Bowen Wang Trinity College Dublin,Dublin,From ut pictura poesis to intermediality,the close,interactive,and complicated relationship between poetry and painting has been an inevitable subject under discussion througho...Bowen Wang Trinity College Dublin,Dublin,From ut pictura poesis to intermediality,the close,interactive,and complicated relationship between poetry and painting has been an inevitable subject under discussion throughout the historiography of literature and fine art.Different approaches and interpretations to/on their sisterhood could come to a broad spectrum of interartistic ideas and practices.William Blake,an English Romantic poet,painter,and printmaker,links word and image by his invention of relief etching,or more understandably,the illuminated painting which juxtaposes his verse with in-text illustrations simultaneously on the same page.His technical strategy has already implied a dynamic and dialectical interrelation between word and image,like the treatment of earlier medieval manuscripts,yet in a more innovative rather than decorative manner.This article,therefore,through a comparative analysis of both Blake’s verbal and visual representations,will first attempt to clarify two distinct modes of combining poetic language with visualisation vis-à-vis form and content,and then critically investigate how this word-image interaction can be used to reflect the poet’s Romantic thought about sociocultural changes and provide new possibilities of reading,interpretation,and aesthetic complexity in that specific epoch.展开更多
KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to eva...KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to evaluate the influence of varying hydrothermal synthesis temperatures on the physicochemical properties of both the KIT-5/Beta supports and the resulting catalysts.The catalytic performances of catalysts were evaluated under reaction conditions of 320℃,4 MPa H_(2)pressure,and a weight hourly space velocity(WHSV)of 4.8 h^(-1)for hydrodenitrogenation(HDN)of quinoline.The results indicated that the specific surface area and pore structure of the materials could be effectively regulated by adjusting the hydrothermal synthesis temperature,which in turn influenced the number of active sites on the catalyst.The NiW/KB-125 catalyst,synthesized at 125℃,presented the highest quinoline HDN efficiency(96.8%),which can be attributed to its favorable pore channel structure,greater Brønsted acid number,higher degree of metal sulfidation(80.12%)and appropriate metal-support interaction(MSI).展开更多
Magnetic Monopole SearchesIsolated supermassive monopole candidate events have not been confirmed. The most sensitive experiments obtain negative results.
Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the...Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.展开更多
In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires...In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires.Microstructure and property analyses in both the cold-drawn and annealed states show that the incorporation of graphene significantly improves the ductility and electrical conductivity of the copper wire.After annealing at 350℃ for 30 minutes,the composite wire demonstrates a tensile strength of 270 MPa and an electrical conductivity of 102.74%IACS,both superior to those of pure copper wire under identical conditions.At 150℃,the electrical conductivity of the annealed composite wire reaches 72.60%IACS,notably higher than the 68.19%IACS of pure copper.The results suggest that graphene is uniformly distributed within the composite wire,with minimal impact on conductivity,while effectively refining the copper grain structure to enhance ductility.Moreover,graphene suppresses copper lattice vibrations at elevated temperatures,reducing the rate of conductivity degradation.展开更多
Installing internal bulkheads in a composite bucket foundation alters the rotational symmetry characteristic of a single-compartment bucket foundation,consequently influencing the stress distribution within the bucket...Installing internal bulkheads in a composite bucket foundation alters the rotational symmetry characteristic of a single-compartment bucket foundation,consequently influencing the stress distribution within the bucket and surrounding soil.During the seabed penetration of a spudcan from a jack-up wind turbine installation vessel,an angle may form between the spudcan’s axis and the axis of symmetry of the adjacent composite bucket foundation in the horizontal plane.Such a misalignment may affect load distribution and the non-uniform interaction between the foundation,soil,and spudcan,ultimately influencing the foundation’s stability.This study employs physical model tests to ascertain the trends in end resistance during spudcan penetration in sand,the extent of soil disturbance,and the backflow condition.The finite element coupled Eulerian-Lagrangian method is validated and utilized to determine the range of penetration angles that induce alterations in the maximum vertical displacement and tilt rate of the composite bucket foundation in sand.The differential contact stress distribution at the base of the bucket is analyzed,with qualitative criteria for sand backflow provided.Findings demonstrate that the maximum vertical displacement and tilt rate of the composite bucket foundation display a“wave-like”variation with the increasing spudcan penetration angle,peaking when the angle between the spudcan and bulkhead is the smallest.Stress distribution is predominantly concentrated at the base and apex of the bucket,becoming increasingly uneven as the penetration angle deviates from the foundation’s symmetry axis.The maximum stress gradually shifts to the junction of the bulkhead and bucket bottom on the side with the shortest net distance from the spudcan.Considering the in-place stability and stress state of the composite bucket foundation is therefore imperative,and particular attention should be paid to the foundation’s state when the angle between the spudcan and bulkhead is small.展开更多
Nail changes following upper extremity transplantation(UET)cannot be overlooked as they possess diagnostic and prognostic relevance in allotransplantation of upper limbs.This comprehensive review explores nail and nai...Nail changes following upper extremity transplantation(UET)cannot be overlooked as they possess diagnostic and prognostic relevance in allotransplantation of upper limbs.This comprehensive review explores nail and nail bed related changes encountered in UET recipients in the literature.The differential diagnosis of nail abnormalities in UET includes a wide range of systemic,local and iatrogenic conditions other than immune responses to the allograft.It requires interdisciplinary evaluation by primary transplant surgeons,pathologists,dermatologists and immunologists.The possible underlying mechanisms of nail pathology in UET and the management are discussed.It also underscores the importance of onychodystrophy and need for timely intervention and to improve outcomes in UET recipients.展开更多
