Herein,CdS@H_(0.95)MoO_(3)(L-CMx)composites with a core-shell structure were obtained through a solvothermal method combined with photo-reduction.Experimental results indicate that the photoreduction treatment will ge...Herein,CdS@H_(0.95)MoO_(3)(L-CMx)composites with a core-shell structure were obtained through a solvothermal method combined with photo-reduction.Experimental results indicate that the photoreduction treatment will generate a large number of Mo^(4+)ions inside the composite,and the appearance of Mo^(4+)greatly increases the concentration of free electrons in the composite.Moreover,DFT calculations show that abundant Mo^(4+)ions can enhance the metallic properties of the material.展开更多
基金supported by the link project of the National Natural Science Foundation of China(51772158)the Basic Research Expenses of Universities Directly under the Autonomous Region(JY20220231 and JY20220073)。
文摘Herein,CdS@H_(0.95)MoO_(3)(L-CMx)composites with a core-shell structure were obtained through a solvothermal method combined with photo-reduction.Experimental results indicate that the photoreduction treatment will generate a large number of Mo^(4+)ions inside the composite,and the appearance of Mo^(4+)greatly increases the concentration of free electrons in the composite.Moreover,DFT calculations show that abundant Mo^(4+)ions can enhance the metallic properties of the material.
