Anode active materials involving transition metal oxides and sulfides are of great significance for high energy density lithium-ion batteries(LIBs),but the huge volume expansion and inferior electronic conductivity up...Anode active materials involving transition metal oxides and sulfides are of great significance for high energy density lithium-ion batteries(LIBs),but the huge volume expansion and inferior electronic conductivity upon cycling critically constrain their further application.Herein,from a new perspective,a highly conductive and stable 3D flexible composite current collector is rationally designed by facilely electrodepositing metallic Ni thin layer onto the carbon cloth(CC/Ni),which endows the supported active materials with exceptional electronic conductivity and structural stability.In addition,the homogeneously distributed metallic Ni protrusions external CC can strongly bond with the active components,ensuring the structural integrity of electrodes upon cycling.More importantly,the 3D network structure with large specific surface area provides abundant space to alleviate the volume expansion and more active sites for electrochemical reactions.Therefore,taking Ni_(3)S_(2)nanosheet(Ni_(3)S_(2)NS)anode as an example,the prepared Ni_(3)S_(2)NS@CC/Ni electrode shows a high specific capacity of 2.32 mAh/cm^(2)at 1mA/cm^(2)and high capacity retention of 1.68 mAh/cm^(2)at a high rate of 8mA/cm^(2).This study provides a universal approach to obtain highly conductive and stable 3D flexible current collectors towards high performance metal-ion batteries beyond LIBs.展开更多
Two Al2O3/Cu composites containing 0.24 wt.% Al2O3 and 0.60 wt.% Al2O3 separately are prepared by internal oxidation. Effects of sliding speed and pressure on the frictional characteristics of the composites and coppe...Two Al2O3/Cu composites containing 0.24 wt.% Al2O3 and 0.60 wt.% Al2O3 separately are prepared by internal oxidation. Effects of sliding speed and pressure on the frictional characteristics of the composites and copper against brass are investigated and compared. The changes in morphology of the sliding surface and subsurface are examined with scanning electron microscope （SEM） and energy dispersive X-ray spectrum （EDS）. The results show that the wear resistance of the Al2O3/Cu composites is superior to that of copper under the same conditions, Under a given electrical current, the wear rate of Al2O3/Cu composites decreases as the Al2O3-content increases, However, the wear rates of the Al2O3/Cu composites and copper increase as the sliding speed and pressure increase under dry sliding condition. The main wear mechanisms for Al2O3/Cu composites are of abrasion and adhesion; for copper, it is adhesion, although wear by oxidation and electrical erosion can also be observed as the speed and pressure rise.展开更多
Cu matrix composite reinforced with 10%（volume fraction） carbon nanotubes（CNTs/Cu） and pure Cu bulk were prepared by powder metallurgy techniques under the same consolidation processing condition.The effect of ele...Cu matrix composite reinforced with 10%（volume fraction） carbon nanotubes（CNTs/Cu） and pure Cu bulk were prepared by powder metallurgy techniques under the same consolidation processing condition.The effect of electrical current on tribological property of the materials was investigated by using a pin-on-disk friction and wear tester.The results show that the friction coefficient and wear rate of CNTs/Cu composite as well as those of pure Cu bulk increase with increasing the electrical current without exception,and the effect of electrical current is more obvious on tribological property of pure Cu bulk than on that of CNTs/Cu composite;the dominant wear mechanisms are arc erosion wear and plastic flow deformation,respectively;CNTs can improve tribological property of Cu matrix composites with electrical current.展开更多
The effects of current pulsing on the microstructure, hardness and tensile properties at different temperatures of gas tungsten arc （GTA） weldments of titanium matrix composites were studied. Full-penetration butt j...The effects of current pulsing on the microstructure, hardness and tensile properties at different temperatures of gas tungsten arc （GTA） weldments of titanium matrix composites were studied. Full-penetration butt joints were made with or without current pulsing. Optical microscopy, hardness test and scanning electron microscopy were employed to evaluate the metallurgical characteristics of welded joints. Tensile properties of weldments at different temperatures were studied and correlated with the microstructure. The results exhibit that current pulsing leads to the refinement of the weld microstrucmre and TiB whisker and the redistribution of reinforcements resulting in higher hardness, tensile strength and ductility of weldments in the as-welded condition.展开更多
Al/conductive coating/α-Pb O2-Ce O2-Ti O2/β-PbO 2-MnO 2-WC-Zr O2 composite electrode material was prepared on Al/conductive coating/α-PbO 2-Ce O2-Ti O2 substrate by electrochemical oxidation co-deposition technique...Al/conductive coating/α-Pb O2-Ce O2-Ti O2/β-PbO 2-MnO 2-WC-Zr O2 composite electrode material was prepared on Al/conductive coating/α-PbO 2-Ce O2-Ti O2 substrate by electrochemical oxidation co-deposition technique. The effects of current density on the chemical composition, electrocatalytic activity, and stability of the composite anode material were investigated by energy dispersive X-ray spectroscopy（EDXS）, anode polarization curves, quasi-stationary polarization（Tafel） curves, electrochemical impedance spectroscopy（EIS）, scanning electron microscopy（SEM）, and X-ray diffraction（XRD）. Results reveal that the composite electrode obtained at 1 A/dm2 possesses the lowest overpotential（0.610 V at 500 A/m2） for oxygen evolution, the best electrocatalytic activity, the longest service life（360 h at 40 °C in 150 g/L H2SO4 solution under 2 A/cm2）, and the lowest cell voltage（2.75 V at 500 A/m2）. Furthermore, with increasing current density, the coating exhibits grain growth and the decrease of content of Mn O2. Only a slight effect on crystalline structure is observed.展开更多