Pipelines are extensively used in environments such as nuclear power plants,chemical factories,and medical devices to transport gases and liquids.These tubular environments often feature complex geometries,confined sp...Pipelines are extensively used in environments such as nuclear power plants,chemical factories,and medical devices to transport gases and liquids.These tubular environments often feature complex geometries,confined spaces,and millimeter-scale height restrictions,presenting significant challenges to conventional inspection methods.Here,we present an ultrasonic microrobot(weight,80 mg;dimensions,24 mm×7 mm;thickness,210μm)to realize agile and bidirectional navigation in narrow pipelines.The ultrathin structural design of the robot is achieved through a high-performance piezoelectric composite film microstructure based on MEMS technology.The robot exhibits various vibration modes when driven by ultrasonic frequency signals,its motion speed reaches81 cm s-1 at 54.8 k Hz,exceeding that of the fastest piezoelectric microrobots,and its forward and backward motion direction is controllable through frequency modulation,while the minimum driving voltage for initial movement can be as low as 3 VP-P.Additionally,the robot can effortlessly climb slopes up to 24.25°and carry loads more than 36 times its weight.The robot is capable of agile navigation through curved L-shaped pipes,pipes made of various materials(acrylic,stainless steel,and polyvinyl chloride),and even over water.To further demonstrate its inspection capabilities,a micro-endoscope camera is integrated into the robot,enabling real-time image capture inside glass pipes.展开更多
Based on reanalysis data from 1979 to 2021,this study explores the spatial distribution of the Southern Indian Ocean Dipole(SIOD)and its individual and synergistic effects with the El Niño-Southern Oscillation(EN...Based on reanalysis data from 1979 to 2021,this study explores the spatial distribution of the Southern Indian Ocean Dipole(SIOD)and its individual and synergistic effects with the El Niño-Southern Oscillation(ENSO)on summer precipitation in China.The inverse phase spatial distribution of sea surface temperature anomalies(SSTAs)in the southwest and northeast of the southern Indian Ocean is defined as the SIOD.Positive SIOD events(positive SSTAs in the southwest,negative SSTAs in the northeast)are associated with La Niña events(Central Pacific(CP)type),while negative SIOD events(negative SSTAs in the southwest,positive SSTAs in the northeast)are associated with El Niño events(Eastern Pacific(EP)type).Both SIOD and ENSO have certain impacts on summer precipitation in China.Precipitation in the Yangtze River basin decreases,while precipitation in southern China increases during pure positive SIOD(P_PSIOD)events.During pure negative SIOD(P_NSIOD)events,the changes in precipitation are exactly the opposite of those during P_PSIOD events,which may be due to differences in the cross-equatorial flow in the southern Indian Ocean,particularly in low-level Australian cross-equatorial flow.When positive SIOD and CP-type La Niña events occur simultaneously(PSIOD+La_Niña),precipitation increases in the Yangtze-Huaihe River basin,while it decreases in northern China.When negative SIOD and EP-type El Niño events occur simultaneously(NSIOD+El_Niño),precipitation in the Yangtze-Huaihe River basin is significantly lower than during P_NSIOD events.This is caused by differences in water vapor originating from the Pacific Ocean during different events.展开更多
Monocolumn composite bucket foundation is a new type of offshore wind energy foundation.Its bearing characteristics under shallow bedrock conditions and complex geological conditions have not been extensively studied....Monocolumn composite bucket foundation is a new type of offshore wind energy foundation.Its bearing characteristics under shallow bedrock conditions and complex geological conditions have not been extensively studied.Therefore,to analyze its bearing characteristics under complex conditions-such as silty soil,chalky soil,and shallow bedrock-this paper employs finite element software to establish various soil combination scenarios.The load-displacement curves of the foundations under these scenarios are calculated to subsequently evaluate the horizontal ultimate bearing capacity.This study investigates the effects of shallow bedrock depth,the type of soil above the bedrock,the thickness of layered soil,and the quality of layered soil on the bearing characteristics of the monocolumn composite bucket foundation.Based on the principle of single-variable control,the ultimate bearing capacity characteristics of the foundation under different conditions are compared.The distribution of soil pressure inside and outside the bucket wall on the compressed side of the foundation,along with the plastic strain of the soil at the base of the foundation,is also analyzed.In conclusion,shallow bedrock somewhat reduces foundation bearing capacity.Under shallow bedrock conditions,the degree of influence on foundation bearing capacity characteristics can considerably vary on different upper soils.The thickness of each soil layer and the depth to bedrock in stratified soils also affect the bearing capacity of the foundation.The findings of this paper provide a theoretical reference for related foundation design and construction.In practice,the bearing performance of the foundation can be enhanced by improvingthe soil quality in the bucket,adjusting the penetration depth,adjusting the percentage of different types of soil layers in the bucket,and applying other technical construction methods.展开更多
Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler ...Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler metals is ever-increasing.It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals.This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals,formability and processability,and overall cost.The basic properties of brazing filler metals refer to their mechanical properties,physicochemical properties,electromagnetic properties,corrosion resistance,and the wettability and fluidity during brazing.The formability and processability of brazing filler metals include the processes of smelting and casting,extrusion,rolling,drawing and ring-making,as well as the processes of granulation,powder production,and the molding of amorphous and microcrystalline structures.The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost.Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators.Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators.Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals,and solid solution structures contribute to the formability.By employing the proposed design guidelines,typical Ag based,Cu based,Zn based brazing filler metals,and Sn based solders were designed and successfully applied in major scientific and engineering projects.展开更多
