The effect of boron doping on the sensitivity to environmental embrittlement of Ni3Al-based alloys was investigated in this paper. The results show that the ductilizing effect of boron in Ni3Al is partly to suppress ...The effect of boron doping on the sensitivity to environmental embrittlement of Ni3Al-based alloys was investigated in this paper. The results show that the ductilizing effect of boron in Ni3Al is partly to suppress moisture-induced hydrogen embrittlement.The mechanism of this suppressing effect of boron relates to its severely decreasing the hydrogen diffusivity by boron segregated at the grain boundaries. The surface reaction of Fe3Al with water vapor and oxygen was experimentally confirmed by AES and XPS analysis. The kinetics of these reactions can be used to explain the different ductility behavior of aluminides in various environments.展开更多
文摘The effect of boron doping on the sensitivity to environmental embrittlement of Ni3Al-based alloys was investigated in this paper. The results show that the ductilizing effect of boron in Ni3Al is partly to suppress moisture-induced hydrogen embrittlement.The mechanism of this suppressing effect of boron relates to its severely decreasing the hydrogen diffusivity by boron segregated at the grain boundaries. The surface reaction of Fe3Al with water vapor and oxygen was experimentally confirmed by AES and XPS analysis. The kinetics of these reactions can be used to explain the different ductility behavior of aluminides in various environments.