CNTs-Cu and graphite-Cu composites were separately prepared by powder metallurgy technique under the same consolidation processing. Tribological behavior of the composites with electric current was investigated by usi...CNTs-Cu and graphite-Cu composites were separately prepared by powder metallurgy technique under the same consolidation processing. Tribological behavior of the composites with electric current was investigated by using a pin-on-disk friction and wear tester. The results show that the friction coefficient and wear rate of the composites decrease with increasing the reinforcement content, and increase with increasing the electric current density; the effects of electric current are more obvious on tribological properties of graphite-Cu composites than on CNTs-Cu composites; for graphite-Cu composites the dominant wear mechanisms are electric arc erosion and adhesive wear, while for CNTs-Cu composites are adhesive wear.展开更多
Bonded Terfenol-D composites,with high electrical resistivity and low eddy current loss,can be used in an alternating magnetic field with high frequency.However,the nonmagnetic binder impairs the magnetostriction of t...Bonded Terfenol-D composites,with high electrical resistivity and low eddy current loss,can be used in an alternating magnetic field with high frequency.However,the nonmagnetic binder impairs the magnetostriction of the composites.To achieve high magnetostriction and low eddy current loss,the mixture of the alloy powder and binder was compressed at low pressure in an oriented magnetic field.After this,the aligned samples were recompressed by cold isostatic pressing（CIP）.Besides,the effect of particle size on the magnetostriction of the bonded Terfenol-D composites was also studied.The results showed that the bonded Terfenol-D composites had excellent magnetostriction when the particle size was 50-80 μm.The oriented magnetic field and CIP could improve the magnetostriction of the bonded composites,which reaches 1020×10-6.The bonded Terfenol-D composites had good compact structure and high density（7.24 g/cm3）.The magnetic loss of the bonded Terfenol-D composites was 192 mW/cm3 at a frequency of 100 kHz in a magnetic field of 960 A/m,which was about one third of that of casting Terfenol-D alloys.展开更多
Ni/n-SiO2 composite coating was electrodeposited by brush-plating with pulse-reverse current（RC）. The morphology, hardness, and tribological properties of the coating were investigated and compared with those of Ni ...Ni/n-SiO2 composite coating was electrodeposited by brush-plating with pulse-reverse current（RC）. The morphology, hardness, and tribological properties of the coating were investigated and compared with those of Ni and composite coatings electrodeposited with direct current（DC）. The results indicate that Ni/n-SiO2 composite coating electrodeposited by RC, because of RC and the nano powders, has denser coating, finer crystal grains, higher hardness（HV650.0, nearly 1.5 times higher than that of Ni coating electrodeposited by DC） and lower friction coefficient（nearly 0.62）, as a result, in the wearing experiment, the Ni/n-SiO2 composite coating electrodeposited by RC has the least worn loss. So this kind of coating has better wear resistance. And RC electro brush-plating can be used as a new technology of brush-plating in the area of wear resistance.展开更多
As the traditional graphite-based composites cannot meet the requirement of rapid developing modern industry,novel sliding electrical contact materials with high self-lubricating performance in multiple environments a...As the traditional graphite-based composites cannot meet the requirement of rapid developing modern industry,novel sliding electrical contact materials with high self-lubricating performance in multiple environments are eagerly required.Herein a copper-based composite with WS2 and graphite as solid lubricant are fabricated by powder metallurgy hot-pressed method.The friction and wear behaviors of the composites with and without current are investigated under the condition with sliding velocity of 10 m/s and normal load of 2.5N/cm 2 in both air and vacuum.Morphologies of the worn surfaces are observed by optical microscope and compositions of the lubricating films are analyzed by XPS.Surface profile curves and roughness of the worn surfaces are obtained by 2205 surface profiler.The results of wear tests show that the friction coefficient and wear volume loss of the composites with current are greater than that without current in both air and vacuum due to the adverse effects of electrical current which damaged the lubricating film partially and roughed the worn surfaces.XPS results demonstrate that the lubricating film formed in air is composed of oxides of Cu,WS2,elemental S and graphite,while the lubricating film formed in vacuum is composed of Cu,WS2 and graphite.Because of the synergetic lubricating action of oxides of Cu,WS2 and graphite,the composites show low friction coefficient and wear volume loss in air condition.Owing to the fact that graphite loses its lubricity which makes WS2 become the only lubricant,severe adhesive and abrasive wear occur and result in a high value of wear rate in vacuum condition.The formation of the lubricating film on the contact interface between the brush and ring is one of the factors which can greatly affect the wear performance of the brushes.The low contact voltage drop of the composites in vacuum condition is attributed to the high content of Cu in the surface film.This study fabricated a kind of new sliding electrical contact self-lubricating composite with dual-lubricant which can work well in both air and vacuum environments and provides a comprehensive analysis on the lubrication mechanisms of the composite.展开更多