With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite h...With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.展开更多
This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),YGdTbDyHo.Results indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with t...This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),YGdTbDyHo.Results indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed homogeneously.Upon hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase precipitated.The alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period observed.The reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral interstices.These results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.展开更多
Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships w...Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships with antioxidant activity and oxidative stability,gas chromatography-mass spectrometry was performed to characterize the associated fatty acid profiles.The antioxidant activity of vegetable oils,based on their DPPH-scavenging capacity(expressed as IC_(50) values),was used to assess their impact on human health,and their oxidative stability was characterized by performing lipid oxidation analysis to determine the oxidative induction time of fats and oils.In addition,correlation analyses were performed to examine associations between the fatty acid composition of the oils and DPPH-scavenging capacity and oxidative stability.The results revealed that among the assessed oils,coffee seed oil has the highest saturated fatty acid content(355.10 mg/g),whereas Garddenia jaminoides oil has the highest unsaturated fatty acid content(844.84 mg/g).Coffee seed oil was also found have the lowest DPPH IC_(50) value(2.30 mg/mL)and the longest oxidation induction time(17.09 h).Correlation analysis revealed a significant linear relationship(P<0.05)between oxidative stability and unsaturated fatty acid content,with lower contents tending to be associated with better oxidative stability.The findings of this study provide reference data for the screening of functional edible vegetable oils.展开更多
Zirconium-titanium-steel composite plate with the size of 2500 mm×7800 mm×(3+0.7+22)mm was prepared by explosive welding+rolling method,and its properties were analyzed by ultrasonic nondestructive testing,p...Zirconium-titanium-steel composite plate with the size of 2500 mm×7800 mm×(3+0.7+22)mm was prepared by explosive welding+rolling method,and its properties were analyzed by ultrasonic nondestructive testing,phased array waveform shape,interface structure shape,electronic scanning,and mechanical property testing.Results show that the rolling temperature of zirconiumtitanium complex should be controlled at 760°C,and the rolling reduction of each pass should be controlled at 10%–25%.The explosive velocity to prepare zirconium-titanium-steel composite plates should be controlled at 2450–2500 m/s,the density should be 0.78 g/cm3,the stand-off height should be 12 mm,and the explosive height of Zone A and Zone B should be 45–50 mm.Explosive welding combined with rolling method reduces the impact of explosive welding and multiple heat treatment on material properties.Meanwhile,the problems of surface wrinkling and cracking,which occur during the preparation process of large-sized zirconiumtitanium-steel composite plate,can be solved.展开更多
Because of the challenge of compounding lightweight,high-strength Ti/Al alloys due to their considerable disparity in properties,Al 6063 as intermediate layer was proposed to fabricate TC4/Al 6063/Al 7075 three-layer ...Because of the challenge of compounding lightweight,high-strength Ti/Al alloys due to their considerable disparity in properties,Al 6063 as intermediate layer was proposed to fabricate TC4/Al 6063/Al 7075 three-layer composite plate by explosive welding.The microscopic properties of each bonding interface were elucidated through field emission scanning electron microscope and electron backscattered diffraction(EBSD).A methodology combining finite element method-smoothed particle hydrodynamics(FEM-SPH)and molecular dynamics(MD)was proposed for the analysis of the forming and evolution characteristics of explosive welding interfaces at multi-scale.The results demonstrate that the bonding interface morphologies of TC4/Al 6063 and Al 6063/Al 7075 exhibit a flat and wavy configuration,without discernible defects or cracks.The phenomenon of grain refinement is observed in the vicinity of the two bonding interfaces.Furthermore,the degree of plastic deformation of TC4 and Al 7075 is more pronounced than that of Al 6063 in the intermediate layer.The interface morphology characteristics obtained by FEM-SPH simulation exhibit a high degree of similarity to the experimental results.MD simulations reveal that the diffusion of interfacial elements predominantly occurs during the unloading phase,and the simulated thickness of interfacial diffusion aligns well with experimental outcomes.The introduction of intermediate layer in the explosive welding process can effectively produce high-quality titanium/aluminum alloy composite plates.Furthermore,this approach offers a multi-scale simulation strategy for the study of explosive welding bonding interfaces.展开更多
Latent heat thermal energy storage(TES)effectively reduces the mismatch between energy supply and demand of renewable energy sources by the utilization of phase change materials(PCMs).However,the low thermal conductiv...Latent heat thermal energy storage(TES)effectively reduces the mismatch between energy supply and demand of renewable energy sources by the utilization of phase change materials(PCMs).However,the low thermal conductivity and poor shape stability are the main drawbacks in realizing the large-scale application of PCMs.Promisingly,developing composite PCM(CPCM)based on porous supporting mate-rial provides a desirable solution to obtain performance-enhanced PCMs with improved effective thermal conductivity and shape stability.Among all the porous matrixes as supports for PCM,three-dimensional carbon-based porous supporting material has attracted considerable attention ascribing to its high ther-mal conductivity,desirable loading capacity of PCMs,and excellent chemical compatibility with various PCMs.Therefore,this work systemically reviews the CPCMs with three-dimensional carbon-based porous supporting materials.First,a concise rule for the fabrication of CPCMs is illustrated in detail.Next,the experimental and computational research of carbon nanotube-based support,graphene-based support,graphite-based support and amorphous carbon-based support are reviewed.Then,the applications of the shape-stabilized CPCMs including thermal management and thermal conversion are illustrated.Last but not least,the challenges and prospects of the CPCMs are discussed.To conclude,introducing carbon-based porous materials can solve the liquid leakage issue and essentially improve the thermal conductivity of PCMs.However,there is still a long way to further develop a desirable CPCM with higher latent heat capacity,higher thermal conductivity,and more excellent shape stability.展开更多
