research and Development Program for Application and Verification of Typical Groundwater Contaminated Sites(No.2019YFC1804805)Shenyang Key Laboratory of Safety Evaluation and Disaster Prevention of Engineering Structures(No.S230184)the Funding Project of Northeast Geological S&T Innovation Center of China Geological Survey(No.QCJJ2023-39)。
文摘Traditional machine learning(ML)encounters the challenge of parameter adjustment when predicting the compressive strength of reclaimed concrete.To address this issue,we introduce two optimized hybrid models:the Bayesian optimization model(B-RF)and the optimal model(Stacking model).These models are applied to a data set comprising 438 observations with five input variables,with the aim of predicting the compressive strength of reclaimed concrete.Furthermore,we evaluate the performance of the optimized models in comparison to traditional machine learning models,such as support vector regression(SVR),decision tree(DT),and random forest(RF).The results reveal that the Stacking model exhibits superior predictive performance,with evaluation indices including R2=0.825,MAE=2.818 and MSE=14.265,surpassing the traditional models.Moreover,we also performed a characteristic importance analysis on the input variables,and we concluded that cement had the greatest influence on the compressive strength of reclaimed concrete,followed by water.Therefore,the Stacking model can be recommended as a compressive strength prediction tool to partially replace laboratory compressive strength testing,resulting in time and cost savings.
文摘Introduction It is necessary for an ideal bioceramic scaffold to have a suitable structure.The structure can affect the mechanical properties of the scaffold(i.e.,elastic modulus and compressive strength)and the biological properties of the scaffold(i.e.,degradability and cell growth rate).Lattice structure is a kind of periodic porous structure,which has some advantages of light weight and high strength,and is widely used in the preparation of bioceramic scaffolders.For the structure of the scaffold,high porosity and large pore size are important for bone growth,bone integration and promoting good mechanical interlocking between neighboring bones and the scaffold.However,scaffolds with a high porosity often lack mechanical strength.In addition,different parts of the bone have different structural requirements.In this paper,scaffolds with a non-uniform structure or a hierarchical structure were designed,with loose and porous exterior to facilitate cell adhesion,osteogenic differentiation and vascularization as well as relatively dense interior to provide sufficient mechanical support for bone repair.Methods In this work,composite ceramics scaffolds with 10%akermanite content were prepared by DLP technology.The scaffold had a high porosity outside to promote the growth of bone tissue,and a low porosity inside to withstand external forces.The compressive strength,fracture form,in-vitro degradation performance and bioactivity of graded bioceramic scaffolds were investigated.The models of scaffolds were imported into the DLP printer with a 405 nm light.The samples were printed with the intensity of 8 mJ/cm^(2)and a layer thickness of 50μm.Finally,the ceramic samples were sintered at 1100℃.The degradability of the hierarchical gyroid bioceramic scaffolds was evaluated through immersion in Tris-HCl solution and SBF solution at a ratio of 200 mL/g.The bioactivity of bioceramic was obtained via immersing them in SBF solution for two weeks.The concentrations of calcium,phosphate,silicon,and magnesium ions in the soaking solution were determined by an inductively coupled plasma optical emission spectrometer.Results and discussion In this work,a hierarchical Gyroid structure HA-AK10 scaffold(sintered at 1100℃)with a radial internal porosity of 50%and an external porosity of 70%is prepared,and the influence of structural form on the compressive strength and degradation performance of the scaffold is investigated.The biological activity of the bioceramics in vitro is also verified.The mechanical simulation results show that the stress distribution corresponds to the porosity distribution of the structure,and the low porosity is larger and the overall stress concentration phenomenon does not appear.After soaking in SBF solution,Si—OH is firstly formed on the surface of bioceramics,and then silicon gel layer is produced due to the presence of calcium and silicon ions.The silicon gel layer is dissociated into negatively charged groups under alkaline environment secondary adsorption of calcium ions and phosphate ions,forming amorphous calcium phosphate,and finally amorphous calcium phosphate crystals and adsorption of carbonate ions,forming carbonate hydroxyapatite.This indicates that the composite bioceramics have a good biological activity in-vitro and can provide a good environment for the growth of bone cells.A hierarchical Gyroid ceramic scaffold with a bone geometry is prepared via applying the hierarchical structure to the bone contour scaffold.The maximum load capacity of the hierarchical Gyroid ceramic scaffold is 8 times that of the uniform structure.Conclusions The hierarchical structure scaffold designed had good overall compressive performance,good degradation performance,and still maintained a good mechanical stability during degradation.In addition,in-vitro biological experimental results showed that the surface graded composite scaffold could have a good in-vitro biological activity and provide a good environment for bone cells.Compared to the heterosexual structure,the graded scaffold had greater mechanical properties.