Definite-time zero-sequence over-current protection is presently used in systems whose neutral point is grounded by a low resistance(low-resistance grounding systems).These systems frequently malfunction owing to thei...Definite-time zero-sequence over-current protection is presently used in systems whose neutral point is grounded by a low resistance(low-resistance grounding systems).These systems frequently malfunction owing to their high settings of the action value when a high-impedance grounding fault occurs.In this study,the relationship between the zero-sequence currents of each feeder and the neutral branch was analyzed.Then,a grounding protection method was proposed on the basis of the zero-sequence current ratio coefficient.It is defined as the ratio of the zero-sequence current of the feeder to that of the neutral branch.Nonetheless,both zero-sequence voltage and zero-sequence current are affected by the transition resistance,The influence of transition resistance can be eliminated by calculating this coefficient.Therefore,a method based on the zero-sequence current ratio coefficient was proposed considering the significant difference between the faulty feeder and healthy feeder.Furthermore,unbalanced current can be prevented by setting the starting current.PSCAD simulation results reveal that the proposed method shows high reliability and sensitivity when a high-resistance grounding fault occurs.展开更多
Current--voltage measurements obtained from lead zirconate titanate/nickel bilayered hollow cylindrical magnetoelectric composite showed that a sinusoidal current applied to the copper coil wrapped around the hollow c...Current--voltage measurements obtained from lead zirconate titanate/nickel bilayered hollow cylindrical magnetoelectric composite showed that a sinusoidal current applied to the copper coil wrapped around the hollow cylinder circumference induces voltage across the lead zirconate titanate layer thickness. The current--voltage coefficient and the maximum induced voltage in lead zirconate titanate at 1~kHz and resonance （60.1~kHz） frequencies increased linearly with the number of the coil turns and the applied current. The resonance frequency corresponds to the electromechanical resonance frequency. The current--voltage coefficient can be significantly improved by optimizing the magnetoelectric structure geometry and/or increasing the number of coil turns. Hollow cylindrical lead zirconate titanate/nickel structures can be potentially used as current sensors.展开更多
Metal and nano-ceramic nanocomposite coatings were prepared on the gray cast iron surface by the electrodeposition method. The Ni-Co was used as the metal matrix,and nano-Al2O3 was chosen as the second-phase particula...Metal and nano-ceramic nanocomposite coatings were prepared on the gray cast iron surface by the electrodeposition method. The Ni-Co was used as the metal matrix,and nano-Al2O3 was chosen as the second-phase particulates. To avoid poor inter-face bonding and stress distribution,the gradient structure of biology materials was found as the model and therefore the gradient composite coating was prepared. The morphology of the composite coatings was flatter and the microstructure was denser than that of pure Ni-Co coatings. The composite coatings were prepared by different current densities,and the 2-D and 3-D morphologies of the surface coatings were observed. The result indicated that the 2-D structure became rougher and the 3-D surface density of apices became less when the current density was increased. The content of nanoparticulates reached a maximum value at the current density of 40mA·cm^-2,at the same time the properties including microhardness and wear-resistance were analyzed. The microhardness reached a maximum value and the wear volume was also less at the current density of 40mA·cm^-2. The reason was that nano-Al2O3 particles caused dispersive strengthening and grain refining.展开更多
Dual three-phase permanent-magnet synchronous machines(DTP-PMSM)connected with a single neutral point provide a loop for zero-sequence current(ZSC).This paper proposes a novel space vector pulse width modulation(SVPWM...Dual three-phase permanent-magnet synchronous machines(DTP-PMSM)connected with a single neutral point provide a loop for zero-sequence current(ZSC).This paper proposes a novel space vector pulse width modulation(SVPWM)strategy to suppress the ZSC.Five vectors are selected as basic voltage vectors in one switching period.The fundamental and harmonic planes and the zero-sequence plane are taken into consideration to synthesis the reference voltage vector.To suppress the ZSC,a non-zero zero-sequence voltage(ZSV)is generated to compensate the third harmonic back-EMF.Rather than triangular carrier modulation,the sawtooth carrier modulation strategy is used to generate asymmetric PWM signals.The modulation range is investigated to explore the variation of modulation range caused by considering the zero-sequence plane.With the proposed method,the ZSC can be considerably reduced.The simulated and experimental results are presented to validate the effectiveness of the proposed modulation strategy.展开更多
Effects of pulse current on properties of electrodeposited RE-Ni-W-P-SiC composite coating were studied. The results show that hardness of the pulse current electrodeposited composite coatings is higher than that of t...Effects of pulse current on properties of electrodeposited RE-Ni-W-P-SiC composite coating were studied. The results show that hardness of the pulse current electrodeposited composite coatings is higher than that of the direct current electrodeposited composite coatings while other parameters are the same. Otherwise, the deposited velocity is higher, and wear resistance and corrosion resistance of the pulse current electrodeposited composite coatings are also improved when the average current density is 10 A/dm2 , pulse frequency is 800 Hz and duty ratio is 1: 5. The hardness of the coating as-deposited is HV500 - 700, and it reaches HV1300 after heat treatment at 400 ℃ for 1 h.展开更多