With the increasing complexity of the current electromagnetic environment,excessive microwave radi-ation not only does harm to human health but also forms various electromagnetic interference to so-phisticated electro...With the increasing complexity of the current electromagnetic environment,excessive microwave radi-ation not only does harm to human health but also forms various electromagnetic interference to so-phisticated electronic instruments.Therefore,the design and preparation of electromagnetic absorbing composites represent an efficient approach to mitigate the current hazards of electromagnetic radiation.However,traditional electromagnetic absorbers are difficult to satisfy the demands of actual utilization in the face of new challenges,and emerging absorbents have garnered increasing attention due to their structure and performance-based advantages.In this review,several emerging composites of Mxene-based,biochar-based,chiral,and heat-resisting are discussed in detail,including their synthetic strategy,structural superiority and regulation method,and final optimization of electromagnetic absorption ca-pacity.These insights provide a comprehensive reference for the future development of new-generation electromagnetic-wave absorption composites.Moreover,the potential development directions of these emerging absorbers have been proposed as well.展开更多
Improving the accuracy of anthropogenic volatile organic compounds(VOCs)emission inventory is crucial for reducing atmospheric pollution and formulating control policy of air pollution.In this study,an anthropogenic s...Improving the accuracy of anthropogenic volatile organic compounds(VOCs)emission inventory is crucial for reducing atmospheric pollution and formulating control policy of air pollution.In this study,an anthropogenic speciated VOCs emission inventory was established for Central China represented by Henan Province at a 3 km×3 km spatial resolution based on the emission factormethod.The 2019 VOCs emission in Henan Provincewas 1003.5 Gg,while industrial process source(33.7%)was the highest emission source,Zhengzhou(17.9%)was the city with highest emission and April and August were the months with the more emissions.High VOCs emission regions were concentrated in downtown areas and industrial parks.Alkanes and aromatic hydrocarbons were the main VOCs contribution groups.The species composition,source contribution and spatial distribution were verified and evaluated through tracer ratio method(TR),Positive Matrix Factorization Model(PMF)and remote sensing inversion(RSI).Results show that both the emission results by emission inventory(EI)(15.7 Gg)and by TRmethod(13.6 Gg)and source contribution by EI and PMF are familiar.The spatial distribution of HCHO primary emission based on RSI is basically consistent with that of HCHO emission based on EI with a R-value of 0.73.The verification results show that the VOCs emission inventory and speciated emission inventory established in this study are relatively reliable.展开更多
SiC_(f)/SiC ceramic matrix composites(SiC_(f)/SiC composites)are difficult to drill small holes due to their heterogeneity,high hardness,and low electrical conductivity.In order to solve the difficulties of poor quali...SiC_(f)/SiC ceramic matrix composites(SiC_(f)/SiC composites)are difficult to drill small holes due to their heterogeneity,high hardness,and low electrical conductivity.In order to solve the difficulties of poor quality and low efficiency when drilling small holes,a novel femtosecond laser rotary drilling(FLRD)technique is proposed.Beam kinematic paths and experimental studies were carried out to analyze the effects of processing parameters on the drilling results in the two-step drilling process.In the through-hole drilling stage,the material removal rate increases with increasing laser power,decreasing feed speed and decreasing pitch.As for the finishing stage of drilling,the exit diameter increased with increasing laser power and decreasing feed speed.The drilling parameters were selected by taking the processing efficiency of through-hole and the quality of finished hole as the constraint criteria.Holes with a diameter of 500μm were drilled using FLRD in 3 mm thick SiC_(f)/SiC composites with a drilling time<150 s.The hole aspect ratio was 6,the taper<0.2°,and there was no significant thermal damage at the orifice or the wall of the hole.The FLRD provides a solution for precision machining of small holes in difficult-to-machine materials by offering the advantages of high processing quality and short drilling times.展开更多
文摘Bowen Wang Trinity College Dublin,Dublin,From ut pictura poesis to intermediality,the close,interactive,and complicated relationship between poetry and painting has been an inevitable subject under discussion throughout the historiography of literature and fine art.Different approaches and interpretations to/on their sisterhood could come to a broad spectrum of interartistic ideas and practices.William Blake,an English Romantic poet,painter,and printmaker,links word and image by his invention of relief etching,or more understandably,the illuminated painting which juxtaposes his verse with in-text illustrations simultaneously on the same page.His technical strategy has already implied a dynamic and dialectical interrelation between word and image,like the treatment of earlier medieval manuscripts,yet in a more innovative rather than decorative manner.This article,therefore,through a comparative analysis of both Blake’s verbal and visual representations,will first attempt to clarify two distinct modes of combining poetic language with visualisation vis-à-vis form and content,and then critically investigate how this word-image interaction can be used to reflect the poet’s Romantic thought about sociocultural changes and provide new possibilities of reading,interpretation,and aesthetic complexity in that specific epoch.