In this study, neutral salt spray accelerated corrosion test of copper–aluminium composite under 0–125 A DC current was carried out under 5% concentration. The effect of corrosion behaviour on copper–aluminium comp...In this study, neutral salt spray accelerated corrosion test of copper–aluminium composite under 0–125 A DC current was carried out under 5% concentration. The effect of corrosion behaviour on copper–aluminium composite by DC current was carried out by a scanning electron microscope(SEM) with energy-dispersive spectroscopy(EDS), X-ray diffraction(XRD) patterns, X-ray photoelectron spectroscopy(XPS), weight-loss method and electrochemical analysis. The results show that the current can accelerate the corrosion rate. Meanwhile, the current temperature effect can reduce the corrosion rate. The current caused directional migration of ions resulting in different corrosion products on positive and negative poles of specimen, and the corrosion degree on the positive pole was more serious. The galvanic corrosion mechanism at the copper–aluminium interface is different from the pitting corrosion mechanism far away from the interface, and the latter is more affected by DC current.展开更多
Nickel and silicon dioxide nanoparticle composite coatings were prepared by brush plating with direct and pulse current.The surface morphology,microstructure,hardness and wear resistance of the coatings were investiga...Nickel and silicon dioxide nanoparticle composite coatings were prepared by brush plating with direct and pulse current.The surface morphology,microstructure,hardness and wear resistance of the coatings were investigated by scanning electron microscope(SEM),transmission electron microscope(TEM),mirohardness tester and ball-on-disk tribotester.The results show that the technical parameters,pulse current,duty circle and frequency,are of great influence on the growth of crystalline and properties of the coating.Compared with the coating plated with direct current,the coatings plated with pulse currents have smaller nanocrystalline,contain more SiO2 nanoparticle and have higher hardness and wear resistance.展开更多
-A composite pipeline is defined as a pipeline system composed of one big pipe and one or several small pipes. Based on the theory of wave- current interaction and physical model test, the hydrodynamic characteristics...-A composite pipeline is defined as a pipeline system composed of one big pipe and one or several small pipes. Based on the theory of wave- current interaction and physical model test, the hydrodynamic characteristics of the submarine composite pipeline in wave-current coexisting field (both regular and irregular waves) are investigated. The so-called 'modified diameter method' is used for analyzing the in-fine hydrodynamic coefficients of the composite pipeline, which are well related to KC number. The comparison of test data for regular and irregular waves shows that in the region of 90 > KC> 20, the results in these two cases can be unified. The effect of water depth is analyzed in details. The relationships between CD, CM and KC , which are based on the results of present research, may be used as a reference in engineering design.展开更多
Dense and submicron-grained NiAl-Al2O3 composite was fabricated by pulse current auxiliary sintering（PCAS）.Its microstructure was analyzed by XRD,SEM and TEM,and its mechanical behavior was evaluated through compres...Dense and submicron-grained NiAl-Al2O3 composite was fabricated by pulse current auxiliary sintering（PCAS）.Its microstructure was analyzed by XRD,SEM and TEM,and its mechanical behavior was evaluated through compression test and fracture toughness test.The average grain sizes of NiAl and Al2O3 are about 200 nm and 100 nm respectively.The Al2O3 particles dispersed in NiAl matrix,forming intergranular structure and intragranular structure.During sintering,Al2O3 particles were remarkably spherized due to the unique sintering mechanism of PCAS,which is beneficial to the improvement of toughness.The NiAl-Al2O3 composite exhibits high compressive yield strength,whether at room temperature or elevated temperature.Its room-temperature（23 ℃） and elevated-temperature（1 200 ℃） compressive yield strength are up to 2 050 MPa and 140 MPa,respectively.Meanwhile,its fracture toughness is significantly enhanced,which is up to 8.2 MPa？m1/2.It is suggested that the main strengthening-toughening mechanisms are grain refinement strengthening and Al2O3 dispersion strengthening.The fracture of larger NiAl grain is the transgranular cleavage and this is induced by crack tip deflection and grain boundary weakening which are caused by intergranular and intragranular Al2O3 particles,respectively.展开更多
Compared with the traditional three-phase star connection winding,the open-end winding permanent magnet synchronous motor(OW-PMSM)system with a common direct current(DC)bus has a zero-sequence circuit,which makes the ...Compared with the traditional three-phase star connection winding,the open-end winding permanent magnet synchronous motor(OW-PMSM)system with a common direct current(DC)bus has a zero-sequence circuit,which makes the common-mode voltage and the back electromotive force(EMF)harmonic generated by the inverters produce the zero-sequence current in the zero-sequence circuit,and the zero-sequence current has great influence on the operation efficiency and stability of the motor control system.A zero-sequence current suppression strategy is presented based on model predictive current control for OW-PMSM.Through the mathematical model of OW-PMSM to establish the predictive model and the zero-sequence circuit model,the common-mode voltage under different voltage vector combinations is fully considered during vector selection and action time calculation.Then zero-sequence loop constraints are established,so as to suppress the zero-sequence current.In the end,the control strategy proposed in this paper is verified by simulation experiments.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.52075351,51604177)the National Key Research and Development Program of China(No.2019YFA0705701)+4 种基金the National Funded Postdoctoral Researcher Program(No.GZC20231762)the Major S&T Infrastructure Construction Project of Sichuan Province(No.2020-510000-73-01441847)the International S&T Innovation Cooperation Program of Sichuan Province(No.2020YFH0039)the Chengdu International S&T Cooperation Funded Project(Nos.2020-GH02-00006HZ,2022-GH02-00027-HZ)the“1000 Talents Plan”of Sichuan Province,and the Talent Introduction Program of Sichuan University(No.YJ201410)。
文摘Anode active materials involving transition metal oxides and sulfides are of great significance for high energy density lithium-ion batteries(LIBs),but the huge volume expansion and inferior electronic conductivity upon cycling critically constrain their further application.Herein,from a new perspective,a highly conductive and stable 3D flexible composite current collector is rationally designed by facilely electrodepositing metallic Ni thin layer onto the carbon cloth(CC/Ni),which endows the supported active materials with exceptional electronic conductivity and structural stability.In addition,the homogeneously distributed metallic Ni protrusions external CC can strongly bond with the active components,ensuring the structural integrity of electrodes upon cycling.More importantly,the 3D network structure with large specific surface area provides abundant space to alleviate the volume expansion and more active sites for electrochemical reactions.Therefore,taking Ni_(3)S_(2)nanosheet(Ni_(3)S_(2)NS)anode as an example,the prepared Ni_(3)S_(2)NS@CC/Ni electrode shows a high specific capacity of 2.32 mAh/cm^(2)at 1mA/cm^(2)and high capacity retention of 1.68 mAh/cm^(2)at a high rate of 8mA/cm^(2).This study provides a universal approach to obtain highly conductive and stable 3D flexible current collectors towards high performance metal-ion batteries beyond LIBs.
基金National Natural Science Foundation of China (50432020)Henan Innovation Project for University Prominent Re- search Talents (2007KYCX008)+3 种基金Henan Education Department Science and Technology Project (2007430004)Henan Plan Project for College Youth Backbone TeacherHenan University of Science and Technology Major Pre-research Foundation (2005ZD003)Henan University of Science and Technology Personnel Scientific Research Foundation (of023)
文摘Two Al2O3/Cu composites containing 0.24 wt.% Al2O3 and 0.60 wt.% Al2O3 separately are prepared by internal oxidation. Effects of sliding speed and pressure on the frictional characteristics of the composites and copper against brass are investigated and compared. The changes in morphology of the sliding surface and subsurface are examined with scanning electron microscope （SEM） and energy dispersive X-ray spectrum （EDS）. The results show that the wear resistance of the Al2O3/Cu composites is superior to that of copper under the same conditions, Under a given electrical current, the wear rate of Al2O3/Cu composites decreases as the Al2O3-content increases, However, the wear rates of the Al2O3/Cu composites and copper increase as the sliding speed and pressure increase under dry sliding condition. The main wear mechanisms for Al2O3/Cu composites are of abrasion and adhesion; for copper, it is adhesion, although wear by oxidation and electrical erosion can also be observed as the speed and pressure rise.
基金Project(2007CB607603)supported by the National Basic Research Program of China
文摘Cu matrix composite reinforced with 10%（volume fraction） carbon nanotubes（CNTs/Cu） and pure Cu bulk were prepared by powder metallurgy techniques under the same consolidation processing condition.The effect of electrical current on tribological property of the materials was investigated by using a pin-on-disk friction and wear tester.The results show that the friction coefficient and wear rate of CNTs/Cu composite as well as those of pure Cu bulk increase with increasing the electrical current without exception,and the effect of electrical current is more obvious on tribological property of pure Cu bulk than on that of CNTs/Cu composite;the dominant wear mechanisms are arc erosion wear and plastic flow deformation,respectively;CNTs can improve tribological property of Cu matrix composites with electrical current.
基金Project(51371114)supported by the National Natural Science Foundation of ChinaProject(2012CB619600)supported by the National Basic Research Program of China+1 种基金Project(10SG15)supported by the Dawn Program of Shanghai Education Commission,ChinaProject(12XD1402800)supported by Shanghai Science and Technology Committee,China
文摘The effects of current pulsing on the microstructure, hardness and tensile properties at different temperatures of gas tungsten arc （GTA） weldments of titanium matrix composites were studied. Full-penetration butt joints were made with or without current pulsing. Optical microscopy, hardness test and scanning electron microscopy were employed to evaluate the metallurgical characteristics of welded joints. Tensile properties of weldments at different temperatures were studied and correlated with the microstructure. The results exhibit that current pulsing leads to the refinement of the weld microstrucmre and TiB whisker and the redistribution of reinforcements resulting in higher hardness, tensile strength and ductility of weldments in the as-welded condition.