基金Supported by the Autonomous Research Project of SKLCC(2024BWZ003)Strategic Priority Research Program of the Chinese Academy of Sciences(XDA0390401)the Doctoral Research Start-up Funding of Shanxi Institute of Technology(026012).
文摘KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to evaluate the influence of varying hydrothermal synthesis temperatures on the physicochemical properties of both the KIT-5/Beta supports and the resulting catalysts.The catalytic performances of catalysts were evaluated under reaction conditions of 320℃,4 MPa H_(2)pressure,and a weight hourly space velocity(WHSV)of 4.8 h^(-1)for hydrodenitrogenation(HDN)of quinoline.The results indicated that the specific surface area and pore structure of the materials could be effectively regulated by adjusting the hydrothermal synthesis temperature,which in turn influenced the number of active sites on the catalyst.The NiW/KB-125 catalyst,synthesized at 125℃,presented the highest quinoline HDN efficiency(96.8%),which can be attributed to its favorable pore channel structure,greater Brønsted acid number,higher degree of metal sulfidation(80.12%)and appropriate metal-support interaction(MSI).
文摘Magnetic Monopole SearchesIsolated supermassive monopole candidate events have not been confirmed. The most sensitive experiments obtain negative results.
基金support provided by the Center for Fabrication and Application of Electronic Materials at Dokuz Eylül University,Türkiye。
文摘Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.
基金Funded by Hunan Provincial Natural Science Foundation(No.2023JJ40074)Hunan Provincial Education Department Excellent Youth Project(No.21B0757)Hunan Provincial Engineering Technology Center(No.2022TP2036)。
文摘In this study,multilayer lamination welding was employed to prepare graphene/copper(Gr/Cu)composite billets from graphene-coated copper foils,followed by multi-pass cold drawing to produce Φ1 mm Gr/Cu composite wires.Microstructure and property analyses in both the cold-drawn and annealed states show that the incorporation of graphene significantly improves the ductility and electrical conductivity of the copper wire.After annealing at 350℃ for 30 minutes,the composite wire demonstrates a tensile strength of 270 MPa and an electrical conductivity of 102.74%IACS,both superior to those of pure copper wire under identical conditions.At 150℃,the electrical conductivity of the annealed composite wire reaches 72.60%IACS,notably higher than the 68.19%IACS of pure copper.The results suggest that graphene is uniformly distributed within the composite wire,with minimal impact on conductivity,while effectively refining the copper grain structure to enhance ductility.Moreover,graphene suppresses copper lattice vibrations at elevated temperatures,reducing the rate of conductivity degradation.
文摘Installing internal bulkheads in a composite bucket foundation alters the rotational symmetry characteristic of a single-compartment bucket foundation,consequently influencing the stress distribution within the bucket and surrounding soil.During the seabed penetration of a spudcan from a jack-up wind turbine installation vessel,an angle may form between the spudcan’s axis and the axis of symmetry of the adjacent composite bucket foundation in the horizontal plane.Such a misalignment may affect load distribution and the non-uniform interaction between the foundation,soil,and spudcan,ultimately influencing the foundation’s stability.This study employs physical model tests to ascertain the trends in end resistance during spudcan penetration in sand,the extent of soil disturbance,and the backflow condition.The finite element coupled Eulerian-Lagrangian method is validated and utilized to determine the range of penetration angles that induce alterations in the maximum vertical displacement and tilt rate of the composite bucket foundation in sand.The differential contact stress distribution at the base of the bucket is analyzed,with qualitative criteria for sand backflow provided.Findings demonstrate that the maximum vertical displacement and tilt rate of the composite bucket foundation display a“wave-like”variation with the increasing spudcan penetration angle,peaking when the angle between the spudcan and bulkhead is the smallest.Stress distribution is predominantly concentrated at the base and apex of the bucket,becoming increasingly uneven as the penetration angle deviates from the foundation’s symmetry axis.The maximum stress gradually shifts to the junction of the bulkhead and bucket bottom on the side with the shortest net distance from the spudcan.Considering the in-place stability and stress state of the composite bucket foundation is therefore imperative,and particular attention should be paid to the foundation’s state when the angle between the spudcan and bulkhead is small.
文摘Nail changes following upper extremity transplantation(UET)cannot be overlooked as they possess diagnostic and prognostic relevance in allotransplantation of upper limbs.This comprehensive review explores nail and nail bed related changes encountered in UET recipients in the literature.The differential diagnosis of nail abnormalities in UET includes a wide range of systemic,local and iatrogenic conditions other than immune responses to the allograft.It requires interdisciplinary evaluation by primary transplant surgeons,pathologists,dermatologists and immunologists.The possible underlying mechanisms of nail pathology in UET and the management are discussed.It also underscores the importance of onychodystrophy and need for timely intervention and to improve outcomes in UET recipients.