基金Projects(51004056,51004057)supported by the National Natural Science Foundation of ChinaProject(KKZ6201152009)supported by the Opening Foundation of Key Laboratory of Inorganic Coating Materials,Chinese Academy of Sciences+2 种基金Project(2010ZC052)supported by the Applied Basic Research Foundation of Yunnan Province,ChinaProject(20125314110011)supported by the Specialized Research Fund for the Doctoral Program of Higher Education,ChinaProject(2010247)supported by Analysis&Testing Foundation of Kunming University of Science and Technology,China
文摘Al/conductive coating/α-Pb O2-Ce O2-Ti O2/β-PbO 2-MnO 2-WC-Zr O2 composite electrode material was prepared on Al/conductive coating/α-PbO 2-Ce O2-Ti O2 substrate by electrochemical oxidation co-deposition technique. The effects of current density on the chemical composition, electrocatalytic activity, and stability of the composite anode material were investigated by energy dispersive X-ray spectroscopy（EDXS）, anode polarization curves, quasi-stationary polarization（Tafel） curves, electrochemical impedance spectroscopy（EIS）, scanning electron microscopy（SEM）, and X-ray diffraction（XRD）. Results reveal that the composite electrode obtained at 1 A/dm2 possesses the lowest overpotential（0.610 V at 500 A/m2） for oxygen evolution, the best electrocatalytic activity, the longest service life（360 h at 40 °C in 150 g/L H2SO4 solution under 2 A/cm2）, and the lowest cell voltage（2.75 V at 500 A/m2）. Furthermore, with increasing current density, the coating exhibits grain growth and the decrease of content of Mn O2. Only a slight effect on crystalline structure is observed.
基金Project (2007CB607603) supported by the National Basic Research Program of China
文摘CNTs-Cu and graphite-Cu composites were separately prepared by powder metallurgy technique under the same consolidation processing. Tribological behavior of the composites with electric current was investigated by using a pin-on-disk friction and wear tester. The results show that the friction coefficient and wear rate of the composites decrease with increasing the reinforcement content, and increase with increasing the electric current density; the effects of electric current are more obvious on tribological properties of graphite-Cu composites than on CNTs-Cu composites; for graphite-Cu composites the dominant wear mechanisms are electric arc erosion and adhesive wear, while for CNTs-Cu composites are adhesive wear.
基金supported by the National Natural Science Foundation of China (No.51004011 and 50874010)the Specialized Research Fund for the Doctoral Program of China Higher Education (No.20090006120012)
文摘Bonded Terfenol-D composites,with high electrical resistivity and low eddy current loss,can be used in an alternating magnetic field with high frequency.However,the nonmagnetic binder impairs the magnetostriction of the composites.To achieve high magnetostriction and low eddy current loss,the mixture of the alloy powder and binder was compressed at low pressure in an oriented magnetic field.After this,the aligned samples were recompressed by cold isostatic pressing（CIP）.Besides,the effect of particle size on the magnetostriction of the bonded Terfenol-D composites was also studied.The results showed that the bonded Terfenol-D composites had excellent magnetostriction when the particle size was 50-80 μm.The oriented magnetic field and CIP could improve the magnetostriction of the bonded composites,which reaches 1020×10-6.The bonded Terfenol-D composites had good compact structure and high density（7.24 g/cm3）.The magnetic loss of the bonded Terfenol-D composites was 192 mW/cm3 at a frequency of 100 kHz in a magnetic field of 960 A/m,which was about one third of that of casting Terfenol-D alloys.
文摘Ni/n-SiO2 composite coating was electrodeposited by brush-plating with pulse-reverse current（RC）. The morphology, hardness, and tribological properties of the coating were investigated and compared with those of Ni and composite coatings electrodeposited with direct current（DC）. The results indicate that Ni/n-SiO2 composite coating electrodeposited by RC, because of RC and the nano powders, has denser coating, finer crystal grains, higher hardness（HV650.0, nearly 1.5 times higher than that of Ni coating electrodeposited by DC） and lower friction coefficient（nearly 0.62）, as a result, in the wearing experiment, the Ni/n-SiO2 composite coating electrodeposited by RC has the least worn loss. So this kind of coating has better wear resistance. And RC electro brush-plating can be used as a new technology of brush-plating in the area of wear resistance.
基金supported by Major Research Program of National Natural Science Foundation of China(Grant No.91026018)National Natural Science Foundation of China(Grant No.60979017)Doctoral Fund of Ministry of Education of China(Grant No.20110111110015)
文摘As the traditional graphite-based composites cannot meet the requirement of rapid developing modern industry,novel sliding electrical contact materials with high self-lubricating performance in multiple environments are eagerly required.Herein a copper-based composite with WS2 and graphite as solid lubricant are fabricated by powder metallurgy hot-pressed method.The friction and wear behaviors of the composites with and without current are investigated under the condition with sliding velocity of 10 m/s and normal load of 2.5N/cm 2 in both air and vacuum.Morphologies of the worn surfaces are observed by optical microscope and compositions of the lubricating films are analyzed by XPS.Surface profile curves and roughness of the worn surfaces are obtained by 2205 surface profiler.The results of wear tests show that the friction coefficient and wear volume loss of the composites with current are greater than that without current in both air and vacuum due to the adverse effects of electrical current which damaged the lubricating film partially and roughed the worn surfaces.XPS results demonstrate that the lubricating film formed in air is composed of oxides of Cu,WS2,elemental S and graphite,while the lubricating film formed in vacuum is composed of Cu,WS2 and graphite.Because of the synergetic lubricating action of oxides of Cu,WS2 and graphite,the composites show low friction coefficient and wear volume loss in air condition.Owing to the fact that graphite loses its lubricity which makes WS2 become the only lubricant,severe adhesive and abrasive wear occur and result in a high value of wear rate in vacuum condition.The formation of the lubricating film on the contact interface between the brush and ring is one of the factors which can greatly affect the wear performance of the brushes.The low contact voltage drop of the composites in vacuum condition is attributed to the high content of Cu in the surface film.This study fabricated a kind of new sliding electrical contact self-lubricating composite with dual-lubricant which can work well in both air and vacuum environments and provides a comprehensive analysis on the lubrication mechanisms of the composite.