基金supported by the National Key Research and Development Program of China(No.2024YFB3212901)National Natural Science Foundation of China(12072189)the Medicine and Engineering Interdisciplinary Research Fund of Shanghai Jiao Tong University(No.YG2025ZD05)。
文摘Pipelines are extensively used in environments such as nuclear power plants,chemical factories,and medical devices to transport gases and liquids.These tubular environments often feature complex geometries,confined spaces,and millimeter-scale height restrictions,presenting significant challenges to conventional inspection methods.Here,we present an ultrasonic microrobot(weight,80 mg;dimensions,24 mm×7 mm;thickness,210μm)to realize agile and bidirectional navigation in narrow pipelines.The ultrathin structural design of the robot is achieved through a high-performance piezoelectric composite film microstructure based on MEMS technology.The robot exhibits various vibration modes when driven by ultrasonic frequency signals,its motion speed reaches81 cm s-1 at 54.8 k Hz,exceeding that of the fastest piezoelectric microrobots,and its forward and backward motion direction is controllable through frequency modulation,while the minimum driving voltage for initial movement can be as low as 3 VP-P.Additionally,the robot can effortlessly climb slopes up to 24.25°and carry loads more than 36 times its weight.The robot is capable of agile navigation through curved L-shaped pipes,pipes made of various materials(acrylic,stainless steel,and polyvinyl chloride),and even over water.To further demonstrate its inspection capabilities,a micro-endoscope camera is integrated into the robot,enabling real-time image capture inside glass pipes.
基金supported by the National Natural Science Foundation of China[grant numbers 41975087,U2242212,and 41975085]supported by the National Natural Science Foundation of China[grant number U2242212]。
文摘Based on reanalysis data from 1979 to 2021,this study explores the spatial distribution of the Southern Indian Ocean Dipole(SIOD)and its individual and synergistic effects with the El Niño-Southern Oscillation(ENSO)on summer precipitation in China.The inverse phase spatial distribution of sea surface temperature anomalies(SSTAs)in the southwest and northeast of the southern Indian Ocean is defined as the SIOD.Positive SIOD events(positive SSTAs in the southwest,negative SSTAs in the northeast)are associated with La Niña events(Central Pacific(CP)type),while negative SIOD events(negative SSTAs in the southwest,positive SSTAs in the northeast)are associated with El Niño events(Eastern Pacific(EP)type).Both SIOD and ENSO have certain impacts on summer precipitation in China.Precipitation in the Yangtze River basin decreases,while precipitation in southern China increases during pure positive SIOD(P_PSIOD)events.During pure negative SIOD(P_NSIOD)events,the changes in precipitation are exactly the opposite of those during P_PSIOD events,which may be due to differences in the cross-equatorial flow in the southern Indian Ocean,particularly in low-level Australian cross-equatorial flow.When positive SIOD and CP-type La Niña events occur simultaneously(PSIOD+La_Niña),precipitation increases in the Yangtze-Huaihe River basin,while it decreases in northern China.When negative SIOD and EP-type El Niño events occur simultaneously(NSIOD+El_Niño),precipitation in the Yangtze-Huaihe River basin is significantly lower than during P_NSIOD events.This is caused by differences in water vapor originating from the Pacific Ocean during different events.
文摘Monocolumn composite bucket foundation is a new type of offshore wind energy foundation.Its bearing characteristics under shallow bedrock conditions and complex geological conditions have not been extensively studied.Therefore,to analyze its bearing characteristics under complex conditions-such as silty soil,chalky soil,and shallow bedrock-this paper employs finite element software to establish various soil combination scenarios.The load-displacement curves of the foundations under these scenarios are calculated to subsequently evaluate the horizontal ultimate bearing capacity.This study investigates the effects of shallow bedrock depth,the type of soil above the bedrock,the thickness of layered soil,and the quality of layered soil on the bearing characteristics of the monocolumn composite bucket foundation.Based on the principle of single-variable control,the ultimate bearing capacity characteristics of the foundation under different conditions are compared.The distribution of soil pressure inside and outside the bucket wall on the compressed side of the foundation,along with the plastic strain of the soil at the base of the foundation,is also analyzed.In conclusion,shallow bedrock somewhat reduces foundation bearing capacity.Under shallow bedrock conditions,the degree of influence on foundation bearing capacity characteristics can considerably vary on different upper soils.The thickness of each soil layer and the depth to bedrock in stratified soils also affect the bearing capacity of the foundation.The findings of this paper provide a theoretical reference for related foundation design and construction.In practice,the bearing performance of the foundation can be enhanced by improvingthe soil quality in the bucket,adjusting the penetration depth,adjusting the percentage of different types of soil layers in the bucket,and applying other technical construction methods.
基金National Natural Science Foundation of China(U22A20191)。
文摘Brazing filler metals are widely applied,which serve as an industrial adhesive in the joining of dissimilar structures.With the continuous emergence of new structures and materials,the demand for novel brazing filler metals is ever-increasing.It is of great significance to investigate the optimized composition design methods and to establish systematic design guidelines for brazing filler metals.This study elucidated the fundamental rules for the composition design of brazing filler metals from a three-dimensional perspective encompassing the basic properties of applied brazing filler metals,formability and processability,and overall cost.The basic properties of brazing filler metals refer to their mechanical properties,physicochemical properties,electromagnetic properties,corrosion resistance,and the wettability and fluidity during brazing.The formability and processability of brazing filler metals include the processes of smelting and casting,extrusion,rolling,drawing and ring-making,as well as the processes of granulation,powder production,and the molding of amorphous and microcrystalline structures.The cost of brazing filler metals corresponds to the sum of materials value and manufacturing cost.Improving the comprehensive properties of brazing filler metals requires a comprehensive and systematic consideration of design indicators.Highlighting the unique characteristics of brazing filler metals should focus on relevant technical indicators.Binary or ternary eutectic structures can effectively enhance the flow spreading ability of brazing filler metals,and solid solution structures contribute to the formability.By employing the proposed design guidelines,typical Ag based,Cu based,Zn based brazing filler metals,and Sn based solders were designed and successfully applied in major scientific and engineering projects.
基金sponsored by National Natural Science Foundation of China(No.52302121,No.52203386)Shanghai Sailing Program(No.23YF1454700)+1 种基金Shanghai Natural Science Foundation(No.23ZR1472700)Shanghai Post-doctoral Excellent Program(No.2022664).
文摘With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.
基金financially supported by the National Natural Science Foundation of China(Nos.21171018 and 51271021)the State Key Laboratory for Advanced Metals and Materials。
文摘This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),YGdTbDyHo.Results indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed homogeneously.Upon hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase precipitated.The alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period observed.The reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral interstices.These results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.
文摘Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships with antioxidant activity and oxidative stability,gas chromatography-mass spectrometry was performed to characterize the associated fatty acid profiles.The antioxidant activity of vegetable oils,based on their DPPH-scavenging capacity(expressed as IC_(50) values),was used to assess their impact on human health,and their oxidative stability was characterized by performing lipid oxidation analysis to determine the oxidative induction time of fats and oils.In addition,correlation analyses were performed to examine associations between the fatty acid composition of the oils and DPPH-scavenging capacity and oxidative stability.The results revealed that among the assessed oils,coffee seed oil has the highest saturated fatty acid content(355.10 mg/g),whereas Garddenia jaminoides oil has the highest unsaturated fatty acid content(844.84 mg/g).Coffee seed oil was also found have the lowest DPPH IC_(50) value(2.30 mg/mL)and the longest oxidation induction time(17.09 h).Correlation analysis revealed a significant linear relationship(P<0.05)between oxidative stability and unsaturated fatty acid content,with lower contents tending to be associated with better oxidative stability.The findings of this study provide reference data for the screening of functional edible vegetable oils.
基金Key R&D Plan of Shaanxi Province(2021LLRH-05-09)Shaanxi Province Youth Talent Support Program Project(CLGC202234)Sponsored by Innovative Pilot Platform for Layered Metal Composite Materials(2024CX-GXPT-20)。
文摘Zirconium-titanium-steel composite plate with the size of 2500 mm×7800 mm×(3+0.7+22)mm was prepared by explosive welding+rolling method,and its properties were analyzed by ultrasonic nondestructive testing,phased array waveform shape,interface structure shape,electronic scanning,and mechanical property testing.Results show that the rolling temperature of zirconiumtitanium complex should be controlled at 760°C,and the rolling reduction of each pass should be controlled at 10%–25%.The explosive velocity to prepare zirconium-titanium-steel composite plates should be controlled at 2450–2500 m/s,the density should be 0.78 g/cm3,the stand-off height should be 12 mm,and the explosive height of Zone A and Zone B should be 45–50 mm.Explosive welding combined with rolling method reduces the impact of explosive welding and multiple heat treatment on material properties.Meanwhile,the problems of surface wrinkling and cracking,which occur during the preparation process of large-sized zirconiumtitanium-steel composite plate,can be solved.
基金Opening Foundation of Key Laboratory of Explosive Energy Utilization and Control,Anhui Province(BP20240104)Graduate Innovation Program of China University of Mining and Technology(2024WLJCRCZL049)Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX24_2701)。
文摘Because of the challenge of compounding lightweight,high-strength Ti/Al alloys due to their considerable disparity in properties,Al 6063 as intermediate layer was proposed to fabricate TC4/Al 6063/Al 7075 three-layer composite plate by explosive welding.The microscopic properties of each bonding interface were elucidated through field emission scanning electron microscope and electron backscattered diffraction(EBSD).A methodology combining finite element method-smoothed particle hydrodynamics(FEM-SPH)and molecular dynamics(MD)was proposed for the analysis of the forming and evolution characteristics of explosive welding interfaces at multi-scale.The results demonstrate that the bonding interface morphologies of TC4/Al 6063 and Al 6063/Al 7075 exhibit a flat and wavy configuration,without discernible defects or cracks.The phenomenon of grain refinement is observed in the vicinity of the two bonding interfaces.Furthermore,the degree of plastic deformation of TC4 and Al 7075 is more pronounced than that of Al 6063 in the intermediate layer.The interface morphology characteristics obtained by FEM-SPH simulation exhibit a high degree of similarity to the experimental results.MD simulations reveal that the diffusion of interfacial elements predominantly occurs during the unloading phase,and the simulated thickness of interfacial diffusion aligns well with experimental outcomes.The introduction of intermediate layer in the explosive welding process can effectively produce high-quality titanium/aluminum alloy composite plates.Furthermore,this approach offers a multi-scale simulation strategy for the study of explosive welding bonding interfaces.
基金supported by the National Natural Science Foundation of China(No.52127816),the National Key Research and Development Program of China(No.2020YFA0715000)the National Natural Science and Hong Kong Research Grant Council Joint Research Funding Project of China(No.5181101182)the NSFC/RGC Joint Research Scheme sponsored by the Research Grants Council of Hong Kong and the National Natural Science Foundation of China(No.N_PolyU513/18).