基金supported in part by National Key Research and Development Program of China(2016YFB0900603)Technology Projects of State Grid Corporation of China(52094017000W).
文摘Definite-time zero-sequence over-current protection is presently used in systems whose neutral point is grounded by a low resistance(low-resistance grounding systems).These systems frequently malfunction owing to their high settings of the action value when a high-impedance grounding fault occurs.In this study,the relationship between the zero-sequence currents of each feeder and the neutral branch was analyzed.Then,a grounding protection method was proposed on the basis of the zero-sequence current ratio coefficient.It is defined as the ratio of the zero-sequence current of the feeder to that of the neutral branch.Nonetheless,both zero-sequence voltage and zero-sequence current are affected by the transition resistance,The influence of transition resistance can be eliminated by calculating this coefficient.Therefore,a method based on the zero-sequence current ratio coefficient was proposed considering the significant difference between the faulty feeder and healthy feeder.Furthermore,unbalanced current can be prevented by setting the starting current.PSCAD simulation results reveal that the proposed method shows high reliability and sensitivity when a high-resistance grounding fault occurs.
基金supported by the National Natural Science Foundation of China (Grant Nos. 50572006, 50802008 and 50874010)the Natural Science Foundation of Beijing, China (Grant No. 2073026)+2 种基金the Program for New Century Excellent Talents in University(Grant No. 20060420152)Scholars and Innovative Research Team in University (Grant No. 0509)Alex A. Volinsky wouldlike to acknowledge support from NSF (Grant No. CMMI-0600266)
文摘Current--voltage measurements obtained from lead zirconate titanate/nickel bilayered hollow cylindrical magnetoelectric composite showed that a sinusoidal current applied to the copper coil wrapped around the hollow cylinder circumference induces voltage across the lead zirconate titanate layer thickness. The current--voltage coefficient and the maximum induced voltage in lead zirconate titanate at 1~kHz and resonance （60.1~kHz） frequencies increased linearly with the number of the coil turns and the applied current. The resonance frequency corresponds to the electromechanical resonance frequency. The current--voltage coefficient can be significantly improved by optimizing the magnetoelectric structure geometry and/or increasing the number of coil turns. Hollow cylindrical lead zirconate titanate/nickel structures can be potentially used as current sensors.
基金the National Natural Science Foundation of China (No50635030)the National Basic Research of China (No2007CB616913)the Program for New Century Excellent Talents in University (2005)
文摘Metal and nano-ceramic nanocomposite coatings were prepared on the gray cast iron surface by the electrodeposition method. The Ni-Co was used as the metal matrix,and nano-Al2O3 was chosen as the second-phase particulates. To avoid poor inter-face bonding and stress distribution,the gradient structure of biology materials was found as the model and therefore the gradient composite coating was prepared. The morphology of the composite coatings was flatter and the microstructure was denser than that of pure Ni-Co coatings. The composite coatings were prepared by different current densities,and the 2-D and 3-D morphologies of the surface coatings were observed. The result indicated that the 2-D structure became rougher and the 3-D surface density of apices became less when the current density was increased. The content of nanoparticulates reached a maximum value at the current density of 40mA·cm^-2,at the same time the properties including microhardness and wear-resistance were analyzed. The microhardness reached a maximum value and the wear volume was also less at the current density of 40mA·cm^-2. The reason was that nano-Al2O3 particles caused dispersive strengthening and grain refining.
基金supported in part by the National Natural Science Foundation of China under Grant 51977099。
文摘Dual three-phase permanent-magnet synchronous machines(DTP-PMSM)connected with a single neutral point provide a loop for zero-sequence current(ZSC).This paper proposes a novel space vector pulse width modulation(SVPWM)strategy to suppress the ZSC.Five vectors are selected as basic voltage vectors in one switching period.The fundamental and harmonic planes and the zero-sequence plane are taken into consideration to synthesis the reference voltage vector.To suppress the ZSC,a non-zero zero-sequence voltage(ZSV)is generated to compensate the third harmonic back-EMF.Rather than triangular carrier modulation,the sawtooth carrier modulation strategy is used to generate asymmetric PWM signals.The modulation range is investigated to explore the variation of modulation range caused by considering the zero-sequence plane.With the proposed method,the ZSC can be considerably reduced.The simulated and experimental results are presented to validate the effectiveness of the proposed modulation strategy.
文摘Effects of pulse current on properties of electrodeposited RE-Ni-W-P-SiC composite coating were studied. The results show that hardness of the pulse current electrodeposited composite coatings is higher than that of the direct current electrodeposited composite coatings while other parameters are the same. Otherwise, the deposited velocity is higher, and wear resistance and corrosion resistance of the pulse current electrodeposited composite coatings are also improved when the average current density is 10 A/dm2 , pulse frequency is 800 Hz and duty ratio is 1: 5. The hardness of the coating as-deposited is HV500 - 700, and it reaches HV1300 after heat treatment at 400 ℃ for 1 h.
基金financially supported by the National Natural Science Foundation of China(No.U1604251)the Doctoral Start-up Foundation of Liaoning Province(No.2019-BS-178)the National Outstanding Youth Science Fund Project of National Natural Science Foundation of China(CN)(No.U52001216)。
文摘In this study, neutral salt spray accelerated corrosion test of copper–aluminium composite under 0–125 A DC current was carried out under 5% concentration. The effect of corrosion behaviour on copper–aluminium composite by DC current was carried out by a scanning electron microscope(SEM) with energy-dispersive spectroscopy(EDS), X-ray diffraction(XRD) patterns, X-ray photoelectron spectroscopy(XPS), weight-loss method and electrochemical analysis. The results show that the current can accelerate the corrosion rate. Meanwhile, the current temperature effect can reduce the corrosion rate. The current caused directional migration of ions resulting in different corrosion products on positive and negative poles of specimen, and the corrosion degree on the positive pole was more serious. The galvanic corrosion mechanism at the copper–aluminium interface is different from the pitting corrosion mechanism far away from the interface, and the latter is more affected by DC current.
文摘Nickel and silicon dioxide nanoparticle composite coatings were prepared by brush plating with direct and pulse current.The surface morphology,microstructure,hardness and wear resistance of the coatings were investigated by scanning electron microscope(SEM),transmission electron microscope(TEM),mirohardness tester and ball-on-disk tribotester.The results show that the technical parameters,pulse current,duty circle and frequency,are of great influence on the growth of crystalline and properties of the coating.Compared with the coating plated with direct current,the coatings plated with pulse currents have smaller nanocrystalline,contain more SiO2 nanoparticle and have higher hardness and wear resistance.
文摘-A composite pipeline is defined as a pipeline system composed of one big pipe and one or several small pipes. Based on the theory of wave- current interaction and physical model test, the hydrodynamic characteristics of the submarine composite pipeline in wave-current coexisting field (both regular and irregular waves) are investigated. The so-called 'modified diameter method' is used for analyzing the in-fine hydrodynamic coefficients of the composite pipeline, which are well related to KC number. The comparison of test data for regular and irregular waves shows that in the region of 90 > KC> 20, the results in these two cases can be unified. The effect of water depth is analyzed in details. The relationships between CD, CM and KC , which are based on the results of present research, may be used as a reference in engineering design.
文摘Dense and submicron-grained NiAl-Al2O3 composite was fabricated by pulse current auxiliary sintering（PCAS）.Its microstructure was analyzed by XRD,SEM and TEM,and its mechanical behavior was evaluated through compression test and fracture toughness test.The average grain sizes of NiAl and Al2O3 are about 200 nm and 100 nm respectively.The Al2O3 particles dispersed in NiAl matrix,forming intergranular structure and intragranular structure.During sintering,Al2O3 particles were remarkably spherized due to the unique sintering mechanism of PCAS,which is beneficial to the improvement of toughness.The NiAl-Al2O3 composite exhibits high compressive yield strength,whether at room temperature or elevated temperature.Its room-temperature（23 ℃） and elevated-temperature（1 200 ℃） compressive yield strength are up to 2 050 MPa and 140 MPa,respectively.Meanwhile,its fracture toughness is significantly enhanced,which is up to 8.2 MPa？m1/2.It is suggested that the main strengthening-toughening mechanisms are grain refinement strengthening and Al2O3 dispersion strengthening.The fracture of larger NiAl grain is the transgranular cleavage and this is induced by crack tip deflection and grain boundary weakening which are caused by intergranular and intragranular Al2O3 particles,respectively.
基金Fundamental Research Funds for the Central Universities,China(No.2232019D3-53)Initial Research Funds for Young Teachers of Donghua University,China(104070053029)Shanghai Rising-Star Program,China(No.19QA1400400)。
文摘Compared with the traditional three-phase star connection winding,the open-end winding permanent magnet synchronous motor(OW-PMSM)system with a common direct current(DC)bus has a zero-sequence circuit,which makes the common-mode voltage and the back electromotive force(EMF)harmonic generated by the inverters produce the zero-sequence current in the zero-sequence circuit,and the zero-sequence current has great influence on the operation efficiency and stability of the motor control system.A zero-sequence current suppression strategy is presented based on model predictive current control for OW-PMSM.Through the mathematical model of OW-PMSM to establish the predictive model and the zero-sequence circuit model,the common-mode voltage under different voltage vector combinations is fully considered during vector selection and action time calculation.Then zero-sequence loop constraints are established,so as to suppress the zero-sequence current.In the end,the control strategy proposed in this paper is verified by simulation experiments.