文摘Latent heat thermal energy storage(TES)effectively reduces the mismatch between energy supply and demand of renewable energy sources by the utilization of phase change materials(PCMs).However,the low thermal conductivity and poor shape stability are the main drawbacks in realizing the large-scale application of PCMs.Promisingly,developing composite PCM(CPCM)based on porous supporting mate-rial provides a desirable solution to obtain performance-enhanced PCMs with improved effective thermal conductivity and shape stability.Among all the porous matrixes as supports for PCM,three-dimensional carbon-based porous supporting material has attracted considerable attention ascribing to its high ther-mal conductivity,desirable loading capacity of PCMs,and excellent chemical compatibility with various PCMs.Therefore,this work systemically reviews the CPCMs with three-dimensional carbon-based porous supporting materials.First,a concise rule for the fabrication of CPCMs is illustrated in detail.Next,the experimental and computational research of carbon nanotube-based support,graphene-based support,graphite-based support and amorphous carbon-based support are reviewed.Then,the applications of the shape-stabilized CPCMs including thermal management and thermal conversion are illustrated.Last but not least,the challenges and prospects of the CPCMs are discussed.To conclude,introducing carbon-based porous materials can solve the liquid leakage issue and essentially improve the thermal conductivity of PCMs.However,there is still a long way to further develop a desirable CPCM with higher latent heat capacity,higher thermal conductivity,and more excellent shape stability.
基金supported by the Surface Project of Local De-velopment in Science and Technology Guided by Central Govern-ment(No.2021ZYD0041)the National Natural Science Founda-tion of China(Nos.52377026 and 52301192)+3 种基金the Natural Science Foundation of Shandong Province(No.ZR2019YQ24)the Taishan Scholars and Young Experts Program of Shandong Province(No.tsqn202103057)the Special Financial of Shandong Province(Struc-tural Design of High-efficiency Electromagnetic Wave-absorbing Composite Materials and Construction of Shandong Provincial Tal-ent Teams)the“Sanqin Scholars”Innovation Teams Project of Shaanxi Province(Clean Energy Materials and High-Performance Devices Innovation Team of Shaanxi Dongling Smelting Co.,Ltd.).
文摘With the increasing complexity of the current electromagnetic environment,excessive microwave radi-ation not only does harm to human health but also forms various electromagnetic interference to so-phisticated electronic instruments.Therefore,the design and preparation of electromagnetic absorbing composites represent an efficient approach to mitigate the current hazards of electromagnetic radiation.However,traditional electromagnetic absorbers are difficult to satisfy the demands of actual utilization in the face of new challenges,and emerging absorbents have garnered increasing attention due to their structure and performance-based advantages.In this review,several emerging composites of Mxene-based,biochar-based,chiral,and heat-resisting are discussed in detail,including their synthetic strategy,structural superiority and regulation method,and final optimization of electromagnetic absorption ca-pacity.These insights provide a comprehensive reference for the future development of new-generation electromagnetic-wave absorption composites.Moreover,the potential development directions of these emerging absorbers have been proposed as well.
基金supported by Zhengzhou PM_(2.5)and O_(3)Collaborative Control and Monitoring Project(No.20220347A)the 2020 National Supercomputing Zhengzhou Center Innovation Ecosystem Construction Technology Project(No.201400210700).
文摘Improving the accuracy of anthropogenic volatile organic compounds(VOCs)emission inventory is crucial for reducing atmospheric pollution and formulating control policy of air pollution.In this study,an anthropogenic speciated VOCs emission inventory was established for Central China represented by Henan Province at a 3 km×3 km spatial resolution based on the emission factormethod.The 2019 VOCs emission in Henan Provincewas 1003.5 Gg,while industrial process source(33.7%)was the highest emission source,Zhengzhou(17.9%)was the city with highest emission and April and August were the months with the more emissions.High VOCs emission regions were concentrated in downtown areas and industrial parks.Alkanes and aromatic hydrocarbons were the main VOCs contribution groups.The species composition,source contribution and spatial distribution were verified and evaluated through tracer ratio method(TR),Positive Matrix Factorization Model(PMF)and remote sensing inversion(RSI).Results show that both the emission results by emission inventory(EI)(15.7 Gg)and by TRmethod(13.6 Gg)and source contribution by EI and PMF are familiar.The spatial distribution of HCHO primary emission based on RSI is basically consistent with that of HCHO emission based on EI with a R-value of 0.73.The verification results show that the VOCs emission inventory and speciated emission inventory established in this study are relatively reliable.
基金the support of the Xingliao Talent Program of Liaoning Province(No.XLYC2001004)the High Level Talents Innovation Plan of Dalian(No.2020RD02)the Fundamental Research Funds for the Central Universities(No.DUT22LAB501).
文摘SiC_(f)/SiC ceramic matrix composites(SiC_(f)/SiC composites)are difficult to drill small holes due to their heterogeneity,high hardness,and low electrical conductivity.In order to solve the difficulties of poor quality and low efficiency when drilling small holes,a novel femtosecond laser rotary drilling(FLRD)technique is proposed.Beam kinematic paths and experimental studies were carried out to analyze the effects of processing parameters on the drilling results in the two-step drilling process.In the through-hole drilling stage,the material removal rate increases with increasing laser power,decreasing feed speed and decreasing pitch.As for the finishing stage of drilling,the exit diameter increased with increasing laser power and decreasing feed speed.The drilling parameters were selected by taking the processing efficiency of through-hole and the quality of finished hole as the constraint criteria.Holes with a diameter of 500μm were drilled using FLRD in 3 mm thick SiC_(f)/SiC composites with a drilling time<150 s.The hole aspect ratio was 6,the taper<0.2°,and there was no significant thermal damage at the orifice or the wall of the hole.The FLRD provides a solution for precision machining of small holes in difficult-to-machine materials by offering the advantages of high processing quality and short drilling times.